Device for converting a liquid to a vapour

Abstract

A device for converting a liquid into vapor includes an enclosure, a heating surface with a downward slope arranged in the enclosure, and a liquid inlet port connected to an upper portion of the heating surface so that a liquid introduced from the liquid inlet port flows on the heating surface. The device also includes a vapor outlet port formed through a wall of the enclosure. The heating surface includes a heat transfer pipe configured to allow the flowing of a heat transfer fluid to heat the heating surface, and a corner piece including a U-shaped cross-section with a semi-circular portion arranged around the heat transfer pipe and an upper portion forming an opening on the enclosure.

Claims

1. A device for converting a liquid into vapor, said device comprising: an enclosure; a heating surface with a consistently downward slope arranged in said enclosure and defining a liquid flow path; a liquid inlet port connected to an upper portion of said heating surface so that the liquid introduced from said liquid inlet flows on said slope of the heating surface; and a vapor outlet port formed through a wall of the enclosure; wherein the heating surface comprises: a heat transfer pipe configured to allow the flowing of a heat transfer fluid heating said heating surface; and a channel piece comprising a U-shaped cross-section with a semi-circular portion arranged around said heat transfer pipe and an upper portion forming an opening on said enclosure; and wherein the heat within the enclosure enters the enclosure via the heat transfer fluid.

2. The device for converting a liquid into vapor of claim 1, wherein a diameter of the semi-circular portion of the channel piece is substantially equal to the diameter of the heat transfer pipe.

3. The device for converting a liquid into vapor of claim 2, wherein the channel piece is bent around the heat transfer pipe.

4. The device for converting a liquid into vapor of claim 1, wherein the heating surface forms a spiral.

5. The device for converting a liquid into vapor of claim 1, wherein the heating surface has a slope in the range from 1 to 4%.

6. The device for converting a liquid into vapor of claim 1, wherein the channel piece comprises at least one groove extending on one side of the heat transfer pipe.

7. The device for converting a liquid into vapor of claim 1, wherein the channel piece and/or the heat transfer pipe are made of a material neutral for the liquid.

8. The device for converting a liquid into vapor of claim 7, wherein the channel piece and/or the heat transfer pipe are made of stainless steel.

9. The device for converting a liquid into vapour of claim 7, wherein the material neutral for the liquid is stainless steel.

10. The device for converting a liquid into vapor of claim 1, wherein the enclosure comprises an insulating outer jacket and a temperature-controlled inner jacket.

11. The device for converting a liquid into vapor of claim 1, wherein the heat transfer pipe is configured to circulate a heat transfer fluid in a circulation direction inverse to the direction of a liquid in the channel piece.

12. The device for converting a liquid into vapor of claim 1, wherein said device comprises two portions: an upper portion where the heat transfer pipe is arranged in the semi-circular portion of the channel piece; and a lower portion where an electric heating resistor is arranged in the semi-circular portion of the channel piece.

13. A vapor generator comprising: a liquid flow regulator capable of generating a constant liquid flow rate in the range from 0 to 10 kg/hr; the device for converting liquid into vapor of claim 1, the inlet port of the device coupled to said liquid flow regulator; and an energy source capable of supplying a sufficient quantity of energy to the heating surface of the conversion device to heat the liquid.

14. The vapor generator of claim 13, further comprising a source for heating the heat transfer pipe of the conversion device, arranged on an inlet port of heat transfer fluid of said heat transfer pipe.

15. A device for converting a liquid into vapor, said device comprising: an enclosure into which heat is introduced by a heat transfer fluid; a heating surface formed as an open channel having a U-shaped cross-section and forming a helix extending downward from an upper portion of the heating surface at a top of the enclosure; a heat transfer pipe configured to provide heat to the heating surface via the heat transfer fluid flowing therein, the heat transfer pipe disposed within the channel of the heating surface, having a cross-section complementary to the U-shaped cross-section of the heating surface, and further having a helical shape corresponding to that of the heating surface such that the heating surface and the heat transfer pipe are in contact over at least the upper portion of the heating surface; a liquid inlet port connected to the upper portion of the heating surface such that a liquid introduced through said liquid inlet port flows, by gravity, within the channel formed by the heating surface and around the heat transfer pipe from the upper portion to a lower portion of the heating surface; and a vapor outlet port formed through a wall of the enclosure.

16. A device according to claim 15, further comprising an electrolyzer having an inlet coupled to the vapor outlet port and operating at atmospheric pressure such that an inner pressure of the enclosure is equal to the atmospheric pressure.

17. A device according to claim 15, wherein the heating surface extends downward with a constant slope over a majority of its helical length.

