FURNACE FOR MELTING AND TREATING METAL AND METALLIC WASTE AND METHOD THEREFOR
20180156540 · 2018-06-07
Inventors
Cpc classification
F27D27/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27D11/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27D2003/0083
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27D2003/0054
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27B3/10
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
A furnace includes a tank having outer and inner walls defining a closed canal configured to be filled with molten metal continuously circulating along the closed canal. The closed canal includes at least one heating area having a heating component configured to transfer energy to the molten metal thus overheating it; at least one loading area configured for material to be melted or treated, dragged by the overheated molten metal on its surface; a melting/treatment area configured to receive the overheated molten metal and material dragged on its surface. The overheated molten metal transfers its exceeding energy to the material, causing its melting/treatment. The furnace has a central hollow delimited by the inner wall. The furnace includes a driving component within the hollow, having a rotor with at least one magnet body. The rotor is coupled to a motor and configured to rotate upon activation of the motor, generating a magnetic field capable of causing circulation of the molten metal in a continuous and cyclical manner.
Claims
1. A furnace comprising: a tank having an outer wall and an inner wall, arranged to define a closed canal between said inner wall and said outer wall, a central hollow delimited by said inner wall, and at least one driving means located within said central hollow, wherein said at least one driving means comprises a rotor comprising at least two permanent magnets, the rotor being coupled to a motor and configured to rotate upon activation of said motor, thus generating a magnetic field, the furnace being wherein the tank is configured to, in use of the furnace, be filled with molten metal which will circulate along said closed canal in a continuous and cyclical manner, said furnace comprising in said closed canal between said inner wall and said outer wall: at least one heating area comprising heating means configured to transfer energy to the molten metal thus overheating said molten metal; at least one loading area configured for loading metal or metallic waste into said molten metal to be melted or treated, said metal or metallic waste, in used of the furnace, being dragged by the overheated molten metal on its surface; a melting/treatment area configured to receive the overheated molten metal and the metal or metallic waste dragged on its surface, the overheated molten metal transferring its exceeding energy to the dragged metal or metallic waste thus causing its melting/treatment; said magnetic field generated by said rotor being capable of causing said circulation of the molten metal within said closed canal in a continuous and cyclical manner along the heating area, loading area and melting/treatment area.
2. The furnace of claim 1, wherein said at least one loading area overlaps partially or totally with said at least one heating area.
3. The furnace of claim 1, wherein said melting/treatment area overlaps at least partially with said at least one heating area.
4. The furnace of claim 1, wherein said rotor is surrounded by a first thermal isolating body permeable to the magnetic field disposed between the rotor and an outer face of the inner wall of the tank which delimits the central hollow, said first thermal isolating body defining a first channel between the rotor and an inner wall of the thermal isolating body and a second channel between an outer wall of the first thermal isolating body and the outer face of the inner wall which delimits said central hollow, at least one of said first and second channels being configured to receive an air flow from blowing means configured to provide refrigerating air to the rotor in order to prevent the rotor from heating over a certain temperature.
5. The furnace of claim 1, wherein the outer face of the inner wall of the tank, which delimits said cavity, is covered with a second thermal isolating body.
6. The furnace of claim 1, wherein the outer face of the inner wall of the tank, which delimits said cavity, is made of a second thermal isolating body.
7. The furnace of claim 4, wherein said thermal isolating body is made of a material chosen from the following materials: stainless steel, mica, a composite material or a combination thereof.
8. The furnace of claim 1, wherein at said at least one heating area the heating means is placed substantially outside the effect of the magnetic field generated by the driving means.
9. The furnace of claim 8, wherein at said at least one heating area the outer wall of the tank defines a protrusion, said heating means being placed in said protrusion.
10. The furnace of claim 8, wherein at said at least one heating area the inner wall of the tank defines a protrusion, said heating means being placed in said protrusion.
11. The furnace of claim 1, further comprising an extraction area ending in a siphoning wall configured for preventing the progress of the slag, said extraction area comprising extraction means for pouring part of the molten metal and/or slag.
