Systems, Methods, and Compounds for Sustainable Wastewater Treatment and Co-Products Thereof

Abstract

A sequential batch reactor wastewater treatment system and method, a material combination for practicing the method, and a fertilizer co-product deriving therefrom. A pH lowering agent comprising an acid lowers the pH of wastewater. A first compound including chitin or chitosan comprises a filtering medium, a coagulant, and a flocculant, and a second compound comprises an adsorbent and a pH raising agent. Wastewater is mixed and aerated subsequent to introduction of each of the first and second compounds, and flocculation yields treated water and a sludge byproduct that may be dewatered and further processed to yield a useful fertilizer co-product. Within the first compound, diatomaceous earth operates as a filtering medium and bentonite clay acts as a coagulant and filtering medium. Within the second compound, activated carbon, calcium oxide (CaO), and caustic soda (NaOH) are operative to adsorb, disinfect, and raise the pH of the wastewater.

Claims

1. A method for the treatment of wastewater, the method comprising: introducing a pH lowering agent to the wastewater to lower the pH of the wastewater; introducing a first compound to the wastewater wherein the first compound comprises a filtering medium, a coagulant, and a flocculant and wherein the first compound includes chitin or chitosan operative as a coagulant and flocculant; mixing and aerating the wastewater with the first compound introduced therein for a first mixing and aeration time; introducing a second compound to the wastewater wherein the second compound comprises an adsorbent and a pH raising agent; mixing and aerating the wastewater with the second compound introduced therein for a second mixing and aeration time; providing a flocculation period sufficient to allow at least partial separation of the wastewater to yield treated water and a sludge byproduct; and whereby undesirable content within the wastewater is reduced and the sludge byproduct is yielded.

2. The method of claim 1, further comprising the step of dewatering the sludge byproduct.

3. The method of claim 2, wherein the step of dewatering the sludge byproduct is performed with a sludge dewatering machine.

4. The method of claim 3, wherein the sludge dewatering machine is chosen from the group consisting of a plate-and-frame filter press, a belt filter press, a centrifuge, a stacked sludge system, and a screw press.

5. The method of claim 2, wherein the step of sludge dewatering is performed with an enhanced evaporation system chosen from the group consisting of an open bed dryer and a greenhouse evaporation dryer.

6. The method of claim 1, wherein the step of introducing a pH lowering agent comprises applying an acid to the wastewater.

7. The method of claim 6, wherein the acid comprises sulfuric acid (H.sub.2SO.sub.4) or hydrochloric acid (HCl).

8. The method of claim 1, wherein the first compound further comprises diatomaceous earth as a filtering medium.

9. The method of claim 8, wherein the first compound further comprises bentonite clay as a coagulant and filtering medium.

10. The method of claim 9, wherein the diatomaceous earth is according to CAS Registry Number 91053-39-3, the bentonite clay is according to CAS Registry Number 1302-78-9, and the chitin or chitosan is according to CAS Registry Number 9012-76-4.

11. The method of claim 1, wherein the chitin or chitosan comprises approximately 5 to 10% by weight of the first compound.

12. The method of claim 11, wherein the first compound further comprises diatomaceous earth and bentonite clay.

13. The method of claim 1, wherein the second compound comprises activated carbon.

14. The method of claim 13, wherein the second compound further comprises calcium oxide (CaO).

15. The method of claim 14, wherein the second compound further comprises caustic soda (NaOH).

16. The method of claim 15, wherein the second compound further comprises silicon dioxide.

17. The method of claim 15, wherein the activated carbon comprises approximately 40-50% by weight of the second compound and wherein the calcium oxide and caustic soda each comprise approximately 20-25% by weight of the second compound.

18. The method of claim 1, wherein the second compound is introduced in a quantity and composition sufficient to raise the pH balance of the wastewater to between approximately 7 and 10 on the pH scale.

19. The method of claim 1, further comprising the steps of measuring the pH of the wastewater, determining a volume of the wastewater, and calculating the quantity of pH lowering agent to be introduced to the wastewater based on the pH of the wastewater as measured and the volume of the wastewater, all prior to the step of introducing the pH lowering agent to the wastewater.

