THERMAL RUNAWAY PIN-POINT HEATING TEST

Abstract

A method and apparatus permit the testing of electrochemical cells. The apparatus includes a heat source, a chamber, and a diffuser coupling the heat source to the chamber. The heat source applies heat via the diffuser to a pin-point section of the electrochemical cell. This application of heat causes a thermal runaway condition due to a localized internal short circuit in the electrochemical cell. It is then determined whether the electrochemical cell has vented, ruptured, or exploded in response to the application of the heat source to the thermal runaway pin-point section of the electrochemical cell.

Claims

1. A process to test an electrochemical cell comprising: applying a heat source to a section of the electrochemical cell, thereby causing a thermal runaway condition due to a localized internal short circuit in the electrochemical cell; and determining whether the electrochemical cell has vented, ruptured, or exploded in response to the application of the heat source to the section of the electrochemical cell.

2. The process of claim 1, wherein the localized internal short circuit comprises a single point of contact between a positive electrode and a negative electrode.

3. The process of claim 1, wherein the localized internal short circuit occurs at an internal or external jellyroll layer of the electrochemical cell.

4. The process of claim 1, wherein the section of the electrochemical cell comprises an area of the electrochemical cell that is less than 1% of a total area of the electrochemical cell.

5. The process of claim 1 wherein the section comprises a pin-point section.

6. The process of claim 1, wherein the localized internal short circuit comprises a single negative electrode, a single positive electrode, and a single insulation layer.

7. The process of claim 1, wherein the localized internal short circuit comprises three or fewer negative electrodes, three or fewer positive electrodes, and two or fewer insulation layers.

8. The process of claim 1, wherein the localized internal short circuit comprises a number of negative electrodes, positive electrodes, and insulation layers that comprises less than 1% of a total number of negative electrodes, positive electrodes, and insulation layers in the battery.

9. The process of claim 1, wherein the localized internal short circuit comprises a localized shrinking of an insulation layer positioned between a negative electrode and a positive electrode.

10. The process of claim 1, wherein the heat source comprises one or of a flame, a hot air heater, an electric heater, and a laser.

11. A system comprising: a heat source: a chamber; and a diffuser coupling the heat source to the chamber; wherein the system is operable for testing an electrochemical cell comprising: positioning the electrochemical cell in the chamber; applying the heat source via the diffuser to a section of the electrochemical cell, thereby causing a thermal runaway condition due to a localized internal short circuit in the electrochemical cell; and determining whether the electrochemical cell has vented, ruptured, or exploded in response to the application of the heat source to the section of the electrochemical cell.

12. The system of claim 11, comprising an apparatus to receive, the electrochemical cell, the apparatus comprising a thermocouple.

13. The system of claim 11, wherein the chamber comprises an explosion proof window.

14. The system of claim 11, wherein the section of the electrochemical cell comprises an area of the electrochemical cell that is less than 1% of a total area of the electrochemical cell.

15. The system of claim 11, wherein the section comprises a pin point section.

16. The system of claim 11, wherein the localized internal short circuit comprises a single negative electrode, a single positive electrode, and a single insulation layer.

17. The system of claim 11, wherein the localized internal short circuit comprises three or fewer negative electrodes, three or fewer positive electrodes, and two or fewer insulation layers.

18. The system of claim 11, wherein the localized internal short circuit comprises a number of negative electrodes, positive electrodes, and insulation layers that comprises less than 1% of a total number of negative electrodes, positive electrodes, and insulation layers in the electrochemical cell.

19. The system of claim 11, wherein the localized internal short circuit comprises a localized shrinking of an insulation layer positioned between a negative electrode and a positive electrode.

20. The system of claim 11, wherein the heat source comprises one or more of a flame, a hot air heater, an electric heater, and a laser.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0012] In the drawings, which are not necessarily drawn to scale, like numerals may describe similar components in different views. Like numerals having different letter suffixes may represent different instances of similar components. Some embodiments are illustrated by way of example, and not limitation, in the figures of the accompanying drawings.

