CARBOXYLIC ACID ESTERS OF XYLITOL AND PROCESS FOR ENZYMATICALLY PREPARING SAME

Abstract

Xylitol carboxylates are products of interest in the food and cosmetics industries. A process can be used for the enzymatic preparation of xylitol carboxylates.

Claims

1: A xylitol carboxylate, comprising: at least one carboxylic ester of xylitol, and at least one of a carboxylic ester of 1,4-anhydroxylitol, a carboxylic ester of 1,4-anhydroarabitol, and a carboxylic ester of 1,4-anhydroribitol, wherein a ratio by weight of xylitol residues present in the xylitol carboxylate to a sum total of all 1,4-anhydroxrlitol residues, 1,4-anhydroarabitol residues, and 1,4-anhydroribitol residues present in the xylitol carboxylate is greater than or equal to 96:4, and wherein a molar ratio of esterified primary hydroxyl groups to esterified secondary hydroxyl groups in the at least one carboxylic ester of xylitol is 80:20 to 20:80.

2: The xylitol carboxylate according to claim 1, wherein a carboxylic acid component is derived from a carboxylic acid containing 2 to 34, carbon atoms or a mixture thereof.

3: The xylitol carboxylate according to claim 1, wherein an average degree of esterification of the at least one carboxylic ester of xylitol present is from 1.0 to 4.0.

4: The xylitol carboxylate according to claim 1, wherein the at least one carboxylic ester of xylitol present comprise monoesters of xylitol, diesters of xylitol and triesters of xylitol.

5: The xylitol carboxylate according to claim 1, wherein the xylitol carboxylate comprises 0.05% to 40% by weight, of free xylitol.

6: The xylitol carboxylate according to claim 1, wherein the xylitol carboxylate comprises less than 25% by weight of at least one free carboxylic acid.

7: The xylitol carboxylate according to claim 1, wherein a total monoester component of the at least one carboxylic ester of xylitol contains from 5% by weight to 25% by weight of secondary ester regioisomers.

8: The xylitol carboxylate according to claim 1, wherein a total monoester component of the at least one carboxylic ester of xylitol and a total diester component of the at least one carboxylic ester of xylitol each comprise at least two regioisomers.

9: A process for the enzymatic preparation of a xylitol carboxylate, comprising: A) providing xylitol and at least one acyl group donor, B) reacting the xylitol with the at least one acyl group donor in the presence of a lipase at a temperature of from 75° C. to 110° C., to give a xylitol carboxylate, and C) optionally, purifying the xylitol carboxylate.

10: The process according to claim 9, wherein A) comprises blending the xylitol and the at least one acyl group donor for at least ten minutes.

11: The process according to claim 9, wherein in B), the xylitol and the at least one acyl group donor make up at least 80% by weight, based on an overall reaction mixture at the start of B).

12: The process according to claim 9, wherein the lipase is selected from the group consisting of a lipase from Thermomyces lanuginosus, a lipases A or B from Candida antarctica, a lipase from Mucor miehei, a lipase from Humicola sp., a lipase from Rhizomucor javanicus, a lipase from Rhizopus oryzae, a lipase from Candida rugosa, a lipase from Rhizopus niveus, a lipase from Penicillium camemberti, a lipase from Aspergillus niger, a lipase from Penicillium cyclopium, and a respective at least 60% homologue at an amino acid level.

13: The process according to claim 9, wherein B) is carried out at a pressure of less than 1 bar.

14: A xylitol carboxylate obtainable by the process according to claim 9.

15: The xylitol carboxylate according to claim 1, wherein the xylitol carboxylate is a viscosity regulator, a care active ingredient, a foam booster or solubilizer, a antimicrobial agent, a antistat, a binder, a corrosion inhibitor, a dispersant, an emulsifier, a film former, a humectant, an opacifier, an oral care agent, a preservative, a skincare agent, a hydrophilic emollient, a foam stabilizer, or a nonionic surfactant.

16: The xylitol carboxylate according to claim 1, wherein the molar ratio of esterified primary hydroxyl groups to esterified secondary hydroxyl groups in the at least one carboxylic ester of xylitol is from 65:35 to 40:60.

17: The xylitol carboxylate according to claim 2, wherein the carboxylic acid component is derived from a natural fatty acid or a mixture thereof.

18: The xylitol carboxylate according to claim 4, wherein the triesters of xylitol are present in an amount of from 10% to 50% by weight, based on all carboxylic esters of xylitol present.

19: The process according to claim 9, wherein the at least one acyl group donor is selected from the group consisting of fatty acid esters and fatty acids.

20: The process according to claim 10, wherein in A), the blending is carried out within a temperature range from 80° C. to 120° C.

Description

EXAMPLES

[0161] Various xylitol carboxylates were synthesized as described hereinbelow.

[0162] Method for Determining Colour Numbers

[0163] An aliquot (approx. 10 g. so that the cuvette is sufficiently filled), was measured in a Lico 690 spectral colorimeter at room temperature or 90° C. in an 11 mm round cuvette and the colour numbers indicated in each case were recorded.

Example 1: Enzymatic Esterification of Xylitol with 2.00 Equiv. of Caprylic Acid (Inventive)

[0164] A mixture of xylitol (60.0 g, 0.394 mol, 1.00 equiv.) and caprylic acid (acid value=389 mg KOH/g, >98%, 113.70 g, 0.788 mol, 2.00 equiv.) was heated to 80° C. with stirring and while passing N.sub.2 through, and after 1 h immobilized Candida antarctica lipase B enzyme (5.21 g; Purolite D5619, corresponding to 45110 PLU) was added. The mixture was stirred at 80° C. and 15 mbar for 24 h, during which time the water that formed was continuously distilled off. The mixture was then filtered at 80° C. through a Büchner funnel with black ribbon filter to remove the enzyme. The product 25 obtained was homogeneous in the melt, colourless and had an acid value of 1.2 mg KOH/g. The content of triesters based on the sum total of all carboxylic esters of xylitol present was 27% by weight, determined via the area-% values of the GC-FID peaks.

Example 2: Enzymatic esterification of xylitol with 2.00 equiv. of caprylic/capric acid (Inventive)

[0165] A mixture of xylitol (70.8 g, 0.465 mol, 1.00 equiv.) and a caprylic/capric acid mixture (acid value=382 mg KOH/g, mixing ratio of caprylic acid to capric acid 60:40, 146.0 g, 0.930 mol, 2.00 equiv.) was heated to 90° C. for 1 h with stirring and while passing N.sub.2 through and, after cooling to 85° C., immobilized Candida antarctica lipase B enzyme (6.50 g; Purolite D5819, corresponding to 56280 PLU) was added. The mixture was stirred at 85° C. and 50 mbar for 24 h, during which time the water that formed was continuously distilled off. The mixture was then filtered at 80° C. through a Buchner funnel with black ribbon filter to remove the enzyme. The product obtained was homogeneous in the melt, colourless and had an acid value of 2.7 mg KOH/g. The content of triesters based on the sum total of all carboxylic esters of xylitol present was 28% by weight, determined via the area-% values of the GC-FID peaks.

Example 3: Enzymatic Esterification of Xylitol with 1.80 Equiv. of Capryllic/Capric Acid (Inventive)

[0166] A mixture of xylitol (75.7 g, 0.497 mol, 1.00 equiv.) and a caprylic/capric acid mixture (acid value=362 mg KOH/g, mixing ratio of caprylic acid to capric acid 60:40, 140.5 g, 0.895 mol, 1.80 equiv.) was heated to 90° C. for 1 h with stirring and while passing N.sub.2 through and, after cooling to 85° C., immobilized Candida antarctica lipase B enzyme (6.48 g: Purolite D5819, corresponding to 58106 PLU) was added. The mixture was stirred at 85° C. and 50 mbar for 24 h. during which time the water that formed was continuously distilled off. The mixture was then filtered at 80° C. through a Büchner funnel with black ribbon filter to remove the enzyme. The product obtained was homogeneous in the melt, colourless and had an acid value of 1.5 mg KOH/g. The content of triesters based on the sum total of all carboxylic esters of xylitol present was 25% by weight, determined via the area-% values of the GC-FID peaks.

Example 4: Enzymatic Esterification of Xylitol with 2.00 Equiv. of Stearic Acid (Inventive)

[0167] A mixture of xylitol (40.00 g, 0.263 mol, 1.00 equiv.) and stearic acid (acid value=198 mg KOH/g, >92%, 148.18 g, 0.526 mol, 2.00 equiv.) was heated to 90° C. with stirring and while passing N.sub.2 through, and after 1 h immobilized Candida antarctica lipase B enzyme (5.65 g; Purolite D5619, corresponding to 48919 PLU) was added. The mixture was stirred at 90° C. and 15 mbar for 24 h, during which time the water that formed was continuously distilled off. The mixture was then filtered at 80° C. through a Büchner funnel with black ribbon filter to remove the enzyme. The product obtained was homogeneous in the melt, clear, pale yellow and had an acid value of 1.3 mg KOH/g. The content of triesters based on the sum total of all carboxylic esters of xylitol present was 35% by weight, determined via the area-% values of the GC-FID peaks.

Example 5: Enzymatic Esterification of Xylitol with 2.00 Equiv. of Oleic Acid (Inventive)

[0168] A mixture of xylitol (40.00 g, 0.263 mol, 1.00 equiv.) and oleic acid (acid value=200 mg KOH/g, iodine value=92.3 g I.sub.2/100 g, 147.5 g, 0.526 mol, 2.00 equiv.) was heated to 90° C. with stirring and while passing N.sub.2 through and, after 1 h, immobilized Candida antarctica lipase B enzyme (5.65 g; Purolite D5619, corresponding to 48919 PLU) was added. The mixture was stirred at 80° C. and 15 mbar for 24 h, during which time the water that formed was continuously distilled off. The mixture was then filtered at 80° C. through a Büchner funnel with black ribbon filter to remove the enzyme. The product obtained was homogeneous in the melt, clear, yellowish and had an acid value of 1.1 mg KOH/g. The content of triesters based on the sum total of all carboxylic esters of xylitol present was 34% by weight, determined via the area-% values or the GC-FID peaks.

Example 6: Xylidyl Caprate/Caprylate (Noninventive)

[0169] A commercial product, GiO™-103 from GiOrbis Laboratories served here as the sample.

Example 7: Esterification of Xylitol with 2.00 Equiv. of Caprylic Acid According to KR101939851 (Noninventive)

[0170] The esterification of xylitol with fatty acids in the presence of acid catalysts at high temperatures is described for example in KR101939851 or EP2902009A1:

[0171] A mixture of xylitol (76.1 g, 0.500 mol, 1.00 equiv.) and caprylic acid (acid value=389 mg KOH/g, >98%, 144.2 g, 1.00 mol, 2.00 equiv.) was, after addition of para-toluenesulfonic acid (0.29 g, 0.2% based on caprylic acid), heated to 200° C. while stirring and passing N.sub.2 through. The mixture was then stirred at this temperature for 8 h, during which time the water that formed was continuously distilled off, until an acid value of 0.7 mg KOH/g was reached. The product obtained was yellow to brown and had a Gardner colour number of 6.4.

Example 8: Enzymatic Esterication of Xylitol with 2.00 Equiv. of Caprylic Acid at Low Temperature (Noninventive)

[0172] A mixture of xylitol (75.2 g, 0.494 mol, 1.00 equiv.), caprylic acid (acid value=389 mg KOH/g, >98%, 142.6 g, 0.989 mol, 2.00 equiv.), was reacted enzymatically as described in Basri et al. (Carbohydr. Res. 2011, 346, 472-479) at 60° C. for 29 h while stirring and passing N.sub.2 through. The product obtained was inhomogeneous in the melt (i.e. it formed two phases) and had an acid value of approx. 360 mg KOH/g.

[0173] Table 1 compares the parameters determined for the inventive and noninventive examples.

TABLE-US-00001 TABLE 1 Ratio Free Gardner Xylitol:degradation NMR xylitol Acid colour Ex. products (prim.:sec.) by GC [%] value number 1 * >99:1    51:49 1.9 1.2 0 2 * >99:1    53:47 1.6 2.7 0 3 * >99:1    54:46 4.4 1.5 0 4 * >99:1    57:43 0.9 1.3 0 5 * >99:1    55:45 1.3 1.1 1 6 95:5  67:33 10 3 7 7  1:99 Method not <0.05 0.7 6.4 applicable 8 >99:1    81:19 0.3 (360) 0 inventive examples are marked with an asterisk

Example 9: Thickening Performance in a Cosmetic Formulation

[0174] The thickening effect of inventive examples 1, 2 and 3 was evaluated in comparison with noninventive thickeners. For this purpose, a cosmetic formulation consisting of 9% SLES, 3% Cocamidopropyl Betaine and 0.7% NaCl in water was produced. The pH of this formulation was adjusted to 5.2 with citric acid. Into this formulation was in each case incorporated 1.1% of the example substances mentioned above by stirring at 60° C. for 30 min, and the viscosities were measured using a Brookfield viscometer (spindle 62, 30 rpm) at 22° C. The results of the viscosity measurements are shown in Table 2.