20. The method of claim 1, wherein the first mixing and aeration time is between 1 and 12 hours.

21. The method of claim 20, wherein the second mixing and aeration time is between 1 and 12 hours.

22. The method of claim 1, wherein the step of providing a flocculation period is performed in a settling tank.

23. The method of claim 1, further comprising processing the sludge byproduct to produce a fertilizer co-product.

24. The method of claim 23, wherein processing the sludge byproduct to produce a fertilizer co-product includes the step of dewatering the sludge byproduct.

25. The method of claim 24, wherein processing the sludge byproduct to produce a fertilizer co-product includes the step of introducing and blending nitrogen in solid form with the sludge byproduct.

26. The method of claim 25, wherein processing the sludge byproduct to produce a fertilizer co-product includes the step of pelletizing the sludge byproduct.

27. A fertilizer co-product produced from the sludge byproduct yielded by the method of claim 1.

28. The fertilizer co-product of claim 27, wherein the fertilizer co-product is produced by a method further comprising the step of dewatering the sludge byproduct.

29. The fertilizer co-product of claim 28, wherein the fertilizer co-product is produced by a method further comprising the step of introducing and blending nitrogen in solid form with the sludge byproduct.

30. The fertilizer co-product of claim 29, wherein the fertilizer co-product is produced by a method further comprising the step of pelletizing the sludge byproduct.

31. A sequential batch reactor wastewater treatment system for treating wastewater to yield treated water and sludge byproduct, the wastewater treatment system comprising: a holding tank; a pH lowering agent for lowering the pH of the wastewater; a first reaction tank; a first compound comprising a filtering medium, a coagulant, and a flocculant wherein the first compound includes chitin or chitosan operative as a coagulant and flocculant; a second compound comprising an adsorbent and a pH raising agent; and a settling tank.

32. The wastewater treatment system of claim 31, further comprising a sludge dewatering machine for dewatering the sludge byproduct.

33. The wastewater treatment system of claim 32, wherein the sludge dewatering machine is chosen from the group consisting of a plate and frame filter press, a belt filter press, a centrifuge, a stacked sludge system, and a screw press.

34. The wastewater treatment system of claim 31, further comprising an enhanced evaporation system for dewatering the sludge byproduct, the enhanced evaporation system chosen from the group consisting of an open bed dryer and a greenhouse evaporation dryer.

35. The wastewater treatment system of claim 31, wherein the pH lowering agent comprises an acid.

36. The wastewater treatment system of claim 31, wherein the first compound further comprises diatomaceous earth as a filtering medium.

37. The wastewater treatment system of claim 36, wherein the first compound further comprises bentonite clay as a coagulant and filtering medium.

38. The wastewater treatment system of claim 31, wherein the second compound comprises activated carbon.

39. The wastewater treatment system of claim 38, wherein the second compound further comprises calcium oxide (CaO) and caustic soda (NaOH).

40. The wastewater treatment system of claim 31, further comprising a second reaction tank.

41. A material combination for the treatment of wastewater, the material combination comprising: a first compound comprising a filtering medium, a coagulant, and a flocculant wherein the first compound includes chitin or chitosan operative as a coagulant and flocculant; and a second compound comprising an adsorbent and a pH raising agent.

42. The material combination of claim 41, further comprising a pH lowering agent for lowering the pH of the wastewater.

43. The material combination of claim 41, wherein the first compound further comprises diatomaceous earth as a filtering medium.

44. The material combination of claim 43, wherein the first compound further comprises bentonite clay as a coagulant and filtering medium.

45. The material combination of claim 41, wherein the chitin or chitosan comprises approximately 5 to 10% by weight of the first compound.

46. The material combination of claim 41, wherein the second compound comprises activated carbon.

47. The material combination of claim 46, wherein the second compound further comprises calcium oxide (CaO).

48. The material combination of claim 47, wherein the second compound further comprises caustic soda (NaOH).

49. The material combination of claim 48, wherein the activated carbon comprises approximately 40-50% by weight of the second compound and wherein the calcium oxide and caustic soda each comprise approximately 20-25% by weight of the second compound.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0032] In the accompanying drawing figures:

[0033] FIG. 1 is a schematic view of a wastewater treatment system according to the present invention;

[0034] FIG. 2 is a schematic view of an alternative wastewater treatment system pursuant to the invention; and

[0035] FIG. 3 is a schematic view of a further wastewater treatment system as disclosed herein.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

[0036] To ensure that one skilled in the art will fully understand and, in appropriate cases, be able to practice the present invention, certain preferred embodiments of the wastewater treatment method, system, and compounds revealed herein are described below and shown in the accompanying drawing figure. It will be understood, however, that the wastewater treatment systems, compounds, and methods are subject to a variety of further embodiments, each within the scope of the invention.