18. A device according to claim 17, wherein the constant slope is between 1% and 4%.

19. A device according to claim 15, wherein the heat transfer pipe includes an inlet port and an outlet port, the inlet and outlet ports arranged such that the flow of heat transfer fluid through the heat transfer pipe is against gravity.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The present description will be better understood on reading of the following description provided as an example only in relation with the accompanying drawings, where the same reference numerals designate the same or similar elements, among which:

(2) FIG. 1 is a simplified representation of a device for converting a liquid into vapor according to a first embodiment;

(3) FIGS. 2a and 2b are simplified representations of a cross-section of the heating surface of FIG. 1 before and after bending;

(4) FIG. 3 is a simplified representation of a device for converting a liquid into vapor according to a second embodiment; and

(5) FIG. 4 is a simplified representation of a device for converting a liquid into vapor according to a third embodiment.

DETAILED DESCRIPTION

(6) In the following description, expression “substantially” means with a tolerance of plus or minus 10%.

(7) The structure of a device 10 for converting a liquid 20, particularly water, into vapor 21 according to a specific embodiment illustrated in FIG. 1 is described hereafter.

(8) The conversion device is formed, in particular, of an enclosure 11 provided with a vapor outlet port 14 and with a liquid inlet port 13 intended to be coupled to a conventional water flow regulator (not shown). The liquid water flow regulator may be a regulator available for sale, for example, a thermal mass flow or Coriolis regulator.

(9) Enclosure 11 is formed of a thermally-insulating outer jacket 40 and of an inner jacket 41 which enables to retain the vapor generated in enclosure 11 and to channel it onto vapor outlet port 14 so that it can be used. Inner jacket 41 is preferably made of a metallic material. Inner jacket 41 is heated to be maintained at a sufficient temperature, for example, 200° C., to avoid the appearing of condensate on the inner walls of enclosure 11. Inner jacket 41 also has the function of withstanding the maximum operating pressure of the vapor generator. For example, for a production flow rate from 0 to 5 kg/hr at the atmospheric pressure, inner jacket 41 has a 220-millimeter diameter for a 470-millimeter height in a steel sheet having a 2-millimeter thickness.

(10) The inner volume of enclosure 11 being in connection, via vapor outlet port 14, with the outside, the inner pressure of enclosure 11 is set by the outer pressure. For example, vapor outlet port 14 is directly connected to the inlet of an electrolyzer operating at the atmospheric pressure, so that the inner pressure of enclosure 11 is equal to the atmospheric pressure, and thus substantially constant. Of course, the outer pressure, which sets the inner pressure of enclosure 11, may be different, particularly greater. Similarly, a pressure regulator may be provided to directly regulate the inner pressure of enclosure 11 to obtain a substantially constant pressure.

(11) An open heating surface 12 of helical shape, for compactness reasons, is arranged in enclosure 11. Heating surface 12 is formed by a corner piece 15 having a U-shaped cross-section, with a semi-circular portion 17 and an upper portion 19 forming an opening 18 on enclosure 11. Preferably, corner piece 15 is made of stainless steel and rests on a support base of enclosure 11. In particular, the support base is horizontal, that is, substantially perpendicular to the direction of gravity.

(12) Heating surface 12 has a downward slope, for example, between 1 and 4%, which allows a flow by gravity of liquid water 20 from liquid inlet port 13.

(13) Further, a heat transfer pipe 16 is arranged in semi-circular portion 17 of corner piece 15. Heat transfer pipe 16 has a round cross-section adapted to semi-circular cross-section 17 of corner piece 15 so as to be positioned at closest to the back of corner piece 15. Heat transfer pipe 16 is further intended to heat up liquid 20 flowing through corner piece 15 to take it to its evaporation temperature. In practice, to efficiently transmit the thermal energy to the liquid to be evaporated, the surface area of contact between heat transfer pipe 16 and liquid 20 should be large. According to an embodiment comprising a 10-meter long heat transfer pipe 16 having an 8-millimeter diameter, the contact surface area is estimated to be 12 dm.sup.2.

(14) More particularly, as illustrated in FIGS. 2a and 2b, corner piece 15 is bent around heat transfer pipe 16. For this purpose, heat transfer pipe 16 is inserted into the back of corner piece 15 such as illustrated in FIG. 2a. As illustrated in FIG. 2b, upper portion 19 of corner piece 15 narrows along directions d1 and d2 during the bending operation, so that heat transfer pipe 16 is trapped in semi-circular portion 17 of corner piece 15.

(15) As a variation, lower portion 17 of corner piece 15 may comprise a groove to allow a flow of liquid 20 by capillarity. The flow by capillarity is particularly advantageous in the case of a low liquid flow rate 20, and particularly in the case where liquid 20 is injected dropwise. The flow by capillarity indeed enables to uniformly spread liquid 20 to be evaporated on heating surface 12, with no forming of a drop train, guaranteeing a regularity of the vapor flow rate at the output.

