Dry cement mixture

Abstract

A dry cement mixture comprises Portland cement and an ultra-fine component consisting of at least one ultra-fine additive, said ultra-fine component being a hydraulic binder, wherein Portland cement is present in an amount of at least 70 wt % of the mixture and the ultra-fine component is present in an amount of at least 5 wt % of the mixture, wherein the ultra-fine component has a particle size distribution characterized by a particle diameter D.sub.10 of between 0.5 m and 2 m and a particle diameter D.sub.90 of between 2 m and 8 m.

Claims

1. A dry cement mixture comprising (a) at least 70 wt % of Portland cement; and (b) at least 5 wt % of an ultra-fine component, which is different than the (a) Portland cement, consisting of at least one ultra-fine additive, said ultra-fine component being a hydraulic binder that contains slag, the ultra-fine component having a particle size distribution characterized by a particle diameter D.sub.10 of between 0.5 m and 2 m and a particle diameter D.sub.90 of between 2 m and 8 m, and the at least one ultra-fine additive containing slag in an amount of >70 wt. %.

2. The dry cement mixture according to claim 1, wherein the Portland cement is present in an amount of at least 80 wt. % of the dry cement mixture.

3. The dry cement mixture according to claim 1, wherein Portland cement is present in an amount of 70-79 wt. % of the dry cement mixture.

4. The dry cement mixture according to claim 1, wherein the Portland cement is present in an amount of at least 85 wt. % of the dry cement mixture; and the ultra-fine component is present in an amount of at least 7 wt. % of the dry cement mixture.

5. The dry cement mixture according to claim 1, wherein the weight ratio of Portland cement and the ultra-fine component is between 85/15 and 95/5.

6. The dry cement mixture according to claim 1, wherein the ultra-fine component has a particle size distribution characterized by a particle diameter D.sub.10 of between 0.7 m and 1 m.

7. The dry cement mixture according to claim 1, wherein the ultra-fine component has a particle size distribution characterized by a particle diameter D.sub.90 of between 4 m and 6 m.

8. The dry cement mixture according to claim 1, wherein the ultra-fine component has a particle size distribution characterized by a particle diameter D.sub.100 of 10 m-15 m.

9. The dry cement mixture according to claim 1, wherein the Portland cement has a particle size distribution characterized by a particle diameter D.sub.10 of between 1 m and 3 m, and a particle diameter D.sub.90 of between 30 m and 60 m.

10. The dry cement mixture according to claim 1, wherein the Portland cement is a CEM I cement according to EN 197-1.

11. The dry cement mixture according to claim 1, wherein the slag comprises ground blast furnace slag.

12. The dry cement according to claim 1, wherein the ultra-fine component has a particle size distribution characterized by a particle diameter D.sub.10 of between 0.7 m and 1 m, a particle diameter D.sub.90 of between 4 m and 6 m, and a particle size distribution characterized by a particle diameter D.sub.100 of (i) 10 m-15 m; the Portland cement has a particle size distribution characterized by a particle diameter D.sub.10 of between 1 m and 3 m, and a particle diameter D.sub.90 of between 30 m and 60 m; and wherein the weight ratio of Portland cement to the ultra-fine hydraulic component is between 85/15 and 95/5.

13. The dry cement according to claim 1, wherein the at least one ultra-fine additive is comprised of slag in an amount of >80 wt. %.

14. The dry cement according to claim 13, wherein the Portland cement is present in an amount of at least 85 wt. % of the dry cement mixture.

15. The dry cement mixture according to claim 1, wherein the Portland cement is present in an amount of at least 90 wt. % of the dry cement mixture.

16. The dry cement mixture according to claim 1, wherein the weight ratio of Portland cement and the ultra-fine component is about 90/10.

17. The dry cement mixture according to claim 1, wherein the Portland cement has a particle size distribution characterized by a particle diameter D.sub.10 of between 1.6 m and 2 m, and a particle diameter D.sub.90 of between 35 and 45 m.

18. The dry cement according to claim 12, wherein the Portland cement has a particle size distribution characterized by a particle diameter D.sub.10 of 1.6 m and 2 m, a particle diameter D.sub.90 of between 35 and 45 m.

