Substrate processing apparatus
10026596 ยท 2018-07-17
Assignee
Inventors
Cpc classification
H01J37/32568
ELECTRICITY
International classification
H01L21/00
ELECTRICITY
H01L21/67
ELECTRICITY
Abstract
A substrate processing apparatus includes: a cylindrical shaped chamber configured to accommodate a substrate; a movable electrode capable of moving along a central axis of the cylindrical shaped chamber within the cylindrical shaped chamber; a facing electrode facing the movable electrode within the cylindrical shaped chamber; and an expansible/contractible partition wall connecting the movable electrode with an end wall on one side of the cylindrical shaped chamber. A high frequency power is applied to a first space between the movable electrode and the facing electrode, a processing gas is introduced thereto, and the movable electrode is not in contact with a sidewall of the cylindrical shaped chamber, a first dielectric member is provided at the cylindrical shaped chamber's sidewall facing the movable electrode, and an overlap area between the first dielectric member and a side surface of the movable electrode is changed according to movement of the movable electrode.
Claims
1. A substrate processing apparatus comprising: a cylindrical shaped chamber having a circular pipe-shaped sidewall and a circular plate-shaped cover that covers an upper end of the circular pipe-shaped sidewall and configured to accommodate a substrate; a movable electrode having a top surface facing the circular plate-shaped cover and a bottom surface facing a facing electrode and a side surface facing the circular pipe-shaped sidewall and capable of moving along a central axis of the cylindrical shaped chamber within the cylindrical shaped chamber; the facing electrode facing the movable electrode within the cylindrical shaped chamber; and an expansible/contractible partition wall connecting the movable electrode with the circular plate-shaped cover, wherein a high frequency power is applied to a first space between the movable electrode and the facing electrode, a processing gas is introduced thereto, and the movable electrode is not in contact with the circular pipe-shaped sidewall, and a first dielectric member is provided at only a part of the circular pipe-shaped sidewall facing the movable electrode, and an overlap area between the first dielectric member and the side surface of the movable electrode is changed according to movement of the movable electrode, further wherein a second dielectric member is provided at the movable electrode's side surface facing the first dielectric member and an overlap area between the first dielectric member and the second dielectric member is changed according to movement of the movable electrode, in a cross section of the first dielectric member along a central axis of the cylindrical shaped chamber, a width in a direction orthogonal to the central axis is gradually changed along the central axis, and in a cross section of the second dielectric member along the central axis of the cylindrical shaped chamber, a width in a direction orthogonal to the central axis is gradually changed along the central axis.
2. The substrate processing apparatus of claim 1, wherein each of the first dielectric member and the second dielectric member is made of quartz, ceramic or an insulating resin.
3. The substrate processing apparatus of claim 1, wherein a recess is formed in the circular pipe-shaped sidewall, and the first dielectric member is inserted into the recess.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The disclosure may best be understood by reference to the following description taken in conjunction with the following figures:
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DETAILED DESCRIPTION OF THE INVENTION
(14) Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings.
(15) Above all, there will be explained a substrate processing apparatus in accordance with a first embodiment of the present invention.
(16)
(17) As illustrated in
(18) The inside of the chamber 11 is depressurized by a TMP (Turbo Molecular Pump) and a DP (Dry Pump) (both not illustrated), and an internal pressure of the chamber 11 is controlled by an APC valve (not illustrated).
(19) The susceptor 12 is connected with a first high frequency power supply 15 via a first matching unit 16 and with a second high frequency power supply 17 via a second matching unit 18. The first high frequency power supply 15 is configured to apply a high frequency bias power having a relatively low frequency of, e.g., about 3.2 MHz to the susceptor 12. The second high frequency power supply 17 is configured to apply a plasma-generating high frequency power having a relatively high frequency of, e.g., about 100 MHz to the susceptor 12. The susceptor 12 is configured to apply the plasma-generating power to the inside of the chamber 11.
