METHOD AND DEVICE FOR PREPARING ACTIVE PARTICLE-CONTAINING STEAM
20180117559 ยท 2018-05-03
Inventors
Cpc classification
C10J3/00
CHEMISTRY; METALLURGY
B01J2219/0869
PERFORMING OPERATIONS; TRANSPORTING
C10J2300/0946
CHEMISTRY; METALLURGY
B01J19/088
PERFORMING OPERATIONS; TRANSPORTING
B01J12/002
PERFORMING OPERATIONS; TRANSPORTING
B01J2219/0894
PERFORMING OPERATIONS; TRANSPORTING
International classification
B01J12/00
PERFORMING OPERATIONS; TRANSPORTING
C10J3/00
CHEMISTRY; METALLURGY
Abstract
A device for preparing a high-temperature and active particle-containing steam. The device includes a steam generator including an inlet for introducing a plasma medium and an inlet for introducing a steam. In the steam generator, the steam is heated and activated by the plasma medium to form an active particle-containing steam which improves the gasification rate and efficiency in the gasification of coal, biomass, and garbage.
Claims
1. A device for preparing an active particle-containing steam, the device comprising: a plasma generator, the plasma generator comprising a non-oxidizing gas inlet and a plasma outlet; and a steam generator, the steam generator comprising a plasma inlet and a steam inlet; wherein: the non-oxidizing gas inlet is adapted to receive non-oxidizing gases into the plasma generator; the plasma generator is adapted to ionize the non-oxidizing gases to form a plasma working medium; the plasma inlet is surrounded by the steam inlet; the plasma inlet communicates with the plasma outlet and is adapted to receive the plasma working medium into the steam generator; the steam inlet is adapted to receive a first steam into the steam generator; and when in use, the first steam is heated and activated by the plasma working medium in the steam generator to form the active particle-containing steam.
2. The device of claim 1, wherein the steam generator further comprises between 1 and 4 annular gaps, a housing, a pressure conveyor, and a plurality of nozzles, the between 1 and 4 annular gaps are sequentially arranged at intervals on the housing and divide the housing into a plurality of sections, each of the plurality of sections has an inner diameter; the inner diameters of the plurality of sections are sequentially larger along the direction from the plasma inlet to the plasma outlet; and the between 1 and 4 annular gaps are connected to the pressure conveyor through the plurality of nozzles and are adapted to receive a second steam into the steam generator, wherein the second steam is pushed into the steam generator by the pressure conveyor.
3. The device of claim 2, wherein each of the plurality of sections has a length of between 300 and 800 mm.
4. The device of claim 2, wherein each of the between 1 and 4 annular gaps has a radial width of between 3 and 15 mm.
5. The device of claim 1, wherein the steam generator further comprises an end surface comprising a central part; and the plasma inlet is disposed at the central part.
6. The device of claim 1, wherein the steam generator further comprises a rotary guide vane; and the rotary guide vane is disposed inside the steam inlet and is adapted to rotate the first steam.
7. The device of claim 1, wherein the steam inlet is in an annular shape.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0020]
[0021]
[0022]
DETAILED DESCRIPTION OF THE EMBODIMENTS
[0023] To further illustrate the invention, experiments detailing a method and a device for preparing high-temperature, active particle-containing steam by using plasma are described below. It should be noted that the following examples are intended to describe and not to limit the invention.
[0024] As shown in
[0025] The high-temperature steam generator 2 comprises a housing in a gradually enlarged step structure. The housing comprises between 1 and 4 steps. Take a 3 steps housing of the high-temperature steam generator 2 as an example, the housing of the high-temperature steam generator 2 comprises sections of 2a, 2b, and 2c.
[0026] Annular gaps 3a, 3b, and 3c are arranged between every two adjacent steps of the housing for allowing the steam to enter the high-temperature steam generator. The annular gaps 3a, 3b, and 3c are connected to the pressure conveyor 3 through nozzles 3a1, 3b1, and 3c1 provided with annular cavities, respectively.
[0027] Each of the gradually enlarged steps of the housing of the high-temperature steam generator has a length of between 300 and 800 mm. The housing is made of a fire-proof material.
[0028] The annular gap has a radial width of between 3 and 15 mm.
[0029] A method for preparing high-temperature, active particle-containing steam by using plasma, comprises the following steps: [0030] 1) preparing steam; selecting one or several non-oxidizing gases as a working gas; ionizing the working gas into a plasma working medium by using a plasma generator; and [0031] 2) injecting the plasma working medium into a high-temperature steam generator comprising a rotary guide vane to form high-temperature ionized environment while introducing the steam through the rotary guide vane into the high-temperature steam generator for allowing the steam to contact with the plasma working medium so that the steam is heated and activated to form active particle-containing steam.
[0032] The working gas in step 1) is ionized into high-temperature plasma having a temperature of between 3,000 and 12,000 K by the plasma generator.
