Anionic surfactant compositions and use thereof

Abstract

Provided are surfactant compositions that are useful as alternatives to alkylphenol ethoxylates (APEs) type surfactants in emulsion polymerization. The surfactant compositions comprise: an alkyl alkoxylate sulfate of formula (I): R.sup.1O(CH.sub.2CH(R.sup.2)O).sub.x(CH.sub.2CH.sub.2O).sub.ySO.sub.3M wherein R.sup.1, R.sup.2, x, y, and M are as defined herein.

Claims

1. A surfactant composition comprising an alkyl alkoxylate sulfate of formula I:
R.sup.1O(CH.sub.2CH(R.sup.2)O).sub.x(CH.sub.2CH.sub.2O).sub.ySO.sub.3M(I) wherein R.sup.1 is linear or branched C.sub.4-C.sub.10 alkyl; R.sup.2 is CH.sub.3 or CH.sub.3CH.sub.2; x is a real number from 1to 11; y is a real number from 1 to 20; and M is an alkali metal or NH.sub.4; the surfactant composition further comprising a nonionic alkyl alkoxylate of formula II:
R.sup.1O(CH.sub.2CH(R.sup.2)O).sub.x(CH.sub.2CH.sub.2O).sub.yH(II) wherein R.sup.1 is linear or branched C.sub.4-C.sub.10 alkyl; R.sup.2 is CH.sub.3 or CH.sub.3CH.sub.2; x is a real number from 1 to 11; and y is a real number from 1 to 20.

2. The surfactant composition of claim 1 further comprising water, and wherein the amount of the alkyl alkoxylate sulfate of formula I is from 20 to 70% by weight, the amount of the nonionic alkyl alkoxylate of formula II is from 1 to 30% by weight, and the amount of water is from 25 to 75% by weight, based on the total weight of the anionic alkoxylate of formula I, the nonionic alkyl alkoxylate of formula II, and the water.

3. The surfactant composition of claim 1 or 2 wherein R.sup.1 in formula I and formula II is independently linear or branched C.sub.6-C.sub.10 alkyl.

4. The surfactant composition of claim 1, wherein R.sup.1 in formula I and formula II is independently 2-ethylhexyl or 2-propylheptyl.

5. The surfactant composition of claim 1, wherein x in formula I and formula II is independently from 4 to 6.

6. The surfactant composition of claim 1, wherein y in formula I and formula II is independently from 1 to 11.

7. The surfactant composition of claim 1, that is present in an emulsion polymerization formulation.

8. A method of use of the surfactant composition of claim 1, comprising: forming a styrene-butyl acrylate emulsion; and adding the surfactant composition of claim 1 to the styrene-butyl acrylate emulsion as an emulsifier for emulsion polymerization.

Description

BRIEF DESCRIPTION OF THE FIGURES

(1) FIG. 1 is plot showing foaming properties for an inventive emulsion according to one embodiment of the invention (Emulsion 1) and a comparative emulsion (Emulsion 2).

(2) FIG. 2 is plot showing foaming properties for an inventive emulsion according to one embodiment of the invention (Emulsion 3) and comparative emulsions (Emulsions 4 and 5).

(3) FIG. 3 is plot showing foaming properties for an inventive emulsion according to one embodiment of the invention (Emulsion 6) and a comparative emulsion (Emulsion 4).

(4) FIG. 4 is plot showing foaming properties for an inventive emulsion according to one embodiment of the invention (Emulsion 7) and a comparative emulsion (Emulsion 8).

DETAILED DESCRIPTION

(5) Unless otherwise indicated, numeric ranges, for instance as in from 2 to 10, are inclusive of the numbers defining the range (e.g., 2 and 10).

(6) Unless otherwise indicated, ratios, percentages, parts, and the like are by weight.

(7) As noted above, the invention provides a surfactant composition comprising an alkyl alkoxylate sulfate of formula I. The surfactant composition exhibits several useful properties, including one or more of good surface tension reduction, low foam and quick foam collapse, rapid wetting, and calcium ion stability. The advantageous properties render the surfactant composition suitable as an emulsifier for emulsion polymerization.

