INTEGRATION PROCESS PRINCIPLES FOR MAXIMIZING THE BOIL OFF RECOVERY ON A H2 LIQUEFIER PLANT
20230096282 · 2023-03-30
Inventors
- Florence DIAS (Noisy le Grand, FR)
- Oriane Farges (Houston, TX, US)
- Ludovic GRANADOS (Puteaux, FR)
- Baptiste PAGES (Vincennes, FR)
Cpc classification
F25J1/0072
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/0271
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/001
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/0045
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2245/90
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/0245
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/0208
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2290/62
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/0025
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/027
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2290/60
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2230/24
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2230/30
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
A method for recovering boil-off gas from a system including one or more liquefaction trains including transport trucks or loading bays, a gaseous hydrogen feed stream, a lower-temperature cold box, and a low-pressure hydrogen compressor. The method including collecting a boil-off gas stream from the transport trucks or loading bays, determining the pressure of the boil-off gas stream, and depending on the pressure, recycling the boo-off gas stream to predetermined destinations. Wherein the boil-off gas stream has either a low-pressure, having a pressure of less than 2 bara, or a medium-pressure, having a pressure equal to or greater than 2 bara.
Claims
1. A method for recovering boil-off gas from a system comprising one or more liquefaction trains, the one or more liquefaction trains comprising: transport trucks or loading bays, a gaseous hydrogen feed stream, a lower-temperature cold box, and a low-pressure hydrogen compressor; the method comprising: collecting a boil-off gas stream from the transport trucks or loading bays, determining the pressure of the boil-off gas stream, and depending on the pressure, recycling the boil-off gas stream to predetermined destinations, wherein the boil-off gas stream has either a low-pressure, having a pressure of less than 2 bara, or a medium-pressure, having a pressure equal to or greater than 2 bara.
2. The method of claim 1, wherein at least a portion of the low-pressure boil-off gas stream is recycled to the lower-temperature cold box.
3. The method of claim 1, wherein at least a portion of the low-pressure boil-off gas stream is recycled to the low-pressure hydrogen compressor.
4. The method of claim 1, wherein at least a portion of the medium-pressure boil-off gas stream is recycled to the gaseous hydrogen feed stream, thereby forming a compressor feed stream.
5. The method of claim 4, further comprising: a hydrogen generation unit configured to produce a gaseous hydrogen stream, a hydrogen stream flow control valve, and a first boil-off gas flow indicator, wherein the first boil-off gas flow indicator detects the flowrate of medium-pressure boil-off gas stream, and sends a signal to the hydrogen stream flow control valve, thereby adjusting the flowrate of the gaseous hydrogen stream such that the flowrate of the compressor feed stream remains constant.
6. The method of claim 1, further comprising a liquid hydrogen storage unit, wherein the liquid hydrogen storage unit provides liquid hydrogen to the transport trucks or loading bays and collecting a second boil-off gas stream from the liquid hydrogen storage unit and recycling the second boil-off gas stream to the lower-temperature cold box.
7. The method of claim 1, wherein the boil-off gas is hydrogen.
8. A method for recovering boil-off gas from a system comprising one or more liquefaction trains, the one or more liquefaction trains comprising: transport trucks or loading bays, a gaseous hydrogen feed stream, and a low-pressure hydrogen compressor; the method comprising: collecting a boil-off gas stream from the transport trucks or loading bays, and recycling at least a portion of the boil-off gas stream to either the low-pressure hydrogen compressor or the gaseous hydrogen feed stream, or both.
9. The method of claim 8, further comprising a liquid hydrogen storage unit, and a lower-temperature cold boxy, wherein the liquid hydrogen storage unit provides liquid hydrogen to the transport trucks or loading bays and collecting a second boil-off gas stream from the liquid hydrogen storage unit and recycling the second boil-off gas stream to the lower-temperature cold box.
