PROCESS FOR PROCESSING AN ADHESIVE AND A DEVICE THEREFOR

Abstract

The invention relates to a process for processing an adhesive, wherein the process comprises applying an adhesive precursor product onto an adhesive carrier and activating and crosslinking the adhesive precursor product by treating the adhesive precursor product with water vapor and heat in a reaction chamber, and wherein the process is characterized in that air mixed with reaction gases forming during the activation and crosslinking in the reaction chamber is conducted away from the reaction chamber and recirculated as circulating air into the reaction chamber, wherein a portion of used air of the air recirculated as circulating air is replaced by fresh air. The invention further relates to a corresponding device for processing a pressure sensitive hot-melt adhesive.

Claims

1. A process for processing an adhesive, wherein the process comprises applying an adhesive precursor product onto an adhesive carrier and activating and crosslinking the adhesive precursor product by treating the adhesive precursor product with water vapor and heat in a reaction chamber, and wherein the process is characterized in that air mixed with reaction gases forming during the activation and crosslinking in the reaction chamber is conducted away from the reaction chamber and recirculated as circulating air into the reaction chamber, wherein a portion of used air of the air recirculated as circulating air is replaced by fresh air.

2. The process according to claim 1, in which the portion of used air replaced by fresh air is determined so that, in the case of an expected formation of the reaction gas, a reaction gas concentration limit is not reached at least for a minimum process duration, wherefore the portion of used air replaced by fresh air is selected to be at least sufficiently large so that, based on a reaction gas formation determined by calculation or estimated upwards, an upper limit of a reaction gas concentration is not reached.

3. The process according to claim 1, in which, in at least two positions spaced laterally from one another in the reaction chamber, a local reaction gas concentration is determined periodically or continuously and used as control variable in a control loop for the determination of the portion of used air of the circulating air discharged from the reaction chamber and replaced by fresh air.

4. The process according to claim 1, which moreover comprises a moisture control, in which a water vapor concentration in the reaction chamber is readjusted based on the used air discharged from the reaction chamber and replaced by fresh air in accordance with an expected or measured water vapor loss, so that the water vapor concentration in the reaction chamber is kept substantially constant at a predetermined point of the process for the activation and/or the crosslinking of the adhesive precursor product.

5. The process according to claim 1, which moreover comprises a moisture control, in which, in the case of an excess increase in a water vapor concentration in the reaction chamber, in particular in a rear subchamber of the reaction chamber viewed in feed direction of the adhesive precursor product through the reaction chamber, a moisture control of the recirculated circulating air occurs by varying the portion of used air replaced by fresh air.

6. The process according to claim 1, in which the reaction chamber is subdivided into several subsections or subchambers through which the adhesive precursor product on the adhesive carrier is passed successively, wherein, in at least two of the subsections, the adhesive precursor product on the adhesive carrier is treated by a separate process air feed, and wherein in each case a local reaction gas concentration in the subsections is measured continuously and compared with a local target value, wherein, for the process control, the portion of used air of the circulating air which is discharged from the reaction chamber and replaced with fresh air is readjusted in accordance with the determined deviations between the target values and the actual measured values for the reestablishment of the local target values.

7. The process according to claim 1, in which the reaction chamber is subdivided into several subsections or subchambers through which the adhesive precursor product on the adhesive carrier is passed successively, wherein, in a first subchamber of the reaction chamber viewed in feed direction of the adhesive precursor product on the adhesive carrier, the adhesive precursor product is treated with water vapor with simultaneous temperature increase, and wherein, in a second subchamber of the reaction chamber viewed in feed direction of the adhesive precursor product on the adhesive carrier, with maintenance of the temperature or additional temperature increase, the water vapor treatment is interrupted.

8. The process according to claim 1, wherein, during the activation and crosslinking of the adhesive precursor product, a compound that is highly flammable in air, for example, methanol, is released.

9. The process according to claim 8, in which the reaction chamber is subdivided into several subsections or subchambers through which the adhesive precursor product on the adhesive carrier is passed successively, wherein, in several of the subsections or subchambers, a methanol content in the air is measured, and wherein, based on a known feed speed of the adhesive precursor product on the adhesive carrier through the reaction chamber and on an expected total methanol release during the activation and crosslinking, the treatment of the adhesive precursor product with water vapor and heat in the reaction chamber is controlled in such a manner that, after leaving the reaction chamber, the adhesive precursor product on the adhesive carrier is activated and crosslinked to a certain minimum extent.