[0037] In one practice of the disclosed method for wastewater treatment, a volume of wastewater to be treated is provided, whether by being received into one or more vessels or other retaining areas, by its preexistence as a body of water, or otherwise. The volume of wastewater to be treated can be calculated, whether by measurement using a flow meter, by receipt into a vessel or vessels of known volume, by mathematical calculation, or by some other method or combination thereof. If and as necessary, the original pH of the wastewater can be measured and recorded.

[0038] With the volume of wastewater thus received or otherwise in place for treatment and the original pH of the wastewater known, the wastewater treatment process proceeds with a lowering of the pH of untreated wastewater. The pH may, by way of non-limiting example, be lowered by approximately two to three points on the pH scale. One method of lowering the pH pursuant to the invention is through the addition of a pH lowering agent comprising an acid, such as sulfuric acid (H.sub.2SO.sub.4), hydrochloric acid (HCl), or another acid effective to reduce the pH of the wastewater by a predetermined amount on the pH scale. The volume or otherwise measured amount, the type, and, additionally or alternatively, other characteristics of the pH lowering agent to be added to the wastewater may be calculated or otherwise determined dependent on multiple factors, including the volume of wastewater to be treated and the initial pH and other characteristics of the wastewater.

[0039] With the pH lowered, the wastewater is ready for the introduction of compounds according to the present method for wastewater treatment. In one practice of the invention, for instance, a first of two compounds is introduced. The volume, mass, or other measured amount, the composition, and, additionally or alternatively, other characteristics of the first compound introduced may be calculated based on one or more factors, including the volume of wastewater to be treated and, potentially, measured, expected, or predicted characteristics of the wastewater. With the first compound introduced, the wastewater is then mixed and aerated for a predetermined first mixing and aeration time. The first mixing and aeration time in certain practices of the invention ranges from 1 to 12 hours. With the wastewater mixed and aerated, a second compound is introduced into the wastewater, and the wastewater is again mixed and aerated for a predetermined second mixing and aeration time. The volume, mass, or other measured amount, the composition, and, additionally or alternatively, other characteristics of the second compound introduced may be calculated based on one or more factors, including the volume of wastewater to be treated and, potentially, measured, expected, or predicted characteristics of the wastewater. The second mixing and aeration time in particular practices of the invention ranges from 1 to 12 hours.

[0040] With the first and second compounds and the wastewater mixed and aerated over the first and second mixing and aeration times, the wastewater is retained to flocculate in a settling tank over a flocculation period. In certain practices of the invention, the settling tank can be a cone-shaped or tapered tank. As the flocculation occurs, unwanted substances within the wastewater tend to bond together through absorption and/or adsorption and precipitate to the bottom of the settling tank. Volumes of treated water and sludge byproduct are thus created.

[0041] So treated, the wastewater can then be drawn off, decanted, or otherwise separated from the sludge byproduct. Where the treated wastewater is drawn off, for example, the sludge byproduct will be left behind in the settling tank. The sludge is then dewatered, whether in place within the settling tank, in one or more dewatering locations, or otherwise. For instance, the sludge can be removed from the settling tank and dewatered, such as but not limited to by use of a sludge dewatering machine. The sludge dewatering could by way of example and not limitation be performed by a sludge dewatering machine comprising a plate-and-frame filter press, a belt filter press, a centrifuge, a stacked sludge system, a screw press, or any other effective sludge dewatering mechanism. Additionally or alternatively, an enhanced evaporation system can be employed for dewatering the sludge byproduct. The enhanced evaporation system can, for example, be chosen from the group consisting of an open bed dryer and a greenhouse evaporation dryer.

