LIQUID-CRYSTAL URETHANE COMPOUND, THERMALLY RESPONSIVE LIQUID-CRYSTAL POLYURETHANE ELASTOMER, AND PRODUCTION METHOD THEREFOR

Abstract

The purpose of the present invention is to provide: a thermally responsive liquid-crystal polyurethane elastomer which is capable of being industrially continuously molded, and which is liquid crystal and has rubber elasticity at low temperatures (in the vicinity of room temperature); and a production method and a starting material therefor. This liquid-crystal urethane compound is obtained by reacting a mesogenic group-containing compound having at least active hydrogen groups, an alkylene oxide and/or a styrene oxide, and a diisocyanate compound.

Claims

1. A liquid-crystal urethane compound obtained by reacting a mesogenic group-containing compound having at least an active hydrogen group, an alkylene oxide and/or a styrene oxide, and a diisocyanate compound.

2. The liquid-crystal urethane compound according to claim 1, wherein the mesogenic group-containing compound is a compound represented by the following general formula (1): ##STR00005## wherein X is an active hydrogen group, R.sub.1 is a single bond, NN, CO, COO, or CHN, R.sub.2 is a single bond or O, and R.sub.3 is a single bond or an alkylene group having 1 to 20 carbon atoms, provided that the compound when R.sub.2 is O and R.sub.3 is a single bond is excluded.

3. The liquid-crystal urethane compound according to claim 1, wherein the alkylene oxide is at least one member selected from the group consisting of ethylene oxide, propylene oxide, and butylene oxide.

4. The liquid-crystal urethane compound according to claim 1, wherein 2 to 10 moles of the alkylene oxide and/or the styrene oxide are added to 1 mole of the mesogenic group-containing compound.

5. A starting material composition for a thermally responsive liquid-crystal polyurethane elastomer, which contains the liquid-crystal urethane compound according to claim 1 and a polyfunctional compound having a functionality of 3 or more which reacts with an active hydrogen group or an isocyanate group of the liquid-crystal urethane compound.

6. A thermally responsive liquid-crystal polyurethane elastomer obtained by reacting the starting material composition for a thermally responsive liquid-crystal polyurethane elastomer according to claim 5.

7. The thermally responsive liquid-crystal polyurethane elastomer according to claim 6, wherein the melting point of a mesogen does not exist between the glass transition temperature (Tg) and the transition temperature (Ti) from a liquid-crystal phase to an isotropic phase, and a liquid-crystal appears at a temperature of between Tg and Ti.

8. The thermally responsive liquid-crystal polyurethane elastomer according to claim 7, wherein the Ti is from 0 to 100 C.

9. A method for producing a thermally responsive liquid-crystal polyurethane elastomer, comprising the step of stretching the starting material composition for a thermally responsive liquid-crystal polyurethane elastomer according to claim 5 while extruding the composition at a temperature at which liquid-crystallinity is exhibited and curing the composition in a state of being oriented the mesogenic group of the liquid-crystal urethane compound in the stretching direction.

10. The liquid-crystal urethane compound according to claim 2, wherein the alkylene oxide is at least one member selected from the group consisting of ethylene oxide, propylene oxide, and butylene oxide.

11. The liquid-crystal urethane compound according to claim 2, wherein 2 to 10 moles of the alkylene oxide and/or the styrene oxide are added to 1 mole of the mesogenic group-containing compound.

12. The liquid-crystal urethane compound according to claim 3, wherein 2 to 10 moles of the alkylene oxide and/or the styrene oxide are added to 1 mole of the mesogenic group-containing compound.

13. A starting material composition for a thermally responsive liquid-crystal polyurethane elastomer, which contains the liquid-crystal urethane compound according to claim 2 and a polyfunctional compound having a functionality of 3 or more which reacts with an active hydrogen group or an isocyanate group of the liquid-crystal urethane compound.

14. A starting material composition for a thermally responsive liquid-crystal polyurethane elastomer, which contains the liquid-crystal urethane compound according to claim 3 and a polyfunctional compound having a functionality of 3 or more which reacts with an active hydrogen group or an isocyanate group of the liquid-crystal urethane compound.

15. A starting material composition for a thermally responsive liquid-crystal polyurethane elastomer, which contains the liquid-crystal urethane compound according to claim 4 and a polyfunctional compound having a functionality of 3 or more which reacts with an active hydrogen group or an isocyanate group of the liquid-crystal urethane compound.

