Process for the preparation of ceramic glass material in the form of sheets, sheets thus obtained and use thereof

Abstract

A process allowing to obtain ceramic glass material in the form of sheets of large dimensions usable in constructions for panelling or for flooring is described.

Claims

1. A process suitable for manufacturing ceramic glass material in the form of sheets, the process comprising: melting an oxide mixture used for manufacturing ceramic glass material to form a vitreous mass; refining the vitreous mass thus obtained to form a molten glass material; passing the molten glass material through a roller system to form a continuous sheet, wherein the sheet has a dimension of about 23 meters; annealing the continuous sheet; and subjecting the continuous sheet to a thermal crystallization cycle after said annealing, wherein said oxide mixture comprises: SiO.sub.2: 50%-80%; Al.sub.2O.sub.3: 5%-30%; and Li.sub.2O: about 7% to about 11%, wherein the ceramic glass material consists essentially of one or more of lithium phyllodisilicate and -spodumene phase, and wherein the thermal crystallization cycle comprises a last stage of the process before final cooling and is conducted at a temperature from 550 C. to 920 C. for 2 to 6 hours, having a total cycle lasting for 12-25 hours.

2. A process according to claim 1, wherein the oxide mixture further comprises other oxides chosen from the group consisting of ZnO, P.sub.2O.sub.5, K.sub.2O, Na.sub.2O, CaO, MgO, BaO, and ZrO.sub.2.

3. A process according to claim 2, wherein said other oxides, if present in the mixture, represent a percentage by weight comprised between respectively: ZnO: 0.1-3%; P.sub.2O.sub.5: 0.1-5%; K.sub.2O: 1-5%; Na.sub.2O: 0.1-6%; CaO: 0.1-6%; MgO: 0.1-6%; BaO: 0.1-5%; and ZrO.sub.2: 0.1-4%.

4. A process according to claim 1, wherein the thermal crystallization cycle is conducted beginning from 550 C. and varying the temperature in 20 increases.

5. The process of claim 1 wherein the oxide mixture comprises one of the following compositions represented as a percentage by weight: TABLE-US-00008 a) SiO.sub.2 78.57 Al.sub.2O.sub.3 5.35 ZnO 0.52 Li.sub.2O 11.23 P.sub.2O.sub.5 1.95 K.sub.2O 2.34; b) SiO.sub.2 74.47 Al.sub.2O.sub.3 9.35 ZnO 0.52 Li.sub.2O 11.23 P.sub.2O.sub.5 1.95 K.sub.2O 2.34; c) SiO.sub.2 75.50 Al.sub.2O.sub.3 8.35 ZnO 0.50 Li.sub.2O 9.75 P.sub.2O.sub.5 1.95 K.sub.2O 2.35 Na.sub.2O 1.00 CaO 0.50; d) SiO.sub.2 77.51 Al.sub.2O.sub.3 5.35 ZnO 1.52 Li.sub.2O 10.23 P.sub.2O.sub.5 2.95 K.sub.2O 2.34; e) SiO.sub.2 78.46 Al.sub.2O.sub.3 5.35 ZnO 4.52 Li.sub.2O 7.23 P.sub.2O.sub.5 1.95 MgO 1.00; f) SiO.sub.2 78.59 Al.sub.2O.sub.3 5.36 ZnO 0.52 Li.sub.2O 11.24 P.sub.2O.sub.5 1.95 MgO 3.00 K.sub.2O 2.34; or g) SiO.sub.2 75.13 Al.sub.2O.sub.3 8.31 ZnO 0.52 Li.sub.2O 9.68 P.sub.2O.sub.5 1.94 K.sub.2O 2.33 BaO 0.93 ZrO.sub.2 0.93.

6. The process according to claim 1, wherein the oxide mixture comprises a melting point of 1500 C. to 1550 C.

7. The process according to claim 1, wherein said annealing is carried out in a controlled temperature oven to relieve mechanical stresses caused to the glass during said passing the molten glass material through a roller system.

8. The process according to claim 7, wherein said annealing is carried out for approximately 1 hour.

Description

DETAILED DESCRIPTION OF THE INVENTION

(1) The present invention consists in overcoming the aforesaid problems in virtue of a process which comprises the melting of an appropriate mixture of oxides, the processing of the molten mass according to the normal glass manufacturing processes (rolling, shaping, blowing, etc.) and the subsequent treatment of the material thus obtained in appropriate crystallisation cycles.

