Non-thermal refined soft-nitrided component

Abstract

Provided is a non-thermal refined soft-nitrided component including chemical composition of a steel material of a base metal containing: in mass %, C: 0.25 to 0.40%; Si: 0.10 to 0.35%; Mn: more than 2.0% to 2.8% or less; N: 0.0030 to 0.0250%; Cu: 0 to 1.0%; Mo: 0 to 0.3%; Ni: 0 to 0.5%; Ti: 0 to 0.020%; and a balance being Fe and impurities, the impurities including P: 0.08% or less; S: 0.10% or less; Al: 0.05% or less; and Cr: less than 0.20%, wherein a Vickers hardness at a position of 0.05 mm from the surface is 400 to 480, a Vickers hardness at a position of 1.0 mm from the surface is 200 or more, and a compound-layer depth at a stress concentrated region is 5 m or less. This non-thermal refined soft-nitrided component has an excellent bending straightening property and a high fatigue strength.

Claims

1. A non-thermal refined soft-nitrided component having a compound layer in a surface layer of a steel material of a base metal, chemical composition of the steel material of the base metal containing: in mass %, C: 0.25 to 0.40%; Si: 0.10 to 0.35%; Mn: more than 2.0% to 2.8% or less; N: 0.0030 to 0.0250%; Cu: 0 to 1.0%; Mo: 0 to 0.3%; Ni: 0 to 0.5%; Ti: 0 to 0.020%; and a balance being Fe and impurities, the impurities including P: 0.08% or less; S: 0.10% or less; Al: 0.05% or less; and Cr: less than 0.20%, wherein an HV hardness at a position of 0.05 mm from the surface is 400 to 480, an HV hardness at a position of 1.0 mm from the surface is 200 or more, and a compound-layer depth at a stress concentrated region is 5 m or less.

2. The non-thermal refined soft-nitrided component according to claim 1, wherein the steel material of the base metal contains, in mass %, one or more types of elements selected from Cu: 0.05 to 1.0% and Mo: 0.05 to 0.3%.

3. The non-thermal refined soft-nitrided component according to claim 1, wherein the steel material of the base metal contains, in mass %, one or more types of elements selected from Ni: 0.05 to 0.5% and Ti: 0.005 to 0.020%.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a drawing exemplifying a part of a crankshaft as a non-thermal refined soft-nitrided component, and explaining a pin fillet section and a journal fillet section equivalent to a stress concentrated region of the crankshaft.

(2) FIG. 2 is a drawing showing a shape of a grooved Ono-type rotating bending fatigue test specimen used in Example; and a unit of measurement in the drawing is mm.

(3) FIG. 3 is a drawing showing a shape of a four-point bending test specimen used in Example; and a unit of measurement in the drawing is mm.

MODE FOR CARRYING OUT THE INVENTION

(4) Each requirement of the present invention will be described in detail, hereinafter. It should be noted that % for a content of each element denotes mass %.

(5) (A) Chemical Composition of Steel Material of Base Metal:

(6) C: 0.25 to 0.40%

(7) C has an action to improve the internal hardness and the surface-layer hardness, and enhance the bending fatigue strength. The C content is required to be 0.25% or more in order to attain a desired bending fatigue strength. However, an excessive C content results in an excessively high surface-layer hardness, so that it is hard to attain a sufficient bending straightening property even if the compound-layer depth at the stress concentrated region is 5 m or less. Hence, the C content is set to be 0.25 to 0.40%. The C content is preferably 0.28% or more, and preferably 0.38% or less.

(8) Si: 0.10 to 0.35%

(9) Si is an element necessary for deoxidation during melting the steel, and the Si content of at least 0.10% is required for obtaining the above effect. However, an excessive content of Si causes excessive deterioration of the bending straightening property even if the compound-layer depth at the stress concentrated region is 5 m or less. Hence, the Si content is set to be 0.10 to 0.35%. The Si content is preferably 0.15% or more, and preferably 0.30% or less.

