Semiconductor device with high thermal conductivity substrate and process for making the same
10037899 ยท 2018-07-31
Assignee
Inventors
- Xing Gu (Allen, TX, US)
- Jinqiao Xie (Allen, TX, US)
- Edward A. Beam, III (Plano, TX, US)
- Cathy Lee (Plano, TX, US)
Cpc classification
H01L29/7787
ELECTRICITY
H01L29/66462
ELECTRICITY
H01L29/7786
ELECTRICITY
International classification
H01L23/373
ELECTRICITY
H01L29/778
ELECTRICITY
H01L29/66
ELECTRICITY
H01L29/20
ELECTRICITY
Abstract
The present disclosure relates to a process of forming a high thermal conductivity substrate for an Aluminum/Gallium/Indium (III)-Nitride semiconductor device. According to an exemplary process, a semiconductor precursor including a substrate structure and a buffer structure is provided. The buffer structure is formed over the substrate structure and has a first buffer surface and a second buffer surface. Herein, the second buffer surface is adjacent to the substrate structure and the first buffer surface is opposite the second buffer surface. Next, a high thermal conductivity substrate with a thermal conductivity greater than 400 W/mK is formed over the first buffer surface. A heat sink carrier is then provided over the high thermal conductivity substrate. The substrate structure is then substantially removed to provide a thermally enhanced precursor for the III-Nitride semiconductor device.
Claims
1. A method comprising: providing a semiconductor precursor comprising a substrate structure, and a buffer structure over the substrate structure, and having a first buffer surface and a second buffer surface, which has a first polarity, wherein the first buffer surface is opposite the second buffer surface and the second buffer surface is adjacent to the substrate structure; forming a high thermal conductivity substrate over the first buffer surface, wherein the high thermal conductivity substrate has a thermal conductivity greater than 400 W/mK; providing a heat sink carrier over the high thermal conductivity substrate to form an intermediate structure; and removing substantially all of the substrate structure to provide a thermally enhanced precursor with an exposed surface, which has the first polarity.
2. The method of claim 1 further comprising flipping the intermediate structure before removing the substrate structure, such that the substrate structure is over the buffer structure and at a top portion of the intermediate structure.
3. The method of claim 1 wherein the buffer structure comprises: a buffer layer having a first surface and a second surface opposite the first surface of the buffer layer and adjacent to the substrate structure; and a transition layer having a first surface and a second surface opposite the first surface of the transition layer, wherein the second surface of the transition layer is adjacent to the first surface of the buffer layer, the first surface of the transition layer is the first buffer surface, and the second surface of the buffer layer is the second buffer surface.
4. The method of claim 3 wherein the buffer layer is formed of Gallium Nitride (GaN), and the transition layer is formed of Aluminum Nitride (AlN) or Silicon Nitride (SiN.sub.x).
5. The method of claim 1 wherein the buffer structure comprises a buffer layer having a first surface and a second surface opposite the first surface of the buffer layer, wherein the first surface of the buffer layer is the first buffer surface and the second surface of the buffer layer is the second buffer surface and adjacent to the substrate structure.
6. The method of claim 5 wherein the buffer layer is formed of Gallium Nitride (GaN).
7. The method of claim 1 wherein the first polarity is a group III polarity.
8. The method of claim 7 further comprising forming a channel structure over the exposed surface of the thermally enhanced precursor.
9. The method of claim 8 wherein forming the channel structure comprises: forming a channel layer over the exposed surface, wherein the channel layer has a first surface adjacent to the exposed surface and a second surface opposite the first surface of the channel layer; and forming an energy barrier layer over the channel layer, wherein the energy barrier layer has a first surface adjacent to the second surface of the channel layer and a second surface opposite the first surface of the energy barrier layer.
10. The method of claim 9 wherein: the channel layer is formed of GaN, such that the first surface of the channel layer has a Nitrogen(N)-polarity and the second surface of the channel layer has a group III-polarity; and the energy barrier layer is formed of Aluminum Gallium Nitride (AlGaN), such that the first surface of the energy barrier layer has an N-polarity and the second surface of the energy barrier layer has a group III-polarity.
11. The method of claim 1 wherein the first polarity is an N-polarity.
12. The method of claim 11 further comprising forming a channel structure over the exposed surface of the thermally enhanced precursor.
