Concrete with oil shale waste residue as aggregates and preparation method thereof

Abstract

A concrete with oil shale waste residue as aggregates and a preparation method thereof are provided by the present disclosure, belonging to the technical field of concrete. Oil shale waste residue is used to partially or completely replace the fine aggregates and coarse aggregates in the concrete, where the oil shale waste residue is deoiled oil shale waste residue. The oil shale waste residue is subjected to oil removal treatment and applied to the preparation of concrete.

Claims

1. A concrete with oil shale waste residue as aggregates, comprising replacing fine aggregates and coarse aggregates in a concrete partially or completely with oil shale waste residue as aggregates; wherein the oil shale waste residue is deoiled oil shale waste residue; a preparation method of the deoiled oil shale waste residue comprises: adding a degreasing agent into the oil shale waste residue, wherein a material-liquid ratio of the oil shale waste residue to the degreasing agent is 1 kg:5 L; conducting hot washing and standing to obtain the deoiled oil shale waste residue; wherein the degreasing agent is sophorolipid or Polysorbate 80; a concentration of the sophorolipid or Polysorbate 80 is 20-60 mg/L; and a temperature during the hot washing is 40 C.

2. The concrete with oil shale waste residue as aggregates according to claim 1, wherein concentrations of the sophorolipid or Polysorbate 80 are all of 20 mg/L, 40 mg/L or 60 mg/L.

3. The concrete with oil shale waste residue as aggregates according to claim 2, wherein a concentration of the sophorolipid is 60 mg/L.

4. The concrete with oil shale waste residue as aggregates according to claim 1, wherein when the deoiled oil shale waste residue is used as the fine aggregates, the deoiled oil shale waste residue is ground into particles, and a particle size of the particles is 80 meshes; and when the deoiled oil shale waste residue is used as the coarse aggregates, the deoiled oil shale waste residue is crushed into a mixture of blocks of different particle sizes, and the different particle sizes are 5-10 mm and 10-20 mm.

5. A method for preparing the concrete with oil shale waste residue as aggregates according to claim 1, comprising following steps: adding deoiled oil shale waste residue coarse aggregates and deoiled oil shale waste residue fine aggregates, standing, adding cement, stirring, adding half of water and half of water reducer, stirring, and finally adding remaining water and a remaining water reducer and stirring to obtain the concrete with the oil shale waste residue as the aggregates.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The accompanying drawings, which constitute a part of the present disclosure, are used to provide a further understanding of the present disclosure, and the illustrative embodiments of the present disclosure and their descriptions are used to explain the present disclosure, and do not constitute an undue limitation of the present disclosure. In the attached drawings:

(2) FIG. 1 shows the 7-day compressive strength of concrete prepared in Embodiments 7-12 and Comparative embodiments 3-4;

(3) FIG. 2 shows the 7-day compressive strength of concrete prepared by replacing aggregate with deoiled oil shale waste residue in different proportions in Embodiments 13-17.

DETAILED DESCRIPTION OF THE EMBODIMENTS

(4) A number of exemplary embodiments of the present disclosure will now be described in detail, and this detailed description should not be considered as a limitation of the present disclosure, but should be understood as a more detailed description of certain aspects, characteristics and embodiments of the present disclosure.

(5) It should be understood that the terminology described in the present disclosure is only for describing specific embodiments and is not used to limit the present disclosure. In addition, for the numerical range in the present disclosure, it should be understood that each intermediate value between the upper limit and the lower limit of the range is also specifically disclosed. Intermediate values within any stated value or stated range, as well as each smaller range between any other stated value or intermediate values within the stated range are also included in the present disclosure. The upper and lower limits of these smaller ranges can be independently included or excluded from the range.

(6) Unless otherwise specified, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this present disclosure relates. Although the present disclosure only describes the preferred methods and materials, any methods and materials similar or equivalent to those described herein can also be used in the practice or testing of the present disclosure. All documents mentioned in this specification are incorporated by reference to disclose and describe methods and/or materials related to the documents. In case of conflict with any incorporated document, the contents of this specification shall prevail.