(10) Mn: more than 2.0% to 2.8% or less

(11) Mn is an element having a deoxidizing action similar to Si. Mn also has an action to improve the internal hardness, and increase a solute nitrogen content in the surface layer during the soft-nitriding to improve the surface-layer hardness, thereby enhancing the bending fatigue strength. In order to exert this effect, the Mn content is required to be more than 2.0%. On the other hand, the Mn content of more than 2.8% causes an excessively high surface-layer hardness, which excessively deteriorates the bending straightening property even if the compound-layer depth at the stress concentrated region is 5 m or less. Accordingly, the Mn content is set to be more than 2.0% to the 2.8% or less. The Mn content is preferably 2.2% or more, and preferably 2.7% or less.

(12) N: 0.0030 to 0.0250%

(13) N is an element to improve the bending fatigue strength and the bending straightening property. In order to attain this effect, the N content is required to be 0.0030% or more. On the other hand, the N content of more than 0.0250% rather saturates this effect. Accordingly, the N content is set to be 0.0030 to 0.0250%. The N content is preferably 0.0080% or more, and preferably 0.0220% or less.

(14) One of the steel materials of the base metal of the non-thermal refined soft-nitrided component according to the present invention contains the C to N elements, and a balance made of Fe and impurities, wherein P, S, Al, and Cr among the impurities are set such that P: 0.08% or less, S: 0.10% or less, Al: 0.05% or less, and Cr: less than 0.20%.

(15) P: 0.08% or less

(16) P is an impurity contained in the steel, and deteriorates the bending fatigue strength. Particularly, the P content of more than 0.08% significantly deteriorates the bending fatigue strength. Accordingly, the P content is set to be 0.08% or less. It is preferable to set the P content to be 0.04% or less.

(17) S: 0.10% or less

(18) S is an impurity contained in the steel. An effect to improve machinability can be attained by actively containing S. However, the S content of more than 0.10% significantly deteriorates the bending fatigue strength and the bending straightening property. Accordingly, the S content is set to be 0.10% or less. It is preferable to set the S content to be 0.08% or less. In order to attain the effect to improve machinability, it is preferable to set the S content to be 0.04% or more.

(19) Al: 0.05% or less

(20) Al is an impurity contained in the steel. An excessive Al content deteriorates the bending straightening property. Particularly, the S content of more than 0.05% significantly deteriorates the bending straightening property even if the compound-layer depth at the stress concentrated region is 5 m or less. Accordingly, the Al content is set to be 0.05% or less. The Al content is preferably 0.03% or less.

(21) Cr: less than 0.20%

(22) Cr is an impurity contained in the steel. Containing Cr may excessively increase the surface-layer hardness, which deteriorates the bending straightening property; thus it is preferable to set the Cr content to be as small as possible. Accordingly, the Cr content is set to be less than 0.20%. The Cr content is preferably 0.10% or less.

(23) Another of the steel materials of the base metal of the non-thermal refined soft-nitrided component according to the present invention contains one or more types of elements selected from Cu, Mo, Ni, and Ti instead of part of Fe.

(24) Each operational effect of Cu, Mo, Ni, and Ti that are optional elements, and a reason for limitation of each content will be described, hereinafter.

(25) Cu and Mo may be contained for the purpose of enhancing the bending fatigue strength. Detailed description regarding this will be provided as below.

(26) Cu: 0 to 1.0%

(27) Cu is an element to improve the internal hardness, and enhance the bending fatigue strength. Hence, Cu may be contained. However, the Cu content of more than 1.0% deteriorates hot workability. Accordingly, the amount of Cu to be contained is set to be 1.0% or less. The amount of Cu is preferably 0.4% or less, and more preferably 0.3% or less.

(28) In order to stably attain the above effect, it is preferable to set the amount of Cu to be 0.05% or more, and more preferably 0.1% or more.

(29) Mo: 0 to 0.3%

(30) Mo has an action to strengthen ferrite, and improve the internal hardness to enhance the bending fatigue strength. Hence, Mo may be contained. However, an excessive Mo content of more than 0.3% rather saturates the above effect, only to deteriorate economic efficiency. Accordingly, the amount of Mo to be contained is set to be 0.3% or less. The amount of Mo is preferably 0.2% or less.

(31) In order to stably attain the above effect, the amount of Mo is preferably 0.05% or more, and more preferably 0.1% or more.

