Method and device for producing containers filled with a liquid filling material

Abstract

A method and device for producing containers filled with a liquid filling material from preforms made of a thermoplastic material, wherein the respective preform is at least thermally conditioned and subsequently re-formed during a forming and filling phase into the container with at least one liquid filling material as a pressure medium having a filling pressure p.sub.2. The filling material or portions of the filling material is/are supplied at at least two points in time and/or during at least two process phases having different carbon dioxide contents and/or different temperatures. The filling pressure p.sub.2 of the container formed in the first process phase is reduced to a pressure p.sub.1 and filling material is supplied in the second process phase, after which the pressure of the container is reduced to atmospheric pressure p.sub.0. In the first process phase filling material that has been previously degassed and/or uncarbonated is supplied.

Claims

1. A method for producing containers filled with a liquid filling material from preforms made of a thermoplastic material, the method comprising the steps of: thermally conditioning a respective preform and subsequently transforming the preform during a forming and filling phase in a mold with at least one liquid filling material as a pressure medium with a filling pressure p.sub.2 into the container, wherein the filling material or portions of the filling material are supplied at least at two points in time and/or in at least two process phases with different carbon dioxide contents and/or with different temperatures, wherein the container formed in a first of the process phases is relieved from the filling pressure p.sub.2 to a pressure p.sub.1 and the filling material is supplied in a second of the process phases, after which the container is relieved to atmospheric pressure p.sub.0 and wherein in the first process phase previously degassed and/or uncarbonated filling material is supplied.

2. The method according to claim 1, including guiding the preform during transformation into the container at least temporarily via a stretching bar and stretching the preform in an axial direction.

3. The method according to claim 1, including supplying the filling material in the second process phase in gaseous and/or liquid and/or solid phase.

4. The method according to claim 3, wherein the filling material is syrup and/or dry ice.

5. The method according to claim 2, wherein in the second process phase chronologically following the first process phase the filling material or the portion of filling material with a higher concentration of carbon dioxide is supplied.

6. The method according to claim 5, including cooling the filling material or the portion of filling material with the higher concentration of carbon dioxide before introduction and/or in the second process phase the filling material or the portion of filling material with the higher concentration of carbon dioxide has a lower temperature than the filling material or the portion of filling material of the first process phase.

7. The method according to claim 1, wherein the carbon dioxide content of the filling material or of the portion of filling material in the second process phase is 30% in weight greater than the carbon dioxide content of the filling material or of the portion of filling material of the first process phase.

8. The method according to claim 7, wherein the carbon dioxide content of the filling material or of the portion of filling material in the second process phase is 50 to 100% in weight greater than the carbon dioxide content of the filling material or of the portion of filling material of the first process phase.

9. The method according to claim 1, wherein the temperature of the filling material or of the portion of filling material of the second process phase is less than 10 C.

10. The method according to claim 9, wherein the temperature is between 4 and 8 C.

11. The method according to claim 6, wherein the pressure during the forming and filling phase or during the transformation process of the filling material or of the portion of filling material with the higher carbon dioxide concentration and/or the lower temperature, is at least temporarily higher than the pressure of at least one other or of a residual portion of filling material by at least 1 bar.

12. The method according to claim 11, wherein the pressure on a section of the liquid path is higher than the pressure of the filling material or of the portion of the filling material which has the higher carbon dioxide concentration and/or the lower temperature, and during the forming and filling phase or during the shaping process is at least temporarily higher by 2 bars to 5 bars than the pressure of at least one other or a residual portion of the filling material.

13. The method according to claim 11, including providing a throttle element or a narrowing cross-section in a flow path of the filling material or of the portion of the filling material flowing inside the stretching rod, wherein the throttle element is arranged close to at least one filling material outlet.

14. The method according to claim 2, wherein a portion of the filling material is guided past the stretching rod and a portion of the filling material is guided through the stretching rod.

15. The method according to claim 2, wherein the filling material with a higher concentration of carbon dioxide or the portion of said filling material are cooled and/or at least the filling material with the higher concentration of carbon dioxide or the portion of said filling material are guided through the stretching rod.

16. The method according to claim 2, wherein the stretching rod is thermally insulated at least in certain sections with respect to the filling material.

17. The method according to claim 1, wherein the process phases are partial phases of the forming and filling phase.

18. A device for producing containers filled with a liquid filling material from preforms made of a thermoplastic material, comprising: a heating device for preheating the preforms; at least one forming and filling station including a mold; at least one supply device to provide the filling material; and a carbonation unit for introducing or dissolving carbon dioxide at least into a partial flow of the filling material, wherein said at least one forming and filling station includes at least one valve arrangement via which the filling material or portions of the filling material are conveyed, at least at two points in time or in at least two process phases with different carbon dioxide contents, to a respective preform or to a respective container in formation, wherein in a first of the process phases previously degassed and/or uncarbonated filling material is supplied.

