A PROCESS FOR MANUFACTURING POLYMER COATED, CONTROLLED RELEASE FERTILIZER, AND RELATED SYSTEMS
20180214834 ยท 2018-08-02
Inventors
Cpc classification
B01J2/006
PERFORMING OPERATIONS; TRANSPORTING
B65G21/2036
PERFORMING OPERATIONS; TRANSPORTING
B05D2258/02
PERFORMING OPERATIONS; TRANSPORTING
B01J2/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
B01J2/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A frame for holding a small object while coating the small object with a coating composition includes a first plate and a second plate coupled to the first plate and movable relative to the first plate. The first plate includes a platform having a longitudinal axis. The second plate includes a wall adjacent a hole, wherein the hole receives the first plate's platform and is configured to allow the wall to move relative to the platform in a direction along the platform's longitudinal axis. When the first and second plate are coupled together, the first plate's platform and the second plate's wall define a receptacle of the frame that is operable to hold a small object.
Claims
1. A method for coating a small object with a coating composition, the method comprising: moving a first frame in a first direction, the first frame having a plurality of receptacles disposed in an orderly arrangement that move with the first frame; while the first frame is moving, positioning a small object in a respective one of the first frame's plurality of receptacles such that a region of the small object contacts the receptacle; while the first frame is moving, applying a coating composition onto the small object; moving a second frame in a second direction, the second frame having a plurality of receptacles disposed in an orderly arrangement that move with the second frame; while the first and second frames are moving: transferring the small object from the first frame's receptacle to a respective one of the second frame's plurality of receptacles, and positioning the small object such that the region of the small object that contacted the first frame's receptacle does not contact the second frame's receptacle; and while the second frame is moving, applying a coating composition onto the small object.
2. The method of claim 1 wherein the first frame's orderly arrangement includes a rectangular arrangement having three receptacles disposed side-by-side and substantially perpendicular to the first direction that the first frame moves in.
3. The method of claim 1 wherein moving the first frame in the first direction includes moving the first frame in a direction that is opposite the second direction that the second frame moves in.
4. The method of claim 1 wherein moving the first frame includes moving the first frame along an oblong, circular path.
5. The method of claim 1 wherein positioning a small object in a respective one of the first frame's plurality of receptacles includes positioning a single object into the receptacle.
6. The method of claim 1 wherein positioning a small object in a respective one of the first frame's plurality of receptacles includes dropping at least one of the following: a pellet, a spike, a granule, a briquette and a nodule, into the receptacle.
7. The method of claim 1 wherein positioning a small object in a respective one of the first frame's plurality of receptacles includes positioning the small object on a platform of the receptacle that is movable relative to a wall of the receptacle.
8. The method of claim 1 wherein applying a coating composition onto the small object includes at least one of the following: spraying, melting, melt extruding, thermal laminating, and powder coating.
9. The method of claim 1 wherein applying a coating composition onto the small object includes cutting the coating composition with an edge of a wall of the receptacle.
10. The method of claim 9 wherein cutting the coating composition with an edge of a wall of the receptacle includes moving the receptacle's wall.
11. The method of claim 1 wherein applying a coating composition onto the small object includes at least one of the following: a polymer, a processing additive, a plasticizer, a wax, a co-initiator or cure catalyst, an antioxidant, a tackifier, a mineral filler, a pigment, a lubricant, and a taggant.
12. The method of claim 1 wherein the second frame's orderly arrangement includes a rectangular arrangement having three receptacles disposed side-by-side and substantially perpendicular to the second direction that the second frame moves in.
13. The method of claim 1 wherein moving the second frame in the second direction includes moving the second frame at the same speed that the first frame moves.
14. The method of claim 1 wherein transferring the small object from the first frame's receptacle to the second frame's receptacle includes moving the first frame in the second direction, adjacent the second frame.
15. The method of claim 1 wherein transferring the small object from the first frame's receptacle to the second frame's receptacle includes dropping the small object into the second frame's receptacle.
16. The method of claim 1 wherein transferring the small object from the first frame's receptacle to the second frame's receptacle includes holding the small object in the receptacle by applying a vacuum to a port in the first frame's receptacle.
17. The method of claim 1 wherein positioning the small object in the second frame's receptacle includes locating the second frame's receptacle immediately adjacent the first frame's receptacle before transferring the small object to the second frame's receptacle.
18. The method of claim 1 wherein positioning the small object in the second frame's receptacle includes positioning the small object on a platform of the receptacle that is movable relative to a wall of the receptacle.