10. The method of claim 8, wherein the boil-off gas is hydrogen.
Description
BRIEF DESCRIPTION OF THE FIGURES
[0017] For a further understanding of the nature and objects for the present invention, reference should be made to the following detailed description, taken in conjunction with the accompanying drawings, in which like elements are given the same or analogous reference numbers and wherein:
[0018]
[0019]
[0020]
[0021]
[0022]
[0023]
ELEMENT NUMBERS
[0024] 101=feed stream
[0025] 102=hydrogen generation unit
[0026] 103=hydrogen stream
[0027] 104=hydrogen stream flow control valve
[0028] 105=gaseous hydrogen feed stream
[0029] 106=higher-temperature cold box
[0030] 107=nitrogen compressor
[0031] 108=cold hydrogen stream
[0032] 109=lower-temperature cold box
[0033] 110=low-pressure hydrogen compressor
[0034] 111=high-pressure hydrogen compressor
[0035] 112=liquid hydrogen stream (into storage)
[0036] 113=liquid hydrogen storage unit
[0037] 114=liquid hydrogen stream (out of storage)
[0038] 115=loading bay
[0039] 116=cool boil off gas (from loading bay)
[0040] 117=boil off gas heater
[0041] 118=warm boil off gas
[0042] 119=first flow indicator
[0043] 120=boil off gas (from liquid hydrogen storage)
[0044] 301=compressor feed stream
[0045] 302=feed compressor
[0046] 303=compressed feed stream
[0047] 401=boil off gas temperature indicator
[0048] 402=boil off gas pressure indicator
[0049] 403=first portion (of cool boil off gas)
[0050] 404=second portion (of cool boil off gas)
[0051] 405=third portion (of cool boil off gas)
[0052] 406=first LP flow control valve
[0053] 407=MP flow control valve
[0054] 408=second LP flow control valve
[0055] 409=LP boil off gas heater
[0056] 410=MP boil off gas heater
[0057] 411=warm LP boil off gas stream
[0058] 412=warm MP boil off gas stream
[0059] 413=second flow indicator
[0060] 414=feed bypass stream
[0061] 415=feed bypass valve
[0062] 501=feed stream
[0063] 502=hydrogen generation unit
[0064] 503=hydrogen output stream
[0065] 503A-E=compressor feed streams
[0066] 504A-E=feed compressors
[0067] 505=compressed feed stream
[0068] 505 A-E=compressed feed stream s
[0069] 506=purification unit
[0070] 507=purified stream
[0071] 508=portion of purified stream buffer)
[0072] 509=buffer compressor
[0073] 510=compressed buffer stream
[0074] 511=buffer tank
[0075] 512=outlet buffer stream
[0076] 513=buffer valve
[0077] 514=regulated buffer stream
[0078] 515=combined purified stream
[0079] 515A-E=inlet streams
[0080] 601=portion of warm BOG stream (to low-pressure hydrogen compressor)
[0081] 602=second portion of warm BOG stream
[0082] 603=BOG compressor
DESCRIPTION OF PREFERRED EMBODIMENTS
[0083] Illustrative embodiments of the invention are described below, While the invention is susceptible to various modifications and alternative forms. specific embodiments thereof have been shown by way of example in the drawings and are herein described in detail. It should be understood, however, that the description herein of specific embodiments is not intended to limit the invention to the particular forms disclosed, but on the contrary, the intention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention as defined by the appended claims.
[0084] It will of course be appreciated that in the development of any such actual embodiment, numerous implementation-specific decisions must be made to achieve the developer's specific goals, such as compliance with system-related and business-related constraints, which will vary from one implementation to another. Moreover, it will be appreciated that such a development effort might be complex and time-consuming, but would nevertheless be a routine undertaking for those of ordinary skill in the art having the benefit of this disclosure.
[0085] The present schemes maximize the recovery of Liquid Hydrogen BOG by valorizing these hydrogen molecules in one of three different ways: [0086] By sending the BOG to the liquefier(s) (depending on the global plant configuration several liquefiers train may be implemented) after being compresses and re-liquefied as necessary, [0087] By sending the BOG upstream of the liquefier(s), specifically at compression trains inlet, and [0088] By valorizing cold BOG directly in the liquefier to benefit from its inherent cold.
[0089] For such a configuration, one important aspect of the present system is separating the BOG depending on their pressure level, and temperature conditions and designing the compression trains capacities in consistency with the truck operations. The process control philosophy of the overall system is based on the adaptability of the hydrogen feedstock load to follow BOG generation and BOG recycle.
[0090] The present system allows for a reduction of the capacity of the upstream hydrogen generation system (e.g. electrolyzers or steam methane reformer) by controlling the feed flow rate (at the inlet of the hydrogen liquefaction system) with the BOG flow rate (by turning down the production capacity of hydrogen generation unit (or Feed flow rate) simultaneously with the recovery of BOG). The combination of these different BOG recovery options on the same site also improves the mutual flexibility of the different hydrogen compressors by separating the BOG depending on their pressure level and temperature conditions in order to route them to different tie-in points with different inlet pressure to maximize the flexibility of the integrated liquefaction system and speed up the filling sequence of the trucks or increase the recovery of BOG. Finally, the speeding up of the filling sequence will allow for a reduction of the number of truck loading bays.
