METHODS OF EDGE FINISHING LAMINATED GLASS STRUCTURES
20180154493 ยท 2018-06-07
Assignee
Inventors
- Dominick John Forenz (Hammondsport, NY, US)
- TIMOTHY DESMOND HARSH (ELMIRA, NY, US)
- Mark Lee Humphrey (Burdett, NY, US)
- Michael William Price (Corning, NY, US)
- Eric Joseph Teator (Corning, NY, US)
- PETER JOSEPH WEBSTER (CORNING, NY, US)
Cpc classification
C03C3/078
CHEMISTRY; METALLURGY
B32B27/06
PERFORMING OPERATIONS; TRANSPORTING
B32B23/00
PERFORMING OPERATIONS; TRANSPORTING
B24B9/065
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B9/04
PERFORMING OPERATIONS; TRANSPORTING
B24D15/04
PERFORMING OPERATIONS; TRANSPORTING
C03C19/00
CHEMISTRY; METALLURGY
B24B23/04
PERFORMING OPERATIONS; TRANSPORTING
B32B21/02
PERFORMING OPERATIONS; TRANSPORTING
B32B21/14
PERFORMING OPERATIONS; TRANSPORTING
B32B7/14
PERFORMING OPERATIONS; TRANSPORTING
B32B15/20
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/546
PERFORMING OPERATIONS; TRANSPORTING
B32B3/02
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B3/02
PERFORMING OPERATIONS; TRANSPORTING
C03C19/00
CHEMISTRY; METALLURGY
B24B23/04
PERFORMING OPERATIONS; TRANSPORTING
B32B17/06
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method of finishing a laminated glass structure (102) comprising a flexible glass sheet (130) having a thickness of no greater than about 0.3 mm laminated to a non-glass substrate (116) by an adhesive layer (135) is provided. The method includes applying a compressive force against a cut edge (106) of the flexible glass sheet (130) using an abrasive surface (108) of a hand-held finishing tool (105). Material of the laminated glass structure (102) is removed at the cut edge (106) such that a glass edge strength of the flexible glass sheet (130) is at least about 50 MPa.
Claims
1. A method of finishing a laminated glass structure comprising a flexible glass sheet having a thickness of no greater than about 0.3 mm laminated to a non-glass substrate by an adhesive layer, the method comprising: applying a compressive force against a cut edge of the flexible glass sheet using an abrasive surface of a hand-held finishing tool; and removing material of the laminated glass structure at the cut edge such that a glass edge strength of the flexible glass sheet is at least about 50 MPa.
2. The method of claim 1, wherein the abrasive surface comprises an abrasive material having an ISO/FEPA grit designation of 180 or finer.
3. The method of claim 1 further comprising directing a liquid over the cut edge during the step of removing material of the laminated glass structure.
4. The method of claim 1 further comprising positioning the abrasive surface at an angle of no more than about 20 degrees to a plane transverse to a broad surface of the flexible glass sheet during the step of removing material of the laminated glass structure.
5. The method of claim 1, wherein the finishing tool is a sanding block and the abrasive surface is provided by sandpaper.
6. The method of claim 1, wherein the finishing tool is an orbital sander comprising a head that includes the abrasive surface.
7. The method of claim 1, wherein the finishing tool is a belt sander comprising a belt that includes the abrasive surface.
8. The method of claim 1, wherein the finishing tool comprises a compliant sanding ball that includes the abrasive material.
9. The method of claim 8, wherein the compliant sanding ball has a durometer of between of about 20 Shore A to about 35 Shore A.
10. The method of claim 1, wherein the finishing tool comprises an inflatable bulb and a sanding sleeve carried by the inflatable bulb and including the abrasive material.
