Rubber composition with high processability for run-flat tire
09944777 ยท 2018-04-17
Assignee
Inventors
Cpc classification
B60C15/0018
PERFORMING OPERATIONS; TRANSPORTING
C08L9/00
CHEMISTRY; METALLURGY
B60C1/00
PERFORMING OPERATIONS; TRANSPORTING
B60C9/08
PERFORMING OPERATIONS; TRANSPORTING
B60C2017/0054
PERFORMING OPERATIONS; TRANSPORTING
B60C2009/0475
PERFORMING OPERATIONS; TRANSPORTING
B60C9/0042
PERFORMING OPERATIONS; TRANSPORTING
B60C17/0009
PERFORMING OPERATIONS; TRANSPORTING
B60C2009/0035
PERFORMING OPERATIONS; TRANSPORTING
B60C15/0036
PERFORMING OPERATIONS; TRANSPORTING
B60C2001/0033
PERFORMING OPERATIONS; TRANSPORTING
C08L9/00
CHEMISTRY; METALLURGY
International classification
B60C9/00
PERFORMING OPERATIONS; TRANSPORTING
B60C17/00
PERFORMING OPERATIONS; TRANSPORTING
B60C9/08
PERFORMING OPERATIONS; TRANSPORTING
C08L9/00
CHEMISTRY; METALLURGY
B60C15/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The crosslinkable rubber composition comprises a first elastomer consisting of polybutadiene having a Mooney plasticity ranging from 40 to 70 Mooney units, the content of the first elastomer being strictly greater than 50 phr, a second elastomer, and a carbon black having a specific surface area within a range of values extending from 15 m.sup.2/g to 25 m.sup.2/g and an oil adsorption number of compressed sample (COAN) within a range of values extending from 65 ml/100 g to 85 ml/100 g.
Claims
1. A sidewall insert manufactured from a crosslinkable rubber composition comprising: a first elastomer consisting of polybutadiene having a Mooney plasticity ranging from 40 to less than 55 Mooney units; a second elastomer; and a carbon black having a specific surface area within a range of values extending from 15 m.sup.2/g to 25 m.sup.2/g and an oil adsorption number of compressed sample (COAN) within a range of values extending from 65 ml/100 g to 85 ml/100 g.
2. The sidewall insert according to claim 1, wherein the content of the first elastomer is greater than 50 phr.
3. The sidewall insert according to claim 1, wherein the content of the first elastomer is within a range of values extending from 50 to 80 phr.
4. The sidewall insert according to claim 3, wherein the content of the first elastomer is within a range of values extending from 55 to 75 phr.
5. The sidewall insert according to claim 4, wherein the content of the first elastomer is within a range of values extending from 60 to 70 phr.
6. The sidewall insert according to claim 1, wherein the second elastomer is a diene elastomer.
7. The sidewall insert according to claim 1, wherein the second elastomer is selected from the group consisting of polybutadienes, synthetic polyisoprenes, natural rubber, butadiene copolymers, isoprene copolymers and mixtures thereof.
8. The sidewall insert according to claim 1, wherein a content of carbon black is within a range of values extending from 30 to 100 phr.
9. The sidewall insert according to claim 8, wherein the content of carbon black is within a range of values extending from 35 to 80 phr.
10. The sidewall insert according to claim 9, wherein the content of carbon black is within a range of values extending from 40 to 75 phr.
11. The sidewall insert according to claim 10, wherein the content of carbon black is within a range of values extending from 40 to 60 phr.
12. A run-flat tire comprising a sidewall insert according to claim 1.
13. The run-flat tire according to claim 12 further comprising a carcass reinforcement comprising at least one carcass ply.
14. The run-flat tire according to claim 13, wherein the carcass reinforcement comprises a single carcass ply.
15. The run-flat tire according to claim 13, wherein the carcass ply comprises at least one reinforcing clement made of polyester.
Description
(1) The invention will be better understood on reading the following description, given solely by way of non-limiting example and with reference to the drawings in which:
(2)
(3)
(4)
(5) When using the term radial, a distinction should be made between several different uses of the word by the person skilled in the art. Firstly, the expression refers to a radius of the tyre. It is in that sense that a point A is said to be radially inside a point B (or radially on the inside of the point B) if it is closer to the axis of rotation of the tyre than is the point B. Conversely, a point C is said to be radially outside a point D (or radially on the outside of the point D) if it is further from the axis of rotation of the tyre than is the point D. Progress radially inwards (or outwards) will mean progress towards smaller (or larger) radii. In terms of radial distances, it is this sense of the word that applies also.