12. The furnace of claim 1, wherein said at least one melting/treatment area comprises retaining means whose lower part ends slightly above the level reached by the melted metal within the tank, the retaining means being configured for, when the circulating molten metal and the dragged metal or metallic waste on its surface reach the retaining means, preventing the metal or metallic waste on the melted surface from travelling forward, so that the waste is substantially smelted on the surface of the molten metal bed, without preventing the progress of the molten metal beneath the retaining means.
13. The furnace of claim 1, wherein said heating means is a plasma torch.
14. The furnace of claim 1, wherein the angular velocity of the circulating molten metal is constant at the melting/treatment area.
15. Use of the furnace of claim 1 for melting or treating ferrous or non-ferrous materials.
16. A method for treating or melting metal or metallic waste in a furnace comprising a tank having an outer wall and an inner wall, said furnace defining a closed canal between said inner wall and said outer wall of the tank, the method being wherein it comprises the steps of: filling said tank with molten metal, at at least one heating area, transferring energy to the molten metal thus overheating said molten metal; at at least one loading area, loading metal or metallic waste to be melted or treated, said metal or metallic waste being dragged by the overheated molten metal on its surface; at at least one melting/treatment area, receiving the overheated molten metal and the metal or metallic waste dragged on its surface, the overheated molten metal transferring its exceeding energy to the dragged metal or metallic waste; wherein said molten metal circulates along said closed canal in a continuous and cyclical manner, said movement being achieved by the action of at least one driving means located within a central hollow delimited by said inner wall of the tank, said at least one driving means comprising a rotor comprising at least two permanent magnets, the rotor being coupled to a motor and configured to rotate upon activation of said motor, thus generating a magnetic field capable of causing said circulation of the molten metal in a continuous and cyclical manner along the heating area, loading area and melting/treatment area.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0036] In the figures:
[0037]
[0038]
[0039]
[0040]
[0041]
[0042]
[0043]
[0044]
DETAILED DESCRIPTION OF THE DRAWINGS
[0045] In this text, the term comprises and its derivations (such as comprising, etc.) should not be understood in an excluding sense, that is, these terms should not be interpreted as excluding the possibility that what is described and defined may include further elements, steps, etc.
[0046] In the context of the present disclosure, the term approximately and terms of its family (such as approximate, etc.) should be understood as indicating values very near to those which accompany the aforementioned term. That is to say, a deviation within reasonable limits from an exact value should be accepted, because a skilled person in the art will understand that such a deviation from the values indicated is inevitable due to measurement inaccuracies, etc. The same applies to the terms about and around and substantially.
[0047] The following description is not to be taken in a limiting sense but is given solely for the purpose of describing the broad principles of the disclosure. Next embodiments of the disclosure will be described by way of example, with reference to the above-mentioned drawings showing apparatuses and results according to the disclosure.
[0048] In reference to the figures, a preferred embodiment of the furnace of this disclosure is described below.
[0049] The furnace of the disclosure is based on the indirect heating of the loaded material by means of a circulating molten metal which transfers the energy necessary for the melting or treatment of the loaded solid metal. This indirect heating is especially important when the material to be treated/melted is loaded in an area separate from a heating area. In some other cases, in which the loaded material can be in contact with or in the vicinity of the heating means (i.e. plasma torch), the heating means has a relevant contribution to the heating of the loaded material.
[0050]
[0051] The tank 1 of the furnace comprises a closed-looped outer wall 5 and a closed looped inner wall 5 which delimits a central cavity or hollow (through hole) 16. Driving means 17 are housed within the cited central cavity 16. The driving means 17 is preferably a rotor 17 which comprises at least one magnet body having at least two permanent magnets. The rotor 17 is mounted on a vertical axis 19 which is coupled to an electric motor 20. This coupling can be either direct or indirect, for example by means of a pulley. There is preferably a cooling means 18 for cooling the motor 20 disposed below the rotor 17. The function of the rotor 17 is to create a constant magnetic field when it turns (rotates) around said axis 19 upon activation of the motor 20. The magnetic field thus generated causes the circulation of the molten metal in a continuous and cyclical manner along the closed canal defined by the tank 1.
