PASTEURIZATION PLANT HAVING AN ION EXCHANGE DEVICE AND METHOD OF OPERATING A PASTEURIZATION PLANT
20180116254 ยท 2018-05-03
Assignee
Inventors
- Gunnar Demoulin (Salzburg, AT)
- Roland CONCIN (Fuschl am See, AT)
- Christian RINDERER (Fuschl am See, AT)
Cpc classification
A23L3/02
HUMAN NECESSITIES
C02F2103/32
CHEMISTRY; METALLURGY
A23V2002/00
HUMAN NECESSITIES
C02F9/00
CHEMISTRY; METALLURGY
A23L3/001
HUMAN NECESSITIES
C02F1/283
CHEMISTRY; METALLURGY
International classification
A23L3/02
HUMAN NECESSITIES
Abstract
The invention relates to a pasteurization plant and a method of operating a pasteurization plant. During operation of the pasteurization plant, a tempered process liquid is applied to containers filled with food products in one or more treatment zone(s). At least a part of the process liquid is fed back to the treatment zone(s) for reuse in at least one recirculation loop. At least a partial quantity of a volumetric flow of the process liquid fed per unit of time via the at least one recirculation loop is diverted to create at least one partial flow, circulated through at least one cleaning device and then returned to a recirculation loop or a treatment zone again. The at least one cleaning device comprises a membrane filtration device and an ion exchange device.
Claims
1. Method of operating a pasteurization plant (1), comprising conveying containers filled with food products and closed (6) through one or more treatment zone(s) (2), treating the containers (6) with a tempered aqueous process liquid (4) in the treatment zone(s) (2) by applying the process liquid (4) to an external surface (5) of the containers (6), wherein at least a part of the process liquid (4) from the treatment zone(s) (2) is fed back to a treatment zone (2) for reuse in at least one recirculation loop (11), and wherein at least a partial quantity of a volumetric flow of the process liquid (4) fed per unit of time via the at least one recirculation loop (11) is diverted to create at least one partial flow (19), which at least one partial flow (19) is filtered by means of a membrane filtration device (23), and dissolved ions are then removed from the at least one partial flow (19) by means of an ion exchange device (24) having at least one strongly acidic cation exchanger (32), and the at least one partial flow (19) is then returned to a recirculation loop (11) or a treatment zone (2) again.
2. Method according to claim 1, wherein a pH value of the partial flow (19) is influenced means of the at least one strongly acidic cation exchanger (32) with a view to obtaining a desired pH level.
3. Method according to claim 1, wherein the at least one strongly acidic cation exchanger (32) is regenerated depending on a change in pH value of the partial flow (19).
4. Method according to claim 1, wherein anions are removed from the partial flow (19) by means of at least one strongly basic anion exchanger (33).
5. Method according to claim 4, wherein a pH value of the partial flow (19) is influenced by means of the at least one strongly basic anion exchanger (33) with a view to obtaining a desired pH level.
6. Method according to claim 4, wherein the at least one strongly basic anion exchanger (33) is regenerated depending on a change in pH value of the partial flow (19).
7. Method according to claim 1, wherein a content of ions dissolved in the partial flow (19) is monitored by sensors upstream and downstream of the ion exchange device (24) respectively.
8. Method according to claim 7, wherein a content of ions dissolved in the partial flow (19) is monitored by measuring a pH value of the partial flow (19) respectively upstream and downstream of the point where ions are removed by means of the ion exchange device (24).
9. Method according to claim 1, wherein the partial quantity of process liquid (4) diverted from the at least one recirculation loop (11) in order to create the partial flow (19) is regulated by means of a flow regulating device (35).
10. Method according to claim 1, wherein at least a part of the process liquid (4) removed from the partial flow (19) by means of at least one flow regulating means (38) is fed through the ion exchange device (24) and then returned to the partial flow (19) again.
11. Method according to claim 10, wherein a flow quantity of process liquid (4) through the ion exchanger(s) (32, 33) is regulated respectively by means of a flow regulating means (38) separately for each ion exchanger (32, 33) of the ion exchange device (24).
