Gas sampling device and filling station comprising such a device

Abstract

The invention relates to a gas sampling device for a filling station for hydrogen tanks, said device comprising a circuit comprising a first upstream end provided with an inlet connector to a detachably connected to an outlet connector of a filling station, and two conduits respectively for sampling and filling connected in parallel to the inlet connector, the sampling conduit comprising a valve system, a first pressure reducing valve and a container for collecting a sample of gas expanded by said first pressure reducing valve, and the filling conduit comprising a downstream end provided with a first outlet connector to a detachably connected to an inlet connector of a tank to be filled.

Claims

1. A gas sampling device for a hydrogen tank filling station, the device comprising a circuit comprising: a first upstream end provided with an inlet connector intended to be connected removably to an outlet connector of a filling station: a sampling pipe comprising a system of valves, a first pressure regulator and a container for collecting a sample of gas expanded by said first regulator; a filling pipe comprising a downstream end provided with a first outlet connector intended to be connected removably to an inlet connector of a tank that is to be filled, wherein the sampling pipe and the filling pipe are connected in parallel to the inlet connector of the first upstream end of the circuit; and a vent pipe comprising at least one pressure-sensitive relief valve, the vent pipe having a downstream discharge end opening to the outside of the device, a first upstream end connected to the sampling pipe upstream of the collecting container, and a second upstream end connected to the sampling pipe downstream of the collecting container.

2. The device of claim 1, wherein the sampling pipe further comprises at least one calibrated orifice situated upstream of the first pressure regulator between the inlet connector and the first pressure regulator.

3. The device of claim 1, wherein the sampling pipe further comprises a calibrated orifice situated downstream of the first regulator between the first regulator and the collecting container.

4. The device of claim 1, wherein the sampling pipe further comprises first and second calibrated orifices arranged in series upstream of the first regulator between the inlet connector and the first regulator, the first calibrated orifice having dimensions greater than that of the second calibrated orifice.

5. The device of claim 1, wherein the sampling pipe further comprises, downstream of the collecting container, a valve and a second outlet connector for withdrawing sample gas taken from the collecting container.

6. The device of claim 5, wherein the sampling pipe further comprises a second pressure regulator situated between the collecting container and the second outlet connector.

7. The device of claim 1, wherein a first isolation valve is disposed upstream of the first regulator.

8. The device of claim 7, wherein a second isolation valve is disposed between the first regulator and the collecting container.

9. The device of claim 8, wherein a third isolation valve is disposed downstream of the collecting container.

10. The device of claim 1, wherein it is arranged and configured to be a manually transportable.

11. A filling station for filling hydrogen tanks, comprising a gas sampling device of claim 1.

Description

BRIEF DESCRIPTION OF THE FIGURES

(1) FIG. 1 is a schematic and partial view illustrating one example of a structure of a sampling device collaborating with a hydrogen filling station.

DETAILED DESCRIPTION OF THE INVENTION

(2) Other specifics and advantages will become apparent on reading the following description given with reference to the single FIGURE which is a schematic and partial view illustrating one example of a structure of a sampling device collaborating with a hydrogen filling station.

(3) The gas sampling device for a hydrogen tank filling station and depicted in the FIGURE comprises a fluid circuit 2, 3, 5 comprising a first upstream end equipped with an inlet connector 4 intended to be connected removably to an outlet connector 6 of a filling station 34.

(4) What that means to say is that the sampling device may be connected removably directly to the downstream end of the filling station, at the gas outlet nozzle 6 intended to be connected to a tank 14 or to a vehicle 13. Alternatively, the sampling device may be connected to the outlet connector of a compressor or of a buffer storage tank of a filling station 34.

(5) Likewise, the sampling device may be connected to the downstream outlet of a filling station, at the orifice intended to be connected usually to a hose fitted with a fuel filling gun or nozzle intended to be connected to the tanks that are to be filled. What that means to say is that the sampling device can be connected in place of a hose or upstream or downstream of a gas dispensing hose of a station.

(6) The circuit of the sampling device comprises two pipes 2, 5, these respectively being a sampling pipe 2 and a filling pipe 5 which are connected in parallel to the inlet connector 4.

(7) The filling pipe 5 comprises a downstream end equipped with a first outlet connector 12 intended to be connected removably to an inlet connector 35 of a tank 13, 14 that is to be filled. The filling pipe 5 is preferably without a pressure regulator or regulating valve (such members are present upstream in the circuit of the station 34). The station 34 may notably comprise its own vent circuit 42.

