Metal matrix composite and method of forming

Abstract

Use of Ca in metal matrix composites (MMC) allows for incorporation of small and large amounts of ceramic (e.g. rutile TiO.sub.2) into the metal (Al, or its alloys). Calcium remains principally out of the matrix and is part of a boundary layer system that has advantages for integrity of the MMC. Between 0.005 and 10 wt. % calcium (Ca) may be included, and more than 50 wt. % of rutile has been shown to be integrated. Rutile may therefore be used to reduce melt loss due to calcium from an aluminum or aluminum alloy melt.

Claims

1. A method for producing a metal matrix composite comprising: stirring a reinforcement with an aluminum-containing molten or semisolid metal or alloy and between 0.005 and 10 wt. % calcium (Ca) to form a mixture, wherein the reinforcement is composed of particles each having a surface with a surface area bearing at least 20% of titanium oxide (TiO.sub.2), and the TiO.sub.2 is of crystal form other than anatase; and cooling the mixture to produce a solid metal matrix composite to form a boundary material system between the crystals and the matrix, the boundary material system comprising calcium and aluminum oxides.

2. The method of claim 1 wherein the reinforcement is a cermet or ceramic powder including the TiO.sub.2, or a compound coated with the TiO.sub.2.

3. The method of claim 1 wherein the TiO.sub.2 is in a rutile crystal form.

4. The method of claim 1 wherein at least 60 wt. % of the mixture comprises the reinforcement and molten metal or alloy.

5. The method of claim 1 wherein the molten or semisolid metal is liquid aluminum with at least 80 wt. % or more of Al.

6. The method of claim 1 wherein the molten metal or alloy includes aluminum, and at least one alloying metal in liquid or semisolid form with the aluminum, the alloying metal being a metal other than magnesium.

7. The method of claim 1 wherein the particles are spherical, cubic, prismatic, polyhedral, angular, amorphous, elongated, rod-like, tubular, conic, fibrous, filamentary, platelet-like, disc-like, irregular, or any combination of the above.

8. The method of claim 1 wherein the surfaces of the particles are flat or curved, smooth or rough, randomly textured or patterned, concave or convex, or any combination of the above.

9. The method of claim 1 wherein the particles have a predefined distribution of dimensions, with less than 10% of the powders having dimensions greater than a maximum dimension, which is less than 1 cm, and with less than 10% of the powders having dimensions smaller than a minimum dimension, which is greater than 10 nm.

10. The method of claim 1 wherein each surface of the typical particle has a surface area with at least 20% of TiO.sub.2.

11. The method of claim 10 wherein each surface of the typical particle bears at least 60% of TiO.sub.2.

12. The method of claim 1 wherein cooling the mixture to produce a solid metal matrix composite comprises: sandcasting, die casting, centrifugal casting, compocasting, thixocasting, rheocasting, thixomolding or other semisolid casting, pressure die casting, injection molding or extrusion.

13. The method of claim 1 wherein at least 80 wt. % of the mixture comprises the reinforcement and molten metal or alloy.

14. The method of claim 1 wherein at least 97 wt. % of the mixture comprises the reinforcement and molten metal or alloy.

15. The method of claim 1 wherein the calcium is added to the liquid or semisolid aluminum prior to introduction of the reinforcements.

16. The method of claim 1 wherein the calcium is added in an amount of 0.005 to 5 wt. %.

17. The method of claim 1 wherein the calcium is added in an amount of 0.01 to 2.5 wt. %.

18. A metal matrix composite (MMC) comprising: a metal matrix of an aluminum or an alloy of aluminum; and numerous sub-millimeter dimension embedded particles of a ceramic distributed throughout the metal matrix, the embedded particles comprising crystals of titanium oxide (TiO.sub.2) in crystal form other than anatase, wherein 0.005 to 10 wt. % calcium is present, and a boundary material system is formed between the crystals and the matrix, the boundary system comprising calcium and aluminum oxides.

19. The MMC of claim 18 wherein the calcium present is in an amount of 0.005 to 5 wt. %.

20. The MMC of claim 18 wherein the crystals are of rutile crystal form.

21. The MMC of claim 20 wherein the calcium is more highly concentrated within the boundary material system than within the embedded particles.

