SELF-DRAINING SOLAR COLLECTOR SYSTEMS AND ASSOCIATED METHODS
20180195769 ยท 2018-07-12
Inventors
- Nathan Schuknecht (Golden, CO, US)
- David WHITE (Denver, CO, US)
- Patrick J. STOEVER (Denver, CO, US)
- Jennifer McDaniel (Arvada, CO, US)
Cpc classification
F24S23/74
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F24S40/60
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02E10/40
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
Abstract
A self-draining solar collector system includes one or more solar collector assemblies, a manifold connecting assembly, and a crossover connecting assembly. Each solar collector assembly includes a collector support subsystem, one or more heating pipes, and one or more parabolic reflectors. The manifold connecting assembly connects the heating pipes of each solar collector assembly to a manifold disposed at a lower elevation than the heating pipes of the solar collector assemblies when the solar collector assemblies are oriented in respective draining positions. The crossover connecting assembly connects the heating pipes of each solar collector assembly to a crossover pipe disposed at a higher elevation than the heating pipes of the solar collector assemblies when the solar collector assemblies are oriented in their respective draining positions.
Claims
1. A self-draining solar collector system, comprising: one or more solar collector assemblies, each solar collector assembly including a collector support subsystem, one or more heating pipes, and one or more parabolic reflectors, the one or more parabolic reflectors and the one or more heating pipes of each solar collector assembly configured to rotate with respect to the collector support subsystem of the solar collector assembly; a manifold connecting assembly connecting the one or more heating pipes of each of the one or more of solar collector assemblies to a manifold disposed at a lower elevation than the one or more heating pipes of the one or more solar collector assemblies when the one or more solar collector assemblies are oriented in respective draining positions, the manifold connecting assembly configured to have a downward slope toward the manifold to allow fluid within the one or more heating pipes of the one or more solar collector assemblies to gravitationally drain into the manifold when the one or more solar collector assemblies are oriented in their respective draining positions; and a crossover connecting assembly connecting the one or more heating pipes of each of the one or more solar collector assemblies to a crossover pipe disposed at a higher elevation than the one or more heating pipes of the one or more solar collector assemblies when the one or more solar collector assemblies are oriented in their respective draining positions, the crossover connecting assembly configured to have a downward slope toward the one or more heating pipes of the one or more solar collector assemblies to allow fluid within the crossover pipe to gravitationally drain into the one or more heating pipes of the one or more solar collector assemblies when the one or more solar collector assemblies are oriented in their respective draining positions.
2. The self-draining solar collector system of claim 1, wherein the crossover connecting assembly has a different structural configuration than the manifold connecting assembly.
3. The self-draining solar collector system of claim 1, the crossover connecting assembly comprising (a) a crossover end pipe and (b) a flexible crossover hose connected between the crossover end pipe and the crossover pipe.
4. The self-draining solar collector system of claim 3, further comprising a crossover flexible expansion hose connected between the crossover end pipe and the one or more heating pipes of the one or more solar collector assemblies.
5. The self-draining solar collector system of claim 1, the manifold connecting assembly comprising a flexible manifold hose connected between the manifold and the one or more heating pipes of the one or more solar collector assemblies.
6. The self-draining solar collector system of claim 1, the manifold connecting assembly comprising (a) a rotary joint connected to the manifold and (b) a flexible manifold hose connected between the rotary joint and the one or more heating pipes of the one or more solar collector assemblies.
7. The self-draining solar collector system of claim 1, the crossover connecting assembly comprising (a) one or more crossover spherical joint connectors connected to the crossover pipe and (b) a spherical joint crossover end pipe connected between the one or more crossover spherical joint connectors and the one or more heating pipes of the one or more solar collector assemblies.
8. The self-draining solar collector system of claim 1, the manifold connecting assembly comprising (a) one or more manifold spherical joint connectors connected to the manifold and (b) a manifold end pipe connected between the one or more manifold spherical joint connectors and the one or more heating pipes of the plurality of solar collector assemblies.