(16) For example, liquid inlet port 13 may be a stainless steel pipe positioned in contact with corner piece 15 and with heat transfer pipe 16, and sized to authorize a sucking in by capillarity of liquid 20 into corner piece 15, with no forming of drops.

(17) Of course, according to the type of injection of liquid 20, dropwise or continuous, and to the liquid flow rate to be introduced, it is possible to form the device without the groove. In this case, liquid 20 only flows by gravity.

(18) As a variation, heat transfer pipe 16 may take other shapes without modifying the contemplated embodiments.

(19) According to another variation, illustrated in FIG. 3, heat transfer pipe 16 is heated by an electric heating source 35 before penetrating into enclosure 11. Complementary heating source 35 may take the form of a resistor surrounding heat transfer pipe 16.

(20) According to another variation illustrated in FIG. 4, heating surface 12 comprises two different heating means. An upper portion 30 of heating surface 12 is heated by heat transfer pipe 16 and a lower portion 31 of heating surface 12 is heated by a heating resistor 32. To achieve this, in lower portion 31, the back of corner piece 15 comprises a groove having heating resistor 32 inserted therein. The groove is opened and sized to allow the insertion by caulking of heating resistor 32 and a flow by capillarity of the liquid in corner piece 15. For example, for a heating surface having a 3.5-millimeter diameter and a flow rate range from 0 to 5 l/hr, corner piece 15 has a 8.5-millimeter height for a 17-millimeter width and the groove has a height and a width of 3.5 millimeters, allowing the caulking of wire-shaped electric resistor 32.

(21) Heating resistor 32 is further coupled to a voltage source regulated to supply the energy necessary to the heating of the water during its descent along corner piece 15 until its evaporation.

(22) The generated vapor 21 is then discharged at the periphery via opening 18 of corner piece 15 without disturbing the flow to guarantee a regularity in the heating operation.

(23) To ensure an efficient evaporation of all the liquid 20 introduced into corner piece 15 with or without boiling, it is necessary to homogeneously heat up liquid 20. In practice, the temperature of heat transfer pipe 16 is calibrated to ensure a temperature rise, preferably regular, of a given quantity of water in corner piece 15 until its total evaporation before the end of the travel.

(24) The energy power of the heat transfer fluid flowing in heat transfer pipe 16 may be optimized according to the quantity of water to be introduced, to distribute the water all along corner piece 15 and to have a very stable vapor generation with a minimum energy expenditure. Such an optimization may be performed by calculating the energy necessary for the heating of the water, and then for its vaporization, while taking thermal losses into account.

(25) In practice, a maximum flow rate of liquid 20 to be injected into corner piece 15 is defined, for example, 10 kg/hr. Such a maximum flow rate defines a maximum quantity of liquid 20 to be evaporated, here 10 kg. The total thermal power necessary to vaporize this maximum quantity of liquid 20 is calculated, by of course taking into account the initial temperature of liquid 20 and the pressure under which the heating is performed. For example, the total thermal power may be calculated to take the liquid water from 20° C. to an overheated vapor state at 150° C. at the atmospheric pressure. Such a calculation is for example performed according to the following relations:
P={dot over (m)}.Math.Cp.sub.1.Math.(100−20)+{dot over (m)}.Math.L+{dot over (m)}.Math.Cp.sub.2.Math.(150−100)
P={dot over (m)}.Math.(Cp.sub.1.Math.(100−20)+L+Cp.sub.2.Math.(150−100))
P={dot over (m)}.Math.(4195.Math.(100−20)+2,258.Math.10.sup.6+2030.Math.(150−100))
P={dot over (m)}.Math.2695100
P=2.77.Math.10.sup.−3.Math.2695100
P=7486 W
with: P: Minimum necessary thermal power [W]; {dot over (m)}: water mass flow rate [2.77.Math.10.sup.−3 kg/s]; Cp.sub.1: Mean specific heat of water between 20° C. and 100° C. [4,195 J/(kg.Math.K)]; Cp.sub.2: Mean specific heat of steam between 100° C. and 150° C. [2,030 J/(kg.Math.K)]; L: Latent heat of water vaporization [2.258.Math.10.sup.6 J/(kg.Math.K)].

(26) According to an embodiment, the energy power of the heat transfer fluid flowing in heat transfer pipe 16 will preferably be selected with at least 30% of the additional heating capacity to have a better reactivity during changes of evaporation instructions. In the disclosed case of a vapor production flow rate of 10 kg/hr, the power recommended for heating surface 12 is (1.3. P)=9,732 W, rounded up to 10 kW.