[0091] This document primarily focuses on the BOG generation and recovery from the loading area, which is located downstream the hydrogen liquefaction unit and downstream the liquid hydrogen storage unit. The BOG generated in the loading area presents many challenges, for example the BOG amount generated when a truck returns to the loading bay depends on the logistics chain, delivery method, distance to customers, number of customers delivered, billing method etc. As used herein, the terms “loading area” or “loading” are understood to apply to truck loading. However, one skilled in the art can recognize that the present system may be equally applicable to the loading of ships, or any other means for transporting hydrogen.
[0092] Examples of potential sources of BOG generation may be as diversified as the following operations: [0093] Truck depressurization, In the case of a truck arriving on site at high pressure with a residue of liquid H2. The truck depressurization is the step that generates the highest peak flow of BOG [0094] Truck filling. This operation will generate gaseous hydrogen return at low pressure, and [0095] “natural heat release” around the storage systems.
[0096] Valorizing all the types of BOG simply according to
[0099] Managing the BOG only with solution principle described on
[0101] Turning to
[0102] Hydrogen feed stream 101 is introduced into hydrogen generation unit 102.
[0103] Hydrogen generation unit 102 may be any system known in the art, such as a steam methane reformer (SMR) or Electrolysis. Hydrogen generation unit 102 generates hydrogen output stream 103. Hydrogen output stream 103 may also come from an industrial complex off gas or from a pipeline. Once free of any components that may freeze in the downstream cold box (purification system not shown), but typically downstream of the compressors), Hydrogen output stream 103 passes through hydrogen output stream flow control valve 104, the function of which will be described below. Controlled hydrogen output stream 105 then combines warm MP BOG stream 412 thus forming compressor feed stream 301. Compressor feed stream 301 is then compressed in feed compressor 302, thus forming compressed feed stream 303, which enters the liquefier. While, typically, the medium-pressure BOG is at a lower pressure than required at the inlet of the liquefier, compressor feed stream 301 may, if necessary or desired, bypass feed compressor 302 by means of feed bypass stream 414 and feed bypass valve 415.
[0104] Again, in
[0105]
[0106] Cool BOG stream 116 is split into at least two of the three portions presented herein. The first portion of cool BOG stream portion 403, the flowrate of which is controlled by first LP flow control valve 406, is warmed up through LP BOG heater 409 and recycled via warm LP BOG stream 411 to low-pressure hydrogen compressor 110. The second portion of cool BOG stream portion 404, the flowrate of which is controlled by MP flow control valve 407, is warmed up through MP BOG heater 410 and recycled via warm MP BOG stream 412 to compressor feed stream 301. The BOG flow is then mixed with the hydrogen cycle flow. The third portion of cool BOG stream portion 405, the flowrate of which is controlled by second LP flow control valve 408, may be recycled back into lower-temperature cold box 109 as an alternative path to first portion 403.
[0107] First flow indicator 119 senses the flowrate of BOG flowing through warm MP BOG stream 412 and then sends a signal to hydrogen output stream flow control valve 104. Second flow indicator 413 senses the flowrate of BOG flowing through warm LP BOG stream 411 and then sends a signal to hydrogen output stream flow control valve 104. Hydrogen output stream flow control valve 104 then adjusts to regulate the total hydrogen flowrate through the liquefier. Note, it is shown that first flow indictor 119 sends a signal directly to hydrogen output stream flow control valve 104, but the skilled artisan will recognize that this communication may be controlled by a local computer, distributed control system (DCS), a programmable logic controller (PLC), or other systems known in the art.
[0108] Turning to
[0109]
[0110] This process scheme is typically applicable for liquefaction trains from about 5 to about 100 tpd and consists of producing two different BOG networks and separating the high pressure from the low-pressure truck BOG recovery networks. The BOG generated during the filling of the truck (<2 bara) is routed either to the warm end of the LP cycle compressor, similar to
[0111] Feed stream 501 is introduced into hydrogen generation unit 502. Hydrogen generation unit 502 may be any system known in the art, such as a steam methane reformer (SMR) or Electrolysis. Hydrogen generation unit 502 generates hydrogen output stream 503. Hydrogen output stream 503 may also come from an industrial complex off gas or from a pipeline. Once free of any components that may freeze in the downstream cold box (not shown), Hydrogen output stream 503 combines with warm MP BOG stream 412 and is split into multiple compressor feed streams 503A-503E. It should be noted that while 5 separate compressor streams are indicated, one skilled in the art will recognize that this number may be as few as 2 or as many as necessary for the design of the system. Compressor feed streams 503A-503E are then compressed in feed compressors 504A-504E, thus forming compressed feed streams 505A-505E, which combine into compressed feed stream 505 which may then enter purification unit 506.