9. The self-draining solar collector system of claim 1, the one or more solar collector assemblies comprising a plurality of solar collector assemblies, the self-draining solar collector system further comprising one or more shared connecting assemblies connecting the one or more heating pipes of adjacent ones of the plurality of solar collector assemblies such that the one or more heating pipes of the plurality of solar collector assemblies are connected in series, each shared connecting assembly configured to allow fluid within the one or more heating pipes of the plurality of solar collector assemblies to drain into the manifold when the plurality of solar collector assemblies are oriented in respective draining positions.
10. The self-draining solar collector system of claim 9, each of the one or more the shared connecting assemblies capable of being changed between a normal operating mode and a draining operating mode.
11. The self-draining solar collector system of claim 10, wherein each of the one or more shared connecting assemblies comprises: a shared pipe; and first and second flexible shared hoses each having proximal and distal ends, proximal ends of each of the first and second flexible shared hoses being connected to respective ends of the shared pipe, and distal ends of each of the first and second flexible shared hoses being connected to respective heating pipes of the plurality solar collector assemblies.
12. The self-draining solar collector system of claim 11, each of the one or more shared connecting assemblies further comprising a clamping subsystem configured to: secure the shared pipe of the shared connecting assembly to a pipe support having a fixed position with respect to the one or more heating pipes of the plurality of solar collector assemblies, in the normal operating mode of the shared connecting assembly; and secure each of the first and second shared flexible hoses of the shared connecting assembly to respective rotation supports, in the draining operating mode of the shared connecting assembly.
13. The self-draining solar collector system of claim 11, each of the one or more shared connecting assemblies further comprising a mode changing subsystem configured to change the operating mode of the shared connecting assembly between its normal operating mode and its draining operating mode.
14. The self-draining solar collector system of claim 10 wherein each of the one or more shared connecting assemblies comprises: one or more shared spherical joint connectors; and first and second spherical joint shared pipes each having proximal and distal ends, proximal ends of each of the first and second spherical joint shared pipes being connected to the one or more shared spherical joint connectors, and distal ends of each of the first and second spherical joint shared pipes being connected to respective heating pipes of the plurality of solar collector assemblies.
15. The self-draining solar collector system of claim 14, wherein the one or more shared spherical joint connectors are collinear with rotational axes of the parabolic reflectors of each of the plurality of solar collector assemblies.
16. The self-draining solar collector system of claim 1, each of the one or more of solar collector assemblies further including a tracking subsystem configured to rotate the one or more parabolic reflectors and the one or more heating pipes of the solar collector assembly with respect to the collector support subsystem of the solar collector assembly, to track an incident light source and reflect light from the incident light source onto the one or more heating pipes of the one or more solar collector assemblies.
17. A self-draining solar collector system, comprising: a plurality of solar collector assemblies, each solar collector assembly including a collector support subsystem, one or more heating pipes, and one or more parabolic reflectors, the one or more parabolic reflectors and the one or more heating pipes of each solar collector assembly configured to rotate with respect to the collector support subsystem of the solar collector assembly; and one or more shared connecting assemblies connecting the one or more heating pipes of adjacent ones of the plurality of solar collector assemblies such that the one or more heating pipes of the plurality of solar collector assemblies are connected in series, each shared connecting assembly capable of being changed between a normal operating mode and a draining operating mode, each shared connecting assembly configured to allow fluid within the one or more heating pipes of the plurality of solar collector assemblies to drain into a manifold when the plurality of solar collector assemblies are oriented in respective draining positions and each shared connected assembly is operating in its draining operating mode.
18. The self-draining solar collector system of claim 17, wherein each of the one or more shared connecting assemblies comprises: a shared pipe; and first and second flexible shared hoses each having proximal and distal ends, proximal ends of each of the first and second flexible shared hoses being connected to respective ends of the shared pipe, and distal ends of each of the first and second flexible shared hoses being connected to respective heating pipes of the plurality of solar collector assemblies.