(6) On the other hand, a reinforcing element or a reinforcement is said to be radial when the reinforcing element or the reinforcing elements of the reinforcement make an angle greater than or equal to 65 and less than or equal to 90 with the circumferential direction.
(7) Finally, a radial cross section or radial section here means a cross section or a section in a plane which contains the axis of rotation of the tyre.
(8) An axial direction is a direction parallel to the axis of rotation of the tyre. A point E is said to be axially inside a point F (or axially on the inside of the point F) if it is closer to the median plane of the tyre than is the point F. Conversely, a point G is said to be axially outside a point H (or axially on the outside of the point H) if it is further from the median plane of the tyre than is the point H.
(9) The median plane of the tyre is the plane which is perpendicular to the axis of rotation of the tyre and which lies equal distances from the annular reinforcing structures of each bead.
(10) A circumferential direction is a direction which is perpendicular both to a radius of the tyre and to the axial direction.
EXAMPLES OF A TYRE ACCORDING TO THE INVENTION
(11)
(12) This tyre P1 comprises a crown 12 comprising a crown reinforcement 14, formed of two crown plies of reinforcing elements 16, 18 and of a hooping ply 19. The crown reinforcement 14 is surmounted by a tread 20. Here, the hooping ply 19 is positioned radially outside the plies 16, 18, between the plies 16, 18 and the tread 20. Two self-supporting sidewalls 22 extend the crown radially inwards.
(13) The tyre P1 additionally comprises two beads 24 radially inside the sidewalls 22 and each comprising an annular reinforcing structure 26, in this instance a bead wire 28, surmounted by a mass of filling rubber 30 on the bead wire, and a radial carcass reinforcement 32.
(14) The carcass reinforcement 32 preferably comprises a single carcass ply 34 of reinforcing elements 36, the ply 34 being anchored to each of the beads 24 by a turn-up around the bead wire 28, so as to form, within each bead 24, a main strand 38 extending from the beads through the sidewalls towards the crown, and a turn-up strand 40, the radially outer end 42 of the turn-up strand 40 being substantially midway up the height of the tyre. The carcass reinforcement 32 extends from the beads 24 through the sidewalls 22 towards the crown 12.
(15) The rubber compositions used for the crown plies 16, 18 and carcass ply 34 are conventional compositions for the calendering of reinforcing elements, typically based on natural rubber, carbon black, a vulcanization system and the usual additives. When the reinforcing elements are textile reinforcing elements, in particular here in the carcass reinforcement, adhesion between the textile reinforcing element and the rubber composition that coats it is ensured for example by a standard adhesive of RFL type.
(16) The tyre P1 also comprises two sidewall inserts 44, axially inside the carcass reinforcement 32. These inserts 44 with their characteristic crescent-shaped radial cross section are intended to reinforce the sidewall. Each insert 44 is manufactured from a rubber composition based on a crosslinkable rubber composition M1 described hereinbelow. Each sidewall insert 44 is capable of helping to support a load corresponding to a portion of the weight of the vehicle during a run-flat situation.
(17) Amongst other characteristics, the composition M1 comprises a first elastomer consisting of polybutadiene having a Mooney plasticity PMoo ranging from 40 to 70 Mooney units. In this instance, the first elastomer has a Mooney plasticity PMoo ranging from 40 to 65 Mooney units. Furthermore, the content of the first elastomer of M1 is within a range of values extending from 50 to 80 phr, preferably from 55 to 75 phr and more preferably from 60 to 70 phr.
(18) Moreover, in the composition M1, the content of the first elastomer is strictly greater than 50 phr.
(19) The composition M1 comprises a second elastomer forming, with the first elastomer, all of the rubber of the composition.
(20) The composition M1 comprises a carbon black having a specific surface area within a range of values extending from 15 m.sup.2/g to 25 m.sup.2/g and an oil adsorption number of compressed sample (COAN) within a range of values extending from 65 ml/100 g to 85 ml/100 g.