13. The method of claim 12 wherein forming the channel structure comprises: forming a second buffer layer over the exposed surface, wherein the second buffer layer has a first surface adjacent to the exposed surface and a second surface opposite the first surface of the second buffer layer; forming an energy barrier layer over the second buffer layer, wherein the energy barrier layer has a first surface adjacent to the second surface of the second buffer layer and a second surface opposite the first surface of the energy barrier layer; and forming a channel layer over the energy barrier layer, wherein the channel layer has a first surface adjacent to the second surface of the energy barrier layer and a second surface opposite the first surface of the channel layer.
14. The method of claim 13 wherein: the second buffer layer is formed of GaN, such that the first surface of the second buffer layer has a group III-polarity and the second surface of the channel layer has a N-polarity; the energy barrier layer is formed of AlGaN, such that the first surface of the energy barrier layer has a group III-polarity and the second surface of the energy barrier layer has a N-polarity; and the channel layer is formed of GaN, such that the first surface of the channel layer has a group III-polarity and the second surface of the channel layer has a N-polarity.
15. The method of claim 1 wherein the high thermal conductivity substrate is formed from diamond.
16. The method of claim 15 wherein forming the high thermal conductivity substrate is provided by a deposition process.
17. The method of claim 1 wherein the heat sink carrier is formed from polycrystalline diamond.
18. The method of claim 17 wherein forming the heat sink carrier is provided by a wafer bonding process or a thick film growth process.
Description
BRIEF DESCRIPTION OF THE DRAWING FIGURES
(1) The accompanying drawing figures incorporated in and forming a part of this specification illustrate several aspects of the disclosure, and together with the description serve to explain the principles of the disclosure.
(2)
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(7) It will be understood that for clear illustrations,
DETAILED DESCRIPTION
(8) The embodiments set forth below represent the necessary information to enable those skilled in the art to practice the embodiments and illustrate the best mode of practicing the embodiments. Upon reading the following description in light of the accompanying drawing figures, those skilled in the art will understand the concepts of the disclosure and will recognize applications of these concepts not particularly addressed herein. It should be understood that these concepts and applications fall within the scope of the disclosure and the accompanying claims.
(9) It will be understood that, although the terms first, second, etc. may be used herein to describe various elements, these elements should not be limited by these terms. These terms are only used to distinguish one element from another. For example, a first element could be termed a second element, and, similarly, a second element could be termed a first element, without departing from the scope of the present disclosure. As used herein, the term and/or includes any and all combinations of one or more of the associated listed items.
(10) It will be understood that when an element, such as a layer, region, or substrate is referred to as being on or extending onto another element, it can be directly on or extend directly onto the other element or intervening elements may also be present. In contrast, when an element is referred to as being directly on or extending directly onto another element, there are no intervening elements present. Likewise, it will be understood that when an element such as a layer, region, or substrate is referred to as being over or extending over another element, it can be directly over or extend directly over the other element or intervening elements may also be present. In contrast, when an element is referred to as being directly over or extending directly over another element, there are no intervening elements present. It will also be understood that when an element is referred to as being connected or coupled to another element, it can be directly connected or coupled to the other element or intervening elements may be present. In contrast, when an element is referred to as being directly connected or directly coupled to another element, there are no intervening elements present.
(11) Relative terms such as below or above or upper or lower or horizontal or vertical may be used herein to describe a relationship of one element, layer, or region to another element, layer, or region as illustrated in the Figures. It will be understood that these terms and those discussed above are intended to encompass different orientations of the device in addition to the orientation depicted in the Figures.
(12) The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the disclosure. As used herein, the singular forms a, an, and the are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms comprises, comprising, includes, and/or including when used herein specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
(13) Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs. It will be further understood that terms used herein should be interpreted as having a meaning that is consistent with their meaning in the context of this specification and the relevant art and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
(14) The present disclosure relates to a semiconductor device that has a high thermal conductivity substrate and a process for making the same. Although various types of materials may be used for the semiconductor device, the following examples incorporate group III-Nitrides as the desired materials. Herein group III-Nitrides are those that include Nitrogen (N) and one or more of Aluminum (Al), Gallium (Ga), and Indium (In), or other group III material. A layer within a group III-Nitride semiconductor device has a surface with an N-polarity and an opposite surface with a group III polarity.