22. The MMC of claim 20 wherein the ceramic particles are composed of a ceramic oxide, boride, carbide, nitride or graphite coated with the rutile TiO.sub.2.

23. The MMC of claim 20 wherein the ceramic particles are composed of an oxide or boride, or a ceramic that has a naturally formed oxidization layer coated with the rutile TiO.sub.2.

24. The MMC of claim 18 wherein the calcium present is in an amount of 0.01 to 2.5 wt. %.

25. The MMC of claim 18 wherein the ceramic particles are spherical, cubic, prismatic, polyhedral, angular, amorphous, elongated, rod-like, tubular, conic, fibrous, filamentary, platelet-like, disc-like, irregular, or any combination of the above.

26. The MMC of claim 18 wherein the ceramic particles have a predefined distribution of dimensions, with less than 10% of the powders having dimensions greater than a maximum dimension, which is less than 1 cm, and with less than 10% of the powders having dimensions smaller than a minimum dimension, which is greater than 10 nm.

27. A method for reducing melt loss due to calcium defects in parts formed from an aluminum or aluminum alloy melt, the method comprising estimating a molar amount of calcium present, and adding at least an equal molar amount of rutile titania to the aluminum or aluminum alloy melt to form within the aluminum a boundary material system between crystals of the rutile titania and the aluminum, the boundary system comprising calcium and aluminum oxides.

28. A method for producing a metal matrix composite comprising: at least partially melting an aluminum metal or alloy to form a molten or semisolid metal or alloy containing between 0.005 and 10 wt. % calcium (Ca); stirring into the metal or alloy a reinforcement composed of particles of titanium oxide (TiO.sub.2) of a crystal form other than anatase to form a mixture; and cooling the mixture to produce a solid metal matrix composite forming a boundary material system between the crystals and the matrix, the boundary material system comprising calcium and aluminum oxides.

29. The method of claim 28 wherein the TiO.sub.2 is in a rutile crystal form.

30. The method of claim 28 wherein at least 60 wt. % of the mixture comprises the reinforcement and molten metal or alloy.

31. The method of claim 28 wherein at least 97 wt. % of the mixture comprises the reinforcement and molten metal or alloy.

32. The method of claim 28 wherein the molten or semisolid metal or alloy comprises at least 80 wt. % of liquid aluminum.

33. The method of claim 28 wherein the molten or semisolid metal or alloy includes aluminum, and at least one alloying metal in liquid or semisolid form with the aluminum, the one alloying metal being a metal other than magnesium.

34. The method of claim 28 wherein the particles are spherical, cubic, prismatic, polyhedral, angular, amorphous, elongated, rod-like, tubular, conic, fibrous, filamentary, platelet-like, disc-like, irregular, or any combination of the above.

35. The method of claim 28 wherein the particles have surfaces that are: flat or curved, smooth or rough, randomly textured or patterned, concave or convex, or any combination of the above.

36. The method of claim 28 wherein the particles have a predefined distribution of dimensions, with less than 10% of the powders having dimensions greater than a maximum dimension, which is less than 1 cm, and with less than 10% of the powders having dimensions smaller than a minimum dimension, which is greater than 10 nm.

37. The method of claim 28 wherein cooling the mixture to produce a solid metal matrix composite comprises: sandcasting, die casting, centrifugal casting, compocasting, thixocasting, rheocasting, thixomolding or other semisolid casting, pressure die casting, injection molding or extrusion.

38. The method of claim 28 wherein the calcium is added in an amount of 0.005 to 5 wt. %.

39. The method of claim 28 wherein the calcium is added in an amount of 0.01 to 2.5 wt. %.

40. A cast part comprising: a metal matrix of an aluminum or an alloy of aluminum; and numerous sub-millimeter dimension embedded particles of a ceramic distributed throughout the metal matrix, the embedded particles comprising crystals of titanium oxide (TiO.sub.2) in crystal form other than anatase, wherein 0.005 to 10 wt. % calcium is present, and a boundary material system is formed between the crystals and the matrix, the boundary system comprising calcium and aluminum oxides.

41. The cast part of claim 40 wherein the calcium is more highly concentrated within the boundary material system than within the embedded particles.