(20) Installed at the upper part of the susceptor 12 is an electrostatic chuck 20 including therein an electrostatic electrode plate 19. The electrostatic chuck 20 is made of a ceramic member having a circular plate shape, and the electrostatic electrode plate 19 is connected with a DC power supply 21. If a positive DC voltage is supplied to the electrostatic electrode plate 19, a negative potential is generated on the wafer W's surface (hereinafter, referred to as rear surface) facing the electrostatic chuck 20. As a result, a potential difference is generated between the electrostatic electrode plate 19 and the rear surface of the wafer W. Accordingly, the wafer W is attracted to and held on the electrostatic chuck 20 by Coulomb force or Johnson-Rahbek force caused by the potential difference.
(21) Further, a ring-shaped focus ring 22 is mounted on the susceptor 12 so as to surround the wafer W attracted to and held on the electrostatic chuck 20. The focus ring 22 is made of a conductive material such as single crystalline silicon which is the same material as that of the wafer W. Since the focus ring 22 is made of the conductive material, plasma can be distributed not only on the wafer W but also on the focus ring 22. Therefore, a plasma density on a peripheral portion of the wafer W can be maintained at the substantially same level as a plasma density on a central portion of the wafer W. Accordingly, it is possible to maintain uniformity of the dry etching process to be performed on the entire surface of the wafer W.
(22) A shower head (movable electrode) 23 is installed to face the susceptor 12 at the upper part inside the chamber 11. The shower head 23 includes a conductive upper electrode plate 25 formed into a circular plate shape and having a plurality of gas holes 24; a cooling plate 26 attachably/detachably holding the upper electrode plate 25; a shaft 27 holding the cooling plate 26; and a processing gas container 28 positioned at the upper end of the shaft 27. The shower head 23 is grounded via the cover 14 and the sidewall 13 and serves as a ground electrode for a plasma-generating power applied to the inside of the chamber 11.
(23) The shaft 27 includes a gas path 29 penetrating the inside of the shaft 27 in a vertical direction of the drawing, and the cooling plate 26 includes therein a buffer room 30. The gas path 29 connects the processing gas container 28 with the buffer room 30, and the buffer room 30 is communicated with the inside of the chamber 11 through each gas hole 24. In the shower head 23, the gas holes 24, the processing gas container 28, the gas path 29, and the buffer room 30 constitute a processing gas introducing unit. Further, this processing gas introducing unit introduces the processing gas supplied to the processing gas container 28 into the chamber 11, to be specific, to a processing space PS (a first space) between the shower head 23 and the susceptor 12.
(24) Since an outer diameter of the upper electrode plate 25 of the shower head 23 is set to be a bit smaller than an inner diameter of the chamber 11, the shower head 23 is not in contact with the sidewall 13. That is, the shower head 23 is installed within the chamber 11 in a movable state. The shaft 27 penetrates the cover 14 and an upper portion of the shaft 27 is connected with a lift mechanism (not illustrated) positioned above the substrate processing apparatus 10. The lift mechanism is configured to move the shaft 27 in a vertical direction of the drawing. Here, the shower head 23 vertically moves along a central axis of the chamber 11 like a piston. Accordingly, a gap, i.e., a thickness of the processing space PS, between the shower head 23 and the susceptor 12 can be adjusted. The maximum moving distance of the shower head 23 in the vertical direction of the drawing is about 70 mm, for example.
(25) Particles may be generated due to a friction between the shaft 27 and the cover 14. Therefore, a side surface of the shaft 27 is covered by, e.g., a bellows 31. The bellows 31 is an expansible/contractible pressure partition wall made of, e.g., stainless steel. One end of the bellows 31 is joined to the cover 14 and the other end thereof is joined to the shower head 23. Further, the bellows 31 seals the inside of the chamber 11 from the outside of the chamber 11.
(26) In the substrate processing apparatus 10, the processing gas supplied to the processing gas container 28 is introduced into the processing space PS through the processing gas introducing unit, and the introduced processing gas is excited into plasma by the plasma-generating power applied to the processing space PS. Positive ions in the plasma are attracted toward the wafer W mounted on the susceptor 12 by a negative bias potential caused by a bias power applied to the susceptor 12, and a dry etching process is performed on the wafer W.
(27) The operations of respective components such as the first high frequency power supply 15 or the second high frequency power supply 17 of the substrate processing apparatus 10, are controlled by a CPU of a controller (not illustrated) provided in the substrate processing apparatus 10 according to a program corresponding to a dry etching process.