19. A frame for holding a small object while coating the small object with a coating composition; the frame comprising: a first plate including a platform having a longitudinal axis; a second plate coupled to the first plate and movable relative to the first plate, the second plate including a wall adjacent a hole, wherein the hole receives the first plate's platform and is configured to allow the wall to move relative to the platform in a direction along the platform's longitudinal axis; wherein the platform and wall define a receptacle of the frame operable to hold a small object.
20. The frame of claim 19 wherein: the first plate includes a plurality of platforms each having a respective longitudinal axis, and the second plate includes: a plurality of holes each corresponding to a respective one of the first plate's platforms, and a plurality of walls each corresponding to a respective one of the second plate's holes.
21. The frame of claim 19 wherein the second plate's wall surrounds the second plate's hole.
22. The frame of claim 19 wherein the second plate's wall includes an edge configured to cut a coating composition.
23. The frame of claim 19 wherein the first plate's platform includes a cylindrical shape.
24. The frame of claim 19 wherein the first frame's platform includes a bore aligned with the platform's longitudinal axis.
25. The frame of claim 19 wherein the receptacle includes a rectangular shape.
26. A system for coating a small object with a coating composition, the system comprising: a first frame to hold a small object, the first frame comprising: a first plate including a platform having a longitudinal axis, a second plate coupled to the first plate and movable relative to the first plate, the second plate including a wall adjacent a hole, wherein the hole receives the first plate's platform and is configured to allow the wall to move relative to the platform in a direction along the platform's longitudinal axis, wherein the platform and wall define a receptacle of the first frame to hold the small object; a first conveyor operable to convey the first frame toward a second conveyor; a first applicator operable to coat a small object held in the receptacle of the first frame with a coating composition; a second frame to hold a small object, the second frame comprising: a first plate including a platform having a longitudinal axis, a second plate coupled to the first plate and movable relative to the first plate, the second plate including a wall adjacent a hole, wherein the hole receives the first plate's platform and is configured to allow the wall to move relative to the platform in a direction along the platform's longitudinal axis, wherein the platform and wall define a receptacle of the second frame to hold the small object; a second conveyor operable to convey the second frame toward a collector; a transfer interface where, when a small object is held in the receptacle of the first frame, the small object is transferred to the receptacle of the second frame; a second applicator operable to coat a small object held in the receptacle of the second frame with a coating composition.
27. The system of claim 26 wherein the first conveyor is disposed above the second conveyor, and the transfer interface lies between the first and second conveyors and includes a portion of the first conveyor above and immediately adjacent a portion of the second conveyor.
28. The system of claim 26 wherein the first conveyor includes a component to secure the small object in the first frame's receptacle as the first frame's receptacle enters the transfer interface.
29. The system of claim 28 wherein the component to secure the small object in the first frame's receptacle includes pump that generates a vacuum between the small object and the platform of the first frame's receptacle.
30. The system of claim 28 wherein: gravity holds the small object in the first frame's receptacle as the first conveyor conveys the first frame toward the second conveyor, gravity urges the small object from the first frame's receptacle and toward the second frame's receptacle, and gravity holds the small object in the second frame's receptacle as the second conveyor conveys the second frame toward the collector.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0017]
[0018]
[0019]
[0020]
[0021]
[0022]
[0023]
[0024]
DETAILED DESCRIPTION
[0025]
[0026] The system 20 includes a first frame 26 carried by a first conveyor 28 toward an applicator 30 that may apply a coating composition to a region of the small object 22, and a second frame 32 carried by a second conveyor 34 toward an applicator 36 that may apply a coating composition to another region of the small object 22. Each of the first and second frames 26 and 30 (discussed in greater detail in conjunction with
[0027] In operation, the first conveyor 28 moves a first frame 26 in the direction indicated by the arrow 48. While the first frame 26 is moving, the distributor 44 positions a small object 22 in a receptacle 38 of the first frame 26 such that a region 50 (
[0028] Because the wall 42 of each receptacle 38 moves relative to the platform 40 of each receptacle 38, a small object 22 may be easily positioned and held in the receptacle 38 while the small object 22 is moved to the applicator 30 and 36 of the system 20 to have a coating composition evenly applied to it. In addition, the small object 22 may be easily transferred to and positioned in the second frame's receptacle so that the exposed region of the small object 22 is the region that was not exposed before the transfer. Thus, the frames 26 and 32 allow one to use a continuous-run method to produce a uniformly-coated small object 22.