TABLE-US-00002 TABLE 2 Viscosity of the example formulation containing 1.1% thickener Example Viscosity [mPa*s] 1 inventive 7733 2 inventive 7200 3 inventive 7776 6 noninventive 5995 7 noninventive 1313 8 noninventive 3968

[0175] The results shown in Table 2 show that the formulations obtained in inventive examples 1, 2 and 3 have higher viscosity than in the noninventive examples.

Formulation Examples

[0176] Recipes 1a, 1b and 1c: Antiperspirant/Deodorant Formulations Containing Aluminium Salts

TABLE-US-00003 Recipe 1a 1b 1c Composition from example 4  3.2%  3.2%  3.2% C18-C22 Hydroxyalkyl Hydroxypropyl Guar (ESAFLOR HM 22,  0.2% Lamberti S.p.A.) Hydroxypropyl Guar (ESAFLOR HDR, Lamberti S.p.A.)  0.2%  0.2% Isoamyl Cocoate (TEGOSOFT ® AC, Evonik Operations GmbH)  5.4%  5.4%  5.4% Water to to to  100%  100%  100% Aluminum Chlorohydrate (50% aq.; Locron LIC, Clariant AG) 20.0% 20.0% 20.0% Methylisothiazolinone, Methylparaben, Ethylparaben; Dipropylene  0.8%  0.8% Glycol (Microcare MEM, Thor) Undecylenamidopropyltrimonium Methosulfate; Aqua; Propylene  1.0% Glycol (dermosoft ® UTM, Evonik Dr. Straetmans GmbH)

[0177] Recipes 2a, 2b and 2c: Aluminium-Free Deodorant Formulation without Antiperspirant Active Ingredients

TABLE-US-00004 Recipe 2a 2b 2c Composition from example 4  3.2%  3.2%  3.2% Hydroxypropyl Guar (ESAFLOR HDR, Lamberti S.p.A.) 0.15% C18-C22 Hydroxyalkyl Hydroxypropyl Guar (ESAFLOR HM 22, 0.15% 0.15% Lamberti S.p.A.) Polyglycery-3 Caprylate (TEGO ® Cosmo P 813, Evonik Operations  0.5%  0.5%  0.5% GmbH) Zinc Ricinoleate (TEGODEO ® PY 88 G, Evonik Operations GmbH)  1.0%  1.0%  1.0% Caprylic/Capric Triglyceride (TEGOSOFT ® CT, Evonik Operations 5.65% 5.65% 5.65% GmbH) Water to to to  100%  100%  100% Glycerin  3.0%  3.0%  3.0% Benzyl Alcohol, Benzoic Acid, Sorbic Acid (Rokonsal BSB-N,  1.0%  1.0%  1.0% Ashland Specialty Ingredients) Citric Acid (50% aq.) q.s. q.s. q.s. Pentylene Glycol (dermosoft ® Pentiol eco, Evonik Dr. Straetmans 4.0 GmbH)

[0178] Recipes 3a, 3b and 3c: O/W Deodorant Emulsion Containing Potassium Alum

TABLE-US-00005 Recipe 3a 3b 3c Composition from example 4  4.8%  4.8%  4.8% C18-C22 Hydroxyalkyl Hydroxypropyl Guar (ESAFLOR HM 22, 0.25% Lamberti S.p.A.) Hydroxypropyl Guar (ESAFLOR HDR, Lamberti S.p.A.) 0.25% 0.25% Isopropyl Palmitate (TEGOSOFT ® P, Evonik Operations GmbH)  5.0%  5.0%  5.0% Water to to to  100%  100%  100% Glycerin  3.0%  3.0%  3.0% Potassium alum  5.0%  5.0%  5.0% Methylisothiazolinone, Methylparaben, Ethylparaben; Dipropylene  0.8%  0.8% Glycol (Microcare MEM, Thor) Pentylene Glycol (dermosoft ® Pentiol eco, Evonik Dr. Straetmans  3.5% GmbH

[0179] Recipes 4a and 4b: Antiperspirant/Deodorant Lotion

TABLE-US-00006 Recipe 4a 4b Composition from example 4  3.0%  3.0% Diethylhexyl Carbonate (TEGOSOFT ® DEC, Evonik Operations GmbH)  3.0%  3.0% PPG-14 Butyl Ether (TEGOSOFT ® PBE, Evonik Operations GmbH)  3.0%  3.0% Polyglyceryl-3 Caprylate (TEGO ® Cosmo P813, Evonik Operations GmbH)  0.5%  0.5% Demineralized water to to  100%  100% Hydroxyethylcellulose (Natrosol 250 HHR, Ashland Specialty Chemicals)  1.0%  1.0% Aluminum Chlorohydrate (50%) (Reach 501L, Reheis) 15.0% 15.0% Methylisothiazolinone, Methylparaben, Ethylparaben; Dipropylene Glycol  0.8%  3.0% (Microcare MEM, Thor) 1,2-Hexanediol (dermosoft ® Hexiol, Evonik Dr. Straetmans GmbH)  2.8%

[0180] Recipe 5a and 5b 5c: Antiperspirant/Deodorant Creams

TABLE-US-00007 Recipe 5a 5b 5c Composition from example 4 3.0% 2.5% 2.5% Sodium Cetearyl Sulfate (Lanette E, BASF SE) 0.5% 0.5% Glyceryl Stearate 1.0% 1.0% 1.0% Stearyl Alcohol 1.0% 1.0% 1.0% PPG-15 Stearyl Ether 5.0% 5.0% 5.0% Isoamyl Cocoate (TEGOSOFT ® AC, Evonik Operations GmbH) 5.0% 5.0% 5.0% Diethylhexyl Carbonate (TEGOSOFT ® DEC, Evonik Operations 5.0% 5.0% 5.0% GmbH) Persea Gratissima (avocado) Oil 2.0% 2.0% 2.0% Polyglycery-3 Caprylate (TEGO ® Cosmo P813, Evonik 0.5% 0.5% 0.5% Operations GmbH) Zinc Ricinoleate (TEGODEO ® PY88 G, Evonik Operations 1.0% 1.0% 1.0% GmbH) Demineralized water to to to 100% 100% 100% Hydroxyethylcellulose (Natrosol 250 HHR (Ashland Specialty 1.0% 1.0% 1.0% Chemicals) Aluminum Chlorohydrate (50% aq.; Locron LIC, Clariant AG) 15.0% 15.0% 15.0% Methylisothiazolinone, Methylparaben, Ethylparaben; Dipropylene 0.8% 0.8% Glycol (Microcare MEM, Thor) Methylpropanediol; Caprylyl Glycol; Phenylpropanol (dermosoft ® 3.5% OMP; Evonik Dr. Straetmans GmbH)

[0181] Recipes 6a and 6b: Sun Care Spray SPF 30

TABLE-US-00008 Recipe 6a 6b Composition from example 4  4.0%  4.0% Phenoxyethyl Caprylate (TEGOSOFT ® XC, Evonik Operations GmbH)  3.2%  3.2% Isopropyl Palmitate (TEGOSOFT ® P, Evonik Operations GmbH)  2.0%  2.0% Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (Tinosorb S, BASF SE)  3.0%  3.0% Butyl Methoxydibenzoylmethane  2.0%  2.0% EHC  2.0%  2.0% Ethylhexyl Salicylate  4.0%  4.0% Octocrylene  4.0%  4.0% Glycerin  3.0%  3.0% Water to to  100%  100% Carbomer suspension 1 (Acrylates/C10-30 Alkyl Acrylate Crosspolymer,  1.0%  1.0% TEGO ® Carbomer 341ER, Evonik Operations GmbH, 20% in Phenoxyethyl Caprylate) Tris(hydroxymethyl)aminomethane (30% aq.)  0.6%  0.6% UV filter solution (20% Phenylbenzimidazole Sulfonic Acid, 8.8% 10.0% 10.0% tris(hydroxymethyl)aminomethane, demineralized water to 100%) Methylisothiazolinone, Methylparaben, Ethylparaben; Dipropylene Glycol  0.8% (Microcare MEM, Thor) Methylpropanediol; Caprylyl Glycol (dermosoft ® OM, Evonik Dr. 4.0 Straetmans GmbH)

[0182] Recipes 7a and 7b: Sunscreen Spray

TABLE-US-00009 Recipe 7a 7b 7c Composition from example 4 3.0% 2.5% 2.5% Glyceryl Stearate Citrate (AXOL ® C 62, Evonik Operations GmbH) 0.5% 0.5% Glyceryl Stearate 0.5% 0.5% 0.5% Stearyl Alcohol 0.5% 0.5% 0.5% Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (Tinosorb S, 3.0% 3.0% 3.0% BASF SE) Butyl Methoxydibenzoylmethane 2.0% 2.0% 2.0% Ethylhexyl Methoxycinnamate 2.0% 2.0% 2.0% Ethythexyl Salicylate 4.0% 4.0% 4.0% Octocrylene 4.0% 4.0% 4.0% Isopropyl Palmitate 2.0% 2.0% 2.0% Phenoxyethyl Caprylate (TEGOSOFT ® XC, Evonik Operations 3.2% 3.2% 3.2% GmbH) Glycerin 3.0% 3.0% 3.0% Demineralized water to to to  100%   100%   100%  Carbomer suspension (Acrylates/C10-30 Alkyl Acrylate 1.0% 1.0% 1.0% Crosspolymer, TEGO ® Carbomer 341ER, 20% in Phenoxyethyl Caprylate) Tromethamine (30%) 0.9% 0.9% 0.9% UV filter solution (20% Phenylbenzimidazole Sulfonic Acid, 8.8% 10.0%  10.0%  10.0%  tris(hydroxymethyl)aminomethane, demineralized water to 100%) Methylisothiazolinone, Methylparaben, Ethylparaben; Dipropylene 0.8% 0.8% Glycol (Microcare MEM, Thor) Methylpropanediol; Caprylyl Glycol; Phenylpropanol (dermosoft ® 3.0% OMP; Evonik Dr. Straetmans GmbH)

[0183] Recipes 8a, 8b and 8c: Sunscreen Lotion, SPF 30

TABLE-US-00010 Recipe 8a 8b 8c Composition from example 4 3.00% 2.00% 2.00% Cetearyl Glucoside (TEGO ® Care CG 90, 0.50% 0.50% Evonik Operations GmbH) Phenoxyethyl Caprylate (TEGOSOFT ® XC, 8.00% 8.00% 8.00% Evonik Operations GmbH) Diethylamino Hydroxybenzoyl Hexyl 6.00% 6.00% 6.00% Benzoate (Uvinul A Plus, BASF SE) Ethylhexyl Methoxycinnamate 8.00% 8.00% 8.00% Stearyl Alcohol 1.00% 1.00% 1.00% Glyceryl Stearate 1.00% 1.00% 1.00% Tocopheryl Acetate 0.50% 0.50% 0.50% Glycerin 2.00% 2.00% 2.00% Demineralized water to 100% to 100% to 100% Tromethamine 0.90% 0.90% 0.90% Phenylbenzimidazole Sulfonic Acid 2.00% 2.00% 2.00% Acrylates/C10-30 Alkyl Acrylate 0.30% 0.30% 0.30% Crosspolymer (TEGO ® Carbomer 341 ER, Evonik Operations GmbH) Sodium hydroxide (10% aq.) q.s. q.s. q.s. Methylisothiazolinone, Methylparaben, 0.80% 0.80% Ethylparaben; Dipropylene Glycol (Microcare MEM, Thor) Caprylyl Glycol; Glycerin; Glyceryl 1.0 Caprylate; Phenylpropanol; Aqua (dermosoft ® LP MB; Evonik Dr. Straetmans GmbH)