12. Method according to claim 1, wherein before removing the dissolved ions, the partial flow (19) is additionally directed through a liquid treatment device (42) comprising metal particles or a metal mesh comprising copper and/or zinc.
13. Method according to claim 1, wherein after removing dissolved ions, dissolved substances are also removed from the partial flow (19) by means of an adsorption device (43).
14. Method according to claim 13, wherein the dissolved substances are removed from the partial flow (19) by means of an activated carbon filter (44).
15. Method according to claim 1, wherein the food products in the containers (6) are heated in a treatment zone (2) or are heated in several treatment zones (2) successively and then pasteurized in a treatment zone (2) or several treatment zones (2),, after which they are cooled in a treatment zone (2) or cooled in several treatment zones (2) successively.
16. Method according to claim 1, wherein a partial volumetric flow of process liquid (4) is directed through a heat exchanger (46) of an air-cooled cooling tower (45), depending on requirements.
17. Method according to claim 1, wherein containers (6) incorporating a metal material, in particular an aluminum material, can be treated by means of the pasteurization plant (1), at least temporarily.
18. Pasteurization plant (1), comprising one or more treatment zone(s) (2) with delivery means(n) (3) for applying a tempered process liquid (4) to an external surface (5) of containers (6), a conveyor device (7) for conveying the containers (6) through the treatment zone(s) (2), and at least one recirculation loop (11) for diverting the process liquid (4) from the treatment zone(s) (2) and for recirculating at least a part of the diverted process liquid (4) to a treatment zone (2), wherein at least one cleaning device (16) is provided, which at least one cleaning device (16) is fluidically connected to a removal means (17) for removing a partial flow (19) of process liquid (4) from the at least one recirculation loop (11), and which at least one cleaning device (16) is connected to a returning means (18) for returning the partial flow (19) to a recirculation loop (11) or a treatment zone (2), which at least one cleaning device (16) comprises a membrane filtration device (23) for filtering the partial flow (19), and which at least one cleaning device (16) comprises an ion exchange device (24) having at least one strongly acidic cation exchanger (32) fluidically connected downstream of the membrane filtration device (23).
19. Pasteurization plant according to claim 18, wherein the ion exchange device (24) comprises at least one strongly basic anion exchanger (33).
20. Pasteurization plant according to claim 18, wherein the ion exchange device (24) is fluidically connected to at least one regeneration means (40, 41) for regenerating the ion exchanger(s) (32, 33).
21. Pasteurization plant according to claim 18, wherein a sensor means for monitoring a content of ions dissolved in the partial flow (19) is arranged fluidically upstream and downstream of the ion exchange device (24) respectively.
22. Pasteurization plant according to claim 21, wherein a pH value sensor (34) is arranged fluidically upstream and downstream of the ion exchange device (24) respectively.
23. Pasteurization plant according to claim 19, wherein a ratio of an ion exchange total capacity of all the available strongly acidic cation exchangers (32) to an ion exchange total capacity of all the available strongly basic anion exchangers (33) is selected depending on requirements with a view to obtaining a desired pH value of the partial flow (19) or process liquid (4).
24. Pasteurization plant according to claim 18, wherein a flow regulating device (35) is assigned to the at least one cleaning device (16).
25. Pasteurization plant according to claim 18, wherein the ion exchange device (24) is arranged fluidically parallel with a flow line (39) for the partial flow (19) in the at least one cleaning device (16) via at least one flow regulating means (38).
26. Pasteurization plant according to claim 25, wherein every ion exchanger (32, 33) of the ion exchange device (24) is assigned a flow regulating means (38).
27. Pasteurization plant according to claim 18, wherein the at least one cleaning device (16) comprises another liquid treatment device (42) comprising metal particles or a metal mesh comprising copper and/or zinc, which liquid treatment device (42) is fluidically connected between the membrane filtration device (23) and the ion exchange device (24).
28. Pasteurization plant according to claim 18, wherein the at least one cleaning device (16) comprises an adsorption device (43), which adsorption device (43) is fluidically connected downstream of the ion exchange device (24).
