Thermally insulated shipping system for pallet-sized payload, methods of making and using the same, and kit for use therein
11572227 · 2023-02-07
Assignee
Inventors
- Fery Pranadi (Pleasanton, CA, US)
- Shreyas S. Panse (Boston, MA, US)
- TzeHo Lee (Needham, MA, US)
- Mark Fontes (North Scituate, RI, US)
- Gregory Cook (Holliston, MA, US)
- Richard Orsini (Roxbury, MA, US)
- Richard M. Formato (Grafton, MA)
- Karen L. Snyder (Natick, MA, US)
- Douglas Johnson (Mansfield, MA, US)
- Timothy D. Stovall (Montgomery, TX, US)
Cpc classification
F25D2303/08221
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25D2303/085
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B65D2519/00293
PERFORMING OPERATIONS; TRANSPORTING
B65D2519/00587
PERFORMING OPERATIONS; TRANSPORTING
B65D19/06
PERFORMING OPERATIONS; TRANSPORTING
B65D2519/0086
PERFORMING OPERATIONS; TRANSPORTING
B65D2519/00502
PERFORMING OPERATIONS; TRANSPORTING
B65D81/3823
PERFORMING OPERATIONS; TRANSPORTING
B65D2519/00273
PERFORMING OPERATIONS; TRANSPORTING
B65D2519/00184
PERFORMING OPERATIONS; TRANSPORTING
B65D2519/00218
PERFORMING OPERATIONS; TRANSPORTING
B65D2519/00641
PERFORMING OPERATIONS; TRANSPORTING
B65D2519/00338
PERFORMING OPERATIONS; TRANSPORTING
B65D2519/00044
PERFORMING OPERATIONS; TRANSPORTING
F25D3/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
Thermally insulated shipping system for use in transporting a pallet-sized payload. In one embodiment, the system includes a plurality of thermally insulating walls arranged to define an interior volume suitable for receiving a pallet-sized payload. The thermally insulating walls include a top wall, a bottom wall, a front wall, a rear wall, a left wall, and a right wall, of which all but the bottom wall include at least two slots facing towards the interior volume. One of the slots is an inner slot that is more proximal to the interior volume, and one of the slots is an outer slot that is more distal to the interior volume. The system also includes a plurality of inner cassettes disposed in at least some of the inner slots and a plurality of outer cassettes disposed in at least some of the outer slots. The inner and outer cassettes include phase-change materials.
Claims
1. A shipping system for use in transporting a pallet-sized payload, the shipping system comprising: (a) a plurality of walls, the plurality of walls being arranged to define an interior volume suitable for receiving a pallet-sized payload, wherein at least one of the walls comprises at least two slots facing towards the interior volume, one of the slots being an inner slot that is more proximal to the interior volume and one of the slots being an outer slot that is more distal to the interior volume; and (b) a first cassette, the first cassette comprising a quantity of phase-change material and being removably mounted in one of the inner slot and the outer slot.
2. The shipping system as claimed in claim 1 wherein the plurality of walls comprises a top wall, a bottom wall, a front wall, a rear wall, a left wall and a right wall.
3. The shipping system as claimed in claim 2 wherein the interior volume has a generally rectangular prismatic shape.
4. The shipping system as claimed in claim 3 wherein the interior volume is dimensioned to receive a payload having dimensions of length×width×height selected from at least one of 48″×40″×45″, 48″×42″×45″, and 48″×42″×46″.
5. The shipping system as claimed in claim 2 wherein each of the top wall, the bottom wall, the front wall, the rear wall, the left wall, and the right wall comprises thermal insulation.
6. The shipping system as claimed in 5 wherein the thermal insulation comprises a panel of rigid polyurethane foam.
7. The shipping system as claimed in claim 2 wherein each of the top wall, the front wall, the rear wall, the left wall and the right wall comprises a pair of brackets facing towards the interior volume, each of the brackets comprising an inner track and an outer track, the inner tracks of the pair of brackets jointly defining the inner slot, the outer tracks of the pair of brackets jointly defining the outer slot.
8. The shipping system as claimed in claim 1 wherein the first cassette is removably mounted in the inner slot, the shipping system further comprising a second cassette, the second cassette comprising a quantity of phase-change material and being removably mounted in the outer slot.
9. The shipping system as claimed in claim 1 wherein the plurality of walls comprises a top wall, a bottom wall, and a plurality of side walls and wherein at least one of the plurality of side walls comprises a pair of brackets facing towards the interior volume, each of the brackets comprising an inner track and an outer track, the inner tracks of the pair of brackets jointly defining the inner slot, the outer tracks of the pair of brackets jointly defining the outer slot.
10. The shipping system as claimed in claim 9 wherein each of the inner slot and the outer slot is oriented horizontally.
11. The shipping system as claimed in claim 10 wherein the first cassette comprises a first receptacle holding a plurality of sleeves, each of the plurality of sleeves comprising a first container holding a quantity of phase-change material.
12. The shipping system as claimed in claim 11 wherein the plurality of sleeves are different in composition from one another.
13. The shipping system as claimed in claim 8 wherein the first cassette and the second cassette are different in composition from one another.
14. The shipping system as claimed in claim 1 further comprising at least one corner bracket pivotally mounted on the exterior of one of said walls and constructed to support the weight of said wall when said wall is pivoted outwardly.
15. The shipping system as claimed in claim 7 wherein each of the top wall, the front wall, the rear wall, the left wall and the right wall has exactly one inner slot and exactly one outer slot and wherein the first cassette comprises a first receptacle holding a plurality of sleeves, each of the plurality of sleeves comprising a first container holding at least one quantity of phase-change material and at least one piece of insulation.
16. The shipping system as claimed in claim 7 wherein the first cassette comprises a plurality of sleeves, wherein each of the plurality of sleeves contains phase-change material, and wherein at least one of the plurality of sleeves contains a different type and/or quantity of phase-change material than at least another of the plurality of sleeves.
17. The shipping system as claimed in claim 16 wherein the first cassette has four corners and wherein the plurality of sleeves is constructed and arranged to provide greater thermal protection proximate to the four corners of the first cassette than elsewhere in the first cassette.
