Device for managing an accumulator
10020546 · 2018-07-10
Assignee
Inventors
- Sylvie Genies (St Egreve, FR)
- Melanie Alias (Poligny, FR)
- Caroline Coutier (Grenoble, FR)
- Estelle Le Baron (Barraux, FR)
- Sophie Mailley (Le Pin, FR)
Cpc classification
H01M10/48
ELECTRICITY
Y02E60/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M2010/4271
ELECTRICITY
H01M10/425
ELECTRICITY
H01M10/482
ELECTRICITY
International classification
Abstract
A device for managing an accumulator, including: a plurality of strain gauges including at least three strain gauges, the strain gauges being arranged to measure stresses along at least three distinct stress axes; a measuring device measuring strains undergone by each gauge along its stress axis; a reversible electrical switch; a calculating device controlling opening and closing of the electrical switch, depending on measurements carried out by the measuring device.
Claims
1. A device for managing an accumulator, comprising: a plurality of strain gauges including at least three strain gauges, the strain gauges being configured to measure stresses along at least three distinct stress axes; circuitry configured to measure strains undergone by each gauge along its stress axis; a reversible electrical switch; a processor configured to determine a state of charge of the accumulator based on the measured strains and configured to control opening and closing of the reversible electrical switch, depending on the determined state of charge of the accumulator.
2. A device for managing an accumulator according to claim 1, the processor including storage storing a first series of values and a second series of values being different from the first series of values, the processor controlling: closing the reversible electrical switch when the measured strains belong to the first series of values; and opening the reversible electrical switch when the measured strains belong to the second series of values.
3. A device for managing an accumulator according to claim 2, the processor configured to implement an algorithm comprising calculating evolution of the stresses measured by the plurality of strain gauges.
4. A device for managing an accumulator according to claim 3, the processor configured to implement an algorithm identifying a result of the evolution of the stresses, measured by the plurality of strain gauges, in the first series of values or in the second series of values stored by the storage.
5. A device for managing an accumulator according to claim 4, the calculating the evolution of the stresses comprising calculating the abscissa and the radius of the Mohr circle at a time t.
6. A device for managing an accumulator according to claim 1, the plurality of strain gauges being held in contact with a cover including a connection terminal, and including at least one accumulator including at least one connection terminal, such that the strain gauges measure mechanical stresses exerted on the cover.
7. A device for managing an accumulator according to claim 6, the connection terminal of the cover being connected to the reversible electrical switch and to the connection terminal of the accumulator.
8. A device for managing an accumulator according to claim 6, the accumulator being wound around a mandrel.
9. A device for managing an accumulator according to claim 6, the accumulator being a lithium accumulator.
10. A device for managing an accumulator according to claim 6, wherein the device is included in a pack comprising the cover including the connection terminal, connected to the connection terminals belonging to at least two accumulators contained in the cover, the device corresponding to one of the accumulators.
11. A method for calibrating a managing device according to claim 6, comprising recording a first series of measurements, on a storage included in the processor, the measurements being carried out by the circuitry, upon charging and discharging an accumulator, to maintain integrity of the accumulator.
12. A method for calibrating a managing device according to claim 11, further comprising recording a second series of measurements, on the storage included in the processor, the measurements being carried out by the circuitry, upon charging and discharging an accumulator, to prevent an irreversible damage of the integrity of the accumulator.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Further details and characteristics of the invention will appear upon reading the description that follows, made with regard to the following appended figures. Identical, similar, or equivalent parts for the different figures bear the same reference numerals so as to facilitate switching from one figure to another. The different parts represented in the figures are not necessarily drawn to a uniform scale, to make the figures more legible.
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
(17)
(18)
DETAILED DISCLOSURE OF PARTICULAR EMBODIMENTS
(19) The invention relates to a managing device for monitoring the state of charge and safety (with the meaning already defined above) of a pack comprising a lithium accumulator, and enabling the state of aging of said pack to be known in real time. An exemplary embodiment of a managing device is described in a first part of the present disclosure. In a second part, an exemplary method for calibrating and using the managing device, enabling a pack to be optimally used is described. These two exemplary embodiments are completed with several alternatives or variants which can be combined together to form new embodiments.
(20) The first part of the detailed disclosure thus relates to an exemplary managing device enabling the state of charge or safety, as well as the state of health, of a pack 20 comprising a single lithium accumulator, to be followed up in real time. In order to aid the reader in understanding the invention, the managing device 100 is represented attached to the pack 20, but the managing device does not necessarily include the pack 20.
