OPTICALLY VARIABLE SECURITY DEVICES
20230101526 · 2023-03-30
Assignee
Inventors
- Roger W. Phillips (Santa Rosa, CA)
- Thomas MAYER (Bogart, GA, US)
- Scott LAMAR (Santa Rosa, CA, US)
- Elena TAGUER (Ottawa, CA)
Cpc classification
B42D25/328
PERFORMING OPERATIONS; TRANSPORTING
B42D25/351
PERFORMING OPERATIONS; TRANSPORTING
B42D25/425
PERFORMING OPERATIONS; TRANSPORTING
B42D25/00
PERFORMING OPERATIONS; TRANSPORTING
D21H21/40
TEXTILES; PAPER
G03H2001/188
PHYSICS
B32B2425/00
PERFORMING OPERATIONS; TRANSPORTING
B42D25/369
PERFORMING OPERATIONS; TRANSPORTING
G02B5/1814
PHYSICS
B32B37/18
PERFORMING OPERATIONS; TRANSPORTING
Y10T156/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
B32B37/12
PERFORMING OPERATIONS; TRANSPORTING
B32B37/18
PERFORMING OPERATIONS; TRANSPORTING
B42D25/00
PERFORMING OPERATIONS; TRANSPORTING
B42D25/328
PERFORMING OPERATIONS; TRANSPORTING
G03H1/00
PHYSICS
Abstract
An optical device is formed by hot stamping a demetallized hologram to an optically variable foil or to a coating of optically variable ink. In another embodiment a hologram is hot stamped to a banknote or document printed with a color-shifting ink.
Claims
1-24. (canceled)
25. A method of manufacturing a device for providing an image having an optically variable feature, comprising: a) providing a diffractive structure for forming at least a portion of the image; b) providing an optically variable structure distinct from the diffractive structure, for providing the optically variable feature to the image, wherein the optically variable structure changes color with a change in angle of incident light, and wherein the optically variable structure comprises a first reflector layer, an absorber layer, and a dielectric layer between the reflector and absorber layers; c) covering the diffractive structure or the optically variable structure with an adhesive; d) after steps (a)-(c), activating, with energy, the adhesive and coupling the diffractive structure and the optically variable structure together in a predetermined mutual arrangement, wherein the energy activated adhesive forms a layer; wherein the diffractive structure comprises a relief pattern and a high refraction index layer made of a material having an index of refraction no less than 1.65; and wherein the diffractive structure comprises a patterned opaque coating so that the diffractive structure has opaque regions and light transmissive regions.
26. The method as defined in claim 25, wherein the opaque regions for preventing light incident on the diffractive structure from propagating through to the optically variable structure via the layer of the energy activated adhesive, and light transmissive regions for allowing light incident on the diffractive structure to propagate through to the optically variable structure via the layer of the energy activated adhesive.
27. The method as defined in claim 25, wherein in step (a) comprises providing a second reflector layer to the diffractive structure.
28. The method as defined in claim 27, wherein the second reflector layer is partially demetallized.
29. The method as defined in claim 28, wherein the second reflector layer is segmented so that the reflector layer has one or more light transmissive windows, so that the optically variable structure is visible through said windows.
30. The method as defined in claim 27 wherein the optically variable structure comprises a coating with a plurality of multilayer optical interference flakes therein or thereon.
31. The method as defined in claim 25, wherein step (a) comprises providing a substrate having a first side supporting the diffractive structure, wherein the first side of the substrate has a first region wherein the diffractive structure is therein or thereon, and the first side of the substrate has a second region wherein the diffractive structure is absent, and in step (c) the layer of the energy activated adhesive is adjoined to the first side of the substrate so that the optically variable structure is adhesively bound solely to the substrate and coupled to the diffractive structure by the surrounding adhesive.
32. A device manufactured by the method defined in claim 25.
33. The method as defined in claim 25, wherein the diffractive structure includes a grating to form a light transmissive region for allowing light incident on the diffractive structure to propagate through to the optically variable structure via the layer of the energy activated adhesive.