[0184] Recipes 9a, 9b and 9c. Sunscreen Lotion SPF 30, High UVA Protection

TABLE-US-00011 Recipe 9a 9b 9c Composition from example 4 3.00% 2.50% 2.50% Sodium Cetearyl Sulfate (Lanette E, BASF SE) 0.50% 0.50% Phenoxyethyl Caprylate (TEGOSOFT ® XC, Evonik 7.30% 7.30% 7.30% Operations GmbH) Butyl Methoxydibenzoylmethane 5.00% 5.00% 5.00% Diethylhexyl Butamido Triazone (UVAsorb HEB, 3V 1.00% 1.00% 1.00% Sigma) Ethylhexyl Salicylate 1.50% 1.50% 1.50% Octocrylene 3.50% 3.50% 3.50% Titanium Dioxide; Diethylhexyl Carbonate; Polyglyceryl-6 2.20% 2.20% 2.20% Polyhydroxystearate (TEGO ® Sun TDEC 45, Evonik Operations GmbH) Stearyl Alcohol 1.00% 1.00% 1.00% Nylon-10/10 (TEGOLON ® ECO 10-10, Evonik Operations 0.50% 0.50% 0.50% GmbH) Glyceryl Stearate 1.00% 1.00% 1.00% Tocopheryl Acetate 0.50% 0.50% 0.50% Glycerin 2.00% 2.00% 2.00% Demineralized water to 100% to 100% to 100% Citric Acid (50% aq.) 0.10% 0.10% 0.10% Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine 20.00% 20.00% 20.00%  (Tinosorb S, BASF SE) Acrylates/C 10-30 Alkyl Acrylate Crosspolymer (TEGO ® 0.30% 0.30% 0.30% Carbomer 341 ER, Evonik Operations GmbH) Sodium Hydroxide (10% aq.) 0.90% 0.90% 0.90% Methylisothiazolinone, Methylparaben, Ethylparaben; 0.80% 0.80% Dipropylene Glycol (Microcare MEM, Thor) Triethyl Citrate; Caprylyl Glycol; Benzoic Acid (Verstatil ®  1.0% TBO; Evonik Dr. Straetmans GmbH)

[0185] Recipes 10a, 10b and 10c: Sunscreen Lotion, SPF 30

TABLE-US-00012 Recipe 10a 10b 10c Composition from example 4 3.00% 2.00% 2.00% Methyl Glucose Sesquistearate 1.00% 1.00% (TEGO ® Care PS, Evonik Operations GmbH) Phenoxyethyl Caprylate 1.50% 1.50% 1.50% (TEGOSOFT ® XC, Evonik Operations GmbH) Octocrylene 10.00% 10.00% 10.00%  Butyl Methoxydibenzoylmethane 3.50% 3.50% 3.50% Titanium Dioxide; Diethylhexyl 14.50% 14.50% 14.50%  Carbonate; Polyglyceryl-6 Polyhydroxystearate (TEGO ® Sun TDEC 45, Evonik Operations GmbH) Stearyl Alcohol 0.20% 0.20% 0.20% Glyceryl Stearate 0.20% 0.20% 0.20% Tocopheryl Acetate 0.50% 0.50% 0.50% Glycerin 2.00% 2.00% 2.00% Demineralized water to 100% to 100% to 100% Acrylates/C10-30 Alkyl Acrylate 0.20% 0.20% 0.20% Crosspolymer (TEGO ® Carbomer 341 ER, Evonik Operations GmbH) Sodium Hydroxide (10% aq.) 0.60% 0.60% 0.60% Methylisothiazolinone, Methylparaben, 0.80% 0.80% Ethylparaben; Dipropylene Glycol (Microcare MEM, Thor) Methylpropanediol; Caprylyl Glycol;  3.0% Phenylpropanol (dermosoft ® OMP; Evonik Dr. Straetmans GmbH)

[0186] Recipes 11a, 11b and 11c: Sunscreen Lotion SPF 50, High UVA Protection

TABLE-US-00013 Recipe 11a 11b 11c Composition from example 4 3.00% 2.50% 2.50% Polyglycery-3 Methylglucose Distearate 0.50% 0.50% (TEGO ® Care 450, Evonik Operations GmbH) Phenoxyethyl Caprylate (TEGOSOFT ® 2.00% 2.00% 2.00% XC, Evonik Operations GmbH) Nylon-10/10 (TEGOLON ® ECO 10-10, 0.50% 0.50% 0.50% Evonik Operations GmbH) Butyl Methoxydibenzoylmethane 5.00% 5.00% 5.00% Diethylhexyl Butamido Triazone (UVAsorb 1.00% 1.00% 1.00% HEB, 3V Sigma) Bis-Ethylhexyloxyphenol Methoxyphenyl 3.00% 3.00% 3.00% Triazine (Tinosorb S, BASF SE) Ethylhexyl Salicylate 1.00% 1.00% 1.00% Octocrylene 8.00% 8.00% 8.00% Stearyl Alcohol 0.45% 0.45% 0.45% Glyceryl Stearate 0.45% 0.45% 0.45% Xanthan Gum (Keltrol CG-SFT, CP Kelco) 0.30% 0.30% 0.30% Tocopheryl Acetate 0.50% 0.50% 0.50% Hydroxyethylcellulose (Natrosol 250 0.50% 0.50% 0.50% HHR (Ashland Specialty Chemicals) Demineralized water to 100% to 100% to 100% Sodium Hydroxide (10% aq., pH adjustment q.s. q.s. q.s. to 7.5) Disodium Phenyl Dibenzimidazole 5.00% 5.00% 5.00% Tetrasulfonate (Neoheliopan AP, Symrise) Methylene Bis-Benzotriazolyl 8.00% 8.00% 8.00% Tetramethylbutylphenol (Tinosorb M, BASF SE) Methylisothiazolinone, Methylparaben, 0.80% 0.80% Ethylparaben; Dipropylene Glycol (Microcare MEM, Thor) Methylpropanediol; Caprylyl Glycol  3.8% (dermosoft ® OM, Evonik Dr. Straetmans GmbH)

[0187] Recipes 12a, 12b and 12c: Sunscreen Lotion, SPF 50

TABLE-US-00014 Recipe 12a 12b 12c Composition from example 4  3.50%  3.00%  3.00% Glyceryl Stearate Citrate (AXOL ® C 62, Evonik Operations GmbH)  1.00%  1.00% Phenoxyethyl Caprylate (TEGOSOFT ® XC, Evonik Operations  2.50%  2.50%  2.50% GmbH) Diethylamino Hydroxybenzoyl Hexyl Benzoate 10.00% 10.00% 10.00% Ethylhexyl Methoxycinnamate 10.00% 10.00% 10.00% Stearyl Alcohol  1.00%  1.00%  1.00% Glyceryl Stearate  1.00%  1.00%  1.00% Xanthan Gum (Keitrol CG-SFT, CP Kelco)  0.50%  0.50%  0.50% Tocopheryl Acetate  0.50%  0.50%  0.50% Glycerin  2.00%  2.00%  2.00% Demineralized water to 100% to 100% to 100% Phenylbenzimidazole Sulfonic Acid  4.00%  4.00%  4.00% Tromethamine  1.80%  1.80%  1.80% Methylisothiazolinone, Methylparaben, Ethylparaben; Dipropylene  0.80%  0.80% Glycol (Microcare MEM, Thor) Triethyl Citrate; Glyceryl Caprylate; Benzoic Acid (Verstatil ®   1.2% TBG MB, Evonik Dr. Straetmans GmbH)

[0188] Recipes 13a, 13b and 13c: Sunscreen Lotion SPF 50+

TABLE-US-00015 Recipe 13a 13b 13c Composition from example 4  3.00%   2.5%   2.5% Potassium Cetyl Phosphate   1.0%   1.0% Phenoxyethyl Caprylate (TEGOSOFT ® XC, Evonik Operations  3.00%  3.00%  3.00% GmbH) Butyl Methoxydibenzoylmethane  5.00%  5.00%  5.00% Octocrylene  4.90%  4.90%  4.90% Ethylhexyl Methoxycinnamate  0.10%  0.10%  0.10% Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (Tinosorb S, BASF  4.70%  4.70%  4.70% SE) Diethylhexyl Butamido Triazone (UVAsorb HEB, 3V Sigma)  3.70%  3.70%  3.70% Titanium Dioxide; Diethylhexyl Carbonate; Polyglyceryl-6 11.00% 11.00% 11.00% Polyhydroxystearate (TEGO ® Sun TDEC 45, Evonik Operations GmbH) Stearyl Alcohol  0.50%  0.50%  0 50% Glyceryl Stearate  0.50%  0.50%  0.50% Xanthan Gum (Keltrol CG-SFT, CP Kelco)  0.20%  0.20%  0.20% Glycerin  2.00%  2.00%  2.00% Demineralized water to 100% to 100% to 100% Methylisothiazolinone, Methylparaben, Ethylparaben; Dipropylene  0.80%  0.80% Glycol (Microcare MEM, Thor) Triethyl Citrate; Caprylyl Glycol; Benzoic Acid (Verstatil ® TBO;   0.9% Evonik Dr. Straetmans GmbH)

[0189] Recipes 14a and 14b: Body Lotion

TABLE-US-00016 Recipe 14a 14b Composition from example 4 4.0% 4.0% Isoamyl Cocoate (TEGOSOFT ® AC, Evonik Operations GmbH) 2.5% 2.5% Caprylic/Capric Triglyceride (TEGOSOFT ® CT, Evonik Operations 3.5% 3.5% GmbH) Water to 100% to 100% Creatine (TEGO ® Cosmo C 100, Evonik Operations GmbH) 0.5% 0.5% Carbomer suspension 2 (Carbomer, TEGO ® Carbomer 141, Evonik 1.0% 1.0% Operations GmbH, 20% in Ethylhexyl Stearate) Sodium Hydroxide (10% aq.) 0.6% 0.6% Phenoxyethanol, Ethylhexylglycerin (Euxyl PE 9010, Schülke & Mayr 0.7% GmbH) Aqua; Sodium Levulinate; Sodium Benzoate (Verstatil ® BL; Evonik Dr. 1.5% Straetmans GmbH) Glyceryl Caprylate (dermosoft ® GMCY MB; Evonik Dr. Straetmans 0.3% GmbH)

[0190] Recipes 15a and 15b: Natural Care Cream

TABLE-US-00017 Recipe 15a 15b Composition from example 4  6.0%  6.0% Caprylic/Capric Triglyceride (TEGOSOFT ® CT, Evonik Operations  8.0%  8.0% GmbH) Isopropyl Palmitate (TEGOSOFT ® P, Evonik Operations GmbH) 11.0% 11.0% Prunus Amygdalus Duicis (sweet almond) Oil 10.0% 10.0% Water to 100% to 100% Glycerin  3.0%  3.0% Sodium Hydroxide (10% aq.)  0.2%  0.2% Benzyl Alcohol, Benzoic Acid, Sorbic Acid (Rokonsal BSB-N,  0.8% Ashland Specialty Ingredients) Glycerin; Aqua; Sodium Levulinate; Sodium Anisate (dermosoft ®   3% 1388 eco; Evonik Dr. Straetmans GmbH) Glyceryl Caprylate (dermosoft ® GMCY MB; Evonik Dr. Straetmans  0.2% GmbH)

[0191] Recipe 16a and 16b: Anti-Ageing Cream

TABLE-US-00018 Recipe 16a 16b Composition from example 4 6.0% 6.0% Caprylic/Capric Triglyceride (TEGOSOFT ® CT, Evonik Operations 9.5% 9.5%| GmbH) C12-15 Alkyl Benzoate (TEGOSOFT ® TN, Evonik Operations GmbH) 9.5% 9.5% Water to 100% to 100% Glycerin 3.0% 3.0% Tetrapeptide-21; Glycerin; Butylene Glycol; Aqua (TEGO ® Pep 4-17, 4.0% 4.0% Evonik Operations) Sodium Hyaluronate (HyaCare ®, Evonik Operations GmbH) 0.1% 0.1% Hydrolyzed Hyaluronic Acid (HyaCare ® 50, Evonik Operations GmbH) 0.1% 0.1% Aqua; Ethylhexyl Stearate; Sodium Hyaluronate Crosspolymer; 5.0% 5.0% Polyglyceryl-4 Diisostearate/Polyhydroxystearate/Sebacate; Sodium Isostearate (HyaCare ® Filler CL, Evonik Operations GmbH) Methylisothiazolinone, Methylparaben, Ethylparaben; Dipropylene 0.8% Glycol (Microcare MEM, Thor) Aqua; Sodium Levulinate; Potassium Sorbate (VERSTATIL SL non 1.2% GMO; Evonik Dr. Straetmans GmbH9 Caprylyl Glycol (dermosoft ® Octiol; Evonik Dr. Straetmans GmbH) 0.2%