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(16) Initially, a semiconductor precursor 10, including a substrate structure 12 and a buffer structure 14 over the substrate structure 12, is provided as depicted in
(17) In addition, the buffer structure 14 includes a buffer layer 20 and a transition layer 22 over the buffer layer 20, and has a first buffer surface BS1 and a second buffer surface BS2. In this embodiment, the buffer layer 20 may be formed of Gallium Nitride (GaN) or the like, having a first surface S20-1 with an N-polarity and a second surface S20-2 with a group III-polarity, and for this example, a Ga-polarity. Herein, the transition layer 22 is an in situ transition layer, which is used to achieve a reliable bonding between the buffer structure 14 and a high thermal conductivity substrate in a following process. The transition layer 22 may be formed from amorphous or polycrystalline materials, such as AlN, Silicon Nitride (SiN.sub.x), or the like, with a thickness between 0 nm and 100 nm. The transition layer 22 is not necessarily polarized and/or may have mixed polarization. The transition layer 22 has a first surface S22-1 and a second surface S22-2, which is opposite the first surface S22-1 of the transition layer 22 and adjacent to the first surface S20-1 of the buffer layer 20. The second surface S20-2 of the buffer layer 20 is opposite the first surface S20-1 of the buffer layer 20. Further, the first surface S22-1 of the transition layer 22 may be the first buffer surface BS1 and the second surface S20-2 of the buffer layer 20 may be the second buffer surface BS2, which is opposite the first buffer surface BS1. In some applications, the buffer structure 14 may not include the transition layer 22. As such, the first surface S20-1 of the buffer layer 20 may be the first buffer surface BS1 and the second surface S20-2 of the buffer layer 20 may be the second buffer surface BS2. Herein the second buffer surface BS2 is adjacent to the first substrate surface SS1.
(18) Next, a high thermal conductivity substrate 24 is formed over the buffer structure 14 and adjacent to the first buffer surface BS1 as depicted in
(19) After the intermediate structure 28 is formed, the intermediate structure 28 is flipped as depicted in
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(21) The thermal enhanced precursor 30 has the heat sink carrier 26 at a bottom portion of the thermal enhanced precursor 30, the high thermal conductivity substrate 24 over the heat sink carrier 26, and the buffer structure 14 over the high thermal conductivity substrate 24. The high thermal conductivity substrate 24 has a thermal conductivity greater than 400 W/mK. A growth direction of the buffer structure 14 is from the second buffer surface BS2 with the group III-polarity toward the heat sink carrier 26.
(22) It will be clear to those skilled in the art that the thermal enhanced precursor 30 may have a different polarity order and the exposed surface of the thermal enhanced precursor 30 may have a different polarity. As shown in
(23) The thermal enhanced precursor 30 has the heat sink carrier 26 at a bottom portion of the thermal enhanced precursor 30, the high thermal conductivity substrate 24 over the heat sink carrier 26, and the buffer structure 14 over the thermal conductivity substrate 24. The high thermal conductivity substrate 24 has a thermal conductivity greater than 400 W/mK. A growth direction of the buffer structure 14 is from the second buffer surface BS2 with the N-polarity toward the heat sink carrier 26.
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(25) Next, an energy barrier layer 34 is formed over the channel layer 32 to complete a channel structure 36 and provide a semiconductor device 38, as depicted in
(26) The semiconductor device 38 has the heat sink carrier 26 at a bottom portion of the semiconductor device 38, the high the thermal conductivity substrate 24 over the heat sink carrier 26, the buffer structure 14 over the thermal conductivity substrate 24, and a channel structure 36 over the buffer structure 14. The high thermal conductivity substrate 24 has a thermal conductivity greater than 400 W/mK. The channel structure 36 has a first channel surface CS1 and a second channel surface CS2. In this embodiment, the first surface S32-1 of the channel layer 32 may be the first channel surface CS1, and the second surface S34-2 of the energy barrier layer 34 may be the second channel surface CS2, which is opposite the first channel surface CS1. The growth direction of the buffer structure 14 is from the second buffer surface BS2 with a group III-polarity toward the heat sink carrier 26. A growth direction of the channel structure 36 is from the first channel surface CS1 with an N-polarity to the second channel surface CS2 with a group III-polarity.