29. Pasteurization plant according to claim 28, wherein the adsorption device (43) has an activated carbon filter (44).
30. Pasteurization plant according to claim 18, wherein it comprises an air-cooled cooling tower (45) having a heat exchanger (46) through which the process liquid (4) can be guided if necessary.
Description
[0086] These are highly simplified, schematic diagrams respectively illustrating the following:
[0087]
[0088]
[0089]
[0090] Firstly, it should be pointed out that the same parts described in the different embodiments are denoted by the same reference numbers and the same component names and the disclosures made throughout the description can be transposed in terms of meaning to same parts bearing the same reference numbers or same component names. Furthermore, the positions chosen for the purposes of the description, such as top, bottom, side, etc., relate to the drawing specifically being described and can be transposed in terms of meaning to a new position when another position is being described.
[0091]
[0092] Food products are pasteurized during operation of the pasteurization plant 1 and the containers 6 are firstly filled with the food products and the containers 6 are then closed. The containers 6 filled with the food products and then closed are treated in a respective treatment zone 2 by applying an aqueous process liquid 4 to an external surface 5 of the containers 6 via the delivery means 3. The delivery means 3 of a respective treatment zone 2 may be provided in the form of sprinkler or nozzle type sprying means or generally means for distributing the process liquid in a respective treatment zone 2. The tempered aqueous process liquid 4 is applied to the external surface 5 of the containers 6 in this manner so that the containers 6 and hence the food products packaged in the containers 6 can be tempered in a specific way and pasteurized. In principle, containers 6 incorporating a metal material, in particular containers 6 incorporating an aluminum material, can be at least intermittently treated by means of the pasteurization plant 1.
[0093] In order to convey the containers 6 through the treatment zone(s) 2, a conveyor device 7 is provided. In the embodiment illustrated as an example in
[0094] During operation of the pasteurization plant 1, the food products in the containers 6 can be heated first of all in a treatment zone 2 or in several treatment zones 2. In the embodiment illustrated as an example in
[0095] For example, the food products are heated in treatment zone 2 disposed first of all in the conveying direction 9 and are then further heated in the next treatment zone 2 disposed in the conveying direction 9. In the next treatment zone 2 disposed in the conveying direction 9, the food products can then be pasteurized by applying a process liquid 4 at a particularly high temperature, for example between 70 C. and 110 C., to the external surface 5 of the containers 6. In the next two treatment zones 2 disposed in the conveying direction 9, the food products and containers 6 can then be cooled in a specific manner using an appropriately tempered cooler process liquid 4. The main advantage of this is that the food products are pasteurized as gently as possible, in particular without the tempering process itself causing damage to the food products.
[0096] After applying the tempered process liquid 4 to the external surface 5 of the containers 6 in the treatment zone(s) 2, the process liquid can be collected in a bottom floor region 10 of a respective treatment zone 2 and fed back out of a respective treatment zone 2. In order to discharge the process liquid 4 from the treatment zone(s) 2 and return at least a part of the discharged process liquid 4 to a treatment zone 2 or to one of the treatment zones 2, the pasteurization plant 1 comprises at least one recirculation loop 11. During operation of the pasteurization plant 1, therefore, at least a part of the process liquid 4, preferably a predominant part of the process liquid 4 or the entire process liquid 4, is fed out of the treatment zone(s) 2 for reuse in this at least one recirculation loop 11 and back into a treatment zone 2 again.