(8) The alkyl alkoxylate sulfate is of the following formula I:
R.sup.1O(CH.sub.2CH(R.sup.2)O).sub.x(CH.sub.2CH.sub.2O).sub.ySO.sub.3M(I)
wherein R.sup.1 is linear or branched C.sub.4-C.sub.10 alkyl; R.sup.2 is CH.sub.3 or CH.sub.3CH.sub.2; x is a real number from 1 to 11; y is a real number from 1 to 20; and M is an alkali metal or NH.sub.4.

(9) In some embodiments, R.sup.1 in formula I is linear or branched C.sub.6-C.sub.10 alkyl, alternatively linear or branched C.sub.8-C.sub.10 alkyl. In some embodiments, R.sup.1 is 2-ethylhexyl (CH.sub.3CH.sub.2CH.sub.2CH.sub.2CH(CH.sub.2CH.sub.3)CH.sub.2). In some embodiments, R.sup.1 is 2-propylheptyl (CH.sub.3CH.sub.2CH.sub.2CH.sub.2CH.sub.2CH(CH.sub.2CH.sub.2CH.sub.3)CH.sub.2).

(10) In some embodiments, R.sup.2 in formula I is CH.sub.3. In some embodiments, R.sup.2 is CH.sub.3CH.sub.2.

(11) In some embodiments, x in formula I is from 4 to 6.

(12) In some embodiments, y in formula I is from 1 to 11, alternatively from 3 to 11.

(13) In some embodiments, M in formula I is sodium, potassium, or ammonium. In some embodiments, M is sodium or ammonium.

(14) In some embodiments, in addition to the alkyl alkoxylate sulfate of formula I, the surfactant composition of the invention also comprises a nonionic alkyl alkoxylate of formula II:
R.sup.1O(CH.sub.2CH(R.sup.2)O).sub.x(CH.sub.2CH.sub.2O).sub.yH(II)
wherein R.sup.1 is linear or branched C.sub.4-C.sub.10 alkyl; R.sup.2 is CH.sub.3 or CH.sub.3CH.sub.2; x is a real number from 1 to 11; and y is a real number from 1 to 20.

(15) In some embodiments, R.sup.1 in formula II is linear or branched C.sub.6-C.sub.10 alkyl, alternatively linear or branched C.sub.8-C.sub.10 alkyl. In some embodiments, R.sup.1 is 2-ethylhexyl (CH.sub.3CH.sub.2CH.sub.2CH.sub.2CH(CH.sub.2CH.sub.3)CH.sub.2). In some embodiments, R.sup.1 is 2-propylheptyl (CH.sub.3CH.sub.2CH.sub.2CH.sub.2CH.sub.2CH(CH.sub.2CH.sub.2CH.sub.3)CH.sub.2).

(16) In some embodiments, R.sup.2 in formula II is CH.sub.3. In some embodiments, R.sup.2 is CH.sub.3CH.sub.2.

(17) In some embodiments, x in formula II is from 4 to 6.

(18) In some embodiments, y in formula II is from 1 to 11, alternatively from 3 to 11.

(19) When the nonionic alkyl alkoxylate of formula II is present in the surfactant composition, the groups R.sup.1, R.sup.2, x, and y in formula I and formula II may be the same or different. In some embodiments, the groups R.sup.1, R.sup.2, x, and y in formula I and formula II are the same.

(20) In some embodiments, the surfactant composition of the invention comprises an alkyl alkoxylate sulfate of formula I and a nonionic alkyl alkoxylate of formula II, wherein the weight ratio of the alkyl alkoxylate sulfate of formula Ito the nonionic alkyl alkoxylate of formula II is from 99:1 to 10:90. In some embodiments, the weight ratio is from 95:5 to 50:50, alternatively from 90:10 to 70:30.

(21) In some embodiments, the surfactant composition of the invention further comprises water.