42. The cast part of claim 40 wherein the crystals are of rutile crystal form.

43. The cast part of claim 40 wherein the ceramic particles are composed of a ceramic oxide, boride, carbide, nitride or graphite coated with the rutile TiO.sub.2.

44. The cast part of claim 40 wherein the ceramic particles are spherical, cubic, prismatic, polyhedral, angular, amorphous, elongated, rod-like, tubular, conic, fibrous, filamentary, platelet-like, disc-like, irregular, or any combination of the above.

45. The cast part of claim 40 wherein the ceramic particles have a predefined distribution of dimensions, with less than 10% of the powders having dimensions greater than a maximum dimension, which is less than 1 cm, and with less than 10% of the powders having dimensions smaller than a minimum dimension, which is greater than 10 nm.

46. The cast part of claim 40 wherein the calcium present is in an amount of 0.005 to 5 wt. %.

47. The cast part of claim 40 wherein the calcium present is in an amount of 0.01 to 2.5 wt. %.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) In order that the invention may be more clearly understood, embodiments thereof will now be described in detail by way of example, with reference to the accompanying drawings, in which:

(2) FIGS. 1a, b show separation of rutile titania in molten aluminum shown on an X ray image and photograph, respectively; and

(3) FIGS. 2a, b, c, d are images at increasing magnifications of an extracted sample of a wedge in the casting campaign, and an EDS analysis of calcium at the largest magnification.

DESCRIPTION OF PREFERRED EMBODIMENTS

(4) Herein a MMC material system is described, the material system formed of at least a metal matrix that includes aluminum, and embedded reinforcements dispersed within the matrix. The reinforcements are composed of, or coated with ceramic particles, which may be a ceramic oxide, boride, carbide, nitride or graphite. More preferably the ceramic is an oxide or boride, or a ceramic that has a naturally formed oxidization layer, such as silicon carbide, for example. More preferably the ceramic is an oxide, such as titania in a crystal form other than anatase. More preferably the ceramic is rutile titania, brookite titania, or a combination thereof. Most preferably the ceramic is rutile.

(5) An interface region is formed at the boundaries between the ceramic and matrix. The interface region includes Ca, and the concentration of Ca in the interface region is far greater than the concentration of Ca in the metal matrix. Preferably the Ca is effectively not present in the metal matrix away from the interface region. The Ca may be effectively only in the interface region, or effectively only in the interface region and within the reinforcements. The preferred order for affinities for oxygen of these metals is preferably calcium, matrix metal and the ceramic (and its constituents). Rutile TiO.sub.2 has a particular ability to react with calcium in the metal matrix, and thus even though calcium can be a problem in aluminum and aluminum alloys, it can be effectively used to promote the integration of ceramics since its reaction has been found to remove it from the matrix.

(6) A method of producing a MMC involves mixing reinforcements with an aluminum-containing molten metal, and between 0.005 and 10 wt. % Ca (more preferably 0.005 to 5 wt. %, and more preferably from 0.01 to 2.5 wt. %), wherein the reinforcements are particles that have a surface bearing at least 20% of titanium oxide (TiO.sub.2), in a crystal form other than anatase (preferably rutile), and cooling the mixture to produce a solid metal matrix composite. The titania may include brookite, which is expected to equally improve integration, given similarities in the crystal structures of the two polymorphs. The crystal structure of brookite is compatible with rutile, and brookite can grow epitaxially on rutile. Anatase, on the other hand, has a very different crystal structure, which is evidently less compatible with the formation of the calcium-containing composition observed. It is noted that brookite is a relatively scarce polymorph of rutile.

(7) The reinforcements may be ceramic or cermet, and may consist of ceramic compositions having a variety of grains of different composition, crystal form, or shape. The particles are typically dense, if a strong MMC is desired. Some properties of ceramics are achieved only with particles smaller than a given size, and frequently the size is in the nanometer scale. The addition of Ca, given the markedly improved integration of rutile with Al-containing metals and alloys, may allow for higher ceramic content in the MMC, or for better integration of finer rutile reinforcements, or other reinforcements coated with rutile powder.