34. The method as defined in claim 25, wherein the diffractive structure includes indicia.
35. The method as defined in claim 25, wherein the diffractive structure includes a substrate having the grating impressed on a surface of the substrate.
36. The method as defined in claim 25, wherein the diffractive structure includes a protective coating.
37. The method as defined in claim 25, wherein the adhesive includes covert flakes.
38. The method as defined in claim 37, wherein the covert flakes include charms, taggants, shaped pigments, magnetic flakes, or fluorescent pigments.
39. The method as defined in claim 25, wherein in step c) the adhesive covers the diffractive structure or the optically variable structure in a pattern.
40. The method as defined in claim 39, wherein the diffractive structure has regions not bonded to the optically variable structure based upon the pattern.
41. The method as defined in claim 39, wherein the pattern of adhesive forms a frame around the diffractive structure.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0029] To further clarify the above and other advantages and features of the present invention, a more particular description of the invention will be rendered by reference to specific embodiments thereof that are illustrated in the appended drawings. It is to be appreciated that these drawings depict only typical embodiments of the invention and are therefore not to be considered limiting of its scope. The invention will be described and explained with additional specificity and detail through the use of the accompanying drawings in which:
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DETAILED DESCRIPTION
[0041] The present invention is related to optical devices wherein a relief structure providing an optical effect such as a hologram or diffraction grating is coupled to an optically variable structure by an adhesive, which may be an energy activated adhesive. The resulting optical structure exhibits unique optical effects.
[0042] For the purpose of this application, the term “energy activated adhesive” or “energy activated binder”, means a bonding substance that requires an energy source for curing. The energy activated adhesives include, but are not limited to, hot stamp adhesives, UV or e-beam activated adhesives, thermoplastic and thermoset adhesives, paint-based polymeric compositions, varnishes, and staining compositions. By way of example, an adhesive is selected from the group of: polymethacrylate, polyacrylate, polyamide, nitrocellulose, alkyd resin, polyvinyl alcohol, polyvinyl acetate, and polyurethane.
[0043] The methods of activating the adhesives include hot stamping, UV curing, applying heat, pressure, or a beam of electrons. For brevity, an energy activated adhesive, possibly with special flakes therein, is referred to as “an adhesive” hereinbelow where it does not lead to confusion.
[0044] As was described heretofore, in the background of the invention, the field of hot stamping and more particularly, hot stamping of one optical coating or substrate with another is well known. For example, coated substrates bearing images, logos or other indicia are hot stamped onto lottery cards, passports, banknotes, driver’s licenses, poker chips, and a variety of other articles and substrates are well known.
[0045] The adhesive may be printed into patterns or flood coated over the entire surface. If patterned, the product becomes more tamper proof since the product cannot be physically removed in one piece. Attempts to remove the device by dissolving the adhesive using solvents would also be detrimental since the solvent would also attack the hardcoat/release which in turn would destroy the device, making tampering obvious.
[0046] The device disclosed in the present application comprises a diffractive structure, which can take various conventional forms including diffraction patterns such as diffraction gratings, refraction patterns, holographic patterns such as two-dimensional and three-dimensional holographic images, demetallized holograms, coatings with varied index of refraction, light transmissive dielectric coatings with refractive flakes therein or thereon, Kinegram.sup.R devices, Pixelgram.sup.R devices, corner cube reflectors, zero order diffraction structures, moiré patterns, and light interference patterns based on microstructures having dimensions of from about 0.1 .Math.m to about 10 .Math.m.
[0047] In accordance with one embodiment of the present invention, the diffractive structure comprises a reflector layer, having at least a part demetallized. A demet layer can be made of Al, Cu, Ni, and other metals and metal alloys that have been patterned by demetallization. Various techniques may be used to pattern the metal layer, such as chemical etching or oil ablation in vacuum, both done in registration with the relief image.
[0048] In one embodiment of the present invention, the diffractive structure comprises a windowed or segmented opaque layer having one or more light transmissive windows to allow combining of optical effects provided by the diffractive and optically variable structures, so that the optically variable structure is visible through said windows when the device is viewed from the side of the diffractive structure. Preferably, the windowed coating is reflective to provide an additional security feature.