(22) In some embodiments, the surfactant composition of the invention comprises an alkyl alkoxylate sulfate of formula I, a nonionic alkyl alkoxylate of formula II, and water. In some embodiments, the amount of the alkyl alkoxylate sulfate of formula I is from 20 to 70% by weight, preferably from 30 to 60% by weight; the amount of the alkoxylate of formula II is from 0.1 to 30% by weight, preferably from 0.1 to 10% by weight; and the amount of water is from 25 to 75% by weight, preferably from 40 to 70% by weight, based on the total weight of the alkyl alkoxylate sulfate of formula I, the nonionic alkyl alkoxylate of formula II, and the water.

(23) The surfactant composition of the invention may comprise additional additives, such as other surfactants/emulsifiers, and other additives commonly use in emulsion polymerization. In some embodiments, the surfactant composition of the invention further comprises a nonionic surfactant of the formula III: R.sup.3O(AO).sub.zH (III), wherein R.sup.3 is linear or branched C.sub.6-C.sub.24 alkyl, AO at each occurrence is ethyleneoxy, propyleneoxy, butyleneoxy, or random or block mixtures thereof, and z is from 1 to 50.

(24) The surfactant compositions of the invention exhibit good surface tension reduction, low foam and quick foam collapse, rapid wetting, and they provide formulation stability properties, including good Ca.sup.2+ stability. Ca.sup.2+ stability may be understood as the tolerance of an emulsion to electrolytes. In downstream application, numerous additives may be mixed with an emulsion, thus, a good Ca.sup.2+ stability indicates a good formulation stability. As a result of these properties, the surfactant compositions are suitable for use as emulsifiers in emulsion polymerization and indeed may be used as replacements for traditional APE based emulsifiers.

(25) The emulsions in which the surfactant compositions of the invention may be used as emulsifiers are typically aqueous emulsions or dispersions of polymers and/or copolymers which are normally obtainable by emulsion polymerization. There are no particular restrictions as to the nature of the polymers and copolymers in these formulations. Polymers or copolymers based on the following monomer units are preferred: acrylic acid, acrylates, butadiene, methacrylic acid, methacrylates, styrene, and vinyl acetate. Thus for instance in some embodiments an emulsion formulation according to the invention comprises a surfactant composition as described above (including all described embodiments thereof), water, and a monomer.

(26) A person of ordinary skill in the art can readily determine the effective amount of the surfactant composition of the invention that should be used in an emulsion polymerization formulation, via a combination of general knowledge of the applicable field as well as routine experimentation where needed. For instance, in some embodiments, a quantity of from 0.01 to 10 phm (per hundred monomer) by active weight of the surfactant composition, alternatively from 0.1 to 5 phm by active weight of the surfactant composition, or alternatively from 0.2 to 3 phm by active weight of the surfactant composition, based on the total weight of monomers used in the emulsion polymerization, may be suitable.

(27) Nonionic alkyl alkoxylates of formula II as described above may be purchased from commercial vendors or they may be prepared by those skilled in the art using literature techniques (see for instance U.S. Patent publication number 2011/0098492, which is incorporated herein by reference). In a typical procedure, a suitable alcohol or fatty acid alcohol is alkoxylated with alkylene oxide compounds. Alkoxylation processes may, for instance, be carried out in the presence of acidic or alkaline catalysts, or by using metal cyanide catalysts. Alkaline catalysts may include, for instance, hydroxides or alcoholates of sodium or potassium, including NaOH, KOH, sodium methoxide, potassium methoxide, sodium ethoxide and potassium ethoxide. Base catalysts are normally used in a concentration of from 0.05 percent to about 5 percent by weight, preferably about 0.1 percent to about 1 percent by weight based on starting material.

(28) The addition of alkylene oxides may, for instance, be carried out in an autoclave under pressures from about 10 psig to about 200 psig, preferably from about 60 to about 100 psig. The temperature of alkoxylation may range from about 30 C. to about 200 C., preferably from about 100 C. to about 160 C. After completion of oxide feeds, the product is typically allowed to react until the residual oxide is less than about 10 ppm. After cooling the reactor to an appropriate temperature ranging from about 20 C. to 130 C., the residual catalyst may be left unneutralized, or neutralized with organic acids, such as acetic, propionic, or citric acid. Alternatively, the product may be neutralized with inorganic acids, such as phosphoric acid or carbon dioxide. Residual catalyst may also be removed using ion exchange or an adsorption media, such as diatomaceous earth.