19. The device according to claim 18, wherein the forming station has a guiding device configured as a stretching rod acting at least temporarily upon the preform during transformation into the container and at least one portion of the filling material being conveyed through a cavity of the stretching rod, outlet openings are provided at least at a lower end of the stretching rod.

20. The device according to claim 19, wherein said at least one forming and filling station has at least one valve arrangement via which the filling material or portions of the filling material are conveyed at least at two points in time or in at least two process phases with various carbon dioxide contents and/or with various temperatures to a respective preform or to a respective container in formation.

21. The device according to claim 18, further comprising a cooling unit provided along a conduit or a conduit section for the filling material in which downstream, after cooling and flowing through the conduit or the conduit section, carbon dioxide is dissolved or which flows towards the conduit or towards the conduit section from the carbonation unit.

22. The device according to claim 21, wherein at least a conduit section in which the filling material or the portion of the filling material with the high CO.sub.2 content is guided is insulated and/or at least the conduit section in which the filling material or the portion of the filling material with the high CO.sub.2 content is guided, is cladded with an insulation.

23. The device according to claim 22, wherein the insulation is Teflon or a Teflon-containing material.

Description

BRIEF DESCRIPTION OF THE DRAWING

(1) The invention is described more in detail below in the light of the figures illustrating exemplary embodiments. The figures are as follows:

(2) FIG. 1 is a diagrammatical illustration of a basic configuration of a device or forming and filling machine to perform the hydraulic formation of containers by using a filling material,

(3) FIG. 2 shows a diagrammatical longitudinal section through a preform with a partially inserted stretching rod as well as a venting system,

(4) FIG. 3 shows a diagrammatical longitudinal section through a formed container with a partially inserted stretching and filling device,

(5) FIG. 4 shows a longitudinal section through a forming and filling device or station in a modified embodiment,

(6) FIG. 5 shows a longitudinal section through a forming and filling device or station with a seal to prevent dripping,

(7) FIG. 6 shows an embodiment with controllable supply of the filling material and separately controllable venting,

(8) FIG. 7 shows a diagrammatical illustration of a combined forming, filling and closing device or station and

(9) FIG. 8 shows another embodiment of the combined forming, filling and closing device or station according to FIG. 7,

(10) FIGS. 9-11 show a diagrammatical sectional view of a further embodiment of the stretching rod of a forming and filling machine or station according to the invention in different process phases;

(11) FIG. 12 show in a similar representation to FIGS. 10-12 a further modified embodiment of the stretching rod of the forming and filling machine or station according to the invention,

(12) FIG. 13 shows a block diagram of an embodiment of a method according to the invention.

DETAILED DESCRIPTION OF THE INVENTION

(13) The general configuration of a combined forming and filling device or machine is represented in FIG. 1. Preforms 2 are conveyed from a feeding device 1, by using a transfer wheel 3, from a heating device 4. In the region of the heating device 4, in which the preforms 2 are preheated or thermally conditioned, the preforms 2 can be transported, depending on the application, for example with their mouth sections 5 upwards in vertical direction or downwards in vertical direction. The heating device 4 can for example be fitted with heating elements 6, which are arranged along a transport device 7. A rotating chain for example can be used as a transport device 7. IR or NIR radiators as well as other energy-emitting radiators are for example appropriate as heating elements 6.

(14) After sufficient tempering (also thermal conditioning), the preforms 2 are transferred by a transfer wheel 8 to a rotor or process wheel 9 which can be driven to rotate around a vertical machine axis or to forming and filling stations 10 arranged on the rotor or process wheel 9. The process wheel 9 is fitted with a plurality of such forming stations 10, in the region of which the preforms 2 are transformed into the diagrammatically represented containers 11, as well as the containers 11 are filled with the filling material provided. Every container 11 is formed at the same time as it is filled whereby the filling material serves as a pressure medium during the forming process.

(15) After forming and filling, the containers 11 are transported away from the process wheel 9 by an extraction wheel 12 and conveyed to an output line 13.

(16) According to the embodiment of FIG. 1, diagrammatically represented closing members 15 are supplied to the process wheel 9 via a feeding device 14. It is thus possible to close hermetically the containers 11 on the process wheel 9 and to manipulate fully formed, filled and closed containers 11 by using the extraction device 12. The closing member 15 may be designed for example as a screw-on closure cap, as a crown cap or as a seal film.

(17) Preferably various thermoplastic materials can be used as a material for the preforms 1. By way of example, we may quote polyethylene terephthalate (PET), polyethylene (PE), polyethylene naphthalate (PEN) or polypropylene (PP). The dimensioning as well as the weight of the preforms 2 can be adapted to the size, the weight and/or the design of the containers 11 to be manufactured.