(8) By contrast, the filling pipe 5 preferably comprises a safety device 37 preventing any leak in the event of the hose pulling out.

(9) The sampling pipe 2 for its part comprises a system of valves 9, 10, 11, a first pressure regulator 7 and a collecting container 8 for collecting a sample of gas expanded by said first regulator 7.

(10) The sampling pipe 2 comprises at least one, and preferably two, calibrated orifices arranged in series upstream of the first regulator 7, namely situated between the inlet connector 4 and the first regulator 7. More specifically, the sampling pipe 2 may comprise a first 15 and a second 16 calibrated orifice, the first calibrated orifice 15 having an orifice of dimensions greater than the dimensions of the orifice of the second calibrated orifice 16.

(11) For example, the first calibrated orifice 15 has an orifice of dimensions of between 0.5 and 2 mm and preferably of 1 mm, while the second calibrated orifice 16 has a dimension of between 100 m and 300 m and preferably of 200 m.

(12) As illustrated, the sampling pipe 2 may comprise a first isolation valve 9 arranged upstream of the first regulator 7, between the second calibrated orifice 16 and the first regulator 7.

(13) This first valve 9 allows the high pressure upstream circuit portion to be selectively isolated from the remainder of the circuit.

(14) The sampling pipe 2 preferably comprises a first pressure gauge 38 arranged upstream of the first regulator 7, for example between the second calibrated orifice 16 and the first isolation valve 9.

(15) Of course, other arrangements are possible, and for example the first isolation valve 9 may be arranged between the first calibrated orifice 15 and the second calibrated orifice 16 (as may the first pressure gauge 38).

(16) As illustrated, the sampling pipe 2 preferably comprises a second isolation valve 10 arranged between the first regulator 7 and the collecting container 8.

(17) In addition, an additional calibrate orifice 17 may be arranged downstream of the first regulator 7, namely between the first regulator 7 and the collecting container 8. This calibrated orifice 17 for example has an orifice of dimensions of between 200 and 900 m, for example 500 m.

(18) A second pressure gauge 39 may be provided between the first regulator 7 and the collecting container 8, for example between the calibrated orifice 17 and the first regulator 7.

(19) In the example illustrated, the sampling pipe 2 comprises, downstream of the collecting container 8, a third valve 11, a second regulator 18 (optional) and a second outlet connector 19 (preferably self-sealing) for withdrawing sample gas taken from the collecting container 8.

(20) The second isolation valve 10 and the third isolation valve 11 allow the sample in the container 8 to be isolated at the upstream and downstream orifices thereof respectively.

(21) As depicted, a third pressure gauge 40 may be provided downstream of the container 8 (between the container 8 and the third valve 11). A fourth pressure gauge 41 may be provided downstream of the second regulator 18.

(22) Finally, the circuit comprises a vent pipe 3 comprising at least one pressure-sensitive relief valve 20, 22. The vent pipe 3 comprises a downstream discharge end 33 opening to the outside of the device. The vent pipe 3 comprises a first upstream end 21 connected to the sampling pipe 2, upstream of the collecting container 8 via a first pressure-sensitive relief valve 20.

(23) The vent pipe 3 may comprise a second upstream end 23 connected to the sampling pipe 2, downstream of the collecting container 8 for example between the second outlet connector 19 and the second pressure regulator 18. The second upstream end 23 may be connected to the sampling pipe 2 via a second pressure-sensitive relief valve 22.

(24) The vent pipe 3 may comprise a third upstream end 24 equipped with a valve 41 and with a nonreturn check valve 42 and connected to the sampling pipe 2 upstream of the collecting container 8, for example between the first regulator 7 and the third calibrated orifice 17. This valve 41 allows the circuit to be depressurized via the vent 3 at the end of use.

(25) The vent pipe 3 may comprise a fourth upstream end 25 equipped with a valve 26 and with a nonreturn check valve 27 and connected to the sampling pipe 2 downstream of the second regulator 18. This valve 26 allows the purging of the downstream portion of the sampling circuit upstream of the second outlet connector 19.

(26) The nonreturn check valves 27, 42 prevent any contamination of the circuit with air if the associated valves 26, 41 are opened.

(27) The safety relief valves 20, 22 present downstream of the regulators 7, 18 allow any overpressure to be discharged to the vent 3 in the event of failure of the regulators 7, 18. For preference, the downstream end 3 of the vent forms a collector of suitable length (for example 3 meters) for discharging the flammable gas away from the users.