19. A concrete composition comprising (a) a cement mixture according to claim 1; (b) aggregates; and (c) water.

20. A construction element comprising concrete produced by curing a concrete composition according to claim 19.

Description

DETAILED DESCRIPTION OF THE INVENTION

(1) Thus, the invention provides a premix binder based on a combination of a Portland cement with at least one ultra-fine additive. The ultra-fine particles added to the mix allow obtaining a binder showing high performances (durability and strength) that is therefore particularly adapted for the formulation of high and very high performance concretes. Mixing is performed on a cement plant with a dedicated device, which introduces the various components with high accuracy, and allows obtaining a very homogeneous mixture. The inventive cement mixture is preferably delivered to customers as a dry premix for concrete production, wherein the dry premix is packed in bags or other suitable containers.

(2) The invention allows concrete manufacturers to produce high strength and high durability concrete using only one binder, instead of mixing ordinary cement with ultra-fine additions (such as silica fume) on site. Customer benefits are regularity of the quality of the concrete produced, ease-of-use (leading to cost savings), high performances of the concrete produced, and aesthetics (the premix binder color is lighter than most of traditional cement and ultra-fine additions used).

(3) It has surprisingly been found that a relatively low content of the ultra-fine component together with a specific particle size distribution results in durability and compressive strength values that usually are only to be achieved with a substantially higher proportion of ultra-fine additives. In particular, the invention provides for an amount of Portland cement of at least 80 wt % of the mixture, which means that the mixture contains a maximum of 20 wt % of the ultra-fine component. According to the invention, the ultra-fine component is a hydraulic binder and has a particle size distribution characterized by a particle diameter D.sub.10 of between 0.5 m and 2 m and a particle diameter D.sub.90 of between 2 m and 8 m.

(4) The ultra-fine component of the cement mixture may consist of one, two or more ultra-fine additives. According to a preferred embodiment of the invention, the at least one ultra-fine additive comprises slag, in particular ground blast furnace slag. More specifically, the at least one ultra-fine additive comprises slag, in particular ground blast furnace slag, preferably in an amount of >70 wt %, in particular >80 wt %.

(5) According to a further preferred embodiment the ultra-fine component (consisting of one or more ultra-fine additives) has a content of slag, in particular ground blast furnace slag, of >70 wt %, in particular >80 wt %. Thus, the ultra-fine component consists mainly of slag particles.

(6) The cement mixture may, in addition to the ultra-fine component, also contain further additives.

(7) According to a preferred design of the cement mixture, Portland cement is present in an amount of at least 85 wt %, preferably at least 90 wt % of the mixture and the ultra-fine component is present in an amount of at least 7 wt %, preferably at least 10 wt % of the mixture. Thus, the maximum content of the ultra-fine component is narrowed down to 15 wt %.

(8) According to a further preferred embodiment, the weight ratio of Portland cement and ultra-fine component is between 85/15 and 95/5, in particular about 90/10.

(9) As mentioned above, the ultra-fine component binder has a particle size distribution characterized by a particle diameter D.sub.10 of between 0.5 m and 2 m, whereas ultra-fine additives usually have a lower D.sub.10 value in order to achieve the required durability standards. In contrast thereto, it has surprisingly been found that the specific D.sub.10-range as mentioned above also results in sufficient durability and strength of the concrete, while at the same time reducing water demand and costs.

(10) According to a preferred embodiment, the ultra-fine component has a particle size distribution characterized by a particle diameter D.sub.10 of between 0.7 m and 1 m.

(11) With regard to the D.sub.90 value, the ultra-fine component preferably has a particle size distribution characterized by a particle diameter D.sub.90 of between 4 m and 6 m. These preferred D.sub.90 values may be combined with the preferred D.sub.10 values as mentioned above.

(12) Particularly good results have been achieved by using an ultra-fine component that has a particle size distribution characterized by a particle diameter D.sub.100 of 10 m-15 m, in particular 12 m.

(13) In the context of the present invention the particle size distribution is defined by indicating specific percentiles of the particle diameter. The D.sub.90-percentile of the diameter indicates that 90% of the particles have a diameter that is smaller than the given value. For example, a value for D.sub.90 of 4 m indicates that 90% of the particles have a diameter that is smaller than 4 m. Analogously, the D.sub.10-percentile of the diameter indicates that 10% of the particles have a diameter that is smaller than the given value.