19. The self-draining solar collector system of claim 18, each of the plurality of shared connecting assemblies further comprising a clamping subsystem configured to: secure the shared pipe to a pipe support having a fixed position with respect to the one or more heating pipes of the plurality of collector assemblies, in the normal operating mode of the shared connecting assembly; and secure each of the first and second shared flexible hoses to respective rotation supports, in the draining operating mode of the shared connecting assembly.
20. The self-draining solar collector system of claim 17, each of the one or more shared connecting assemblies further comprising a mode changing subsystem configured to change the operating mode of the shared connecting assembly between its normal operating mode and its draining operating mode.
21. A method for operating a self-draining solar collector system, comprising the steps of: (a) rotating one or more parabolic reflectors and respective heating pipes of each of one or more solar collector assemblies to track an incident light source; (b) rotating the one or more parabolic reflectors and the respective heating pipes of each of the one or more of solar collector assemblies to respective draining positions such that a manifold is at a lower elevation and a crossover pipe is at a higher elevation than the one or more heating pipes of the one or more solar collector assemblies; and (c) opening a purge valve in the crossover pipe.
22. The method of claim 21, step (a) comprising rotating the one or more parabolic reflectors and the respective heating pipes of each of the one or more solar collector assemblies independently of the one or more parabolic reflectors and the respective heating pipes of each other one of the one or more solar collector assemblies.
23. The method of claim 22, further comprising, after step (a) but before step (b), changing an operating mode of a shared connecting assembly connected between the one or more heating pipes of a first one of the one or more solar collector assemblies and the one or more heating pipes of a second one of the one or more solar collector assemblies from a normal operating mode to a draining operating mode.
24. The method of claim 23, the step of changing the operating mode of the shared connecting assembly comprising: freeing a shared pipe of the shared connecting assembly from a pipe support having a fixed position with respect to the one or more heating pipes of the one or more solar collector assemblies; and securing each of first and second shared flexible hoses of the shared connecting assembly to respective rotation supports of the plurality of solar collector assemblies.
25. A method for maintaining a self-draining solar collector system comprising executing the method of claim 21 at least once per day.
26. A self-draining solar collector system, comprising: one or more solar collector assemblies, each solar collector assembly including a collector support subsystem, one or more heating pipes, and one or more parabolic reflectors, the one or more parabolic reflectors and the one or more heating pipes of each solar collector assembly configured to rotate with respect to the collector support subsystem of the solar collector assembly; a manifold connecting assembly connecting the one or more heating pipes of each of the plurality of solar collector assemblies to a manifold disposed at a lower elevation than rotational axes of the one or more parabolic reflectors of the one or more solar collector assemblies; and a crossover connecting assembly connecting the one or more heating pipes of each of the one or more solar collector assemblies to a crossover pipe disposed at a higher elevation than the rotational axes of the one or more parabolic reflectors of the one or more solar collector assemblies; wherein the crossover connecting assembly has a different structural configuration than the manifold connecting assembly.
27. The self-draining solar collector system of claim 26, the crossover connecting assembly comprising (a) a crossover end pipe and (b) a flexible crossover hose connected between the crossover end pipe and the crossover pipe.
28. The self-draining solar collector system of claim 27, further comprising a crossover flexible expansion hose connected between the crossover end pipe and the one or more solar collector assemblies.
29. The self-draining solar collector system of claim 26, the manifold connecting assembly comprising a flexible manifold hose connected between the manifold and the one or more solar collector assemblies.
30. The self-draining solar collector system of claim 26, the manifold connecting assembly comprising (a) a rotary joint connected to the manifold and (b) a flexible crossover hose connected between the rotary joint and the one or more heating pipes of the one or more solar collector assemblies.
