Process water for producing salt by means of strong brine concentration after sea water desalination by using a two-way circulation method and bromine extraction

Abstract

A process produces salt by way of strong brine concentration after sea water desalination by using a two-way circulation method and bromine extraction. The process includes the following steps: A, preparing fresh water and strong brine from sea water in a high-pressure reverse osmosis unit by using a reverse osmosis method, wherein the concentration of the prepared strong brine is 70000 to 80000 PPM; and B, performing fresh and concentrated separation on the strong brine with the concentration of 70000 to 80000 PPM in a two-way circulation manner by using a concentration difference method till the strong brine is crystallized.

Claims

1. A process for producing salt from strong brine produced from sea water desalination, comprising the following steps: A. preparing strong brine from sea water by a reverse osmosis method, wherein the concentration of the prepared strong brine is 700080000 PPM; B. separating the strong brine in a two-way circulation manner by using a concentration difference method till the strong brine is crystallized, wherein the two-way circulation manner by the concentration difference method includes the following steps: a. setting several 12 m deep brine tanks and numbering them: I-XVII, in which: every brine tank is divided into three areas, among which an upper 4 m is a low salinity area, a middle 4 m is a medium salinity area and a lower 4 m is a high salinity area; each area of the brine tanks are separated by a concentration difference of 0.21.5, and a concentration difference of the same area of neighboring brine tanks is 13; the brine tanks I-XVII are divided into salt areas with brine concentrations ranging from 429; and the brine tanks I-XVII generally decrease in brine concentration; b. injecting the strong brine with the concentration of 700080000 PPM 6 m deep into brine tank XV having a concentration of 7 in the medium salinity area; c. pumping the brine at a bottom of every brine tank into the medium salinity area of an adjacent brine tank having higher salt content, and the brine of low concentration at a top of a brine tank having higher salt content will overflow to an adjacent brine tank having lower salt content, forming a two-way circulation; d. extracting sodium chloride crystals in a strong brine area at 2729 after a crystallization of sodium chloride at around 29.

2. The process according to claim 1, wherein the process also includes the following step: C. during the step of separating the strong brine, extracting the magnesium chloride, potassium chloride and bromine in strong brine in sequence.

3. The process according to claim 1, magnesium chloride is extracted with a physical method and the extraction is performed in a 1416 strong brine area; after the crystallization of magnesium chloride at around 15, magnesium chloride crystals are extracted.

4. The process according to claim 1, potassium chloride is extracted with a physical method and the extraction is performed in a 2526 strong brine area; after the crystallization of potassium chloride at around 25 , potassium chloride crystals are extracted.

5. The process according to claim 1, the extraction technology of bromine is performed on brine from the brine tanks III and IV, and the steps are as follows: 1) introduce chlorine into the strong brine to extract bromine out, and the reaction formula is as follows:
MgBr.sub.2+Cl.sub.2.fwdarw.MgCl.sub.2+Br.sub.2 2) the bromine is absorbed by alkali liquor and is fixed in the form of sodium bromate, and the reaction formula is as follows:
3Br.sub.2+6NaOH.fwdarw.5NaBr+NaBrO.sub.3+3H.sub.2O 3) bromine is obtained from the aqueous solution of sodium bromate through distillation after neutralizing treatment of sulfuric acid.

6. The process according to claim 5, wherein the bromine extraction uses full-automatic supergravity bromine extraction equipment separate from the brine tanks and a chemical method, and the steps are as follows: 1) introduce strong brine and chlorine into a water distributor in a shell through the brine and chlorine inlets at a bottom of the shell, and then enter a rotating packed bed loaded with filler driven by a motor, and in the water distributor and rotating packed bed, bromine in strong brine will react with chlorine to extract bromine out.

Description

DESCRIPTION OF FIGURE

(1) FIG. 1 is the flow diagram of embodiments 1-5 in the present invention;

(2) FIG. 2 is the schematic diagram of bromine extractor in embodiment 5 in the present invention;

(3) Where, 1Shell; 2Rotating packed bed; 3Fan; 4Motor; 5Chlorine and brine inlet; 6Effluent outlet; 7Alkali liquor tank; 8Water distributor.

(4) Specific Embodiments:

(5) Embodiment 1, a process for producing salt by means of strong brine concentration after sea water desalination by using a two-way circulation method and bromine extraction, comprising the following steps:

(6) A. Preparing fresh water and strong brine from sea water in a high-pressure reverse osmosis unit by using a reverse osmosis method, wherein the concentration of the prepared strong brine is 7000080000 PPM (78);

(7) B. Performing fresh and concentrated separation on the strong brine with the concentration of 7000080000 PPM in a two-way circulation manner by using a concentration difference method till the strong brine is crystallized.