(32) Any one type selected from Cu and Mo, or two types selected from Cu and Mo in combination may be contained. The total content of these elements may be 1.30%, and preferably 0.30% or less.

(33) Ni and Ti may be contained for the purpose of enhancing the bending straightening property. Detailed description regarding this will be provided, hereinafter.

(34) Ni: 0 to 0.5%

(35) Ni is an element to improve toughness, and enhance the bending straightening property. Accordingly, Ni may be contained. However, the Ni content of more than 0.5% rather saturates the above effect, only to deteriorate the economic efficiency. Hence, the amount of Ni to be contained is set to be 0.5% or less. The amount of Ni is preferably 0.3% or less, and more preferably 0.2% or less.

(36) In order to stably attain the above effect, the amount of Ni is preferably 0.05% or more, and more preferably 0.08% or more.

(37) In the case of containing Cu, it is likely to cause hot cracking called Cu checking, and in order to prevent this, it is preferable to contain Cu in combination with Ni in a manner as to satisfy Ni/Cu0.5.

(38) Ti: 0 to 0.020%

(39) Ti is an element that forms nitride, and refines grains to hinder propagation of cracking during the bending-straightening, thereby enhancing the bending straightening property. Accordingly, Ti may be contained. However, the Ti content of more than 0.020% generates coarse nitride, and significantly deteriorates the bending straightening property even if the compound-layer depth at the stress concentrated region is 5 m or less. Accordingly, the amount of Ti to be contained is set to be 0.020% or less. The amount of Ti is preferably 0.015% or less.

(40) In order to stably attain the above effect, the amount of Ti is preferably 0.005% or more.

(41) Any one type selected from Ni and Ti, or two types selected from Ni and Ti in combination may be contained. The total content of these elements may be 0.520%, and preferably 0.30% or less.

(42) (B) Hardness (surface-layer hardness) at a position of 0.05 mm from the surface:

(43) In the non-thermal refined soft-nitrided component according to the present invention, the HV hardness at a position of 0.05 mm from the surface should be 400 to 480.

(44) It is possible to secure a high bending fatigue strength of 750 MPa or more if the HV hardness at a position of 0.05 mm from the surface of the non-thermal refilled soft-nitrided component, that is, the HV hardness in the surface layer is 400 or more, the HV hardness at a position of 1.0 mm from the surface of the component, that is, the HV hardness at the internal part is 200 or more, and the compound-layer depth at the stress concentrated region is 5 m or less. However, if the HV hardness in the surface layer is more than 480, in the case of using a crankshaft shape to likely cause a greater bending than that of a conventional art during the soft-nitriding, it may be hard to attain a practically sufficient bending straightening property even if the compound-layer depth at the stress concentrated region is 5 m or less.

(45) Accordingly, in the non-thermal refined soft-nitrided component according to the present invention, the HV hardness at a position of 0.05 mm from the surface is set to be 400 to 480. The HV hardness at a position of 0.05 mm from the surface is preferably 410 or more, and preferably 470 or less.

(46) (C) Hardness (internal hardness) at a position of 1.0 mm from the surface:

(47) In the non-thermal refined soft-nitrided component according to the present invention, the HV hardness at a position of 1.0 mm from the surface of the component should be 200 or more.

(48) In the non-thermal refined soft-nitrided component, since the endurance ratio of the base metal is lower than that in the thermal refined soft-nitrided component, the fatigue strength of the base metal becomes lower than that in the thermal refined soft-nitrided component even if the non-thermal refined soft-nitrided component has an internal hardness equivalent to that of the thermal refined soft-nitrided component. Consequently, in the non-thermal refined soft-nitrided component, in the case of having an HV hardness of less than 200 at the internal part, even if the non-thermal refined soft-nitrided component has an internal hardness equivalent to that of the thermal refined soft-nitrided component, and also has a surface-layer hardness as high as 400 or more in terms of the HV hardness, fatigue fractures initiated from the internal part may be caused, which makes it hard to attain a high fatigue strength of 750 MPa or more.

(49) Accordingly, in the non-thermal refined soft-nitrided component according to the present invention, the HV hardness at a position of 1.0 mm from the surface is set to be 200 or more. The HV hardness at a position of 1.0 mm from the surface is preferably 210 or more, and preferably 320 or less in the light of machinability.