31. The self-draining solar collector system of claim 26, the crossover connecting assembly comprising (a) one or more crossover spherical joint connectors connected to the crossover pipe and (b) a spherical joint crossover end pipe connected between the one or more crossover spherical joint connectors and the one or more solar collector assemblies.
32. The self-draining solar collector system of claim 26, the manifold connecting assembly comprising (a) one or more manifold spherical joint connectors connected to the manifold and (b) a manifold end pipe connected between the one or more manifold spherical joint connectors and the plurality of solar collector assemblies.
33. The self-draining solar collector system of claim 26, the one or more solar collector assemblies comprising a plurality of solar collector assemblies, the self-draining solar collector system further comprising one or more shared connecting assemblies connecting the one or more heating pipes of adjacent ones of the plurality of solar collector assemblies such that the one or more heating pipes of the plurality of solar collector assemblies are connected in series, each of the one or more shared connecting assemblies having a different structural configuration than each of the manifold connecting assembly and the crossover connecting assembly.
34. The self-draining solar collector system of claim 33, wherein each of the one or more shared connecting assemblies comprises: a shared pipe; and first and second flexible shared hoses each having proximal and distal ends, proximal ends of each of the first and second flexible shared hoses being connected to respective ends of the shared pipe, and distal ends of each of the first and second flexible shared hoses being connected to respective heating pipes of the plurality of solar collector assemblies.
35. The self-draining solar collector system of claim 33, wherein each of the one or more shared connecting assemblies comprises: one or more shared spherical joint connectors; and first and second spherical joint shared pipes each having proximal and distal ends, proximal ends of each of the first and second spherical joint shared pipes being connected to the one or more shared spherical joint connectors, and distal ends of each of the first and second spherical joint shared pipes being connected respective heating pipes of the plurality of solar collector assemblies.
36. The self-draining solar collector system of claim 35, wherein the one or more shared spherical joint connectors are collinear with the rotational axes of the parabolic reflectors of each of the plurality of solar collector assemblies.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
[0051] In general the terms and phrases used herein have their art-recognized meaning, which can be found by reference to standard texts, journal references and contexts known to those skilled in the art.
[0052] Referring to the drawings, like numerals indicate like elements and the same number appearing in more than one drawing refers to the same element. In addition, hereinafter, the following definitions apply:
[0053] The term fluid includes fluid that is within the heating pipes of the solar collector assemblies. The fluid is also known in the art as a working fluid or heat transfer fluid (HTF). The fluid may be in the liquid phase. The fluid is, for example, water, steam, oil, or molten salt. Molten salt refers to a salt that is in a liquid phase, and is typically, but not necessarily, at temperatures above room temperature. Salt refers to any ionic chemical compound. Non-restrictive examples of molten salts include sodium nitrate, potassium nitrate, calcium nitrate and various combinations thereof.
[0054] The term gravitationally, in the context of a fluid flowing or being drained, includes a fluid moving (flowing or draining) under the influence of gravity. The term drain or drained includes fluid flowing out the system, wherein the system in question is a solar collector assembly, for example.
[0055] The term substantially elevated above refers to a majority of the length of pipes and/or hoses of a connecting assembly being elevated above an item or items in question, such as a heating pipe.
[0056] The term downward slope as used in the context of piping or an assembly, such as the manifold connecting assembly and the crossover connecting assembly, being configured to have a downward slope refers to said assembly being configured such that fluid contained in said assembly flows downward (i.e., to a lower elevation with respect to the ground). An assembly which is configured to have a downward slope may have one or more portions (e.g., pipe or hose) that are perpendicular to the ground level while still allowing a fluid contained in said assembly to flow downward. An assembly which is configured to have a downward slope may have one or more portions (e.g., pipe or hose) oriented at an angle (i.e., not parallel) with respect to the ground level. An assembly which is configured to have a downward slope may allow a fluid to drain from said assembly with negligible or no pooling of said fluid at any region within the assembly.