[0192] Recipe 17a and 17b: O/W Foundation

TABLE-US-00019 Recipe 17a 17b Composition from example 4 6.0% 6.0% Myristyl Myristate (TEGOSOFT ® MM, Evonik Operations GmbH) 2.0% 2.0% Isopropyl Myristate (TEGOSOFT ® M, Evonik Operations GmbH) 6.0% 6.0% Decyl Cocoate (TEGOSOFT ® DC, Evonik Operations GmbH) 6.0% 6.0% Cetyl Ricinoleate (TEGOSOFT ® CR, Evonik Operations GmbH) 1.0% 1.0% Water to 1 00% to 100% Glycerin 1.0% 1.0% Titanium Dioxide (Hombitan AC 360, Sachtleben) 8.0% 8.0% Iron Oxides (Sicovit Yellow 72, Rockwood Pigments) 0.9% 0.9% Iron Oxides (Sicovit Red E 172, Rockwood Pigments) 0.2% 0.2% Iron Oxides (Sicovit Brown 172, Rockwood Pigments) 0.4% 0.4% Iron Oxides (Sicovit Black 80 E 172, Rockwood Pigments) 0.1% 0.1% Cellulose (TEGO ® Feel Green, Evonik Operations GmbH) 2.0% 2.0% Sodium Hydroxide (10% aq.) 0.2% 0.2% Benzyl Alcohol, Benzoic Acid, Sorbic Acid (Rokonsal BSB-N, 1.0% Ashland Specialty Ingredients) Methylpropanediol; Caprylyl Glycol; Phenylpropanol (dermosoft ® 3.2% OMP; Evonik Dr. Straetmans GmbH)

[0193] Recipes 18a, 18b, 18c and 18d: Lotions with Cosmetic Active Ingredients

TABLE-US-00020 Recipe 18a 18b 18c 18d Composition from example 4 3.5% 3.5% 3.0% 3.0% Stearic Acid 0.5% 0.5% Glyceryl Stearate 0.5% 0.6% 0.6% 0.6% Cetearyl Alcohol 0.5% 0.6% 0.6% 0.6% Caprylic/Capric Triglyceride 8.5% 8.5% 8.5% 8.5% Ethylhexyl Palmitate (TEGOSOFT ® OP, Evonik 8.5% 8.5% 8.5% 8.5% Operations GmbH) Demineralized water to 100% to 100% to 100% to 100% Xanthan Gum (Keltrol CG-SFT, CP Kelco) 0.8% 0.8% 0.8% 0.8% Terminalia Arjuna Bark Extract; Pentylene Glycol 2.0% 2.0% 2.0% (proposed; TEGO ® Arjuna S, Evonik Operations GmbH) Betaine; Urea; Potassium Lactate; Sodium 5.0% Polyglutamate (proposed); Hydrolyzed Sclerotium Gum (TEGO ® Smooth; Evonik Operations GmbH) Phenoxyethanol, Methylparaben, Ethylparaben, 1.0% Propylparaben (Phenonip XB (Clariant International Ltd.) Methylisothiazolinone, Methylparaben, 0.8% 0.8% Ethylparaben; Dipropylene Glycol (Microcare MEM, Thor) Caprylyl Glycol; Glyceryl Caprylate; Dipropylene 1.0% Glycol (dermosoft ® MCAV MB; Evonik Dr. Straetmans GmbH)

[0194] Recipes 19a, 19b and 19c: Lotion with Low Oil Phase Content

TABLE-US-00021 Recipe 19a 19b 19c Composition from example 4 3.0% 2.0% 2.0% Polyglyceryl-3 Dicitrate/Stearate 1.0% 1.0% (TEGO ® Care PSC 3 (Evonik Operations GmbH) Cetearyl Alcohol 0.5% 0.5% 0.5% Caprylic/Capric Triglyceride 6.5% 6.5% 6.5% Demineralized water to 100% to 100% to 100% Xanthan Gum (Keltrol CG-SFT, CP 0.5% 0.5% 0.5% Kelco) Methylisothiazolinone, Methylparaben, 0.8% 0.8% Ethylparaben; Dipropylene Glycol (Microcare MEM, Thor) Glycerin; Aqua; Sodium Levulinate; 3.0% Sodium Anisate (dermosoft ® 1388; Evonik Dr. Straetmans GmbH

[0195] Recipes 20a, 20b 20c and 20d: O/W Serums 1

TABLE-US-00022 Recipe 20a 20b 20c 20d Composition from example 4 2.5% 2.5%  4.0%  4.0% Sodium Stearoyl Glutamate (Eumulgin SG, BASF 1.0% SE) Glyceryl Stearate 0.75% 0.75% Stearyl Alcohol 0.75% 0.75% Caprylic/Capric Triglyceride 2.0% 2.0%  2.0%  2.0% Oleyl Erucate (TEGOSOFT ® OER, Evonik 2.0% 2.0%  2.0%  2.0% Operations GmbH) Isoamyl Cocoate (TEGOSOFT ® AC, Evonik  3.0%  3.0% Operations GmbH) Persea Gratissima (avocado) Oil 1.0% 1.0%  1.0%  1.0% Aqua; Ethylhexyl Stearate; Sodium Hyaluronate 3.0% 3.0% Crosspolymer; Polyglyceryl-4 Dilsostearate/Polyhydroxystearate/Sebacate; Sodium Isostearate (HyaCare ® Filler CL, Evonik Operations) Demineralized water to 100% to 100% to 100% to 100% Butylene Glycol 5.0% 5.0%  5.0%  5.0% Tetrapeptide-21; Glycerin; Butylene Glycol; Aqua 2.0% 2.0%  2.0%  2.0% (TEGO ® Pep 4-17, Evonik Operations) Hydrolyzed Hyaluronic Acid (HyaCare ® 50, Evonik 0.1% 0.1%  0.1%  0.1% Operations) Xanthan Gum (Keltrol CG-SFT, CP Kelco) 0.5% 0.5%  0.5%  0.5% Sodium Hydroxide (10% aq.) 0.2% 0.2%  0.2%  0.2% Benzyl Alcohol, Benzoic Acid, Sorbic Acid 0.8% 0.8%  0.8% (Rokonsal BSB-N, Ashland Specialty Ingredients) Polygiutamic Acid; Sclerotium glucan; Betaine; 3.0% 3.0%  3.0%  3.0% Urea; Potassium Lactate (TEGO ® Smooth Complex, Evonik Operations) Triethyl Citrate; Glyceryl Caprylate; Benzoic Acid  1.2% (Verstatil ® TBG; Evonik Dr. Straetmans GmbH)

[0196] Recipes 20e, 20f, 20g and 20h: O/W Serums 2

TABLE-US-00023 Recipe 20e 20f 28g 20h Composition from example 4  3.0% 3.0% 2.0% 2.0% Cetearyl Glucoside (TEGO ® Care CG 90, Evonik Operations  0.5% GmbH) Polyglyceryl-3 Dicitrate/Stearate (TEGO ® Care PSC 3, 1.5% 1.5% Evonik Operations GmbH) Glyceryl Stearate 0.75% 0.5% 0.5% 0.5% Stearyl Alcohol 0.75% 0.5% 0.5% 0.5% Caprylic/Capric Triglyceride  2.0% 2.0% 2.0% 2.0% Oleyl Erucate (TEGOSOFT ® OER, Evonik Operations  2.0% 2.0% 2.0% 2.0% GmbH) Isoamyl Cocoate (TEGOSOFT ® AC, Evonik Operations  3.0% GmbH) Persea Gratissima (avocado) Oil  1.0% 1.0% 1.0% 1.0% Aqua; Ethylhexyl Stearate; Sodium Hyaluronate 3.0% 3.0% 3.0% Crosspolymer; Polyglyceryl-4 Diisostearate/Polyhydroxystearate/Sebacate; Sodium Isostearate (HyaCare ® Filler CL, Evonik Operations) Demineralized water to 100% to 100% to 100% to 100% Butylene Glycol  5.0% 5.0% 5.0% 5.0% Tetrapeptide-21; Glycerin; Butylene Glycol; Aqua (TEGO ®  2.0% 2.0% 2.0% 2.0% Pep 4-17, Evonik Operations) Hydrolyzed Hyaluronic Acid (HyaCare ® 50, Evonik  0.1% 0.1% 0.1% 0.1% Operations) Xanthan Gum (Keltrol CG-SFT, CP Kelco)  0.5% 0.5% 0.5% 0.5% Sodium Hydroxide (10% aq.)  0.2% 0.2% 0.2% 0.2% Benzyl Alcohol, Benzoic Acid, Sorbic Acid (Rokonsal BSB-N,  0.8% 0.8% 0.8% Ashland Specialty Ingredients) Polyglutamic Acid; Sclerotium glucan; Betaine;  3.0% 3.0% Urea; Potassium Lactate (TEGO ® Smooth Complex, Evonik Operations) Triethyl Citrate; Caprylyl Glycol; Benzoic Acid (Verstatil ® 1.0% TBO; Evonik Dr. Straetmans GmbH)

[0197] Recipes 21a, 21b and 21c: O/W Blemish Balm Lotion

TABLE-US-00024 Recipe 21a 21b 21c Composition from example 4 4.00% 3.00% 3.00% Polyglycery-3 Methylglucose Distearate (TEGO ® Care 450, 1.00% 1.00% Evonik Operations GmbH) Glyceryl Stearate 0.75% 0.75% 0.75% Stearyl Alcohol 0.75% 0.75% 0.75% Diethylhexyl Carbonate (TEGOSOFT ® DEC, Evonik Operations 7.40% 7.40% 7.40% GmbH) Aqua; Ethylhexyl Stearate; Sodium Hyaluronate Crosspolymer; 2.00% 2.00% 2.00% Polyglyceryl-4 Diisostearate/Polyhydroxystearate/Sebacate; Sodium Isostearate (HyaCare ® Filler CL, Evonik Operations) Ethylhexyl Methoxycinnamate 5.00% 5.00% 5.00% Diethylamino Hydroxybenzoyl Hexyl Benzoate (Uvinul A Plus, 3.00% 3.00% 3.00% BASF SE) Phytosphingosine 0.10% 0.10% 0.10% Hydrolyzed Hyaluronic Acid (HyaCare ® 50, Evonik Operations) 0.10% 0.10% 0.10% Tetrapeptide-21; Glycerin; Butylene Glycol; Aqua (TEGO ® Pep 2.00% 2.00% 2.00% 4-17, Evonik Operations) Demineralized water to 100% to 100% to 100% Titanium Dioxide (Hombitan AC 360, Sachtleben) 3.00% 3.00% 3.00% Talc 2.00% 2.00% 2.00% Iron Oxide (Unipure Yellow LC 182, Sensient Technologies) 0.36% 0.36% 0.36% Iron Oxide (Unipure Red LC 381, Sensient Technologies) 0.12% 0.12% 0.12% Iron Oxide (Unipure Black LC 989, Sensient Technologies) 0.08% 0.08% 0.08% Isoamyl Cocoate (TEGOSOFT ® AC, Evonik Operations GmbH) 4.44% 4.44% 4.44% Phenoxyethyl Caprylate (TEGOSOFT ® XC, Evonik Operations 4.00% 4.00% 4.00% GmbH) Nylon-10/10 (TEGOLON ® ECO 10-10, Evonik Operations 3.00% 3.00% 3.00% GmbH) Glycerin 3.00% 3.00% 3.00% Xanthan Gum (Keltrol CG-SFT, CP Kelco) 0.50% 0.50% 0.50% Ethanol 3.00% 3.00% 3.00% Methylisothiazolinone, Methylparaben, Ethylparaben; 0.80% 0.80% Dipropylene Glycol (Microcare MEM, Thor) Methylpropanediol; Caprylyl Glycol (dermosoft ® OM, Evonik  4.0% Dr. Straetmans GmbH)

[0198] Recipes 22a, 22b, 22c and 22d: Lotion for Sensitive Skin

TABLE-US-00025 Recipe 22a 22b 22c 22d Composition from example 4  3.0%  3.0%  3.0%  3.0% Glyceryl Stearate  0.5%  1.0%  0.5%  0.5% Cetearyl Alcohol  1.0%  1.0%  1.0%  1.0% Butyrospermum Parkii Butter (shea butter)  3.0%  3.0%  3.0%  3.0% Caprylic/Capric Triglyceride  5.0%  5.0%  5.0%  5.0% Isopropyl Palmitate (TEGOSOFT ® P, Evonik  5.0%  5.0%  5.0%  5.0% Operations GmbH) Xanthan Gum (Keltrol CG-SFT, CP Kelco)  0.2%  0.2%  0.2%  0.2% Glycerin  5.0%  5.0%  5.0%  5.0% Urea 10.0% 15.0% 20.0% 20.0% Demineralized water to 100% to 100% to 100% to 100% Phenoxyethanol, Ethylhexylglycerin (Euxyl PE  0.7% 9010, Schülke & Mayr GmbH) Sodium Hydroxide (10% aq.) (pH adjustment to q.s. 5.0) Sodium Benzoate, Potassium Sorbate (Euxyl K  1.2% 712, Schülke & Mayr GmbH) Methylisothiazolinone, Methylparaben,  0.8% Ethylparaben; Dipropylene Glycol (Microcare MEM, Thor) Sodium Anisate (dermosoft ® anisate; Evonik Dr. 0.12% Straetmans GmbH) Levulinic Acid; Sodium Levulinate; Glycerin; Aqua  1.0% (dermosoft ® 700B; Evonik Dr. Straetmans GmbH) Glyceryl Caprylate (dermosoft ® GMC MB;  0.3% Evonik Dr. Straetmans GmbH)