11. A method of finishing a laminated glass structure comprising a flexible glass sheet having a thickness of no greater than about 0.3 mm laminated to a non-glass substrate by an adhesive material, the method comprising: supporting the laminated glass structure on a support surface such that the non-glass substrate is located between the flexible glass sheet and the support surface; removing material of the laminated glass structure at a cut edge using an abrasive surface of a finishing tool; and positioning the abrasive surface at an angle of no more than about 20 degrees to a plane transverse to a broad surface of the flexible glass sheet during the step of removing material of the laminated glass structure.
12-13. (canceled)
14. The method of claim 11, wherein the finishing tool is a sanding block and the abrasive surface is provided by sandpaper.
15. The method of claim 11, wherein the finishing tool is an orbital sander comprising a head that includes the abrasive surface.
16. The method of claim 11, wherein the finishing tool is a belt sander comprising a belt that includes the abrasive surface.
17. The method of claim 11, wherein the finishing tool comprises a compliant sanding ball that includes the abrasive material, and the compliant sanding ball has a durometer of about 20 Shore A to about 35 Shore A.
18. (canceled)
19. The method of claim 11, wherein the finishing tool comprises an inflatable bulb and a sanding sleeve carried by the inflatable bulb and including the abrasive material.
20. A method of finishing a laminated glass structure comprising a flexible glass sheet having a thickness of no greater than about 0.3 mm laminated to a non-glass substrate by an adhesive material, the method comprising: supporting the laminated glass structure on a support surface such that the non-glass substrate is located between the flexible glass sheet and the support surface; and removing material of the laminated glass structure at a cut edge using an abrasive surface of a finishing tool; wherein the abrasive surface of the finishing tool is compliant and resiliently deflects as a compressive force is applied against the cut edge of the flexible glass sheet using the abrasive surface during the step of removing the material of the laminated glass structure.
21. The method of claim 20, wherein the step of removing material of the laminated glass structure at the cut edge is such that a glass edge strength of the flexible glass sheet is at least about 50 MPa.
22-23. (canceled)
24. The method of claim 20, wherein at least one of: the finishing tool is a sanding block and the abrasive surface is provided by sandpaper; the finishing tool is an orbital sander comprising a head that includes the abrasive surface; or the finishing tool is a belt sander comprising a belt that includes the abrasive surface.
25-26. (canceled)
27. The method of claim 20, wherein the finishing tool comprises a compliant sanding ball that includes the abrasive material, and the compliant sanding ball has a durometer of about 20 Shore A to about 35 Shore A.
28. (canceled)
29. The method of claim 20, wherein the finishing tool comprises an inflatable bulb and a sanding sleeve carried by the inflatable bulb and including the abrasive material.
30. The method of claim 20 further comprising positioning the abrasive surface at an angle of no more than about 20 degrees to a plane transverse to a broad surface of the flexible glass sheet during the step of removing material of the laminated glass structure.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0038] These and other features, aspects and advantages of the present disclosure are better understood when the following detailed description of the disclosure is read with reference to the accompanying drawings, in which:
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DETAILED DESCRIPTION
[0056] In the following detailed description, for purposes of explanation and not limitation, example embodiments disclosing specific details are set forth to provide a thorough understanding of various principles of the present disclosure. However, it will be apparent to one having ordinary skill in the art, having had the benefit of the present disclosure, that the present disclosure may be practiced in other embodiments that depart from the specific details disclosed herein. Moreover, descriptions of well-known devices, methods and materials may be omitted so as not to obscure the description of various principles of the present disclosure. Finally, wherever applicable, like reference numerals refer to like elements.
[0057] Ranges can be expressed herein as from about one particular value, and/or to about another particular value. When such a range is expressed, another embodiment includes from the one particular value and/or to the other particular value. Similarly, when values are expressed as approximations, by use of the antecedent about, it will be understood that the particular value forms another embodiment. It will be further understood that the endpoints of each of the ranges are significant both in relation to the other endpoint, and independently of the other endpoint.
[0058] Directional terms as used hereinfor example up, down, right, left, front, back, top, bottomare made only with reference to the figures as drawn and are not intended to imply absolute orientation.
