COSMETIC MASK FOR APPLICATION TO THE SKIN, AND METHOD FOR APPLYING SAME

20230099298 · 2023-03-30

    Inventors

    Cpc classification

    International classification

    Abstract

    The inventions relate to cosmetology and are intended to increase a cosmetic effect. A mask comprises a cream-type cosmetic agent and an additional reagent, which are isolated from one another. The agent contains a water-soluble biocompatible polymer which has a mass in the range of 50,000-1,000,000 Da and is capable of entering into a cross-polymerisation reaction. The reagent consists of a substance-electrolyte solution containing multicharged ions. The mass ratio of polymer and substance-electrolyte is from 10:1 to 1:1 respectively. A method involves separately applying to the skin the cream-type agent and then the additional reagent on top.

    Claims

    1. A cosmetic mask for applying to a skin, comprising a creamy cosmetic product on a fat, emulsion, or gel base and an additional reagent isolated from each other, characterized in that the creamy cosmetic product additionally contains in an amount of 0.01-10.0 wt. % a water-soluble biocompatible polymer with a mass in the range 50,000-1,000,000 Da, capable of undergoing a cross-polymerization reaction and selected from the group consisting of: polyvinyl alcohol, polyvinyl pyrrolidone, water-soluble modifications of polysaccharides, water-soluble copolymers of polysaccharides and mixtures thereof; and the additional reagent of the cosmetic mask contains a 0.5-15.0% aqueous solution of an electrolyte substance containing multiply charged ions, while weight ratio of the water-soluble biocompatible polymer to the electrolyte substance in an aqueous solution is from 10:1 to 1:1, respectively.

    2. The mask according to claim 1, wherein the water-soluble biocompatible polymer includes in its structure free groups, which do not form chemical bonds with monomers, selected from the following: hydroxyl group, carbonyl group, carboxyl group; a carboxyl group that has formed salt-like compounds with singly charged cations, or a combination of the above groups.

    3. The mask according to claim 1, wherein water-soluble modifications of the polysaccharides include a polymer selected from the following: hydroxyethyl starch, chitosan, carrageenan; the water-soluble copolymers of polysaccharides include a polymer selected from the following: xanthan gum, sodium alginate; and the mixtures thereof include polymers selected from following: agar-agar.

    4. The mask according to claim 1, wherein as the mixture of the polymers in the creamy cosmetic product a two-component mixture of these polymers is used in the range of weight ratios from 1:100 to 1:1.

    5. The mask according to claim 1, wherein the creamy cosmetic product in its base contains oils: basic and/or essential; and/or cosmetic emulsifiers; and/or emollients; and/or active components; and water.

    6. The mask according to claim 1, wherein as basic oils a creamy cosmetic contains in its base an Extra Virgin olive oil and/or grape seed oil and/or Shea butter and/or Babassu oil and/or Sesame oil.

    7. The mask according to claim 1, wherein as essential oils the creamy cosmetic product contains in its base bergamot essential oil and/or vanilla essential oil and/or tea tree essential oil and/or ylang-ylang essential oil, and/or sandalwood essential oil, and/or patchouli essential oil, and/or lavender essential oil.

    8. The mask according to claim 1, wherein as cosmetic emulsifiers, the creamy cosmetic product contains in its base cetyl alcohol and/or cetearyl alcohol and/or lecithin and/or beeswax and/or hydroxyethyl cellulose, and/or polyethylene glycol and/or polyvinyl alcohol.

    9. The mask according to claim 1, wherein as emollients, the creamy cosmetic product in its base contains substances selected from the group, including: mineral oils, emollients of natural origin, for example, lanolin, ceresine, low molecular weight silicones.

    10. The mask according to claim 1, wherein as the active components, the cosmetic product in its base contains substances selected from the group, including: hyaluronic acid, or allantoin, or inulin, or herbal extracts, or urea.

    11. The mask according to claim 1, wherein the cosmetic product additionally contains cosmetic components that improve consumer properties, namely: aromatic substances, and/or pigments, and/or preservatives.

    12. The mask according to claim 1, wherein as an electrolyte substance containing multiply charged ions, it contains divalent metal salts, for example, calcium chloride, or zinc chloride, or zinc sulfate, or magnesium sulfate; or polybasic organic and inorganic acids and/or their salts, for example, boric acid, or citric acid, or sodium citrate.

    13. The mask according to claim 1, wherein the additional reagent is an aqueous solution of an electrolyte substance, which contains distilled or double distilled or flower water as water.

