Method for the in situ passivation of the steel surfaces of a nuclear reactor

Abstract

The invention relates to the field of nuclear technology, and specifically to a method for the in situ passivation of steel surfaces. The method consists in installing, in a position intended for a regular core, a core simulator in the form of a model of the core, which models the shape thereof, the relative position of the core components, and also the mass characteristics thereof; next, the reactor is filled with a heavy liquid metal heat transfer medium, the heat transfer medium is heated to a temperature which provides for the conditions of passivation, and in situ passivation is carried out in two stages, the first of which includes an isothermal passivation mode in conformity with the conditions determined for this stage, and the second mode includes non-isothermal passivation, which is carried out under different conditions, after which the core simulator is removed and the regular core is installed in the place thereof. The method provides for the corrosion-resistance of steel elements in a heavy liquid metal heat transfer medium environment and permits a decrease in the maximum rate of oxygen consumption during the initial period of operation of a nuclear actor.

Claims

1. A method for in situ passivation of steel surfaces of a nuclear reactor, comprising the steps of: forming a protective film on a surface of the nuclear reactor primary circuit elements by introduction of a substance interacting with a material of the primary circuit elements into a primary circuit coolant, thus forming the protective film; wherein, during installation of the nuclear reactor prior to its filling with a reactor coolant, a core simulator is installed in place of a core, the nuclear reactor is filled with a reactor coolant that is heated to temperatures ensuring passivation conditions and then the core simulator is removed and replaced with a standard core.

2. The method according to claim 1, wherein a liquid metal coolant is used as the primary circuit coolant.

3. The method according to claim 2, wherein the in situ passivation is carried out in two stages, wherein the first stage is carried out under isothermal passivation conditions where oxygen is introduced into the liquid metal coolant, and the second stage is conducted under non-isothermal passivation conditions.

4. The method according to claim 3, wherein the isothermal passivation is carried out at T=300? C.-330? C.

5. The method according to claim 4, wherein oxygen is introduced in the liquid metal coolant with a thermodynamic activity a=10.sup.?1?10.sup.?3.

6. The method according to claim 5, wherein the oxygen thermodynamic is maintained fort=220 (?20) hours.

7. The method according to claim 3, wherein the non-isothermal passivation is performed with at least one pump on.

8. The method according to claim 7, wherein a power of the pump amounts to at least 30 percent of a rated value.

9. The method according to claim 7, wherein an oxygen concentration is maintained at a level of Co.sub.2=(1-4)*10.sup.?6 wt %.

10. The method according to claim 7, wherein the oxygen thermodynamic activity a is increased to a=10.sup.?2? 10.sup.?4.

11. The method according to claim 7, wherein the power of the pump is at least 30 percent of the rated value, the oxygen concentration Co.sub.2=(1-4)*10.sup.?6 wt % and the oxygen thermodynamic activity a=10.sup.?2?10.sup.?4 are maintained for t=550 (?50) hours.

12. The method according to claim 1, wherein the core simulator is a core model simulating its shape, relative position of core elements, and their masses and dimensions.

Description

INVENTION DISCLOSURE

(1) The purpose of the invention is reliable in situ passivation of steel surfaces of the primary circuit elements of a nuclear reactor with a heavy liquid metal coolant by means of creation of conditions for oxidation process development to ensure the required level of passivation at the initial stage of nuclear reactor operation.

(2) Considering the existing physical limitations of the known means in terms of possible intensity of oxygen introduction into the coolant, a situation may occur when the oxygen consumption due to oxidation reactions will exceed the rate of its introduction into a heavy liquid metal coolant, which means that maintaining the required oxygen conditions for the said coolant is impossible. The initial stage of nuclear reactor operation is the most problematic in this respect. The situation is further complicated by the fact that the initial stage of oxide film formation on steel products immersed in a heavy liquid metal coolant cannot be calculated correctly at the moment. Therefore, material errors occur during estimation of initial rates of steel oxidation making it difficult to compare with the capabilities of the heavy liquid metal coolant technology.

(3) A solution to these tasks allows to maintain a passivating film on the surfaces of steel elements during further operation of a nuclear reactor exclusively by standard means of mass transfer used in the nuclear reactor.

(4) The process of in situ passivation with a core simulator provides the following technical results: corrosion resistance of steel specimens not subjected to any special pretreatment for operation in a heavy liquid metal coolant; reduced maximum oxygen consumption rates that decrease as the primary circuit surfaces are oxidized at the initial stage of nuclear reactor operation; reduced dissolved oxygen performance of the process means of oxygen introduction into the coolant that maintain the required oxygen conditions at the initial stage of nuclear reactor operation.

(5) Given the fact that FEs can be pre-passivated, oxygen consumption for their oxidation can be further reduced significantly.

(6) These technical results are influenced by the following essential features of the nuclear reactor steel surface in situ passivation method.

(7) A method for the in situ passivation of the steel surfaces of a nuclear reactor consisting in that a protective film is formed on the surface of the nuclear reactor primary circuit elements by introduction a substance interacting with the material of the primary circuit elements into the coolant, thus forming a protective film, wherein, during installation of the nuclear reactor prior to its filling with the reactor coolant, a core simulator is installed in the place of the core, the reactor is filled with a coolant that is heated to temperatures ensuring passivation conditions and then the core simulator is removed and replaced with the standard core.

(8) A liquid metal coolant is used as the primary circuit coolant.

(9) The in situ passivation is carried out in two stages, wherein the first stage is carried out under isothermal passivation conditions where oxygen is introduced into the liquid metal coolant, and the second stage is conducted under non-isothermal passivation conditions.

(10) The isothermal passivation is carried out at T=300? C.-330? C.

