Tire having low rolling resistance
09987884 ยท 2018-06-05
Assignee
Inventors
- Bernard Guerinon (Clermont-Ferrand, FR)
- Eric Berger (Clermont-Ferrand, FR)
- Melaine Guillou (Clermont-Ferrand, FR)
- BERTRAND BOISDON (Clermont-Ferrand, FR)
- CHRISTINE NOURRY (Clermont-Ferrand, FR)
Cpc classification
B60C2011/1286
PERFORMING OPERATIONS; TRANSPORTING
B60C11/0058
PERFORMING OPERATIONS; TRANSPORTING
B60C11/11
PERFORMING OPERATIONS; TRANSPORTING
Y02T10/86
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B60C2011/129
PERFORMING OPERATIONS; TRANSPORTING
B60C5/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
B60C11/00
PERFORMING OPERATIONS; TRANSPORTING
B60C5/00
PERFORMING OPERATIONS; TRANSPORTING
B60C11/11
PERFORMING OPERATIONS; TRANSPORTING
B60C1/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
Tire tread having a central part (I) made from at least one first rubber compound and having at least one circumferential rib (121-123) formed of a plurality of blocks (1210) separated by sipes; a first and a second lateral part (II and III) made of at least a second and third rubber compound, and having a circumferential rib (131,141) formed by a plurality of blocks (1310,1410), separated by sipes, wherein the at least one second and third rubber compounds have a value of tan at 23 C.at a frequency of 10 Hz and an elongation of 10% of less than 0.25, wherein the complex modulus G*(T) of the at least one first rubber compound is greater than the complex moduli G*(T) of at least one second and third rubber compounds for all temperatures T greater than or equal to 0 and less than or equal to 60 C.
Claims
1. A tire comprising: two beads intended to come into contact with a mounting rim, each bead comprising at least one annular reinforcing structure defining a median plane perpendicular to an axis of rotation of the tire and situated equidistant from the annular reinforcing structures of each bead, two sidewalls extending the beads radially outwards, the two sidewalls meeting in a crown comprising a crown reinforcement radially surmounted by a sub-tread extending across an entire axial width of the crown reinforcement and itself surmounted by a tread provided with a tread pattern formed of elements in relief, the tread having, in each radial section, a first axial edge and a second axial edge; wherein the tread comprises: a central part made of at least one first rubber compound extending, in each radial section, on either side of the median plane, between a first axial end and a second axial end, the central part comprising at least one circumferential rib, each rib being formed of a plurality of blocks separated by sipes so that a mean distance separating two adjacent blocks is less than 0.8 mm, a number of blocks being greater than or equal to 100; a first lateral part made of at least one second rubber compound, extending from the first axial edge of the tread as far as the first axial end of said central part, the first lateral part comprising at least one circumferential rib formed by a plurality of blocks separated by sipes so that a mean distance separating two adjacent blocks is greater than 0.8 mm and less than 5 mm, a number of blocks being less than the number of blocks that make up each at least one circumferential rib of the central part; and a second lateral part made of at least one third rubber compound, extending from the second axial edge of the tread as far as the second axial end of said central part, the second lateral part comprising at least one circumferential rib formed by a plurality of blocks separated by sipes so that a mean distance separating two adjacent blocks is greater than 0.8 mm and less than 5 mm, a number of blocks being less than the number of blocks that make up each at least one circumferential rib of the central part; wherein the at least one second and third rubber compounds have a value of tan at 23 C., at a frequency of 10 Hz and an elongation of 10%, which is less than 0.25; and wherein the complex modulus G*(T) of said at least one first rubber compound is greater than the complex moduli G*(T) of said at least one second and third rubber compounds for all temperatures T greater than or equal to 0 and less than or equal to 60 C., wherein each rib of the central part satisfies the following inequality:
0.90.Math.EC/RC<SLEC/(2.Math..Math.RC)<1.10.Math.EC/RC where EC denotes the mean radial thickness of the tread measured at each rib of the central part, RC denotes the mean radius of ech rib of the central part, and SLEC denotes the sum of the mean circumferential widths of the sipes of each rib of the central part, and wherein each rib of the first lateral part and of the second lateral part satisfies the following inequality:
1.50.Math.EL/RL<SLEL/(2.Math..Math.RL) where EL denotes the mean radial thickness of the tread measured at each rib of the lateral part, RL denotes the mean radius of each rib of the lateral part, and SLEL denotes the sum of the mean circumferential widths of the sipes of each rib of the lateral part.