[0112] Purification unit 506 produce purified stream 507, which then enters one or more liquefaction trains A/B. It should be noted that while 2 separate liquefaction trains are indicated, one skilled in the art will recognize that this number may be many as necessary for the design of the system. At least a portion 508 of purified stream 507 may be introduced into buffer compressor 509, thereby producing compressed buffer stream 510, which may then enter buffer tank 511. Buffer tank 511, as needed, may the release outlet buffer stream 512, the flowrate of which may be regulated by buffer valve 513, thus producing regulated buffer stream 514, which may combine with purified stream 507 as needed, thus forming combined purified stream 515, which is split into inlet streams 515A/B, which the then enter multiple liquefaction trains A/B
[0113] Again, in
[0114]
[0115] Cool BOG stream 116 is split into at least two portions. The first portion of cool BOG stream portion 403, the flowrate of which is controlled by first LP flow control valve 406, is warmed up through LP BOG heater 409, thus producing warm LP BOG stream 411. Warm LP BOG stream 411 is then split into warm LP BOG streams 411A/B which are recycled to low-pressure hydrogen compressors 110A/B. The second portion of cool BOG stream portion 404, the flowrate of which is controlled by MP flow control valve 407, is warmed up through MP BOG heater 410 and recycled via warm MP BOG stream 412 to compressor feed stream 503.
[0116] Turning to
[0117]
[0118] This process scheme is typically applicable for liquefaction trains from about 5 to about 100 tpd and consists of producing one single BOG network. BOG generated during filling are at low pressure and preferentially routed to the LP compressor of the liquefier. BOG generated during depressurization are at a higher pressure and also much higher flowrate. These BOG are all collected and letdown to the same low-pressure level and recycled preferentially to the LP compressor. The extra capacity that cannot be handled by the LP compressor (for example during a peak of BOG) is routed to the BOG compressor and/or feed gas compressor. Depending on the suction conditions of feed gas compressor 302, BOG compressor 603 may or may not be required.
[0119] Hydrogen feed stream 101 is introduced into hydrogen generation unit 102. Hydrogen generation unit 102 may be any system known in the art, such as a steam methane reformer (SMR) or Electrolysis. Hydrogen generation unit 102 generates hydrogen output stream 103. Hydrogen output stream 103 may also come from an industrial complex off gas or from a pipeline. Hydrogen output stream 103 then combines warm BOG stream 602 thus forming compressor feed stream 301. Compressor feed stream 301 is then compressed in feed compressor 302, thus forming compressed feed stream 303, which enters the liquefier.
[0120] Again, in
[0121]
[0122] Cool BOG stream 116 is warmed up through BOG heater 117. At least a portion 601 of warm BOG stream 118 is recycled to low-pressure hydrogen compressor 110. Another portion 602 of warm BOG stream 118 is then mixed with the hydrogen output stream 103.
ADVANTAGES
[0123] Operating range of the LP compressor is much narrower and LP compressor design gets simpler. The LP compressor can easily operate considering 0 BOG returning to the liquefier but also can well perform if multiple trucks are being filled simultaneously. The ramp-up and down between the running cases with or without BOG recovering is therefore reduced and the reactivity of the LP cycle compressor is enhanced
[0124] The liquefier production capacity becomes independent from the truck BOG recycle to the LP machine since LP BOG represent a much smaller and much more stable flow
[0125] As mentioned above, the Feed gas compressor system design can handle the depressurization BOG by reducing the production of the upstream H2 generation unit The BOG flow is typically much smaller compared to the nominal capacity of the feed compressor; hence the depressurization BOG flow can be increased and the depressurization time decreased. That way, the entire loading process duration might be reduced to the point that it may be possible to consider one less loading bay for the design of the plant. The ramping up and down of the integrated system to recover depressurization BOG is therefore beneficiating from the mutualized flexibility of the hydrogen generation system as well as from the Feed compressor.
[0126] BOG recovery is maximized (up to more than 90% recovery) and the sizing of the equipment is very little dependent on the BOG flowrate recycled.