[0013] FIGS. 1A and 1B are a block diagram illustrating operations and features of an electrochemical cell thermal runaway pin-point heating test system.

[0014] FIG. 2 illustrates an embodiment of an electrochemical cell thermal runaway pin-point heating system.

[0015] FIG. 3 illustrates another embodiment of an electrochemical cell thermal runaway pin-point heating test system.

[0016] FIG. 4 illustrates differences in heating area of an electrochemical cell using an embodiment disclosed herein and a prior normal heating method.

DETAILED DESCRIPTION

[0017] To overcome the shortcomings of existing electrochemical cell safety tests, what is needed is a test that provides qualitative and quantitative means to measure the chances of an electrochemical cell failure under thermal runaway conditions, and a test that can evaluate the vent performance and can structure integrity of the electrochemical cell under thermal runaway conditions. While thermal runaway and venting are expected, can rupture should not occur. If can rupture occurs, there is a problem with the design and/or materials of the cell. An embodiment of the present disclosure addresses these shortcomings of the existing electrochemical cell tests and satisfies these needs.

[0018] An embodiment dynamically can step through all the protection mechanisms that are built into the cell. Prior methods cannot do this. For example, the center pipe for gas discharge, pressure relief safety valve, and other features of a cell can be observed during the test. That is, failure of these mechanisms which resulted in metal can disintegration, ejection of jelly roll, and casing explosion can actually be observed in the embodiment of the thermal runaway pin-point heating test. The embodiment finds defects in electrochemical cell design that could cause safety concerns for a user, shows that the safety mechanism of a cell (e.g., a current interrupt device (CID)) works as intended under thermal runaway conditions, and creates an internal short circuit without affecting the cell integrity like tests that puncture, deform, bend, and/or crush the cell.

[0019] There are several advantages to the thermal runaway pin-point heating test. There is precise temperature control. The test is applied directly to a final cell product without any extra preparation like in some existing tests. The test allows for real time data collection and visual observation. The test provides quantitative measurements, and it is flexible, simple, safe, reliable, fast, inexpensive, and reproducible.

[0020] FIGS. 1A and 1B illustrate the steps, operations, and features of the thermal runaway pin-point heating test for an electrochemical cell. At 110, a heat source is applied to a section of the electrochemical cell. One such electrochemical cell that the test can be used on is a Lithium-ion battery. These electrochemical cells can be used in many products such as computer laptops and electric vehicles. In an embodiment, as illustrated at 112, the section of the electrochemical cell comprises an area of the electrochemical cell that is less than 1% of a total area of the electrochemical cell. In other embodiments, the heated section can be less than or greater than 1% of the total area of the electrochemical cell. The differences in total area of heating of the cell for an embodiment of this disclosure and a prior normal heating method are illustrated in FIG. 4. FIG. 4 illustrates four areas of heating (center side, corner side, bottom center side, and terminal side), and the differences in the heating areas 410. This heating of the electrochemical cell causes a thermal runaway condition due to a localized internal short circuit in the electrochemical cell. FIG. 2 illustrates a heat source 210 that is applied to a limited, concentrated, or pin-point section of the electrochemical cell 200. As illustrated in FIG. 2, in this particular embodiment, the heating source is directed at a particular section or point 220 of the electrochemical cell 200, and the heating source is placed, without physical contact, in close proximity to the electrochemical cell 200 at a specific angle from the casing of the electrochemical cell. The heating source can be anything such as a flame, a hot air heater, an electric heater, and/or a laser (113).

[0021] As indicated at 115, the localized internal short circuit is caused by a localized shrinking of the separator/insulation layer 250 that is positioned between the negative electrode 240 and the positive electrode 260. In an embodiment, the localized internal short circuit involves a single negative electrode, a single positive electrode, and a single insulation layer (115A). In another embodiment, the localized internal short circuit involves three or fewer negative electrodes, three or fewer positive electrodes, and two or fewer insulation layers (115B). In yet another embodiment, the localized internal short circuit consists of a number of negative electrodes, positive electrodes, and insulation layers that involves less than 1% of a total number of negative electrodes, positive electrodes, and insulation layers in the battery (115C). As indicated at 116, a jellyroll internal short circuit can be caused by an anode crimping past a shrunken separator and causing a single point of failure contact with a cathode.