[0042] According to certain manifestations of the invention, the first of the two compounds comprises a mixture of a filtering medium and one or more coagulants and flocculants. More particularly, manifestations of the first compound incorporate diatomaceous earth as a filtering medium, bentonite clay as a coagulant and filtering medium, and chitosan or chitin as a coagulant and flocculant. Without imposing any limitations on the invention apart from those expressly included in the claims, the Diatomaceous Earth can be according to CAS Registry Number 91053-39-3, the Bentonite can be according to CAS Registry Number 1302-78-9, and the Chitosan or Chitin can be according to CAS Registry Number 9012-76-4.

[0043] Diatomaceous earth is operative within the waste water treatment method and compounds as a natural filtration aid. Formed largely of silica, diatomaceous earth improves filtering capacity and helps to remove suspended solids, semi-colloids, and oily liquids. Bentonite clay is operative as a coagulant and filtration aid to absorb a wide variety of contaminants and to encapsulate suspended solids, organic compounds, and toxicants. Chitin as employed within the waste water treatment method and compounds is operative as a coagulating and flocculating agent. Chitin effectively coagulates organic compounds, acts as a chelating polymer for binding toxic heavy metals, and performs as an adsorption medium for dyes and small concentrations of phenols and polychlorinated biphenyls (PCBs) as are commonly present in industrial wastewaters.

[0044] In particular practices of the method and compound, chitosan makes up approximately 5 to 10% by weight of the first compound with the remainder of the first compound being approximately evenly split between the diatomaceous earth and the bentonite clay. As a result in such embodiments, each of diatomaceous earth and bentonite clay comprises approximately 45 to 47.5% by weight of the first compound. The amount of the first compound to be added to the wastewater may be dependent on a plurality of factors including the volume of wastewater to be treated and the initial pH and other characteristics of the wastewater.

[0045] In preferred embodiments, the chitosan is provided in powdered form. Chitosan is a molecular derivative of chitin produced by the removal of acetyl groups. Chitin occurs naturally in the shells of shellfish and is derived therefrom. It has been found that the exoskeleton of shellfish is typically composed of chitin (20-30% w/w), proteins (20-40% w/w), minerals (30-60% w/w), and by pigments and lipid in traces. Chitin and chitosan are naturally nontoxic, biodegradable, and biocompatible. In view of the many tons of chitin that is otherwise wasted as, for instance, shrimp, lobster, and crab shell residue, the exploitation of chitosan in wastewater treatment methods and compounds as disclosed herein is efficient and environmentally sustainable.

[0046] In practices of the invention, the second compound may comprise a mixture of activated carbon, calcium oxide (CaO), caustic soda (NaOH), and, potentially, silicon dioxide (SiO.sub.2). The activated carbon, alternatively referred to as activated charcoal, is operative to adsorb natural organic compounds, taste and odor compounds, and synthetic organic chemicals. It has been found effective as an adsorbent based on its high porosity and large surface area to which contaminants may adsorb. Calcium oxide is operative as a pH raising agent and as a disinfectant. It also improves water taste, smell, and color. Caustic soda is also operative as a pH raising agent. Where included, silicon dioxide is operative as a defoaming and carrier agent.

[0047] Again without limiting the invention except as may be expressly provided in the claims, the activated carbon, charcoal or tempered charcoal may be according to CAS Registry Numbers 64365-11-3 or 7440-44-0, the calcium oxide may be according to CAS Registry Number 73018-51-6, the caustic soda may be according to CAS Registry Number 1310-73-2, and the silicon dioxide may be according to CAS Registry Number 7631-86-9. In particular examples, the charcoal comprises approximately 40-50% by weight of the mixture, calcium oxide and caustic soda are each approximately 20-25% by weight of the mixture, and the silicon is the remaining approximately 5-10% by weight. The second compound is a base and thus is operative to raise the pH balance of the wastewater, such as to the 7-10 range on the pH scale dependent on, among other things, the pH of the wastewater prior to treatment and the relative volumes of wastewater and the second compound.