[0052]
[0053] The rotor 17 is preferably surrounded by (or housed within) a first thermal isolating body 6, shown in
[0054] The thermal isolating body 6 is permeable to the magnetic field. The isolating body 6 comprises a nonmagnetic material which supports high temperatures (up to 700 C.). Non-limiting examples of such material are stainless steel, mica or a composite material, among others. The purpose of this thermal isolating body 6 is to guarantee that the temperature around the rotor 17 is not higher than about 80 C. and to shield the radiation of the furnace. The height of the isolating body 6 is at least that of the rotor 17. It can also be higher than the rotor 17.
[0055] Conventional furnaces normally have a metallic wall or sheet 35 externally covering the refractory body (which is normally concrete or brick), as shown for example in
[0056] In a preferred embodiment, however, such metallic wall or sheet has been removed from the outer surface of the inner body wall (that is to say, the part which in
[0057] This second thermal isolating body 6 is shown in
[0058] In use of the furnace, the tank 1 is filled with molten metal (4 in
[0059] In the embodiment shown in
[0060] In the embodiment shown in
[0061] The furnace can have different walls, disposed between the main body 5 (or outer wall 5) of the tank 1 and its inner wall 5, associated to the different working areas in which de furnace is divided. In other words, the walls are transversal to the flow or movement of the molten metal. Depending on the height of each wall with respect to surface of molten metal bed, each wall will permit or not the travel of, the slag and/or the solid metal or waste dragged by the molten metal. The molten metal always passes down the walls. In the embodiment of
[0062] As already mentioned, in a particular embodiment, the melting/treatment area B comprises waste retaining means 24. In this embodiment, when the metal SM or metallic waste R travelling on the surface of the molten metal X reaches the retaining means 24, this does not allow the floating solid metal SM or floating metallic waste R having height above the lower end of the retaining means 24, to pass, whereas the molten metal X together with the metallic particles it may contain, continues its movement beneath the solid metal SM or metallic waste, causing the complete melting/treatment of the solid metal SM or metallic waste R, as will be described next. In other words, the retaining means 24 is for retaining such waste or solid metal on the surface of the circulating metal. The retaining means 24 can be implemented as a wall supported or leant against the inner surface of the tank 1. Preferably, the lower end of the retaining wall 24 is at the most 2 mm above the level of molten metal. That is to say, there is a minimum gap of 2 mm between the lower end of the retaining wall 24 and the level of molten metal. This height depends on the size of the metallic waste or solid metal SM to be melted/treated and varies depending on the type of metallic waste or solid metal.
[0063] The furnace shown in
[0064] In the embodiment shown in
[0065] The embodiment shown in
[0066] If, on the contrary, the material to be treated/melted is clean enough and therefore does not generate large amounts of slag, the treatment/melting area B can include one or more supplementary plasma torches in a zone at this area B furthest away from the loading area A. Non-limiting examples of such materials are scrap, metallic shavings, copper oxide or iron oxide. This is because, due to their little gaseous evolution and low melting point, such materials can be subject to the action of the plasma torch without evaporating. For this reason, the loaded material can be in contact with or in the vicinity of the plasma torch. That is why the loading area A and/or the melting/treatment area B can overlap (partially or totally) with the heating area D. These materials require also the presence of two walls: wall or retaining means 24 and siphoning wall 25, for preventing the travel of the slag towards the heating area D.
[0067] In another alternative embodiment, the furnace is used for melting/treating material having high melting/treatment point and little gaseous evolution, such as asbestos, waste from automobile catalyst, which are normally combined with ceramics, petrochemical waste with high degree of molybdenum. These materials are preferably loaded (A) at the heating area D, either through the plasma torch (which is hollow) or in the vicinity thereof. In this same area the materials are processed (treated or melted). The furnace is therefore preferably configured with a main chamber/area for heating and treating, and with a small extraction area C at the end of the main area. In this case, only siphoning wall 25 and separating wall 27 are strictly required, for respectively preventing the travel of the slag towards the main area (for heating, leading and treating) and for acting as retaining means.
[0068] In another alternative embodiment, used for melting or treating material having high gaseous evolution and high temperature of treatment/melting, the material must be loaded (loaded area A) in a chamber prior to the heating area (D) and following the extraction area C. The heating area D can overlap partially with the treating/melting area B because the material can be treated/melted at both areas. Therefore, for such materials, siphoning wall 25 and separating wall 27 are required. It is remarked that, in this embodiment, separating wall 27 works as retaining means.