[0057] The term normal operating mode, in the context of a self-draining solar collector system and its constituent elements, refers to an operating mode where the self-draining solar collector system is intended to transport, circulate and/or heat a fluid, such as a working fluid or heat transfer fluid. In certain embodiments, normal operating mode refers to an operating mode for power generation via using a concentrating solar power system.
[0058] The term draining operating mode, in the context of a self-draining solar collector system and its constituent elements, refers to an operating mode where the self-draining solar collector system is intended to be partially or fully drained, for example, via the transfer, removal and/or storage of a heat transfer material, such as working fluid or heat transfer fluid.
[0059] The term draining position, in the context of a solar collector assembly and its constituent elements, refers to a configuration of the solar collector assembly during draining operating mode, such as a configuration wherein one or more parabolic reflectors and respective heating pipe(s) are rotated to respective draining positions wherein a manifold is at a lower elevation and a crossover pipe is at a higher elevation than the one or more heating pipes of a solar collector assemblies.
[0060] Without wishing to be bound by any particular theory, there may be discussion herein of beliefs or understandings of underlying principles relating to the devices and methods disclosed herein. It is recognized that regardless of the ultimate correctness of any mechanistic explanation or hypothesis, an embodiment of the invention can nonetheless be operative and useful.
[0061] This invention provides self-draining solar collector systems, including solar collector assemblies with parabolic reflectors, that can be drained gravitationally into a manifold without the need for collection vessels at intermediate points, such as in between solar collector assemblies. This invention further provides methods for gravitationally draining a self-draining solar collector system. In an embodiment, the manifold includes pipes for supply (e.g., cold) and return (e.g., hot) HTF. The solar collector systems may be drained automatically and gravitationally from a control room or with manual opening of a valve (e.g., a purge valve) located at each crossover pipe, in particular embodiments. As a result, personnel exposure to the high temperature fluids is minimized or eliminated during draining. Use of certain embodiments of the self-draining solar collector systems helps reduce operational costs of a solar thermal power plant, which employs parabolic reflectors and high temperature fluids, while also potentially making frequent draining of the solar collector assemblies economically viable.
[0062] Frequent draining may be advantageous for solar thermal power plants that use high-temperature fluids, such as molten salt, to reduce heat loss during periods of inactivity. Periods of inactivity may occur due to weather related events, seasonal shutdowns, maintenance events, or night.
[0063] Certain embodiments of the self-draining solar collector systems include connecting assemblies with pipes and/or flexible hoses and spherical and/or rotary joint connectors. However, the connection assemblies of the present systems are not limited to the particular illustrated embodiments. For example, spherical joint connectors (e.g., 312, 422, or 532 of
[0064] In certain embodiments of the self-drawing solar collector systems, the following three distinct locations have different structural configurations of pipes and/or hoses: (1) the manifold (i.e., manifold connecting assembly), (2) in between adjacent solar collector assemblies or parabolic reflectors (i.e., shared connecting assembly), and (3) at the crossover (i.e., crossover connecting assembly). Fluid (e.g., HTF) may be drained from the system of solar collector assemblies gravitationally in certain embodiments. Gravitational draining is achieved because the crossover pipe is located at an elevation higher than the heating pipe(s) of the solar collector assemblies and the manifold is located at an elevation lower than the heating pipe(s) of the solar collector assemblies, at least when the solar collector assemblies are oriented in respective draining positions. Additionally, particular embodiments of the self-draining solar collector systems disclosed herein minimize fluid pooling (i.e., collection of fluid) in the pipes and/or hoses during draining, including in the manifold, shared, and crossover connecting assemblies.