10. The process according to claim 8, in which the reaction chamber is subdivided into several subsections or subchambers through which the adhesive precursor product on the adhesive carrier is passed successively, wherein, in at least one last subchamber viewed in feed direction of the adhesive precursor product on the adhesive carrier, a concentration of the compound that is highly flammable in air in the chamber air is determined.

11. The process according to claim 10, in which the feed of the adhesive precursor product on the adhesive carrier is slowed or interrupted if the determination of the concentration of the compound that is highly flammable in air in the chamber air has shown that a certain upper threshold value has been exceeded.

12. The process according to claim 1, in which a feed speed of the adhesive precursor product on the adhesive carrier is adjusted in such a manner that a methanol concentration or a certain methanol concentration range in the reaction chamber air is complied with, so that an equilibrium reaction for the curing of an adhesive formed from the adhesive precursor product can be controlled based on the methanol concentration in the reaction chamber air.

13. The process according to claim 1, in which an oxidative, preferably thermal chemical or biological, or a filtering and/or washing used gas after-treatment is applied to the portion of used air discharged from the reaction chamber and replaced by fresh air.

14. A device for processing an adhesive, wherein the device is set up to carry out a process according to claim 1.

15. The device according to claim 14, which has a reaction chamber subdivided into several subchambers, wherein, in several or all of the subchambers, in each case a separate heat source is present, by means of which the adhesive precursor product can be treated with heat, wherein in some of the subchambers in each case a water vapor source is present, by means of which the adhesive precursor product can be treated with water vapor, and wherein at least one last subchamber viewed in feed direction of the adhesive precursor product through the reaction chamber comprises a heat source, but not a water vapor source.

16. The device according to claim 14, which, for the application of the adhesive precursor product onto the adhesive carrier, has a broad-slit nozzle with or without a roll rod, a roll coater or an alternative roll device.

17. The device according to claim 14, in which the adhesive carrier is temperature controlled by contact heat or radiation heat in transport direction before and after a station for the application of the adhesive precursor product.

18. The device according to claim 14, in which the adhesive precursor product applied on the adhesive carrier is transported, encapsulated and/or air-conditioned, in an area between a station for the application of the adhesive precursor product and a reaction chamber.

19. The device according to claim 14, in which, as path-guiding counter-roll in the area of a station for the application of the adhesive precursor product on an adhesive carrier, a rubber roll having a hardness between 20 Shore A and 80 Shore D, in particular between 60 Shore A and 95 Shore A, is used.

20. The device according to claim 14, in which, in a reaction chamber, the adhesive carrier with applied adhesive precursor product is exposed to air from above and/or below, wherein the adhesive carrier is fixed by means of lower air nozzles according to the Coanda or Venturi principle on guide rolls provided in the reaction chamber for the transport.

21. The device according to claim 14, in which the reaction chamber is designed as a hover channel with hover nozzles.

22. The device according to claim 14, in which the reaction chamber has a housing made of a corrosion-resistant material, particularly stainless steel.

23. The device according to claim 14, in which the reaction chamber, the subsections of the reaction chambers and the connection sections of the subsections are insulated against heat loss.

24. The device according to claim 14, in which the moisture in the reaction chamber or in subsections of the reaction chamber is prepared in the form of vapor, aerosol, water or feed air with very humid air.

25. The device according to claim 14, in which, after leaving the reaction chamber, the adhesive carrier with applied adhesive product is cooled to temperatures of less than 60 C., in particular less than 30.

Description

DRAWINGS

[0032] The drawings described herein are for illustrative purposes only of selected embodiments and not all possible implementations, and are not intended to limit the scope of the present disclosure.

[0033] Additional details of the invention are explained in reference to the following FIGURE. This FIGURE diagrammatically shows an example of a processing installation for implementing the process for processing an adhesive as described above.

DETAILED DESCRIPTION

[0034] Example embodiments will now be described more fully with reference to the accompanying drawings.