(2) According to the invention, the mixture of initial oxides essentially consists of SiO.sub.2, Al.sub.2O.sub.3 and Li.sub.2O possibly in presence of other oxides.

(3) Preferably, according to the invention, the percentages of the three aforesaid components (expressed by weight with respect to the total weight of the final mixture) are:

(4) SiO.sub.2: 50% -80%; Al.sub.2O.sub.3: 5% -30%; Li.sub.2O 3% -20%

(5) The other oxides possibly present are chosen from the group consisting of ZnO, P.sub.2O.sub.5, K.sub.2O, Na.sub.2O, CaO, MgO, BaO.

(6) More preferably, the aforesaid oxides, if present in the mixture, represents a percentage by weight comprised between respectively:

(7) ZnO: 0.1 -3%; P.sub.2O.sub.5: 0.1-5%; K.sub.2O: 1-5%, Na.sub.2O: 0.1-6%, CaO: 0.1-6%; MgO: 0.1-6%, BaO: 0.1-5%; ZrO.sub.2: 0.1-4%.

(8) The oxide mixtures as described above present a melting point from 1500 to 1550 C. and may therefore be melted in the normal gas ovens used for melting glass and the molten materials are free from batch stones and bubbles and with a viscosity so as to allow the further forming process thereof.

(9) The forming process and the subsequent annealing is performed in the normal processing conditions used for glass forming.

(10) For example, the molten material is rolled by making it pass through a roller system which at the same time squeezes the laminate to the required thickness and feeds it forward. Subsequently, the continuous sheet thus formed enters in a controlled temperature oven called annealing oven which allows to relieve possible mechanical stresses caused to the glass during the roller forming step. At the exit of the annealing oven, the edges of the sheet are cut, possibly straightened and cut according to appropriate sizes, the process allows, for example, the continuous manufacturing of sheets of large dimensions.

(11) Preferably, the mass is processed at viscosity of about Log =4.

(12) Normally, the molten mass during the pressing process is subjected to a rapid cooling, to a temperature corresponding to log=13, at which the accumulated stresses are dissipated in a time of approximately 1 hour.

(13) In addition to the composition of the mixture, the thermal crystallisation cycle is also important for the process according to the invention.

(14) Said thermal cycle must be performed at a temperature from 550 C. to 920 C. and for times from 2 to 6 hours, the overall cycle lasting for 12-25 hours.

(15) By varying the times and the temperature within the aforesaid intervals it is also possible to vary the appearance features of each material.

(16) For example, starting from a temperature of 550 C. and varying it in 20 C. step increases, it is possible to obtain a range which spans from the blue effect due to the Tyndall phenomenon, to semi-transparent up to a perfectly opaque white.

(17) Some examples of preparation of ceramic glass materials according to the invention are shown below.

EXAMPLE 1

(18) A mixture of oxides having the following composition:

(19) TABLE-US-00001 Oxides wt % SiO.sub.2 78.61 Al.sub.2O.sub.3 5.35 ZnO 0.52 Li.sub.2O 11.23 P.sub.2O.sub.5 1.95 K.sub.2O 2.34
was melted in a gas furnace (oxygen-methane) at the temperature of 1450 C. After approximately 36 hours, the molten material appears perfectly refined, and is thus taken to processing temperature (log =4) and shaped according to the known technique for glass processing, in the desired shape and dimensions. In this case, the molten mass during the pressing process is subjected to a rapid cooling, to a temperature corresponding to log =13, and maintained constant so that the accumulated stresses are dissipated in a time of approximately 1 hour.

(20) The crystallisation cycle was performed by maintaining the sheet at 820 C. for 1 hour and then constantly decreasing the temperature to reach the ambient temperature in 12 hours.

(21) Diffraction analysis shows how after crystallisation at 820 C. for 130 minutes the following phases are present: beta-quartz [11-0252] and lithium silicate Li.sub.2Si.sub.2O.sub.5 [40-0376] (JCPDS (Joint Committee on Powder Diffraction Standards) numbering).