[0048] A wastewater treatment system according to the invention is depicted in FIG. 1. There, the wastewater treatment system is indicated generally at 10. As disclosed herein, wastewater can be held initially in a holding tank 12 where the pH balance of the wastewater is lowered by the addition of the pH lowering agent. The wastewater can then be forwarded to a first reaction tank 14 where the first compound is introduced. The wastewater and the first compound are then mixed and aerated within the first reaction tank 14 for a period of time, which can be a predetermined first mixing and aeration time ranging, for instance, from 1 to 12 hours. After that period of time, the wastewater is advanced to a second reaction tank 16. The second compound is then introduced. The wastewater and the second compound are mixed and aerated within the second reaction tank 16 for a second mixing and aeration time, which can be a predetermined period of time ranging, for instance, from 1 to 12 hours. As noted hereinabove, the second compound comprises a base and tends to raise the pH balance of the wastewater, such as to the 7-10 range on the pH scale. The rise in pH will be dependent on, among other things, the pH level of the wastewater then to be treated with the second compound and the relative volumes of the wastewater and the second compound. The aforedescribed lowering and raising of the pH of the wastewater according to the invention have been found to promote flocculation.

[0049] The wastewater with the flocculated aggregates therein then travels to a settling tank 18 where the wastewater and flocculated aggregates are separated or permitted to separate into treated water and a sludge byproduct. The treated water is drawn off and provided to a treated water recipient 20. The treated water recipient 20 could comprise drainage piping or any other conduit or, additionally or alternatively, any vessel, body of water, or other location capable of receiving water. In certain practices of the invention, the treated water can be recycled through the wastewater treatment system 10 one or more times to enable increasingly refined treatment of the wastewater.

[0050] In any event, once the treated water is drawn off, the sludge byproduct left behind is dewatered. Dewatering could be effected, for instance, by use of a sludge dewatering machine 22. By way of non-limiting example, the sludge dewatering machine 22 could comprise a plate-and-frame filter press, a belt filter press, a centrifuge, a stacked sludge system, a screw press, or any other effective sludge dewatering machine 22. Dewatering can alternatively or additionally be accomplished by drying on a drying bed, by enhanced drying through evaporation, or through any other effective method.

[0051] The holding tank 12, the reaction tanks 14 and 16, the settling tank 18, and the sludge dewatering machine 22 thus cooperate to form the wastewater treatment system 10. The wastewater treatment system 10 may alternatively be referred to as a Sequential Batch Reactor 10. The Sequential Batch Reactor 10 so shown and described has been found to demonstrate substantial utility and effectiveness in treating wastewater.

[0052] An alternative wastewater treatment system 10 pursuant to the present invention is shown in FIG. 2. There, a single holding, treatment, and settlement vessel 24 is employed in place of the holding tank 12, the first and second reaction tanks 14 and 16, and the settling tank 18. A treated water recipient 20 is again included and again could comprise any vessel, conduit, body of water, or other location or combination thereof capable of receiving water.

[0053] In this embodiment, however, enhanced evaporation systems are provided for dewatering and drying the sludge byproduct. More particularly, an open bed dryer 26 is provided for receiving sludge byproduct and permitting a dewatering and drying thereof. Without limitation, an open bed dryer 26 according to the invention could, for instance, comprise a porous bed of sand and, additionally or alternatively, gravel. In use of the open bed dryer 26, a thin layer, such as 12 inches or less, of sludge byproduct can be spread over the substrate of the open bed dryer 26. Wastewater within the sludge can be permitted to drain under the force of gravity through the open bed dryer 26 and to, for instance, drainage pipes or another water recipient 20. Further water removal is naturally provided by evaporation from the sludge surface.

[0054] The wastewater treatment system 10 of FIG. 2 includes a further enhanced evaporation system in the form of a greenhouse evaporation dryer 28. The greenhouse evaporation dryer 28 provides a covered drying environment that exploits solar energy to promote the evaporation of water from the sludge byproduct. Where necessary or desirable, solar energy can be supplemented within the greenhouse evaporation dryer 28 by a supplementary heat source, such as a heat pump or other heat source. Wastewater within the sludge can again be permitted to drain under the force of gravity from the greenhouse evaporation dryer 28 to, for instance, drainage pipes or another water recipient 20. Further water removal is naturally provided by evaporation from the sludge surface accelerated by recipient solar energy.