18. A shipping system for use in transporting a pallet-sized payload, the shipping system comprising: (a) a plurality of thermally insulating walls, the plurality of thermally insulating walls being arranged to define an interior volume suitable for receiving a pallet-sized payload, the plurality of thermally insulating walls comprising a top wall, a bottom wall, a front wall, a rear wall, a left wall, and a right wall, wherein at least two of the top wall, the front wall, the rear wall, the left wall, and the right wall comprise at least two slots facing towards the interior volume, one of the slots being an inner slot that is more proximal to the interior volume and one of the slots being an outer slot that is more distal to the interior volume; (b) a plurality of inner cassettes, the plurality of inner cassettes being disposed in at least some of the inner slots, each of the inner cassettes comprising at least a first phase-change material; and (c) a plurality of outer cassettes, the plurality of outer cassettes being disposed in at least some of the outer slots, each of the outer cassettes comprising at least a second phase-change material, the second phase-change material being different from the first phase-change material.
19. The shipping system as claimed in claim 18 wherein each of the top wall, the front wall, the rear wall, the left wall, and the right wall comprises the inner slot and the outer slot.
20. The shipping system as claimed in claim 19 wherein the plurality of inner cassettes comprises five inner cassettes and the plurality of outer cassettes comprises five outer cassettes, the five inner cassettes disposed in the inner slots of the top wall, the front wall, the rear wall, the left wall and the right wall, the five outer cassettes disposed in the outer slots of the top wall, the front wall, the rear wall, the left wall and the right wall.
21. The shipping system as claimed in claim 20 wherein each of the inner cassettes comprises a first receptacle holding two identical outer sleeves and three identical inner sleeves, each of the two identical outer sleeves comprising a first container holding a first insulation panel, a first temperature-control member aligned with the first insulation panel, and a plurality of second temperature-control members positioned at opposite ends of the first insulation panel, the first temperature-control member comprising a first gelled organic phase-change material having a phase-change temperature of approximately +3° C., the second temperature-control member comprising a second gelled organic phase-change material having a phase-change temperature of approximately +5° C., each of the three identical inner sleeves comprising a second container holding a second insulation panel and a third temperature-control member aligned with the second insulation panel, the third temperature-control member comprising a third gelled organic phase-change material having a phase-change temperature of approximately +3° C.
22. The shipping system as claimed in claim 21 wherein each of the outer cassettes comprises a second receptacle holding two identical outer sleeves and three identical inner sleeves, each of the two identical outer sleeves comprising a third container holding a plurality of fourth temperature-control members, each of the fourth temperature-control members comprising a foam brick impregnated with water or a water-based phase-change material and sealed within a pair of polymer films, each of the three identical inner sleeves comprising a fourth container holding a fifth temperature-control member, the fifth temperature-control member comprising a multi-compartmented container holding a plurality of foam bricks impregnated with water or a water-based phase-change material, the inner sleeves holding less phase-change material than the outer sleeves.
23. The shipping system as claimed in claim 22 wherein the inner cassettes are preconditioned at +5° C. and wherein the outer cassettes are preconditioned at −20° C.
24. The shipping system as claimed in claim 18 wherein the plurality of inner cassettes are removably disposed in at least some of the inner slots, wherein the plurality of outer cassettes are removably disposed in at least some of the outer slots, wherein one of the plurality of inner cassette comprises a plurality of sleeves, wherein each of the plurality of sleeves contains phase-change material, and wherein at least one of the plurality of sleeves contains a different type and/or quantity of phase-change material than at least another of the plurality of sleeves.
25. A shipping system for use in transporting a pallet-sized payload, the shipping system comprising: (a) a plurality of thermally insulating walls, the plurality of thermally insulating walls being arranged to define an interior volume suitable for receiving a pallet-sized payload, the plurality of thermally insulating walls comprising a top wall, a bottom wall, a front wall, a rear wall, a left wall, and a right wall, wherein each of the front wall, the rear wall, the left wall, and the right wall comprises at least two slots facing towards the interior volume, one of the slots being an inner slot that is more proximal to the interior volume and one of the slots being an outer slot that is more distal to the interior volume; (b) a first inner sleeve, the first inner sleeve disposed in the inner slot of the front wall and comprising a phase-change material; (c) a second inner sleeve, the second inner sleeve disposed in the inner slot of the rear wall and comprising a phase-change material; (d) a third inner sleeve, the third inner sleeve disposed in the inner slot of the left wall and comprising a phase-change material; and (e) a fourth inner sleeve, the fourth inner sleeve disposed in the inner slot of the right wall and comprising a phase-change material.
26. The shipping system as claimed in claim 25 further comprising a tray positioned over the payload in the interior volume, the tray holding a phase-change material.
27. The shipping system as claimed in claim 26 wherein the phase-change material in the first, second, third and fourth sleeves and in the tray is dry ice.
28. The shipping system as claimed in claim 27 further comprising eight additional inner sleeves, a first two of the eight additional sleeves disposed adjacent to the first inner sleeve in the inner slot of the front wall to form a first triplet of sleeves, a second two of the eight additional sleeves disposed adjacent to the second inner sleeve in the inner slot of the rear wall to form a second triplet of sleeves, a third two of the eight additional sleeves disposed adjacent to the third inner sleeve in the inner slot of the left wall to form a third triplet of sleeves, and a fourth two of the eight additional sleeves disposed adjacent to the fourth inner sleeve in the inner slot of right wall to form a fourth triplet of sleeves, wherein the outer sleeves of each triplet contain dry ice and the middle sleeve of each triplet is empty.
29. The shipping system as claimed in claim 28 wherein the outer slot of each of the front wall, the rear wall, the left side wall, and the right side wall is empty.
30. The shipping system as claimed in claim 28 further comprising a first insulation panel disposed in the outer slot of the front wall, a second insulation panel disposed in the outer slot of the rear wall, a third insulation panel disposed in the outer slot of the left wall, and a fourth insulation panel disposed in the outer slot of the right wall.