2. A tire comprising: two beads intended to come into contact with a mounting rim, each bead comprising at least one annular reinforcing structure defining a median plane perpendicular to an axis of rotation of the tire and situated equidistant from the annular reinforcing structures of each bead, two sidewalls extending the beads radially outwards, the two sidewalls meeting in a crown comprising a crown reinforcement radially surmounted by a sub-tread extending across an entire axial width of the crown reinforcement and itself surmounted by a tread provided with a tread pattern formed of elements in relief, the tread having, in each radial section, a first axial edge and a second axial edge; wherein the tread comprises: a central part made of at least one first rubber compound extending, in each radial section, on either side of the median plane, between a first axial end and a second axial end, the central part comprising at least two circumferential ribs, each rib being formed of a plurality of blocks separated by sipes so that a mean distance separating two adjacent blocks is less than 0.8 mm, a number of blocks in each rib being greater than or equal to 100; a first lateral part made of at least one second rubber compound, extending from the first axial edge of the tread as far as the first axial end of said central part, the first lateral part comprising at least one circumferential rib formed by a plurality of blocks separated by sipes so that a mean distance separating two adjacent blocks is greater than 0.8 mm and less than 5 mm, a number of blocks being less than the number of blocks that make up each of the at least two circumferential ribs of the central part; and a second lateral part made of at least one third rubber compound, extending from the second axial edge of the tread as far as the second axial end of said central part, the second lateral part comprising at least one circumferential rib formed by a plurality of blocks separated by sipes so that a mean distance separating two adjacent blocks is greater than 0.8 mm and less than 5 mm, a number of blocks being less than the number of blocks that make up each of the at least two circumferential ribs of the central part; wherein the at least one second and third rubber compounds have a value of tan at 23 C., at a frequency of 10 Hz and an elongation of 10%, which is less than 0.25; wherein the complex modulus G*(T) of said at least one first rubber compound is greater than the complex moduli G*(T) of said at least one second and third rubber compounds for all temperatures T greater than or equal to 0 and less than or equal to 60 C., and wherein each of said at least two ribs of the central part satisfies the following inequality:
0.90.Math.EC/RC<SLEC/(2.Math..Math.RC)<1.10.Math.EC/RC where EC denotes the mean radial thickness of the tread measured at each rib of the central part, RC denotes the mean radius of each rib of the central part, and SLEC denotes the sum of the mean circumferential widths of the sipes of each rib of the central part, and wherein each rib of the first lateral part and of the second lateral part satisfies the following inequality:
1.50.Math.EL/RL<SLEL/(2.Math..Math.RL) where EL denotes the mean radial thickness of the tread measured at each rib of the lateral part, RL denotes the mean radius of each rib of the lateral part, and SLEL denotes the sum of the mean circumferential widths of the sipes of each rib of the lateral part.
3. The tire according to claim 2, wherein the sub-tread is made of at least one fourth rubber compound having a complex modulus G*(T) and a value of tan at 23 C., at a frequency of 10 Hz and an elongation of 10%, which are such that the complex modulus G*(T) of the sub-tread is less than the complex moduli G*(T) of said at least one first, second and third rubber compounds for all temperatures T greater than or equal to 0 and less than or equal to 60 C., and that its value of tan is less than the tan value of said at least one first, second and third rubber compounds.
4. The tire according to claim 2, wherein the at least one third rubber compound is identical to said at least one second rubber compound.
5. The tire according to claim 2, wherein each boundary between said central part and said first and second lateral parts lies in a circumferential groove of the tread.
6. The tire according to claim 2, wherein each boundary between said central part and each of the said first and second lateral parts is formed of an interface surface, the interface surface being inclined with respect to the median plane so that in each radial section, the intersection of the interface surface with the radially outer surface of the tread is axially on the inside of the intersection of the interface surface with the surface of the tread in contact with said sub-tread.
7. The tire according to claim 2, wherein the central part consists of two circumferential ribs.
8. The tire according to claim 2, wherein the central part consists of three circumferential ribs.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) All the figures in this document are schematic.