[0199] Recipes 23a, 23b, 23c and 23d: Care Lotion for Dry Skin 1

TABLE-US-00026 Recipe 23a 23b 23c 23d Composition from example 4  3.0%  2.5%  3.0%  3.0% Sodium Stearoyl Glutamate (Eumulgin SG, BASF  1.0% SE) Glyceryl Stearate  1.0%  1.0%  1.5%  1.5% Cetearyl Alcohol  1.0%  1.0%  1.5%  1.5% Cetyl Ricinoleate  2.0%  2.0%  2.0%  2.0% Oleyl Erucate (TEGOSOFT ® OER, Evonik  5.0%  5.0%  5.0%  5.0% Operations GmbH) Isoamyl Cocoate (TEGOSOFT ® AC, Evonik  8.0%  8.0%  8.0%  8.0% Operations GmbH) Decyl Cocoate (TEGOSOFT ® DC, Evonik  3.0%  3.0%  3.0%  3.0% Operations GmbH) Xanthan Gum (Keltrol CG-SFT, CP Kelco)  0.2%  0.2%  0.2%  0.2% Glycerin  5.0%  5.0%  5.0%  5.0% Urea 10.0% 10.0% 15.0% 15.0% Demineralized water to 100% to 100% to 100% to 100% Methylisothiazolinone, Methylparaben,  0.8%  0.8%  0.8% Ethylparaben; Dipropylene Glycol (Microcare MEM, Thor) Phenethyl Alcohol (dermosoft ® PEA; Evonik Dr.  1.0% Straetmans GmbH)

[0200] Recipes 23e, 23f, 23g and 23h: Care Lotion for Dry Skin 2

TABLE-US-00027 Recipe 23e 23f 23g 23h Composition from example 4  2.5%  3.0%  3.0%  3.0% Polyglyceryl-6 Distearate  0.5% Stearic Acid  0.5%  0.5% Glyceryl Stearate  1.5%  1.5%  1.5%  1.5% Cetearyl Alcohol  1.5%  1.5%  1.5%  1.5% Cetyl Ricinoleate  2.0%  2.0%  2.0%  2.0% Oleyl Erucate (TEGOSOFT ® OER, Evonik  5.0%  5.0%  5.0%  5.0% Operations GmbH) Isoamyl Cocoate (TEGOSOFT ® AC, Evonik  8.0%  8.0%  8.0%  8.0% Operations GmbH) Decyl Cocoate (TEGOSOFT ® DC, Evonik  3.0%  3.0%  3.0%  3.0% Operations GmbH) Xanthan Gum (Keltrol CG-SFT, CP Kelco)  0.2%  0.2%  0.2%  0.2% Glycerin  5.0%  5.0%  5.0%  5.0% Urea 15.0% 20.0% 20.0% 20.0% Demineralized water to 100% to 100% to 100% to 100% Methylisothiazolinone, Methylparaben,  0.8%  0.8%  0.8% Ethylparaben; Dipropylene Glycol (Microcare MEM, Thor) Phenylpropanol (dermosoft ® 250 eco; Evonik Dr.  0.4% Straetmans GmbH) 1,2-Hexanediol (dermosoft ® Hexiol; Evonik Dr.  3.0% Straetmans GmbH)

[0201] Recipes 24a, 24b and 24c: Preservative-Free Lotions 1

TABLE-US-00028 Recipe 24a 24b 24c Composition from example 4  3.0%  2.0%  3.0% (AXOL ® C 62, Evonik Operations GmbH)  1.0% Glyceryl Stearate  0.2%  0.2%  0.5% Stearyl Alcohol  0.2%  0.2%  0.5% Prunes Amygdalus Dulcis (sweet almond) Oil 10.0% 10.0% 10.0% Isoamyl Cocoate (TEGOSOFT ® AC, Evonik Operations  6.6%  6.6%  6.0% GmbH) Glycerin  4.0%  4.0%  4.0% Demineralized water to 100.0% to 100.0% to 100.0% Caprylyl Glycol, Glycerin, Glyceryl Caprylate, Phenylpropanol  1.0%  1.0% (Dermosoft ® LP, Evonik Dr. Straetmans GmbH) Methylpropanediol, Caprylyl Glycol, Phenylpropanol  4.0% (Dermosoft ® OMP, Evonik Dr. Straetmans GmbH) Xanthan Gum (Keltrol CG-SFT, CP Kelco)  0.5%  0.5%  0.5%

[0202] Recipes 24d, 24e and 24f: Preservative-Free Lotions 2

TABLE-US-00029 Recipe 24d 24e 24f Composition from example 4  3.0%  3.0%  1.5% Glyceryl Stearate SE  0.5% Polyglyceryl-3 Dicitrate/Stearate (TEGO ® Care PSC 3, Evonik  1.5% Operations GmbH) Glyceryl Stearate  0.5%  0.5%  0.5% Stearyl Alcohol  0.5%  0.5%  0.5% Prunus Amygdalus Dulcis (sweet almond) Oil 10.0% 10.0% 10.0% Isoamyl Cocoate (TEGOSOFT ® AC, Evonik Operations GmbH)  6.0%  6.0%  6.0% Glycerin  4.0%  4.0%  4.0% Demineralized water to to to 100.0% 100.0% 100.0% Methylpropanediol, Caprylyl Glycol, Phenylpropanol  4.0% (Dermosoft ® OMP, Evonik Dr. Straetmans GmbH) Caprylyl Glycol (Dermosoft ® Octiol, Evonik Dr. Straetmans  0.4%  0.4% GmbH) p-Anisic Acid 10% solution (dissolve 3.0 g of Sodium Hydroxide  2.0%  2.0% in 56.5 g of demineralized water, add 30.0 g of Glycerin and 10.0 g of Dermosoft ® Octiol [Evonik Dr. Straetmans GmbH], and stir until the solution is clear) Citric Acid (10% aq.) (pH adjustment to 6.0) q.s. q.s. Xanthan Gum (Keltrol CG-SFT, CP Kelco)  0.5%  0.5%  0.5%

[0203] Recipes 25a and 25b: W/O Lotion

TABLE-US-00030 Recipe 25a 25b Composition from example 5  2.0%  2.0% Beeswax  0.5%  0.5% Castor wax  0.5%  0.5% Paraffinum perliquidum 10.5% 10.5% Decyl Cocoate (TEGOSOFT ® DC,  8.0%  8.0% Evonik Operations GmbH) Tocopheryl Acetate  0.5%  0.5% Cyclopentasiloxane  6.0%  6.0% Sodium Chloride  0.5%  0.5% Water to 100% to 100% Glycerin  3.0%  3.0% Phenoxyethanol; Ethylhexylglycerin  0.7% (Euxyl PE 9010, Schülke & Mayr GmbH) Ethanol  5.0%  5.0% Glyceryl Caprylate (dermosoft ® GMC;  0.4% Evonik Dr. Straetmans GmbH) Zinc Sulfate  1.0%

[0204] Recipes 26a and 26b: W/O Cream

TABLE-US-00031 Recipe 26a 26b Composition from example 5  2.0%  2.0% Mineral oil 17.0% 17.0% Castor wax  0.4%  0.4% Microcrystalline Wax  0.6%  0.6% Water to 100% to 100% Sodium Chloride  0.5%  0.5% Urea 10.0% 10.0% Phenoxyethanol; Ethylhexylglycerin  0.7% (Euxyl PE 9010, Schülke & Mayr GmbH) Glyceryl Caprylate (dermosoft ® GMC; 0.35% Evonik Dr. Straetmans GmbH) Pentylene Glycol (dermosoft ® Pentiol  2.0% eco; Evonik Dr. Straetmans GmbH)

[0205] Recipes 27a and 27b: Quick-Breaking Cream

TABLE-US-00032 Recipe 27a 27b Composition from example 5 0.8%  0.8% Cetyl Dimethicone (ABIL ® Wax 9801, 1.6%  1.6% Evonik Operations GmbH) Diethylhexyl Carbonate (TEGOSOFT ® 4.0%  4.0% DEC, Evonik Operations GmbH) Dimethicone (ABIL ® 350, Evonik 1.0%  1.0% Operations GmbH) Cyclopentasiloxane 4.0%  4.0% Magnesium Stearate 0.3%  0.3% Water to 100% to 100% Propylene Glycol 5.0%  5.0% Sodium Chloride 1.0%  1.0% Methylisothiazolinone, Methylparaben, 0.8% Ethylparaben; Dipropylene Glycol (Microcare MEM, Thor) Glyceryl Caprylate (dermosoft ® GMC; 0.25% Evonik Dr. Straetmans GmbH) Phenylpropanol (dermosoft ® 250 eco; 0.35% Evonik Dr. Straetmans GmbH)

[0206] Recipes 28a, 26b and 28c: Cooing Body Lotion

TABLE-US-00033 Recipe 28a 28b 28c Composition from example 5  2.0%  1.5%  1.5% Polyglyceryl-4 —  0.5%  0.5% Diisostearate/Polyhydroxystearate/Sebacate (ISOLAN ® GPS, Evonik Operations GmbH) Castorwax  0.5%  0.5%  0.5% Beeswax  0.5%  0.5%  0.5% Ethylhexyl Stearate (TEGOSOFT ® OS, Evonik 10.0% 10.0% 10.0% Operations GmbH) Diethylhexyl Carbonate (TEGOSOFT ® DEC,  8.5%  8.5%  8.5% Evonik Operations GmbH) Dimethicone (Belsil DM 5, Wacker Chemical  6.0%  6.0%  6.0% Corp.) Tocopheryl Acetate  0.5%  0.5%  0.5% Glycerin  3.0%  3.0%  3.0% Water to to to  100%  100%  100% Sodium Chloride  1.0%  1.0%  1.0% Ethanol 20.0% 20.0% 20.0% Ethylhexylglycerin (dermosoft ® EHG; Evonik  0.5% Dr. Straetmans GmbH)

[0207] Recipes 29a, 29b and 29c: W/O Cream Based on Natural Ingredients

TABLE-US-00034 Recipe 29a 29b 29c Composition from example 5 3.0% 2.5% 2.5% Diisostearoyl Polyglyceryl-3 Dimer Dilinoleate — 0.5% 0.5% (ISOLAN ® PDI, Evonik Operations GmbH) Diethylhexyl Carbonate (TEGOSOFT ® DEC, 7.0% 7.0% 7.0% Evonik Operations GmbH) Oleyl Erucate (TEGOSOFT ® OER, Evonik 3.0% 3.0% 3.0% Operations GmbH) Almond oil 7.0% 7.0% 7.0% Shea butter 2.0% 2.0% 2.0% Cetyl Ricinoleate (TEGOSOFT ® CR, Evonik 1.0% 1.0% 1.0% Operations GmbH) Beeswax 0.6% 0.6% 0.6% Castor wax 0.4% 0.4% 0.4% Glycerin 5.0% 5.0% 5.0% Water to to to 100% 100% 100% Magnesium sulfate heptahydrate 1.5% 1.5% 1.5% Sodium Benzoate, Potassium Sorbate (Euxyl K 0.5% 0.5% 712, Schülke & Mayr GmbH) Pentylene Glycol (dermosoft ® Pentiol eco; 3.0% Evonik Dr. Straetmans GmbH)

[0208] Recipes 30a, 30b and 30c: Cold-Preparable Lotion

TABLE-US-00035 Recipe 30a 30b 30c Composition from example 5  3.0%  2.5%  2.5% Polyglyceryl-3 Oleate (ISOLAN ® GO 33, —  0.5%  0.5% Evonik Operations GmbH) Isoamyl Cocoate (TEGOSOFT ® AC, Evonik  5.0%  5.0%  5.0% Operations GmbH) Diethylhexyl Carbonate (TEGOSOFT ® DEC, 12.0% 12.0% 12.0% Evonik Operations GmbH) Phenoxyethyl Caprylate (TEGOSOFT ® XC,  4.0%  4.0%  4.0% Evonik Operations GmbH) Zinc Stearate  0.5%  0.5%  0.5% Water to to to  100%  100%  100% Glycerin  3.0%  3.0%  3.0% Sodium Chloride  1.5%  1.5%  1.5% Phenoxyethanol; Ethylhexylglycerin (Euxyl PE  0.7%  0.7% 9010, Schülke & Mayr GmbH) Benzyl Alcohol; Caprylyl Glycol; Benzoic Acid  1.5% (VERSTATIL ® BOB; Evonik Dr. Straetmans GmbH)