31. The shipping system as claimed in claim 25 wherein the first inner sleeve is removably disposed in the inner slot of the front wall, wherein the second inner sleeve is removably disposed in the inner slot of the rear wall, wherein the third inner sleeve is removably disposed in the inner slot of the left wall, wherein the fourth inner sleeve is removably disposed in the inner slot of the right wall, and wherein each of the first inner sleeve, the second inner sleeve, the third inner sleeve, and the fourth inner sleeve comprises a first container holding at least one quantity of phase-change material and at least one piece of insulation.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The accompanying drawings, which are hereby incorporated into and constitute a part of this specification, illustrate various embodiments of the invention and, together with the description, serve to explain the principles of the invention. In the drawings wherein like reference numerals represent like parts:
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DETAILED DESCRIPTION OF THE INVENTION
(32) The present invention is directed at a shipping system that may be used to maintain a temperature-sensitive payload within a desired temperature range for a particular period of time. The system, which may be used with a pallet-sized payload optionally positioned on a pallet, possesses certain features of modularity that permit the system to be modified, if desired, to suit particular thermal needs. More specifically, the system may comprise a plurality of thermally insulated walls. The plurality of walls may be used collectively to fashion a thermally insulated volume for receiving the payload. In addition, one or more of the walls may include a mounting mechanism facing towards the thermally insulated volume and defining, at least in part, an inner slot and an outer slot. The inner slot, which is located more proximal to the payload, may be used to receive a first thermal device. The outer slot, which is located more distal to the payload, may be used to receive a second thermal device. As can be appreciated, by selectively using the first thermal device and/or the second thermal device and by modifying the thermal characteristics of the first thermal device and/or the second thermal device, one may adjust the thermal characteristics of the shipping system as a whole.
(33) Referring now to
(34) System 11, which may be used to maintain a payload within a temperature range of +2° C. to +8° C. for an extended period of time, such as up to five days or longer, may comprise a skid 13, a bottom wall 15, a front wall 17, a rear wall 19, a left wall 21, a right wall 23, a top wall 25, a plurality of inner cassettes 27-1 through 27-5, and a plurality of outer cassettes 29-1 through 29-5.
(35) Skid 13, which is also shown separately in
(36) Without wishing to be limited to any particular dimensions, skid 13 may have a length l.sub.1 of approximately 70 inches, a width w.sub.1 of approximately 60 inches, and a height h.sub.1 of approximately 9.50 inches.
(37) Bottom wall 15, which is also shown separately in
(38) Bottom wall 15 may be appropriately dimensioned to be received on top of and across the width of base portion 31 of skid 13, with left side 53 of bottom wall 15 being positioned just inside or in contact with an inside surface of peripheral wall 35 and with right side 55 of bottom wall 15 being positioned just inside or in contact with an inside surface of peripheral wall 35. In this manner, with bottom wall 15 mounted on skid 13, left wall 21 may be positioned on top of first stepped portion 57 of bottom wall 15, right wall 23 may be positioned on top of second stepped portion 59 of bottom wall 15, front wall 17 may be positioned in the space between front 49 of bottom wall 15 and peripheral wall 35 of skid 13, and rear wall 19 may be positioned in the space between rear 51 of bottom wall 15 and peripheral wall 35 of skid 13.
(39) Without wishing to be limited to any particular dimensions, bottom wall 15 may have a length l.sub.2 of approximately 58 inches, a width w.sub.2 of approximately 58 inches, a maximum height h.sub.2 of approximately 4 inches, and a minimum height h.sub.3 of approximately 2 inches.
(40) Front wall 17, which is also shown separately in
(41) Without wishing to be limited to any particular dimensions, the combination of insulating panel 61 and cover 63 may have a length l.sub.3 of approximately 58 inches, a width w.sub.3 of approximately 57.75 inches, and a thickness t.sub.1 of approximately 4 inches.
(42) Front wall 17 may further comprise a pair of brackets 81 and 83. Each of brackets 81 and 83 may be a unitary (i.e., one-piece) structure preferably made of a molded polymer or another similarly suitable material. Bracket 81, which may be mounted generally horizontally on rear 71 a short distance from top 67 using mechanical fasteners 84 (e.g., studs) and/or other suitable fastening means, may be shaped to define a pair of parallel tracks, namely, an outer track 85 that is proximal to rear 71 and an inner track 87 that is distal to rear 71. Each of outer track 85 and inner track 87 may have a generally inverted U-shape, with the respective ends and bottom of each of outer tracks 85 and 87 being open. Bracket 81 may additionally be shaped to include a stop 88, which may be used to limit forward sliding movement of cassettes 27-5 and 29-5. Bracket 83, which may be mounted generally horizontally on rear 71 a short distance from bottom 65 using mechanical fasteners 86 (e.g., studs) and/or other suitable fastening means, may be shaped to define a pair of parallel tracks, namely, an outer track 91 that is proximal to rear 71 and an inner track 93 that is distal to rear 71. Each of outer track 91 and inner track 93 may be generally U-shaped, with the respective ends and top of each of outer tracks 91 and 93 being open. Brackets 81 and 83 may be appropriately positioned relative to one another to jointly define an inner slot and an outer slot. In this manner, inner cassette 27-1 and outer cassette 29-1 may be removably mounted within the inner slot and the outer slot, respectively, for example, by sliding inner cassette 27-1 into inner track 87 of bracket 81 and into inner track 93 of bracket 83 and by sliding outer cassette 29-1 into outer track 85 of bracket 81 and into outer track 91 of bracket 83. For example, without wishing to be limited to any particular dimensions, brackets 81 and 83 may be spaced apart so as to receive cassettes whose respective top and bottom edges are separated by a distance of approximately 40 inches.
(43) Although not included in the present embodiment, it is to be understood that a mounting plate may be inserted into panel 61 or between panel 61 and cover 63 to facilitate the mounting of brackets 81 and 83 to cover 63.
(44) Rear wall 19, which is also shown separately in
(45) Although not included in the present embodiment, a mounting plate may be inserted into panel 101 or between panel 101 and cover 103 to facilitate the mounting of brackets 105 and 107 to cover 103.
(46) Left wall 21, which is also shown separately in
(47) Without wishing to be limited to any particular dimensions, the combination of insulating panel 111 and cover 113 may have a length l.sub.4 of approximately 58 inches, a width w.sub.4 of approximately 53.25 inches, and a thickness t.sub.2 of approximately 4 inches.
