Estimation method of state of charge of power storage device and estimation system of state of charge of power storage device
11493558 · 2022-11-08
Assignee
Inventors
Cpc classification
H01M10/425
ELECTRICITY
H02J7/342
ELECTRICITY
Y04S30/12
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M2010/4278
ELECTRICITY
H02J7/0048
ELECTRICITY
H01M10/48
ELECTRICITY
Y02T10/70
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E60/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M2220/20
ELECTRICITY
B60L3/12
PERFORMING OPERATIONS; TRANSPORTING
H01M10/482
ELECTRICITY
B60L50/64
PERFORMING OPERATIONS; TRANSPORTING
G01R31/367
PHYSICS
Y02T90/167
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
G01R31/367
PHYSICS
H01M10/48
ELECTRICITY
H01M10/42
ELECTRICITY
Abstract
A capacity measurement system of a secondary battery that estimates an SOC with high estimation accuracy in a short time at low cost is provided. The capacity measurement system of a secondary battery is an estimation system of a state of charge of a power storage device that includes a unit for acquiring time-series data of a voltage measured value and a current measured value of a first power storage device; a unit for normalizing the time-series data of the voltage measured value; a unit for normalizing the time-series data of the current measured value; a database creation unit for creating a database where an SOC of the first power storage device is linked to superimposed data of time-series data of a time axis corresponding to a vertical axis and time-series data of a time axis corresponding to a horizontal axis; and a neural network unit.
Claims
1. An estimation system of a state of charge of a second power storage device comprising: a computer configured to: acquire voltage time-series data of a first power storage device and current time-series data of the first power storage device; and store the voltage time-series data of the first power storage device and the current time-series data of the first power storage device as normalized data in a database, in which a state of charge of the first power storage device is linked to first superimposed data; and a neural network unit comprising a neural network configured to include the data in the database as learning data, the neural network unit configured to output, based upon the learning data, an estimated state of charge value of the second power storage device when a second superimposed data is input, wherein the first superimposed data is formed by superimposing first data where a vertical axis represents a voltage value of normalized voltage time-series data of the first power storage device and a horizontal axis represents a time axis of the normalized voltage time-series data of the first power storage device on second data where a horizontal axis represents a current value of normalized current time-series data of the first power storage device and a vertical axis represents a time axis of the normalized current time-series data of the first power storage device, and wherein the second superimposed data is formed by superimposing third data where a vertical axis represents a voltage value of normalized voltage time-series data of the second power storage device and a horizontal axis represents a time axis of the normalized voltage time-series data of the second power storage device on fourth data where a horizontal axis represents a current value of normalized current time-series data of the second power storage device and a vertical axis represents a time axis of the normalized current time-series data of the second power storage device.
2. The estimation system of a state of charge of a second power storage device, according to claim 1, wherein the second power storage device includes a plurality of battery cells.
3. The estimation system of a state of charge of a second power storage device, according to claim 1, wherein the neural network is a convolutional neural network.
4. The estimation system of a state of charge of a second power storage device according to claim 1, wherein each of the first superimposed data and the second superimposed data is image data.
5. The estimation system of a state of charge of a second power storage device according to claim 1, wherein each of the first superimposed data and the second superimposed data is encoded digital data.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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MODE FOR CARRYING OUT THE INVENTION
(12) Embodiments of the present invention will be described in detail with reference to the drawings. Note that the present invention is not limited to the following description, and it will be readily understood by those skilled in the art that modes and details of the present invention can be modified in various ways. In addition, the present invention should not be construed as being limited to the description of embodiments below.
Embodiment 1
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(14) In an estimation system of a state of charge of a power storage device, a neural network unit 23 is first constructed by a database creation unit 14 using current time-series data, voltage time-series data, SOC data for learning of a secondary battery 10 for learning. Second, current time-series data and voltage time-series data of a secondary battery 20 are input to the constructed learned neural network unit 23, and the SOC of the target secondary battery 20 is output. The current time-series data and the voltage time-series data are measured by a data acquisition unit 11 and are stored in a memory or the like. A data creation unit 12 makes the database creation unit 14 store acquired data as normalized data. In addition, the SOC data for learning that corresponds to the normalized data is stored in a label storage unit 13 and is linked to data in the database creation unit 14.