(28) In the substrate processing apparatus 10, the shower head 23 is not in contact with the sidewall 13. Thus, a high frequency current caused by the plasma-generating power applied to the processing space PS flows through the shower head 23, the upper space US, the cover 14, and the sidewall 13 and reaches a ground. Here, since the bellows 31 has high impedance, a potential difference is generated between the shower head 23 and the cover 14. Therefore, an electric field may be generated in the upper space US (a second space) between the shower head 23 and the cover 14.
(29) In accordance with the present embodiment, a voltage drop in the upper space US is reduced. To be specific, there is installed a first capacitor layer 32 made of a low dielectric constant material on the shower head 23's surface facing the upper space US, and there is installed a second capacitor layer 33 made of a low dielectric constant material on the cover 14's surface facing the upper space US. Here, the space between the shower head 23 and the cover 14 can be represented by an electrical series circuit of three capacitors as depicted in
(30) Desirably, the first capacitor layer 32 and the second capacitor layer 33 may be made of a material having a dielectric constant of about 10 or less. Thus, the voltage drop to be shared by the first capacitor layer 32 or the second capacitor layer 33 can be appropriately adjusted. As a material of the first capacitor layer 32 or the like, it is possible to use an insulating resin such as polytetrafluoroethylene (PTFE), a copolymer of tetrafluoroethylene and perfluoroalkyl vinyl ether (PFA) or polychlorotrifluoroethylene (PCTFE); an engineering plastic-based resin; quartz (SiO.sub.2); alumina ceramic (Al.sub.2O.sub.3); aluminum nitride (AlN); and silicon nitride (SiN). In particular, polytetrafluoroethylene, the copolymer of tetrafluoroethylene and perfluoroalkyl vinyl ether, and polychlorotrifluoroethylene have a high resistance to radicals. Therefore, even if plasma is introduced into the upper space US from the processing space PS, it is possible to prevent the first capacitor layer 32 or the second capacitor layer 33 from being eroded by using these materials having a high resistance to radicals.
(31) In the substrate processing apparatus in accordance with the present embodiment, the first capacitor layer 32 and the second capacitor layer 33 are provided in the upper space US between the shower head 23 and the cover 14. Thus, a voltage drop related to a high frequency current caused by a high frequency power applied to the processing space PS and flowing through the shower head 23, the upper space US, the cover 14, and the sidewall 13 is shared by the first capacitor layer 32 and the second capacitor layer 33. Accordingly, a voltage drop in the upper space US can be reduced and a potential difference in the upper space US can be reduced. As a result, it is possible to suppress generation of an electric field in the upper space US and further suppress generation of plasma therein. Therefore, it is possible to prevent the cover 14 or the shower head 23 of the chamber 11 from being eroded and further prevent generation of deposits (particles) in the upper space US.
(32) Further, in the substrate processing apparatus 10, the first capacitor layer 32 is installed on the shower head 23 and the second capacitor layer 33 is installed on the cover 14, and, thus, a configuration of the substrate processing apparatus 10 can be simplified. Therefore, the substrate processing apparatus 10 may be easily assembled.
(33) In the above-described substrate processing apparatus 10, two capacitor layers are provided in the upper space US, but the number of the capacitor layers is not limited. Even if there is installed one capacitor layer therein, the voltage drop can be shared by the capacitor layer, and, thus, at least one capacitor may be installed in the upper space US. For example, in the upper space US, only the second capacitor layer 33 may be provided on the cover 14 (see
(34) In the first embodiment, there has been explained a case where the shower head 23 moves and there exists the upper space US between the shower head 23 and the cover 14. However, in the case where the susceptor moves and there exists a lower space between the susceptor and a bottom wall of the chamber, at least one capacitor layer may be provided in the lower space, thereby suppressing generation of an electric field in the lower space and further suppressing generation of plasma therein.
(35) Hereinafter, there will be explained a substrate processing apparatus in accordance with a second embodiment of the present invention.
(36) The present embodiment is basically the same as the first embodiment in view of a configuration or an operation but different from the first embodiment only in that a low dielectric member is installed between a shower head and a sidewall of a chamber. Therefore, redundant description of the same will be omitted, but only different configuration and operation will be explained.