[0065] The manifold connecting assembly has a general downward slope toward the manifold pipes and no fluid-containing pipe or hose of the manifold connecting assembly is substantially elevated above the heating pipe(s) during draining operating mode, thereby allowing fluid to drain from the heating pipes gravitationally without pooling. Significant pooling of fluid within the pipes and/or hoses of the crossover connecting assembly is also prevented because no fluid-containing pipes or hoses are substantially elevated above the crossover pipe during draining operating mode, and there is a general downward slope of the crossover connecting assembly from each crossover pipe to the respective heating pipe(s) of each respective solar collecting assembly. Also, during draining operating mode, no fluid-containing pipes and/or hoses of the shared connecting assemblies are substantially elevated above or below the heating pipes, or the rotational axes of the parabolic reflectors, of the respective solar collector assemblies (i.e., on either side of the shared connecting assembly). In some embodiments, while in a normal operating mode, any two parabolic reflectors, with respective heating pipe(s), or solar collector assemblies may rotate independently about a rotation axis to track incident light (e.g., sunlight). Certain embodiments of the systems provided herein also allow one or more of the pipes and/or hoses of the shared connecting assemblies to rotate together with the parabolic reflectors, with respective heating pipe(s), or solar collector assemblies, instead of being fixed to a pylon (i.e., an upright fixed and stationary support structure), to achieve a draining operating mode.
[0066] In some embodiments, where a connection is made between a crossover pipe and a solar collector assembly that is farthest from the manifold (i.e., last solar collector assembly), the flexible pipe is connected to the parabolic reflector at a location that is on the opposite side of the rotational axis from the heating pipe. It rotates through a path that opposes the path of the heating pipe, and is connected to the crossover connecting assembly at a location above the rotational axis of the parabolic reflector.
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[0068] Self-draining solar collector system 100 includes of one or more rows 101 of solar collector assemblies 102, which include one or more solar collector assemblies 102, one or more shared connecting assemblies 116, a crossover connecting assembly 118, and a manifold connecting assembly 114. Rows 101 (e.g., 101(1) and 101(2)), illustrated in
[0069] In the example of
[0070] In normal operating mode, in the embodiment illustrated in
[0071] In draining operating mode, parabolic reflectors 113 and heating pipes 112 of each solar collector assembly 102 are rotated to respective draining positions whereby crossover pipe 128 is at a higher elevation than heating pipes 112 and shared connecting assemblies 116, and whereby manifold 121 (i.e., manifold pipes 122, 124) are at a lower elevation than heating pipes 112 and shared connecting assemblies 116. Consequently, manifold connecting assemblies 114 are configured to have a downward slope toward manifold 121 in the draining operating mode to allow fluid within heating pipes 112 to gravitationally drain into manifold 112. Additionally, crossover connecting assemblies 118 are configured to have a downward slope toward heating pipes 112 in the draining operating mode to allow fluid within crossover pipe 128 to drain into heating pipes 112. Additionally, shared connecting assemblies 116 are configured in the draining operating mode to allow fluid within heating pipe(s) 112 of one respective solar collector assembly 102 to drain into heating pipe(s) 112 of another respective solar collector assembly 102, such that fluid within heating pipes 112 drains into manifold 112.
[0072] For example, the parabolic reflectors are rotated, about their rotation axis 120, to a substantially horizontal draining position as illustrated in
[0073] Manifold, shared, and crossover connecting assemblies (114, 116, and 118, respectively) may have a variety of configurations without departing from the scope hereof. For example,
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Statements Regarding Variations
[0086] All references throughout this application, for example patent documents including issued or granted patents or equivalents; patent application publications; and non-patent literature documents or other source material; are hereby incorporated by reference herein in their entireties, as though individually incorporated by reference, to the extent each reference is at least partially not inconsistent with the disclosure in this application (for example, a reference that is partially inconsistent is incorporated by reference except for the partially inconsistent portion of the reference).
[0087] Having now fully described the present invention in some detail by way of illustration and examples for purposes of clarity of understanding, it will be clear to one of ordinary skill in the art that the same can be performed by modifying or changing the invention within a wide and equivalent range of conditions, formulations and other parameters without affecting the scope of the invention or any specific embodiment thereof, and that such modifications or changes are intended to be encompassed within the scope of the appended claims.