(48) Left wall 21 may further comprise a pair of brackets 122 and 124. Bracket 122 may be identical to bracket 81, except that bracket 122 need not include structure corresponding to stop 88, and bracket 124 may be identical to bracket 83. Bracket 122 may be mounted generally horizontally on right side 125 a short distance from top 117 using mechanical fasteners 126 (e.g., studs) and/or other suitable fastening means. Bracket 124 may be mounted generally horizontally on right side 125 a short distance from bottom 115 using mechanical fasteners 128 (e.g., studs) and/or other suitable fastening means. Brackets 122 and 124 may be appropriately positioned relative to one another to jointly define an inner slot and an outer slot. In this manner, inner cassette 27-3 and outer cassette 29-3 may be removably mounted within the inner slot and the outer slot, respectively, for example, by sliding inner cassette 27-3 into an inner track 129 of bracket 122 and into an inner track 131 of bracket 124 and by sliding outer cassette 29-3 into an outer track 133 of bracket 122 and into an outer track 135 of bracket 124. For example, without wishing to be limited to any particular dimensions, brackets 122 and 124 may be spaced apart so as to receive cassettes whose respective top and bottom edges are separated by a distance of approximately 40 inches. Preferably, brackets 122 and 124 are appropriately positioned on right side 125 so that, when system 11 is assembled, bracket 122 may be substantially aligned with brackets 81 and 105 and bracket 124 may be substantially aligned with brackets 83 and 107.
(49) Although not included in the present embodiment, a mounting plate may be inserted into panel 111 or between panel 111 and cover 113 to facilitate the mounting of brackets 122 and 124 to cover 113.
(50) Right wall 23, which is also shown separately in
(51) Although not included in the present embodiment, a mounting plate may be inserted into panel 141 or between panel 141 and cover 143 to facilitate the mounting of brackets 145 and 147 to cover 143.
(52) Top wall 25, which is also shown separately in
(53) Top wall 25 may differ from bottom wall 15 in that top wall 25 may further comprise a pair of brackets 171 and 173. Bracket 171 may be identical to bracket 81, except that bracket 171 need not include structure corresponding to stop 88, and bracket 173 may be identical to bracket 83. Bracket 171 may be mounted on bottom 155 a short distance from first stepped portion 167 using mechanical fasteners 174 (e.g., studs) and/or other suitable fastening means. Bracket 173 may be mounted on bottom 155 a short distance from second stepped bottom 169 using mechanical fasteners 176 (e.g., studs) and/or other suitable fastening means. Brackets 171 and 173 may be appropriately positioned relative to one another to jointly define an inner slot and an outer slot. In this manner, inner cassette 27-5 and outer cassette 29-5 may be removably mounted within the inner slot and the outer slot, respectively, for example, by sliding inner cassette 27-5 into an inner track 179 of bracket 171 and into an inner track 181 of bracket 173 and by sliding outer cassette 29-5 into an outer track 183 of bracket 171 and into an outer track 185 of bracket 173. For example, without wishing to be limited to any particular dimensions, brackets 171 and 173 may be spaced apart so as to receive cassettes whose opposite edges are separated by a distance of approximately 40 inches.
(54) Although not included in the present embodiment, a mounting plate may be inserted into panel 151 or between panel 151 and cover 153 to facilitate the mounting of brackets 171 and 173 to cover 153.
(55) Inner cassettes 27-1 through 27-5 may be identical to one another and, in the present embodiment, are, in fact, identical to one another. Referring now to
(56) Without wishing to be limited to any particular dimensions, inner cassette 27-1 may have a length l.sub.5 of approximately 48 inches, a width w.sub.5 of approximately 40 inches, and a thickness t.sub.3 of approximately 1.75 inches.
(57) Container 201, which is also shown separately in
(58) Divider 203, which is also shown separately in
(59) Sleeves 205-1 and 205-5 may be identical to one another and, in the present embodiment, are, in fact, identical to one another. Sleeve 205-1, which is also shown separately in
(60) Container 261, which may comprise a box of corrugated cardboard or another similarly suitable material, may be shaped to include a generally rectangular prismatic cavity 281 that may be accessible through a pair of front closure flaps 283-1 and 283-2 extending between a first closed end 284 of container 261 and a second closed end 286 of container 261. Flaps 283-1 and 283-2 may have opposing edges 287-1 and 287-2, respectively, with matching stepped shapes so as to jointly define a plurality of windows 288, the purpose of which will be discussed below.
(61) Insulating member 263, which may be a block of expanded polystyrene or another similarly suitable material, may be disposed within cavity 281 of container 261. Insulating member 263 may be appropriately dimensioned to have a length that is substantially shorter than the length of cavity 281. In addition, insulating member 263 may be positioned against a back wall 289 of container 261 and may be centered between first end 284 of container 261 and second end 286 of container 261. (Insulating member 263 may be secured in the above-mentioned position by an adhesive or other suitable means.) In this manner, a first end 291 of insulating member 263 and first end 284 of container 261 may jointly define a space that may be used to receive a stacked arrangement of second temperature-control member 267 and third temperature-control member 269, and a second end 293 of insulating member 263 and second end 286 of container 261 may jointly define a space that may be used to receive a stacked arrangement of fourth temperature-control member 271 and fifth temperature-control member 273.
(62) First temperature-control member 265 may comprise a quantity of a phase-change material positioned within a suitable container. For example, the phase-change material may comprise any phase-change material including any water-based phase-change material or organic phase-change material. In a preferred embodiment, the phase-change material may be a gelled organic phase-change material of the type disclosed in U.S. Patent Application Publication No. US 2014/0290285 A1, inventors Formato et al., published Oct. 2, 2014, the disclosure of which is incorporated herein by reference. More specifically, such a phase-change material may be formed by mixing one or more n-alkanes, such as n-tetradecane (C14), n-pentadecane (C15), n-hexadecane (C16), and n-octadecane (C18), with a gelling agent in the form of a styrene-ethylene-butylene-styrene triblock copolymer or a styrene-ethylene-propylene-styrene triblock copolymer. Examples of the aforementioned gelling agent may include one or more of Kraton™ G1651 copolymer (a high molecular weight SEBS tri-block copolymer with a styrene:rubber ratio of 30:70% by weight), Kraton™ G1654 copolymer (a high molecular weight SEBS tri-block copolymer with a styrene:rubber ratio of 33:67% by weight), or Kraton™ G1660 copolymer (an SEBS tri-block copolymer with a styrene:rubber ratio of 31:69% by weight), or an SEPS copolymer, such as, but not limited to, SEPTON™ S2005 copolymer (a high molecular weight SEPS tri-block copolymer with a styrene:rubber ratio of 20:80% by weight). The mixing of the above-described one or more n-alkanes and the above-described gelling agent may take place at a first temperature at which the at least one n-alkane is in a liquid state and which is below the flashpoint of the at least one n-alkane and at which the mixture is not a viscoelastic liquid, whereby a non-homogeneous mixture is produced; then, heating the non-homogenous mixture to a second temperature that is below the flashpoint of the at least one n-alkane and at which a viscoelastic liquid is formed; and, then, cooling the viscoelastic liquid to room temperature.