(15) The estimation system of a state of charge of a power storage device includes a data acquisition unit 21, a data creation unit 22, and the neural network unit 23. The neural network unit 23 is composed of a circuit (a microcomputer) that performs neural network calculation and is an IC in which an AI (Artificial Intelligence) system is incorporated, for example.
(16) The estimation system of a state of charge of a power storage device can output an estimated SOC value in accordance with a flow chart shown in
(17) First, voltage time-series data and current time-series data are acquired in the data acquisition unit 21 that acquires parameters such as electrical performance and temperature of a secondary battery, and each of the voltage time-series data and the current time-series data is normalized. The order of the voltage performance (voltage time-series data) normalization (S1) and the current performance (current time-series data) normalization (S2) may be reversed. In the normalization, part of a region with a small change (e.g., an idle period or the like) may be eliminated.
(18) Then, a vertical axis represents a time axis of the normalized current time-series data and the current time-series data is superimposed on the voltage time-series data so that a piece of data (also referred to as two-dimensional data or an image pattern) is produced (S3). In the case where the piece of data is produced, the lengths of the vertical axis and the horizontal axis are made substantially equal to each other and the piece of data is adjusted as appropriate not to have a too large blank area.
(19) Then, the piece of data is input to the learned neural network (S4). An SOC is estimated with high accuracy by calculation in the neural network unit 23 according to the above series of steps (S5).
(20) In addition, here, learning of the neural network is described below with reference to
(21) In this embodiment, in order to check the SOC accuracy, learning is performed using one battery cell NCR18650B and data (including an SOC value) that is acquired from charging and discharging cycle test patterns for an EV described in International Standard IEC62660-01.
(22) Here, a description is made using the charging and discharging cycle test patterns described in IEC62660-01; however, it is preferable to use charging and discharging data based on actual behavior of an assumed application for learning. In the case where a plurality of pieces of data are prepared, the pieces of data are repeatedly accumulated, and measurement at different ambient temperatures or measurement of a cell with degradation caused by repeated cycles is further preferably added. Note that a secondary battery for learning has the same size and the same kind as those of a secondary battery to be examined, preferably a secondary battery for learning whose manufacturing time is close to that of the secondary battery to be examined is used, further preferably a secondary battery for learning that is in the same lot as that of the secondary battery to be examined is used, in which case the SOC can be output with higher accuracy.
(23) Then,
(24)
(25) In addition, as a comparative example,
(26) Although an example in which measured IEC data is used is described in this embodiment, in the case where a neural network is constructed based on secondary battery data for learning in advance, usage history data of the secondary battery to be examined is actually obtained at regular time intervals or in real time so that the SOC can be estimated with high accuracy.
Embodiment 2
(27) In this embodiment, a structure example of a neural network NN used in Steps S4 and S5 shown in
(28)
(29) A function of analyzing the state of a storage battery is added to the neural network NN by learning. Then, calculation processing is performed in each layer when the parameter of the measured storage battery is input to the neural network NN. The calculation processing in each layer is executed through the product-sum operation or the like of an output from a neuron circuit in the previous layer and a weight coefficient. Note that the connection between layers may be a full connection where all of the neuron circuits are connected or may be a partial connection where some of the neuron circuits are connected.
(30) For example, a convolutional neural network (CNN), which includes a convolutional layer and a pooling layer in which only specific units in adjacent layers have connection, may be used. The CNN is used for classification of image data that is converted from charging performance data, for example. In the convolutional layer, product-sum operation of the image data and a weight parameter is performed, for example. The pooling layer is preferably placed directly after the convolutional layer.
(31) The convolutional layer has a function of performing convolution on image data. The convolution is performed by repetition of the product-sum operation of part of the image data and a weight parameter's filter value. Features of the image data are extracted through the convolution in the convolutional layer.
(32) A weight parameter (also referred to as a weight filter) can be used for the convolution. The image data input to the convolutional layer is subjected to filter processing using the weight parameter.