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(28) An energy barrier layer 42 is then formed over the buffer II layer 40 as depicted in
(29) Finally, a channel layer 44 is formed over the energy barrier layer 42 to complete a channel structure 46 and provide a semiconductor device 48 as depicted in
(30) The semiconductor device 48 has the heat sink carrier 26 at a bottom portion of the semiconductor device 48, the high thermal conductivity substrate 24 over the heat sink carrier 26, the buffer structure 14 over the thermal conductivity substrate 24, and the channel structure 46 over the buffer structure 14. The high thermal conductivity substrate 24 has a thermal conductivity greater than 400 W/mK. The channel structure 46 has a first channel surface CS1 and a second channel surface CS2. In this embodiment, the first surface S40-1 of the buffer II layer 40 may be the first channel surface CS1, and the second surface S44-2 of the channel layer 44 may be the second channel surface CS2, which is opposite the first channel surface CS1. The growth direction of the buffer structure 14 is from the second buffer surface BS2 with the N-polarity toward the heat sink carrier 26. A growth direction of the channel structure 46 is from the first channel surface CS1 with the group III-polarity to the second channel surface CS2 with the N-polarity.
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(32) Initially, a semiconductor precursor 50 including a substrate structure 52, a buffer structure 54 over the substrate structure 52, and a channel structure 56 over the buffer structure 54 is provided as depicted in
(33) The buffer structure 54 includes a buffer layer 62 and a release layer 64 over the buffer layer 62, and has a first buffer surface BS1 and a second buffer surface BS2. The buffer layer 62 may be formed of GaN or the like, having a first surface S62-1 with an N-polarity and a second surface S62-2 with a group III-polarity. The release layer 64 may be formed of Indium gallium nitride (InGaN) or the like, having a first surface S64-1 with an N-polarity and a second surface S64-2 with a group III-polarity. The first surface S62-1 of the buffer layer 62 is adjacent to the second surface S64-2 of the release layer 64. The second surface S62-2 of the buffer layer 62 is opposite the first surface S62-1 of the buffer layer 62, and the first surface S64-1 of the release layer 64 is opposite the second surface S64-2 of the release layer 64. Further, the first surface S64-1 of the release layer 64 may be the first buffer surface BS1 and the second surface S62-2 of the buffer layer 62 may be the second buffer surface BS2. Herein the second buffer surface BS2 is opposite the first buffer surface BS1 and adjacent to the first substrate surface SS1.
(34) In addition, the channel structure 56 includes an energy barrier layer 66 and a channel layer 68 over the energy barrier layer 66. The energy barrier layer 66 may be formed of AlGaN or the like, having a first surface S66-1 with an N-polarity and a second surface S66-2 with a group III-polarity. The channel layer 68 may be formed of GaN or the like, having a first surface S68-1 with an N-polarity and a second surface S68-2 with a group III-polarity. A 2DEG is formed at an interface between the energy barrier layer 66 and the channel layer 68. Since the 2DEG is normally formed adjacent to both an N-polarity surface of the energy barrier layer 66 and a group III-polarity surface of the channel layer 68, the first surface S66-1 of the energy barrier layer 66 with the N-polarity needs to be adjacent to the second surface S68-2 of the channel layer 68 with the group III-polarity.
(35) The channel structure 56 having a first channel surface CS1 and a second channel surface CS2 may further include a transition layer 70 over the channel layer 68. Herein, the transition layer 70 is an in situ transition layer, which is used to achieve a reliable bonding between the channel structure 56 and a high thermal conductivity substrate in a following process. The transition layer 70 may be formed from amorphous or polycrystalline materials, such as AlN, Silicon Nitride (SiN.sub.x), or the like, with a thickness between 0 nm and 100 nm. In different applications, the transition layer 70 may be not polarized or have mixed polarization. The transition layer 70 has a first surface S70-1 and a second surface S70-2, which is opposite the first surface S70-1 of the transition layer 70 and adjacent to the first surface S68-1 of the channel layer 68. Further, the first surface S70-1 of the transition layer 70 may be the first channel surface CS1 and the second surface S66-2 of the energy barrier layer 66 may be the second channel surface CS2. Herein, the second channel surface CS2 is opposite the first channel surface CS1 and adjacent to the first buffer surface BS1. In some applications, the channel structure 56 may not include the transition layer 70. As such, the first surface S68-1 of the channel layer 68 may be the first channel surface CS1 and the second surface S66-2 of the energy barrier layer 66 may be the second channel surface CS2.
(36) Next, a high thermal conductivity substrate 72 is formed over the channel structure 56 and adjacent to the first channel surface CS1 as depicted in
(37) After the intermediate structure 76 is formed, the intermediate structure 76 is flipped as depicted in
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(40) Those skilled in the art will recognize improvements and modifications to the preferred embodiments of the present disclosure. All such improvements and modifications are considered within the scope of the concepts disclosed herein and the claims that follow.