(8) The reinforcements typically have all dimensions smaller than 1 cm and may be nanostructured or microstructured, coated with rutile, a cermet of rutile in a metal (the same as or different than the matrix metal), or monolithic. The reinforcements may have any distribution of sizes, angularities, or surface areas, although are expected to have at least one sub-milimeter, and often sub-micron dimension. Substantially equiaxed powders may be preferable in many applications, although fibres, filaments and rods, and platelets, discs or flakes may be useful in others. The presence of rutile on the surface of the powders permits the formation of a Ca containing boundary layer that links the metal matrix and the particles which may improve adherence of the MMC, and may improve longevity of the MMC, and further attracts the Ca away from the metal matrix.

(9) The molten metal is preferably Al or an alloy of Al (with at least 10%, or more preferably 20, 30, 40, 50, 60, 70, 80, 90, 95, 97, 99 wt. % or more of Al). If a high ceramic content is desired (i.e. more than 35 wt. %), the alloy may preferably not contain Mg. Even moderately small amounts of Mg (2%) have been found to impair the integration of high concentrations of rutile by liquid Al, although greater amounts of Ca, and other alloys of Al may reduce this effect. The metal matrix may contain moderately small amounts of boron, or other metals, and may include other reinforcements (be they ceramic or other) not linked to the matrix, by a systematically Ca-containing boundary layer.

(10) If a molten alloy of Al is used, preferably no alloying metal present in substantial quantities, have a higher affinity for oxygen than Ca. Any alloying metals included preferably do not react more readily with the reinforcements than Al, or otherwise impede the reactions between the Al, Ca, and ceramic.

(11) The MMC may be composed entirely of the monolithic ceramic powder, molten metal, and Ca, each with their respective impurities. Alternatively other reinforcements, solid metals in the molten metal (forming a semi-solid) or other alloying materials, or other materials may be present, and so the mixture may be at least 60 wt. %, more preferably 80 wt. %, more preferably 90 wt. %, more preferably 95 wt. %, more preferably 97 wt. % of the powder and molten metal.

(12) Cooling the mixture to produce a solid metal matrix composite may involve known processes such as: sandcasting, die casting, centrifugal casting, compocasting, thixocasting, rheocasting, thixomolding or other semisolid forming, pressure die casting, injection molding or extrusion.

(13) This method may produce a metal matrix composite (MMC) formed of a metal matrix of a first metal or alloy; and numerous sub-milimeter dimension embedded particles distributed uniformly throughout the metal matrix, wherein 0.005 to 10 wt. % calcium is present, but is at least mostly confined within a boundary layer produced around the ceramic particles. For example a concentration of calcium confined to the embedded particles and surrounding the embedded particles, is more than double a concentration of the calcium in the metal matrix away from the embedded particles. The concentration of calcium within and around the embedded particles may be more than 10 times, more than 50 times, and more than 100, or 1000 times the concentration of calcium in the metal matrix away from the embedded particles.

(14) With the formation of a boundary layer around the embedded particles, the calcium may be more highly concentrated at a periphery of the particles than within the particles themselves. The boundary layer may better link the first metal and the ceramic clusters. The embedded ceramic particles may include titanium, calcium, oxygen, and aluminum, and the first metal may be aluminum or an alloy of aluminum, and preferably the embedded ceramic particles were prepared from compounds of known purities of rutile titanium oxide (TiO.sub.2), with calcium oxide and substantially aluminum oxide, and the first metal is aluminum or an alloy of aluminum.

(15) As calcium is a known impurity for Al, and as rutile titania is abundant, it also makes sense to treat the rutile as an additive that compensates for and effectively removes the Ca from Al. As such rutile titania may be used to reduce melt loss, energy, labour, and processing when an aluminum metal or alloy is known to contain calcium.