(18) A plurality of electrical and electronic components is arranged typically in the region of the heating device 4. Moreover, the heating elements 6 are fitted with moisture-sensitive reflectors. As the containers are filled and formed in the region of the process wheel 9 by using the liquid filling material, it must be ensured that any unintentional ingress of moisture into the region of the heating device 4 is prevented. This can for instance be in the form of a partitioning 16 which at least provides a splashguard. Moreover, it is also possible to temper the transport elements for the preforms as appropriate in the region of the transfer wheel 8 or to act upon them with thrusts of compressed gas in such a way that any adhering moisture cannot reach into the region of the heating device 4.

(19) The preforms 2 and/or the containers 11 can be manipulated preferably using claws and/or clamping or plug-in elements acting upon the mouth section 5 at least in certain areas from the inside or from the outside.

(20) FIG. 2 shows a longitudinal section through a preform 2 into which a stretching bar or a stretching rod 17 is inserted. The stretching rod 17 serves for at least temporary guiding of the preform 2 during its transformation to the container 11. Typically, there is a contact between a point 18 of the stretching rod 17 and a bottom 19 of the preform 2. The preform 2 is stretched longitudinally when the stretching rod 17 penetrates further into the preform 2. Upon completion of the stretching cycle or at least temporarily during the performance of the stretching cycle, the filling material 21 extracted from a supply device 20 is conveyed into the preform 2.

(21) The filling material 21 is metered by using a multi-way metering valve 22. In the exemplary embodiment represented, the stretching rod 17 is at least in certain areas hollow or has a duct and the filling material 21 is conveyed to a cavity of the stretching rod 17. The region of a wall of the stretching rod 17 includes outlet openings 24 which can be shut off by a return valve 25 with respect to the multi-way metering valve 22. This enables to avoid or to minimize unintentional dripping of the filling material 21 from the stretching rod 17.

(22) The preform 2 can be vented by using a venting valve 26. The venting valve 26 is connected to an outlet opening 27 which is arranged in the region of a connecting element 28 acting upon the preform 1. The stretching rod 17 can be positioned through the connecting element 28. The preform 2 is sealed by a gasket 29 with respect to the connecting element 28, which can be in the form of an O-ring for instance. A cavity 30 of the preform can be connected to the outlet opening 27 via an annular slit 31. To do so, the annular slit 31 surrounds the stretching rod 17.

(23) FIG. 3 shows diagrammatically a similar device as in the illustration according to FIG. 2 by using a hollow stretching rod 17 with a built-in return valve 25. An already fully formed container 11 is however represented. FIG. 2 as well as FIG. 3 clearly show that preferably a plurality of outlet openings 24 is arranged in the region of the stretching rod 17. With the exemplary embodiment represented, such outflow openings 24 are positioned at different height levels along a longitudinal axis 32 of the stretching rod 17. Likewise, the exemplary embodiment represented shows an orientation of the outflow openings 24 with a substantially horizontal outlet direction. The arrangement of the outlet openings 24 in the region of the stretching rod 17 as well as the orientation of the outlet openings 24 can be varied. The aim is to provide typically the quietest and the most splash-free outflow behavior.

(24) According to the embodiment of FIG. 4, a massive stretching rod 17 is used. The filling material 21 is supplied along at least a flow duct past the stretching rod 17. Preferably, the annular slit 31 is used to do so. Also with this embodiment, it is possible to perform a targeted ventilation.

(25) FIG. 5 shows an embodiment with a stretching rod 17 possessing an optimized form to prevent any dripping. A sealing element 33 is therefore arranged in the region of the tip 17. The sealing element 33 can for example be provided by enlarging the diameter of the stretching rod 17. Likewise, an appropriate selection of materials can be envisaged. When retracting the stretching rod 17 from the container, the sealing element 33 enters into contact with a counter element 34 which is arranged in the region of the connecting element 28. The counter element 34 is preferably designed as a gasket. The outlet openings 24 of the stretching rod 17 are arranged separately and sealed from the container 11 after appropriate positioning of the stretching rod 17 so that dripping from the cavity 23 of the stretching rod 17 can be avoided reliably. Typically, at least one bearing 35 is arranged in the region of the connecting element 28 for guiding the stretching rod 17.

(26) FIG. 6 shows a form of embodiment in which again a massive stretching rod 17 is used. The multi-way metering valve 22 for the filling material 21, as well as the venting valve 26, are connected to the cavity 30 of the preform 2 or of the container 11 via flow ducts running past the stretching rod 17, in particular through the annular slit 31. In the exemplary embodiment represented, the outlet opening 27 is arranged in a radial direction of the connecting element 28 opposite to a supply opening 36 which is connected to the multi-way metering valve 22.