[0022] After the heat source is directed at the electrochemical cell in operation 110, then at 120, it is then observed whether the electrochemical cell has vented, ruptured, or exploded in response to the application of the heat source to the section of the electrochemical cell.

[0023] In an embodiment, the system 300 of FIG. 3 can be used to apply the heat source to the electrochemical cell and to make the observation and determination of whether the electrochemical cell has vented, ruptured, or exploded. The system 300 includes a chamber 310, a hot air generator 320, and a diffuser 330 coupling the hot air generator 320 to the chamber 310. The hot air generator has a temperature controller 325. The chamber 310 is manufactured out of metal walls 311 and an explosion proof window 312, and further includes an exhaust vent 313. Within the chamber 310 is a metal platform 314, and a sample holder 315. In an embodiment, the sample holder 315 includes one or more thermocouples. The sample holder 315 maintains the electrochemical cell in place, and the thermocouples provide an accurate temperature of the sample electrochemical cell. The electrochemical cell to be tested is positioned in the chamber 310. The operations of FIG. 1A and are then carried out on the electrochemical cell being tested. That is, the hot air generator applies heat to a pin-point section of the electrochemical cell via the diffuser. As noted, this causes a thermal runaway condition due to a localized internal short circuit in the electrochemical cell. The electrochemical cell is then observed through the explosion proof window, and it is determined whether the electrochemical cell has vented, ruptured, or exploded in response to the application of the heat source to the section of the electrochemical cell.

[0024] The above detailed description includes references to the accompanying drawings, which form a part of the detailed description. The drawings show, by way of illustration, specific embodiments that may be practiced. These embodiments are also referred to herein as “examples.” Such examples may include elements in addition to those shown or described. However, also contemplated are examples that include the elements shown or described. Moreover, also contemplated are examples using any combination or permutation of those elements shown or described (or one or more aspects thereof), either with respect to a particular example (or one or more aspects thereof), or with respect to other examples (or one or more aspects thereof) shown or described herein.

[0025] Publications, patents, and patent documents referred to in this document are incorporated by reference herein in their entirety, as though individually incorporated by reference. In the event of inconsistent usages between this document and those documents so incorporated by reference, the usage in the incorporated reference(s) are supplementary to that of this document; for irreconcilable inconsistencies, the usage in this document controls.

[0026] In this document, the terms “a” or “an” are used, as is common in patent documents, to include one or more than one, independent of any other instances or usages of “at least one” or “one or more.” In this document. the term “or” is used to refer to a nonexclusive or, such that “A or B” includes “A but not B,” “B but not A.” and “A and B,” unless otherwise indicated. In the appended claims, the terms “including” and “in which” are used as the plain-English equivalents of the respective terms “comprising” and “wherein.” Also, in the following claims, the terms “including” and “comprising” are open-ended, that is, a system, device, article, or process that includes elements in addition to those listed after such a term in a claim are still deemed to fall within the scope of that claim. Moreover, in the following claims, the terms “first,” “second,” and “third.” etc. are used merely as labels, and are not intended to suggest a numerical order for their objects.

[0027] The above description is intended to be illustrative, and not restrictive. For example, the above-described examples (or one or more aspects thereof) may be used in combination with others. Other embodiments may be used, such as by one of ordinary skill in the art upon reviewing the above description. The Abstract is to allow the reader to quickly ascertain the nature of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. Also, in the above Detailed Description, various features may be grouped together to streamline the disclosure. However, the claims may not set forth every feature disclosed herein as embodiments may feature a subset of said features. Further, embodiments may include fewer features than those disclosed in a particular example. Thus, the following claims are hereby incorporated into the Detailed Description, with a claim standing on its own as a separate embodiment. The scope of the embodiments disclosed herein is to be determined with reference to the appended claims, along with the full scope of equivalents to which such claims are entitled.