[0097] As may be seen from the embodiment illustrated as an example in
[0098] In order to convey and/or direct respective volumetric flows of process liquid 4 in the recirculation loop 11 or in the recirculation loops 11, conveying means 12 may be respectively provided, for example pumps, as illustrated in
[0099] Due to the continuous circulation of the process liquid 4 via the recirculation loop 11 or recirculation loops 11 and/or the continuous reuse of the process liquid 4 during operation of the pasteurization plant 1, contaminants and/or undesired substances can get into the aqueous process liquid over time. To enable these undesired substances and/or contaminants to be continuously removed from the process liquid 4, at least one cleaning device 16 is provided. The at least one cleaning device 16 is fluidically connected to a removal means 17 for removing a partial flow 19 of process liquid 4 from the at least one recirculation loop 11. The at least one cleaning device 16 is also fluidically connected to a returning means 18 for returning the removed partial flow 19 to a recirculation loop 11 or a treatment zone 2. As a result, during operation of the pasteurization plant 1, at least a partial quantity of a volumetric flow of process liquid 4 circulated via the at least one recirculation loop 11 per unit of time can be diverted to create at least one partial flow 19, as indicated by the arrows in
[0100] In the embodiment illustrated as an example in
[0101] In principle, a removal means 17 may be a simple distribution element, for example having a T-piece 20 which enables a partial flow 19 to be diverted from a recirculation loop 11, as schematically illustrated in
[0102] As also illustrated in
[0103] As a result, during operation of the pasteurization plant 1, the at least one partial flow 19 removed or diverted from a recirculation loop 11 can be filtered by means of a membrane filtration device 23 and dissolved ions can then be removed from the at least one partial flow 19 by means of an ion exchange device 24 having at least one strongly acidic cation exchanger. Having been cleaned in this manner, the at least one partial flow 19 can then be returned via a returning means 18 to a recirculation loop 11 or to a treatment zone 2 again. The at least one diverted partial flow 19 is preferably returned to the process liquid 4 of the same recirculation loop 11 from which it was removed, as also illustrated in
[0104] In this manner, undesired substances can be continuously and/or constantly removed from the process liquid 4 during operation of the pasteurization plant 1. This firstly enables the process liquid 4 to be kept as clear and germ-free as possible for the ongoing operation of a pasteurization plant 1. In addition, the concentration of undesired ions such as metal cations, for example aluminum ions or aluminum compounds present in ionic form, can be kept as low as possible.
[0105] In addition, a pH value of the partial flow can be influenced by means of the at least one strongly acidic cation exchanger of the ion exchange device 24 with a view to obtaining a desired pH level during operation of the pasteurization plant 1 because the cations removed from the partial flow 19 are replaced by solvated H.sup.+ ions.
[0106] Other advantageous embodiments of the pasteurization plant 1 and embodiments of the method will be explained in more detail with reference to
[0107] As illustrated in
[0108] The individual filter modules 26 may basically be of any design as long as they enable a tempered aqueous process liquid to be filtered. For example, a filter module 26 may have a plurality of hollow fiber membranes which may be mounted in a retentate chamber 27 on the intake side. These hollow fiber membranes may have pores with a pore diameter of between 0.01 m and 0.5 m for example, thus being suitable for micro- and/or ultra-filtration. The respectively open ends of the hollow fiber membranes of a filter module 26 may be embedded in a sealing means 28 in such a way that the open ends and the inner cavities of the hollow fibers open into a filtrate or permeate chamber 29 of a filter module 26. Accordingly, the sealing means 28 separate the retentate chamber 27 from the permeate chamber 29 in a sealed arrangement so that the at least one partial flow 19 of aqueous process liquid can only flow from the retentate chambers 27 by passing through the hollow fiber membrane walls from an external surface of the hollow fiber membranes into the interior of the hollow fibers and into the permeate chambers 29 of the filter modules 26. The at least one partial flow 19 is thus filtered and particulate and/or coagulated contaminants are held back on the retentate side.
[0109] As also illustrated in
[0110] As illustrated in
[0111] As also illustrated in
[0112] In principle, in order to influence the pH value of the at least one partial flow 19 in a specific way, a ratio of an ion exchange total capacity of all the available strongly acidic cation exchangers 32 to an ion exchange total capacity of all the available, strongly basic anion exchangers 33 is selected depending on requirements with a view to obtaining a desired pH value of the at least one partial flow 19 or the process liquid. A pH value of the at least one partial flow 19 is preferably adjusted to a slightly acidic level. For example, it may be of advantage if an average pH value of the process liquid for treating the external surface of the containers is between 4 and 7 during operation of the pasteurization plant 1. This may be of advantage as a means of preventing the occurrence of so-called wet storage stain on aluminum materials on the treated containers, for example. Accordingly, the ion exchange total capacity of all the available strongly acidic cation exchangers 32 may be selected so that it is higher than the ion exchange total capacity of all the available strongly basic anion exchangers 33. Care must naturally be taken to ensure that the ion exchange total capacity is sufficient to efficiently remove undesired dissolved ions from the at least one partial flow 19.