(27) The length of heating surface 12 is calculated to limit the linear thermal power within the limit of the efficiency of the linear thermal transfer to the liquid water, preferably in the range from 0.5 to 1 kW/m. In the disclosed case of a vapor generation rate of 10 kg/hr, that is, a 10-kW total power, the length recommended for heating surface 12 is thus in the range from 10 to 20 meters.

(28) In other words, the method of calculating the linear thermal power particularly comprises:

(29) defining a maximum flow rate of liquid 20 to be injected, such a maximum flow rate providing the maximum quantity of liquid to be evaporated;

(30) calculating the total thermal power necessary to vaporize this maximum quantity of liquid, that is, to raise the temperature of the quantity of liquid by an initial temperature to at least its evaporation temperature, to achieve the actual evaporation, and to overheat the generator vapor; and

(31) calculating the linear thermal power to be generated for a travel length equal to the maximum length of the travel.

(32) For example, the minimum total heating power P necessary to vaporize a quantity of liquid 20 may in particular be obtained by the sum of energy P.sub.1 necessary to heat this quantity of liquid up to its boiling temperature, of energy P.sub.2 for carrying out the actual vaporization, and of energy P.sub.3 for overheating the generated vapor:
P=P.sub.1+P.sub.2+P.sub.3

(33) In particular, the calculation of the power necessary to take a given flow rate of the liquid from an initial temperature to a final temperature, for example, its evaporation temperature, is for example provided by relation:
P.sub.1={dot over (m)}.Math.Cp.sub.1.Math.ΔT.sub.1
with: P.sub.1 the power in Watt [W]; {dot over (m)} has the flow rate of liquid to be heated [kg/s]; Cp.sub.1 the mass thermal capacity at a constant pressure of the liquid [J/(kg.Math.K)]; ΔT.sub.1 the temperature difference between the final temperature to be reached and the initial temperature [K].

(34) The calculation of the power necessary to vaporize a given liquid flow rate is for example given by relation:
P.sub.2={dot over (m)}.Math.L
with: P.sub.2 the power in Watt [W]; {dot over (m)} the flow rate of liquid to be heated [kg/s]; L the latent mass heat of vaporization at constant pressure of the liquid [J/kg].

(35) The calculation of the power necessary to overheat a given flow rate of the liquid from an initial temperature to a final temperature, for example, up to a temperature greater by 50° C. than the evaporation temperature, is for example provided by relation:
P.sub.3={dot over (m)}.Math.Cp.sub.3.Math.ΔT.sub.3
with: P.sub.3 the power in Watt [W]; {dot over (m)} the flow rate of vapor to be re-heated [kg/s]; Cp.sub.3 the mass thermal capacity at a constant pressure of the vapor [J/(kg.Math.K)]; ΔT.sub.3 the temperature difference between the final temperature to be reached and the initial temperature [K].

(36) Of course, this relation may be weighted by taking into account possible heat losses, preferably by adding a minimum margin of 30% to the total power.

(37) Thus, water 20 to be evaporated is introduced into corner piece 15 via liquid inlet port 13 and flows into corner piece 15, by gravity and/or by capillarity. Water 20 heats during its descent until it evaporates. Vapor 21 is discharged through opening 18 of corner piece 15 without disturbing the flow, which guarantees the regularity of the operation.

(38) According to a variation, it is possible to provide a regulation of the energy power of the heat transfer fluid flowing through heat transfer pipe 16. For example, it is possible to couple a temperature sensor with a voltage regulator. The temperature sensor, for example, a thermocouple, measures the temperature of the heat transfer fluid flowing in heat transfer pipe 16 at the level of outlet port 24 of the heat transfer fluid. The temperature of the heat transfer fluid at inlet port 23 of heat transfer fluid 16 is then adjusted according to this measured temperature and to a reference temperature corresponding to the thermal power necessary to vaporize the water. In practice, a table or a diagram giving the correspondences between the temperature, the water flow rate, and the temperature of the heat transfer fluid to be supplied is available.

(39) Preferably, the heat transfer fluid flows in heat transfer pipe 16 in the direction opposite to that of liquid flow 20 in corner piece 15.

(40) Thus, the evaporator provided by the present disclosure is adapted to generating small vapor flow rates, particularly flow rates in the range from 10 g/hr to 10 kg/hr, and does not require using a carried gas.

(41) In particular, the provided evaporator enables to generate dry vapor at a constant pressure, and the vapor flow rate desired at the outlet port is simply obtained by a regulation of the liquid flow rate at the inlet port. In particular, it is possible to combine the dropwise injection of liquid and the generation of a regular vapor flow rate.