(33) The data subjected to the convolution is converted by an activation function, and then is output to the pooling layer. As the activation function, ReLU (Rectified Linear Units) or the like can be used. The ReLU is a normalization linear function in which “0” is output when an input value is negative and the input value is directly output when the input value is greater than or equal to “0.” In addition, as the activation function, a sigmoid function, a tanh function, or the like can also be used.
(34) The pooling layer has a function of performing pooling on the image data input from the convolutional layer. Pooling is processing in which the image data is partitioned into a plurality of regions, and predetermined data is extracted from each of the regions and the data are arranged in a matrix. The pooling reduces the image data with the features extracted by the convolutional layer remaining. Note that as the pooling, max pooling, average pooling, Lp pooling, or the like can be used.
(35) In the convolutional neural network (CNN), feature extraction is performed using the convolution processing and pooling processing. Note that the CNN can be composed of a plurality of convolutional layers and a plurality of pooling layers.
(36) A fully-connected layer is preferably placed after several convolutional layers and several pooling layers that are arranged alternately, for example. A plurality of fully-connected layers may be placed. The fully-connected layer preferably has a function of determining whether a secondary battery is normal or abnormal by using the image data subjected to the convolution and the pooling.
(37) In addition, this embodiment can be freely combined with Embodiment 1.
Embodiment 3
(38) An example of a cylindrical secondary battery is described with reference to
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(40) Since a positive electrode and a negative electrode that are used for a cylindrical storage battery are wound, active materials are preferably formed on both surfaces of a current collector. A positive electrode terminal (positive electrode current collector lead) 603 is connected to the positive electrode 604, and a negative electrode terminal (negative electrode current collector lead) 607 is connected to the negative electrode 606. For both the positive electrode terminal 603 and the negative electrode terminal 607, a metal material such as aluminum can be used. The positive electrode terminal 603 and the negative electrode terminal 607 are resistance-welded to a safety valve mechanism 612 and the bottom of the battery can 602, respectively. The safety valve mechanism 612 is electrically connected to the positive electrode cap 601 through a PTC element (Positive Temperature Coefficient) 611. The safety valve mechanism 612 cuts off electrical connection between the positive electrode cap 601 and the positive electrode 604 when the internal pressure of the battery exceeds a predetermined threshold value. In addition, the PTC element 611 is a thermally sensitive resistor whose resistance increases as temperature rises, and limits the amount of current by increasing the resistance to prevent abnormal heat generation. Barium titanate (BaTiO.sub.3)-based semiconductor ceramics or the like can be used for the PTC element.
(41) A lithium-ion secondary battery using an electrolyte solution includes a positive electrode, a negative electrode, a separator, an electrolyte solution, and an exterior body. Note that in a lithium-ion secondary battery, an anode (positive electrode) and a cathode (negative electrode) are interchanged in charging and discharging, and oxidation reaction and reduction reaction are interchanged; thus, an electrode with a high reaction potential is called a positive electrode and an electrode with a low reaction potential is called a negative electrode. For this reason, in this specification, the positive electrode is referred to as a “positive electrode” or a “+ electrode (plus electrode)” and the negative electrode is referred to as a “negative electrode” or a “− electrode (minus electrode)” in any of the case where charging is performed, the case where discharging is performed, the case where reverse pulse current is supplied, and the case where charging current is supplied. The use of terms “anode” and “cathode” related to oxidation reaction and reduction reaction might cause confusion because the anode and the cathode interchange in charging and in discharging. Thus, the terms “anode” and “cathode” are not used in this specification. If the term “anode” or “cathode” is used, it should be clearly mentioned that the anode or the cathode is which of the one in charging or in discharging and corresponds to which of the positive electrode (plus electrode) or the negative electrode (minus electrode).
(42) A charger is connected to two terminals illustrated in
(43) In this embodiment, an example of a lithium-ion secondary battery is shown; however, it is not limited to a lithium-ion secondary battery and a material including an element A, an element X, and oxygen can be used as a positive electrode material for the secondary battery, for example. The element A is preferably one or more selected from the Group 1 elements and the Group 2 elements. As the Group 1 element, for example, an alkali metal such as lithium, sodium, or potassium can be used. In addition, as the Group 2 element, for example, calcium, beryllium, magnesium, or the like can be used. As the element X, for example, one or more selected from metal elements, silicon, and phosphorus can be used. Furthermore, the element X is preferably one or more selected from cobalt, nickel, manganese, iron, and vanadium. Typical examples include lithium-cobalt composite oxide (LiCoO.sub.2) and lithium iron phosphate (LiFePO.sub.4).