    14. The mask according to claim 13, wherein as the flower water, the aqueous solution of the electrolyte substance contains lavender flower water, or melissa flower water, or pink flower water.

    15. A method of applying a cosmetic mask to a skin, comprising: applying a creamy cosmetic product with a fat, emulsion, or gel base onto the skin and then applying an additional reagent on top of it, characterized in that the creamy cosmetic product is first applied to the skin, containing an additional water-soluble biocompatible polymer with a mass in the range of 50,000-1,000,000 Da, capable of undergoing a cross-polymerization reaction, and selected from the group including: polyvinyl alcohol, polyvinylpyrrolidone, water-soluble polysaccharide modifications, water-soluble polysaccharide copolymers and mixtures thereof; incubating for 5-7 minutes, and then applying the additional reagent on top of the creamy cosmetic product, wherein the additional reagent is a 0.5-15.0% aqueous solution of an electrolyte substance containing multiply charged ions, while weight ratio of the water-soluble biocompatible polymer and the electrolyte substance in the aqueous solution is from 10:1 to 1:1, respectively.

    16. The method according to claim 15, wherein the aqueous solution of the electrolyte substance is applied in the form of a spray or aerosol sprayed onto a surface of the applied creamy cosmetic product for no more than 2-3 seconds.

    Description

    DETAILED DESCRIPTION OF THE INVENTION

    [0059] In the process of testing the following water-soluble biocompatible polymers were studied, selected from the claimed:

    [0060] Polyvinylpyrrolidone (from now on—PVP) is a biopolymer from the poly group (N-vinyl lactam), which is part of the blood plasma. Mass up to 360,000 Da. In cosmetics, a mixture of polymers of various molecular weights that have a lifting effect on the skin is used (http://cosmobase.ru/handbook/show/PVP).

    [0061] Polyvinyl alcohol is a carbochain polymer. The chemical formula of polyvinyl alcohol is (C2H4O)x, where x is responsible for the degree of polymerization. Mass from ˜90,000 to ˜200,000 Da. Due to its properties, polyvinyl alcohol is used as a modifier and thickener in the composition of polyvinyl acetate adhesives. This substance is used as a stabilizer of emulsion polymerization, as well as a protective colloid in the manufacturing process of polyvinyl acetate dispersions.

    [0062] Xanthan gum (Xanthan gum) is a branched polysaccharide, a microbial extracellular polysaccharide that is a product of the fermentation of the bacterium Xanthomonas campestris. Mass ˜1 000 000 Da. It is widely used as a gelling agent, thickener and emulsion stabilizer. Xanthan gum gels are resistant to alcohols, surfactants, acids and alkalis. Also, xanthan gum solutions have the property of thixotropy, which manifests itself in a wide pH range (2-12).

    [0063] Chitosan is a naturally occurring linear polysaccharide consisting of acylated and non-acylated D-glucosamine units. Mass from 50,000 to 1,000,000 Da. Due to the presence of a large number of amino groups, it is able to acquire a partially positive charge in solutions, to form a dense network of hydrogen bonds, due to which chitosan has exceptional sorbing properties of both organic substances and metal ions. It is used in cosmetics (as part of gels, shampoos, creams, etc.), in medicine (accelerating wound healing systems), in water treatment systems, in the textile and food industries.

    [0064] Starch is a natural polymer composed of a-glucose units. Mass 60,000 to >600,000 Da. It is soluble in hot water, forming three-dimensional gel structures due to the partial exit of small amylase molecules from the crystalline starch domains. It is used in the manufacture of paper, textile, pharmaceutical and food industries as a thickener, sizing, flocculant, filler, adhesive and viscosity modifier. Due to its wide availability and residually high reactivity, starch is used as a raw material for the synthesis of modified starches for specific technical needs.

    [0065] However, it should be noted that the scope of the water soluble biocompatible polymers claimed in the present invention is not limited thereto. They are given only as separate examples to illustrate the invention.

    [0066] The creamy cosmetic product that is part of the proposed mask contains a water-soluble biocompatible polymer capable of forming elastic water-fat-insoluble polymer gels by ion cross-polymerization. And along with this, the specified cosmetic product may include any traditional cosmetic ingredients, for example, oils: base and/or essential; and/or cosmetic emulsifiers; and/or emollients; and/or active ingredients, and water. It may also include, for example, surfactants (hereinafter referred to as surfactants), for example, polyoxyethylene monolaurate, water and fat soluble extracts, pigments, preservatives, flavorings, etc. That is, in fact, you can use any ready-made cosmetic products of any type in the proposed cosmetic mask, depending on the desired cosmetic effect, add the mentioned polymer to them in the claimed ratio, add (in isolation before the procedure for applying to the skin) an aqueous solution of an electrolyte substance, fragments of molecules which act as nodes of ionic cross-polymerization of these polymers, and get the claimed cosmetic mask. Testing was performed with various types of creamy cosmetic products.