[0055] Under such embodiments, wastewater provided for treatment can be held in the vessel 24. The pH balance of the wastewater can then be lowered by the addition of the pH lowering agent and a mixing of the wastewater and the pH lowering agent. With the wastewater retained within the vessel 24, the first compound is introduced, and the wastewater and the first compound are mixed and aerated for a period of time, which can be a predetermined first mixing and aeration time ranging, for instance, from 1 to 12 hours. After that period of time and with the wastewater remaining within the vessel 24, the second compound is introduced and the wastewater and the second compound are mixed and aerated for a second mixing and aeration time. The mixing and aeration time can be a predetermined period of time ranging, for instance, from 1 to 12 hours.

[0056] As before, the second compound is a base that tends to raise the pH balance of the wastewater, such as to the 7-10 range on the pH scale, dependent on, among other things, the pH level of the wastewater then to be treated with the second compound and the relative volumes of the wastewater and the second compound. As noted previously, the lowering and raising of the pH of the wastewater according to the invention have been found to promote flocculation.

[0057] Again while in the vessel 24 and with the first and second compounds and the wastewater mixed and aerated over the first and second mixing and aeration times, the wastewater is retained to flocculate over a flocculation period. As the flocculation occurs, unwanted substances within the wastewater tend to bond together through absorption and/or adsorption and precipitate to the bottom of the settling tank such that volumes of treated water and sludge byproduct are created.

[0058] The treated water can then be drawn off and provided to a treated water recipient 20. Again, the treated water recipient 20 could be any vessel, conduit, body of water, or other location or combination thereof capable of receiving water. As set forth hereinabove, treated water can be recycled through the wastewater treatment system 10 one or more times to enable increasingly refined treatment of the wastewater.

[0059] Once the treated water is drawn off, the sludge byproduct is dewatered. For instance, the sludge byproduct can be removed from the vessel 24, transferred to the open bed dryer 26, and spread in one or more layers for dewatering by drainage under the force of gravity to a water recipient 20 and through natural evaporation. Additionally or alternatively, the sludge byproduct can be transferred to the greenhouse evaporation dryer 28 for dewatering through drainage under the force of gravity and evaporation enhanced by recipient solar energy. So disclosed, the wastewater treatment system 10 again is operative as a Sequential Batch Reactor 10.

[0060] A further Sequential Batch Reactor wastewater treatment system according to the invention is again indicated generally at 10 in FIG. 3. A holding tank 12 is provided for initially holding received wastewater, and the pH balance of the wastewater can be lowered, such as while it is in the holding tank 12, by the addition of the pH lowering agent. A first reaction tank 14 then receives the wastewater, and the first compound is introduced. The wastewater and the first compound are then mixed and aerated within the first reaction tank 14 for a first mixing and aeration time ranging, for instance, from 1 to 12 hours. The wastewater is then advanced to a second reaction tank 16 where the second compound is introduced and mixing and aeration are performed for a second mixing and aeration time. The second mixing and aeration time can be a predetermined period of time ranging, for instance, from 1 to 12 hours.

[0061] The wastewater is then advanced to a settling tank 18 where the wastewater is retained for a predetermined period of time to permit flocculation to produce flocculated aggregates and a separation into treated water and a sludge byproduct. The treated water is drawn off and provided to a treated water recipient 20, such as but not limited to a vessel, conduit, body of water, or any other location or combination thereof capable of receiving water. Once the treated water is drawn off, the sludge byproduct is dewatered, such as by transfer to an open bed dryer 26 as previously described and by a spreading into one or more layers for drainage and natural evaporation. The sludge byproduct can additionally or alternatively be transferred to a greenhouse evaporation dryer 28 for dewatering through drainage and evaporation enhanced by recipient solar energy.

[0062] It is also contemplated that the compounds disclosed herein could be applied to wastewater in other environments. By way of further example but not limitation, the first and second compounds and the pH lowering agent as necessary could be introduced into ponds, lakes, reservoirs, lagoons or other bodies of water to treat retained wastewater of poor quality, including by promoting flocculation. In such practices of the invention, lower capital costs may be required. Moreover, the treatment method and compounds can, for instance, be applied in situations requiring limited application, such as one-time or periodic remediation.