EXAMPLES

(16) Applicant has experimented with the incorporation and integration of TiO.sub.2 in liquid aluminum. Specifically, approximately 50 g of rutile TiO.sub.2 powder (99.9%, <5 m, 4.17 g/cm.sup.3, product No. 224227, Sigma-Aldrich), was folded in an aluminum foil and placed at the bottom of a steel crucible. Commercially pure aluminum (>99.9%, Al PO404, AIM Metals and Alloys) was melted in an electric furnace at a temperature of approximately 720 C. and then poured in the steel crucible over the foil which freed the powder as it melted. A total of 5 slugs were produced in this manner and it was observed during these trials that the TiO.sub.2 tended to rise to the surface. An X-Ray inspection system (model Y Multiplex 5500 M, 225 kV, variofocus tube, YXLON) was used to examine the slugs and revealed the presence of large porosity in their upper portions, a typical radiograph being shown in FIG. 1a. Large defects are shown in the upper portions of the slug by the radiograph. The slugs were then sliced for internal examination, and are photographed (presented as FIG. 1b). The presence of large porosity originating from solidification shrinkage was observed as well as some TiO.sub.2 powder clustered inside the cavities. Some white TiO.sub.2 power was found clustered in some of the cavities.

(17) An examination with a scanning electron microscope (Hitachi SU-70 FEG SEM) revealed that the TiO.sub.2 powder was mainly located in the shrinkage porosity and had remained unwetted by aluminum. The chemical composition provided by the energy dispersive X-ray spectroscopy (EDS) system (Oxford EDS INCA 300) showed the presence of aluminum, oxygen and titanium along with some contaminants.

(18) No evidence was found of aluminum reacting with the TiO.sub.2. Aluminum has a very high affinity for oxygen, its reaction producing aluminum oxide, Al.sub.2O.sub.3. This compound is more stable than titanium oxide, TiO.sub.2, and some reduction would thus be expected when TiO.sub.2 additions are made to liquid aluminium unless kinetic barriers are present. Moreover, titanium has limited solubility in liquid aluminium (<1 wt % at 800 C.) and titanium aluminides would be expected to form even when a small amount of TiO.sub.2 is reduced. With sufficient mass fractions of TiO.sub.2 in liquid aluminum, aluminum oxide and titanium aluminide would be expected to be produced according to the following exothermic reaction: 3 TiO.sub.2+7 Al.fwdarw.2 Al.sub.2O.sub.3+3 TiAl. The results from the gravity casting showed a tendency for TiO.sub.2 to agglomerate and poor integration with liquid aluminum. There is no sign of a chemical reaction between the Al and titania.

(19) Additional tests to evaluate the incorporation of TiO.sub.2 were carried out with the stir-casting technique and an attempt to produce wedges by high pressure die casting with this slurry was made. In these tests, anatase TiO.sub.2 was used (99%, <44 m, 3.9 g/cm.sup.3, product No. 248576, Sigma-Aldrich). Approximately 90 kg of aluminum (>99.9%, Al P0404, AIM Metals and Alloys) was melted in an electric furnace and a vortex in liquid aluminum was created by the rotating impeller of a mixer. The anatase was first heated to 300 C. for at least 1 hour to remove moisture and a total of 9 kg was poured into the vortex by incremental additions of 300 g batches.

(20) Agglomeration and lack of wetting were again observed with this mode of incorporation and once the vortex stopped, the TiO.sub.2 immediately separated from the melt and floated to the surface. Although the supplier specified a density of 3.9 g/cm.sup.3 for the anatase TiO.sub.2, the apparent density was measured to be 0.5 g/cm.sup.3 and combined with the lack of wetting, is believed to account for the observed rise to the surface of liquid aluminum (Al=2.4 g/cm3). The high pressure die casting trials also failed to produce presentable wedges and the separation of the solid TiO.sub.2 from the liquid aluminium was the main reason.

(21) Experiments were performed to assess the effect on integration of two different TiO.sub.2 forms (rutile and anatase) having different granulometry and hence different apparent densities, and the effects of small additions of boron, magnesium and calcium metals (that could modify wetting of aluminum with TiO.sub.2). A two-level screening design comprising 16 trials was selected, having for response variable the amount of TiO.sub.2 that could be incorporated in aluminum.

(22) These tests were performed in a small furnace with a capacity to melt approximately 5 kg of aluminum. A mechanical stirrer (IKA, model RW20DWMNS1, Fischer Scientific) mounted with a steel impeller was used for mixing the TiO.sub.2. Oxidation of aluminum was reduced with argon at a flow rate of 15 L/min that was supplied by a ring placed above the crucible and made with a copper tube () having perforated holes.