[0069]
[0070] The retaining means 24 are designed in such a way that its lower part ends slightly above the level reached by the molten metal X within the tank 1. In other words, the retaining means 24 ends at a level with respect to the level of the molten metal X which is higher enough to let slag I go forward but to prevent solid metal MS from going further. It is located at a distance from the metal bed which can vary (depending on the use for which the furnace is intended). Its goal is to prevent the travelling forward of the floating rests before its substantially total melting. The height of retaining wall 24 depends on the size of the metallic waste R or solid metal SM to be melted/treated and varies depending on the type of metallic waste R or solid metal SM. The molten metal X having floating slag I on its surface travels along the closed canal defined by the tank. If the molten metal level exceeds the height at which a tapping spout is (or tapping spouts are), the exceeding amount of molten metal leaves the tank through tapping spouts (not shown in
[0071] Siphoning wall 25 delimits a metal extraction area and is slightly submerged into the molten metal bed. It penetrates within the molten metal down to a certain depth, thus preventing the travel of the slag I towards the heating area. If there are two tapping spouts 9 9, the exceeding molten metal is extracted by one of them and the slag is extracted by the other one. If there is a single tapping spout, molten metal and slag are extracted by that single spout. Thus, the substantially slag-free molten metal reaches the heating area. Separating wall 27 delimits the end of heating area in which the plasma torch 11 is located.
[0072]
[0073] While the angular velocity of the circulating molten metal is constant for the whole volume of motel metal at the melting/treatment area B, in the heating area D the velocity due to the magnetic field is much lower because the magnetic field is much lower at this area (see for example
[0074] In an alternative embodiment, the isolation of the heating means 11 from the effect of the magnetic field generated by the driving means 17 is achieved by means of a different configuration of the furnace. Instead of having a protrusion 311 (or protrusions 211 311), the width of the canal forming a closed loop (defined by the two walls of the tank) is constant, but thick enough so as to have substantially no influence of the magnetic field generated by the driving means 17 at the heating means 11 located at the heating area D. In this embodiment, the linear velocity of the circulating molten metal is not constant any more, said linear velocity being lower at the outer part of the canal.
[0075] In a preferred embodiment, the furnace has two covers or lids, not shown: a first cover which covers the melting/treatment area and a second cover which covers the heating area. The lid or lids permit the access of one or more gas burners, for example for preheating and/or for supplying additional energy to the heating means 11. The different walls 24 25 27 can be either fixed to the tank or to the lid or lids.
[0076] Operational melting or treatment in a furnace, such as the mode for carrying out the disclosure of
[0077] After adjusting the rotational speed of the molten metal the plasma torch 11 is activated to raise the temperature of the metal until the melting or required treatment is reached and, once achieved, the loading of solid material R (or SM) starts, which is melted by contact with the molten metal stream X in its circulation towards the tapping spout. The incorporation of this metal causes the bath level (molten metal bed) to rise and overflow of the same occurs in the tapping spout, by dragging the floating slag I with it, in the case that a single common tapping spout is used. In this case, the mixture of metal and slag is separated into the exterior siphon (not shown), which pours two separate streams of clean metal and slag. Alternatively, if two tapping spouts 9 9 are used, the floating slag is extracted from the tank in the second tapping spout 9.
[0078] To ensure proper operation of the process, the furnace preferably has the two walls described, placed next to the tapping spout or spouts. The first one (wall 24) is located in the area immediately above the spout (or first spout 9 in the case of two spouts) with respect to the direction of the stream and at flush level with the height of the bath. As explained, its aim is to retain the still unmelted load residue that may remain floating. These remains end up melting by the combined action of the forced convection provided by the circulating metal on a static element and optionally by direct heating of, for example, a low power gas burner situated over the retaining wall 24 itself. The siphoning wall 25 is placed in the rear area of the outlet spout (or between the two spouts 9 9, in the case of two) with respect to the direction of the metal and in the bath its level sinks to a depth sufficient to prevent passage of the slag into the heating chamber D but allows recirculation of metal. In the case of having two tapping spouts 9 9, at its outer end this siphoning wall 25 is directly connected with the second tapping spout 9, through which slag flows by being poured into a separating siphon.