    [0067] It should be clarified that traditionally a creamy cosmetic product is a fat-based one, in the form of an emulsion, in the form of a gel (http://allrefs.net/c12/3szr8/p6/; http://www.cosmetika-gloris.ru/vse-o-kosmetike/sostav-kosmetiki).

    [0068] As the fatty substances used in such product, there can be mentioned, for example, base oils: Extra Virgin olive oil and/or grape seed oil and/or Shea butter and/or Babassu oil and/or sesame oil; essential oils: bergamot essential oil and/or vanilla essential oil and/or tea tree essential oil and/or ylang-ylang essential oil and/or sandalwood essential oil and/or patchouli essential oil and/or lavender essential oil.

    [0069] It is possible to use, for example, mineral oils (petroleum jelly, mineral oil), vegetable oils and their hydrogenated derivatives, animal oils, synthetic oils, silicone oils (dimethicone, cyclomethicone) and fluorinated oils. Other fatty substances include fatty alcohols, fatty acids and waxes.

    [0070] The composition of the specified cosmetic products may also include, for example, aqueous, alcoholic or aqueous-alcoholic solutions, hydrophilic or lipophilic gels, and may be in the form of microemulsions, oil-in-water or water-in-oil emulsions or water-in-oil-in-water or oil-in-water-in-oil, having the appearance of a cream or gel.

    [0071] As it is well known, the creamy cosmetic component of the claimed mask may contain, for example, hydrophilic or lipophilic gelling agents, and/or surface-active agents, and/or hydrophilic or lipophilic active substances, and/or preservatives, and/or antioxidants and/or solvents and/or aromatic substances and/or fillers, filters, and/or colorants.

    [0072] The amounts of various constituents in such products do not exceed the concentrations corresponding to the classically used amounts in this field, for example, determined in accordance with GOST 31460-2012.

    [0073] In laboratory conditions, a series of experiments were conducted to produce the claimed mask applied to the skin by the proposed method. The examples shown in Table 1 are given as an illustration to better understand the invention, but the scope of the rights of the present invention is not limited to them. To prove that the composition of the proposed cosmetic mask as a creamy cosmetic product (component No. 1) products of various cosmetic types may be used, providing consumer properties of creams (nourishing creams, creams for smoothing the skin, moisturizing, emulsion creams, etc.) d.), so such various ingredients were used in the tests. The amount of ingredients is given in weight percent. Component No. 2 is an aqueous solution of an electrolyte substance containing multiply charged ions.

    [0074] An example of the preparation of the claimed mask (for example 1 from Table 1).

    [0075] Component No. 1: 18.8 g of cocoa butter, 6.3 g of ceresin, 5 g of cetyl alcohol and 2.5 g of calendula oil extract were mixed in a thermostatically controlled container, the container was heated to a temperature of +65° C. and mixed using immersion mixers for 5 minutes at a speed of 250 rpm until complete dissolution of the components of the mixture and its homogenization. Next, 59.2 g of hot (+70° C.) water was poured into the mixture heated to +65° C., after which the heating was turned off and the resulting mixture was stirred for 15 minutes at a rotation speed of 500 rpm. Next, 5.3 g of chitosan, 1 g of polysorbate-80, 0.76 g of starch, 0.5 g of methylisothiazolinone, 0.2 g of geraniol, 0.2 g of rosehip essential oil and 0.2 g of limonene were added to the mixture, cooled to room temperature, after which the mixture was mixed for 25 minutes at a speed of a submersible mixer of 500 rpm. As a result, component No. 1 was obtained (Example 1 of Table 1) with the following ratio of ingredients, wt. %: Cocoa butter—18.8%; Rosehip essential oil—0.2%; Cetyl alcohol—5%; Ceresin—6.3%; Calendula extract—2.5%; A mixture of chitosan and starch (7:1)—6.1%; other cosmetic substances (polysorbate-80, methylisothiazolinone, geraniol, limonene)—1.9%; water 59.2%.

