Method for surface-treating a metallic substrate

Abstract

A method for surface-treating a metallic substrate, in particular steel plate, using a protective coating on a Zn basis, according to which a chloride-containing solution is applied to the protective coating and as a result an anti-corrosion layer comprising hydrozincite and simonkolleite is formed at least in parts. To increase the corrosion resistance of the protective coating and to improve the process sequence and reproducibility of the method, the invention proposes reacting the protectively coated substrate with the solution which, using an acid, is adjusted to a pH of 4 to 6 and contains 1.8 to 18.5% by weight chloride, so as to increase the proportion of simonkolleite in relation to the proportion of hydrozincite in the anti-corrosion layer.

Claims

1. A method for surface-treating a metallic substrate in order to improve corrosion resistance of the metallic substrate, the method comprising: adjusting a pH value of a chloride-containing solution to a range from 4 to 6 using an acid, wherein the chloride-containing solution contains 1.8 to 18.5 wt % chloride; applying the chloride-containing solution to a Zn-based protective coating on the metallic substrate and, as a result, forming an anti-corrosion layer containing hydrozincite and simonkolleite in at least some areas, the anti-corrosion layer having a layer thickness in a mute from 150 nm to 1.5 m, wherein the protectively coated substrate reacts with the solution for a maximum of 20 minutes in order to form an elevated proportion of simonkolleite relative to the proportion of hydrozincite in the anti-corrosion layer.

2. The method according to claim 1, wherein the protective coating has a ZnAlMg base to which the chloride-containing solution is applied and as a result, an anti-corrosion layer containing hydrozincite, simonkolleite, and hydrotalcite forms in at least some areas.

3. The method according to claim 2, wherein in the ZnAlMg protective coating, a ratio of Al/(Al+Mg) is in a range from 0.5 to 1.0.

4. The method according to claim 1, wherein the solution contains 5 to 30 wt. % NaCl.

5. The method according to claim 1, comprising adjusting the pH value of the solution using HCl.

6. The method according to claim 5, wherein the solution that is applied to the protective coating is composed of water, NaCl, and HCl.

7. The method according to claim 1, wherein the metallic substrate is anodically charged during the reaction with the solution.

8. The method according to claim 1, comprising adjusting the temperature of the solution to a range from 30 to 60 degrees Celsius.

9. The method according to claim 1, comprising applying the Zn-based protective coating to the sheet using a hot-dip immersion process.

10. Me method according to claim 1, wherein the reaction of the solution with the protective coating forms an anti-corrosion layer with a proportion of at least 80% simonkolleite.

11. The method according to claim 1, wherein the metallic substrate is steel sheet.

Description

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

(1) The invention will be explained by way of example below in conjunction with exemplary embodiments:

(2) To verify that the improved corrosion resistance had been achieved, two steel sheets coated with ZnAlMg were surface treated according to the invention with a solution composed of NaCl, HCl, and water, together with inevitable production-related impurities, and were compared to a ZnAlMg-coated steel sheet without the surface treatment according to the invention. The ratio of Al/(Al+Mg) of the ZnAlMg protective coating region is set to 0.5.

(3) The tested protectively coated steel sheets are listed in Table 1.

(4) TABLE-US-00001 TABLE 1 Overview of the tested protectively coated steel sheets 1, 2, 3 Composition of the solution Simonkolleite Hydrozincite Hydrotalcite 1 No treatment Undefined/variable 2 5% NaCl with a pH 90% 5% 5% value of 4-5 3 10% NaCl with a pH 90% 5% 5% value of 5

(5) The protectively coated sheets treated with the solution according to the invention had compact anti-corrosion layers with layer thicknesses in the range from 150 nm to 1.5 m.

(6) An increased corrosion resistance of the ZnAlMg protective coating in protectively coated steel sheet 2 could already be achieved after 10 minutes and at a solution temperature of 30 degrees Celsius; during the reaction of the solution with the protective coating, an anodic charge (20 V, 50 Am.sup.2) was applied.

(7) The same increased corrosion resistance of the ZnAlMg protective coating could be achieved in protectively coated steel sheet 3 after 20 minutes and at a solution temperature of 60 degrees Celsius. In this case, it was possible to omit an anodic charging of the protective coating.