[0033] The steam comprises: unsaturated steam, saturated steam, superheated steam, or a mixture of a steam and the air or/and oxygen. Preferably, the steam is saturated steam.
[0034] Common non-oxidizing gas comprises: Ar, N.sub.2, H.sub.2, CO.sub.2, and CH.sub.4. Preferably, the non-oxidizing gas is nitrogen.
[0035] The plasma working medium in step 2) is injected into the high-temperature steam generator at a speed of between 30 and 100 m/s. The steam is injected into the high-temperature steam generator at a speed of between 5 and 30 m/s. A mass flow ratio of the plasma working medium to the steam in the high-temperature steam generator is adjusted for enabling the steam at an outlet of the high-temperature steam generator to have a temperature of between 1,000 and 4,000 K.
[0036] Between 1 and 4 annular gaps are arranged at intervals on the housing of the high-temperature steam generator. Part of the steam is guided through the annular gaps into the high-temperature steam generator by the force of a pressure conveyor and forms a low temperature water film on the wall of the high-temperature steam generator for protection.
[0037] Each of the gradually enlarged steps of the housing of the high-temperature steam generator has a length of between 300 and 800 mm. The annular gap has a radial width of between 3 and 15 mm.
EXAMPLE 1
[0038] Working gas N.sub.2 is ionized into high-temperature plasma having the temperature of 3,000 K by a plasma generator 1 and is injected into a high-temperature steam generator 2 at a speed of 30 m/s, so that a 3,000 K of high-temperature ionized environment is formed. One part of saturated steam is introduced through an annular steam inlet 3d provided with a rotary guide vane into the high-temperature steam generator 2 in the form of a rotary flow at a speed of 10 m/s, and the steam contacts with the high-temperature plasma. The other part of the steam is guided through annular gaps 3a, 3b, and 3c and into the high-temperature steam generator 2 at a speed of 5 m/s and forms a low temperature water film on a wall of the high-temperature steam generator 2 for protection. As the high-temperature plasma is abundant in ionized active particles, when the saturated steam is mixed and contacts with the high-temperature plasma, the steam is heated and ionized to be high-temperature steam containing active particles (active H.sub.2O, active H, active O and HO.sup., and H.sup., O.sup.+2). The steam after the reaction at an outlet 5 of the high-temperature steam generator 2 has the temperature of 1,500 K, and can be directly transferred into a gasification device for gasification.
EXAMPLE 2
[0039] Working gas CO.sub.2 is ionized into high-temperature plasma having the temperature of 5,000 K by a plasma generator 1 and is injected into a high-temperature steam generator 2 at a speed of 70 m/s, so that a 5,000 K of high-temperature ionized environment is formed. One part of saturated steam is introduced through an annular steam inlet 3d provided with a rotary guide vane into the high-temperature steam generator 2 in the form of a rotary flow at a speed of 15 m/s, and the steam contacts with the high-temperature plasma. The other part of the steam is guided through annular gaps 3a, 3b, and 3c and into the high-temperature steam generator 2 at a speed of 7 m/s and forms a low temperature water film on the wall of the high-temperature steam generator 2 for protection. As the high-temperature plasma is abundant in ionized active particles, when the saturated steam is mixed and contacts with the high-temperature plasma, the steam is heated and ionized to be high-temperature steam containing active particles (active H.sub.2O, active H, active O and HO.sup., and H.sup., O.sup.+2). The steam after the reaction at an outlet 5 of the high-temperature steam generator 2 has the temperature of 2,400 K, and can be directly transferred into a gasification device for gasification.
EXAMPLE 3
[0040] Working gas Ar is ionized into high-temperature plasma having the temperature of 12,000 K by a plasma generator 1 and is injected into a high-temperature steam generator 2 at a speed of 100 m/s, so that a 10,000 K of high-temperature ionized environment is formed. One part of saturated steam is introduced through an annular steam inlet 3d provided with a rotary guide vane into the high-temperature steam generator 2 in the form of a rotary flow at a speed of 30 m/s, and the steam contacts with the high-temperature plasma. The other part of the steam is guided through annular gaps 3a, 3b, and 3c having a width of 10 mm and into the high-temperature steam generator 2 at a speed of 10 m/s and forms a low temperature water film on the wall of the high-temperature steam generator 2 for protection. As the high-temperature plasma is abundant in ionized active particles, when the saturated steam is mixed and contacts with the high-temperature plasma, the steam is heated and ionized to be high-temperature steam containing active particles (active H.sub.2O, active H, active O and HO.sup., and H.sup., O.sup.+2). The steam after the reaction at an outlet 5 of the high-temperature steam generator 2 has the temperature of 3,000 K, and can be directly transferred into a gasification device for gasification.
[0041] Steam inlets of the high-temperature steam generator of the invention are individually designed for preventing the steam from contacting with the electrodes. Therefore, those technical schemes that employ non-oxygen gas as an ionizing medium and adopt individual inlets to allow the steam to enter the high-temperature steam generator will fall within the protection scope of the invention.