(7) It is obvious to those skilled in the art that many improvements and changes may be made to the specific embodiments of the present disclosure without departing from the scope or spirit of the present disclosure. Other embodiments will be apparent to the skilled person from the description of the present disclosure. The description and embodiments of that present disclosure are exemplary only.

(8) The terms including, comprising, having and containing used in this specification are all open terms, which means including but not limited to.

Embodiment 1

(9) Polysorbate 80 (Tween 80), a degreasing agent with a concentration of 20 mg/L, is added to the oil shale waste residue, and the material-liquid ratio of oil shale waste residue to the degreasing agent is 1 kg: 5 L. After hot washing at 40 C. and standing for 30 min, the deoiled oil shale waste residue is obtained, which is designated as A3.

Embodiment 2

(10) Same as Embodiment 1, differing only in that the concentration of Polysorbate 80 (Tween 80) is 40 mg/L, and the deoiled oil shale waste residue obtained is noted as A4.

Embodiment 3

(11) Same as Embodiment 1, with the difference being only that the concentration of Polysorbate 80 (Tween 80) is 60 mg/L, and the deoiled oil shale waste residue obtained is noted as A5.

Embodiment 4

(12) Same as in Embodiment 1, the only difference is that the degreasing agent is sophorolipid with a concentration of 20 mg/L, and the deoiled oil shale waste residue obtained is designated as A6.

Embodiment 5

(13) The same as in Embodiment 1, the only difference is that the degreasing agent is sophorolipid with a concentration of 40 mg/L, and the deoiled oil shale waste residue obtained is designated as A7.

Embodiment 6

(14) The same as in Embodiment 1, the only difference is that the degreasing agent is sophorolipid with a concentration of 60 mg/L, and the deoiled oil shale waste residue obtained is designated as A8.

Comparative Embodiment 1

(15) With no treatment of oil shale waste residue, designated as A1.

Comparative Embodiment 2

(16) It is the same as Embodiment 1, but the only difference is that the degreasing agent is replaced by the same amount of water, which is denoted as A2.

(17) See Table 1 for the experimental schemes of oil shale waste residue degreasing in Embodiments 1-6 and Comparative embodiments 1-2.

(18) TABLE-US-00001 TABLE 1 Oil removal experimental scheme of oil shale waste residue Hot washing Standing Degreasing Concentration temperature duration S/N material (mg/L) ( C.) (min) A1 / / / / A2 Water / 40 30 A3/A4/A5 Polysorbate 80 20/40/60 40 30 (Tween 80) A6/A7/A8 Sophorolipid 20/40/60 40 30

Embodiments 7-12

(19) The deoiled oil shale waste residue from Embodiment 1-6 is ground into particles with a particle size of 80 mesh for later use.

(20) Based on the ratio of C30 reference concrete, the mixer is started, and when it is in normal operation, the particles of deoiled oil shale waste residue are added and waited for 2-3 min to make it fully mixed, and then cement (P.O42.5 ordinary silicate cement) is added and stirred for 2-3 min, and then half of water and half of polycarboxylic acid high-efficiency water reducer PCE-101 are added and stirred for 1-2 min, and then finally, the rest of water and the polycarboxylic acid high-efficiency water reducer are poured and stirred for 2-3 min to obtain the concrete, and the specific ratio of concrete is shown in Table 2.

Comparative Embodiment 3

(21) Concrete is prepared according to the method of Embodiments 7-12, only the difference is that the oil shale waste residue of Comparative embodiment 1 is added, and the specific proportion is shown in Table 2.

Comparative Embodiment 4

(22) Concrete is prepared according to the method of Embodiments 7-12, only the difference is that the oil shale waste residue of Comparative embodiment 2 is added, and the specific proportion is shown in Table 2.