[0059] Unless otherwise expressly stated, it is in no way intended that any method set forth herein be construed as requiring that its steps be performed in a specific order. Accordingly, where a method claim does not actually recite an order to be followed by its steps or it is not otherwise specifically stated in the claims or descriptions that the steps are to be limited to a specific order, it is no way intended that an order be inferred, in any respect. This holds for any possible non-express basis for interpretation, including: matters of logic with respect to arrangement of steps or operational flow; plain meaning derived from grammatical organization or punctuation; the number or type of embodiments described in the specification.
[0060] As used herein, the singular forms a, an and the include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to a component includes aspects having two or more such components, unless the context clearly indicates otherwise.
[0061] Although glass is an inherently strong material, its strength and mechanical reliability is a function of its surface defect or flaw size density distribution and the cumulative exposure of stress to the material over time. During an entire product life cycle, a laminated glass structure may be subjected to various kinds of static and dynamic mechanical stresses. Embodiments described herein generally relate to methods of finishing laminated glass structures at an installation location or machining environment. Particular examples may relate to laminated glass structures where the non-glass substrate is a wood, fiberboard, laminate, polymer and/or metal or metal alloy, such as stainless steel, aluminum, nickel, magnesium, brass, bronze, titanium, tungsten, copper, cast iron or a noble metal.
[0062] Referring to
[0063] The non-glass substrate 18 may be formed using a polymer material, for example, any one or more of polyethylene teraphthalate (PET), polyethylene Naphthalate (PEN), ethylene tetrafluoroethylene (ETFE), or thermopolymer polyolefin (TPOpolymer/filler blends of polyethylene, polypropylene, block copolymer polypropylene (BCPP), or rubber), polyesters, polycarbonate, polyvinylbuterate, polyvinyl chloride, polyethylene and substituted polyethylenes, polyhydroxybutyrates, polyhydroxyvinylbutyrates, polyetherimides, polyamides, polyethylenenaphalate, polyimides, polyethers, polysulphones, polyvinylacetylenes, transparent thermoplastics, transparent polybutadienes, polycyanoacrylates, cellulose-based polymers, polyacrylates and polymethacrylates, polyvinylalcohol, polysulphides, polyvinyl butyral, polymethyl methacrylate and polysiloxanes. It is also possible to use polymers which can be deposited/coated as pre-polymers or pre-compounds and then converted, such as epoxy-resins, polyurethanes, phenol-formaldehyde resins, and melamine-formaldehyde resins. Many display and electrical applications may prefer acrylic based polymers, silicones and such structural aiding layers, for example, commercially available SentryGlas from DuPont. The polymer layers may be transparent for some applications, but need not be for other applications.