(29) Alkyl alkoxylates sulfate of formula I may be prepared by sulfation of nonionic alkyl alkoxylates of formula II. For instance, the Chemithon sulfation process via sulfur trioxide is a sulfation process well known to those skilled in the art. Typically, pre-heated nonionic alkyl alkoxylate (40 C.) may be first contacted with an air-diluted sulfur trioxide in a continuous thin-film reactor, resulting in a quick and exothermic reaction. The crude sulfuric ester acid may be collected at about 55 C. A prompt neutralization by NaOH or NH.sub.4OH to transform sulfuric ester acid to sulfate salt is advantageous to avoid dark color formation and to reduce formation of impurities. Precise control of the molar ration of SO.sub.3 to nonionic alkyl alkoxylate is preferred in order to produce high quality alkyl alkoxylate sulfate.

(30) Some embodiments of the invention will now be described in detail in the following Examples.

EXAMPLES

(31) Materials used in the examples include the following:

(32) Alkyl alkoxylate sulfate means 2-ethylhexyl-O(CH.sub.2CH(CH.sub.3)O).sub.5.5(CH.sub.2CH.sub.2O).sub.3SO.sub.3NH.sub.4.

(33) Nonionic alkyl alkoxylate 1 means 2-ethylhexyl-O(CH.sub.2CH(CH.sub.3)O).sub.5.5(CH.sub.2CH.sub.2O).sub.3H.

(34) Nonionic alkyl alkoxylate 2 means 2-ethylhexyl-O(CH.sub.2CH(CH.sub.3)O).sub.5.5(CH.sub.2CH.sub.2O).sub.9H.

(35) APE Sulfate means nonylphenol-(EO)4 Sulfate (an APE material) available from Rhodia as RHODAPEX CO-436 (comparative material).

(36) APE-free sulfate means a C12-14 alcohol(EO)4 sulfate available from Cognis as DISPONIL FES-32 (comparative material).

(37) Nonylphenol Ethoxylate: An APE material available from The Dow Chemical Company.

Example 1

(38) Several alkyl alkoxylate sulfate compositions were prepared, including both sodium salt and ammonium salt. Lab-scale samples were prepared based on Chemithon sulfation process. The SO.sub.3 was diluted with air to the ratio at 3.5% vol., then, reacted with pre-heated nonionic alkyl alkoxylate surfactants (at 40 C.) in a falling thin film reactor (length 2 m). Molar ratio of SO.sub.3 to nonionic alkyl alkoxylate was maintained in the range of 0.98-1.0 by adjustment of the flowrate of nonionic alkyl alkoxylate (3-5 kg/h) to the reactor. Cooling water system was applied in the thin film reactor and the temperature in the ether sulfuric acid tank was measured around 55 C., followed with a prompt neutralization by NaOH or ammonia water with stirring.

(39) Formation of the desired compound was confirmed by NMR. The .sup.13C NMR spectrum showed the disappearance of CH.sub.2OH carbon at the chemical shift at =62.0 ppm and the presence of CH.sub.2OSO.sub.3.sup. carbon at =68.0 ppm, which indicated the high conversion of nonionic alkyl alkoxylate to alkyl alkoxylate sulfate.

(40) The Table 1 shows some analytical date of these samples.

(41) TABLE-US-00001 TABLE 1 Sample 1 (NH.sub.4.sup.+) Sample 2 (NH.sub.4.sup.+) Sample 3(Na.sup.+) Formula I (% wt.) 31.09 72.73 32.44 pH 7.4 8.0 8.3

Example 2

Property Testing

(42) Various properties of inventive and comparative compositions are shown in Table 2.