(14) In order to optimize the durability and strength of the resulting concrete, a specific particle size distribution of the Portland cement may also be adjusted. Preferably, the Portland cement has a particle size distribution characterized by a particle diameter D.sub.10 of between 1 m and 3 m, preferably between 1.6 m and 2 m, in particular 1.8 m, and a particle diameter D.sub.90 of between 30 m and 60 m, preferably between 35 and 45 m, in particular 40 m.

(15) The Portland cement preferably is a CEM I cement according to EN 197-1.

(16) The invention also refers to a concrete composition comprising a cement mixture according to the invention, aggregates and water. Preferably, the water/cement ratio is chosen between 0.3 and 0.6.

(17) Finally, the invention also refers to a construction element comprising concrete produced using a concrete composition as described above.

(18) In the following, the invention will be explained in more detail by reference to exemplary embodiments.

Example 1

(19) A dry cement mixture with the following components was produced. 90 wt % of Portland cement of the type CEM I 52.5 N 10 wt % of an ultra-fine blast furnace slag binder.

(20) Portland cement having the following particle size distribution was used: D.sub.10=1.8 m and D.sub.90=ca. 40 m.

(21) Ultra-fine blast furnace slag binder having the following particle size distribution was used: D.sub.10=ca. 0.8 m and D.sub.90=ca. 5.5 m.

(22) The resulting mixture had the following composition: Clinker: 86.06 wt % Blast furnace slag: 7.8 wt % Gypsum: 5.6 wt % Anhydrite: 0.3 wt % Dust: 0.2 wt % NaCl: 0.04 wt %

Example 2

(23) Concrete was produced from the dry cement mixture as described in example 1. The following components were mixed in a mixer: 410 kg of dry cement mixture as described in example 1 907 kg of aggregates with a nominal maximum coarse diameter of 12.5 mm 797 kg of sand with a nominal maximum coarse diameter of 4 mm 90 kg of limestone filler Superplasticizer admixture in the amount of 1.2 wt % of the dry cement mixture 160 l of water

(24) The wet concrete mass was poured into a form and cured to obtain a concrete block having the following mechanical strength values:

(25) Compressive strength: 1 day: 39 MPa 7 days: 76 MPa 28 days: 89 MPa

(26) Flexural strength: 28 days: 6 MPa

(27) Young modulus: 28 days: 44 GPa

Example 3

(28) Concrete was produced form the dry cement mixture as described in example 1. The following components were mixed in a mixer: 450 kg of dry cement mixture as described in example 1 930 kg of aggregates with a nominal maximum coarse diameter of 12.5 mm 790 kg of sand with a nominal maximum coarse diameter of 4 mm 80 kg of limestone filler Superplasticizer admixture in the amount of 2.0 wt % of the dry cement mixture 148 l of water

(29) The wet concrete mass was poured into a form and cured to obtain a concrete block having the following mechanical strength values:

(30) Compressive strength: 1 day: 49 MPa 7 days: 81 MPa 28 days: 94 MPa

(31) Flexural strength: 28 days: 6 MPa

(32) Young modulus: 28 days: 43 GPa

Example 4

(33) A comparative study was carried out between concretes composed respectively of:

(34) A/ C50/60 with ordinary Portland cement

(35) B/ C50/60 with dry cement mixture with an optimized dosage

(36) C/ C60/75 with ordinary Portland cement and silica fume addition

(37) D/ C60/75 with dry cement mixture

(38) The denominations C50/60 and C65/70 refer to the strength class according to Eurocode 2 (European Standard EN 1992). For example, C50/60 means that the concrete must have a compressive cylinder strength of 50 N/mm.sup.2 and a cube compressive strength of 60 N/mm.sup.2.

(39) A/ C50/60 with Ordinary Portland Cement: 425 kg of ordinary Portland cement 315 kg of aggregates with a nominal maximum coarse diameter of 12 mm 670 kg of aggregates with a nominal maximum coarse diameter of 20 mm 730 kg of sand with a nominal maximum coarse diameter of 4 mm Superplasticizer admixture in the amount of 1.3 wt % of the dry cement mixture 175 l of water

(40) The wet concrete mass was poured into a form and cured to obtain a concrete block having the following mechanical strength values:

(41) Compressive strength: 1 day: 12 MPa 7 days: 47 MPa 28 days: 56 MPa 90 days: 57 MPa