(28) The vent circuit allows the purging of the filling pipe 5 (preferably a hose) that provides the connection with the tank that is to be filled. This purging can be carried out via the second end by opening the corresponding valve 41.

(29) This avoids contaminating the tank. It will be possible for the vehicle to be used after the sample has been taken.

(30) The calibrated orifices 15, 16 thus make it possible to limit the rate of flow of gas to the first regulator 7 and the container 8 without contaminating the gas intended to be sampled for analysis.

(31) In addition, by limiting the downstream flow rate these calibrated orifices 15, 16 make it possible to reduce the size of the pressure-sensitive relief valves 20, 22 of the vent circuit and of the collector 3 of this vent circuit.

(32) The third calibrated orifice 17 itself makes it possible to limit the flow rate at which the collecting container 8 is filled. This makes it possible to avoid excessive heating thereof as it fills.

(33) The second regulator 18 arranged downstream of the container 8 allows an additional reduction in pressure, for example for distributing the sampled gas under conditions compatible with the technical features of an analyzer.

(34) The two, sampling 2 and filling, pipes may be put into service simultaneously when the inlet connector 4 is connected to the gas outlet 6 of the filling station 34. These two lines respectively perform a filling of the tank 13, 14 of the vehicle at high pressure and a withdrawing of a sample of gas at low pressure into a container 8.

(35) The sampling of gas for analyzing low-content impurities implies the use of suitable hardware (valves, regulators, tubes, cylinders, etc.) in terms of the technical design, cleanliness, surface treatment and surface condition.

(36) The low pressure obtained downstream of the first regulator 7 (pressure of below 100 bar) means that suitable hardware is easy to find.

(37) In the event that the first regulator 7 is of the controlled type, the pressure ramp and target pressure may be controlled downstream. That allows sampling at lower pressures and lower flow rates.

(38) The hydrogen contained in the container 8 can then be analyzed in a laboratory (for example impurities can be measured for fuel cell applications).

(39) Although of simple and inexpensive structure, the proposed solution constitutes a novel system for sampling hydrogen at the outlet of a filling station 34. Sampling can be performed simultaneously and under conditions that are identical to the filling of a tank.

(40) The device may be interposed directly between the filling station 34 (or buffer storage tank) and the vehicle 13 using connections already present and without the need to modify the hardware.

(41) The pressure gauges 38, 39, 40 (which are optional) indicate the pressure in the various parts of the circuit.

(42) The sampling device may thus be incorporated into a manually transportable mobile unit 36, for example having a volume of between 0.1 and 0.3 m.sup.3 and a mass of between 5 and 35 kg.

(43) While the invention has been described in conjunction with specific embodiments thereof, it is evident that many alternatives, modifications, and variations will be apparent to those skilled in the art in light of the foregoing description. Accordingly, it is intended to embrace all such alternatives, modifications, and variations as fall within the spirit and broad scope of the appended claims. The present invention may suitably comprise, consist or consist essentially of the elements disclosed and may be practiced in the absence of an element not disclosed. Furthermore, if there is language referring to order, such as first and second, it should be understood in an exemplary sense and not in a limiting sense. For example, it can be recognized by those skilled in the art that certain steps can be combined into a single step.

(44) The singular forms a, an and the include plural referents, unless the context dearly dictates otherwise.

(45) Comprising in a claim is an open transitional term which means the subsequently identified claim elements are a nonexclusive listing i.e. anything else may be additionally included and remain within the scope of comprising, Comprising is defined herein as necessarily encompassing the more limited transitional terms consisting essentially of and consisting of; comprising may therefore be replaced by consisting essentially of or consisting of and remain within the expressly defined scope of comprising.

(46) Providing in a claim is defined to mean furnishing, supplying, making available, or preparing something. The step may be performed by any actor in the absence of express language in the claim to the contrary.

(47) Optional or optionally means that the subsequently described event or circumstances may or may not occur. The description includes instances where the event or circumstance occurs and instances where it does not occur.

(48) Ranges may be expressed herein as from about one particular value, and/or to about another particular value. When such a range is expressed, it is to be understood that another embodiment is from the one particular value and/or to the other particular value, along with all combinations within said range.

(49) All references identified herein are each hereby incorporated by reference into this application in their entireties, as well as for the specific information for which each is cited.