(63) Examples of gelled organic phase-change materials that may be suitable for use as phase-change material may include the following (the phase-change temperatures reported below being approximate and, in some cases, spanning a range of 1.5° C. to 2.0° C.):
(64) TABLE-US-00001 Phase- Change Composi- % Composition Example Temper- % N- tion of N- Gelling of Gelling No. ature Alkane Alkane(s) Agent Agent 1 3° C. 92.6% 96.5% C14 7.4% Kraton ™ and 3.5% G1654 C16 powder 2 3° C. 92.6% 98.5% C14 7.4% Kraton ™ and 1.5% G1654 C16 powder 3 5° C. 92.6% 100% C14 7.4% Kraton ™ G1654 powder 4 7° C. 92.6% 38.2% C14 7.4% Kraton ™ and 61.8% G1654 C16 powder 5 7° C. 92.6% 16% C14 and 7.4% Kraton ™ 84% C15 G1654 powder 6 17° C. 92.6% 100% C16 7.4% Kraton ™ G1654 powder 7 24° C. 92.6% 10.5% C16 7.4% Kraton ™ and 89.5% G1654 C18 powder
(65) The gelled organic phase-change materials of the above-identified Examples were prepared by placing the above-described mixtures into a pre-heated oven operating at 50° C. for a period of 2.5 hours and then removing the mixtures from the oven and allowing the mixtures to cool to room temperature. Some of the properties of temperature-control members including the resulting mixtures are presented below.
(66) TABLE-US-00002 Measured Measured THAW FREEZE 12 Phase- Phase- Freeze/ Compres- Avg. Change Change Thaw Cycle sive Example Thickness Temp Temp Syneresis Modulus No. (inches) (Deg C.) (Deg C.) (% weight) (psi) 1 0.466 4.18 1.89 0.0 Not tested 2 0.473 4.26 3.28 0.0 Not tested 3 0.508 5.27 4.27 <0.5 4.09 (8 cycles) 4 0.479 7.78 7.79 0.0 Not tested 5 0.502 7.42 7.03 0.0 Not tested 6 0.475 17.46 16.95 0.0 Not tested 7 Not Not Not Not Not tested tested tested tested tested
(67) Gelled organic phase-change materials of the type described above possess many desirable attributes. For example, such gelled materials are capable of conforming to virtually any shaped pouch or other receptacle therefor while, at the same time, being less susceptible to leaking than liquid phase-change materials. In addition, such gelled materials possess good shock absorption and, therefore, provide physical protection to a payload covered thereby. Additionally, such gelled materials are capable of surviving many freeze/thaw cycles while maintaining good performance as a phase-change material. Moreover, such gelled materials possess excellent compression strength—even when placed under a payload (as in certain embodiments discussed below). Furthermore, the above-described gelled phase-change materials tend to cover more surface area of a product load than do an equivalent amount of a liquid phase-change material, especially when the phase-change material is oriented vertically. This is because liquid phase-change materials tend to flow to the bottom of the receptacle containing the liquid phase-change material. Consequently, orienting the receptacle vertically tends to cause a significant portion of the liquid phase-change material to pool at the bottom of the receptacle. (This problem may persist, albeit to a lesser extent, even if the receptacle is oriented horizontally.) By contrast, the subject gelled materials tend not to flow much, if at all, to the bottom of a receptacle therefor.
(68) The container used to hold the phase-change material may be, for example, a flexible or rigid pouch or a series of interconnected flexible or rigid pouches whose contents are sealed from one another and the environment. In the present embodiment, the container is in the form of six interconnected flexible pouches whose contents are sealed from one another. The container may be formed by thermoforming a polymer film to define a plurality of troughs and then sealing the thermoformed film to a flat polymer film around their respective peripheries and in the spaces between the troughs of the thermoformed film. The sealing together of the two polymer films is preferably performed after phase-change material has been loaded into the troughs. As can be appreciated, the thermoforming, loading, and sealing steps may be performed as part of a continuous manufacturing process or may be performed batch-wise.
(69) Preferably, each pouch of the six interconnected pouches of first temperature-control member 265 contains approximately the same quantity of the same type of phase-change material. In the present embodiment, the phase-change material preferably has a phase-change temperature of approximately +3° C. and may have, for example, the composition of Example 2 above.
(70) Second temperature-control member 267, third temperature-control member 269, fourth temperature-control member 271, and fifth temperature-control member 273 may be identical to one another and may differ from first temperature-control member 265 only in that each of second temperature-control member 267, third temperature-control member 269, fourth temperature-control member 271, and fifth temperature-control member 273 may comprise two interconnected, yet sealed, pouches, as opposed to the six interconnected, yet sealed, pouches of first temperature-control member 265, and in that the type of phase-change material in temperature-control members 267, 269, 271 and 273 may differ from that of temperature-control member 265. More specifically, whereas temperature-control member 265 may comprise a first gelled organic phase-change material having a comparatively lesser latent heat, temperature-control members 267, 269, 271 and 273 may comprise a second gelled organic phase-change material having a comparatively greater latent heat. In the present embodiment, the phase-change material of temperature-control members 267, 269, 271 and 273 may have a phase-change temperature of approximately +5° C. and may have, for example, the composition of Example 3 above.
(71) Preferably, the combined thickness of insulating member 263 and first temperature-control member 265 is approximately equal to the combined thickness of second temperature-control member 267 and third temperature-control member 269 and is approximately equal to the combined thickness of fourth temperature-control member 271 and fifth temperature-control member 273. In this manner, sleeve 205-1 may position more phase-change material at the respective ends of sleeve 205-1 than at the intermediate portion of sleeve 205-1. This may be desirable as the corners of the payload volume tend to be the locations where undesired thermal incursions are most likely; consequently, positioning more phase-change material at these locations may counter this effect.
(72) To keep first temperature-control member 265, second temperature-control member 267 and fourth temperature-control member 271 from moving when sleeve 205-1 is positioned vertically, one may secure the foregoing temperature-control members to container 201 by applying one or more strips of adhesive tape (not shown) across windows 288.
