COMPOSITION COMPRISING AT LEAST ONE OXIDATION DYE, 1,3-PROPANEDIOL, AT LEAST ONE ALKALINE AGENT AND AT LEAST ONE FATTY SUBSTANCE

Abstract

The invention relates to a composition comprising at least one oxidation dye, 1,3-propanediol, at least one alkaline agent and at least one fatty substance other than fatty acids.

Claims

1-23. (canceled)

24. A composition comprising: at least one oxidation dye chosen from: (i) at least one coupler chosen from: 6-hydroxybenzomorpholine of formula (I), addition salts thereof, solvates thereof and/or the solvates of salts thereof; hydroxyethyl-3,4-methylenedioxyaniline of formula (II), addition salts thereof, solvates thereof and/or the solvates of salts thereof; or 2-amino-5-ethylphenol of formula (III), addition salts thereof, solvates thereof and/or the solvates of salts thereof; ##STR00012## (ii) at least one base chosen from: 2-p-hydroxyethyl-para-phenylenediamine and addition salts thereof, solvates thereof and/or the solvates of salts thereof; 2-(-hydroxypropyl)-para-phenylenediamine and addition salts thereof, solvates thereof and/or the solvates of salts thereof; or 2-methoxymethyl-para-phenylenediamine and addition salts thereof, solvates thereof and/or the solvates of salts thereof; or (iii) mixtures of any two or more oxidation dyes thereof; propane-1,3-diol; at least one alkaline agent; and at least one fatty substance other than fatty acids.

25. The composition of claim 24, wherein the at least one oxidation dye is chosen from the (i) coupler(s).

26. The composition of claim 25, wherein the total amount of the coupler(s) (i) ranges from 0.001% to 20% by weight, relative to the total weight of the composition.

27. The composition of claim 24, wherein the total amount of propane-1,3-diol ranges from 0.01% to 25% by weight, relative to the total weight of the composition.

28. The composition of claim 24, wherein the at least one alkaline agent is chosen from alkanolamines.

29. The composition of claim 24, wherein the total amount of the alkaline agent(s) ranges from 0.1% to 40% by weight, relative to the total weight of the composition.

30. The composition of claim 24, wherein the at least one fatty substance other than fatty acids comprises at least one liquid fatty substance other than fatty acids.

31. The composition of claim 24, wherein the at least one fatty substance other than fatty acids comprises at least one solid fatty substance other than fatty acids.

32. The composition of claim 24, wherein the total amount of fatty substance(s) other than fatty acids ranges from 5% to 30% by weight, relative to the total weight of the composition.

33. The composition of claim 31, wherein the total amount of solid fatty substance(s) other than fatty acids ranges from 5% to 30% by weight, relative to the total weight of the composition.

34. The composition of claim 30, wherein the total amount of liquid fatty substance(s) other than fatty acids ranges from 0.5% to 15% by weight, relative to the total weight of the composition.

35. The composition of claim 24, further comprising (iii) at least one additional coupler other than the (ii) at least one coupler.

36. The composition of claim 24, further comprising at least one surfactant.

37. The composition of claim 36, wherein the at least one surfactant is chosen from anionic surfactants, nonionic surfactants, or mixtures thereof.

38. The composition of claim 24, further comprising at least one sequestrant.

39. The composition of claim 24, further comprising at least one thickening polymer.

40. The composition of claim 24, wherein the composition is free of any chemical oxidizing agents.

41. The composition of claim 24, further comprising at least one chemical oxidizing agent.

42. A method for dyeing keratin fibres, comprising mixing at least a dyeing composition and an oxidizing composition, wherein the dyeing composition comprises: at least one coupler chosen from: 6-hydroxybenzomorpholine of formula (I), addition salts thereof, solvates thereof and/or the solvates of salts thereof; hydroxyethyl-3,4-methylenedioxyaniline of formula (II), addition salts thereof, solvates thereof and/or the solvates of salts thereof; 2-amino-5-ethylphenol of formula (111), addition salts thereof, solvates thereof and/or the solvates of salts thereof; or mixtures thereof; ##STR00013## propane-1,3-diol; at least one alkaline agent; at least one fatty substance other than fatty acids; and optionally at least one oxidation base; and wherein the oxidizing composition comprises at least one chemical oxidizing agent.