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DETAILED DESCRIPTION OF THE INVENTION
(11) When using the term radial it is appropriate to make a distinction between the various different uses made of this word by those skilled in the art. Firstly, the expression refers to a radius of the tire. It is in this sense that a point P1 is said to be radially inside a point P2 (or radially on the inside of the point P2) if it is closer to the axis of rotation of the tire than is the point P2. Conversely, a point P3 is said to be radially outside a point P4 (or radially on the outside of the point P4) if it is further away from the axis of rotation of the tire than is the point P4. Progress will be said to be radially inwards (or outwards) when it is in the direction towards smaller (or larger) radii. It is this sense of the term that applies also when matters of radial distances are being discussed.
(12) By contrast, a thread or a reinforcement is said to be radial when the thread or the reinforcing elements of the reinforcement make an angle greater than or equal to 80 and less than or equal to 90 with the circumferential direction. Let us specify that, in this document, the term thread is to be understood in a very general sense and comprises threads in the form of monofilaments, multifilaments, cords, folded yarns or equivalent assemblies, irrespective of the material of which the thread is made or of any surface treatment it may have received in order to enhance its bonding with the rubber compound in which it is embedded.
(13) Finally, a radial section or radial cross section here means a section or a cross section on a plane containing the axis of rotation of the tire.
(14) An axial direction is a direction parallel to the axis of rotation of the tire. A point P5 is said to be axially inside a point P6 (or axially on the inside of the point P6) if it is closer to the median plane of the tire than is the point P6. Conversely, a point P7 is said to be axially outside a point P8 (or axially on the outside of the point P8) if it is further away from the median plane of the tire than is the point P8. The median plane of the tire is the plane which is perpendicular to the axis of rotation of the tire and which lies equal distances from the annular reinforcing structures of each bead. When the median plane is said to separate, in any radial section, the tire into two tire halves, that does not mean that the median plane necessarily constitutes a plane of symmetry of the tire. The expression tire half here has a broader meaning and denotes a portion of the tire that has an axial width of close to half the axial width of the tire.
(15) A circumferential direction is a direction which is perpendicular both to a radius of the tire and to the axial direction.
(16) The rolling surface of a tread in this document denotes all those points on the tread that come into contact with the ground when the tireinflated to its service pressureis running along the ground.
(17) In the context of this document, the expression rubber compound denotes a compound of rubber containing at least one elastomer and a filler.
(18) In this document, tan denotes a dynamic property well known to those skilled in the art. This property is measured on a Metravib VA4000 viscoanalyser on test specimens moulded from uncured compositions or on test specimens which have been bonded from cured compositions. Test specimens such as those described in Standard ASTM D 5992-96 (the version published in September 2006, initially approved in 1996) in Figure X2.1 (circular embodiment) are used. The diameter d of the test specimen is 10 mm (it therefore has a circular cross section of 78.5 mm.sup.2), the thickness L of each of the portions of rubber composition is 2 mm, giving a d/L ratio of 5 (in contrast with Standard ISO 2856 mentioned in the ASTM Standard, paragraph X2.4, which recommends a d/L value of 2).
(19) The response of a test specimen of vulcanized rubber composition subjected to a simple alternating sinusoidal shear loading at a frequency of 10 Hz and a stabilized temperature at the recommended value (for example, 23 C.) is recorded. The test specimen is loaded symmetrically about its equilibrium position. The sweep covers amplitudes of deformation from 0.1% to 50% (peak-peak; on the outward cycle; 12 measurement points), then from 50% to 0.1% (peak-peak; on the return cycle; 11 measurement points). Following each data acquisition, the dynamic shear elastic modulus (or dynamic modulus; G) and the viscous shear modulus (G) on the return cycle, together with the loss factor tan , which corresponds to the ration G/G, are calculated.
(20) The complex modulus G* is defined as the absolute value of the complex sum of the elastic modulus G and viscous modulus G:
G*={square root over (G.sup.2+G.sup.2)}.