(27) FIG. 7 shows an embodiment in which the containers 11 are also closed hermetically in the region of the process wheel 9 according to FIG. 1. The container 11 is still arranged in the region of a mould 37 which forms a portion of the forming station 10 according to FIG. 1. A closing device 38 is arranged coaxially to the connecting element 28 with respect to the longitudinal axis 32 in this embodiment. The closing device 38 includes for example grippers 39 mounted pivotably which are provided for acting upon the closing element 15. The idea behind that in particular is to arrange the closing device 38 rotatably with respect to the connecting element 28. Thereby, the closing member 15 can be screwed with an internal thread on an external thread of the mouth section 5.

(28) FIG. 8 shows an alternative form of embodiment for the construction according to FIG. 7. The closing device 38 and the connecting element 28 are here not arranged coaxially relative to one another but are positioned by a tool carrier alternately in a working arrangement or in a resting arrangement. The tool carrier 40 can be designed for example in a revolver-type arrangement and be fitted with a rotational axis 41.

(29) Certain process-typical parameters are for example described more in detail below. The filling material 21 is supplied to the connecting element 28 preferably with a temperature of the surrounding room, for example in the range of 20 C. to 30 C. The filling material 21 thereby cools the material of the container 11 and supports a rapid form stability of the formed container 11. This provides a very short cycle time. Likewise, it is also possible to supply the filling material 21 once it has been cooled or heated up more strongly.

(30) During the forming of the container 11, the filling material can be introduced at least temporarily with a constant volume flow rate into the preform 2 or into the container 11. But it is also possible to provide for the volume flow rate an appropriate temporal profile in such a way that different volume flow rates are generated at different points in time.

(31) Before introducing the filling material 21 it is possible to suck away the air situated inside the preform 1 and/or to replace it with an inert gas. This is particularly recommended with oxidation-sensitive filling media 21.

(32) Either pure liquids can be used as a filling material 21, preferably previously degassed water for the first process phase, or liquids provided with additives. The supply of carbonized filling media is considered in particular, which are supplied in the second process phase. Since the filling material 21 is supplied to the preform 1 or to the container 2 under pressure, for instance with a pressure of 10 bars, it appears appropriate to design all the flow paths for the filling material 21 in such a way that local decompressions are prevented by the flow processes. Otherwise, a local or temporary decompression could lead to outgassing of the carbon dioxide.

(33) Alternatively to the heating represented in FIG. 1 of preferably injection-molded preforms 2, it is also possible to produce the preforms 2 immediately before their transformation into the containers 11. This can be realized for example using an injection-molding process as in a so-called single-stage injection blow method; a compression forming process is likewise possible. Such a forming of the preforms 2 avoids using electrical and electronic components in the region of a heating device or at least reduces substantially the extent of use of such parts since the latter are only required for possibly necessary temperature profiling.

(34) Corrosion-resistant substances are preferably used as materials for the components of the process wheel 9, in particular stainless steels as well as plastics. In particular, the moulds 37 can be made totally or partially out of an appropriate plastic.

(35) In order to minimize the necessary stretching forces it is possible to support the stretching cycle by the supply of the filling material 21. When supporting the stretching cycle in this way, it must however be assured that the preform 2 is guided by the stretching rod 17. The operation may for instance consist in measuring the acting stretching force and in controlling the volume flow rate of the filing material 21 in such a way that a minimum stretching force is always maintained. The magnitude of the stretching force can be determined in particular quite easily with electrically driven stretching systems by measuring the drive current or with pneumatic stretching systems by measuring the pressure.

(36) When filling containers 11 with the filling material 21 it is often desirable to provide a gas-filled headroom after closing the container hermetically 11. Said free headroom can be generated by the volume reduction which results from the retraction of the stretching rod 17.

(37) The selection of materials already mentioned above takes given hygiene requirements into account. Degermination or sterilization can thus be guaranteed. The construction design shall be carried out in such a way that the requirements in good cleanability are fulfilled.

(38) One or several of the transfer wheels can be fitted with servo drives.

(39) This supports in particular a complete separation of the heating device 4 from the process wheel 9 during cleaning cycles. Likewise, in the region of at least one of the transfer wheels retractable manipulation elements may be arranged. The use of a dry air tunnel can provide a further protection against moisture.