(43) TABLE-US-00002 TABLE 2 Alkyl alkoxylate Alkyl sulfate + Nonionic alkoxylate alkyl alkoxylate 1 sulfate (90:10 by wt) APE Sulfate APE-free sulfate (inventive) (inventive) (comparative) (comparative) Active content (%) 50 50 58-60 30-32 Appearance (20 C.) clear, pale clear, pale clear, pale clear, pale (visual measurement) yellow yellow yellow yellow Surface Tension at 35 32 34 42 CMC (mN/m, 20 C.).sup.1 CMC (ppm) 3000 2000 300 125 (Based on Surface Tension measurement) Foam Height (Ross 108/24 93/17 106/102 113/112 Miles, 0/5 min at 0.2%).sup.2 Draves wetting (s).sup.3 5.3 +/ 0.5 3.0 +/ 0.4 5.9 +/ 0.4 263.0 +/ 32.9 Ca.sup.2+ stability 10-15% wt. 10-15% wt. <2.5% wt. 15% wt. (CaCl2, 1% Surfactant).sup.4 Anti-alkaline (NaOH, 5-10% wt. 5-10% wt. <2.5% wt. 10-15% wt. 1% surfactant)5 Viscosity (cP, at 20 C. 245 202 120.5 63.5 & 60 rpm, #62 probe) .sup.1Measured according to standard GB/T-5549-2010; .sup.2by GB/T 7462-94 standard; .sup.3by GB/T 11983-2008 standard; .sup.4by GB/T 7381-2010; 5by GB/T 5556-2003 standard.

(44) As is apparent from Table 2, in comparison with APE sulfate or APE-free sulfate, the inventive compositions showed various useful properties. For instance, the alkyl alkoxylate sulfate +nonionic alkyl alkoxylate 1 composition exhibited surface tension at 32 mN/m, lower than APE sulfate and APE-free sulfate. Both inventive compositions showed low foam, and quick foam collapse, properties, in contrast to both the APE sulfate and APE-free sulfate compositions, which have almost no foam collapse property. Both inventive compositions showed quick wetting property, which was lower than the APE-free sulfate.

Example 3

Emulsion Polymerization

(45) Basic Formula of Styrene-Butyl Acrylate Emulsion:

(46) Monomers include: butyl acrylate, styrene, acrylamide and acrylic acid;

(47) Initiator is ammonium persulfate;

(48) Glass transition temperature (Tg): 23 C.;

(49) Anionic surfactants: 0.51 phm (per hundred monomer); non-ionic surfactants: 0.54 phm.

(50) Basic Formulation of Pure Acrylate Emulsion:

(51) Monomers include: acrylic acid, butyl acrylate, methacrylic acid;

(52) Glass transition temperature (Tg): 10 C.;

(53) Anionic surfactants: 1.0 phm.

(54) Basic Polymerization Procedure of Styrene-Butyl Acrylate Emulsion:

(55) Pre-emulsify the alkyl alkoxylate sulfate composition with sodium bicarbonate, water and above mentioned monomers. Add the second part of surfactant composition and water into the reactor; start heating to a temperature in the range of 80-90 C.; then, add the first part of ammonium persulfate. Start dropwise addition of pre-emulsion with the second part of ammonium persulfate during 3 h. After addition, keep at the same temperature for 1 h; an emulsion polymerization is performed. After cooling down to room temperature and pH adjustment by aqueous ammonia to neutral 40 C., the polymer emulsion is obtained.

(56) Preparation of other Emulsions:

(57) For the other emulsions preparation, the procedure described above is followed. Emulsifier composition is changed. See the below Table 3 for the emulsifier details of other emulsions.

(58) TABLE-US-00003 TABLE 3 Details of emulsion preparation Example Type Emulsion Emulsion type Surfactant composition +Non-ionic Inventive 1 St-Acrylate alkyl alkoxylate sulfate Comparative 2 St-Acrylate APE sulfate Inventive 3 St-Acrylate alkyl alkoxylate sulfate Nonylphenol Ethoxylate Comparative 4 St-Acrylate APE sulfate Nonylphenol Ethoxylate Comparative 5 St-Acrylate APE-free sulfate Nonylphenol Ethoxylate Inventive 6 St-Acrylate alkyl alkoxylate sulfate nonionic alkyl alkoxylate 2 Comparative 4 St-Acrylate APE sulfate Nonylphenol Ethoxylate Inventive 7 Pure-Acrylate alkyl alkoxylate sulfate Comparative 8 Pure-Acrylate APE-free sulfate
Foaming Property

(59) The emulsion is diluted to 1% by weight of its solid content. Then, 250 mL of diluted emulsion are poured into a test tube. Air-bubble (air-flow at 1.8 L/s) the aqueous emulsion solution for 1 min; stop air-bubbling and record the foam heights in the next 5 min. Foam test results are shown in FIGS. 1-4.