16. A thermally responsive liquid-crystal polyurethane elastomer obtained by reacting the starting material composition for a thermally responsive liquid-crystal polyurethane elastomer according to claim 13.

17. The thermally responsive liquid-crystal polyurethane elastomer according to claim 16, wherein the melting point of a mesogen does not exist between the glass transition temperature (Tg) and the transition temperature (Ti) from a liquid-crystal phase to an isotropic phase, and a liquid-crystal appears at a temperature of between Tg and Ti.

18. The thermally responsive liquid-crystal polyurethane elastomer according to claim 17, wherein the Ti is from 0 to 100 C.

19. A method for producing a thermally responsive liquid-crystal polyurethane elastomer, comprising the step of stretching the starting material composition for a thermally responsive liquid-crystal polyurethane elastomer according to claim 13 while extruding the composition at a temperature at which liquid-crystallinity is exhibited and curing the composition in a state of being oriented the mesogenic group of the liquid-crystal urethane compound in the stretching direction.

Description

MODE FOR CARRYING OUT THE INVENTION

[0021] The liquid-crystal urethane compound of the present invention is one obtained by reacting a mesogenic group-containing compound having at least an active hydrogen group, an alkylene oxide and/or a styrene oxide, and a diisocyanate compound.

[0022] The mesogenic group-containing compound having an active hydrogen group is not particularly limited as long as it is a compound having an active hydrogen group and a mesogenic group, but said mesogenic group-containing compound is preferably a compound represented by the following general formula (1):

##STR00002##

wherein X is an active hydrogen group, R.sub.1 is a single bond, NN, CO, COO, or CHN, R.sub.2 is a single bond or O, and R.sub.3 is a single bond or an alkylene group having 1 to 20 carbon atoms, provided that the compound when R.sub.2 is O and R.sub.3 is a single bond is excluded.

[0023] Examples of X include OH, SH, NH.sub.2, COOH, secondary amines, and the like.

[0024] In order to obtain a thermally responsive liquid-crystal polyurethane elastomer having a transition temperature (Ti) of 0 to 100 C. from a liquid-crystal phase to an isotropic phase or from the isotropic phase to the liquid-crystal phase, it is preferable to use a compound having a biphenyl skeleton (R.sub.1 is a single bond). When R.sub.3 is an alkylene group, the number of carbon atoms is preferably 2 to 10.

[0025] The alkylene oxide to be added is not particularly limited, and examples thereof include ethylene oxide, propylene oxide, 1,2-butylene oxide, 2,3-butylene oxide, cyclohexene oxide, epichlorohydrin, epibromohydrin, methyl glycidyl ether, allyl glycidyl ether, and the like. The styrene oxide to be added may have a substituent such as an alkyl group, an alkoxyl group, or a halogen on the benzene ring.

[0026] In order to obtain a thermally responsive liquid-crystal polyurethane elastomer having a transition temperature (Ti) of 0 to 100 C. at which phase transition from a liquid-crystal phase to an isotropic phase or from the isotropic phase to the liquid-crystal phase occurs, it is preferable to use at least one oxide selected from the group consisting of ethylene oxide, propylene oxide, 1,2-butylene oxide, 2,3-butylene oxide, and styrene oxide.

[0027] The alkylene oxide and/or the styrene oxide is preferably added in an amount of 2 to 10 moles, more preferably 2 to 8 moles, with respect to 1 mole of the compound represented by the general formula (1).

[0028] The known compounds in the field of polyurethanes can be used as the diisocyanate compound without any particular limitation. The diisocyanate compounds include, for example, aromatic diisocyanates such as 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, 2,2-diphenyl methane diisocyanate, 2,4-diphenyl methane diisocyanate, 4,4-diphenyl methane diisocyanate, 1,5-naphthalene diisocyanate, p-phenylene diisocyanate, m-phenylene diisocyanate, p-xylylene diisocyanate and m-xylylene diisocyanate, aliphatic diisocyanates such as ethylene diisocyanate, 2,2,4-trimethyl hexamethylene-1,6-diisocyanate, 2,4,4-trimethyl hexamethylene-1,6-diisocyanate and 1,6-hexamethylene diisocyanate, and cycloaliphatic diisocyanates such as 1,4-cyclohexane diisocyanate, 4,4-dicyclohexyl methane diisocyanate, isophorone diisocyanate and norbornane diisocyanate. These may be used alone or as a mixture of two or more thereof.