(73) Without wishing to be limited to any particular dimensions, sleeve 205-1 may have a length l.sub.6 of approximately 39.375 inches, a width w.sub.6 of approximately 8 inches, and a thickness t.sub.4 of approximately 1.375 inches.
(74) Sleeves 205-2 through 205-4 may be identical to one another and, in the present embodiment, are, in fact, identical to one another. Sleeve 205-2, which is also shown separately in
(75) Sleeves 205-2 through 205-4 may have overall dimensions substantially the same as sleeves 205-1 and 205-5.
(76) As can readily be appreciated, because of the construction of sleeves 205-1 through 205-2, inner cassette 27-1 provides greater thermal protection at its four corners than elsewhere. This is by design as the greatest thermal weakness for the six walls is typically at their corners.
(77) It is to be understood that the number of sleeves in inner cassette 27-1 is merely illustrative. As such, one could increase or decrease the number of sleeves in inner cassette 27-1 without departing from the teachings of the present invention. In addition, it should be understood that, although each of sleeves 205-1 and 205-5 is described above as having a greater quantity of phase-change material than is present in each of sleeves 205-2, 205-3 and 205-4, all of sleeves 205-1, 205-2, 205-3, 205-4 and 205-5 may be identical. Moreover, although each of sleeves 205-1 through 205-5 is described above as having a certain type of phase-change material or as having certain types of phase-change material, the type(s) of phase-change material may be changed.
(78) Assemblies 207-1 and 207-2 may be identical to one another and, in the present embodiment, are, in fact, identical to one another. Assembly 207-1, which is shown separately in
(79) To prepare inner cassette 27-1 for use, sleeves 205-1 through 205-5 may be loaded into container 201, container 201 may be closed using assemblies 207-1 and 207-2, and inner cassette 27-1 may be pre-conditioned, as a unit, at a desired temperature, for example, at about 5° C. (Preferably, the pre-conditioning temperature and the phase-change temperature of the phase-change material in inner cassette 27-1 are within the temperature range that one wishes to maintain the payload.) Depending on the application to which system 11 is to be put and depending on the composition of the sleeves to be used as a part of inner cassette 27-1, one may pre-condition different sleeves of inner cassette 27-1 at different temperatures and then load the differently pre-conditioned sleeves into container 201. (Alternatively, if desired, inner cassette 27-1 may be sealed shut to prevent sleeves 205-1 through 205-5 from being removed therefrom.) Inner cassettes 27-2 through 27-5 may be prepared similarly to inner cassette 27-1.
(80) Outer cassettes 29-1 through 29-5 may be identical to one another and, in the present embodiment, are, in fact, identical to one another. Referring now to
(81) Sleeves 371-1 and 371-5 may be identical to one another and, in the present embodiment, are, in fact, identical to one another. Sleeve 371-1, which is also shown separately in
(82) Container 373, which may comprise a box of corrugated cardboard or another similarly suitable material, may be shaped to include a generally rectangular prismatic cavity 381 that may be accessible through a pair of front closure flaps 383-1 and 383-2 extending between a first closed end 384 of container 373 and a second closed end 386 of container 373.
(83) Insulating member 375, which may be a block of expanded polystyrene or another similarly suitable material, may be disposed within cavity 381 of container 373. More specifically, insulating member 375 may be positioned at appropriately the midpoint of cavity 381 and may be oriented transversely to the length of cavity 381, with temperature-control members 377-1 and 377-2 being positioned in cavity 381 on one side of insulating member 375 and with members 377-3 and 377-4 being positioned in cavity 381 on the opposite side of insulating member 375.
(84) Temperature-control members 377-1 through 377-4 may be identical to one another and, in the present embodiment, are, in fact, identical to one another. Each of temperature-control members 377-1 through 377-4 may comprise a foam block impregnated with a quantity of water or a water-based phase-change material, the impregnated block being positioned within a suitable container, such as a pair of sealed polymer films. Members 377-1 through 377-4 may have a phase-change temperature of approximately 0° C. Also, it should be understood that, although members 377-1 through 377-4 are shown herein as four discrete members, one may join together members 377-1 and 377-2 and may join together members 377-3 and 377-4.
(85) Sleeves 371-2 through 371-4 may be identical to one another and, in the present embodiment, are, in fact, identical to one another. Sleeve 371-2, which is also shown separately in
(86) Each of the compartments of temperature-control member 381 may be thinner than each of temperature-control members 377-1 through 377-4. As such, there is more water or water-based phase-change material in each of sleeves 371-1 and 371-5 (for example, approximately 7 pounds of water per sleeve) than in each of sleeves 371-2 through 371-4 (for example, approximately 4 pounds of water per sleeve).
(87) As can readily be appreciated, because of the construction of sleeves 371-1 through 371-2, outer cassette 29-1 provides greater thermal protection at its four corners than elsewhere. This is by design as the greatest thermal weakness for the six walls is typically at their corners.
(88) It is to be understood that the number of sleeves in outer cassette 29-1 is merely illustrative. As such, one could increase or decrease the number of sleeves in outer cassette 29-1 without departing from the teachings of the present invention. In addition, it should be understood that, although each of sleeves 371-1 and 371-5 is described above as having a greater quantity of water or a water-based phase-change material than is present in each of sleeves 371-2, 371-3 and 371-4, all of sleeves 371-1 through 371-5 may be identical. Moreover, it should be understood that, although all of sleeves 371-1 through 371-5 are described above as having the same type of phase-change material, i.e., water, one could put different types of phase-change materials in different sleeves or in different portions of the same sleeve and could use a phase-change material having a different phase-change temperature.
(89) To prepare outer cassette 29-1 for use, sleeves 371-1 through 371-5 may be loaded into container 351, container 351 may be closed using assemblies 355-1 and 355-2, and outer cassette 29-1 may be pre-conditioned, as a unit, at a desired temperature, for example, at about −20° C. (Preferably, the pre-conditioning temperature for outer cassette 29-1 is below the temperature range that one wishes to maintain the payload.) However, depending on the application to which system 11 is to be put and depending on the composition of the sleeves to be used as a part of outer cassette 29-1, one may pre-condition different sleeves of outer cassette 29-1 at different temperatures and then load the differently pre-conditioned sleeves into container 351. (Alternatively, outer cassette 29-1 may be sealed shut to prevent sleeves 371-1 through 371-5 from being removed therefrom.) Outer cassettes 29-2 through 29-5 may be prepared in a similar fashion to outer cassette 29-1.