[0035] Liquid hot melt adhesive precursor material 5 is provided in a melting vat 1 and applied by means of a nozzle 2 which can be a Nordson TrueCoat nozzle, for example, onto an adhesive carrier 4. The adhesive carrier 4 can be a coated paper or an untreated or treated film such as PET or PMMA. It is transported by means of a roll system which comprises a temperature-controlled roll 3 ensuring that the liquid hot melt adhesive precursor material 5 is kept at a temperature enabling said material to be applied on the adhesive carrier 4 as a thin layer. The hot melt adhesive precursor material 5 forms an adhesive precursor product which, applied on the adhesive carrier 4, is led by means of the roll system through the reaction chamber 6 in order to be activated and crosslinked there by means of a heat and water vapor treatment.

[0036] The reaction chamber 6 is subdivided into subchambers 6.1, 6.2, 6.3, 6.4. It is provided that the reaction chambers 6.1 and 6.2 are used for the activation and crosslinking of the adhesive precursor product 5, for the purpose of which the subchambers 6.1 and 6.2 in each case comprise a separate water vapor supply 8 and a separate heat supply (not shown). The subchambers 6.3 and 6.4 have no water vapor supply. All the subchambers 6.1-6.4 comprise heat sources that are independent of one another, in order to be able to set the process temperature depending on the subchamber for a finer adjustment of the process. The subchambers 6.1-6.4 in each case can comprise a sensor for the determination of a reaction gas, in this case MeOH, so that, in accordance with the measured reaction gas concentration, the process can be regulated by influencing the water vapor supply and/or by influencing the heat supply.

[0037] The subchambers 6.1-6.4 each comprise a used air discharge line 7 and separate process air supplies 9.1-9.4, wherein the process air supplies 9.1-9.4 leading into the subchambers 6.1-6.4 can be readjusted in accordance with the measured reaction gas concentrations in the subchambers 6.1-6.4.

[0038] In particular, the process can thus be controlled in such a manner that, after leaving the last subchamber 6.4 viewed in feed direction of the adhesive carrier 4 with the adhesive precursor product 5, the released residual methanol quantity is reduced to a safe minimum. After leaving the reaction chamber 6, the activated and crosslinked adhesive product is coated with a coating layer 9, so that it is enclosed between the coating layer 9 and the adhesive carrier layer 4. However, the coating layer 9 is only optional and not absolutely necessary. For example, it is possible to provide that the processed product consisting of adhesive carrier 4 and adhesive precursor product 5 is rolled up after leaving the reaction chamber and optionally a certain evaporation distance.

[0039] For the process control it is possible to provide that feed speed, temperature of the recirculated air, vapor concentration of the recirculated air (that is to say the relative humidity of the air that comes in contact with the adhesive) and the feed air and used air volume stream are adjusted.

[0040] By means of the feed speed, as a function of the other parameters, the rough presetting of the process speed is carried out. Via the temperature and the air speed, the heat transfer and the reaction speed can be established. The temperature itself can be set via a heat exchanger (HE), for example, an oil-air HE, a water-air HE, a vapor-air HE, or an electrically heated HE. Alternatively, a direct heating of the reaction chamber 6 can also be provided, for example, by means of a gas burner.

[0041] The vapor concentration can be measured by means of a capacitive air humidity sensor or determined by means of a wet bulb measurement. If the actual value deviates from the target value then, for example, additional moisture can be introduced by means of a vapor lance into one of the subchambers 6.1, 6.2. If the vapor concentration is exceeded, the vapor quantity must be reduced by a careful adaptation (increase) of the used air volume flow and, in a correlated manner, of the feed air volume flow.

[0042] The used air regulation can be carried out with the aid of correlated feed air and used air valves separately for each of the subchambers 6.1, 6.2, 6.3, 6.4. When the vapor or MeOH concentration is exceeded, the used air valves are opened further and the feed air valves are changed accordingly, so that the influence of the valve position change on the respective subchamber remains limited. The quantified amount of feed air and used air is determined, for example, as a differential pressure value via Pitot tubes or as orifice differential pressure or the like.

[0043] The features of the invention disclosed in the above description, in the drawings and in the claims can be essential for carrying out the invention both individually and also in any combination.

[0044] The foregoing description of the embodiments has been provided for purposes of illustration and description. It is not intended to be exhaustive or to limit the disclosure. Individual elements or features of a particular embodiment are generally not limited to that particular embodiment, but, where applicable, are interchangeable and can be used in a selected embodiment, even if not specifically shown or described. The same may also be varied in many ways. Such variations are not to be regarded as a departure from the disclosure, and all such modifications are intended to be included within the scope of the disclosure.