(23) TABLE-US-00002 TABLE 2 Concrete proportion (kg/m.sup.3) Oil shale Fine waste Coarse Coarse Group aggre- residue aggregate aggregate Water No. Cement gate particles 5-10 mm 10-20 mm reducer Water Compar- 390 394.5 263 467.5 702.5 1.95 187.2 ative embod- iment 3 (A1) Compar- 390 394.5 263 467.5 702.5 1.95 187.2 ative embod- iment 4 (A2) Compar- 390 394.5 0 467.5 702.5 1.95 187.2 ative embod- iment 5 Embod- 390 394.5 263 467.5 702.5 1.95 187.2 iment 7 (A3) Embod- 390 394.5 263 467.5 702.5 1.95 187.2 iment 8 (A4) Embod- 390 394.5 263 467.5 702.5 1.95 187.2 iment 9 (A5) Embod- 390 394.5 263 467.5 702.5 1.95 187.2 iment 10 (A6) Embod- 390 394.5 263 467.5 702.5 1.95 187.2 iment 11 (A7) Embod- 390 394.5 263 467.5 702.5 1.95 187.2 iment 12 (A8)

(24) Note: the standard cubic cubes of 150150150 mm are selected for the compressive test, with 3 pieces in each group, and the average value is taken; the fine aggregate is sand with a particle size of 80 mesh, the coarse aggregate is pebbles, and the particle size of oil shale waste residue particles is 80 mesh.

(25) The concretes prepared in Embodiments 7-12 and Comparative embodiments 3-4 are added to a standard cube mold, and the standard cube mold is placed on a vibration table, which requires a total of two vibrations, with half of the material being added for the first vibration, and the mold being filled for the second vibration and then vibrated until the surface is pulped and no bubbles are generated, and then the surface of the test block is smoothed and marked and demolded for the performance test.

(26) The uniaxial compressive strength test of modified oil shale waste residue concrete is conducted as a preliminary screening for analyzing the properties of modified concrete. The test method refers to the Standard for test method of mechanical properties on Ordinary concrete (GB/T 50081-2002). 8 groups (concretes prepared from Embodiments 7-12 and Comparative embodiments 3-4) cubic test specimens of 150 mm150 mm150 mm, and 3 specimens are taken from each group for the compressive strength test, and the 200-ton microcomputer-controlled hydraulic press is used for the cubic compression test, with the pressure applied in the vertical direction along the casting, and the loading speed of specimens being 0.5 Mp/s; the values are read at the time of destruction of specimens and are presented as FIG. 1.

(27) The following conclusions may be drawn from the uniaxial compressive strength test.

(28) (1) Comparative analysis of compressive strength between A1 and A2 shows that washing oil shale waste residue particles with water will not affect the strength of concrete block.

(29) (2) Comparative analysis of compressive strength of A3, A4 and A5 shows that the strength of the test block increases with the increase of Polysorbate 80 (Tween 80) concentration.

(30) (3) As an oil-removing material, Sophorolipid will affect the hydration reaction of concrete and increase the strength of concrete, but the increase is not obvious.

(31) Through the strength analysis of reference blocks, it is concluded that 60 mg/L Polysorbate 80 (Tween 80) is the best material to improve the mechanical properties of concrete.

Embodiments 13-17

(32) Concretes with different substitution rates are prepared from the deoiled oil shale waste residue obtained by using Polysorbate 80 (Tween 80) of 60 mg/L as the deoiling material in Embodiment 3. See Table 3 for specific proportions.

(33) Among them, the amount of coarse and fine aggregates refer to the mixing ratio of the concrete itself, and the calculation method of replacing coarse and fine aggregates with deoiled oil shale waste residue at the same time is as follows: given a substitution rate of deoiled oil shale waste residue to replace coarse and fine aggregates, for example, 40%, then all of the coarse and fine aggregates are 60% of the base amount, that is, at this time, the amount of coarse and fine aggregates used=the amount of the original coarse and fine aggregates*(1substitution rate %), and the amount of deoiled oil shale waste residue used=the total amount of coarse and fine aggregates*substitution rate.

(34) The preparation method of the above concrete is as follows:

(35) based on the ratio of C30 reference concrete, the mixer is started, and when it is running normally, coarse aggregate and fine aggregate are added, followed by waiting for 2-3 min to mix fully, then cement (P.O42.5 ordinary silicate cement) is added and stirred for 2-3 min, then silica fume is added, as well as half of water and half of polycarboxylic acid high efficient water reducer PCE-101 are added and stirred for 1-2 min, and finally the rest of water and water reducer are added and stirred for 2-3 min to obtain the concrete with oil shale waste residue as aggregates; since the substitution of coarse and fine aggregates by the deoiled oil shale waste residue will substantially reduce the properties of the concrete, in order to avoid a substantial reduction in the properties of the concrete, a silica fume is added to the preparation process of the concrete in the present disclosure, and the silica fume allows for a reduction in the porosity of the concrete, an improvement in the densification of the concrete, and an increase in the silicate content of the concrete, thereby contributing to an improvement in the strength and hardness of the concrete.