(23) The anatase was the same as described above (product No. 248576, Sigma-Aldrich) while the rutile was supplied by Rio Tinto Iron and Titanium (>97% pure, UGSTM, 300-350 m, =3.9 g/cm.sup.3, app=1.87 g/cm.sup.3). In all instances, the TiO.sub.2 powder was heated to 300 C. for at least 1 hour to remove moisture. Magnesium (99.9%, Rand Alloys) was added to the melt while calcium (Al-10% Ca, Rand Alloys) and boron (Al-4% B, AIM Metals and Alloys) were added as master alloys. Magnesium, calcium and boron were weighed and added to liquid aluminum before the TiO.sub.2 additions. As it was unknown what amount of titania would be accepted by the melt, fixed amounts of Mg 2 wt. %, Ca 2 wt. %, and B 1 wt. % with respect to the initial quantity of pure liquid aluminum were used or not for each trial.

(24) Regardless of whether Mg, Ca, or B were included, anatase titania exhibited very poor mixing, and separated readily once the mixer stopped. In all cases, except with Mg and Ca and no B (which showed poor mixing/lumpiness), less than 13 wt. % was incorporated, and typically at around 10 wt. % it is clear that no more titania can be added. Sparking and flaring was also observed, indicating poor integration.

(25) Rutile titania, which has exactly the same chemical composition as anatase titania, exhibited very different mixing. While differences in the apparent densities of the anatase (45 microns-0.5 g/cm.sup.3) vs. rutile (300 to 350 microns-1.87 g/cm.sup.3) were considered to possibly have had some effect (liquid aluminium has a density of 2.4 g/cm.sup.3), subsequent experiments with different diameter powders and apparent densities suggest that there is another reason for the different behaviours of these powders, perhaps owing to the crystal structure itself.

(26) With no Mg, Ca or B, the rutile titania did not rise after mixing, but large lumps were included in the melt. Adding only Mg, good mixing is observed up to about 30 wt. %, although surface sparking is observed at higher concentrations of the rutile. Adding B only, or with the Mg makes the clumping worse, and results in separation of the powder once mixing stops.

(27) With Ca but no Mg, the rutile titania exhibited good mixing, little sparking, and no surface segregation when the mixing is stopped. Much more titania could be included. The experiments stopped at 55 wt. %. The slurry with 55 wt. % titania was thick and had a consistency similar to semisolid aluminum billets. The addition of B to this had no appreciable effect.

(28) With Ca and Mg, the mixing was fair, and 55 wt. % of rutile was added. There were some lumps, but no segregation when mixing stopped. Inspection showed wetting was less than without the Mg, and the mixture was not as uniform. With B in addition, there is very poor wetting, and long lived sparks during the addition of the rutile. About 37 wt. % of rutile was added.

(29) The results of the experiments are clearly that using the rutile polymorph had a substantial positive correlation with the ability to integrate more titania in aluminum, that the inclusion of calcium had a substantial positive correlation with the ability to integrate more titania in aluminum (individually or jointly) and that the inclusion of B and Mg are jointly negatively correlated with integration of titania in molten aluminum.

(30) Applicant then produced wedges by high pressure die casting two formulations. In the first, 35 kg of commercially pure aluminum (>99.9%, Al P0404, AIM Metals and Alloys) were melted in an electric furnace. To this, 7 kg of aluminum-calcium master alloy (Al-10% Ca, Rand Alloys) was added. The rutile (>97%, 300-350 m, =3.9 g/cm.sup.3, app=1.87 g/cm.sup.3, UGSTM, Rio Tinto Iron and Titanium) was heated to 300 C. for at least 1 hour to remove moisture and mixed to the liquid aluminum in batches of around 300 g until an amount of 51 kg was added. The additions were made with the stir-casting technique using a mixer with a graphite shaft and impeller. The melt temperature was maintained at 70010 C. during the TiO.sub.2 additions. As in the previous tests, aluminum oxidation was reduced with argon (38 L/min) supplied by a ring made with a copper tube () and perforated holes placed above the crucible. The final composition of the mixture in weight percent was: Al-0.75% Ca-54.8% TiO.sub.2 and a series of 22 wedges were cast with it.