(40) By way of example, a concrete process flow is described below. Before or after inserting the preform 2 into the mould 37, there is first of all a gas exchange in the cavity of the preform, in order to repel oxygen in particular or to reduce the portion of oxygen. The flushing and/or exhaust cycle lasts typically at most 0.1 second. The stretching of the preform 2 by using the stretching rod 17 lasts typically approx. 0.2 second. Likewise, a time span of approx. 0.2 second is provided for the filling and the resulting transformation of the preform 2 into the container 11. A maximum time span of 0.2 second is typically required for the subsequent creation of a headroom. The container filled with still beverages can be calmed down and relieved from pressure extremely fast, whereas with carbonated beverages, this cycle can take a time span of up to 5 seconds.

(41) The headroom can be treated subsequently for example by using a high-pressure foaming or by feeding oxygen. The subsequent supply of a closing cap can take a time span of up to 1.5 seconds with carbonated beverages. Likewise, the closing or screwing cycle takes for instance a time span of 1.5 seconds.

(42) Once the container 11 has been closed hermetically, the mould opens and the filled container 11 is removed and transported away.

(43) When inserting the filling material into the preform 2 to be transformed or into the container 11 still in the forming process there is usually a typical pressure gradient in the filling system or in the preform 2 or more precisely the container 11 still in the forming process. Due to the expansion of the container 11, there is first of all a relatively low pressure which increases till the end of the forming cycle. The corresponding pressure rise or the height of the pressure rise in the filling system, in particular in the filling conduit, can be used as a control parameter for a following process step and if applicable determine the moment of introduction of said next process step. Alternately or in addition thereto, the characteristic of the pressure gradient and/or of the volume flow rate of the filling material can be used as control parameters.

(44) As regards the temperature of the filling material, the filling material may be conveyed with surrounding temperature. Depending on the respective conditions of application, instead of filling at surrounding temperature, a temperature increase or a temperature decrease can be contemplated.

(45) According to a further variation, the filling process may be implemented in two stages, whereas during the first process step the filling material is conveyed at a temperature which is higher than the temperature during the second process step. The first process step can for example be carried out when the longitudinal stretching of the preform 2 is performed over the stretching rod 11. The second process step follows the performance of the stretching cycle and corresponds to the transversal expansion of the container 11.

(46) During the aforementioned appeasement in the headroom after pressure relief, an aspiration of developing gases and/or foam may also be carried out, if applicable.

(47) As regards the closing of the finished formed and filled containers 11, different variations can also be realized. In a variation, it is possible to fit a portion of the manipulation or forming and filling stations 10 on the rotor or process wheel 9 with a revolver head. The revolver head includes on the one hand a blowing or forming and filling head and on the other hand a closing head. This corresponds to the diagrammatical representation of FIG. 8. Likewise, it is also contemplated to use an integrated construction with which the respective head carries out the blowing, the filling and the closing cycle.

(48) According to a further variation, the forming and filling head as well as the closing head are designed as separate components, but arranged to pivot at every forming and filing station 10. According to a third variation, only the forming and filling head is provided on the rotor or process wheel 9 and the container still open is transferred to a separate closing system, for example to a transport wheel, which is fitted with a closing head.

(49) The application of the closing elements 15, for instance of the closing caps, can take place immediately after opening the respective mould 37 and the gripping of the container 11 via a holding and gripping element. An advantageous variation consists in maintaining the mould 37 closed and hence to fix the container 11 in correct position, whereas only the mouth is released for a closing element. Said release takes place in moving the mould 37 either for an angular distance on a radially different position or in pivoting and/or moving the forming and filling head so that the container mouth is free for a closing element.

(50) To do so, the closing caps would be placed on the rotor or the process wheel 9. In particular, an inert gas may be applied to the mouth space of the filled container before positioning the closing elements 15.

(51) In the above description it was considered for simplifying purposes that only one supply device 20 is provided for the filling material 21. In fact, the forming and filling system or machine includes a further supply device 20.1 for an additional portion or a further component of the filling material, which exhibit a higher CO.sub.2 content than the filling material 21 and is designated below with 21.1.

(52) It has proved particularly advantageous to achieve stratification with the aforementioned methods and in particular with respect to the introduction of the portion or of the component of the filling material 21.1 with a CO.sub.2 content or with the higher CO.sub.2 content. It has namely appeared problematic in the case of a full or partial carbonization of the filling material, to obtain the rapid pressure relief after removal from the mould and filling of the containers 11, from the high forming and filling pressure up to the closing of the respective container for instance at ambient pressure without product loss. A massive foaming occurring here with product loss has prevented the use of this hydraulic transformation technique for CO.sub.2 containing products so far.