(42) Abrasion resistance coefficient (following the Compagnie Nationale du Rhne protocol): C=0.5

(43) Shock resistance (following the Compagnie Nationale du Rhne protocol): Volume caused by impacts=108 cm.sup.3

(44) The concrete block showed the following characteristics in terms of durability: Internal porosity: 12.6% Gas permeability: 119 E18 m.sup.2

(45) Chloride diffusion coefficient (migration test in stationary electric field): 6.8 E12 m.sup.2/s

(46) B/ C50/60 with Dry Cement Mixture with an Optimized Dosage 390 kg of dry cement mixture as described in example 1 315 kg of aggregates with a nominal maximum coarse diameter of 12 mm 670 kg of aggregates with a nominal maximum coarse diameter of 20 mm 765 kg of sand with a nominal maximum coarse diameter of 4 mm Superplasticizer admixture in the amount of 1.2 wt % of the dry cement mixture 180 l of water

(47) The wet concrete mass was poured into a form and cured to obtain a concrete block having the following mechanical strength values:

(48) Compressive strength: 1 day: 9 MPa 7 days: 44 MPa 28 days: 53 MPa 90 days: 57 MPa

(49) Abrasion resistance coefficient (following the Compagnie Nationale du Rhne protocol): C=0.5

(50) Shock resistance (following the Compagnie Nationale du Rhne protocol): Volume caused by impacts=118 cm.sup.3

(51) The concrete block showed the following characteristics in terms of durability: Internal porosity: 13% Gas permeability: 76 E18 m.sup.2 Chloride diffusion coefficient (migration test in stationary electric field): 8.0 E12 m.sup.2/s

(52) C/ C60/75 with Ordinary Portland Cement+Silica Fume Addition: 415 kg of ordinary Portland cement 270 kg of aggregates with a nominal maximum coarse diameter of 12 mm 700 kg of aggregates with a nominal maximum coarse diameter of 20 mm 800 kg of sand with a nominal maximum coarse diameter of 4 mm 25 kg of silica fume addition Superplasticizer admixture in the amount of 1.8 wt % of the dry cement mixture 161 l of water

(53) The wet concrete mass was poured into a form and cured to obtain a concrete block having the following mechanical strength values:

(54) Compressive strength: 1 day: 22 MPa 7 days: 56 MPa 28 days: 70 MPa 90 days: 75 MPa

(55) Abrasion resistance coefficient (following the Compagnie Nationale du Rhne protocol): C=0.3

(56) Shock resistance (following the Compagnie Nationale du Rhne protocol): Volume caused by impacts=103 cm.sup.3

(57) The concrete block showed the following characteristics in terms of durability: Internal porosity: 11.8% Gas permeability: 40 E18 m.sup.2

(58) Chloride diffusion coefficient (migration test in stationary electric field): 0.4 E12 m.sup.2/s

(59) D/ C60/75 with Dry Cement Mixture: 440 kg of dry cement mixture as described in example 1 270 kg of aggregates with a nominal maximum coarse diameter of 12 mm 700 kg of aggregates with a nominal maximum coarse diameter of 20 mm 800 kg of sand with a nominal maximum coarse diameter of 4 mm Superplasticizer admixture in the amount of 1.8 wt % of the dry cement mixture 147 l of water

(60) The wet concrete mass was poured into a form and cured to obtain a concrete block having the following mechanical strength values:

(61) Compressive strength: 1 day: 15 MPa 7 days: 63 MPa 28 days: 74 MPa 90 days: 75 MPa

(62) Abrasion resistance coefficient (following the Compagnie Nationale du Rhne protocol): C=0.3

(63) Shock resistance (following the Compagnie Nationale du Rhne protocol): Volume caused by impacts=91 cm.sup.3

(64) The concrete block showed the following characteristics in terms of durability: Internal porosity: 8.9% Gas permeability: 72 E18 m.sup.2 Chloride diffusion coefficient (migration test in stationary electric field): 2.2 E12 m.sup.2/s

(65) This study shows that the performance of the dry cement mixture of the invention enables to decrease the amount of binder in concrete without affecting its mechanical strength development and its durability. It also performs as well as mixtures composed of ordinary Portland cement and ultrafine high performance costly additions such as silica fume, from both a mechanical and a durability point of view. The dry cement mixture of the invention allows the production of high performance concrete in an easy way, and at an optimized cost.