[0049] The diffractive structure may be embossed on an embossable resin layer made of such materials as type G PET, Polycarbonate, polyvinyl chloride or polymethacrylate. An embossable layer may be combined with hardcoat/release layer. An embossing may be either patterned or continuous.
[0050] The diffractive structure may comprise a grating formed in a substrate, preferably a light transmissive or essentially transparent substrate, which may be made of Polyethylene Terephtalate (PET), Oriented Polypropylene (OPP) or other suitable plastic material. By way of example, a PET layer has a thickness of 6-25 microns.
[0051] The diffractive structure may comprise a high refraction index layer coated on a relief pattern, such as an embossed resin layer. The high refraction index layer may be made of a material having the index of refraction no less than 1.65. A high refractive index layer can be made of ZnS, TiO.sub.2, ZrO.sub.2, etc.
[0052] In one embodiment of the present invention, the diffractive structure is visible through the OV structure, so the substrate supporting the diffractive structure may be opaque.
[0053] In one embodiment of the present invention, the diffractive structure is a windowed substrate having a coated pattern thereon, wherein regions that are uncoated form windows therethrough the color shifting background is visible.
[0054] The device disclosed in the present application comprises an optically variable structure which, in one embodiment, is a multilayer optical interference film comprising a reflector layer, an absorber layer, and a dielectric layer between the reflector and absorber layers, as it is known in the art. A reflective layer can be made of any metal that has a reflectance over 20%, preferably aluminum. By way of example, a dielectric layer is made of MgF.sub.2 or other transparent material as known in the art.
[0055] An absorber can be a grey metal with a ratio of n/k about 1, where n is the real part of the refractive index and k is the imaginary part of the reflective index, for example Cr or Ni or other transition metal, or can be a non-selective absorber across the visible spectrum, or can be a cermet, as described in the article entitled “Influence of Nanosized Metal Clusters on the Generation of Strong Colors and Controlling of their Properties through Physical Vapor Deposition (PVD)” by R. Domnick et al., 49th Annual Technical Conference Proceedings (2006), Society of Vacuum Coaters, incorporated herein by reference. By way of example, a cermet material comprises silver islands in a dielectric matrix.
[0056] In another embodiment of the present invention, the optically variable structure is a multilayer optical interference film comprising a first and second absorber layers, and a dielectric layer therebetween. This multilayer film configuration is disclosed in U.S. Pat. No. 5,278,590 to Phillips et al. Such a film structure allows optically variable structure 10b to be transparent to light incident upon the surface thereof.
[0057] In yet another embodiment, the optically variable structure is a multilayer optical interference film comprising alternating low and high refraction index layers, where the individual layers have an index of refraction between 1.38 and 2.3
[0058] In one embodiment of the present invention, the optically variable structure comprises a light transmissive dielectric coating with a plurality of multilayer optical interference flakes therein or thereon. Such flakes are described, for example, in U.S. Pat. No. 6,749,777 granted to Argoitia et al.
[0059] Alternatively, the optically variable structure comprises optically variable ink, comprising optical effect flakes in a carrier, wherein the flakes may have one or more predetermined optical characteristics; for example, flakes may be optically variable changing color with a change in angle of incident light, or flakes may be diffractive, or may have covert symbols therein or thereon, or the flakes may simply be reflective or absorptive. In some instances, optical effect flakes have a combination of optical effects, for example, they may be diffractive and color shifting, or they may be diffractive and reflective, or diffractive and highly absorptive depending upon the desired effect. Furthermore, flakes having different optical effects may be mixed together in desired ratios. Pigments that may be added include those based on interference, for example mica based pigments, Fabry Perot type pigments, liquid crystal type pigments, including those that color shift with viewing angle, non- shifting pigments like gold and nickel, and other metallic flakes.
[0060] In one embodiment of the present invention, the optically variable ink is printed onto a substrate such as a banknote or any other security document.
[0061] The substrate supporting the optically variable structure is either opaque or light-transmissive in various embodiments of the present invention.