(8) C. In the process of performing fresh and concentrated separation on the strong brine, extracting the magnesium chloride, potassium chloride and bromine in strong brine in sequence.

(9) In the said Step B, the process of performing fresh and concentrated separation in a two-way circulation manner by using a concentration difference method includes the following steps:

(10) a. Setting several 12 m deep brine tanks and numbering them: I-XVII; divide every brine tank into three areas, among which the upper 4 m is low salinity area, the middle 4 m is medium salinity area and the lower 4 m is high salinity area; separating concentration difference of every area is 0.21.5, and the concentration difference of the same area of neighboring brine tanks is 13; the several brine tanks are divided into salt areas with the brine concentration of 4-29;

(11) The capacity of brine tank of every stage is 35 times of the daily brine output Q of anti-penetration equipment (keep the standing time above 70 h).

(12) b. Firstly, inject the strong brine with the concentration of 7000080000 ppm in the location 6 m deep in brine tank XV with the concentration of 7 in the medium salinity area;

(13) c. Then, slowly pump the brine at the bottom of every brine tank into the medium salinity area of the upper brine tank with high salt content, and the brine of low concentration at the top of the upper brine tank will overflow to the lower brine tank, forming a two-way circulation.

(14) d. After the crystallization of sodium chloride at around 29, extracting sodium chloride crystals in the strong brine area at 2729.

(15) Embodiment 2, in the said Embodiment 1, magnesium chloride is extracted with a physical method and the extraction is performed in the 1416 strong brine area; after the crystallization of magnesium chloride at around 15, magnesium chloride crystals are extracted.

(16) Embodiment 3, in the said Embodiment 1, potassium chloride is extracted with a physical method and the extraction is performed in the 2526 strong brine area; after the crystallization of potassium chloride at around 25, potassium chloride crystals are extracted.

(17) Embodiment 4, in the said Embodiment 1, the extraction technology of bromine is performed in the optimal brine tank (III and IV) after the demonstration of several tests, and the steps are as follows:

(18) 1) Introduce chlorine into the strong brine to blow bromine out, and the reaction formula is as follows:
MgBr.sub.2+Cl.sub.2.fwdarw.MgCl.sub.2+Br.sub.2

(19) 2) The bromine is absorbed by alkali liquor and is fixed in the form of sodium bromate, and the reaction formula is as follows:
3Br.sub.2+6NaOH.fwdarw.5NaBr+NaBrO.sub.3+3H.sub.2O

(20) 3) Bromine can be obtained from the aqueous solution of sodium bromate through distillation after neutralizing treatment of sulfuric acid.

(21) Embodiment 5, in the said Embodiment 1, the said bromine extraction can adopt full-automatic supergravity bromine extraction equipment and a chemical method, as shown in FIG. 2:

(22) 1) Respectively introduce strong brine and chlorine into the water distributor 8 in Shell 1 through the brine and chlorine inlets 5 at the bottom of Shell 1, and then enter the rotating packed bed 2 loaded with filler driven by the motor 4, and in the water distributor 8 and rotating packed bed 2, bromine in strong brine will react with chlorine:

(23) The reaction formula is as follows:
MgBr.sub.2+Cl.sub.2.fwdarw.MgCl.sub.2+Br.sub.2

(24) Blow out the bromine generated after reaction through the fan 3 and send it to the alkali liquor tank 7;

(25) 2) The bromine is absorbed by alkali liquor and is fixed in the form of sodium bromate, and the reaction formula is as follows:
3Br.sub.2+6NaOH.fwdarw.5NaBr+NaBrO.sub.3+3H.sub.2O

(26) 3) Bromine can be obtained from the aqueous solution of sodium bromate through distillation after neutralizing treatment of sulfuric acid.

(27) A comparison between the refined salt produced by use of the said technology and the refined salt produced with other methods, and the comparison results are shown in the table below:

(28) TABLE-US-00001 Refined salt produced by Solar industrial salt Refined industrial salt use of this Index Premium Grade I Grade II Premium Grade I Grade II technology Sodium chloride 96.00 94.50 92.00 99.10 98.50 97.50 99.40 (%) Moisture (%) 3.00 4.10 6.00 0.30 0.50 0.80 0.20 Water insoluble 0.20 0.30 0.40 0.05 0.10 0.20 0.05 substance (%) Calcium and 0.30 0.40 0.60 0.25 0.40 0.60 0.15 magnesium ion (%) Sulfate ion (%) 0.05 0.70 1.00 0.30 0.50 0.90 0.20
Through the aforesaid comparison, it can be known that the quality grade of salt produced by use of this technology is far higher than that of refined salt produced with other methods.

(29) In the said embodiments, the number of stages of brine tanks depends on the required concentration of the final brine; if it is required to reach the concentration of salt crystallization, 1820 stages shall be set (designed by increasing 1 per stage).