[0064] An adhesive layer 20 may be formed of an adhesive material 22 that may be used to laminate the flexible glass layer 12 to the non-glass substrate layer 16 at the interfaces between their respective broad surfaces 24 and 26. The adhesive material 22 may be a non-adhesive interlayer, an adhesive, a sheet or film of adhesive, a liquid adhesive, a powder adhesive, a pressure sensitive adhesive, an ultraviolet-light curable adhesive, a thermally curable adhesive, or other similar adhesive or combination thereof. The adhesive material 22 may assist in attaching the flexible glass 14 to the non-glass substrate 18 during lamination. Some examples of low temperature adhesive materials include Norland 68 cured by UV, Flexcon V29TT, 3M OCA 8211, 8212, 8146, and 8172 (bonded by pressure at room temperature or above), 3M 4905, OptiClear adhesive, silicones, acrylates, optically clear adhesives, encaptulant material, polyurethane polyvinylbutyrates, ethylenevinylacetates, ionomers, and wood glues. Typical graphic adhesives such as Graphicmount and Facemount may also be used (as available from LexJet Corporation, located in Sarasota Fla., for example). Some examples of higher temperature adhesive materials include DuPont SentryGlas, DuPont PV 5411, Japan World Corporation material FAS and polyvinyl butyral resin. The adhesive layer 20 may be thin, having a thickness less than or equal to about 1000 m, including less than or equal to about 500 m, about 250 m, less than or equal to about 50 m, less than or equal to 40 m, less than or equal to about 25 m, or between about 0.1 mm and about 5 mm. The adhesives may also contain other functional components such as color, decoration, heat or UV resistance, AR filtration etc. The adhesive material 22 may be optically clear on cure, or may otherwise be opaque. In embodiments where the adhesive material 22 is a sheet or film of adhesive, the adhesive material 22 may have a decorative pattern or design visible through the thickness of the flexible glass, as shown in
[0065] In
[0066] The flexible glass sheet 14 may have a thickness 34 of about 0.3 mm or less including but not limited to thicknesses of, for example, about 0.01-0.05 mm, about 0.05-0.1 mm, about 0.1-0.15 mm, about 0.15-0.3 mm, about 0.100 to about 0.200 mm, 0.3, 0.275, 0.25, 0.225, 0.2, 0.19, 0.18, 0.17, 0.16, 0.15, 0.14, 0.13, 0.12, 0.11, 0.10, 0.09, 0.08 0.07, 0.06, 0.05, 0.04, 0.03, 0.02, or 0.01 mm. The flexible glass sheet 14 may be formed of glass, a glass ceramic, a ceramic material or composites thereof. A fusion process (e.g., downdraw process) that forms high quality flexible glass sheets can be used in a variety of devices and one such application is flat panel displays. Glass sheets produced in a fusion process have surfaces with superior flatness and smoothness when compared to glass sheets produced by other methods. The fusion process is described in U.S. Pat. Nos. 3,338,696 and 3,682,609. Other suitable glass sheet forming methods include a float process, updraw and slot draw methods. Additionally, the flexible glass sheet 14 may also contain anti-microbial properties by using a chemical composition for the glass including an Ag ion concentration on the surface in the range greater than 0 to 0.047 g/cm.sup.2, further described in U.S. Patent Application Publication No. 2012/0034435 A1. The flexible glass 14 may also be coated with a glaze composed of silver, or otherwise doped with silver ions, to gain the desired anti-microbial properties, as further described in U.S. Patent Application Publication No. 2011/0081542 A1. Additionally, the flexible glass 14 may have a molar composition of 50% SiO.sub.2, 25% CaO, and 25% Na.sub.2O to achieve the desired anti-microbial effects.
[0067] Once the flexible glass sheet 14 is formed, it may be laminated to the non-glass substrate 18 using a variety of apparatus and processes. Some examples include sheet-to-sheet lamination where pressure and/or heat are used to bond the flexible glass sheet 14 to the non-glass substrate 18, for example, using the adhesive material 22. As another example, a roll-to-sheet or roll-to-roll lamination method may be used where; again, pressure is used to bond a continuous ribbon of flexible glass sheet 14 from a supply roll to a non-glass substrate 18 either as a continuous substrate from a supply roll or a plurality of individual substrates. While it may be possible to form the laminated glass structure to a final, desired dimension, it may be the case that some type of shaping (e.g., cutting) of the laminated glass structure will be needed after the laminated glass structure is formed. In these instances, the laminated glass structure may be referred to as a preform laminated glass structure in that the preform laminated glass structure will undergo final processing in the field, for example, at an installation site to desired dimensions.