[0029] The blending ratio of the diisocyanate compound is preferably 10 to 40 wt %, more preferably 15 to 30 wt %, with respect to all the starting materials of the liquid-crystal urethane compound. When the blending ratio of the diisocyanate compound is less than 10 wt %, it tends to be difficult to continuously form the thermally responsive liquid-crystal polyurethane elastomer because of insufficient increase of the molecular weight in the urethanization reaction. On the other hand, when the blending ratio of the diisocyanate compound exceeds 40 wt %, the blending ratio of the mesogenic group-containing compound decreases, so that the liquid-crystal urethane compound tends to be difficult to exhibit the liquid-crystallinity.

[0030] In order to adjust the molecular weight or viscosity of the liquid-crystal urethane compound, an isocyanate compound having a functionality of 3 or more may be blended. The isocyanate compound having a functionality of 3 or more is not particularly limited, and examples thereof include compounds described later.

[0031] The liquid-crystal urethane compound may be produced by reacting a starting material composition containing at least the mesogenic group-containing compound, the alkylene oxide and/or the styrene oxide, and the diisocyanate compound. Alternatively, the liquid-crystal urethane compound may be produced by reacting the mesogenic group-containing compound with the alkylene oxide and/or the styrene oxide to obtain an oxide-added mesogenic group-containing compound, and reacting the diisocyanate compound or the like with the oxide-added mesogenic group-containing compound. The temperature at which the mesogenic group-containing compound is reacted with the alkylene oxide and/or the styrene oxide is preferably about 110 to 130 C. If the reaction temperature is less than 110 C., the reaction tends to be difficult to proceed. If the reaction temperature exceeds 130 C., side reactions tend to occur, and it tends to become difficult to obtain the desired oxide-added mesogenic group-containing compounds having hydroxyl groups at both ends.

[0032] The transition temperature (Ti) from a liquid-crystal phase to an isotropic phase or from the isotropic phase to the liquid-crystal phase of the liquid-crystal urethane compound is preferably from 15 to 150 C., more preferably from 25 to 125 C.

[0033] The thermally responsive liquid-crystal polyurethane elastomer of the present invention is one obtained by reacting a starting material composition for a thermally responsive liquid-crystal polyurethane elastomer, said composition containing the liquid-crystal urethane compound and a polyfunctional compound having a functionality of 3 or more which reacts with the active hydrogen group or the isocyanate group of the liquid-crystal urethane compound. The liquid-crystal urethane compound may be used singly or in combination of two or more kinds thereof.

[0034] The polyfunctional compound is a starting material for introducing a crosslinking point into the thermally responsive liquid-crystal polyurethane elastomer to form a network structure and imparting rubber elasticity to the thermally responsive liquid-crystal polyurethane elastomer.

[0035] The polyfunctional compound is not particularly limited as long as it is a compound having 3 or more functional groups reactive with the active hydrogen group or the isocyanate group of the liquid-crystal urethane compound, and examples thereof include an isocyanate compound having a functionality of 3 or more, an active hydrogen group-containing compound having a functionality of 3 or more, and the like.

[0036] The isocyanate compounds having a functionality of 3 or more include, for example, triisocyanates (e.g., triphenylmethane triisocyanate, tris(isocyanatephenyl)thio-phosphate, lysine ester triisocyanate, 1,3,6-hexamethylene triisocyanate, 1,6,11-undecane triisocyanate, 1,8-diisocyanate-4-isocyanate methyloctane, and bicycloheptane triisocyanate) and tetraisocyanates (e.g., tetraisocyanate silane). These may be used alone or in combination of two or more thereof. It may also be possible to use a polymerized diisocyanate. As used herein, the term polymerized diisocyanate refers to any of polymerized isocyanate derivatives produced by addition of three or more molecules of diisocyanate, or refers to a mixture of the isocyanate derivatives. For example, the isocyanate derivative may be of (1) trimethylolpropane adduct type, (2) biuret type, (3) isocyanurate type, or the like.