(50) (D) Compound-layer depth at the stress concentrated region:

(51) In the non-thermal refined soft-nitrided component according to the present invention, the compound-layer depth at the stress concentrated region should be 5 m or less.

(52) By setting the compound-layer depth at the stress concentrated region to be thinner, it is possible to improve the bending straightening property without deteriorating the bending fatigue strength, but it is hard to expect significant improvement of the bending straightening property if the compound layer whose depth is more than 5 m still remains.

(53) Accordingly, in the non-thermal refined soft-nitrided component according to the present invention, the compound-layer depth at the stress concentrated region is set to be 5 m or less. The compound-layer depth at the stress concentrated region is preferably 3 m or less, and it is most preferable to have no compound layer, that is, have a compound-layer depth of 0 m.

(54) Such a component that satisfies the above (B) to (D) can be obtained by machining a hot forging that satisfies the chemical composition specified by the present invention, for example, and thereafter, subjecting the machined hot forging to the soft-nitriding treatment to retain this hot forging for two hours in an atmosphere where an RX gas and an ammonia gas are mixed at a mixture ratio of 1:1 at a temperature of 600 C., and then cooling the machined hot forging in an oil having a temperature of 90 C., and subsequently, grinding the stress concentrated region through machining using a lapping machine or the like.

(55) The above mentioned RX gas is one type of a modified gas, and represents a brand name of this gas.

(56) Specifically, representing a crankshaft as an example of the non-thermal refined soft-nitrided component, for example, this crankshaft can be obtained in such a manner that a starting material that satisfies conditions on the chemical composition specified by the present invention is hot-forged into a crankshaft, this crankshaft is machined, and thereafter this crankshaft is subjected to the soft-nitriding treatment to retain the crankshaft for two hours in an atmosphere where an RX gas and an ammonia gas are mixed at a mixture ratio of 1:1 at a temperature of 600 C., and then cooled in an oil having a temperature of 90 C., and subsequently, the pin fillet section and the journal fillet section are ground through machining using a lapping machine or the like.

(57) The present invention will be described in more detail using Example, hereinafter.

EXAMPLE

(58) Each of Steels A to K having respective chemical compositions shown in Table 1 was melt in a 70 t convertor, subjected to continuous casting, and further subjected to blooming into a cast piece having a cross sectional dimension of 180 mm180 mm.

(59) Subsequently, each cast piece was hot-forged under the conditions that a heating temperature was 1200 C., and a finishing temperature was 1000 to 1050 C. into a steel bar having a diameter of 90 mm Each steel bar after the hot-forging was cooled in the atmosphere down to a room temperature through allowing cooling.

(60) In Table 1, each of Steels A to G is an example having chemical composition within the range specified by the present invention, and each of Steels H to K is an example having chemical composition out of the range specified by the present invention.

(61) TABLE-US-00001 TABLE 1 Chemical composition (mass %) Balance: Fe and impurities Steel C Si Mn P S Cu Ni Cr Mo Al Ti N A 0.27 0.20 2.70 0.015 0.084 0.06 0.012 0.0055 B 0.36 0.14 2.25 0.020 0.042 0.14 0.024 0.0063 C 0.30 0.25 2.50 0.014 0.060 0.07 0.019 0.010 0.0150 D 0.32 0.18 2.42 0.011 0.055 0.20 0.18 0.008 0.0095 E 0.29 0.15 2.10 0.010 0.077 0.10 0.14 0.011 0.0063 F 0.32 0.14 2.48 0.012 0.061 0.18 0.08 0.18 0.010 0.0085 G 0.31 0.21 2.10 0.011 0.062 0.12 0.10 0.008 0.0145 H *0.10 0.12 2.20 0.022 0.045 0.10 0.009 0.0101 I 0.37 0.11 *1.25 0.010 0.044 0.11 0.005 0.0122 J 0.32 0.20 *3.20 0.019 0.055 0.14 0.012 0.0063 K 0.33 0.18 2.52 0.014 0.060 *0.34 0.022 0.0050 A mark (*) represents deviation from the chemical composition specified by the present invention.