(31) The second casting campaign was carried out with boron addition. The preparation procedure was the same as the first campaign except that the amounts of components were: 22 kg of the commercially pure aluminum, 4.4 kg of the AlCa master alloy, 5.5 kg of AlB master alloy (Al-4% B, AIM Metals and Alloys) and 36.5 kg of rutile. The final composition of the mixture in weight percent was: Al-0.64% Ca-0.32% B-53.4% TiO2 and a series of 19 wedges were cast.

(32) A high pressure die casting press (Buhler, SC N/53) was used with a die to cast wedge plates and the intensification pressure that was typically 850 bar. Each wedge, with its feeding system and overflows, weighed approximately 2.5 kg and had the following dimensions: L=190 mm, W=100 mm, T=10 to 15 mm. During the first campaign, it was observed that the slurry was thinner at the beginning and thicker towards the end and this may have caused some variations in the amount of ceramic particles in the castings. The consistency of the slurry for the second casting campaign appeared more uniform, probably because of the slightly greater depth of the mixer impeller during preparation. Although the castings produced in both campaigns had, in some instances, surface imperfections, they were all visually in fair condition considering that no attempts were made to optimize the casting parameters.

(33) The solidification of pure aluminum is accompanied with relatively high volume shrinkage (6.7%) and this is often accompanied by hot tearing. While some modest amount of hot tearing was observed, it is believed to be possible to avoid these defects by optimizing the casting parameters. These castings were subjected to radiographic inspections and metallographic analyses that comprised optical microscopy, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS).

(34) The plates were examined with the X-ray inspection system, revealing the presence of plume-like zones in light gray which were less dense than the background. Since the specific gravity of TiO.sub.2 is 3.9 and that of solid aluminum is 2.7, lighter zones are thus considered poorer in TiO.sub.2. The density variations may originate from the feedstock with the AlTiO.sub.2 mixture being not entirely uniform or from segregation produced by shear forces during mold filling.

(35) The castings were cut longitudinally at the center. The left hand side of the plate was used to evaluate specific gravity while a sample for microscopy evaluation approximately 4 cm1.25 cm was extracted from the right hand side, at the mid height. Specific gravity measurements were carried out using Archimedes' principle assuming a law of mixture for pure aluminum and TiO.sub.2 and values for their respective specific gravity of 2.7 and 3.9. Even though the values are conservative, as porosity is not accounted for, the TiO.sub.2 contents are well below expected, suggesting that a reaction between TiO.sub.2 and aluminum may have taken place.

(36) Small samples taken from the right hand side of the wedges were first examined by optical microscopy from which mosaics were made. The one for casting No. 6 at the Al-0.75% Ca-54.8% TiO.sub.2 composition is shown in FIGS. 2a, b and was found to be typical. FIG. 2a shows TiO.sub.2 particles imbedded in aluminum and look as though they are sandwiched between a layer of aluminum at the top and bottom. This phenomenon has also been noticed with semi-solid aluminum and is mainly caused by the presence of a shearing gradient in the injected slurry which is maximal at the interface with the die. This gradient acts as a driving force for segregation. The layer is however quite thin (1 mm) and overall, the particles seem to be relatively well wetted and distributed.

(37) The samples were then examined at larger magnifications (FIG. 2c) with a scanning electron microscope (Hitachi SU-70 FEG SEM). FIG. 2c provides a picture of embedded ceramic particles around which bright layers with thin border lines can be seen. These layers were observed around all the embedded ceramic particles that were examined, whether boron was added or not. An analysis with an energy dispersive X-ray spectroscopy (EDS) system (Oxford EDS INCA 300) showed that most of the calcium was contained in that layer (see FIG. 2d, calcium shown in white). A series of EDS measurements were then carried out to map variations in chemical compositions. As shown in FIG. 2c, five locations that systematically corresponded to the following, were used to generate measurements identified as Spectra 1 to 5: Spectrum 1: In the aluminium matrix; Spectrum 2: In the dark layer around the particle; Spectrum 3: In a white part of the particle, just next to the dark layer; Spectrum 4: Inside the particle, at about half the radius; Spectrum 5: Inside the particle, approximately at the center. This analysis generated Table 1 data.