[0209] Recipes 31a, 31 b and 31c: Moisturizing Lotion Containing Urea

TABLE-US-00036 Recipe 31a 31b 31c Composition from example 5  2.0%  1.5%  1.5% Cetyl PEG/PPG-10/1 Dimethicone (ABIL ® —  0.5%  0.5% EM 180, Evonik Operations GmbH) Microcrystalline Wax  0.5%  0.5%  0.5% Castor wax  0.5%  0.5%  0.5% C12-15 Alkyl Benzoate  7.5%  7.5%  7.5% Oleyl Erucate (TEGOSOFT ® OER, Evonik  5.0%  5.0%  5.0% Operations GmbH) Ethylhexyl Palmitate (TEGOSOFT ® OP,  5.0%  5.0%  5.0% Evonik Operations GmbH) Caprylic/Capric Triglyceride  5.0%  5.0%  5.0% Glycerin  3.0%  3.0%  3.0% Urea 20.0% 20.0% 20.0% Magnesium sulfate heptahydrate  1.0%  1.0%  1.0% Water to to to  100%  100%  100% Phenoxyethanol; Ethylhexylglycerin (Euxyl PE 0.70% 0.70% 9010, Schülke & Mayr GmbH) Parfum 0.10% 0.10% 0.10% Methylpropanediol; Phenoxyethanol; Caprylyl  1.5% Glycol (VERSTATIL ® MFC; Evonik Dr. Straetmans GmbH)

[0210] Recipes 32a 32b 32c and 32d: W/O Lotion with Light-as-Silk Skin Feel

TABLE-US-00037 Recipe 32a 32b 32c 33d Composition from example 5  2.5%  2.0%  2.0%  2.0% Cetyl PEG/PPG-10/1 Dimethicone (ABIL ® EM —  0.5% — — 90, Evonik Operations GmbH) Bis-PEG/PPG-14/14 Dimethicone; Dimethicone — —  1.0%  1.0% (ABIL ® EM 97 S, Evonik Operations GmbH) Microcrystalline Wax  0.1%  0.1%  0.1%  0.1% Castor wax  0.1%  0.1%  0.1%  0.1% Diethylhexyl Carbonate (TEGOSOFT ® DEC, 11.8% 11.8% 11.8% 11.8% Evonik Operations GmbH) Myristyl Myristate (TEGOSOFT ® MM, Evonik  1.0%  1.0%  1.0%  1.0% Operations GmbH) Dimethicone (Belsil DM 5, Wacker Chemical  8.0%  8.0%  8.0%  8.0% Corp.) Dimethicone (ABIL ® 350, Evonik Operations  0.5%  0.5%  0.5%  0.5% GmbH) Glycerin  3.0%  3.0%  3.0%  3.0% Magnesium sulfate heptahydrate  1.5%  1.5%  1.5%  1.5% Water to to to to  100%  100%  100%  100% Benzyl Alcohol; Ethylhexylglycerin; Tocopherol  0.7%  0.7%  0.7% (Euxyl K 900, Schülke & Mayr GmbH) Phenoxyethanol; Ethylhexylglycerin  1.0% (VERSTATIL ® PE; Evonik Dr. Straetmans GmbH)

[0211] Recipes 33a, 33b and 33c: Baby-Care Product

TABLE-US-00038 Recipe 33a 33b 33c Composition from example 5  3.0%  2.0%  2.0% Paraffinum Liquidum; Petrolatum; Ozokerite; Glyceryl —  1.0%  1.0% Oleate; Lanolin Alcohol (PROTEGIN ® XN, Evonik Operations GmbH) Castor wax  0.1%  0.1%  0.1% Microcrystalline Wax  0.1%  0.1%  0.1% Oleyl Erucate (TEGOSOFT ® OER, Evonik Operations  1.0%  1.0%  1.0% GmbH) Isoamyl Cocoate (TEGOSOFT ® AC, Evonik  3.8%  3.8%  3.8% Operations GmbH) Ethylhexyl Palmitate (TEGOSOFT ® OP, Evonik  1.0%  1.0%  1.0% Operations GmbH) Almond oil  1.0%  1.0%  1.0% Zinc Oxide 20.0% 20.0% 20.0% Glycerin  3.0%  3.0%  3.0% Magnesium sulfate heptahydrate  1.0%  1.0%  1.0% Sodium Lactate; Sodium PCA; Glycine; Fructose;  5.0%  5.0%  5.0% Urea; Niacinamide; Inositol; Sodium Benzoate; Lactic Acid (LACTIL, Evonik Operations GmbH) Betaine (TEGO ® Natural Betaine, Evonik Operations  3.0%  3.0%  3.0% GmbH) Water to 100% to 100% to 100% Benzyl Alcohol; Ethylhexylglycerin; Tocopherol (Euxyl  0.7%  0.7% K 900, Schülke & Mayr GmbH) p-Anisic Acid (dermosoft ® 688; Evonik Dr. Straetmans 0.12% GmbH) Pentylene Glycol (dermosoft ® Pentiol eco; Evonik Dr.  2.5% Straetmans GmbH)

[0212] Recipe 34a, 34b and 34c: Foot-Care Product

TABLE-US-00039 Recipe 34a 34b 34c Composition from example 5 3.0% 2.5% 2.5% Petrolatum; Ozokerite; Hydrogenated Castor Oil; Glyceryl — 0.5% 0.5% Isostearate; Polyglyceryl-3 Oleate (PROTEGIN ® W, Evonik Operations GmbH) Castor wax 0.1% 0.1% 0.1% Microcrystalline Wax 0.1% 0.1% 0.1% Diethylhexyl Carbonate (TEGOSOFT ® DEC, Evonik 9.0% 9.0% 9.0% Operations GmbH) Ethylhexyl Palmitate (TEGOSOFT ® OP, Evonik Operations 9.0% 9.0% 9.0% GmbH) Stearyl Heptanoate (TEGOSOFT ® SH, Evonik Operations 8.8% 8.8% 8.8% GmbH) Glycerin 3.0% 3.0% 3.0% Magnesium sulfate heptahydrate 1.0% 1.0% 1.0% Ceramide NP; Ceramide AP; Ceramide EOP; 5.0% 5.0% 5.0% Phytosphingosine; Cholesterol; Sodium Lauroyl Lactylate; Carbomer; Xanthan Gum (SK-INFLUX V, Evonik Operations GmbH) Betaine (TEGO ® Natural Betaine, Evonik Operations 3.0% 3.0% 3.0% GmbH) Water to 100% to 100% to 100% Benzyl Alcohol; Ethylhexylglycerin; Tocopherol (Euxyl K 0.7% 0.7% 900, Schülke & Mayr GmbH) Phenoxyethanol; Benzoic Acid (Verstatil ® BP; Evonik Dr. 1.0% Straetmans GmbH)

[0213] Recipes 35a and 35b: Sunscreen Lotion SPF 30 UVA with Insect Repellent

TABLE-US-00040 Recipe 35a 35b Composition from example 5  3.0%  2.0% Polyglyceryl-2 Dipolyhydroxystearate (Dehymuls —  1.0% PGPH, BASF SE) Oleyl Erucate (TEGOSOFT ® OER, Evonik  1.5%  1.5% Operations GmbH) Diethylhexyl Carbonate (TEGOSOFT ® DEC, Evonik  1.5%  1.5% Operations GmbH) Diethylamino Hydroxybenzoyl Hexyl Benzoate (Uvinul  5.4%  5.4% A Plus, BASF SE) Ethylhexyl Methoxycinnamate 10.0% 10.0% Octocrylene  2.0%  2.0% Polyacrylamide; C13-14 Isoparaffin; Laureth-7  2.1%  2.1% (Sepigel 305, Seppic) Ethyl Butylacetylaminopropionate (R3535, Merck  4.0%  4.0% KGaA) Tocopheryl Acetate  0.5%  0.5% Glycerin  3.0%  3.0% Ethanol  0.5%  0.5% Magnesium sulfate heptahydrate  1.0%  1.0% Water to 100% to 100% Benzyl Alcohol; Ethylhexylglycerin; Tocopherol (Euxyl  0.7%  0.7% K 900, Schülke & Mayr GmbH) Parfum  0.1%  0.1%

[0214] Recipes 36a and 36b: Sunscreen lotion SPF 30 UVA in accordance with Ecocert criteria

TABLE-US-00041 Recipe 36a 36b Composition from example 5  3.0%  2.0% Polyglyceryl-3 Polyricinoleate (Cithrol PG3PR, (Croda Int. Plc) —  1.0% Isoamyl Cocoate (TEGOSOFT ® AC, Evonik Operations GmbH)  2.0%  2.0% Decyl Cocoate (TEGOSOFT ® DC, Evonik Operations GmbH) 10.0% 10.0% Isopropyl Palmitate (TEGOSOFT ® P, Evonik Operations GmbH) 10.0% 10.0% Zinc Oxide (Zinc Oxide PI, Symrise) 16.0% 16.0% Titanium Dioxide (nano); Alumina; Stearic Acid (EusolexT-S, Merck  9.0%  9.0% KGaA) Water to 100% to 100% Glycerin  3.0%  3.0% Magnesium sulfate heptahydrate  1.0%  1.0% Sodium Benzoate, Potassium Sorbate (Euxyl K 712, Schülke & Mayr  0.5%  0.5% GmbH)

[0215] Recipes 37a 37b 37c and 37d: Sunscreen SPF 30 UVA

TABLE-US-00042 Recipe 37a 37b 37c 37d Composition from example 5  3.0%  2.0%  3.0%  2.0% Cetyl PEG/PPG-10/1 Dimethicone (ABIL ® EM —  1.0% — — 90, Evonik Operations GmbH) Polyglyceryl-4 — — —  1.0% Diisostearate/Polyhydroxystearate/Sebacate (ISOLAN ® GPS, Evonik Operations GmbH) Diethylhexyl Carbonate (TEGOSOFT ® DEC, 13.0% 13.0% 11.3% 11.3% Evonik Operations GmbH) C12-15 Alkyl Benzoate 13.0% 13.0% 11.3% 11.3% Bis-Ethylhexyloxyphenol Methoxyphenyl  1.0%  1.0%  1.5%  1.5% Triazine (Tinosorb S, BASF SE) Butyl Methoxydibenzoylmethane — —  3.0%  3.0% Ethylhexyl Methoxycinnamate  5.0%  5.0% Octocrylene — —  6.0%  6.0% Homosalate — —  4.0%  4.0% Diethylamino Hydroxybenzoyl Hexyl Benzoate  5.0%  5.0% — — (Uvinul A Plus, BASF SE) Water to 100% to 100% to 100% to 100% Glycerin  3.0%  3.0%  3.0%  3.0% Magnesium sulfate heptahydrate  1.0%  1.0%  1.0%  1.0% UV filter solution (20% Phenylbenzimidazole 15.0% 15.0% 15.0% 15.0% Sulfonic Acid (Eusolex 232, Merck KGaA, 8.8% tris(hydroxymethyl)aminomethane, water to 100%) Benzyl Alcohol; Ethylhexylglycerin; Tocopherol  0.7%  0.7%  0.7%  0.7% (Euxyl K 900, Schülke & Mayr GmbH)

[0216] Recipes 38a, 38b, 38c and 38d: Sunscreen Lotion SPF 50 UVA

TABLE-US-00043 Recipe 38a 38b 38c 38d Composition from example 5 3.0% 2.5% 3.0% 2.5% Cetyl PEG/PPG-10/1 Dimethicone (ABIL ® — 1.0% — 1.0% EM 90, Evonik Operations GmbH) Microcrystalline Wax 0.3% 0.3% 0.3% 0.3% Castor wax 0.3% 0.3% 0.3% 0.3% Diethylhexyl Carbonate (TEGOSOFT ® 2.4% 2.4% — — DEC, Evonik Operations GmbH) Phenoxyethyl Caprylate (TEGOSOFT ® — — 3.9% 3.9% XC, Evonik Operations GmbH) Bis-Ethylhexyloxyphenol Methoxyphenyl 6.0% 6.0% — — Triazine (Tinosorb S, BASF SE) Diethylamino Hydroxybenzoyl Hexyl 7.0% 7.0% 5.0% 5.0% Benzoate (Uvinul A Pius, BASF SE) Butyl Methoxydibenzoylmethane — — 4.5% 4.5% Ethylhexyl Salicylate 3.0% 3.0% 5.0% 5.0% Ethylhexyl Methoxycinnamate 7.0% 7.0% — — Octocrylene — — 9.0% 9.0% Homosalate 3.0% 3.0% 5.0% 5.0% Ethylhexyl Triazone (Uvinul T 150, BASF SE) 1.0% 1.0% 2.0% 2.0% Titanium Dioxide; silica; Dimethicone 2.0% 2.0% 2.0% 2.0% (Parsol TX (DSM Nutritional Products Llc.) Water to to to to 100% 100% 100% 100% Glycerin 3.0% 3.0% 3.0% 3.0% Magnesium sulfate heptahydrate 1.5% 1.5% 1.5% 1.5% Benzyl Alcohol; Ethylhexylglycerin; Tocopherol 0.7% 0.7% 0.7% (Euxyl K 900, Schülke & Mayr GmbH) Phenethylalcohol nat. 0.7%