[0029] Still referring to
[0030] The first and second conveyors 28 and 34, respectively, may be any desired conveyor capable of moving their respective frames 26 and 32. For example, in this and other embodiments, the first conveyor 28 is a conventional conveyor system that moves the first frame 26 along an oblong circular path. To couple the first frame 26 to the first conveyor 28, the first frame 26 may be bolted to the conveyor belt 58. Similarly, the second conveyor 34 is a conventional conveyor system that moves the second frame along an oblong circular path. To couple the second frame 32 to the second conveyor 34, the second frame 32 may also be bolted to the conveyor belt 60. In other embodiments, the first and second conveyors 28 and 34 may move their respective frames 26 and 32 along different paths, such as a rectangular path or a non-oblong circular path.
[0031] Still referring to
[0032] Still referring to
[0033] In other embodiments of the system 20, each of the applicators 30 and 36 may include a nozzle that sprays the coating composition onto the respective exposed regions of the small object 22. The nozzle may be configured to spray a molten coating composition or a solution of the coating composition dissolved in a solvent. The temperature of the coating composition may range from 40 C. to 400 C. In yet another embodiment of the system 20, the applicators 30 and 36 may include an electrostatic powder-coating system. In this embodiment the powder mixture adheres to the surface of the fertilizer granules and may be heated by an infrared heater to melt and fuse the powder into a film on the small object. In yet another embodiment of the system 20, each of the applicators 30 and 36 may include an ultraviolet or electron beam curing system in which a two-part epoxy based coating composition may be cured by ultraviolet radiation and/or an electron beam.
[0034] In other embodiments of the system 20, each of the applicators 30 and 36 may be a polymer film feeding unit that applies a layer of preformed polymer film 24 onto the respective exposed regions of the small object 22. The polymer film is heated and softened by a suitable heater (not shown) before applying the film onto the respective exposed regions of the small object 22.
[0035] Other embodiments of the system 20 are possible. For example, one or both of the conveyors 28 and 34 may include more than one applicator 30 and 36, respectively. In addition, each of the applicators 30 and 36 may be different than the other. Also, one or both of the conveyors 28 and 34 may include a system for removing dust from the surface of the small object just before the coating composition is applied. Dust may interfere in the adhesion of the coating onto the surface and may cause the coating to separate from the small object. The dusting system may include a pressurized air nozzle. In yet other embodiments one or more of the conveyors 30 and 36 may include a surface-priming system to prepare the small object's surface for coating. Any surface priming methods such as corona treatment, surface heat treatment, surface etching, plasma treatment, adhesive spray may be employed.
[0036]
[0037] As previously mentioned, the first frame 26 includes a plurality of receptacles 38 each configured to receive a small object 22 and each defined by a platform 40 and a wall 42. The first frame 26 may include any desired number of receptacles 38 disposed in any desired orderly arrangement. For example, as shown in
[0038] The first frame 26 may be configured as desired to allow the wall 42 and platform 40 to be moved relative to each other. For example, in this and other embodiments, the first frame 26 includes a first plate 72 that is coupled to the first conveyor's conveyor belt 58, and a second plate 74 that is movable relative to the first plate, while the first conveyor 28 moves the first plate 72. The first plate 72 includes a number of platforms 40 each having a bore 73 in which a vacuum may be generated to hold the small object 22 to the platform 40. The number of platforms 40 equals the number of receptacles 38 to be included in the first frame 26. So, if the first frame 26 includes one receptacle 38, then the first plate 72 would include one platform 40. Similarly, the second plate 74 includes a number of holes 76 and a number of walls 42 both equal to the number of receptacles 38 to be included in the first frame 26. So, if the first frame 26 includes one receptacle 38, then the second plate 74 would include one hole 76 and one wall 42. When the first plate 72 and the second plate 74 are coupled together, the first plate's platform 40 extends into the second plate's hole 76, and when the second plate 74 moves relative to the first plate 72, the platform 40 slides in the hole 76 as shown by the two views in
[0039] The second plate 74 may be moved relative to the first plate 72 in any desired manner. For example, in this and other embodiments, a hydraulic pump (not shown) pumps hydraulic fluid 78 into a cavity between the two plates 72 and 74 to move the wall 42 away from the platform 40. To move the wall 42 toward the platform 40, the hydraulic fluid is allowed to escape the cavity, and thus, allow the weight of the second plate 74 to push the hydraulic fluid out of the cavity. A switch (not shown) located at a desired location on the path of the first conveyor 28 may trigger a valve to open a conduit between the cavity and the high-pressure hydraulic fluid to allow the high-pressure hydraulic fluid into the cavity. Another switch (not shown) located at another desired location on the path of the first conveyor 28 may trigger the open valve to close and may trigger another valve to open a conduit between the cavity and low-pressure hydraulic fluid to allow the hydraulic fluid in the cavity to leave the cavity.