43. A multi-compartment device, comprising: at least a first compartment comprising a dyeing composition comprising: at least one coupler chosen from: 6-hydroxybenzomorpholine of formula (I), addition salts thereof, solvates thereof and/or the solvates of salts thereof; hydroxyethyl-3,4-methylenedioxyaniline of formula (II), addition salts thereof, solvates thereof and/or the solvates of salts thereof; 2-amino-5-ethylphenol of formula (III), addition salts thereof, solvates thereof and/or the solvates of salts thereof; or mixtures thereof; ##STR00014## propane-1,3-diol; at least one alkaline agent; at least one fatty substance other than fatty acids; and optionally at least one oxidation base; and at least a second compartment comprising an oxidizing composition comprising at least one chemical oxidizing agent.

Description

EXAMPLES

[0377] In the examples that follow, all the amounts are given as mass percentages of active material (AM) relative to the total weight of the composition (unless otherwise mentioned).

Example 1

Composition The dye compositions A1 and A2 and the oxidizing composition O were prepared from the ingredients of which the contents are indicated in the table below (% AM):

Dye Compositions

[0378]

TABLE-US-00001 TABLE 1 A1 A2 (invention) (comparative) Xanthan gum 0.2 0.2 Oleic acid 2.7 2.7 Ethanolamine 12.2 12.2 Coco glucoside 1.87 1.87 Hydroxybenzomorpholine 0.3 0.3 2-Methoxymethyl-p-phenylenediamine 0.3 0.3 1,3-Propanediol 5 Propylene glycol 5 Tetrasodium glutamate diacetate 0.24 0.24 Glycerol 5 5 Cetearyl alcohol 16.3 16.3 Oleyl alcohol 2.7 2.70 Water qs 100 qs 100

Oxidizing Composition

[0379]

TABLE-US-00002 TABLE 2 O Trideceth-2 carboxamide MEA 0.85 Tetrasodium etidronate 0.06 Sodium salicylate 0.035 Glycerol 0.5 Cetearyl alcohol 2.28 Ceteareth-25 0.57 Phosphoric acid qs pH = 2.2 0.2 Hydrogen peroxide 6 Tetrasodium pyrophosphate 0.04 Water qs 100

[0380] At the time of use, each of the dye compositions A1 and A2 is mixed with 1.5 times its weight of oxidizing agent O. Each of the mixtures is then applied to locks of moderately sensitized hair (alkaline solubility 20%), in a proportion of 5 g of mixture/g of hair.

[0381] After a leave-on time of 30 minutes on a plate thermostatically regulated at 27 C., the hair is rinsed, washed with a standard shampoo and dried.

Results

[0382] The colorimetric measurements were performed using a Konica Minolta 3600 spectrocolorimeter (illuminant D65, angle 10, specular component included) in the CIELab system.

[0383] In this system, L* represents the luminance.

[0384] The lower the L* value, the more powerful the colouring obtained.

TABLE-US-00003 TABLE 3 L* A1 + O (invention) 36.6 A2 + O (comparative) 40.0

[0385] The composition A1 according to the invention comprising 1,3-propanediol leads to a better colouring power, in comparison with the comparative composition A2 comprising propylene glycol.

Example 2

Compositions

[0386] The dye composition A3 was prepared from the ingredients of which the contents are indicated in the table below (% AM):

Dye Composition

[0387]

TABLE-US-00004 TABLE 4 A3 XANTHAN GUM 0.2 OLEIC ACID 2.7 ETHANOLAMINE 12.7 COCO-GLUCOSIDE 1.87 HYDROXYETHYL-3,4-METHYLENEDIOXYANILINE HCL 0.3 HYDROXYPROPYL-P-PHENYLENEDIAMINE HCL 0.3 1,3-PROPANEDIOL 5 TETRASODIUM GLUTAMATE DIACETATE 0.24 GLYCERIN 5 CETEARYL ALCOHOL 16.3 OLEYL ALCOHOL 2.7 WATER Qs 100

[0388] At the time of use, composition A3 is mixed with 1.5 times its weight of oxidizing agent O disclosed in example 1.

[0389] The mixtures is then applied to locks of 90% permanent-waved grey hair, in a proportion of 5 g of mixture/g of hair.

[0390] After a leave-on time of 30 minutes on a plate thermostatically regulated at 27 C., the hair is rinsed, washed with a standard shampoo and dried.

Results

[0391] The colorimetric measurements were performed using a Konica Minolta CM-3600A spectrocolorimeter (illuminant D65, angle 10, specular component included) in the CIELab system.

[0392] The chromaticity is calculated by the following formula:

[00001]$C^{*}=\sqrt{{\left(a^{*}\right)}^2+{\left(b^{*}\right)}^2}$ [0393] a* indicates the green/red color axis [0394] b* indicates the blue/yellow color axis

[0395] The higher the value of the chromaticity C*, the greater the chromaticity is.

[0396] The composition according to the invention leads to a high C* value, and thus to a good chromaticity.