(53) According to a cognition underlying the invention, it is particularly advantageous to avoid such product losses if the filling material 21 or 21.1 or the portions of the filling material 21 or 21.1 are supplied at least at two points in time or in at least two process phases with different carbon dioxide contents and/or with different temperatures. To do so, it is appropriate in a second or subsequent process phase, to feed the filling material or the filling material component 21.1 with the higher concentration of carbon dioxide. This has the advantage that the filling material 21 and 21.1 in the generated container 11 commonly constitute the hydraulic pressure medium to form the container 11, but the filling material 21 already introduced in the developing container 11 has calmed down or has substantially calmed down and when introducing the filling material 21.1 or the portion of filling material 21.1 with the higher CO.sub.2 concentration, first of all further solution processes take place in the liquid volume. The second or subsequent process phase is thereby for instance a process phase completing the forming and filling phase. The introduction of the filling material 21.1 or of the portion of filling material 21.1 with the higher CO.sub.2 concentration is preferably stratified into the already present liquid volume, i.e. for instance in the region of the bottom of the developing container 11. The introduction of the filling material components or of the filling material 21 and 21.1 takes place in a controlled manner through the multi-way metering valve 22.

(54) A variation consists in cooling the filling material 21.1 or the portion of filling material 21.1 with the higher concentration of carbon dioxide before introduction, and that in the aforementioned second process phase introducing said filling material 21.1 or the corresponding portion with the higher concentration of carbon dioxide with a lower temperature than the filling material 21 or the portion of filling material 21 of the first process phase into the developing container 11. The result is a lower layer with a filling material rich in CO.sub.2, whereas a foaming, also a foaming during the relieving process is decreased to the extent that disadvantageous product losses do not occur.

(55) Therefore, the carbon dioxide content in the second process phase should be 30% in weight above the carbon dioxide content during the first process phase, in particular 50% in weight to 100% in weight above the carbon dioxide content in the first phase. Ideally, during the first or initial process phase, a quiet, i.e. a filling material component free from CO.sub.2, such as the filling material 21 and during the second process phase a filling material component rich in CO.sub.2, i.e. the filling material 21.1, are introduced into the developing container 11.

(56) There is an alternative in which the temperature of the filling material 21 or of the portion of filling material 21.1 of the second process phase is cooled, in which it is at least 10 C. below the temperature of the first or a previous process phase, and in particular is smaller than 10 C. and ideally ranges between 4 C. and 8 C.

(57) It has appeared advantageous that the pressure of the filling material 21 or of the portion of filling material 21.1, which exhibits the higher carbon dioxide concentration and/or the lower temperature, at least during the transformation process or during the forming and filling phase is partially higher than the pressure of at least another portion or of the residual portion of the filing material 21, and preferably by at least 1 bar.

(58) Moreover, the pressure on a conduit section 42 or a portion of the conduit section, via which the filling material 21.1 or the portion of the filling material 21.1 with the higher carbon dioxide concentration and/or the lower temperature is conveyed, is higher than the pressure of the residual filling material 21 or of the residual portion of the filling material 21, and during the shaping process at least temporarily higher by 2 bars to 5 bars.

(59) An embodiment sets forth that a throttle element or a narrowing cross-section is provided in the flow path of the filling material 21 and 21.1 flowing inside the stretching rod 17, whereas the throttle element is arranged in the flow direction of the filling material 21 and 21.1 for instance shortly before at least an output 24 of the stretching rod 17. Consequently, the advantageous high pressure is maintained up to shortly before the first relaxation. This pressure can be raised further when a portion of the filling material 11 is guided past the stretching rod 17 and a portion of the filling material 11 is guided through the stretching rod. The stronger carbon dioxide-containing filling material 21.1 should be conveyed more appropriately through the stretching rod 17. It is also advantageous if the stretching rod 17 is thermally insulated at least in a section with respect to the filling material 21 and 21.1.

(60) The forming and filling system or machine thereby encompasses for producing filled containers 11 made of a thermoplastic material among others the at least one heating section or heating system 4 arranged along a transport path of a preform 2 and at least one forming and filling station 10 fitted with a mould.

(61) Moreover, the forming and filling system or machine encompasses among other things a feeding device 1 for the filling material 21 and 21.1 to be filled into the container as well a carbonization unit 43, which for example is provided in the conduit section 42 and with which carbon dioxide can be dissolved at least in the partial flow of the filling material 21.1, whereas the forming and filling station 10 has a guiding device in the form of a stretching rod 17 acting at least temporarily upon the preform 2 during its transformation into the container 11 and at least one portion of the filling material 21 can be conveyed through the duct or the cavity 23 of the stretching rod 17. At least one outlet opening 24 of the duct or cavity 23 is provided at the lower end of the stretching rod 17.

(62) Advantageously, a cooling unit 44 is provided at least along the conduit section 42 for the filling material 21.1, in which downstream carbon dioxide is dissolved or which flows from the carbonation unit 43.

(63) At least the conduit section 42, in which the filling material 21.1 rich in carbon dioxide or a portion thereof is guided, is thermally insulated at least on a partial length, for example with a Teflon insulation or made of a Teflon-containing material, and/or is cladded with a thermal insulation, for instance with Teflon or a Teflon-containing material.