[0217] Recipes 39a, 39b and 39c: Sunscreen Lotion SPF 50 in Accordance with FDA Criteria

TABLE-US-00044 Recipe 39a 39b 39c Composition from example 5  2.0%  1.5%  1.5% Lauryl PEG-10 Tris(Trimethylsiloxy)Silylethyl —  0.5%  0.5% Dimethicone (ES-5300 Formulation Aid, Dow Coming Corp.) Ethylhexyl Methoxycinnamate;  7.5%  7.5%  7.5% Diethylamino Hydroxybenzoyl Hexyl Benzoate (Uvinul A + B, BASF SE) Ethylhexyl Salicylate  5.0%  5.0%  5.0% Homosalate 15.0% 15.0% 15.0% Butyl Methoxydibenzoylmethane  3.0%  3.0%  3.0% Benzophenone-3  6.0%  6.0%  6.0% Octocrylene 10.0% 10.0% 10.0% Triisostearin  2.0%  2.0%  2.0% Microcrystalline Wax  1.2%  1.2%  1.2% Castor wax  0.8%  0.8%  0.8% Cetyl Dimethicone (ABIL ® Wax 9801, Evonik  2.0%  2.0%  2.0% Operations GmbH) Diethylhexyl Carbonate (TEGOSOFT ® DEC,  2.0%  2.0%  2.0% Evonik Operations GmbH) Water to to to  100%  100%  100% Sodium Chloride  1.0%  1.0%  1.0% Ethylenediaminetetraacetic acid  0.1%  0.1%  0.1% Propylene glycol  3.0%  3.0%  3.0% Phenoxyethanol; Ethylhexylglycerin (Euxyl PE  0.7%  0.7% 9010, Schülke & Mayr GmbH) Verstatil PC  1.0%

[0218] Recipe 40a, 40b, 40c, 40d, 40e, and 40f: Foundation

TABLE-US-00045 Recipe 40a 40b 40c 40d 40e 40f Composition from example 5 4.5% 2.5% 3.0% 2.5% 2.0% 2.0% Bis-(Glyceryl/Lauryl) Glyceryl Lauryl — 2.0% — — — — Dimethicone; Caprylic/Capric Triglyceride (ABIL ® EM 120, Evonik Operations GmbH) Polyglyceryl-4 Isostearate (ISOLAN ®) GI — — 1.0% — — — 34, Evonik Operations GmbH) Cetyl Diglyceryl — — — 1.0% — — Tris(Trimethylsiloxy)Silylethyl Dimethicone (DC-5600, Dow Corning Corp.) Lauryl Polyglycery-3 — — — — 1.0% — Polydimethyisiloxyethyl Dimethicone (KF- 6105, Shin-Etsu Chemical Co.) Polyglyceryl-4 isostearate; Cetyl — — — — — 2.0% PEG/PPG-10/1 Dimethicone; Hexyl Laurate (ABIL ® WE 09, Evonik Operations GmbH) Isoamyl Cocoate (TEGOSOFT ® AC, 10.8%  10.8%  10.8%  10.8%  10.8%  10.8%  Evonik Operations GmbH) Oleyl Erucate (TEGOSOFT ® OER, Evonik 8.0% 8.0% 8.0% 8.0% 8.0% 8.0% Operations GmbH) Titanium Dioxide, Alumina, 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% Triethoxycaprylyisilane (Hombitan AC360, Sachtleben) Iron Oxides (Sicovit Brown 70 E 172, 2.1% 2.1% 2.1% 2.1% 2.1% 2.1% Rockwood) Nylon-12 (TEGOLON ® 12-20, Evonik 2.0% 2.0% 2.0% 2.0% 2.0% 2.0% Operations GmbH) Cyclopentasiloxane 3.5% 3.5% 3.5% 3.5% 3.5% 3.5% Disteardimonium Hectorite (Bentone 38 V 1.0% 1.0% 1.0% 1.0% 1.0% 1.0% CG, Elementis) Propylene carbonate 0.5% 0.5% 0.5% 0.5% 0.5% 0.5% Water to to to to to to 100%  100%  100%  100%  100%  100%  Magnesium sulfate heptahydrate 1.5% 1.5% 1.5% 1.5% 1.5% 1.5% Glycerin 5.0% 5.0% 5.0% 5.0% 5.0% 5.0% Creatine (TEGO ® Cosmo C 100, Evonik 0.5% 0.5% 0.5% 0.5% 0.5% 0.5% Operations GmbH) Ceteareth-25; Glycerin; Cetyl Alcohol; Behenic Acid; Cholesterol; Ceramide EOP; Ceramide EOS; Ceramide NP; Ceramide NS; Ceramide AP; Caprooyl Phytosphingosine; Caprooyl Sphingosine (SKINMIMICS, Evonik Operations GmbH) Benzyl Alcohol; Ethylhexylglycerin; 0.7% 0.7% 0.7% 0.7% 0.7% 0.7% Tocopherol (Euxyl K 900, Schülke & Mayr GmbH)

[0219] Recipe 41a, 41b, 41c, 41d, 41e, 41f, and 41g: CC (Colour Control) Fluid

TABLE-US-00046 Recipe 41a 41b 41c 41d 41e 41f 41g Composition from example 5 3.0% 2.0% 2.5% 3.0% 2.5% 2.0% 1.0% Polyglyceryl-4 — 1.0% — — — — — Diisostearate/Polyhydroxystearate/ Sebacate (ISOLAN ® GPS, Evonik Operations GmbH) Sorbitan Oleate (TEGO ® SMO V, — — 0.5% — — — — Evonik Operations GmbH) PEG-30 Dipolyhydroxystearate (Arlacel — — — 1.0% — — — P135, Croda) Polyglyceryl-3 Diisostearate (Lameform — — — — 1.5% — — TGI, BASF SE) Glyceryl Oleate, Polyglyceryl-3 — — — — — 1.0% — Polyricinoleate, Olea Europaea (olive) Oil Unsaponifiables (Plantasens Natural Emulsifier CP5, Clariant) Lauryl PEG-9 Polydimethylsiloxyethyl — — — — — — 1.0% Dimethicone (KF-6038, Shin-Etsu Chemical Co.) Ethylhexyl Methoxycinnamate; 10.0%  10.0%  10.0%  10.0%  10.0%  10.0%  10.0%  Diethylamino Hydroxybenzoyl Hexyl Benzoate (Uvinul A + B, BASF SE) Cyclopentasiloxane 3.5% 3.5% 3.5% 3.5% 3.5% 3.5% 3.5% Disteardimonium Hectorite (Bentone 38 1.0% 1.0% 1.0% 1.0% 1.0% 1.0% 1.0% V CG, Elementis) Propylene carbonate 0.5% 0.5% 0.5% 0.5% 0.5% 0.5% 0.5% Titanium Dioxide, Alumina, 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% Triethoxycaprylylsilane (Hombitan AC360, Sachtleben) Talc 2.0% 2.0% 2.0% 2.0% | 2.0% 2.0% 2.0% Iron Oxides; Triethoxycaprylylsilane 0.4% 0.4% 0.4% 0.4% 0.4% 0.4% 0.4% (Unipure Yellow LC 182 AS-EM, Sensient) Iron Oxides; Triethoxycaprylylsilane 0.12%  0.12%  0.12%  0.12%  0.12%  0.12%  0.12%  (Unipure Red LC 381 AS-EM, Sensient) Iron Oxides; Triethoxycaprylylsilane 0.08%  0.08%  0.08%  0.08%  0.08%  0.08%  0.08%  (Unipure Black LC 989 AS-EM, Sensient) Diethylhexyl Carbonate (TEGOSOFT ® 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% DEC, Evonik Operations GmbH) C12-15 Alkyl Benzoate 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% Isopropyl Palmitate (TEGOSOFT ® P, 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% Evonik Operations GmbH) Nylon-12 (TEGOLON ® 12-20, Evonik 2.0% 2.0% 2.0% 2.0% 2.0% 2.0% 2.0% Operations GmbH) Water to to to to to to to 100%  100%  100%  100%  100%  100%  100%  Glycerin 5.0% 5.0% 5.0% 5.0% 5.0% 5.0% 5.0% Sodium Chloride 1.5% 1.5% 1.5% 1.5% | 1.5% 1.5% 1.5% Tetrapeptide-30; Glycerin (TEGO ® Pep 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 4-Even, Evonik Operations GmbH) Phenoxyethanol; Methylparaben; 0.7% 0.7% 0.7% 0.7% 0.7% 0.7% 0.7% Ethylparaben; Propylparaben (Phenonip XB, Clariant)

[0220] Recipe 42a 42b 42c 42d and 42e: Antiperspirant/Deodorant Spray or Aerosol Spray

TABLE-US-00047 Recipe 42a 42b 42c 42d 42e Composition from example 5  3.0%  2.0%  3.0%  2.0%  2.0% Polyglyceryl-4 —  1.0% —  1.0%  1.0% Diisostearate/Polyhydroxystearate/ Sebacate (ISOLAN ® GPS, Evonik Operations GmbH) Isopropyl Palmitate (TEGOSOFT ® P, 20.0% 20.0% 20.0% 20.0% 20.0% Evonik Operations GmbH) Diethylhexyl Carbonate (TEGOSOFT ®  7.0%  7.0%  7.0%  7.0%  7.0% DEC, Evonik Operations GmbH) Triethyl Citrate (dermofeel ® TEC eco;  5.0% Evonik Dr. Straetmans GmbH) Water to to to 100% to 100% to  100%  100%  100% Glycerin  2.0%  2.0%  2.0%  2.0%  2.0% Aluminum Chlorohydrate (50% aq.; 30.0% 30.0% 30.0% 30.0% 30.0% Locron LIC, Clariant AG) Parfum  1.0%  1.0%  1.0%  1.0%  1.0% Propellant — — Mix emulsions 42c and 42d with propellant in mass ratio of 5:2 Phenoxyethanol; Caprylyl Glycol  0.8% (Vestatil ® PC; Evonik Dr. Straetmans GmbH)

[0221] Recipe 43a, 43b, 43c, and 43d: Sunscreen aerosol SPF 50 UVA

TABLE-US-00048 Recipe 43a 43b 43c 43d Composition from example 5  4.0%  4.0%  4.0%  4.0% Cetyl PEG/PPG-10/1 Dimethicone (ABIL ® — —  1.0%  1.0% EM 90, Evonik Operations GmbH) C12-15 Alkyl Benzoate 10.0%  8.0% 10.0%  8.0% Diethylhexyl Carbonate (TEGOSOFT ® DEC, 13.0% 10.0% 13.0% 10.0% Evonik Operations GmbH) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine  4.0%  4.0%  4.0%  4.0% (Tinosorb S, BASF SE) Diethylamino Hydroxybenzoyl Hexyl Benzoate  5.0%  5.0%  5.0%  5.0% (Uvinul A Plus, BASF SE) Ethylhexyl Salicylate  5.0%  5.0%  5.0%  5.0% Ethylhexyl Methoxycinnamate  4.0%  4.0%  4.0%  4.0% Water to 100% to 100% to 100% to 100% Glycerin  3.0%  3.0%  3.0%  3.0% UV filter solution (20% Phenylbenzimidazole 20.0% 20.0% 20.0% 20.0% Sulfonic Acid (Eusolex 232, Merck KGaA, 8.8% tris(hydroxymethyl)aminomethane, water to 100%) Magnesium sulfate heptahydrate  1.0%  1.0%  1.0%  1.0% Benzyl Alcohol; Ethylhexylglycerin; Tocopherol  0.7%  0.7%  0.7%  0.7% (Euxyl K 900, Schülke & Mayr GmbH) Mix emulsions 43a, 43b, 43c and 43d with propellant in mass ratio of 2:11