[0063] The Sequential Batch Reactor wastewater treatment system 10 and the methods and compounds disclosed herein have application in a plurality of industries traversing a wide spectrum, including the agricultural, chemical, oil, and gas industries, real estate remediation and development, municipal wastewater treatment, and other industries. Embodiments of the disclosed system and method can confront numerous contaminants, including perfluoroalkyl and polyfluoroalkyl substances (PFAS), chlorinated organic compounds, volatile organic compounds, such as dioxane and furan, regulated metals and other natural and synthetic constituents, which continue to become increasingly problematic. The disclosed wastewater treatment system, method, and compounds are effective in lowering undesirable substances, including total suspended solids (TSS), grease, oil, and other viscous liquids, perfluoroalkyl and polyfluoroalkyl substances (PFAS), nitrogen, phosphates, chemical and biological oxygen demand (COD and BOD), ammonia, fecal matter, synthetic and natural compounds, and other harmful or problematic substances.

[0064] When practiced as disclosed herein, the wastewater treatment method results in treated water and a dewatered sludge byproduct that is free of or substantially reduced in synthetic polymers and other unwanted substances. In many instances, particularly where the wastewater is sourced from agriculture, sewage, or food production environments, the sludge byproduct will include useful levels of nitrogen, such as from 1 to 20% based on weight. As such, the sludge byproduct has physical and chemical properties that can enable it to be useful to produce, for instance, fertilizer as a process co-product. According to practices of the invention, portions of the sludge byproduct can be diverted for production of a co-product while other portions of the sludge byproduct are disposed of or returned, potentially in cake, powder, or other form, to the water treatment system 10 to facilitate further processing.

[0065] Where some or all of the sludge byproduct is to be utilized to produce a fertilizer co-product, further processing may be practiced to facilitate packaging, transport, and application. As necessary or desirable, further components or amounts of components already included may be added to, or potentially removed from, the sludge byproduct during additional processing to produce a fertilizer meeting particular characteristics. The further processing may include, where necessary, the addition and blending of nitrogen fertilizer materials in solid form to the dewatered sludge byproduct. In certain practices of the invention, the dewatered sludge product can be blended with further agents, such as concentrated acid, oxidizing agents, and, additionally or alternatively, other agents and the product so mixed can be converted to a pumpable paste. The pumpable paste may then be mixed with a hardening agent, and the mixed and hardened byproduct may then be pelletized, such as by use of a granulator.

[0066] It will be understood that terms of orientation, nomenclature, and other conventions used herein are merely intended to provide a complete understanding of the disclosed invention and are not limiting. Other conventions may be used without limitation of the teachings herein. Furthermore, the various components disclosed herein are merely illustrative and are not limiting of the invention. For example, except as limited by the claims, each of the components and steps discussed herein may include subcomponents or substeps that collectively provide for the structure and function of the disclosed component or step. Still further, one or more components or steps could be combined as a unitary structure or a single step while still corresponding to the disclosed components or steps. Additional components and steps that provide additional functions, or enhancements to those introduced herein, may be included. For example, additional components, steps, and materials, combinations of components, steps, or materials, and perhaps the omission of components, steps, or materials may be used to create embodiments that are nonetheless within the scope of the teachings herein.

[0067] When introducing elements of the present invention or embodiments thereof, the articles “a,” “an,” and “the” are intended to mean that there are one or more of the elements. The terms “comprising,” “including,” and “having” are intended to be inclusive such that there may be additional elements other than the listed elements. As used herein, the term “example” or “exemplary” is not intended to imply a superlative example. Rather, “exemplary” refers to an embodiment that is one of many possible embodiments.

[0068] With certain details and embodiments of the present invention for wastewater treatment systems, compounds, methods, and co-products disclosed, it will be appreciated by one skilled in the art that numerous changes and additions could be made thereto without deviating from the spirit or scope of the invention. This is particularly true when one bears in mind that the presently preferred embodiments merely exemplify the broader invention revealed herein. Accordingly, it will be clear that those with major features of the invention in mind could craft embodiments that incorporate those major features while not incorporating all of the features included in the preferred embodiments.

[0069] Therefore, the following claims shall define the scope of protection to be afforded to the inventor. Those claims shall be deemed to include equivalent constructions insofar as they do not depart from the spirit and scope of the invention. A plurality of the following claims may express, or be interpreted to express, certain elements as means for performing a specific function, at times without the recital of structure or material. As the law demands, any such claims shall be construed to cover not only the corresponding structure and material expressly described in this specification but also all legally-cognizable equivalents thereof.