    [0076] Component No. 2: 4 grams of magnesium sulfate and 2 g of citric acid were added to the polyethylene container, after which 94 g of warm (˜50° C.) melissa flower water was added. The mixture was stirred with an immersion mixer for 10 minutes at a stirrer speed of 250 rpm. As a result, component No. 2 was obtained with the following content of ingredients, wt. %: Melissa flower water—94, Citric acid—2, Magnesium sulfate—4.

    [0077] Masks with other ingredients were prepared in a similar way.

    [0078] All of these cosmetic masks were applied to the skin of the face by the proposed method, i.e. first, component No. 1 was applied to the skin, exposure was performed, and then component No. 2 was applied on top of this component, and exposure was again performed.

    [0079] During the tests, 15 different masks were tested. At the same time, creamy cosmetics (component No. 1) were used based on base oils and/or essential oils and/or cosmetic emulsifiers and/or emollients and/or active ingredients and water. Component No. 1 also contained water-soluble biocompatible polymers capable of undergoing crosslinking in an amount of 0.01-10.0 wt. %. Various bases were also tested at the same time, namely, Extra Virgin olive oil, and/or grape seed oil, and/or sesame oil.

    [0080] As the essential oils, the creamy base consisted of bergamot essential oil and/or vanilla essential oil and/or tea tree essential oil and/or ylang-ylang essential oil and/or sandalwood essential oil and/or patchouli essential oil, and/or lavender essential oil.

    [0081] As cosmetic emulsifiers, the cosmetic base contained cetyl alcohol and/or cetearyl alcohol and/or lecithin and/or beeswax and/or hydroxyethyl cellulose and/or polyethylene glycol and/or polyvinyl alcohol.

    [0082] As emollients, the cosmetic product in the base contained capric/capric triglycerides, and/or mineral oils.

    [0083] And as the active components for the preparation of the said product, hyaluronic acid, or allantoin, or inulin, or plant extracts were used as the base.

    [0084] As the water there was used distilled or floral water.

    [0085] Also, in a number of cosmetics, other cosmetic ingredients were additionally introduced: aromatic substances, pigments, preservatives and auxiliary cosmetic substances.

    [0086] As an aqueous solution of an electrolyte substance containing multiply charged ions (component No. 2), a 0.5-15% solution (solvent: distilled or double distilled or flower water) was used, in which divalent salts were used as an electrolyte substance metals, for example, calcium chloride, or zinc chloride, or zinc sulfate, or magnesium sulfate; or polybasic organic and inorganic acids and/or their salts, for example, boric acid, or citric acid, or sodium citrate.

    [0087] Moreover, in thirteen experiments, the ratio of water-soluble biocompatible polymers and electrolyte was taken in various ratios of the claimed range from 10:1 to 1:1, respectively; in two experiments (Nos. 8 and 12)-1:10 and 13:1, respectively (to prove the correctness of the declared quantitative limits of the ratios specified in the claims).

    [0088] The recipes of the specific investigated examples of cosmetic masks: component No. 1 and component No. 2 are shown in Table 1.

    [0089] It should be noted that in examples 1-5, the time between application of component No. 1 and component No. 2 was 5 minutes; in examples 6-8—7 minutes; in the remaining examples, 6 minutes.

    [0090] The time of face exposure to the claimed mask (from the moment of applying the creamy cosmetic product) for examples 1, 4-6 was 10 minutes; for examples 7-9—12 minutes; for other examples—15 minutes.

    [0091] In examples 1-9, 14, component No. 2 was applied in the form of a spray, in the remaining examples with a soft brush.

    [0092] During the experiments, the degree of cosmetic effect of the applied mask was determined in accordance with the dermatological protocol of the European Association of Dermatologists (Jain R., Huang P. A new tool to improve delivery of patient-engaged care and satisfaction in facial treatments: the Aesthetic Global Ranking Scale//Journal of Cosmetic Dermatology, No. 1, p. 1-12.).

    [0093] The study involved 150 volunteer patients, women aged 37 to 45 years. An expert assessment was performed by 10 expert cosmetologists. Changes were evaluated on a rank 4-point scale, where one point is equal to 30% of the degree of change of the sign. The following parameters were selected as criteria: increase in elasticity, decrease in dehydration, decrease in volume loss. Assessment was performed before the start of the course and after 4 procedures for applying the claimed mask. Masks were applied no more than once every 48 hours. Masks were applied by the proposed method in an even layer on the face, avoiding the periorbital zone.

