Ternary inorganic compound crystal and preparation method and application thereof

Abstract

Provided is a ternary inorganic compound crystal having a molecular formula of Ca.sub.8Al.sub.12P.sub.2O.sub.31, and a preparation method thereof comprising the following steps: weighing calcium salts, aluminum salts and phosphate respectively according to the molar ratio of calcium, aluminum and phosphorus in the molecular formula Ca.sub.8Al.sub.12P.sub.2O.sub.31; calcining at 15501570 C., cooling, and grinding to obtain the ternary inorganic compound crystal. Also provided is an application of the ternary inorganic compound in gelling materials and molecular sieves, nonlinear optical crystals, and photochromic materials.

Claims

1. A ternary inorganic compound crystal having a molecular formula of Ca.sub.8Al.sub.12P.sub.2O.sub.31, wherein oxide of the Ca.sub.8Al.sub.12P.sub.2O.sub.31 has a composition of 8CaO.6Al.sub.2O.sub.3P.sub.2O.sub.5 and the Ca.sub.8Al.sub.12P.sub.2O.sub.31 is characterized by a powder X-ray diffraction pattern with diffraction peaks at 2 of 9.62, 13.62, 19.31, 23.71, 33.80, 36.59, and 41.71.

2. A method for preparing a ternary inorganic compound crystal, comprising the steps of: weighing calcium nitrate, aluminium nitrate, and ammonium dihydrogen phosphate respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca.sub.8Al.sub.12P.sub.2O.sub.31; adding the calcium nitrate, aluminium nitrate, and ammonium dihydrogen phosphate to a water to give a mixed solution; and heating the mixed solution to 70 C.-80 C. with continuously stirring, the mixed solution form a sol and further form a gel after distillation of water, and presintering the gel at 600 C.-800 C., to obtain a presintered product; and pressing the presintered product into blanks, then calcinating the blanks at 1550 C.-1570 C. for 1.5-2.5 hrs, and cooling them to room temperature, to obtain the ternary inorganic compound crystal.

3. The method according to claim 2, wherein the presintering temperature is 700 C.

4. A method for preparing a ternary inorganic compound crystal, comprising the steps of: weighing calcium carbonate, aluminium hydroxide, and calcium hydrophosphate respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca.sub.8Al.sub.12P.sub.2O.sub.31, mixing the calcium carbonate, aluminium hydroxide, and calcium hydrophosphate and then pressing them into blanks, calcinating the blanks at 1550 C.-1570 C. for at least 7 hrs, and cooling them to room temperature, to obtain the ternary inorganic compound crystal.

5. The method according to claim 4, wherein the blanks are calcinated for 7 to 9 hrs.

Description

BRIEF DESCRIPTION OF THE DRAWING

(1) The FIGURE is an X-ray diffraction pattern of a ternary inorganic compound crystal according to an embodiment of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

(2) To make the objects, technical solutions, and advantages of the present invention clearer, the present invention is described in further detail with reference to accompanying drawings and examples. It should be understood that the specific examples described herein are provided merely for illustrating, instead of limiting the present invention.

(3) A ternary inorganic compound crystal having a molecular formula of Ca.sub.8Al.sub.12P.sub.2O.sub.31 is provided.

(4) Specifically, the oxide composition of the ternary inorganic compound crystal is 8CaO.6Al.sub.2O.sub.3.P.sub.2O.sub.5, wherein the weight percentages of the oxides are respectively: CaO 37.31%, Al.sub.2O.sub.3 50.88%, and P.sub.2O.sub.5 11.81%.

(5) The ternary inorganic compound crystal is characterized by a powder X-ray diffraction pattern with diffraction peaks at 2 of about 9.62, 13.62, 19.31, 23.71, 33.80, 36.59, and 41.71. As shown in the FIGURE, in the powder X-ray diffraction pattern, the 2 values, corresponding indices of crystal face (hkl), and relative intensities (I/I.sub.0) of diffraction peaks are:

(6) 2.sub.1=9.62, (100), I.sub.1=14%; 2.sub.2=13.62, (110), I.sub.2=15.8%;

(7) 2.sub.3=16.70, (111), I.sub.3=1.7%; 2.sub.4=19.31, (200), I.sub.4=4.6%;

(8) 2.sub.5=21.62, (210), I.sub.5=4.3%; 2.sub.6=23.71, (211), I.sub.6=100%;

(9) 2.sub.7=27.44, (220), I.sub.7=8.2%; 2.sub.8=9.62, (300) or (221), I.sub.8=2.4%;

(10) 2.sub.9=30.75, (310), I.sub.9=17.5%; 2.sub.10=33.79, (222), I.sub.10=28.6%;

(11) 2.sub.11=36.59, (321), I.sub.11=12.1%; 2.sub.12=39.21, (400), I.sub.12=5.0%;

(12) 2.sub.13=40.08, (410) or (323), I.sub.13=5.5%; 2.sub.14=41.71, (411) or (330), I.sub.14=13.1%;

(13) 2.sub.15=43.50, (420), I.sub.15=4.5%; 2.sub.16=50.61, (510) or (431), I.sub.16=7.6%;

(14) 2.sub.17=54.88, (521), I.sub.17=3.5%; 2.sub.18=56.61, (440), I.sub.18=7.6%;

(15) 2.sub.19=58.54, (530) or (433), I.sub.19=7.3%; 2.sub.20=67.56, (622), I.sub.20=4.5%; and

(16) 2.sub.21=71.01, (444), I.sub.21=3.3%.