(62) Each steel bar having a diameter of 90 mm obtained in this manner was heated up to a temperature of 1200 C., and then hot-forged at a finishing temperature of 1000 to 1050 C. into a steel bar having a diameter of 50 mm. Each finished steel bar was cooled down to a room temperature through allowing cooling in the atmosphere.

(63) Some of the steel bars, each having a diameter of 50 mm in Steel A were further subjected to a normalizing treatment to austenitize the steel bar under the conditions that a heating temperature is 880 C., and a retaining time period is 60 minutes, and subsequently, cool the steel bar in the atmosphere through allowing cooling.

(64) In each of Steels A to K, a grooved Ono-type rotating bending fatigue test specimen having a shape shown in FIG. 2 was cut out in parallel to the forging axis from an R/2 part (R represents a radius of a steel bar) of each steel bar as hot-forged having a diameter of 50 mm, and a four-point bending test specimen having a shape shown in FIG. 3 was also cut out in the same manner as this grooved Ono-type rotating bending fatigue test specimen.

(65) Similarly, in Steel A, a grooved Ono-type rotating bending fatigue test specimen having the shape shown in FIG. 2 was cut out in parallel to the forging axis from the R/2 part of each steel bar having a diameter of 50 mm, which was further subjected to the normalization, and a four-point bending test specimen having a shape shown in FIG. 3 was also cut out in the same manner as this grooved Ono-type rotating bending fatigue test specimen.

(66) In the test specimen in FIG. 2, the groove bottom of the R3 is equivalent to the stress concentrated region. Similarly, in the test specimen in FIG. 3, the notch bottom of the R3 is equivalent to the stress concentrated region.

(67) Each grooved Ono-type rotating bending fatigue test specimen and each four-point bending test specimen, which were obtained in the above manner, were respectively subjected to the soft-nitriding treatment to retain each test specimen for two hours in an atmosphere where the RX gas and the ammonia gas are mixed at a mixture ratio of 1:1 at a temperature of 600 C.; and thereafter, was cooled in the oil having a temperature of 90 C.

(68) In Test No. 1 to Test No. 12, subsequent to the soft-nitriding treatment, electrolytic grinding was further carried out at the groove bottom of each grooved Ono-type rotating bending fatigue test specimen, and at the notch bottom of each four-point bending test specimen, with a target grinding depth of 0.03 mm under the following conditions. Electrolytic solution: perchloric acid (HClO.sub.4): acetic acid (CH.sub.3COOH)=1:9 Current value: 0.14 A Grinding area: Ono-type rotating bending fatigue test specimen: 160 mm.sup.2 Four-point bending test specimen: 96 mm.sup.2 Grinding time period: Ono-type rotating bending fatigue test specimen: 970 seconds Four-point bending test specimen: 590 seconds [0092]

(69) In Test No. 14 to Test No. 16, subsequent to the soft-nitriding treatment, electrolytic grinding was further carried out at the groove bottom of each grooved Ono-type rotating bending fatigue test specimen, and the notch bottom of each four-point bending test specimen, with a target grinding depth of 0.015 mm under the following conditions. Electrolytic solution: perchloric acid (HClO.sub.4): acetic acid (CH.sub.3COOH)=1:9 Current value: 0.14 A Grinding area: Ono-type rotating bending fatigue test specimen: 160 mm.sup.2 Four-point bending test specimen: 96 mm.sup.2 Grinding time period: Ono-type rotating bending fatigue test specimen: 490 seconds Four-point bending test specimen: 300 seconds

(70) Using the specimens as soft-nitrided (Test No. 13) and the specimens further subjected to the electrolytic grinding after the soft-nitriding treatment (Test No. 1 to Test No. 12, and Test No. 14 to Test No. 16) obtained in the above manner, a study of the bending fatigue strength by the Ono-type rotating bending fatigue test, and a study of the bending straightening property by the four-point bending test were respectively carried out.

(71) In addition, using the specimens as soft-nitrided (Test No. 13) and the specimens subjected to the electrolytic grinding after the soft-nitriding treatment (Test No. 1 to Test No. 12, and Test No. 14 to Test No. 16) for the Ono-type rotating bending fatigue test and the four-point bending test, the surface-layer hardness (i.e., hardness at a position of 0.05 mm from the surface of each specimen), and the internal hardness (i.e., hardness at a position of 1.0 mm from the surface of each specimen) as well as the compound-layer depth at the notch bottom were studied, respectively.