(21) In one example, the pack 20 comprises a lithium accumulator 2 cylindrical in shape. The accumulator is of the LiFePO.sub.4/graphite type and includes a cathode 4 and an anode 6 separated by a separating element 8. The accumulator is wound on itself so as to form a hollow cylinder. The accumulator is insulated from its environment by a sealed cover 12, of aluminium. The cover matches the accumulator shape, it is thus also of a cylindrical shape. The accumulator can for example be the one marketed under the trademark A123Systems, under the reference ANR26650-M1 (see above). The dimensions of the pack 20 are a length of 65 mm along the direction (0; j) and a diameter of 26 mm along the direction (0; i), for a weight of 70 g.
(22) The managing device 100 includes a plurality of strain gauges 14, each gauge being attached or held on an outer face of the cover 12, the inner face of the cover being the face facing the accumulator 2. Preferably, the strain gauges 14 are attached on a bulging part of the pack 20, advantageously at half the length said pack. These strain gauges 14 include a first strain gauge 14A, a second strain gauge 14B and a third strain gauge 14C (
(23) Each strain gauge can be connected to a voltage source powering it. Each gauge is connected to a measuring device 40 for measuring in real time (t) the strain .sub.x(t) undergone by this same gauge 14 (
(24) The exemplary managing device 100 described herein thus includes the devices 14, 40, 50 and 60 defined above (
(25) The detailed disclosure now relates to the algorithm chosen. More precisely, this algorithm enables the managing device 100 to optimally manage the operation of the pack 20. The inventors have surprisingly noticed that the strains of the cover 12 of the pack 20, which are measured by the plurality of strain gauges 14 during charging and discharging cycles of said pack, are not linear.
(26) It is worth to note that these results are contrary to the technical teaching of document WO2011/072295 (
(27) For each gauge, the inventors desired to get rid of the amplitude variation in the measurements provided by this strain gauge as a function of the positioning of its stress axis on the cover 12. For this, they have calculated the strain amplitude along the axis of maximum strains Ep(t) and the strain amplitude along the axis of minimum strains Eq(t) of the cover 12, during the previous charging and discharging cycles (
(28)
(29) The strain amplitude along the axis of minimum strains Eq(t) is calculated according to the following equation 2:
(30)
(31) It can be noted in
(32) The reverse phenomenon is observed during a discharging cycle of the accumulator 2 (
(33) For a charging cycle, between 0 and 20% and between 75% and 90% of the charging state of the accumulator, the curves Eq(t) and Ep(t) evolve substantially linearly (
(34) To determine the charging state of the pack 20 on wider charging ranges, the inventors have thought to correlate the information of the curves Eq(t), Ep(t) and V(t). Table 1 below shows that this correlation does not enable the charging state of the accumulator 2 to be known with certainty for some ranges of the charging values. Indeed, the following ranges of the charging state cannot be differentiated from these measurements only: between 20% and 30% and between 55% and 75%.
(35) TABLE-US-00001 TABLE 1 Determination of the charging state of the pack Charging Evolution Evolution Determination of state of of the of the the charging state the pack (%) curve Eq(t) curve V(t) of the pack 0 to 20% strong
Yes 20 to 30%
low
Indeterminate 30 to 55%
low
Yes 55 to 75%
low
Indeterminate 75 to 100%
strong
Yes
(36) The same is true as regards a discharging cycle as shown in table 2. It is not possible to distinguish from the previous measurements the following ranges of charging state: between 82% and 64% and between 38% and 25%.
(37) TABLE-US-00002 TABLE 2 Determination of the discharging state of the pack Charging Evolution Evolution Determination of state of of the of the the discharging the pack (%) curve Eq(t) curve V(t) state of the pack 100 to 82% strong
Yes 82 to 64%
low
Indeterminate 64 to 38%
low
Yes 38 to 25%
low
Indeterminate 25 to 0%
strong
Yes
(38) The inventors have thought to solve these indeterminations by calculating the slope of the curve Ep(t). Indeed, the inventors have noticed that this slope varies as a function of the charging ranges involved. For this, a charging and discharging cycle is carried out in the charging or discharging indeterminate ranges, to obtain a sufficient number of measurements in order to distinguish these ranges of values. According to this solution, the measurement of V(t) and the calculation of Eq(t) are performed, as well as dEq(t)/dt and the correlation of these three different data (Eq(t), dEq(t)/dt, V(t)). Although this solution is technically feasible, the inventors have wished to use an algorithm enabling the charging state of the pack 20 to be more quickly and simply determined.