[0079] The substantially slag-free circulating metal enters the heating chamber D, wherein its temperature is raised to the necessary and sufficient extent to melt the solid material which is loaded in the area where the metal leaves said chamber (loading area A), thus initiating again the cycle of melting/treatment and dragging of the loaded material and closing the cycle of melting and casting. This process is automatically controlled by controlling the tapping temperature, for which purpose preferably a thermocouple 32 is used. The increase or decrease of the tapping temperature becomes a parameter indicative of the progress of the process and allows the operator to select the operating parameters according to priority needs of the same. The increase or decrease of the set tapping temperature is corrected by adjusting the volume of the load introduced, by increasing or reducing the applied power, or by a combination of both.
[0080] The process described allows for the use of the furnace in a discretionary way, since, after priming with liquid metal, it can be kept waiting for a solid load during the time necessary. To do this, it is sufficient to adjust the heating power required to maintain the metal at a suitable temperature and adjust the rotation speed to the minimum required for this operation. Since the siphon incorporates its own heating system, the melting process can be interrupted and resumed at the operators will, without any negative consequences to the furnace operation.
[0081]
[0082] The disclosure provides a multidisciplinary melting furnace, suitable for melting and treatment of a wide variety of metals and waste with operational, economic and environmental advantages over currently used furnaces. The high energy efficiency of the furnace of the disclosure is due to the combination of several factors: a) heating occurs preferably through highly efficient plasma arc; b) the circulation of the molten metal under the plasma arc increases the degree of heat transfer; c) the water cooling circuit is preferably limited to the flanges of the electrodes (outside the furnace, so there is no cooling in the furnace itself); d) the magnetic rotor is cooled by air at low pressure; e) the motor which drives the metal movement is low power; the addition of the load to a stream of liquid slag-free metal allows the melting of materials with different forms and structures; g) the furnace is suitable for practically all types of metal melting (iron-, copper- and aluminium-based metals, among others); h) its geometry can be adapted to the needs of the smelter; i) the furnace can operate in automatic mode and does not require any interior manipulation nor opening of gates or inspection traps at any stage of the process; (j) its use is completely discretionary, and may operate as a continuous or discontinuous furnace; k) the stirring of the metal permits the continuous adjustment of the chemical composition by adding alloy-forming elements is possible.
[0083] An experiment carried out with a furnace implemented according to
TABLE-US-00001 C 3.60% Si 2.20% [0084] the rest of the chemical composition being Fe and other residual elements.
[0085] The temperature of the molten metal varies between 1,350 and 1,580 C. The rotor comprises one magnet body having 4 neodymium magnets. The magnetic field at the lateral surface of the rotor (area of maximum magnetism) is 4300 Gauss. The magnetic field at the inner wall of the tank (area of maximum magnetism within the tank) is 380 Gauss. The magnetic field at the outer wall of the tank (area of minimum magnetism within the tank) is 30 Gauss. The linear velocity at the axis of the canal of the molten metal is 18 cm/s at 40 Hz of rotating frequency of the rotor
[0086] Next two examples of application of the furnace are described. First, we describe how the furnace can be used for melting a metal (in particular, iron). Then, we describe how the furnace can be used for treating steel dust.
Example 1: Melting Process: Iron
[0087] The use of the present furnace as a smelting furnace is based on the significant improvement of performance in heat transfer by convection caused by the constant movement of the molten metal around a solid mass. In a static bath of molten iron, the convection coefficient is 1,000 W/m2K, however, this coefficient increases due to the movement of the metal up to 12,000 W/m2K with a circulation speed of 18 cm/sec.
[0088] The melting process begins with the setting of the temperature of the circulating metal (in the case of melting iron the temperature is raised up to 1580 C.). Then the loading of scrap metal at the rear area next to the heating chamber and the melting of the added scrap starts, producing a decrease in temperature of the circulating metal. The temperature of the metal at the output of the furnace is controlled by a submerged thermocouple placed in the area of extraction of metal and slag. This temperature is set preferably at 1400 C. and can be controlled by regulating the quantity of scrap loaded and/or the heating power applied to the plasma torch in the heating chamber. The melting of the metal loaded raises the level of the bath and produces an overflow of metal and slag through the outlet spout. This metal is poured into a crucible that has an intermediate wall and two lateral spouts at different heights, with the separation of the metal being performed through decantation and by tapping the metal through the lower spout and the slag through the upper spout.