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[0063] Generally, in the prior art manufacture of chromagrams, an optical effect coating would be applied directly over the Al, as well as over the uncoated portions of the light transmissive substrate. However, in accordance with this invention an entirely separate structure 10b shown in
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[0065] A novel and inventive aspect of this invention is the manufacture of a windowed structure, such as diffractive structure 10a, and a separate optically variable structure, such as structure 10b, wherein the two structures can be married or bonded together forming a chromagram by the application of heat and pressure via hot stamping. Each of the first and second structures can vary; several non-limiting examples are given throughout this application.
[0066] In embodiments of the present application the hot stamp adhesive can be applied and dried upon either a diffractive structure, structure 10a in the aforedescribed example, or an optically variable structure, such as 10b, or both structures, prior to bonding the two structures together. The thickness for hot stamp adhesive may be between 3 .Math.m and 10 .Math.m, with preferable range 3-7 .Math.m.
[0067] Further described embodiments of the present invention shown in
[0068] In embodiment shown in
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[0070] Preferably, reflective layer 16 is windowed, so that substrate 12 has one or more regions 100 thereon embossed and covered with reflective material, said regions separated by regions 17 shown in
[0071] The structure shown in
[0072] Another embodiment of the present invention shown in
[0073] With reference to
[0074] In another embodiment of the present invention, similar to the structures shown in
[0075] In
[0076] These covert flakes serve as a means of authentication. If the covert flakes provide an optical effect, for example under a microscope or being IR activated, additionally to holographic effects exhibited by this structure, though the windows where the Al coating is missing, covert flakes 45 can be seen on color shifting background.
[0077] In another embodiment, optically variable flakes are added to adhesive 40 at low concentrations so that the OV foil colors are modified when viewing from the top.
[0078] According to another embodiment of the present invention,
[0079] The structure shown in
[0080] Conveniently, the aforedescribed manufacturing process allows the first and second substrates to be manufactured in two different facilities and stored in rolls to be united later.
[0081] Conveniently, the second substrate may have any type of optical effect coating thereon that can be seen through windows in the first substrate. Conveniently any of these first windowed substrates can be married to these second coated substrates at a later time or immediately, by way of hot stamping the two together or by hot roll laminating.
[0082] In another embodiment of the present invention, alternatively to hot-stamping, a UV activated adhesive is used to bond the two structures together. By way of example, an optically variable foil printed with an adhesive is brought together with a laminating sheet containing the demet hologram; the adhesive is then cured by irradiating the laminating sheet with UV light, wherein the laminating sheet has a transparent or at least UV light - transmissive substrate. One way to overcome the obstacle to UV light posed by the reflective metal covering the hologram, is to use a patterned or windowed reflective layer wherein areas covered with metal are very narrow, estimated to be less than 2 microns, so that UV light can cure the adhesive by coming in at an angle. Another way is to use a semitransparent reflective layer in the OV structure or to use e-beam curing.
[0083] In one embodiment of the present invention, shown in
[0084] In another embodiment of the present invention shown in
[0085] In a structure similar to the structure shown in
[0086] In reference to
[0087] In one embodiment of the present invention, adhesive layer is patterned so that the diffractive structure has regions not bonded to the optically variable structure.
[0088] In another embodiment of the present invention, the adhesive layer is patterned so that one of the structures, by way of example a OV foil, is bonded to the substrate supporting the second structure, a hologram in our example, forming a frame, or a part of it, around the hologram.
[0089] In one embodiment, shown in
[0090] In one embodiment of the present invention, comprising a demetallized hologram hot stamped onto an optically variable foil, a patterned layer of color shifting ink is deposited underneath the demet hologram. This allows the color shift from the foil to show though to the observer. The flakes of the optically variable ink are generally opaque so that a continuous coating of ink would block out the underlying foil. Alternatively, the color shifting ink has a low concentration of flakes so that the color shift of the foil could still be seen though the optically variable ink; the foil colors are modified by the partially transparent optically variable ink. Alternatively, a patterned layer of the optically variable ink is deposited on the top side of the demet hologram, so that both the color shift from the ink and from the OV foil are visible.
[0091] Referring now to