    [0094] According to the results of the study, it was found that in examples 1, 2, 4, 7, 9-13, 15, component No. 1 had a creamy structure; in other examples, it was gel-like.

    [0095] In examples 1, 3, 4, 6, 7, 9, 10, 13-15, when applying component No. 1, the mask was applied as an even layer, after applying component No. 2, the upper part of the mask was compacted. After the exposure time on the face, the mask was removed easily without injuring or drying the skin. These examples correspond to the claimed formulation of the mask and the proposed method of its application.

    [0096] When using masks according to the specified examples 1, 3, 4, 6, 7, 9, 10, 13-15, intensive skin hydration was observed in 100%, elasticity increased in 65-70% of cases. In examples 2, 5, when applying component No. 1, the masks were applied in an even layer (in these examples, component No. 1 contains a water-soluble biocompatible polymer above the claimed amount), but when component No. 2 was added during compaction of the upper surface of component No. 1, lumps formed, layer became uneven. These masks could only be removed with water, by rinsing. At the same time, dry skin was observed at the sites of lump formation; skin irritation associated with mechanical removal of masks was observed in 10-12% of cases.

    [0097] In examples 8, 11, when applying component No. 1, the masks also were applied m an even layer (in these examples, component No. 1 contains a water-soluble biocompatible polymer lower than claimed), when component No. 2 was added, the upper surface of component No. 1 did not seal. These masks could only be removed with water, by rinsing. When using the masks from examples 8, 11, skin hydration was observed only in 30%, an increase in elasticity was observed in 10%.

    [0098] In example 12, when applying component No. 1, the mask was applied in an even layer (component No. 1 contains a water-soluble biocompatible polymer in the claimed formulation), when component No. 2 was added (component No. 2 contains a solution of an electrolyte substance below the claimed), compaction of the upper surface of component No. 1 did not occur. This mask could only be removed with water, by rinsing. When applying the mask of example 12, skin hydration was observed in 40%, an increase in elasticity was observed in 10%.

    [0099] On the basis of the formulation specified in examples 1, 3, 6, the primary combination of component No. 1 and component No. 2 was carried out directly during mask preparation, in violation of the previously specified application algorithm. When preparing it, after 30 seconds a gel-like structure formed with compacted gel lumps, which was almost impossible to apply to the skin. After 24 hours, the structure divided into layers with an effusion of the oil phase. The use of such a mask was not possible, due to the loss of consumer qualities and the difficulty of application.

    [0100] Tests were also carried out with the claimed masks with other polymers, such as: hydroxyethyl starch, carrageenan, sodium alginate, agar-agar. The results were similar to the positive examples shown in Table 1.

    [0101] Thus, the proposed cosmetic mask applied to the skin using the claimed method has the following advantages over the known products:

    [0102] provision of a modeling lifting effect without the use of additional cosmetics;

    [0103] Prevention of moisture loss and ensuring effective hydration of the skin in 100% of experiments;

    [0104] increased efficiency of penetration into the epidermis of the active components located in the inner layer of the mask;

    [0105] protection of the active components of the mask from oxidation during interaction with atmospheric oxygen.

    [0106] All of the above allows increasing the cosmetic effect of the proposed mask, applied to the skin using the claimed method.