[0089] The loaded materials, depending on their density and geometry, can be submerged in the metal bath or float together with the slag, in which case, they are retained by the retaining means located at the opposite end of the canal. This retaining means are located at sufficient distance with respect to the surface of the molten metal bed, in such a way that it allows the slag to pass through, floating on top of the molten metal bed. On the front wall of the furnace (with respect to the direction of circulation of the molten metal) a burner is provided, which allows full fluidization of semi-solid slag to facilitate its passage to the extraction area. In the extraction area, a second burner is provided, which keeps the slag in a liquid state pushing it in the direction in which of the emptying spout. To avoid the slag passing towards the heating chamber, a wall partially submerged in the metal and closing the extraction area is provided. This way the surface of the metal in the heating chamber is free of slag to proceed to a new cycle of overheating and melting of the load.
[0090] The absence of slag in the loading area and the continuous stirring of the metal through the action of the magnetic rotor, permits the addition of the alloy-forming elements necessary to achieve an adequate metallurgical quality to the requirements of the final product.
Example 2: Treating Process: Steel Dust
[0091] Steel dust collected in aspiration electric arc furnace filters (EAFD) is a residue with high concentrations of metal oxides, mainly iron, zinc and lead. For the recovery of these metals by carbon reduction, it is necessary to agglomerate this dust with a product rich in carbon, mainly those comprising the group of metallurgical coke, anthracite, coal and graphite. Preferred forms of agglomeration of the dust are high density briquette produced by pressing or pellet agglomerated by rotation in a pelletizing drum.
[0092] The process of reduction of metal oxides contained in steel dust is carried out by means of the carbon added to the briquette or pellets in such a way that the iron oxide is reduced to metal and becomes part of the molten metal bath. Similarly, other main oxides, Zn and Pb, at first are reduced to metal and, given the volatility of both metals, are dragged towards the gas treatment system where they oxidise easily giving rise to a concentration of oxides, mainly consisting of zinc oxide and lead and, to a lesser extent, of iron oxides, chlorides, silica, alkali, etc. The thick fraction of this concentration of metal oxides is retained in the gas treatment system, which consists of one or more of the following elements: cyclone, bag filter, scrubber.
[0093] The main reduction processes, given the concentration of these oxides in the steelmaking dust are:
FeO+C.Math.Fe+CO H=38.6 kcal/mol
Fe.sub.2O.sub.3+3C.Math.2Fe+3CO H=117.74 kcal/mol
Fe.sub.3O.sub.4+4C.Math.3Fe+4CO H=161.62 kcal/mol
ZnO+C.Math.Zn+CO H=57.34 kcal/mol
PbO+C.Math.Pb+CO H=25.70 kcal/mol
CO.sub.2+C.Math.2CO H=41.21 kcal/mol
[0094] In addition to these primary reactions, other reactions of reduction with CO and side reactions take place that are set out in the following table:
TABLE-US-00002 TABLE 1 Possible reactions and reaction enthalpies in a furnace loaded with steel dust briquettes. Reaction Enthalpy Reaction (kcal/mol) MnO + C = Mn + CO (g) 65.65 3Fe.sub.2O.sub.3 + 9CO (g) = 6 Fe + 9CO.sub.2 (g) 17.67 MnO + CO (g) = Mn + CO.sub.2 (g) 24.44 ZnO + CO (g) = Zn + CO.sub.2 (g) 16.13 PbO + CO (g) = Pb + CO.sub.2 (g) 15.51 Zn = Zn (g) 31.17 Zn (g) + 1/2O.sub.2 (g) = ZnO (s) 114.93 C + O.sub.2 (g) = CO.sub.2 (g) 94.05 2CO = CO.sub.2 (g) + C 41.21 ZnOFe.sub.2O.sub.3 = ZnO + Fe.sub.2O.sub.3 1.04 ZnOFe.sub.2O.sub.3 + CO = Zn + CO.sub.2 (g) + 17.17 Fe.sub.2O.sub.3 3Fe.sub.2O.sub.3 = 6Fe + 9/2O.sub.2 (g) 591.00 PbSO.sub.4 = PbO + SO.sub.2 (g) + 1/2O.sub.2 (g) 97.57 3CaO + P.sub.2O.sub.5 = Ca.sub.3(PO.sub.4).sub.2 172.93 H.sub.2O = H.sub.2O (v) 10.52 NaCl = NaCl (v) 54.90 KCl = KCl (v) 53.06