(60) FIG. 1 compares inventive Emulsion 1 (see Table 3) and comparative Emulsion 2. As is apparent, the inventive emulsion exhibited improved low foam and quick foam collapse property relative to the comparative emulsion.

(61) FIG. 2 compares foam properties for Emulsion 3 (inventive) and Emulsions 4 and 5 (comparative). Again, the inventive emulsion showed lower foam and fast foam collapse property.

(62) FIG. 3 compares Emulsion 6 (inventive) and Emulsion 4 (comparative). Again, the inventive emulsion showed good low foam and quick foam collapse property.

(63) FIG. 4 compares Emulsion 7 (inventive) and Emulsion 8 (comparative). Low foam and quick foam collapse are again observed with the inventive material.

(64) Ca.sup.2+ Stability

(65) Test method: Add CaCl.sub.2 aqueous solution (concentration at 5 or 10% wt.) into 20 ml of emulsion; store the CaCl.sub.2 containing emulsion for 48 h at room temperature; any agglomeration or non-homogeneity present in the emulsion signifies poor Ca.sup.2+ stability, consequently, failure in the Ca.sup.2+ stability test. Test results are shown in Table 4.

(66) TABLE-US-00004 TABLE 4 Ca.sup.2+ stability Example Type Emulsion & Type Surfactants Ca.sup.2+ stability Comparison Inventive 1 St-Acrylate alkyl alkoxylate sulfate Fail with 10 mL of 1 CaCl.sub.2 aq (5%) Comparative 2 St-Acrylate APE sulfate Fail with 4 mL of CaCl.sub.2 aq (5%) Comparison Inventive 3 St-Acrylate alkyl alkoxylate sulfate + Pass with 20 mL of 2 nonylphenol ethoxylate CaCl.sub.2 aq (10%) Comparative 4 St-Acrylate APE sulfate + Fail with 4 mL of nonylphenol ethoxylate CaCl.sub.2 aq (5%) Comparative 5 St-Acrylate APE-free sulfate + Fail with 4 mL of nonylphenol ethoxylate CaCl.sub.2 aq (5%) Comparison Inventive 6 St-Acrylate alkyl alkoxylate sulfate + Pass with 20 mL of 3 nonionic alkyl alkoxylate 2 CaCl.sub.2 aq (10%) Comparative 4 St-Acrylate APE sulfate + Fail with 4 mL of nonylphenol ethoxylate CaCl.sub.2 aq (5%) Comparison Inventive 7 Pure-Acrylate alkyl alkoxylate sulfate Fail with 10 mL of 4 CaCl.sub.2 aq (10%) Comparative 8 Pure-Acrylate APE-free sulfate Fail with 10 mL of CaCl.sub.2 aq (5%)

(67) In Table 4, the comparison 1 shows that in St-Acrylate emulsion, when no non-ionic surfactant is added as emulsifier, the emulsion with alkyl alkoxylate sulfate as emulsifier demonstrated better Ca.sup.2+ stability than the one with APE sulfate. In the comparison 2, when the same non-ionic surfactant (nonylphenol ethoxylate) was added in the surfactant composition in St-Acrylate emulsion, the emulsion with alkyl alkoxylate sulfate as emulsifier had better Ca.sup.2+ stability than both others with APE sulfate and APE-free sulfate in the surfactant composition.

(68) In the comparison 3, the comparison between alkyl alkoxylate sulfate composition and classic APE surfactant composition in St-Acrylate emulsion was made. Alkyl alkoxylate sulfate offered not only an eco-friendly profile but also better performance on Ca.sup.2+ stability.

(69) In the comparison 4, no non-ionic emulsifier was used in the Pure Acrylate emulsion. Alkyl alkoxylate sulfate provided also an improved Ca.sup.2+ stability.