(39) The inventors have chosen to use the measurements carried out by the strain gauges 14A, 14B and 14C to represent the evolution in the stresses of the cover 12, by graphical representation, according to the Mohr circle. The abscissa d(t) of the Mohr circle is calculated according to the following equation 3:
(40)
(41) The radius r(t) of the Mohr circle is calculated according to the following equation 4:
(42)
(43) The values d(t) and r(t) are calculated in real time, by the calculating device 50. In other words, the algorithm comprises a step of calculating d(t) and r(t).
(44) The algorithm includes another calculating step enabling the couple of values (d(t), r(t)) calculated to be compared with a list of couples of reference values (d.sub.r, r.sub.r). When the couple of values (d(t), r(t)) calculated corresponds to a couple of reference values, called a critical couple (d.sub.rc, r.sub.rc), the calculating device controls opening or keeping open the electrical switch 60 so as to electrically insulate the pack 20 from its client environment 70. Conversely, when the couple of values (d(t), r(t)) calculated corresponds to a couple of reference values, called a normal couple (d.sub.rn, r.sub.rn), the calculating device controls closing or keeping close the electrical switch 60, so as to electrically connect the pack 20 to its client environment 70.
(45) A method for calibrating a managing device 100 as described above is now described, in view of determining the normal and critical reference values. More precisely, a method enabling the couples of reference values of the managing device 100 attached to a control pack 20 to be determined is described (
(46) During these cycles, the device 50 calculates in real time the couples of values (d(t), r(t)) and stores these values in storage means. At each instant, using
(47) The couples of values (d(t), r(t)) can be graphically represented in an investigation graph, that is an orthogonal reference frame including in abscissa the values d(t) and in ordinate the values r(t). In other words, the couples of values (d(t), r(t)) can be the coordinates of an investigation curve f(t) drawn in real time in the investigation graph.
(48)
(49)
(50) When the charge current is maintained, which results in increasing the voltage to its maximum value, that is beyond the recommended maximum charging cut-off threshold of 3.8V, it is noticed that the investigation function f(t) exits from the allowed zone of overcharges (
(51) An allowed overdischarge zone and an unallowed or critical overdischarge zone can be determined in the same way. For the sake of clarity, these zones are not represented in the figures.
(52) The investigation function f(t) advantageously enables the state of the control pack to be simply graphically represented in real time. As a function of the position of the investigation curve f(t) in one of the zones above, it can be known in which state the pack is: state of charge or safety state (
(53) Therefore, it has been observed that the position of the investigation function f(t) in the investigation graph changes as a function of the number of operating cycles of the control pack. This phenomenon is illustrated in
(54) It can be observed in this figure that when the accumulator is new, the investigation function f.sub.1(t) lies within a zone delimited by values of d(t) between 10 and 515, and by values of r(t) between 0 and 330. After 145 charging and discharging cycles, the function f.sub.2(t) moves to a second zone of the investigation graph, which is delimited by values of d(t) between 400 and 185, and by values of r(t) between 685 and 1 020. The movement of the function f(t) in the investigation graph thus enables the state of health of the accumulator to be followed up in real time. In the same way as previously, an operator can associate an aging state of the control pack to each calculated couple of values (d(t); r(t)).
(55) From the calibrating method described above, it is possible to determine the previously mentioned couples of reference values (d.sub.r; r.sub.r). More precisely, couples of values (d(t); r(t)) calculated by the managing device 100 attached on the control pack (
(56) In this way, the managing device 100 is suitable for being used with packs 20 identical or similar to the control pack.
(57) A method for using a managing device 100 is now described. It is reminded that a managing device according to the invention includes means 14, 40, 50, 60 described above (
(58) Variants of the exemplary managing device 100 are now described.
(59) The strain gauges can be made of, or include one, piezoelectric material which creates an electric voltage measurable when it is deformed.