(17) The ternary inorganic compound crystal has a structure of simple cubic Bravais crystal lattice of cubic crystal system, wherein the cell parameter a is 0.91853 nm, and the number Z of molecules inside the cell is 1.

(18) A method (sol-gel process) for preparing a ternary inorganic compound crystal is further provided, which comprises the steps of:

(19) weighing calcium nitrate, aluminium nitrate, and ammonium dihydrogen phosphate respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca.sub.8Al.sub.12P.sub.2O.sub.31; adding the calcium nitrate, aluminium nitrate, and ammonium dihydrogen phosphate to water to give a mixed solution; and heating the mixed solution to 70 C.-80 C. with continuously stiffing, to form a gel from a sol after distillation of water, and presintering the gel at 600 C.-800 C., to obtain a presintered product; and

(20) pressing the presintered product into blanks, then calcinating the blanks at 1550 C.-1570 C. for 1.5-2.5 hrs, and cooling them to room temperature, to obtain the ternary inorganic compound crystal.

(21) Specifically, the calcium nitrate, aluminium nitrate and ammonium dihydrogen phosphate are formulated into a sol in deionized water, from which a gel is then formed. Then the gel is presintered at 600 C.-800 C. The resultant product is further ground, pressed into blanks, and then calcinated at a high temperature. Preferably, the presintering temperature is 700 C., and the high-temperature calcination temperature is not lower than 1550 C. The cooling may be carried out in the air, and the calcinated product may be further ground.

(22) A method (solid-phase reaction process) for preparing a ternary inorganic compound crystal is further provided, which comprises the steps of:

(23) weighing calcium carbonate, aluminium hydroxide, and calcium hydrophosphate respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca.sub.8Al.sub.12P.sub.2O.sub.31, mixing the calcium carbonate, aluminium hydroxide, and calcium hydrophosphate and then pressing them into blanks, calcinating the blanks at 1550 C.-1570 C. for at least 7 hrs, and cooling them to room temperature, to obtain the ternary inorganic compound crystal.

(24) Specifically, the calcium carbonate, aluminium hydroxide and calcium hydrophosphate are uniformly mixed, ground, and pressed into blanks, which are then calcinated directly at a high temperature. The high-temperature calcination temperature is not lower than 1550 C. The calcination time is not less than 7 hrs because the solid-phase reaction progresses slowly. Preferably, the calcination period is from 7 to 9 hrs. The cooling may be carried out in the air, and the calcinated product may be further ground. The cooling may be carried out in the air, and the calcinated product may be further ground.

(25) For the methods for preparing the present ternary inorganic compound crystal, only the sol-gel process and the solid-phase reaction process are described, with the sol-gel process being preferred. Other methods may also be employed.

(26) Use of the ternary inorganic compound crystal in gel materials, molecular sieves, nonlinear optical crystals, and photochromic materials is further provided.

(27) Hereinafter, the method for preparing the ternary inorganic compound crystal and properties thereof are described by way of examples.

Example 1

(28) Calcium nitrate, aluminium nitrate, and ammonium dihydrogen phosphate were weighed respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca.sub.8Al.sub.12P.sub.2O.sub.31, and added with deionized water to give a mixed solution. The mixed solution was heated on a magnetic stirrer to 70-80 C., and continuously stirred to form a gel from a sol after distillation of water. Then, the gel was presintered at 700 C., ground, pressed into blanks, then calcinated for 2 hrs in a muffle furnace at 1550 C., and cooled in the air to room temperature. The calcinated material was ground into fine powder (wherein the residue on a square mesh screen of 75 m was 4%), and mixed with water at a water/cement ratio of 0.32, to prepare a standard paste sample (20 mm20 mm20 mm) The compressive strength over 12 hrs of the standard paste sample is 37 MPa, and the compressive strength over 1 day is 70 MPa.