[0037] Examples of the active hydrogen group-containing compound having a functionality of 3 or more include high molecular weight polyols (molecular weight of 400 or more) having 3 or more hydroxyl groups, such as polyether polyol, polyester polyol, polycarbonate polyol, and polyester polycarbonate polyol; low molecular weight polyols such as trimethylolpropane, glycerin, 1,2,6-hexanetriol, pentaerythritol, tetramethylolcyclohexane, methylglucoside, sorbitol, mannitol, dulcitol, sucrose, 2,2,6,6-tetrakis(hydroxymethyl)cyclohexanol, and triethanolamine; low molecular weight polyamines such as diethylenetriamine; and the like. These may be used singly or in combination of two or more kinds thereof.

[0038] The blending ratio of the polyfunctional compound is preferably 2 to 20 wt %, more preferably 4 to 10 wt %, with respect to all the starting materials of the thermally responsive liquid-crystal polyurethane elastomer. When the blending ratio of the polyfunctional compound is less than 2 wt %, memory of the orientation state after orientation of the mesogenic groups is lowered, so that reversible shape defamation (thermal responsiveness) tends to be lost. On the other hand, when the blending ratio of the polyfunctional compound exceeds 20 wt %, the crosslinking density becomes higher, so that the glass transition temperature rises and the temperature range in which the liquid-crystallinity is exhibited becomes narrower. Therefore, it tends to be difficult to continuously form a liquid-crystal polyurethane elastomer having themal responsibility. In addition, the polyurethane elastomer tends to be difficult to exhibit the liquid-crystallinity.

[0039] The thermally responsive liquid-crystal polyurethane elastomer may be produced by a batch method or may be produced by a continuous production method, but from the viewpoint of industrial production efficiency, it is preferable to produce such a polyurethane elastomer by a continuous production method.

[0040] In the case of a batch method, the liquid-crystal urethane compound is crosslinked with the polyfunctional compound and cured to produce a thermally responsive liquid-crystal polyurethane elastomer. During the crosslinking reaction, the mesogenic group of the liquid-crystal urethane compound is oriented in a uniaxial direction while the liquid-crystal urethane compound exhibits the liquid-crystallinity, and is cured in a state of being oriented. There is no particular limitation on the method of orienting the mesogenic group in the uniaxial direction, and examples of such a method include a method of performing a crosslinking reaction on the oriented film, a method of orientation by applying an electric or magnetic field at the time of crosslinking reaction, a method of stretching in the semi-cured state.

[0041] In the case of the continuous production method, the starting material composition is stretched while extruding at a temperature at which liquid-crystallinity is exhibited, and the mesogenic group of the liquid-crystal urethane compound is cured in a state of being oriented in the stretching direction, whereby a thermally responsive liquid-crystal polyurethane elastomer is obtained. The viscosity of the liquid-crystal urethane compound in a temperature range where liquid-crystallinity is exhibited is preferably 10 to 5000 Pa.Math.s, more preferably 100 to 2000 Pa.Math.s. When the viscosity is less than 10 Pa.Math.s, the oriented state of the mesogenic group at the time of stretching tends to decrease due to relaxation, and when the viscosity exceeds 5000 Pa.Math.s, stretching becomes difficult, so that the mesogen group tends to be difficult to be highly oriented. Further, the molding temperature is preferably in the vicinity of the transition temperature (Ti) of the liquid-crystal urethane compound. In addition, the stretch ratio is preferably about 150 to 500%. When the stretch ratio is less than 150%, it tends to be difficult to obtain a liquid-crystal polyurethane elastomer deformed by a thermal response. On the other hand, when the stretch ratio exceeds 500%, there is a high possibility that the thermally responsive liquid-crystal polyurethane elastomer will rupture during molding, because of which continuous production tends to be difficult.

[0042] In the thermally responsive liquid-crystal polyurethane elastomer of the present invention, the melting point of a mesogen does not exist between the glass transition temperature (Tg) and the transition temperature (Ti) from a liquid-crystal phase to an isotropic phase, and a liquid-crystal appears at a temperature of between Tg and Ti. The transition temperature (Ti) is preferably from 0 to 100 C., more preferably from 0 to 85 C.

EXAMPLES

[0043] Description will be given of the invention with examples, while the invention is not limited to description in the examples.

[Measurement and Evaluation Method]

[0044] (Measurement of Glass Transition Temperature (Tg) of Liquid-Crystal Urethane Compound and Thermally Responsive Liquid-Crystal Polyurethane Elastomer, Melting Point (Tm) of Mesogen, and (Liquid-Crystal Phase)-to-(Isotropic Phase) Transition Temperature (Ti))

[0045] The Tg, Tm, and Ti were measured under the condition of 20 C./min using a differential scanning calorimeter DSC (manufactured by Hitachi High-Tech Science Corp., trade name: X-DSC 7000).