[0040] When the first frame 26 moves in the direction indicated by the arrow 56 in
[0041] Other embodiments are possible. For example, the second plate 74 may be moved relative to the first plate 72 by a pneumatic circuit that urges the two plates away from and toward each other. As another example, the cam or wedge may move the second plate 74 relative to the first plate 72 while the first and second plates 72 and 74, respectively are moved in the direction indicated by the arrow 48 in
[0042]
[0043] As previously mentioned, the coating composition 24 may be any desired composition that performs a desired function. For example, the composition may include a polymer, a processing additive, a plasticizer, a wax, a co-initiator or cure catalyst, an antioxidant, a tackifier, a mineral filler, a pigment, a lubricant, and/or a taggant. More specifically, the coating composition 24 may be a single component or a mixture or blend of two or more components, and may be a solution, a paste, a melt, or a dry film, or a powder. As a melt the majority component is in a molten state and the rest of the constituents (if any) are either in a molten state or dispersed or dissolved in the composition 24. As a solution the components of the composition 24 are either dissolved or suspended in a solution (aqueous or non-aqueous). As a dry film the constituents of the coating composition 24 are pre-made into a film that may contain all of the constituents in its structure. As a dry powder the coating composition 24 is a fine powder and the constituents of the coating composition 24 are mixed in the powder mix.
[0044] In some embodiments the coating composition 24 includes a polymer that may be a biodegradable or a non-biodegradable thermoplastic resin of natural or synthetic origin, a thermoplastic elastomer, a thermosetting resin, an alkyd resin, an ultraviolet or electron-beam curable resin, a biopolymer, and a natural polymer, their copolymer or blend. The thermoplastic polymer may be selected from a group that includes: polyacetals, nylons, polyethylene (PE) of different molecular weights and densities, polypropylene (PP), polystyrene (PS), polyvinyl chloride (PVC), polymethylmethacrylate (PMMA or acrylic), acrylonitrile butadiene styrene (ABS), polycarbonate (PC), polyesters, polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polyamide (PA or nylon), polyphenylene sulfide (PPS), polyphenylene oxide/polystyrene blend, polyetherimide (PEI), polysulfone (PSO), and their blends and copolymers. In other embodiments, a thermoplastic elastomer polymer may be selected from a group that includes: styrene-butadiene rubber, butadiene rubber, isoprene, butyl rubber, chloroprene rubber, nitrile rubber, ethylene-propylene rubber (EPM and EPDM), silicon rubbers, polyureas, polyurethanes, or their blends or derivatives. In other embodiments, a biodegradable thermoplastic polymer may be selected from a group that includes: polyglycolide (PGA), polylactide-co-glycolide (PLGA), polybutylene succinate (PBS) and its copolymers, polyp-dioxanone (PDO or PPDO), polycaprolactone (PCL), polyhydroxyalkanoates (PHA), polyhydroxybutyrate (PHB), polyhydroxyvalerate (PHV), polylactic acid (PLA), biodegradable polycarbonate, polyvinyl alcohol (PVOH), polyvinyl acetate (PVA), and their copolymers and derivatives. In other embodiments, a biopolymer or natural polymer may be selected from a group that includes: cellulose derivatives, polysaccharides, chitin and chitosan polymers, proteins, or gelatins. In other embodiments, a thermosetting polymer may be selected from a group that includes: unsaturated polyesters, phenolic resins, amino resins, urea/formaldehyde resins, polyurethanes, polyureas, epoxy resins, or silicones. Less common thermosets employed in specialized applications may be polybismaleimides, polyimides, and polybenzimidazoles.
[0045] The composition coating 24 may include any polymer that has melt-flow index (MFI) between 0.1 to 5000. And, the coating composition 24 may have a viscosity that ranges between 1.0 centipoise and 2,000,000 centipoises, and may range between 40 C. and 400 C. during its application.
[0046] In yet other embodiments, the coating composition 24 may include: a polymer for cohesive strength, a wax, a tackifier, an anti-block additive, and/or other processing additives such as anti-oxidatives, mineral fillers, and/or superabsorbent particles.