Example 2

(29) Calcium nitrate, aluminium nitrate, and ammonium dihydrogen phosphate were weighed respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca.sub.8Al.sub.12P.sub.2O.sub.31, and added with deionized water to give a mixed solution. The mixed solution was heated on a magnetic stirrer to 70-80 C., and continuously stirred to form a gel from a sol after distillation of water. Then, the gel was presintered at 700 C., ground, pressed into blanks, then calcinated for 2 hrs in a muffle furnace at 1560 C., and cooled in the air to room temperature. The calcinated material was ground into fine powder (wherein the residue on a square mesh screen of 75 m was 4%), and mixed with water at a water/cement ratio of 0.32, to prepare a standard paste sample (20 mm20 mm20 mm) The compressive strength over 12 hrs of the standard paste sample is 38 MPa, and the compressive strength over 1 day is 72 MPa.

Example 3

(30) Calcium nitrate, aluminium nitrate, and ammonium dihydrogen phosphate were weighed respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca.sub.8Al.sub.12P.sub.2O.sub.31, and added with deionized water to give a mixed solution. The mixed solution was heated on a magnetic stirrer to 70-80 C., and continuously stirred, to form a gel from a sol after distillation of water. Then, the gel was presintered at 700 C., ground, pressed into blanks, then calcinated for 2 hrs in a muffle furnace at 1560 C., and cooled in the air to room temperature. The calcinated material was ground into fine powder (wherein the residue on a square mesh screen of 75 m was 4%), and mixed with water at a water/cement ratio of 0.32, to prepare a standard paste sample (20 mm20 mm20 mm) The compressive strength over 12 hrs of the standard paste sample is 38 MPa, and the compressive strength over 1 day is 73 MPa.

Example 4

(31) Calcium carbonate, aluminium hydroxide, and calcium hydrophosphate were weighed respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca.sub.8Al.sub.12P.sub.2O.sub.31, uniformly mixed, pressed into blanks, calcinated for 8 hrs in a muffle furnace at 1550 C., and then cooled in the air to room temperature. The calcinated material was ground into fine powder (wherein the residue on a square mesh screen of 75 m was 4%), and mixed with water at a water/cement ratio of 0.32, to prepare a standard paste sample (20 mm20 mm20 mm) The compressive strength over 12 hrs of the standard paste sample is 31 MPa, and the compressive strength over 1 day is 65 MPa.

Example 5

(32) Calcium carbonate, aluminium hydroxide, and calcium hydrophosphate were weighed respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca.sub.8Al.sub.12P.sub.2O.sub.31, uniformly mixed, pressed into blanks, calcinated for 8 hrs in a muffle furnace at 1560 C., and then cooled in the air to room temperature. The calcinated material was ground into fine powder (wherein the residue on a square mesh screen of 75 m was 4%), and mixed with water at a water/cement ratio of 0.32, to prepare a standard paste sample (20 mm20 mm20 mm) The compressive strength over 12 hrs of the standard paste sample is 33 MPa, and the compressive strength over 1 day is 66 MPa.

Example 6

(33) Calcium carbonate, aluminium hydroxide, and calcium hydrophosphate were weighed respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca.sub.8Al.sub.12P.sub.2O.sub.31, uniformly mixed, pressed into blanks, calcinated for 8 hrs in a muffle furnace at 1570 C., and then cooled in the air to room temperature. The calcinated material was ground into fine powder (wherein the residue on a square mesh screen of 75 m was 4%), and mixed with water at a water/cement ratio of 0.32, to prepare a standard paste sample (20 mm20 mm20 mm) The compressive strength over 12 hrs of the standard paste sample is 36 MPa, and the compressive strength over 1 day is 68 MPa.

Example 7

(34) Calcium nitrate, aluminium nitrate, and ammonium dihydrogen phosphate were weighed respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca.sub.8Al.sub.12P.sub.2O.sub.31, and added with deionized water to give a mixed solution. The mixed solution was heated on a magnetic stirrer to 70-80 C., and continuously stirred, to form a gel from a sol after distillation of water. Then, the gel was presintered at 700 C., ground, pressed into blanks, then calcinated for 2 hrs in a muffle furnace at 1550 C., and cooled in the air to room temperature, to prepare a polycrystal sample of 5-50 m, which is used as a molecular sieve.

Example 8

(35) Calcium nitrate, aluminium nitrate, and ammonium dihydrogen phosphate were weighed respectively according to the molar ratio among calcium, aluminium, and phosphorus in the molecular formula Ca.sub.8Al.sub.12P.sub.2O.sub.31, and added with deionized water to give a mixed solution. The mixed solution was heated on a magnetic stirrer to 70-80 C., and continuously stirred, to form a gel from a sol after distillation of water. Then, the gel was presintered at 700 C., ground, pressed into blanks, then calcinated for 2 hrs in a muffle furnace at 1550 C., cooled in the air to room temperature, and grown into a large-size monocrystal by a molten salt method (flux method), which is used for preparing a non-linear optical material.

(36) The foregoing description is merely preferred embodiments of the present invention, and the present invention is not limited thereto. Any modifications, equivalent replacements, and improvements made without departing from the spirit and principle of the present invention fall within the protection scope of the present invention.