(44) The negative electrode includes a negative electrode active material layer and a negative electrode current collector. In addition, the negative electrode active material layer may contain a conductive additive and a binder.
(45) For a negative electrode active material, an element that enables charge-discharge reaction by alloying reaction and dealloying reaction with lithium can be used. For example, a material containing at least one of silicon, tin, gallium, aluminum, germanium, lead, antimony, bismuth, silver, zinc, cadmium, indium, and the like can be used. Such elements have higher capacity than carbon. In particular, silicon has a high theoretical capacity of 4200 mAh/g.
(46) In addition, the secondary battery preferably includes a separator. As the separator, for example, fiber containing cellulose such as paper; nonwoven fabric; glass fiber; ceramics; synthetic fiber using nylon (polyamide), vinylon (polyvinyl alcohol-based fiber), polyester, acrylic, polyolefin, or polyurethane; or the like can be used.
(47) In addition,
(48) In an electric vehicle, a first battery 301 as a secondary battery for main driving and a second battery 311 that supplies power to an inverter 312 starting a motor 304 are provided. In this embodiment, a neural network unit 300 driven by power supply from the second battery 311 selects and uses each of a plurality of secondary batteries constituting the first battery 301 individually.
(49) The first battery 301 mainly supplies power to in-vehicle parts for 42 V (for a high-voltage system) and the second battery 311 supplies power to in-vehicle parts for 14 V (for a low-voltage system). As the second battery 311, a lead-acid battery is often adopted because it is advantageous in cost. Lead-acid batteries have disadvantages compared with lithium-ion secondary batteries in that they have a larger amount of self-discharge and are more likely to degrade due to a phenomenon called sulfation. An advantage of using a lithium-ion secondary battery as the second battery 311 is eliminating the need for maintenance; however, when the lithium-ion secondary battery is used over a long time, for example three years or longer, abnormalities that cannot be determined at the time of manufacturing the battery might occur. In particular, when the second battery 311 that starts the inverter becomes inoperative, the motor cannot be started even when the first battery 301 has remaining capacity; thus, in order to prevent this, in the case where the second battery 311 is a lead-acid battery, the second battery is supplied with power from the first battery to constantly maintain a fully-charged state.
(50) In this embodiment, an example in which lithium-ion secondary batteries are used as both the first battery 301 and the second battery 311 is described. A lead-acid battery or an all-solid-state battery may be used as the second battery 311.
(51) In addition, regenerative energy the rotation of tires 316 is transmitted to the motor 304 through a gear 305 and a motor controller 303 and a battery controller 302 charges the second battery 311 or the first battery 301.
(52) In addition, the first battery 301 is mainly used to rotate the motor 304 and supplies power to in-vehicle parts for 42 V (such as an electric power steering 307, a heater 308, and a defogger 309) through a DCDC circuit 306. Even in the case where there is a rear motor for rear wheels, the first battery 301 is used to rotate the rear motor.
(53) Furthermore, the second battery 311 supplies power to in-vehicle parts for 14 V (such as a stereo 313, a power window 314, and lamps 315) through a DCDC circuit 310.
(54) In addition, the first battery 301 is composed of a plurality of secondary batteries. As illustrated in
(55) In order to cut off power from the plurality of secondary batteries, the secondary batteries in the vehicle include a service plug or a circuit breaker that can cut off high voltage without the use of equipment; these are provided in the first battery 301. For example, in the case where 48 battery modules that each include two to ten cells are connected directly, the service plug or the circuit breaker is placed between a 24th module and a 25th module.
(56) In addition, a circuit (a microcomputer) that performs neural network calculation may be incorporated in a vehicle component other than the battery controller or may be incorporated in a portable information terminal of a passenger. The microcomputer includes a CPU, a ROM, a RAM, or the like. Furthermore, in the neural network calculation, communication with another computer may be performed and data accumulated in the other computer may be used. When the communication with another computer is performed and the data accumulated in the other computer is used to perform the neural network calculation, the neural network calculation can be performed using a huge amount of data.