(90) Referring now to
(91) Although system 11 is particularly well-suited for use with a pallet-sized payload L, such as a 48″×40″×45″ payload, system 11 may nevertheless be used with a payload that is less than a full pallet-sized payload L.
(92) One may modify system 11 by eliminating inner cassettes 27-1 through 27-5 and/or by eliminating outer cassettes 29-1 through 29-5 or by eliminating one or more of inner cassettes 27-1 through 27-5 and/or by eliminating one or more outer cassettes 29-1 through 29-5 so that less than the full complement of inner cassettes 27 and outer cassettes 29 is used. Alternatively, one may also modify system 11 by replacing one or more of inner cassettes 27 with additional outer cassettes 29 or vice versa. Furthermore, one may also modify system 11 by positioning additional phase-change material, either in a cassette or otherwise, under the payload L, for example, between pallet P and bottom wall 15. As noted above, the above-described gelled organic phase-change material possess excellent compression strength and other attributes that make it particularly well-suited for being used in such a manner.
(93) One may also modify system 11 by providing one or more transverse openings in the top surfaces of the tracks of the top brackets and/or in the bottom surfaces of the tracks of the bottom brackets to promote the convection of air around the payload L. In addition, one may provide handles, whether integrally-formed or otherwise, on one or more of walls 15, 17, 19, 21, 23 and 25 to facilitate handling, particularly during assembly.
(94) It is presently envisioned that system 11 may be delivered to a customer as an unassembled kit comprising skid 13, bottom wall 15, front wall 17, rear wall 19, left wall 21, right wall 23, top wall 25, inner cassettes 27-1 through 27-5, and outer cassettes 29-1 through 29-5, that the customer will pre-condition the inner cassettes 27 and outer cassettes 29, and that the customer will then assemble system 11 and load its product into system 11. However, it is not beyond the realm of the present invention for inner cassettes 27 and outer cassettes 29 to be delivered to a customer in a disassembled state, with a variety of different types of sleeves provided to the customer that may be loaded into the inner and outer cassettes in different permutations. Moreover, it is not beyond the realm of the present invention for inner cassettes 27 and outer cassettes 29, whether delivered to a customer in an assembled state or disassembled state, to be used in combinations other than those disclosed above.
(95) Referring now to
(96) System 511 may be similar in most respects to system 11, the principal difference between the two systems being that system 511 may further comprise a pair of corner brackets 513-1 and 513-2 pivotally mounted on front wall 17 and/or may further comprise a corresponding pair of corner brackets (of which only corner bracket 515-1 is shown) pivotally mounted on rear wall 19. Corner brackets 513-1 and 513-2 (and the corresponding corner brackets on rear wall 19) may be appropriately constructed so that they may support the weight of its respective wall when the wall is pivoted outwardly, thereby enabling cassettes 27 and 29 to be loaded into the respective wall without requiring human intervention.
(97) Alternatively, in another embodiment (not shown), one may maintain front wall 17 and/or rear wall 19 in a pivoted state, for example, to permit the loading of cassettes 27 and 29 thereon, by fixedly attaching one end of a strap to the upper bracket of front wall 17 (or to rear wall 19) and by attaching a hook or similar device to the free end of the strap. Such a hook may then be inserted into an opening provided in the upper bracket of the left wall 21 or right wall 23.
(98) Referring now to
(99) System 611, which may be used to maintain a 48″×42″×45″ payload within a temperature range of +2° C. to +8° C. for an extended period of time, may comprise a skid 613, a bottom wall 615, a front wall 617, a rear wall 619, a left wall 621, a right wall 623, a top wall 625, a plurality of inner cassettes 627-1 through 627-3, a plurality of outer cassettes 629-1 through 629-3, a pair of side cassettes 630-1 and 630-2, and a pair of sleeves 631-1 and 631-2.
(100) Skid 613, bottom wall 615, front wall 617, rear wall 619, and top wall 625 may be identical to skid 13, bottom wall 15, front wall 17, rear wall 19, and top wall 25, respectively, of system 11. Left wall 621 and right wall 623 may be similar to left wall 21 and right wall 23, respectively, of system 11, except that each of left wall 621 and right wall 623 may comprise an upper bracket 641 and a lower bracket 643, wherein each of upper bracket 641 and lower bracket 643 may be shaped to define a single channel, as opposed to inner and outer channels. The aforementioned single channel is preferably located distal to the payload. In other words, brackets 641 and 643 effectively eliminate the inner cassette slot (used to receive an inner cassette) while retaining the outer cassette slot (used to receive an outer cassette).
(101) Inner cassettes 627-1 through 627-3, which may be removably mounted in the inner (i.e., more proximal to payload) slot of front wall 617, rear wall 619, and top wall 625, respectively, may be identical to one another and may be identical to inner cassettes 27-1 through 27-5 of system 11.
(102) Outer cassettes 629-1 through 629-3, which may be removably mounted in the outer slots (i.e., cassette-receiving spaces more distal to payload) of front wall 617, rear wall 619, and top wall 625, respectively, may be identical to one another and may be identical to outer cassettes 29-1 through 29-5 of system 11.
(103) Side cassettes 630-1 and 630-2, which may be removably mounted in the slots of left wall 621 and right wall 623, respectively, may be identical to one another and may be identical to outer cassettes 629-1 through 629-3 (although, as will be discussed further below, side cassettes 630-1 and 630-2 are typically preconditioned at a different temperature than are outer cassettes 629-1 through 629-3).
(104) Sleeves 631-1 and 631-2, which may be seated on top of upper brackets 641 of left wall 621 and right wall 623, respectively, may be identical to one another and may be similar to sleeve 205-2 of system 11, except that sleeves 631-1 and 631-2 may comprise a phase-change material having a phase-change temperature of approximately +5° C., instead of a phase-change material having a phase-change temperature of approximately +3° C. The phase-change material having a phase-change temperature of approximately +5° C. may be a gelled organic phase-change material of the type described above.
(105) System 611 may be assembled and used in a fashion similar to that described above for system 11, except that inner cassettes 627-1 through 627-3 may be preconditioned at about +5° C., outer cassettes 629-1 through 629-3 may be preconditioned at about −20° C., side cassettes 630-1 and 630-2 may be preconditioned at about +5° C., and sleeves 631-1 and 631-2 may be preconditioned at about −20° C.