(37) As described in the first embodiment, in a substrate processing apparatus including therein a movable shower head, the shower head is not in contact with a sidewall. However, in order to prevent plasma from introducing into an upper space from a processing space, a gap between the shower head (an upper electrode plate) and the sidewall is set to a minimum value and the conductive upper electrode plate becomes close to a sidewall in a ground potential. Since two objects having a high potential difference therebetween are close to each other, there is a risk of generation of abnormal electric discharge. In order to lower the risk, the upper electrode plate and the sidewall are separated from each other in the present embodiment.
(38)
(39) As depicted in
(40) Further, a gap between the dielectric ring 42 and the sidewall 13 is set to be in the range from about 0.5 mm to about 3.0 mm. Thus, even if the dielectric ring 42 or the sidewall 13 is thermally expanded, they do not interfere with each other, and a gap between the sidewall 13 and the upper electrode plate 43 is almost filled with the dielectric ring 42. Accordingly, it is possible to prevent plasma generated in a processing space PS from introducing into an upper space US.
(41) The upper electrode plate 43, the dielectric ring 42, and the sidewall 13 form a capacitor and are capacitively-coupled to each other to provide a small capacitance. Thus, a part of a high frequency current caused by a plasma-generating power applied to the processing space PS flows through the upper electrode plate 43, the dielectric ring 42, and the sidewall 13, and reaches a ground. That is, the high frequency current can be divided into one flowing through the upper space US and the other flowing through the dielectric ring 42. Accordingly, the high frequency current flowing through the upper space US can be decreased, thereby reducing a potential difference in the upper space US.
(42) The dielectric ring 42 is exposed to plasma generated in the processing space PS, and, thus, a material of the dielectric ring 42 needs to have a resistance to ion-sputtering as well as a resistance to radicals. It is desirable to use quartz or a ceramic-based material such as alumina ceramic, aluminum nitride, silicon nitride, yttria (Y.sub.2O.sub.3), sapphire, and zirconia. It may be also possible to use an insulating resin such as polytetrafluoroethylene or an engineering plastic-based resin coated with a plasma-resistant material. Further, a dielectric constant of the dielectric ring 42 may be in a range from about 2 to about 30.
(43) In the above-described substrate processing apparatus 40, although the dielectric ring 42 is installed at an outer periphery of the upper electrode plate 43, as depicted in
(44) Further, in the second embodiment, there has been explained a case where the shower head 41 moves and there exists a gap between the shower head 41 and the sidewall 13. However, in the case where a susceptor moves and there exists a gap between the susceptor and the sidewall 13, by installing a dielectric member to fill the gap, it is possible to prevent generation of abnormal electric discharge between the sidewall 13 and the susceptor.
(45) Hereinafter, there will be explained an experimental example of the present invention.
EXPERIMENTAL EXAMPLE
(46) In the substrate processing apparatus 10, the first capacitor layer 32 was formed by stacking two Teflon (registered trademark) sheets each having the thickness of about 1 mm; the second capacitor layer 33 was formed of one Teflon (registered trademark) sheet having a thickness of about 1 mm; a plasma-generating power having a predetermined value was applied to the processing space PS without applying a bias power thereto; and a thickness of the processing space PS (gap) was set to a predetermined value. Then, it was checked whether or not plasma was generated in the upper space US. A result thereof is shown in Table 1 below.
(47) TABLE-US-00001 TABLE 1 Plasma- generating Gap thickness(mm) power (W) 15 40 85 500 1000 1500 2000 2500 The mark in Table 1 represents that plasma is not generated.
COMPARATIVE EXAMPLE
(48) In the substrate processing apparatus 10, the capacitor layer in the upper space US was not installed; a plasma-generating power having a predetermined value was applied to the processing space PS without applying a bias power thereto; a thickness of the processing space PS (gap) was set to a predetermined value. Then, it was checked whether or not plasma was generated in the upper space US. A result thereof is shown in Table 2 below.
(49) TABLE-US-00002 TABLE 2 Plasma- generating Gap thickness (mm) power (W) 15 40 85 500 1000 x 1500 x 2000 x x 2500 x x x The mark x in Table 2 represents that plasma is generated, the mark represents that plasma is sometimes generated, and the mark represents that plasma is not generated.
(50) As can be seen from comparison of Table 1 and Table 2, it is possible to securely prevent generation of plasma by installing the first capacitor layer 32 and the second capacitor 33 in the upper space US.