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(24) The way in which the axial edges of a tread are determined is illustrated in
(25) As suggested by
(26) TABLE-US-00001 TABLE I Sub-tread 35 Tread 40 G* (10 Hz/10%/23 C.) 3.00 2.25 tan (10%/23 C.) 0.100 0.290
(27) The two ribs of the central part are formed of a plurality of blocks 1210 and 1220 separated by sipes; the mean distance E separating two adjacent blocks is equal to 0.8 mm, and the number of blocks in each rib is equal to 80.
(28) The ribs 131 and 141 of the two lateral parts are formed of a plurality of blocks 1310 and 1410 separated by sipes; the mean distance E separating two adjacent blocks is equal to 5.4 mm, and the number of blocks in each rib is equal to 80.
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(30) The tread comprises a central part I (
(31) The tread comprises a first lateral part II (
(32) The tread further comprises a second lateral part III (
(33) In this particular instance, the boundaries between the central part I and the first and second lateral parts II and III lie in circumferential grooves of the tread.
(34) Table II gives, by way of example, the formulation of rubber compounds that can be used to make the tread and a sub-tread of a tire according to an embodiment of the invention. The formulation is given in phr (per hundred rubber), namely in parts by weight per 100 parts by weight of elastomer. The corresponding values for G* (10 Hz/10%/23 C.) and tan (10%/23 C.) are likewise given. BR1, BR2 and BR3 denote the said first, second and third rubber compounds, BR-T denotes a reference compound; SC denotes the rubber compound of the sub-tread and SC-T a reference sub-tread compound.
(35) TABLE-US-00002 TABLE II Parts in phr BR1 BR2 = BR3 BR-T SC SC-T NR 60 60 SBR A [1] 100 100 SBR B [2] 20 BR [3] 80 40 40 N 234 3 3 3 N 683 30 60 Silica 80 110 73 Resin [4] 50 34 20 Oleic sunflower oil [5] 10 8 MES/HPD 6 TESPT [6] 6.4 8.8 5.8 DPG [7] 1.6 1.8 1.3 Antioxidant [8] 2.7 2.7 2.2 1.3 1.3 Stearic acid 2 2 1.6 0.5 0.5 ZnO 1.2 1.2 1.0 3 3 Accelerant [9] 2.3 2.3 1.6 1.5 1.5 Sulphur 1 1 1 2.5 2.5 G* (10Hz/10%/23 C.) 3.50 1.45 2.25 1.40 3.00 tan (10%/23 C.) 0.360 0.220 0.290 0.04 0.100
(36) Annotations in Table II:
(37) [1] SSBR with 24% 1,2-polybutadiene units; 26.5% stirene; Tg=48 C.
(38) [2] SSBR with 58% 1,2-polybutadiene units; 25% stirene; Tg=30 C.
(39) [3] BR (with 0.3% of 1,2-; 2.7% trans) 97% cis-1,4-; Tg=103 C.
(40) [4] High Tg plasticizing resin Escorez 5600 marketed by the Exxon company
(41) [5] Lubrirob TOD 1880 marketed by the Novance company
(42) [6] TESPT (Si69 by the Evonik company);
(43) [7] Diphenylguanidine (Vulcacit D by the Bayer company)
(44) [8] N-1,3-dimethylbutyl-N-phenyl-para-phenylenediamine (Santoflex 6-PPD by the Flexsys company)
(45) [9] N-cyclohexyl-2-benzothiazyl-sulphenamide (CBS; Santocure by the Flexsys company).
(46) The rubber composition is preferably based on at least one diene elastomer, a reinforcing filler and a crosslinking system.
(47) A diene elastomer (used interchangeably with the word rubber) means, in the known way, an elastomer derived at least in part (i.e. a homopolymer or a copolymer) of diene monomers which means monomers carrying two carbon-carbon double bonds, conjugated or otherwise. The diene elastomer used is preferably selected from the group consisting of polybutadienes (BR), natural rubber (NR), synthetic polyisoprenes (IR), butadiene-stirene copolymers (SBR), isoprene-butadiene copolymers (BIR), isoprene-stirene copolymers (SIR), butadiene-stirene-isoprene copolymers (SBIR) and blends of these elastomers.
(48) One preferred embodiment is to use an isoprene elastomer which means a homopolymer or copolymer of isoprene, in other words a diene elastomer selected from the group consisting of natural rubber (NR), synthetic polyisoprenes (IR), the various copolymers of isoprene and blends of these elastomers.