[0113] Based on one advantageous way of implementing the method, it may be of advantage if a content of dissolved ions in the partial flow 19 upstream and downstream of the ion exchange device 24 is monitored respectively by sensors. To this end, a sensor means for monitoring a content of ions dissolved in the partial flow 19 may be fluidically connected upstream and downstream of the ion exchange device 24 respectively. Such sensor means might be provided in the form of conductivity sensors or other suitable measuring devices which enable information to be gleaned about the content of ions, for example.
[0114] As illustrated by way of example in
[0115] By providing the pH sensors 34, a sudden increase in the concentration of ions dissolved in the partial flow 19 or in the process liquid generally can be detected, for example. For example, a sudden increase in the concentration of metal cations in the process liquid can be detected because these metal cations are exchanged by means of the at least one strongly acidic cation exchanger 32 with solvated H.sup.+ ions. This can in turn be detected by means of the pH value sensors 34 directly due to a sudden drop in the pH value of the at least one partial flow 19 after it has passed through the at least one cation exchanger 32 of the ion exchange device 24. Steps can then be taken if necessary to prevent further soiling of the process liquid by undesired dissolved ions. At best, by providing the pH value sensors 34, it is even possible to detect errors in the implementation of the pasteurization process and/or unplanned and undesired influences on the method, for example due to containers that are leaking or soiled with metal or aluminum dust. At the same time, providing such pH sensors 34 is of advantage in that they serve as a reference or measuring means for influencing the pH value of the at least one partial flow 19 with a view to obtaining a desired pH level.
[0116] A pH value of the at least one diverted partial flow 19 can be influenced by means of the ion exchange device 24 by regulating a quantity of process liquid flowing through the ion exchange device 24, for example. To this end, the at least one cleaning device 16 is assigned a flow regulating device 35 as a control means 21 for regulating and/or adjusting a specific volumetric flow of the at least one partial flow 19 for example, as illustrated in both
[0117] In principle, an ion exchange device 24 may be connected to the at least one cleaning device 16 in such a way that the entire at least one partial flow 19 of process liquid 4 diverted or removed from a recirculation loop 11 can be circulated through the ion exchange device 24, as schematically illustrated in
[0118] Alternatively or in addition, it may also be of advantage if a flow regulating means 38 is provided for every ion exchanger 32, 33 of the ion exchange device 24. As a result, during operation of the pasteurization plant 1, a quantity of process liquid flowing through the ion exchanger(s) 32, 33 can be regulated separately by means of a flow regulating means 38 respectively provided for each ion exchanger 32, 33 of the ion exchange device 24, as may be seen in
[0119] As also illustrated in
[0120] To further improve cleaning efficiency for the process liquid, the at least one cleaning device 16 may comprise another liquid treatment device 42 having metal particles or a metal mesh incorporating copper and/or zinc. This liquid treatment device 42 may be fluidically connected between the membrane filtration device 23 and ion exchange device 24 in the at least one cleaning device 16. The liquid treatment device 42 may also be disposed parallel with a flow line 39 for the partial flow 19 in the at least one cleaning device 16 so that it can be selectively fluidically shut off or opened, as illustrated in
[0121] By means of such a liquid treatment device 42, spontaneous oxidation and/or reduction reactions with some of the substances dissolved in the process liquid can be initiated during operation of the pasteurization plant 1. As a result, more noble metal cations than zinc and/or copper, for example heavy metal ions, iron ions, etc., can be removed from a diverted partial flow 19 for example. This is also of advantage for improving the efficiency of the downstream ion exchange device 24 because the ions removed by means of the liquid treatment device 42 no longer have to be removed from the at least one partial flow 19 by means of the ion exchange device 24 and therefore are not competing with other ions dissolved in the partial flow 19 during the ion exchange. The usable ion exchange capacity of the ion exchangers 32, 33 of the ion exchange device 24 is therefore advantageously available for drawing off or removing other undesired dissolved ions that cannot be removed by means of the liquid treatment device 42, for example aluminum ions and/or ions of aluminum compounds.