(22) Mechanical features:

(23) Microhardness: 740 Hv (charge=100 g)

(24) Other features:

(25) TABLE-US-00002 Determination Test type method Minimum values Water absorption EN 99 <0.5% Bending strength EN 100 >27 N/mm.sup.2 Tensile strength >200-250 Kg Abrasion resistance EN 102-EN 154 <205 mm.sup.3 Hardness EN 101-EN 176 >6 Thermal shock resistance EN 104-EN 176 Must pass test Frost resistance EN 102 Must pass test Resistance to chemicals EN 106-EN 122 Must pass test

EXAMPLE 2

(26) A mixture of oxides having the following composition:

(27) TABLE-US-00003 Oxides wt % SiO.sub.2 74.61 Al.sub.2O.sub.3 9.35 ZnO 0.52 Li.sub.2O 11.23 P.sub.2O.sub.5 1.95 K.sub.2O 2.34
was melted in a gas furnace (oxygen-methane) at a temperature of 1450 C. After approximately 36 hours, the molten material appears perfectly refined, and is thus taken to processing temperature (log =4) and shaped according to the technique, desired shape and dimensions. In this case, the molten mass during the pressing process is subjected to a rapid cooling, to a temperature corresponding to approximately log =13, and maintained constant so that the accumulated stresses are dissipated in a time of approximately 1 hour.

(28) The crystallisation cycle was performed by maintaining the sheet at 900 C. for 1 hour and then constantly lowering the temperature to reach the ambient temperature in 12 hours.

(29) Diffraction analysis shows how after crystallisation at 900 C. for 60 minutes the following phases are present: lithium aluminium silicate [35-0794] and lithium silicate Li.sub.2Si.sub.2O.sub.5 [40-0376].

(30) Mechanical features:

(31) Microhardness 832 Hv (charge=100 g)

(32) Other features:

(33) TABLE-US-00004 Determination Test type method Minimum values Water absorption EN 99 <0.5% Bending strength EN 100 >27 N/mm.sup.2 Tensile strength >200-250 Kg Thermal shock resistance EN 104-EN 176 Must pass test Resistance to etching EN 106-EN 122 Must pass test

EXAMPLE 3

(34) A mixture of oxides having the following composition:

(35) TABLE-US-00005 Oxides wt % SiO.sub.2 75.60 Al.sub.2O.sub.3 8.35 ZnO 0.50 Li.sub.2O 9.75 P.sub.2O.sub.5 1.95 K.sub.2O 2.35 Na.sub.2O 1.00 CaO 0.50
was melted in a gas furnace (oxygen-methane) at a temperature of 1450 C. After approximately 36 hours, the molten material appears perfectly refined, and is thus taken to processing temperature (log =4) and shaped according to the technique, desired shape and dimensions.

(36) In this case, the molten mass during the pressing process is subjected to a rapid cooling, to a temperature corresponding to log =13 and maintained constant so that the accumulated stresses are dissipated in a time of approximately 1 hour.

(37) The crystallisation cycle was performed by raising the temperature to 820 C. in approximately 4 hours, maintaining it constant for 4 hours, and then lowering it again to reach the ambient temperature in 12 hours.

(38) Diffraction analysis shows how after crystallisation at 820 C. for 4 hours lithium aluminium silicate [21-0503] and lithium silicate Li.sub.2Si.sub.2O.sub.5 [40-0376].

(39) Mechanical features:

(40) Microhardness: 830 Hv (charge=100 g)

(41) Other features:

(42) TABLE-US-00006 Determination Test type method Minimum values Water absorption EN 99 <0.5% Bending strength EN 100 >27 N/mm.sup.2 Tensile strength >200-250 Kg Abrasion resistance EN 102-EN 154 <205 mm.sup.3 Hardness EN 101-EN 176 >6 Thermal shock resistance EN 104-EN 176 Must pass test Frost resistance EN 102 Must pass test Resistance to etching EN 106-EN 122 Must pass test
Similarly to that described in the preceding examples, similar results have been obtained using the following oxide mixtures:

(43) TABLE-US-00007 Formu- Formu- Formu- Formu- lation A lation B lation C lation D SiO2 77.61 78.46 75.59 75.13 Li2O 10.23 7.23 11.24 9.68 Al2O3 5.35 5.49 5.36 8.31 K2O 2.34 2.34 2.34 2.33 P2O5 2.95 1.95 1.95 1.94 ZnO 1.52 4.52 0.52 0.52 MgO 1.00 3.00 BaO 0.93 ZrO2 1.14
By proceeding as shown in the examples, sheets of considerable size have been obtained, for example up to 2.003.00 meters, which in virtue of the exceptional properties shown above may be used in constructions for flooring and panelling.