(106) It is to be understood that system 611 may be modified by replacing left wall 621 and right wall 623 with left wall 21 and right wall 23, respectively, and by mounting side cassettes 630-1 and 630-2 in the outer slots (i.e., slots more distal to payload) of left wall 21 and right wall 23. However, modifying system 611 in the manner described above may reduce the size of a payload that may be accommodated by the system. It is also to be understood that, if desired, one may place additional phase-change material on bottom wall 615 under the pallet.
(107) Referring now to
(108) System 711, which may be used to maintain a 48″×42″×46″ payload within a temperature range of +2° C. to +8° C. for an extended period of time, may be similar in many respects to system 611. One difference between system 711 and system 611 may be that, whereas system 611 may comprise side cassettes 630-1 and 630-2, system 711 may comprise side cassettes 713-1 and 713-2, which may be identical to one another. Side cassette 713-1 is shown separately in
(109) System 711 may be assembled and used in a fashion similar to that described above for system 611, except that side cassettes 713-1 and 713-2 may be preconditioned at about −20° C.
(110) Referring now to
(111) System 811, which may be used to maintain a 48″×40″×45″ payload within a temperature range of +15° C. to +25° C. for an extended period of time, may comprise a skid 813, a bottom wall 815, a front wall 817, a rear wall 819, a left wall 821, a right wall 823, a top wall 825, a plurality of inner cassettes 827-1 through 827-5, and a plurality of outer cassettes 829-1 through 829-3.
(112) Skid 813, bottom wall 815, front wall 817, rear wall 819, left wall 821, right wall 823, and top wall 825 may be identical to skid 13, bottom wall 15, front wall 17, rear wall 19, left wall 21, right wall 23, and top wall 25, respectively, of system 11.
(113) Inner cassettes 827-1 through 827-5, which may be removably mounted in the inner slots (i.e., slots more proximal to payload) of front wall 817, rear wall 819, left wall 821, right wall 823 and top wall 825, respectively, may be identical to one another. Referring now to
(114) Referring back now to
(115) System 811 may be assembled and used in a fashion similar to that described above for system 11, except that inner cassettes 827-1 through 827-5 may be preconditioned at about +22° C. and outer cassettes 829-1 through 829-3 may be preconditioned at about +5° C. It is to be understood that, if desired, one may place additional phase-change material on bottom wall 815 under the pallet.
(116) Referring now to
(117) System 911, which may be used to maintain a 48″×40″×45″ payload at a temperature below −20° C. for an extended period of time, may comprise a skid 913, a bottom wall 915, a front wall 917, a rear wall 919, a left wall 921, a right wall 923, a top wall 925, a plurality of inner sleeves 927-1 through 927-12, a plurality of outer cassettes 929-1 through 929-4, and a tray 931.
(118) Skid 913, bottom wall 915, front wall 917, rear wall 919, left wall 921, right wall 923, and top wall 925 may be identical to skid 13, bottom wall 15, front wall 17, rear wall 19, left wall 21, right wall 23, and top wall 25, respectively, of system 11. (Top wall 925 may include alternative brackets to brackets 171 and 173 to facilitate the holding of tray 931. For example, such alternative brackets may jointly define a single slot.)
(119) Inner sleeves 927-1 through 927-3 may be removably mounted in the inner slot (i.e., the slot more proximal to payload) of front wall 917, inner sleeves 927-4 through 927-6 may be removably mounted in the inner slot of rear wall 919, inner sleeves 927-7 through 927-9 may be removably mounted in the inner slot of left wall 923, and inner sleeves 927-10 through 927-12 may be removably mounted in the inner slot of right wall 925. Inner sleeves 927-1, 927-3, 927-4, 927-6, 927-7, 927-9, 927-10 and 927-12 may be discrete members that may be identical to one another. Referring now to
(120) Outer cassettes 929-1 through 929-4, which may be removably mounted in the outer slots (i.e., slots more distal to payload) of front wall 917, rear wall 919, left wall 921, and right wall 923, respectively, may be identical to one another and may be identical to outer cassettes 29-1 through 29-5 of system 11.
(121) Tray 931, which may be removably disposed in a slot of top wall 925, may be a unitary structure shaped to define three identical contiguous sections 933-1 through 933-3. Each of sections 933-1 through 933-3 may have an open top and may be loaded with a quantity of pelletized dry ice. For example, each of sections 933-1 through 933-3 may contain approximately 91 lbs of pelletized dry ice.
(122) It is to be understood that, if desired, one may place additional phase-change material on bottom wall 915 under a pallet.
(123) System 911 may be assembled and used in a fashion generally similar to that described above for system 11, except that dry ice is preferably loaded into inner sleeves 927-1, 927-3, 927-4, 927-6, 927-7, 927-9, 927-10 and 927-12 and tray 931 soon before use. Outer cassettes 929-1 through 929-4 may be preconditioned at about −20° C. Consequently, it may be noted that the phase-change material in the outer slots (i.e., water) may be at a higher temperature than the phase-change material in the inner slots (i.e., dry ice).
(124) Referring now to
(125) System 1011 may be similar in most respects to system 911, the principal difference between the two systems being that, whereas system 911 may comprise outer cassettes 929-1 through 929-4, system 1011 may instead comprise insulation panels 1013-1 through 1013-4 removably mounted in the outer slots of front wall 915, rear wall 917, left wall 921 and right wall 923, respectively. Insulation panels 1013-1 through 1013-4 may be identical to one another and may comprise a cut sheet of expanded polystyrene having dimensions of 48″×40″×1.75″.
(126) System 1011 may be assembled and used in a fashion generally similar to that described above for system 911.
(127) Referring now to
(128) System 1111 may be similar in most respects to system 911, the principal difference between the two systems being that, whereas system 911 may comprise outer cassettes 929-1 through 929-4, system 1111 may omit outer cassettes 929-1 through 929-4 and may leave empty the outer slots of front wall 915, rear wall 917, left wall 921 and right wall 923.
(129) System 1111 may be assembled and used in a fashion generally similar to that described above for system 911.
(130) The embodiments of the present invention described above are intended to be merely exemplary and those skilled in the art shall be able to make numerous variations and modifications to it without departing from the spirit of the present invention. All such variations and modifications are intended to be within the scope of the present invention.