(72) The details of each study will be described, hereinafter.

(73) (1) Study of Bending Fatigue Strength:

(74) The Ono-type rotating bending fatigue test was carried out at a room temperature, in the atmosphere, under completely reversed bending at a rotational rate of 3000 rpm so as to study the bending fatigue strength (referred to as w, hereinafter).

(75) The target w was set to be 750 MPa or more.

(76) (2) Study of Bending Straightening Property:

(77) A strain gauge of 2 mm was adhesively bonded to the notch bottom of each four-point bending test specimen, and bending-straightening strain was applied to this specimen until the gauge was broken. A read value of the gauge at the moment when the gauge was broken was evaluated as the bending straightening property.

(78) The target value of the bending straightening property was set to be 22000 (equivalent to the bending-straightening strain of 2.2%) or more.

(79) (3) Surface-Layer Hardness and Internal Hardness:

(80) Each Ono-type rotating bending fatigue test specimen was embedded in resin in a manner as to set a groove-bottom longitudinal sectional portion at the R3 to be a target surface to be examined, and each four-point bending test specimen was embedded in resin in a manner as to set a notch-bottom longitudinal sectional portion at the R3 to be a target surface to be examined, and then, each target surface was polished to be mirror-finished; and subsequently, the surface hardness and the internal hardness were respectively studied on the target surface of each specimen using a Vickers hardness meter.

(81) Specifically, in conformity to the Vickers hardness testTest method described in HS Z 2244, the HV hardness at any six points at a position of 0.05 mm and at any six points at a position of 1.0 mm from the 3R of the groove bottom, and the HV hardness at any six points at a position of 0.05 mm and at any six points at a position of 1.0 mm from the 3R of the notch bottom were respectively measured for each specimen with a test force of 2.94N using a Vickers hardness meter, and the measured values were arithmetically averaged to evaluate the surface-layer hardness and the internal hardness, respectively.

(82) (4) Compound-Layer Depth:

(83) The compound-layer depth was studied using each of the test specimens embedded in the resin that were used in the above (3).

(84) Specifically, each test specimen embedded in the resin was polished once again, etched with nital, and then any five visual fields at the groove bottom of the R3 and any five visual fields at the notch bottom of the R3 were respectively observed with an optical microscope with magnification of 400; and portions observed to be white were determined as the compound layers, and the depths of these layers were measured, and arithmetically averaged as the compound-layer depth.

(85) Results of the above studies are all shown in Table 2.

(86) TABLE-US-00002 TABLE 2 Grooved Ono-type rotating bending fatigue test specimen Four-point bending test specimen Compound- Surface-layer Internal Compound- Surface-layer Internal Bending Test layer depth hardness hardness w layer depth hardness hardness straightening No. Steel Normalizing (m) (HV hardness) (HV hardness) (MPa) (m) (HV hardness) (HV hardness) property () 1 A No 1 458 234 820 1 456 233 26000 2 B No 3 418 243 800 3 415 240 31700 3 C No 0 434 237 810 0 430 235 29400 4 D No 2 458 245 820 2 461 244 25500 5 E No 0 418 220 790 0 414 220 32000 6 F No 0 464 246 830 0 462 246 25100 7 G No 2 453 229 820 2 455 228 26700 8 A Yes 1 428 214 770 1 427 212 30200 9 *H No 2 457 #187 #690 2 460 #189 26100 10 *I No 1 #332 203 #600 1 #333 202 44000 11 *J No 1 #526 271 840 1 #520 274 #16200 12 *K No 3 #520 254 840 2 #518 255 #17100 13 B No #19 448 242 820 #20 443 242 #15400 14 C No #12 455 236 810 #11 449 236 #18700 15 F No #9 480 246 820 #8 480 244 #16400 16 G No #8 471 230 820 #8 470 231 #12000 Normalizing conditions are such that the heating temperature: 880 C., and the retaining time period: 60 minutes. A mark (*) represents deviation from the chemical composition specified by the present invention. A mark (#) represents that the value does not satisfy the target value.