(49) The isoprene elastomer is preferably natural rubber or a synthetic polyisoprene of cis-1,4 type. Among these synthetic polyisoprenes, use is preferably made of polyisoprenes that have a cis-1,4 bonds content (mol %) higher than 90%, more preferably still, higher than 95%. According to other preferential embodiments, the diene elastomer may consist, in full or in part, of another diene elastomer such as, for example, an SBR elastomer (E-SBR or S-SBR) used cut or otherwise with another elastomer, for example of the BR type.
(50) The rubber composition may also contain all or some of the additives conventionally used in rubber matrices intended for the manufacture of tires, such as, for example, reinforcing fillers such as carbon black or inorganic fillers such as silica, coupling agents for inorganic filler, anti-ageing agents, antioxidants, plasticizers or extension oils, whether the latter are of aromatic or non-aromatic nature (notably oils which are very weakly or not at all aromatic, for example of the naphthene or paraffin oil type, of high or preferably low viscosity, MES or TDAE oils), plasticizing resins with a high Tg above 30 C.), processability agents to aid the processing of compositions in the uncured state, tackifying resins, a crosslinking system based either on sulphur or on donors of sulphur and/or peroxide, vulcanization activators or retardants or accelerators, anti-reversion agents, methylene acceptors and donors such as, for example HMT (hexamethylenetetramine) or H3M (hexamethoxymethylmelamine), reinforcing resins (such as resorcinol or bismaleimide).
(51) The compositions are produced in suitable mills using two successive preparation phases well known to those skilled in the art: a first phase of thermomechanical kneading or working (the phase referred to as the non-productive phase) at high temperature, up to a maximum temperature of between 110 C. and 190 C., preferably between 130 C. and 180 C., followed by a second phase of mechanical work (phase referred to as the productive phase) down to a lower temperature, typically of less than 110 C., during which finishing phase the crosslinking system is incorporated.
(52) By way of example, the non-productive phase is performed in a single thermomechanical step lasting a few minutes (for example between 2 and 10 min) during which all the necessary basic constituents and other additives apart from the crosslinking or vulcanization system are introduced into a suitable mill such as a conventional internal mixer. Once the mixture thus obtained has cooled, the vulcanization system is then incorporated in an external mixer such as an open mill, kept at a low temperature (for example of between 30 C. and 100 C.). The mixture is then mixed (productive phase) for a few minutes (for example between 5 and 15 min).
(53) The final composition thus obtained is then calendered, for example into the form of a sheet or plate for characterizing, or is alternatively extruded, to form the tread or the sub-tread used in a tire according to an embodiment of the invention.
(54) Vulcanization (or curing) can then be carried out in the known way at a temperature generally of between 130 C. and 200 C., preferably under pressure, for a sufficient length of time which may vary for example between 5 and 90 min notably depending on the curing temperature, on the vulcanization system adopted and on the vulcanization dynamics of the composition in question.
(55) Let EC denote the mean radial thickness of the tread measured at the rib of the central part, and let RC denote the mean radius of the rib of the central part (see
(56) The tire of
(57) TABLE-US-00003 TABLE III Tire according to an Reference embodiment of the tire invention EC (mm) 10 10 EL (mm) 10 10 RC (mm) 312.5 312.5 RL (mm) 308 308 SLEC (mm) 80 (rib 1) 65 156 (rib 2) SLEL (mm) 435 105 EC/RC 0.032 0.032 0.9 .Math. EC/RC 0.0288 0.0288 SLEC/(2 .Math. .Math. RC) 0.0407 (rib 1) 0.0331 0.0795 (rib 2) 1.1 .Math. EC/RC 0.0352 0.0352 EL/RL 0.0325 0.0325 1.5 .Math. EL/RL 0.0487 0.0487 SLEL/(2 .Math. .Math. RL) 0.225 0.0543
(58) It may be noted that the tire according to an embodiment of the invention satisfies the criteria 0.90.Math.EC/RC<SLEC/(2.Math..Math.RC)<1.10.Math.EC/RC and 1.50.Math.EL/RL<SLEL/(2.Math..Math.RL) whereas the reference tire satisfies only the second criterion.
(59) A tire according to an embodiment of the invention, corresponding to the tire depicted in