    TABLE-US-00001 TABLE 1 Creamy cosmetic product (component No. 1), mass % No. Oil Cosmetic Active Water-soluble Other cosmetic Component Example basic essential emulsifier emollient component biocompatible polymer substances water No. 2 Texture 1 2 3 4 5 6 7 8 9 10 1 Cocoa Rosehip Cetyl Ceresin - Calendula A mixture polysorbate-80, 59.2% melissa flower cream - butter - Essential Oil - alcohol - 6.3% extract - of chitosan methylisothiazolinone, water - 94%, type 18.8% 0.2% 5% 2.5% and starch geraniol, limonene - 1.9% Citric acid - 2% (7:1) - 6.1% Magnesium sulfate - 4% 2 Shea patchouli Emulsion Castor Inulin - Polyvinyl PEG 600, 58.5% Lavender flower cream - butter - essential oil - wax - oil - 3% alcohol - sodium benzoate, water - 92%; type 11% 0.1% 3% 3.7% 18.5% potassium sorbate - 2.2% sodium borate - 5% + boric acid - 3% 3 — Sandalwood — Isopropyl Panthenol - Polyvinylpyrrolidone/ Alpha lipoic acid, 79.5% Distilled water - 97% gel - essential oil - palmitate - 4% starch (1:3) - terpenes, sodium citrate - 2%, type 0.1% - 8.1% 4.9% eucalyptolum - 3.4% boric acid - 1% 4 Olive oil — Cetearyl — Allantoin - Xanthan gum - Polysorbate - 20, 63.8% Distilled water - 99.4% cream - Extra virgin - alcohol - 3.2% 0.2% methylisothiazolinone, sodium borate - 0.1% type 25.3% 5% geraniol, limonene - 2.5% citric acid - 0.1% 5 — Lavender — Isopropyl Urea - Starch, Polysorbate - 80, 58.6% Double distilled gel - essential oil - myristate - 6% polyvinylpyrrolidone phenoxyethanol, water - 94%, type 0.2% 11.4% (10:1) - methylisothiazolinone, citric acid - 3%, 21.5% limonene - 2.3% boric acid - 1% 6 — — — — Urea + Starch/Xanthan PEG - 600, microcrystalline 77.5% Flower pink gel - hyaluronic Gum (92:1) - cellulose, methylparaben, water - 98.8 type acid (20:1) - 4.7% geraniol, limonene - 6.2% Sodium citrate - 1.0%, 11.6% citric acid - 0.2% 7 Sesame oil - — — Capric/capric sage Polyvinyl Azelaic acid, .sup. 67% Melissa Flower cream - 16.8% triglycerides - extract - alcohol/ phenoxyethanol - 2% Water - 99.85% type 10% 2.7% polyvinylpyrrolidone sodium borate - 0.15% (1:2) - 1.5% 8 — Bergamot Polysorbate - Cyclodimethicone - Coenzyme Q10 - Chitosan/polyvinyl Titanium Dioxide, 73.893%  water - 95%, gel - essential oil - 20 - 7% 3.5% alcohol (1:5) - methylisothiazolinone - 4.9% sodium borate - 0.5%, type 0.2% 10.5% 0.007% zinc sulfate - 0.5% 9 Apricot oil - Essential oil Wax tree — Inulin - Polyvinylpyrrolidone - Glycerin monostearate, 65.79%  Floral rose cream - 21% ylang - ylang - Nimes - 1.1% 0.01% methylisothiazolinone - 3% water - 99.99% type, a large 0.1% 9% boric acid - 0.01% excess of spray 10 Macadamia — Cetearyl — Collagen - Chitosan - Phenoxyethanol, 54.3% Lavender flower cream - oil - alcohol - 3.3% 2.7% methylparaben - 1.5% water - 98.2 type 30% 8.2% Magnesium Sulfate - 1.8% 11 Palm kernel — Emulsion Lanolin - — Starch/ Zinc oxide, 66.395%  Distilled Water - 90 cream - oil - wax - 5.2% polyvinylpyrrolidone methylisothiazolinone, Sodium citrate - 9%, type 22.6% 3.2% (6:1) - 0.005% limonene - 2.6% boric acid - 1% 12 Babassu Cinnamon Cetearyl — Chamoile Xanthan gum/ Carboxymethyl cellulose, 63.8% Flower pink cream - oil - Essential oil - alcohol - extract - polyvinyl potassium sorbate, water - 99.7% type, 15% 0.3% 4.1% 4.8% alcohol (6:1) - sodium benzoate - 4.1% citric acid - 0.6%, little sprey 7.9% 13 Palm — Nimes Capric/Capric Squalane - Polyvinyl Phenoxyethanol, .sup. 63% Double-distilled cream - oil - Wax - triglycerides - 2.5% alcohol/starch methylisothiazolinone, water - 99.62%, type 20.1% 4.9% 3.8% (1:2) - 3.8% geraniol, limonene - 1.9% sodium borate - 0.38% 14 Verbena Polysorbate - Ceresin - Allantoin - Triethylcitrate, Triethyl citrate, 82.5% Flower pink gel - essential oil - 20 - 4.9% 3.3% sodium benzoate, sodium benzoate, water - 98.3%, type 0.1% 3.3% potassium sorbate, potassium sorbate, magnesium sulfate - 0.5%, lavender - 4.2% lavender - 4.2% boric acid - 1.2% 15 Jojoba Lemongrass Emulsion Isopropyl Q10 + inlin Starch/Chitosan Polysorbate - 20, .sup. 58% Melissa flower cream - oil - essential oil - wax - palmitate - (1:4) - (19:1) - 4% Eucalyptol, lavender, water - 97.5% type 23.8% 0.2% 4% 2.4% 4.1% geraniol - 3.5% citric acid - 2.5%