[0068] Without wishing to be bound by theory, one difficulty that may be encountered during cutting of the laminated glass structures to a predetermined dimension is maintaining an acceptable edge quality of the flexible glass sheet 14. Edge quality of the flexible glass sheet 14 is related to edge strength and the possibility of initiation/formation of undesirable or unintended cracks and fractures in the flexible glass sheet 14. As used herein, edge strength refers to the strength of a flexible glass sheet of a laminated glass structure determined using a modified procedure based on the procedure described in ASTM C-158 Standard Test Methods for Strength of Glass by Flexure (Determination of Modulus of Rupture), which is incorporated herein by reference in its entirety. The modified procedure is generally the same as the procedure described in ASTM C-158, except for an additional calculation performed to determine the glass strength. The modified procedure includes determining a load vs. glass stress calibration curve for the laminated glass structure using one of the following methods: 1) directly measuring the strain in the flexible glass sheet (e.g., by a strain gauge) at multiple loads and then calculating stress in the flexible glass sheet at the multiple loads using its elastic modulus, 2) directly measuring the stress in the flexible glass sheet (e.g., by a stress optical method) at multiple loads, or 3) beam theory analysis of the laminated glass structure, which may be difficult due to uncertainties in the adhesive properties. The laminated glass structure is tested using the procedure described in ASTM C-158 to determine the load at which the flexible glass sheet (as opposed to the complete laminated glass structure) fails, and the calibration curve is used to translate the determined failure load into a glass stress value, which is reported as the glass strength. In some embodiments, it may be desirable to maintain a predetermined edge strength in the flexible glass sheet 14 after cutting and an even higher predetermined edge strength after edge finishing the flexible glass sheet 14. For example, maintaining an edge strength in the flexible glass sheet 14 of at least about 50 MPa can allow the flexible glass sheet 14 of the laminated glass structure 10 to survive end use conditions, such as handling and installation, without forming cracks and fractures in the flexible glass sheet 14. However, specialized tools for cutting and finishing the flexible glass sheet 14 are generally not available in manufacturing and installation environments. It has been found that, under predetermined conditions, finishing methods and equipment that are not typically used for at least one of the materials in the laminated glass structure can be used to finish the laminated glass structures 10 (e.g., flexible glass sheet 14, adhesive material 22 and non-glass substrate 18), and, in some embodiments, can maintain or provide a predetermined edge strength of at least about 50 MPa, such as at least about 70 MPa in the flexible glass sheets 14.
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[0081] The systems and methods of finishing laminated glass structures described above allow for use of manufacturing-based finishing methods and machines, such as rotary tools and compliant finishing equipment, while maintaining edge strengths of the flexible glass sheets of at least about 50 MPa, such as about 70 MPa. While manual finishing is described primarily above, other automated tools may be used such as a computerized numerical control (CNC) machine, which can utilize one or more of the sanding structures or variations thereon suitable for use with a CNC machine. The flexible glass sheets can be maintained in compression throughout the finishing process and a finishing angle can be maintained to achieve acceptable edge strength. The finishing systems and methods facilitate repair of any damage flexible glass sheets and maintain life expectance of the flexible glass laminate. Finishing operations can be conducted in the field or manufacturing environment where cutting of the flexible glass laminates may take place.
[0082] Although the laminated glass structure 10 is described herein as comprising a single flexible glass sheet 14 laminated to the non-glass substrate 18, other embodiments are included in this disclosure. In some embodiments, the laminated glass structure comprises a second flexible glass sheet laminated to the non-glass substrate. For example, the second flexible glass sheet can be laminated to a second broad surface of the non-glass substrate opposite the first flexible glass sheet. The second flexible glass sheet can be laminated to the non-glass substrate as described herein with respect to the first flexible glass sheet, and one or more edges of the second flexible glass sheet can be finished using the processes described herein with respect to the first flexible glass sheet.
[0083] It should be emphasized that the above-described embodiments of the present disclosure, including any embodiments, are merely possible examples of implementations, merely set forth for a clear understanding of various principles of the disclosure. Many variations and modifications may be made to the above-described embodiments of the disclosure without departing substantially from the spirit and various principles of the disclosure. All such modifications and variations are intended to be included herein within the scope of this disclosure and the present disclosure and protected by the following claims.