(57) The neural network unit 300 performs learning using the same type of battery as the first battery 301 in advance; thus, the SOC of the first battery 301 can be output with high accuracy.
(58) In addition, this embodiment can be freely combined with Embodiment 1 or Embodiment 2.
Embodiment 4
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(60) An automobile 8500 illustrated in
(61) Furthermore, although not illustrated, a power receiving device can be incorporated in the vehicle, and the vehicle can be charged by being supplied with power from an above-ground power transmitting device in a contactless manner. In the case of this contactless power feeding system, by incorporating a power transmitting device in a road or an exterior wall, charging can also be performed while the vehicle is driven without limitation on the period while the vehicle is stopped. In addition, this contactless power feeding system may be utilized to transmit and receive power between vehicles. Furthermore, a solar cell may be provided in an exterior part of the vehicle to charge the secondary battery while the vehicle is stopped or while the vehicle is driven. For power supply in such a contactless manner, an electromagnetic induction method or a magnetic resonance method can be used.
(62) In addition,
(63) Furthermore, in the scooter 8600 illustrated in
(64)
(65) The voltage of the secondary battery 8602 in the scooter 8600 is 48 V or 60 V, and power is supplied to the motor 8606. After a converter lowers the voltage to 12 V, power is supplied to electric equipment such as the direction indicator lamps 8603. An in-wheel motor in which a motor is directly set in a wheel that is to be a driving wheel can also be used.
(66) The charging of the secondary battery 8602 in the scooter 8600 is controlled by a charging control circuit 8608, and the SOC of the secondary battery 8602 is estimated by a neural network unit 8607.
(67) In addition, in the case where regenerative power is used for charging, a regenerative circuit 8621 and a regenerative battery 8622 may be provided. In the case where regenerative power is not used for charging, it is possible to eliminate the need for the regenerative circuit 8621 and the regenerative battery 8622.
(68) Furthermore, when a driver performs accelerator operation, a signal from an accelerator operation detection unit 8610 is transmitted to the control circuit 8609, and the power of the secondary battery is transmitted to the motor in accordance with the degree of opening of an accelerator. Moreover, when the driver performs braking operation, a signal from a braking operation detection unit 8611 is transmitted to the control circuit 8609, the regenerative battery 8622 is once charged with regenerative power at the time of deceleration, and the secondary battery 8602 is charged through the charging control circuit 8608. The charging history is learned by the neural network unit 8607 and feedback is performed.
(69) This embodiment can be combined with the description of the other embodiment as appropriate.
REFERENCE NUMERALS
(70) 10: secondary battery, 11: data acquisition unit, 12: data creation unit, 13: label storage unit, 14: database creation unit, 20: secondary battery, 21: data acquisition unit, 22: data creation unit, 23: neural network unit, 300: neural network unit, 301: battery, 302: battery controller, 303: motor controller, 304: motor, 305: gear, 306: DCDC circuit, 307: electric power steering, 308: heater, 309: defogger, 310: DCDC circuit, 311: battery, 312: inverter, 314: power window, 315: lamps, 316: tire, 600: secondary battery, 601: positive electrode cap, 602: battery can, 603: positive electrode terminal, 604: positive electrode, 605: separator, 606: negative electrode, 607: negative electrode terminal, 608: insulating plate, 609: insulating plate, 611: PTC element, 612: safety valve mechanism, 613: conductive plate, 614: conductive plate, 1400: storage battery, 1402: positive electrode, 1404: negative electrode, 8021: charging device, 8022: cable, 8024: secondary battery, 8400: automobile, 8401: headlamp, 8406: electric motor, 8500: automobile, 8600: scooter, 8601: side mirror, 8602: secondary battery, 8603: direction indicator lamp, 8604: under-seat storage, 8606: motor, 8607: neural network unit, 8608: charging control circuit, 8609: control circuit, 8610: accelerator operation detection unit, 8611: braking operation detection unit, 8621: regenerative circuit, and 8622: regenerative battery.