[0122] Furthermore, the at least one cleaning device 16 may comprise an adsorption device 43, which adsorption device 43 is fluidically connected downstream of the ion exchange device 24. The adsorption device 43 may have an activated carbon filter 44, for example. As a result, during operation of the pasteurization plant 1, after dissolved ions have been removed by means of the ion exchange device 24, dissolved substances may additionally be removed from the at least one partial flow 19 by means of an adsorption device 43, for example by means of an activated carbon filter 44.
[0123] In principle, it may be of practical advantage if the at least one cleaning device 16 is disposed in a recirculation loop 11 and/or is connected to a recirculation loop 11 by pipes, in which recirculation loop 11 process liquid 4 is circulated at a slightly lower temperature during operation of the pasteurization plant 1, as also illustrated in
[0124]
[0125] As may be seen from the parts of the embodiment of the pasteurization plant 1 illustrated as an example in
[0126] Air-cooled cooling towers are often needed in pasteurization plants for cooling a part of the process liquid 4, which cooled process liquid 4 can in turn be used to cool containers on completion of the pasteurization process, for example. Due to the fact that cooling towers usually need a high cooling capacity, a considerable amount of contaminants occur in conventional cooling towers without a heat exchanger. By providing the heat exchanger 46, contaminants can be efficiently prevented from getting into the process liquid 4 via or in the air-cooled cooling tower 45.
[0127] As illustrated in
[0128] The embodiments illustrated as examples represent possible variants, and it should be pointed out at this stage that the invention is not specifically limited to the variants specifically illustrated, and instead the individual variants may be used in different combinations with one another and these possible variations lie within the reach of the person skilled in this technical field given the disclosed technical teaching.
[0129] The protective scope is defined by the claims. The description and drawings may be used to interpret the claims. Individual features or combinations of features from the different embodiments illustrated and described may be construed as independent inventive solutions or solutions proposed by the invention in their own right. The objective underlying the independent inventive solutions may be found in the description.
[0130] All the figures relating to ranges of values in the description should be construed as meaning that they include any and all part-ranges, in which case, for example, the range of 1 to 10 should be understood as including all part-ranges starting from the lower limit of 1 to the upper limit of 10, i.e. all part-ranges starting with a lower limit of 1 or more and ending with an upper limit of 10 or less, e.g. 1 to 1.7, or 3.2 to 8.1 or 5.5 to 10.
[0131] For the sake of good order, finally, it should be pointed out that, in order to provide a clearer understanding of structure, constituent parts are illustrated to a certain extent out of scale and/or on an enlarged scale and/or on a reduced scale.
TABLE-US-00001 List of reference numbers 1 Pasteurization plant 2 Treatment zone 3 Delivery means 4 Process liquid 5 External surface 6 Container 7 Conveyor device 8 Conveyor belt 9 Conveying direction 10 Floor region 11 Recirculation loop 12 Conveying means 13 Means 14 Means 15 Heating device 16 Cleaning device 17 Removal means 18 Returning means 19 Partial flow 20 T-piece 21 Control means 22 Shut-off means 23 Membrane filtration device 24 Ion exchange device 25 Conveying means 26 Filter module 27 Retentate chamber 28 Sealing means 29 Permeate chamber 30 Back-flush liquid source 31 Discharge 32 Cation exchanger 33 Anion exchanger 34 pH value sensor 35 Flow regulating device 36 Flow regulating element 37 Flow sensor means 38 Flow regulating means 39 Flow line 40 Regeneration means 41 Regeneration means 42 Liquid treatment device 43 Adsorption device 44 Activated carbon filter 45 Cooling tower 46 Heat exchanger 47 Process liquid tank