(Measurement of Viscosity of Liquid-Crystal Urethane Compound)

[0046] The viscosity of the liquid-crystal urethane compound was measured using a capillary rheometer (trade name: Semi-Automatic Capillary Rheometer (SAS-2002), manufactured by Yasuda Seiki Seisakusho, Ltd.) in accordance with JIS K 7199 at 60 C. and a shear rate of 1000 sec.sup.1.

(Evaluation of Liquid Crystallinity)

[0047] The presence or absence of liquid crystallinity of the liquid-crystal urethane compound and thermally responsive liquid-crystal polyurethane elastomer were evaluated by using a polarization microscope (manufactured by Nikon Corporation, trade name: LV-100POL) and a differential scanning calorimeter DSC (manufactured by Hitachi High-Tech Science Corp., trade name: X-DSC 7000) under the condition of 20 C./min.

(Measurement of Degree of Orientation of Thermally Responsive Liquid-Crystal Polyurethane Elastomer)

[0048] The degree of orientation of the thermally responsive liquid-crystal polyurethane elastomer was calculated by the following formula. Absorbance was measured under the conditions of single reflection ATR, germanium IRE, the incident angle of 45, and vertical polarization using an FT-IR (trade name: Spectrum 100, manufactured by Perkin Elmer, Inc.). The arrangement of the sample was arbitrary two orthogonal directions (0, 90). A large value of degree of orientation means that the mesogenic groups are highly oriented in the uniaxial direction. The degree of orientation is preferably 0.1 or more, more preferably 0.2 or more.

Degree of orientation of thermally responsive liquid-crystal polyurethane elastomer=(AB)/(A+2B)

A=(Absorbance of antisymmetric stretching vibration of aromatic ether as measured at 0)/(Absorbance of symmetric defamation vibration of methyl group as measured at 0)

B=(Absorbance of antisymmetric stretching vibration of aromatic ether as measured at 90)/(Absorbance of symmetric defo nation vibration of methyl group as measured at 90)

Example 1

[0049] BH4 (500 g), KOH 19.0 g, and DMF 3000 ml were placed in a reaction vessel and mixed, then 2 equivalents of propylene oxide were added to BH4 (1 mole). The mixture was reacted under pressurized conditions at 120 C. for 2 hours. Thereafter, oxalic acid 15.0 g was added thereto to stop the addition reaction, and the salt was removed by suction filtration, after which DMF was further removed by distillation under reduced pressure to obtain the desired mesogenic diol A (which may contain a structural isomer). The reaction is shown below.

##STR00003##

[0050] The mesogenic dial A 500 g, hexamethylene diisocyanate (HDI) 154 g, and a catalyst (TEDA-L33, manufactured by Tosoh Corporation) 5 g were mixed, and the mixture was allowed to react at 100 C. for 2 hours to obtain a liquid-crystal urethane compound Al (NCO index: 0.9).

[0051] While adding 4.9 parts by weight of a trifunctional isocyanurate (SUMIDUR N3300, manufactured by Sumika Bayer Urethane Co., Ltd.) to the liquid-crystal urethane compound A1 (100 parts by weight) with a side feeder, the mixture was extruded with a thickness of 1 mmwidth of 100 mm at 60 C., then molded while stretching to 200% to prepare a thermally responsive liquid-crystal polyurethane elastomer.

Example 2

[0052] Mesogenic diol B (which may include a structural isomer) was obtained in the same manner as in Example 1, except that 3 equivalents of propylene oxide were added to BH4 (1 mole). The mesogenic diol B 500 g, hexamethylene diisocyanate (HDI) 137 g, and a catalyst (TEDA-L33, manufactured by Tosoh Corporation) 5 g were mixed and the mixture was reacted at 100 C. for 2 hours to obtain a liquid-crystal urethane compound B1 (NCO index: 0.9). While adding 4.3 parts by weight of a trifunctional isocyanurate (SUMIDUR N3300, manufactured by Sumika Bayer Urethane Co., Ltd.) to the liquid-crystal urethane compound B1 (100 parts by weight) with a side feeder, the mixture was extruded with a thickness of 1 mmwidth of 100 mm at 60 C., then molded while stretching to 200% to prepare a thermally responsive liquid-crystal polyurethane elastomer.