(36) TABLE-US-00003 TABLE 3 Proportion of substituted aggregate content of oil shale waste residue (kg/m.sup.3) Oil shale waste Coarse Coarse Fine residue aggregate aggregate Water Silica Substitution Group No. Cement aggregate particles 5-10 mm 10-20 mm reducer Water fume rate Embodiment 390 236.7 625.8 280.5 421.5 1.95 187.2 48.2 40% 13 (B1) Embodiment 390 177.5 860.5 210.4 316.1 1.95 187.2 48.2 55% 14 (B2) Embodiment 390 118.4 1095.2 140.3 210.8 1.95 187.2 48.2 70% 15 (B3) Embodiment 390 59.2 1329.8 70.1 105.4 1.95 187.2 48.2 85% 16 (B4) Embodiment 390 0 1564.5 0 0 1.95 187.2 48.2 100% 17 (B5)

(37) Note: standard cubes of 150150150 mm are selected for the compressive test, with 6 cubes in each group, and the average value is taken; the fine aggregate is sand with a particle size of 80 mesh, and the coarse aggregate is pebbles. For replacing fine aggregates, the deoiled oil shale waste residue is ground into particles of 80 mesh, and for replacing coarse aggregates, the deoiled oil shale waste residue is crushed into blocks of 5-10 mm and 10-20 mm.

(38) See FIG. 2 for the 7-day compressive strengths of concretes prepared with deoiled oil shale waste residue in different proportions in Embodiments 13-17. Through the analysis of FIG. 2, it is known that although the substitution ratio increases from 40% to 100% in the process, the compressive strength of concrete specimens is decreasing, but it is still in the reasonable range of the specification, and as compared with the concrete prepared directly with oil shale waste residue and no oil removal treatment, the strength of the concrete is improved, suggesting that it is feasible to use deoiled oil shale waste residue to replace all the aggregates; in addition to meeting the requirements of the strength, the use of oil shale is more effective in achieving the purpose of solid waste utilization.

Comparative Embodiment 5

(39) Same as Embodiment 17, differing only in that the material-liquid ratio of oil shale waste residue to the degreasing agent Polysorbate 80 (Tween 80) at 60 mg/L is 1 kg: 3 L. This material-liquid ratio requires an excessive amount of degreasing agent, which raises the cost of making concrete and is unsuitable for the application, and therefore no subsequent testing is conducted.

Comparative Embodiment 6

(40) The same as Embodiment 17, the difference only lies in the material-liquid ratio of the oil shale waste residue and the degreasing agent Polysorbate 80 (Tween 80) of 60 mg/L is 1 kg: 10 L. This material-liquid ratio requires less degreasing agent, but the degreasing effect is not good, so no follow-up test is conducted, and in summary, the 1 kg: 5 L is selected.

Comparative Embodiment 7

(41) It is the same as Embodiment 17, but the only difference is that the hot washing temperature is 60 C. when preparing deoiled oil shale waste residue. This temperature is too high, and the oil remover will be partially inactivated, resulting in a not so good oil removal effect, so no subsequent testing is conducted.

Comparative Embodiment 8

(42) Same as Embodiment 17, differing only in that the hot washing temperature for the preparation of the deoiled oil shale waste residue is 20 C. This temperature is too low for the degreasing agent to be effective in degreasing the oil, and there is no stimulated activity, so no subsequent testing is conducted. In summary, a hot washing temperature of 40 C. is determined.

(43) The above describes only the preferred embodiments of the present disclosure, but the protection scope of the present disclosure is not limited to this, and any changes or substitutions that may be easily thought of by those familiar with the technical field within the technical scope disclosed by the present disclosure should be included in the protection scope of the present disclosure. Therefore, the scope of protection of the present disclosure should be based on the scope of protection of the claims.