(87) As shown in Table 2, in the cases of Test No. 1 to Test No. 8 that satisfy the conditions specified by the present invention in the chemical composition of the steel material of the base metal, the surface-layer hardness, the internal hardness, and the compound-layer depth at the stress concentrated region, it is apparent that the target values of the w and the bending straightening property were both satisfied, and these cases are excellent in bending fatigue characteristics and bending straightening property.

(88) To the contrary, in the cases of Test No. 9 to Test No. 12, the respective chemical compositions of Steel H to Steel K deviate from the conditions specified by the present invention, and thus these cases are poorer in bending fatigue characteristics or bending straightening property.

(89) Specifically, in the case of Test No. 9, the C content of Steel H that is the steel material of the base metal is less than the range specified by the present invention. Consequently, the internal hardness of the Ono-type rotating bending fatigue test specimen is as low as 187 in terms of the HV hardness, and the w does not satisfy the target value of 750 MPa or more; thus this case is poor in bending fatigue characteristics.

(90) In the case of Test No. 10, the Mn content of Steel I that is the steel material of the base metal is less than the range specified by the present invention. Consequently, the surface-layer hardness of the Ono-type rotating bending fatigue test specimen is as low as 332 in terms of the HV hardness, and the w does not satisfy the target value of 750 MPa or more; thus this case is poor in bending fatigue characteristics.

(91) In the case of Test No. 11, the Mn content of Steel J that is the steel material of the base metal is more than the range specified by the present invention. Consequently, although the compound-layer depth is as small as 1 m, the surface-layer hardness of the four-point bending test specimen is as high as 520 in terms of the HV hardness, and the bending straightening property does not satisfy the target value of 22000 or more in terms of the read value of the gauge; thus this case is poor in bending straightening property.

(92) In the case of Test No. 12, the Cr content of Steel K that is the steel material of the base metal is more than the range specified by the present invention. Consequently, although the compound-layer depth is as small as 2 m, the surface-layer hardness of the four-point bending test specimen is as high as 518 in terms of the HV hardness, and the bending straightening property does not satisfy the target value of 22000 or more in terms of the read value of the gauge; thus this case is poor in bending straightening property.

(93) In the cases of Test No. 13 to Test No. 16, the compound-layer depth of the four-point bending test deviates from the condition specified by the present invention; thus these cases are poor in bending straightening property.

(94) In the case of Test No. 13, although Steel B that is the steel material of the base metal has chemical composition within the range specified by the present invention, the compound-layer depth of the four-point bending test specimen is as high as 20 m, and the bending straightening property does not satisfy the target value of 22000 or more in terms of the read value of the gauge; thus this case is poor in bending straightening property.

(95) In the case of Test No. 14, although Steel C that is the steel material of the base metal has chemical composition within the range specified by the present invention, the compound-layer depth of the four-point bending test specimen is as high as 11 m, and the bending straightening property does not satisfy the target value of 22000 or more in terms of the read value of the gauge; thus this case is poor in bending straightening property.

(96) In the case of Test No. 15, although Steel F that is the steel material of the base metal has chemical composition within the range specified by the present invention, the compound-layer depth of the four-point bending test specimen is as high as 8 m, and the bending straightening property does not satisfy the target value of 22000 or more in terms of the read value of the gauge; thus this case is poor in bending straightening property.

(97) In the case of Test No. 16, although Steel G that is the steel material of the base metal has chemical composition within the range specified by the present invention, the compound-layer depth of the four-point bending test specimen is as high as 8 m, and the bending straightening property does not satisfy the target value of 22000 or more in terms of the read value of the gauge; thus this case is poor in bending straightening property.

INDUSTRIAL APPLICABILITY

(98) The non-thermal refined soft-nitrided component of the present invention is excellent in bending straightening property after the soft-nitriding treatment, and has a bending fatigue strength as high as 750 MPa or more in the bending fatigue test; therefore, this non-thermal refined soft-nitrided component is usable as a component, such as a crankshaft, in automobiles, industrial machines, or construction machinery, and this component is capable of attaining reduction in weight and size.