(11) Oxygen with a thermodynamic activity of a=10.sup.?1?10.sup.?3 is introduced into the liquid metal coolant.

(12) Oxygen thermodynamic activity a=10.sup.?1?10.sup.?3 and temperature T=300? C.-330? C. are maintained for t=220 (?20) hours.

(13) The non-isothermal passivation is performed with a pump or pumps on.

(14) The power of the pump or pumps amounts to at least 30 percent of the rated value.

(15) The oxygen concentration is maintained at Co.sub.2=(1-4)*10.sup.?6 wt %.

(16) Oxygen thermodynamic activity a is increased to a=10.sup.?2?10.sup.?4.

(17) The power of the pump or pumps of at least 30 percent of the rated value, oxygen concentration Co.sub.2=(1-4)*10.sup.?6 wt % and oxygen thermodynamic activity a=10.sup.?2?10.sup.?4 are maintained for t=550 (?50) hours.

(18) The core simulator is a core model simulating its shape, relative position of the core elements, as well as their masses and dimensions.

(19) As in the prior art (RU 2456686), a protective film is formed on the surface of the elements of the reactor primary circuit for in situ passivation of steel surfaces of the fast nuclear reactor primary circuit by introduction of a substance interacting with the primary circuit element material into the nuclear reactor primary circuit heavy liquid coolant to form a protective film.

(20) The distinction of the claimed method is that a core simulator (CS), a core model simulating its shape, relative position of the core elements (including fuel assemblies), as well as their masses and dimensions, is installed in the standard core place during nuclear reactor installation prior to its filling with a liquid reactor coolant.

(21) Then the reactor is filled with a heavy liquid metal coolant, the coolant is heated to temperatures ensuring the passivation conditions.

(22) The in situ passivation is carried out in two stages, the first one including isothermal passivation at T=300-330? C. with pumps off and high oxygen thermodynamic activity a=10.sup.?1?10.sup.?3, where the said temperature and oxygen activity are maintained for t=220?20 hours, and the second stage involves non-isothermal passivation with the pumps on at the power level of at least 30% of the rated value for t=550?50 hours, wherein the oxygen concentration is maintained at the level of Co.sub.2=(1-4)*10.sup.?6 wt % with high oxygen thermodynamic activity a=10.sup.?2?10.sup.?4, then the core simulator is removed and replaced with the standard core, wherein the coolant temperature increases from T=300-330? C. to the level required for passivation (T=410-420? C.).

(23) Then the achieved oxygen concentration is maintained in the liquid metal coolant during normal operation.

(24) Application of a full-scale CS in the hot trial mode to simulate the flow around all elements of the primary circuit of a nuclear reactor allows to improve corrosion resistance of structural steel in the primary circuit with a heavy liquid metal coolant by steel oxidation in the heavy liquid metal coolant medium and reduce the required oxygen concentration for normal operation under oxygen concentration conditions of at least (CO2=(1-10)*10.sup.?6 wt %).

(25) Preliminary (off-circuit, for instance, factory) passivation of such primary circuit elements as the core and steam generators allows to reduce the intensity of oxygen consumption by about 50% during normal operation, wherein passivation of steam generators yields the maximum effect (?30%) due to the fact they have a large surface area in contact with the liquid metal coolant. A significant advantage of the claimed method is that thin continuous and durable (corrosion) protection oxide films are formed when the above conditions are met. Studies have shown that to reduce the intensity of oxidizing interaction of steel with the coolant under normal (operating) conditions effectively, film thickness of approx. 1-2 ?m is sufficient at the initial stage of nuclear reactor operation.

(26) During application of the claimed method of damaging the oxide layer formed in the heavy liquid metal coolant flow in the course of bench corrosion tests of unpassivated steel specimens of the primary circuit at the selected oxygen concentration, no corrosion damage occurred during the tests, on the contrary, damages were remedied and an oxide layer of the required thickness, strength and continuity was formed.

(27) To substantiate the claimed method of in situ passivation, a significant number of experiments were conducted. In particular, with regard to the essential components of the primary circuit, fuel elements (steel EP-823), it was demonstrated that preoxidation in the melt provides reliable corrosion protection of the whole steel surface at higher temperatures (t=620-650? C.) on the basis of 1000 to 5000 hours with good statistics (tens of campaigns). The latter circumstance is essential as pitting corrosion spots were detected from time to time with a statistical dispersion on witness specimens without protection of any kind, including preoxidation, during the very tests.

IMPLEMENTATION OF THE INVENTION

(28) Based on the experimental data, the most suitable mode is the in situ passivation at 410-420? C. with high oxygen concentration (Co.sub.2?1*10.sup.?5 wt %), which allows to combine the passivation with duration between 2 and 4 weeks with other commissioning operations and does not lead to unnecessary delays in the reactor plant start-up.

(29) Implementation of the steel surface in situ passivation with the heavy liquid metal coolant fast reactor core simulator is performed in separate stages and involves the following mandatory process operations: installation of the CS in the regular place of the reactor plant core; reactor filling with a heavy liquid metal cooled; coolant heating up to the temperatures ensuring the passivation conditions; in situ passivation, including isothermal passivation conditions (T=300-330? C., t?220 hours), and non-isothermal passivation conditions (at the pump power level of at least 30% of the rated value for t?550 hours) with high oxygen thermodynamic activity (a=10.sup.?1?10.sup.?3 for isothermal and a=10.sup.?2?10.sup.?4 for non-isothermal); removal of the CS.

(30) Then, after replacement of the CS with the standard core, during normal operation of the fast nuclear reactor, the necessary oxygen concentration is maintained continuously, which ensures continuous passivation of steel parts that goes on at normal coolant temperatures, but less intensively than during the implementation of the claimed method using the CS.