(51) Hereinafter, there will be explained a substrate processing apparatus in accordance with a third embodiment of the present invention.
(52) In this substrate processing apparatus, an electrostatic coupling is formed between a movable electrode and a cylindrical shaped chamber's sidewall facing the movable electrode. Further, a ground path of a high frequency current caused by a high frequency power applied to a susceptor includes a line (hereinafter, referred to as first ground path) to be grounded along the movable electrode, an upper space US, and a cover and a sidewall of the chamber and a line (hereinafter, referred to as second ground path) to be grounded along the movable electrode and the sidewall of the chamber. Furthermore, a capacitance distribution ratio of the ground paths is changed according to movement of the movable electrode.
(53) In a substrate processing apparatus performing a predetermined plasma process onto a wafer, multiple plasma processes may be consecutively performed as a batch process in one chamber. Here, since a processing condition, particularly an optimum position of a shower head serving as a movable electrode, is different in each process, an optimum gap is set for each process. In such a batch process, whenever the gap is changed, desirably, optimization of plasma distribution in a processing space PS may be required, and, thus, there has been a demand for development in a technology of increasing parameters for optimizing the plasma distribution.
(54) To satisfy such a demand, the present embodiment provides a substrate processing apparatus capable of optimizing plasma distribution in a processing space according to a change in a gap.
(55) In accordance with the present embodiment, there is provided a substrate processing apparatus including a cylindrical shaped chamber configured to accommodate a substrate, a movable electrode capable of moving along a central axis of the cylindrical shaped chamber within the cylindrical shaped chamber, a facing electrode facing the movable electrode within the cylindrical shaped chamber, and an expansible/contractible partition wall connecting the movable electrode with an end wall on one side of the cylindrical shaped chamber. Further, a high frequency power is applied to a first space between the movable electrode and the facing electrode and a processing gas is introduced thereto. Furthermore, the movable electrode is not in contact with a sidewall of the cylindrical shaped chamber, and a first dielectric member is provided at the cylindrical shaped chamber's sidewall facing the movable electrode, and an overlap area between the first dielectric member and a side surface of the movable electrode is changed according to movement of the movable electrode.
(56)
(57) In
(58) In a substrate processing apparatus, plasma distribution in a processing space PS of a chamber is affected by, e.g., a gap, a pressure within the chamber, a kind of a processing gas, and an application value of a high frequency power.
(59) The substrate processing apparatus in accordance with the present embodiment is provided to obtain plasma distribution. Here, a basic processing condition, which is determined by a process purpose but cannot be modified in order to achieve the process purpose, is maintained as it is and other processing conditions more appropriate for the process are set in addition to such a basic condition. In order to do so, a dielectric member is provided at a sidewall of the cylindrical shaped chamber, and an electrostatic coupling is formed between the sidewall of the chamber, the dielectric member provided at this sidewall, and a movable electrode facing thereto. In this case, an electrostatic capacitance of the electrostatic coupling is changed according to movement of the movable electrode. Therefore, a capacitance of the second ground path and a capacitance distribution ratio between the second ground path and the first ground path are changed, so that plasma distribution in the processing space PS can be optimized.
(60) The substrate processing apparatus 50 is different from the substrate processing apparatus 10 of
(61) That is, the substrate processing apparatus 50 includes the cylindrical-shaped chamber (cylindrical shaped vessel) 11 and the shower head (movable electrode) 51 which can be moved along a central axis of the chamber 11, and the first dielectric member 55 is installed at the chamber 11's sidewall 53 facing the shower head 51.
(62) The first dielectric member 55 is of a ring shape and inserted and fitted into a ring-shaped recess of a predetermined depth installed at the sidewall 53 of the cylindrical chamber 11. A cross section of the first dielectric member 55 along the central axis of the chamber 11 has, for example, a rectangular shape. Therefore, the first dielectric member 55's width (hereinafter, referred to as thickness) in a direction toward the central axis of the chamber 11 is constant along the central axis of the chamber 11. The first dielectric member 55 faces a side surface of the shower head 51 with a gap G therebetween and an overlapped area sandwiching the gap G (hereinafter, simply referred to as overlap area) is changed according to movement of the shower head 51.