(60) The strain gauges 14A, 14B, 14C can also be arranged such that their stress axes form angles making the calculation of the values d(t) and r(t) easier. The stress axes of the gauges can for example form between them angles with simple values, such as 45, or 60 or 120. The gauges can be arranged according to a delta rosette-type geometry (
(61) The plurality of strain gauges 14 can also be a rectangular gauge rosette characterized by a gauge rated factor and a maximum strain corresponding to the strain amplitudes to be measured, a resistance and an expansion coefficient. To improve the accuracy in the strain measurements of the strain gauges above, regardless of the temperature and without having to have a temperature controlling system for each gauge, it is also possible to add a free gauge (which does not undergo the influence of temperature) attached on a support plate of the same nature as that on which the measurement gauge is attached and to subtract its response to the strains recorded by the other gauges. It is also possible to measure the room temperature using a temperature probe, and then to apply a correction to the strain values measured by the strain gauges after calibration (blank measurement of the gauge strain as a function of temperature).
(62) According to another variant, as regard the calculating device 50, it can include a viewing interface enabling a user of the pack 20 to view the investigation function f(t) in real time.
(63) The calculating device 50 can also include a keyboard type interface, enabling the user of the pack 20 to monitor the charging state and/or discharging state of the accumulator as a function of the behaviour of the function f(t) in the investigation graph.
(64) According to one application, the managing device 100 can be attached on a pack 20 comprising a cylindrical or prismatic shape accumulator 2.
(65) According to another exemplary application, the managing device 100 can also be attached on a pack 20 comprising a lithium accumulator 2 cylindrical in shape, of the LiMn.sub.2O.sub.4LiCoO.sub.2/graphite (LMO-LCO/G) type. The accumulator can be wound around a centre core or mandrel 10 of plastic or metal (
(66) According to yet another application, a pack 20 can include several accumulators, the connection terminals of which are connected to the connection terminals of the pack. Each accumulator can include its own managing device 100, so as to be able to electrically connect or disconnect said accumulator from the pack. More precisely, the electrical switch 60 of each accumulator is connected between a connection terminal of this accumulator and a connection terminal of the pack so as to connect or disconnect both terminals, in a reversible manner.
(67) According to yet another application, the strain gauges can be bonded or attached to the inside of the protecting cover 12, or on a metallic collector external to the accumulator 2. The strain gauges 14A, 14B and 14C can for example be bonded on an inner face of the cover or on the metallic collector external to the accumulator or on a metal sheet supporting the electrode of the last winding of the accumulator 2 or on the last layer of an accumulator prismatic in shape. The gauges can also be bonded on a plastic cover or a film enabling the element making of the accumulator 2 to be held together.
(68) The detailed disclosure now describes several variants of the method for using the managing device 100.
(69) The optimum position of the plurality of strain gauges 14 on the cover 12 of the pack 20 can be empirically determined for each type of the pack 20. Indeed, it has been noticed that the behaviour of the investigation function f(t) substantially varies as a function of the position of the device of the strain gauges on a same pack. In
(70) It has also been observed that the behaviour of the investigation function substantially varies as a function of the nature of the materials making up the accumulator, the quantity of active material per unit area (basis weight), the accumulator shape, the number of windings and the number of stacks of the elements making up the accumulator, whether a mandrel is present or not in the centre of the winding, the shape and nature of the pack cover (plastic, stainless steel, aluminium or else), etc.
(71) For example, a cylindrical accumulator wound around a mandrel (
(72) Conversely, when the accumulator 2 does not include a centre mandrel, the volume expansion occurs towards the inside and towards the outside of the winding; hence, the strains recorded by the strain gauges reflect less faithfully the strains undergone by the accumulator 2. In other words, the presence of a centre mandrel in a cylindrical accumulator enables more precise information about its state to be obtained with respect to a same accumulator not including a mandrel.
(73) It has also been noticed that the variations in the strains of the strain gauges are more significant when said gauges are bonded to a discharged accumulator. It is thus recommended to conduct attaching the strain gauges on the pack cover or on the accumulator present in the cover, when the accumulator is in a discharged or fully discharged state.
(74) In conclusion, the invention relates to a device for managing a pack comprising a lithium accumulator or any other accumulator type having a comparable design (nickel-cadmium or nickel metal hydride for example), as well as a method for using said device. Thanks to the managing device, it is possible to follow up in real time the state of charge or safety of the pack, as well as its aging state. From these information, the managing device monitors the interface between the pack and its client environment so as to avoid an abusive use of the pack, likely to irreversibly deteriorate it or have risks for its environment. The actions of the managing device are advantageously reversible at the pack and do not degrade it.