[0222] Formulation 44: Shower Cream

TABLE-US-00049 Water to 100.0% Composition from example 1, 2 or 3  1.5% Sodium Laureth Sulfate (Texapon NSO, BASF, 28%) 25.0% Coco-Glucoside (Plantacare 818 UP, BASF, 51%)  8.0% Cocamidopropyl Betaine (TEGO ® Betain F 50, Evonik, 38%)  8.0% PEG-18 Glyceryl Oleate/Cocoate (ANTIL ® 171, Evonik)  1.5% Sorbitan Sesquicaprylate (ANTIL ® Soft SC, Evonik)  0.8% Glyceryl Oleate (TEGIN ® O V, Evonik)  0.8% Perfume Spicy Herbs (IFF)  0.2% Polyglyceryl-4 Caprate (TEGOSOFT ® PC 41, Evonik)  0.6% Hellanthus Annuus Seed Oil (AEC Sunflower Oil, A & E  0.2% Connock, Perfumery & Cosmetics Ltd.) Linalool (Lipofresh, Lipo Chemicals, Inc.)  0.1% Coumarin (Rhodiascent extra pure, Solvay Rhodia)  0.1% Glycerin (Glycerol EP, vegetable, Spiga Nord)  0.4% Hydroxypropyl Methylcellulose (TEGOCEL ® HPM 50, Evonik)  0.2% Glycol Distearate (TEGIN ® G 1100 Pellets, Evonik)  0.4% Sodium Chloride  0.5% Hydroxypropyl Guar Hydroxypropyltrimonium Chloride  0.2% (Jaguar C-162, Solvay Rhodia) dermofeel TOCO 70 non GMO  0.1% Disodium EDTA (Dissolvine NA-2-P, AkzoNobel)  0.1% Preservative q.s. Citric Acid to pH 5.2

[0223] Formulation 45: Bogy Shampoo

TABLE-US-00050 phase A Composition from example 1, 2 or 3  5.0% Lavandula Angustifolia (lavender) Oil  0.2% (AEC Lavender Oil, A & E Connock Ltd.) Perfume  0.1% Phase B Sodium Cocoamphoacetate (REWOTERIC ® 10.0% AM C, Evonik, 32%) Phase C Water to 100.0% Xanthan Gum (Keitrol CG-SFT, CP Kelco)  1.2% Phase D Sodium Lauroyl Methyl Isethionate (Iselux,  4.5% Innospec Active Chemicals) Capryl/Capramidopropyl Betaine (TEGO ®  4.5% Betaine 810, Evonik, 38%) Citric Acid  1.2% Phase E Water 10.0% Polyquaternium-7 (Merquat 550, Nalco)  0.4% Preservative q.s.

[0224] Formulation 46: Shampoo

TABLE-US-00051 Phase A Composition from example 1, 2 or 3  3.5% Isopropyl Myristate (TEGOSOFT ® M,  0.2% Evonik) Perfume  0.1% Phase B Water to 100.0% Phase C Sodium Lauryl Sulfate (Texapon LS 35, 28.0% BASF, 30%) Phase D Cocamidopropyl Betaine (TEGO ®  9.0% Betain F 50, Evonik, 38%) Phase E Cocamide MEA (REWOMID ® C 212,  2.0% Evonik) Xanthan Gum (Keltrol CG-SFT, CP Kelco)  0.3% Water 10.0% Phase F Water 10.0% Polyquaternium-10 (Polymer JR 400,  0.2% Amerchol) Phase G Citric Acid to pH 5.0 Phase H Preservative q.s.

[0225] Recipes 47a and 47b: Shampoo

TABLE-US-00052 Recipes 47a 47b Water to 100.0% to 100.0% Composition from example 1, 2 or 3  2.5%  2.5% Composition from example 4  1.5%  1.5% Cocamidopropyl Betaine (TEGO ® Betain F 50, Evonik, 38%) 22.0% 22.0% Lauryl Glucoside (Plantacare 1200 UP, BASF, 50%)  6.0%  6.0% Sodium Cocoyl Glutamate (Plantapon ACG HC, BASF)  1.5%  1.5% Sodium Cocoyl Glycinate (Hostapon SG, Clariant)  0.8%  0.8% Zinc Pyrithione (Microcare ZP, Thor)  0.1%  0.1% PEG-120 Methyl Glucose Dioleate (ANTIL ® 120 Plus, Evonik)  0.4%  0.4% Sodium Chloride  0.5%  0.5% Isostearamide MIPA; Glyceryl Laurate (ANTIL ® SPA 80, Evonik)  0.5%  0.5% Xanthan Gum (Keltrol CG-SFT, CP Kelco)  0.3%  0.3% Hydroxypropyl Guar Hydroxypropyltrimonium Chloride (Jaguar  0.3%  0.3% C-162, Solvay Rhodia) Quaternium-80 (ABIL ® Quat 3272, Evonik)  0.4%  0.4% Palmitamidopropyltrimonium Chloride (VARISOFT ® PATC,  0.4%  0.4% Evonik) Argania spinosa oil (Argan Oil, DSM Nutritional Products Ltd.)  0.1%  0.1% Glycerin (Glycerol EP, vegetable, Spiga Nord)  0.6%  0.6% Tetrasodium EDTA (Versene 100, The Dow Chemical  0.1%  0.1% Company) Caffeine (Merck KGaA/EMD Chemicals, Inc.)  0.1%  0.1% Hydrolyzed Wheat Protein (Gluadin WLM, BASF)  0.1%  0.1% Limonene (Dipentene No. 122, Hercules Inc.)  0.1%  0.1% Citric Acid to pH 5.5 to pH 5.5 Sodium Phytate; Aqua; Alcohol (dermofeel ® PA-3; Evonik Dr.  0.1% Straetmans GmbH (PA-3) Perfume  0.2% Preservative q.s. Aqua; Sodium Levulinate; Sodium Benzoate (Verstatil ® BL non-  1.2% GMO; Evonik Dr. Straetmans GmbH)

[0226] Formulation 48: Liquid Soap

TABLE-US-00053 Water to 100% Glycerin (Glycerol EP, vegetable, Spiga Nord) 4.0% Alcohol 4.0% Sodium Coco-Sulfate (Texapon HC G, BASF) 3.0% Lauryl Glucoside (Plantacare 1200 UP, BASF, 50%) 6.0% Composition from example 1, 2 or 3 3.0% Xanthan Gum (Keltrol CG-SFT, CP Kelco) 1.5% Mangifera Indica (mango) Fruit Extract (Mango 0.5% Extract, Draco Natural Products) Limonene (Dipentene No. 122, Hercules Inc.) 0.1% Linalool (Lipofresh, Lipo Chemicals, Inc.) 0.1% Citric Acid to pH 4.9 Preservative q.s. Dyes q.s.

[0227] Formulation 49: Cream Soap

TABLE-US-00054 Water to 100% Propylene Glycol (Euxyl K 320, Schülke & Mayr GmbH)  2.0% Coco-Glucoside (Plantacare 818 UP, BASF, 51%) 10.0% Glycerin (Glycerol EP, vegetable, Spiga Nord)  5.0% Composition from example 1, 2 or 3  2.5% Disodium Cocoyl Glutamate (Planatpon ACG LC, BASF)  2.5% Xanthan Gum (Keltrol CG-SFT, CP Kelco)  1.2% Stearic Acid (Pristerene 4922, Croda Europe, Ltd.)  1.2% Citric Acid to pH 5.5 Olea Europaea Fruit Oil (Cropure Olive, Croda Europe, Ltd.)  0.2% Glyceryl Oleate (TEGIN ® O V, Evonik)  1.0% Sodium Cocoyl Glutamate (Plantapon ACG HC, BASF)  0.8% Tetrasodium EDTA (Versene 100, The Dow Chemical  0.2% Company) Perfume  0.1% Preservative q.s. Dyes q.s.

[0228] Formulation 50: Oil Bath

TABLE-US-00055 Water to 100.0% Glycine Soja Oil (Cropure Soybean, Croda Europe, Ltd.) 20.0% Composition from example 1, 2 or 3 12.0% Polyglyceryl-3 Palmitate (Dermofeel ® PP, Evonik Dr.  4.5% Straetmans) Glyceryl Caprylate (Dermosoft ® GMCY, Evonik Dr.  3.0% Straetmans) Simmondsia Chinensis Seed Oil (AEC Jojoba Oil Refined,  1.2% A & E Connock, Perfumery & Cosmetics Ltd.) Prunus Amygdalus Dulcis (sweet almond) Oil (Cropure  1.0% Almond, Croda Europe, Ltd.) Triticum Vulgare Germ Oil (Cropure Wheatgerm, Croda  0.5% Europe, Ltd.) Tocopherol (Euxyl K 700, Schülke & Mayr GmbH)  0.2% Limonene (Dipentene No. 122, Hercules Inc.)  0.1% Citral  0.1% Preservative q.s. Dyes q.s.

[0229] Formulation 51: Micellar Water for Makeup Removal

TABLE-US-00056 Water to 100.0% Perfume 0.1% Composition from example 1, 2 or 3 2.0% Capryl/Capramidopropyl Betaine (TEGO ® Betain 1.3% 810, Evonik, 38%) Polyglyceryl-6 Caprylate; Polyglyceryl-3 Cocoate; 1.0% Polyglyceryl-4 Caprate; Polyglyceryl-6 Ricinoleate (TEGO ® Solve 61, Evonik) Betaine (TEGO ® Natural Betaine, Evonik) 2.0% Glycerin (Glycerol EP, vegetable, Spiga Nord) 1.0% Preservative q.s.

[0230] Recipes 52a and 52b: Solution for Wet Wipes

TABLE-US-00057 Recipe 52a 52b Composition from example 1, 2 or 3 3.5% 3.5% Aloe Barbadensis Leaf Extract (Aloe-Con UP 40, Florida Food 0.2% 0.2% Products Inc.) Isopropyl Myristate (TEGOSOFT ® M, Evonik) 0.2% 0.2% Disodium Cocoamphodiacetate (REWOTERIC ® AM 2 C NM, 1.5% 1.5% Evonik, 39%) Perfume 0.2% 0.2% Propylene Glycol (Euxyl K 320, Schülke & Mayr GmbH) 2.5% 2.5% Hydrolyzed Silk (Crosilk 10000, Croda Inc.) 0.2% 0.2% Caprylyl/Capryl Glucoside (Plantacare 810 UP, BASF) 1.0% 1.0% Water to 100.0% to 100.0% Citric Acid to pH 5.0 to pH 5.0 Phenoxyethanol (S&M Phenoxyethanol, Schülke & Mayr GmbH) 0.5% 0.5% Dehydroacetic Acid (Unisept DHA (Universal Preserv-A-Chem, 0.1% 0.1% Inc.) Sodium Benzoate (Euxyl K 712, Schülke & Mayr GmbH) 0.4% 0.4% Salicylic Acid (salicylic acid nat.; Evonik Dr. Straetmans GmbH) 0.5%

[0231] Formulation 53: Antiperspirant Deodorant

TABLE-US-00058 Phase A Composition from example 1, 2 or 3  4.0% Dicaprylyl Ether (Cetiol OE, BASF)  0.3% Geraniol (Nerol 800, International Flavors &  0.1% Fragrances Inc.) Linalool (Lipofresh, Lipo Chemicals, Inc.)  0.1% Perfume  0.1% Phase B Propylene Glycol (Euxyl K 320, Schülke &  1.0% Mayr GmbH) Butylene Glycol (Oxea Corparation)  0.2% Water  5.0% Palmitamidopropyltrimonium Chloride  1.0% (VARISOFT ® PATC, Evonik) Phase C Water 50.0% Hydroxethyl ethylcellulose (Structure  0.8% Cel 4400 E, AkzoNobel) Sodium Hydroxide (10% in water)  0.3% Phase D Aluminium Chlorohydrate (Locron L, 15.0% Clariant) Phase E Preservative q.s. Water to 100.0%

[0232] Formulation 54: Mouthwash

TABLE-US-00059 Composition from example 1, 2 or 3 0.4% Glycolipids (Rheance One, Evonik) 0.2% Flavour 0.2% Water to 100.0% Sorbitol (Karion FP Liquid, Merck) 3.0% Preservative q.s. Dyes q.s.

[0233] Formulation 55: Toothpaste

TABLE-US-00060 A Sorbitol (Karion FP Liquid, Merck) 50.0% Water to 100.0% Sodium carboxymethyl cellulose (Blanose 7MXF,  1.2% Ashland) B Sodium Saccharin (Sigma Aldrich)  0.1% Sodium Fluoride (Sigma Aldrich)  0.1% C Titanium Dioxide (Caesar & Loretz)  0.4% Hydrated Silica (Zeodent ® 113, Evonik) 14.0% Hydrated Silica (Zeodent ® 165, Evonik)  8.0% D Flavour oil  1.0% E Glyceryl Caprylate (dermosoft ® GMCY, Evonik)  0.3% Composition from example 1, 2 or 3  3.5%