(38) TABLE-US-00001 TABLE 1 EDS measured compositions Spectrum O Al Si Ca Ti Fe Total Spectrum 1 99.69 0.31 100.00 Spectrum 2 15.32 80.47 0.67 3.18 0.37 100.00 Spectrum 3 39.34 5.61 0.40 54.08 0.56 100.00 Spectrum 4 38.59 6.74 0.31 53.68 0.68 100.00 Spectrum 5 37.45 26.49 0.18 35.88 100.00

(39) For each sample extracted from the 6 castings, this analysis was repeated on five different particles that were randomly selected for a total of 30 measurements (15 from castings without boron (campaign No. 1) and 15 from castings with boron (campaign No. 2). Differences between the results of the two campaigns are not significant and boron was not detected due to its small content and its low atomic weight. The discussion below thus applies to both sets of results.

(40) The composition at Spectrum 1 was taken in the matrix and consisted, as expected, almost exclusively of aluminum, with some reduced titanium. Spectrum 2, taken in the dark layer around the particles, is rich in aluminum and oxygen but also contains a fair amount of calcium. The presence of this calcium-containing layer bordering the embedded particles provides an explanation for the positive effect that calcium additions had in promoting integration of the particles with aluminum. The titanium content is small at this location. Spectrums 3, 4 and 5, all taken in the pale portion of the particles, show the presence of titanium, oxygen and aluminum at roughly 50 wt %, 35 wt % and 15 wt %, respectively. The 15 wt % aluminum content is relatively high and suggests that a reaction between TiO.sub.2 and aluminum took place. The weight percentages of these 3 elements correspond to a compound with an approximate stoichiometry of Ti.sub.2O.sub.4Al or (with respect to 1 mole of atoms) Ti.sub.0.286O.sub.0.571Al.sub.0.143. A brief literature review of the TiAlO ternary system has not revealed that compounds with this approximate composition have been reported. Although titanium aluminides such as Ti.sub.3Al and TiAl have some oxygen solubility, the amount measured here (35 wt %) appears too high to conclude that they are present, but this possibility is not ruled out.

(41) In conclusion, the preparation of an aluminum feedstock containing high concentrations of rutile TiO.sub.2 (in excess of 30 wt %, 40 wt. % and 50 wt. %) was made possible by adding a small quantity (<0.75 wt %) of calcium in the aluminum. Boron additions (0.3 wt %) were not found to have detrimental effects. Magnesium additions were also made (<2 wt %) but the effect was found to be small and negative, despite the prevalent opinion that Mg is the preferred wetting agent for aluminum. Marked differences were observed between anatase and rutile. EDS analysis showed the systematic presence of thin boundary layers around the embedded particles containing calcium. The considerable positive effect of calcium to the integration of TiO.sub.2 was attributed to the formation of this layer. The particles which initially consisted of TiO.sub.2 (60 wt % titanium and 40% oxygen) reacted and were found after integration to the melt to consist of titanium (50 wt %), oxygen (35 wt %) and aluminum (15 wt %).

(42) Two test bars were tested to estimate strength. The bars were composed of a matrix of Aluminum (>99 wt % purity) with particles that were TiO.sub.2 Rutile (>97 wt. % purity)+Silica (<3 wt. %) The particle granulometry was dp 50 of 300-350 m. The particle content in the matrix was 55 wt. %. The plates were extracted from high pressure die cast plates in the as-cast condition (no heat treatment, tempering or annealing). The bars were finished as required by ASTM standards for strength testing. Nonetheless, useful information about the bars were observed. The Young's modulus for the material was observed to be about 800.5 GPa; the yield strength was found to be 542 MPa; the tensile strength was found to be 6410 MPa; and the elongation was found to be 1.51%. These values appear to compare favourably with commercially available MMCs.

(43) A casting campaign was carried out with finer rutile powders (>99 wt. % purity), and found that even with nominally 30-50 m powders, 55 wt. % of rutile could be incorporated, although this was approaching a limit for the specific composition.

(44) Other advantages that are inherent to the structure are obvious to one skilled in the art. The embodiments are described herein illustratively and are not meant to limit the scope of the invention as claimed. Variations of the foregoing embodiments will be evident to a person of ordinary skill and are intended by the inventor to be encompassed by the following claims.