(64) FIGS. 9-11 show in a partial and sectional representation a stretching rod 17a, which corresponds to the stretching rod 17 in its basic function, i.e. serves during the forming and the filling of the respective preform 11 for guiding and for controlling in particular the axial stretching of the respective preform 2 or of the developing container 11. The stretching rod 17a mainly consists of a bar-shaped stretching rod body 45 with a rounded free stretching rod end 45.1. Several ducts are arranged in the stretching rod body 45, namely an internal duct 46 arranged coaxially with the longitudinal axis of the stretching rod 17a, which emerges in the vicinity of the end 45.1 at several outlet openings 47 distributed around the axis of the stretching rod 17a on the lower level N1, as well as an external annular duct 48 surrounding the internal duct 46 and separate from said internal duct, which external duct emerges at several upper outlet openings 49 distributed around the axis of the stretching rod 17a, at the surrounding or envelope surface of the stretching rod 17a on the upper level N2. A control valve designated with 50 in FIG. 9 is moreover provided in the inside of the stretching rod 17a, a valve with which a connection can be established or interrupted between the internal duct 46 and the external duct 48 in a controlled manner. The control valve 50 is formed substantially of an axially movable lock ring 51 in the represented embodiment, which is preloaded for example by a spring, not represented in detail, in its raised position in FIG. 9 releasing the connection between the ducts 46 and 48. The lock ring 51 is mobile against the effect of the spring in its position interrupting the connection between the ducts 46 and 48 by an actuating device, for instance through a magnet coil 52 housed in the stretching rod 17a.

(65) FIGS. 9-11 represent moreover the multi-way metering valve 22 controlled by the electronic control unit 53, a valve which is again designed as a multiway valve, which is associated with a first connection or inlet with the supply device 20 not represented in FIG. 9 for the filling material 21 and which is associated with a second connection with the supply device 20 not represented in FIG. 9 for the filling material 21.1. The outlets of the multi-way metering valve 22 are associated via a liquid connection 54 with the internal duct 46 or via a liquid connection 55 with the external annular duct 48. The cooling unit 44 is arranged in the liquid connection 54. The control valve 50 or its magnet coil 52 is controlled by the control unit 53, whereas the control valve 50 is realized in the variation represented as an electromagnetically, linearly driven system. This has the particular advantage to be able to adjust the closing and opening speeds continuously. It is therefore not necessary to design the control valve 50 to 100% in a tight manner; a small amount of leak can be tolerated.

(66) Different operating modes are possible with the stretching rod 17a, namely for example the simultaneous introduction of the filling material, for example of the filling material 21 without CO.sub.2 content or with reduced CO.sub.2 content on the lower level N1 via the outlet openings 47 and on the higher level N2 via the outlet openings 49 into the preform 2 or into the developing container 11. Therefore, the control valve 50 is opened by suitable control from the control unit 53 for a connection of both ducts 46 and 48 and moreover the multi-way metering valve 22 is controlled through the control unit 53 in such a way that this metering valve only provides a connection with the liquid connection 55. Said operating condition is represented in FIG. 9.

(67) With a closed control valve 50, it is moreover possible to establish a connection to both ducts 46 and 48 by a suitable control of the multi-way metering valve 22 via said valve for the filling material 21 so that the filling material 21 is again inserted according to the arrows via the outlet openings 47 and 49 at the different levels of height N1 and N2 into the preform 2 or into the developing container 11. In the operating condition represented in FIG. 10, there is still the possibility to cool the partial quantity of the filling material 21 in the cooling unit 44, a quantity fed to the internal duct 46 and exiting the lower outlet openings 47, or to cool the liquid connection 54 for a chronologically following process step with the filling material.

(68) Moreover, there is the possibility by suitable control of the multi-way metering valve 22, to supply the filling material 21.1 via the liquid connection 54 in the internal duct 46 for the exit exclusively at the lower outlet openings 47 or on the high level N1 and to supply the filling material 21 for the exit exclusively at the upper outlet openings 49 or on the higher level N2, whereas the supply of the filling material 21 and 21.1 is either simultaneous, time-delayed or with a time overlap, and namely with an evacuation which is time-delayed or with a time overlap preferably in such a form that first of all the filling material 21 is supplied via the upper outlet openings 47 and then the filling material 21.1 is supplied via the lower outlet openings 49. Said operating condition, in which again the filling material 21.1 is cooled in the cooling unit 44, is represented in FIG. 11. It goes without saying that the various operation conditions represented in FIGS. 9-11 can be combined at will in the respective forming and filling phase.