[0047] Polymers for cohesive strength may be selected from a group that includes: styrenic block copolymers, polyolefins (e.g., amorphous and crystalline polyolefin including homogeneous and substantially linear ethylene/alpha-olefin inter-polymers), interpolymers and copolymers of ethylene including, e.g., ethylene-vinyl acetate, ethylene-vinyl acetate ethylene-acrylic acid, ethylene-methacrylic acid, ethylene-methyl acrylate, ethylene-ethyl acrylate and ethylene n-butyl acrylate and derivatives (e.g., incorporating at least two comonomers), polyacrylic acids, polymethacrylic acids, polyacrylates, polyvinyl acetates, polylactic acids, polylactides, caprolactone polymers, poly (hydroxy-butyrate/hydroxyvalerate), polyvinyl alcohols, polyesters, copolyesters (e.g., biodegradable copolyesters), polyethylene oxidepolyether amide, polyester ether block copolymers, polyvinyl pyrrolidone, polyvinyl pyrrolidone-vinyl acetate copolymer, polyetheroxazoline, polyvinyl ethers (e.g., polyvinyl methyl ether), polyamides, polyurethane, polyacrylamide, Polyesters and combinations and blends thereof.
[0048] Waxes may be selected from a group that includes: paraffin waxes, Fischer-Tropsch waxes, by-product polyethylene waxes, high-density low molecular weight polyethylene waxes, microcrystalline waxes, vegetable waxes, and combinations thereof.
[0049] Tackifying resins or tackifiers are used to modify the tackifying, wetting, and adhesion characteristics of a polymer. Tackifying resins also function to control viscosity, as well as wetting and adhesion. These are usually low-molecular-weight polymers based on aliphatic or aromatic hydrocarbons, rosins, rosin esters, terpenes, styrene or phenol derivatives, or any of these in combination. The formulations include stabilizers and anti-oxidants to prevent premature viscosity change and char or gel formation that could foul one or more components of the system 20. A tackifier may be selected from a group that includes: rosin ester, rosin acid, styrenated terpene, terpene-phenolic resin, aliphatic hydrocarbon resin, aromatic-modified aliphatic resin, aromatic hydrocarbon resin, -methyl styrene resin, hydrogenated hydrocarbon resin, and aromatically-modified hydrocarbon resin.
[0050] In yet other embodiments, the coating composition 24 may include a taggant marker, which may be chosen from a group of chemical and/or physical taggants. In addition, the coating composition 24 may include a laser etching that is subsequently covered by additional coating composition 24. The etching can be conducted on either or both the surfaces of the coatings.
[0051]
[0052] The receptacle 38 may be configured as desired to hold any desired form of the small object 22. For example, in this and other embodiments, the receptacle 38 is rectangular, the first plate's platform 40 defines most of the receptacle's floor, and the second plate's wall 42 surrounds the receptacle's floor. With the platform 40 defining most of the receptacle's floor and the wall 42 surrounding the receptacle's floor, an object 22 that fits within the receptacle 38 can have a variety of different forms yet be properly held on the platform 40 while: 1) the applicator 30 (
[0053] Referring to
[0054] Other embodiments are possible. For example, the platform 40 may include a rectangular shape such as a square or rectangle. As another example, the platform 40 may include a triangular shape. In addition, the platform 40 may have a surface 84 that is curved such as concave relative to the remainder of the platform 40. Also, the orientation of the platform's surface 84 may be angled other than 90 relative to the remainder of the platform 40.
[0055] Referring to
[0056]
[0057] The transfer interface 46 may be configured as desired to transfer the small object 22 and properly orient the small object 22 as the second conveyor 34 moves it toward the applicator 36 (
[0058] In this and other embodiments, the distance between the two frames 26 and 32 while they travel through the transfer interface 46 is such that both of the platforms 40 contact the small object at the same time. This works well when the small objects 22 being coated by the system 20 are each very close to the same size and shape. To account for significant variations in the size of the small objects 22, the distance between the two frames 26 and 32 while they travel through the transfer interface 46 may be greater than the size of the small object 22. In this manner, the small object 22 may move away from the first frame 26 and toward the second frame 32 during its transfer to the second frame 32.
[0059] Still referring to
[0060]
[0061] The preceding discussion is presented to enable a person skilled in the art to make and use the invention. Various modifications to the embodiments will be readily apparent to those skilled in the art, and the generic principles herein may be applied to other embodiments and applications without departing from the spirit and scope of the present invention. Thus, the present invention is not intended to be limited to the embodiments shown, but is to be accorded the widest scope consistent with the principles and features disclosed herein.