[0095] The sequence of the carbothermic reduction procedure of the process can be as follows: [0096] a) Reduction of the zinc oxide by C and CO:
ZnO(s)+C.Math.Zn(s)+CO(g)
ZnO(s)+CO.Math.Zn(s)+CO.sub.2(g) [0097] b) A part of the zinc evaporates and the other condenses on the surface of the briquettes, according to the equations:
Zn(s).Math.Zn(g)
Zn(g).Math.Zn(s) [0098] c) Rapid oxidation of zinc gas according to the equation:
Zn(g)+O.sub.2(g).Math.ZnO(s) [0099] d) Zinc oxidation condensed on the surface of the briquette with the iron oxides of the briquette, according to:
Zn(s)+FeO.Math.ZnO(s)+Fe(s) [0100] e) Reduction of iron oxides (FeO,Fe.sub.2O.sub.3, Fe.sub.3O.sub.4) with carbon and CO, according to:
FeO+C.Math.Fe(s)+CO(g)
Fe.sub.2O.sub.3+3C.Math.2Fe(s)+3CO(g)
Fe.sub.2O.sub.3+CO.Math.2Fe(s)+3CO.sub.2(g) [0101] f) These latest reactions are influenced by competition between the oxidation reactions of coal and the Boudouard reaction:
C+O.sub.2(g).Math.CO(g)
C+CO.sub.2(g).Math.2CO(g)
[0102] The process is carried out starting from a molten metal bath, at a temperature between 1,400 and 1,500 C. Auto reduction briquettes or pellets are added to the molten metal bath in order to facilitate the incorporation of reduced iron to the molten metal bath. A bottom bath saturated in carbon is used that does not disturb the effect of the portion of this element which reduces the different iron oxides in the briquettes or pellets for their later addition to the molten metal, thus allowing the evaluation of changes that are produced in the resulting metal depending on the different origins of the processed dust.
[0103] The briquettes or pellets are placed in the loading area which is free of slag, where they float on the overheated molten metal coming from the heating chamber. This molten metal gives some of its energy to the load (briquettes or pellets) and the process of reduction of dust starts while being dragged by the molten metal along the treatment area. During this movement, the metallic fraction of the dust is incorporated into the molten metal bath, the volatile fraction is aspirated and collected in the filters and the inert fraction floats on the molten metal in the form of liquid slag. On arrival at the retaining means ((located at the end of the treatment area and at a maximum height of 2 mm with respect to the bath) all those particles larger than the height of the passage formed are retained until their dissolution. The floating slag continues its circulation under the retaining means until it reaches the siphoning wall (which is sunk up to a maximum of 40 mm in the bath) where, due to the circulation of molten metal, is directed to the outlet spout together with the metal, leaving the tank of the furnace together with the metal by overflow of the bath. On its exit, the mixture of slag and metal is once again siphoned in a crucible with an intermediate wall, and the slag is separated from the metal.
[0104] The process is done automatically, by adjusting the quantity of material loaded and the heating capacity based upon the temperature of the metal and slag at the exit of the furnace, measured by the thermocouple installed in the extraction area.
[0105] In sum, a furnace of discretionary use has been provided, in which the chemical composition can be modified at will thanks to the available access to the clean metal, which permits continuous removal of slag and which can be loaded with any dry metallic waste, while providing an optimized energetic performance.
[0106] On the other hand, the disclosure is obviously not limited to the specific embodiment(s) described herein, but also encompasses any variations that may be considered by any person skilled in the art (for example, as regards the choice of materials, dimensions, components, configuration, etc.).