(69) It is for example possible during the respective forming and filling phase in a first partial or process phase according to FIG. 9 to introduce the filling material 21 via the outlet openings 47 and 49, in a chronologically following second partial or process phase according to FIG. 10 to introduce the filling material 21 via the outlet openings 47 and 49 further and hence simultaneously to pre-cool the liquid connection 54 with the filling material 21 flowing through the cooling unit 44 and then according to FIG. 11 in a third partial or process phase to introduce the filling material 21.1 via the lower outlet openings 47, whereas for example the filling material 21 is further supplied via the upper outlet openings 49.

(70) A calmed intermediate zone is formed in each of the cases between the height levels N1 and N2, a zone which delineates the portions of filling material from each other. An advantageous influence lies in the aforementioned electromagnetically driven control valve 50, because it enables a low-impulse and low-blending changeover. A further advantage consists with said electromagnetically driven control valve 50 in that it is quite robust and can be cleaned very easily in corresponding cleaning cycles using quick and, if needed, multiple switching.

(71) FIG. 12 shows a simplified sectional view of a further embodiment of a stretching rod 17b, which differentiates from the stretching rod 17a substantially only in that in addition to both ducts 46 and 48 a third annular duct 56 is provided in an upper region, remote from the stretching rod end 45.1, a duct which emerges at several outlet or relief openings 57 distributed around the axis of the stretching rod 17b at the surrounding or envelope surface of the stretching rod 17b. The headroom 59 formed in the container 11 above the surface of the filling material is relieved via the duct 56 for example by a control valve 58 driven by the control unit 53 after forming and filling the respective container 11. The container 11 can be further relieved after forming and filling via the outlet openings 47 and when the control valve 50 is open, also via the outlet openings 49, for example by a control valve 60 driven by the control unit 53.

(72) The stretching rods 17a or 17b represented in FIGS. 10-13 or the forming and filling devices or machines having said stretching rods also enable to evacuate the respective preform before starting the forming and filling phase and/or to rinse it with for example a hot inert gas, and preferably via the lower outlet openings 47.

(73) As shown in FIGS. 9-12, the outlet openings 47 and 49 or the stretching rod 17a are designed at their surrounding or envelope surface in such a way that the main flow direction of the medium exiting the outlet openings 47 or 49 with respect to the longitudinal axis of the stretching rod 17a is tilted in an angle smaller than 90 and namely at the lower outlet openings 47 in such a way that said angle opens at the lower stretching rod end 45.1 and at the upper outlet openings 49 in such a way that said angle opens towards the end of the stretching rod 17a facing away from the lower stretching rod end 45.1.

(74) The outlet openings 47 or 49 have in particular rounded edges or radii so that local turbulences and cavitation are avoided and result in a stable stratification. More advantageously, the rounded edges of the outlet openings 47 and 49 are provided at the stretching rod radially and inwardly as well as radially and outwardly.

(75) FIG. 13 shows the block diagram of an exemplary embodiment of the method according to the invention. A thermally conditioned preform is formed and filled in a first process phase I under the filling pressure p.sub.2 with degassed water to obtain a container. Subsequently, the container is relieved to a pressure p.sub.1 and filling material is conveyed in a second process phase. This can in particular be a syrup, a carbonized liquid or dry ice, in particular in the form of pellets.

(76) Subsequently, the formed and filled container is relieved to atmospheric pressure p.sub.0 and closed hermetically.

LIST OF REFERENCE SIGNS

(77) 1 Feeding device 2 Preform 3 Transfer wheel 4 Heating device 5 Mouth section 6 Heating element 7 Transport device 8 Transfer wheel 9 Process wheel 10 Forming and filling station 11 Container 12 Extraction wheel 13 Output line 14 Input device 15 Closing member 16 Mould partitioning 17 Stretching bar or stretching rod 17.1 Narrowing portion 18 Tip of the stretching rod 19 Bottom of the preform 20 Supply device 21 Filling material 22 Multi-way metering valve 23 Cavity of the stretching rod 24 Outlet opening 25 Return valve 26 Venting valve 27 Outlet opening 28 Connecting element 29 Seal 30 Cavity of the preform 31 Annular slit 32 Longitudinal axis of the bottle or 33 Sealing element 34 Counter element 35 Bearing 36 Supply opening 37 Mould 38 Closing device 39 Gripper 40 Tool carrier 41 Rotational axis 42 Conduit or conduit section 43 Carbonation unit 44 Cooling unit 45 Stretching rod body 45.1 Stretching rod end 46 Duct 47 Outlet opening 48 Duct 49 Outlet opening 50 Control valve 51 Lock ring 52 Magnet coil 53 Control electronics 54, 55 Liquid connections 56 Duct 57 Outlet opening 58 Control valve 59 Headroom 60 Control valve