(63) Further, in
(64)
(65) In
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(67) In accordance with the present embodiment, the ring-shaped first dielectric member 55 is provided at the chamber 11's sidewall 53 facing the shower head 51 and the overlap area between the first dielectric member 55 and the side surface of the shower head 51 is changed according to movement of the shower head 51. Accordingly, the electrostatic capacitance of the electrostatic coupling between the shower head 51, the first dielectric member 55, and the sidewall 53 of the chamber 11 is changed according to movement of the shower head 51. Therefore, the capacitance of the second ground path flowing through the shower head 51, the sidewall 53 of the chamber 11 to the ground is changed. Further, if the capacitance of the second ground path is changed, the capacitance distribution ratio between the second ground path and the first ground path is changed and, particularly, a value of a high frequency current flowing through a peripheral end portion of the shower head 51 is changed, and, thus, plasma distribution in the processing space PS becomes changed.
(68) Accordingly, a capacitance distribution ratio between the first ground path and the second ground path for obtaining a required plasma distribution in a first processing space PS is calculated with respect to a gap in each plasma process. Then, a position at the sidewall 53 of the chamber 11, a shape of a cross section, and a thickness of the first dielectric member 55 for obtaining the calculated ratio are calculated with respect to a gap in each plasma process. Then, the appropriate first dielectric member 55 is provided at the appropriate position, so that plasma distribution in the processing space PS can be optimized depending on different processing conditions for different processing purposes.
(69) By optimizing the plasma distribution in the first processing space PS, in-plane uniformity of an etching rate can be expected.
(70) In the present embodiment, a ring-shaped second dielectric member may be further provided at the shower head 51's side surface facing the first dielectric member 55. In this case, an overlap area between the first dielectric member 55 and the second dielectric member may be changed according to movement of the shower head 51. Accordingly, a range of a change in the electrostatic capacitance of the electrostatic coupling depending on movement of the shower head 51 becomes narrower, and, thus, plasma distribution in the processing space PS according to a change in the gap can be more finely adjusted.
(71) Further, in this case, cross sections of the first dielectric member 55 and the second dielectric member along the central axis of the chamber 11 may have a rectangular shape or a triangular shape and a thickness in a direction orthogonal to the central axis may be constant or gradually changed along the central axis. By arbitrarily combining shapes of the cross sections of the first dielectric member 55 and the second dielectric member along the central axis of the chamber 11, the capacitance of the second ground path according to the change in the gap can be varied. Therefore, a variation of the electrostatic coupling is increased in the third embodiment.
(72) In the present embodiment, each of the first dielectric member 55 and the second dielectric member may be made of quartz, ceramic or an insulating resin. Since these materials have a resistance to ion-sputtering as well as a resistance to radicals, the first dielectric member 55 and the second dielectric member can be prevented from being eroded by plasma generated in the first processing space PS. The ceramic-based material may include, for example, alumina ceramic, aluminum nitride, silicon nitride, yttria (Y.sub.2O.sub.3), sapphire, and zirconia, and the insulating resin may include, for example, polytetrafluoroethylene.
(73) In the above-described third embodiment, it has been described that the shower head 51 moves, but the susceptor 12 may be moved. In this case, the first dielectric member 55 is provided at the chamber 11's sidewall 53 facing a sidewall of the susceptor 12, and an electrostatic coupling is formed between the susceptor 12, the first dielectric member 55, and the sidewall 53 of the chamber 11. Accordingly, an overlap area between the susceptor 12 and the first dielectric member 55 is changed according to movement of the susceptor 12. Therefore, an electrostatic capacitance of the electrostatic coupling is changed, so that plasma distribution in the first processing space PS can be optimized.
(74)
(75) As depicted in
(76) In a status where a shower head 51 is at the lowermost position (see
(77)
(78) In
(79) Further, in
(80) In accordance with the modified examples of the present embodiment, depending on a change in a gap caused by movement of a shower head serving as a movable electrode, a position, a shape of a cross section, and a thickness of an appropriate dielectric member are selected and, then, the dielectric member is provided at the selected position. Accordingly, plasma distribution in the first processing space PS for each plasma process condition can be optimized and a capacitance distribution ratio of a ground path may be added to parameters for adjusting the plasma distribution.