[0088] The terms and expressions which have been employed herein are used as terms of description and not of limitation, and there is no intention in the use of such terms and expressions of excluding any equivalents of the features shown and described or portions thereof, but it is recognized that various modifications are possible within the scope of the invention claimed. Thus, it should be understood that although the present invention has been specifically disclosed by preferred embodiments, exemplary embodiments and optional features, modification and variation of the concepts herein disclosed may be resorted to by those skilled in the art, and that such modifications and variations are considered to be within the scope of this invention as defined by the appended claims. The specific embodiments provided herein are examples of useful embodiments of the present invention and it will be apparent to one skilled in the art that the present invention may be carried out using a large number of variations of the devices, device components, methods steps set forth in the present description. Methods and devices useful for the present methods can include a large number of optional composition and processing elements and steps.
[0089] When a group of substituents is disclosed herein, it is understood that all individual members of that group and all subgroups are disclosed separately. When a Markush group or other grouping is used herein, all individual members of the group and all combinations and subcombinations possible of the group are intended to be individually included in the disclosure.
[0090] It must be noted that as used herein and in the appended claims, the singular forms a, an, and the include plural reference unless the context clearly dictates otherwise. Thus, for example, reference to a heating pipe includes a plurality of such heating pipes and equivalents thereof known to those skilled in the art, and so forth. As well, the terms a (or an), one or more and at least one can be used interchangeably herein. It is also to be noted that the terms comprising, including, and having can be used interchangeably. The expression of any of claims XX-YY (wherein XX and YY refer to claim numbers) is intended to provide a multiple dependent claim in the alternative form, and in some embodiments is interchangeable with the expression as in any one of claims XX-YY.
[0091] Although any methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present invention, the preferred methods and materials are now described. Nothing herein is to be construed as an admission that the invention is not entitled to antedate such disclosure by virtue of prior invention.
[0092] When a group of substituents is disclosed herein, it is understood that all individual members of that group and all subgroups, are disclosed separately. When a Markush group or other grouping is used herein, all individual members of the group and all combinations and subcombinations possible of the group are intended to be individually included in the disclosure. For example, when a device is set forth disclosing a range of materials, device components, and/or device configurations, the description is intended to include specific reference of each combination and/or variation corresponding to the disclosed range.
[0093] Every combination of components described or exemplified herein can be used to practice the invention, unless otherwise stated.
[0094] Whenever a range is given in the specification, for example, a temperature range, a time range, or a composition or concentration range, all intermediate ranges and subranges, as well as all individual values included in the ranges given are intended to be included in the disclosure. As used herein, ranges specifically include the values provided as endpoint values of the range. For example, a range of 1 to 100 specifically includes the end point values of 1 and 100. It will be understood that any subranges or individual values in a range or subrange that are included in the description herein can be excluded from the claims herein.
[0095] As used herein, comprising is synonymous with including, containing, or characterized by, and is inclusive or open-ended and does not exclude additional, unrecited elements or method steps. As used herein, consisting of excludes any element, step, or ingredient not specified in the claim element. As used herein, consisting essentially of does not exclude materials or steps that do not materially affect the basic and novel characteristics of the claim. In each instance herein any of the terms comprising, consisting essentially of and consisting of may be replaced with either of the other two terms.
[0096] One of ordinary skill in the art will appreciate that device elements and combinations of components other than those specifically exemplified can be employed in the practice of the invention without resort to undue experimentation. All art-known functional equivalents, of any such materials and methods are intended to be included in this invention. The terms and expressions which have been employed are used as terms of description and not of limitation, and there is no intention that in the use of such terms and expressions of excluding any equivalents of the features shown and described or portions thereof, but it is recognized that various modifications are possible within the scope of the invention claimed. Thus, it should be understood that although the present invention has been specifically disclosed by preferred embodiments and optional features, modification and variation of the concepts herein disclosed may be resorted to by those skilled in the art, and that such modifications and variations are considered to be within the scope of this invention as defined by the appended claims.