Example 3

[0053] BH6 (500 g), KOH 19.0 g, and DMF 3000 ml were placed in a reaction vessel and mixed, then 2 equivalents of propylene oxide were added to BH6 (1 mole). The mixture was reacted under pressurized conditions at 120 C. for 2 hours. Thereafter, oxalic acid 15.0 g was added thereto to stop the addition reaction, and the salt was removed by suction filtration, after which DMF was further removed by distillation under reduced pressure to obtain the desired mesogenic diol C (which may contain a structural isomer). The reaction is shown below.

##STR00004##

[0054] The mesogenic diol C 500 g, a mixture of 2,2,4-trimethylhexamethylene-1,6-diisocyanate and 2,4,4-trimethylhexamethylene-1,6-diisocyanate (VESTANAT TMDI, manufactured by Evonik Degussa) 188 g, and a catalyst (TEDA-L33, manufactured by Tosoh Corporation) 5 g were mixed and the mixture was reacted at 100 C. for 2 hours to obtain a liquid-crystal urethane compound C1 (NCO index: 0.9).

[0055] While adding 4.3 parts by weight of a trifunctional isocyanurate (SUMIDUR N3300, manufactured by Sumika Bayer Urethane Co., Ltd.) to the liquid-crystal urethane compound C1 (100 parts by weight) with a side feeder, the mixture was extruded with a thickness of 1 mmwidth of 100 mm at 60 C., then molded while stretching to 200% to prepare a thermally responsive liquid-crystal polyurethane elastomer.

Example 4

[0056] The mesogenic diol C 500 g, VESTANART TMDI (168 g) and a catalyst (TEDA-L33, manufactured by Tosoh Corporation) 5 g were mixed and the mixture was reacted at 100 C. for 2 hours to obtain a liquid-crystal urethane compound C2 (NCO index: 0.8).

[0057] While adding 8.9 parts by weight of a trifunctional isocyanurate (SUMIDUR N3300, manufactured by Sumika Bayer Urethane Co., Ltd.) to the liquid-crystal urethane compound C2 (100 parts by weight) with a side feeder, the mixture was extruded with a thickness of 1 mmwidth of 100 mm at 60 C., then molded while stretching to 200% to prepare a thermally responsive liquid-crystal polyurethane elastomer.

Example 5

[0058] The mesogenic diol C 500 g, VESTANART TMDI (199 g) and a catalyst (TEDA-L33, manufactured by Tosoh Corporation) 5 g were mixed and the mixture was reacted at 100 C. for 2 hours to obtain a liquid-crystal urethane compound C3 (NCO index: 0.95).

[0059] While adding 2.2 parts by weight of a trifunctional isocyanurate (SUMIDUR N3300, manufactured by Sumika Bayer Urethane Co., Ltd.) to the liquid-crystal urethane compound C3 (100 parts by weight) with a side feeder, the mixture was extruded with a thickness of 1 mmwidth of 100 mm at 60 C., then molded while stretching to 200% to prepare a thermally responsive liquid-crystal polyurethane elastomer.

TABLE-US-00001 TABLE 1 Characteristics of thermally responsive liquid-crystal Characteristics of liquid-crystal urethane compound polyurethane elastomer Glass Glass Reversible transition Melting Transition Liquid- Viscosity transition Melting Transition Liquid- deformation temperature point temperature crystal- at 60 C. temperature point temperature crystal- Degree of by thermal (Tg) (Tm) (Ti) linity (Pa .Math. s) (Tg) (Tm) (Ti) linity orientation response Example 1 7 77 Yes 450 10 65 Yes 0.21 Yes Example 2 8 69 Yes 350 11 55 Yes 0.18 Yes Example 3 9 62 Yes 280 15 40 Yes 0.14 Yes Example 4 8 65 Yes 40 18 38 Yes 0.11 Yes Example 5 9 61 Yes 1120 11 47 Yes 0.24 Yes

INDUSTRIAL APPLICABILITY

[0060] Since the thermally responsive liquid-crystal polyurethane elastomer of the present invention has a characteristic response behavior such that said elastomer shrinks by a decrease in the degree of the liquid-crystal orientation due to heat applied thereto and extends in the orientation direction by an increase in the degree of the liquid-crystal orientation due to removal of the heat applied, it is possible to apply the liquid-crystal polyurethane elastomer to various fields such as actuators.