(21) The tyre also comprises an airtight inner layer 46, preferably made of butyl rubber, located axially inside the sidewalls 22 and radially inside the crown reinforcement 14 and extending between the two beads 24. The sidewall inserts 44 are located axially outside the inner layer 46. Thus, the sidewall inserts 44 are positioned axially between the carcass reinforcement 32 and the inner layer 46.
(22) The carcass ply 34 comprises textile reinforcing elements 36, one of which is illustrated in
(23) With reference to
(24) The polyester is selected from polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, polybutylene naphthalate, polypropylene terephthalate or polypropylene naphthalate. In this instance, the polyester is polyethylene terephthalate (PET).
(25) The count of each polyester multifilament strand 52, 54 is within a range of values extending from 100 to 500 tex, preferably from 300 to 370 tex. Here, the counts of the polyester multifilament strands 52, 54 are equal and have a value of 334 tex.
(26) The twist of each polyester multifilament strand 52, 54 before plying the multifilament strands together is within a range of values extending from 200 to 500 turns per meter, preferably from 200 to 340 turns per meter, and more preferably from 240 to 300 turns per meter. Here, the producer twists of the polyester multifilament strands 52, 54 before plying the multifilament strands together are equal and have a value of 270 turns per meter.
(27) The constituent elementary filaments of each polyester multifilament strand 52, 54 are plied with a twist factor of between 90 and 170 limits included, preferably between 120 and 150 limits included. Since the PET has a density equal to 1.38, the twist factor of each strand is here equal to 133.
(28) The reinforcing element has, for example, identical strands having the same twist. This is then a twist-balanced strand.
(29) For the manufacture of the reinforcing elements 36 by plying, it will be recalled here simply, in a manner well known to person skilled in the art, that each constituent strand of the final reinforcing element is firstly individually twisted on itself in a given direction (for example Z twisting of Y turns per meter of strand) during a first step in order to form an overtwist yarn, then that the strands thus twisted on themselves are subsequently plied together in the opposite direction (for example S twisting of X turns per meter of reinforcing element) in order to form a plied yarn, here the final reinforcing element 36.
(30) The twist before plying of each multifilament strand may be measured on the final reinforcing element by untwisting the constituent multifilament strands of the reinforcing element (for example by Z untwisting of X turns per meter of reinforcing element) until the reinforcing element no longer has any twist, then by untwisting each multifilament strand (for example by S untwisting of Y turns per meter) until each strand no longer has any twist. The number of turns per meter X, Y necessary for these two untwisting operations then respectively gives the producer twist of the reinforcing element (here X=270) and the twist of each multifilament strand before plying the strands together (here Y=270).
(31)
(32) Unlike the tyre P1 of the first embodiment, the tyre P2 according to the second embodiment is of the type having a shortened turn-up strand. The radially outer end 42 of the turn-up strand 40 is radially on the inside of the radially outermost end 48 of the bead 24 of the portion 50 of the bead 24 intended to bear against the rim flange.
(33)
(34) Unlike the tyre P1 according to the first embodiment, the carcass reinforcement 32 of the tyre comprises two carcass plies 34, 35. The carcass reinforcement 32 comprises a first carcass ply 34 anchored in each of the beads in a manner identical to that of the tyre P1 and a second carcass ply 35, placed next to the first carcass ply and stopping radially on the outside of the bead wire 28. The second carcass ply 35 is inserted between the main strand 38 and turn-up strand 40.
(35) In this third embodiment, the count of each polyester multifilament strand is within a range of values extending from 100 to 500 tex, preferably from 110 to 170 tex. Here, the counts of the polyester multifilament strands 52, 54 are equal and have a value of 144 tex.
(36) The twist of each polyester multifilament strand before plying the strands together is within a range of values extending from 200 to 500 turns per meter, preferably from 300 to 500 turns per meter, and more preferably from 380 to 470 turns per meter. Here, the producer twists of the polyester multifilament strands 52, 54 before plying the strands together are equal and have a value of 420 turns per meter.
(37) The twist factor K of each polyester strand is here equal to 136.
(38) A tye P4 according to a fourth embodiment of the invention was also manufactured.
(39) Unlike the tyre P1 according to the first embodiment, each insert 44 of the tyre P4 according to the fourth embodiment is manufactured from a rubber composition based on a crosslinkable rubber composition M2 described hereinbelow. Unlike the composition M1, the first elastomer has a Mooney plasticity PMoo such that 40 Mooney unitsPMmoo65 Mooney units, preferably such that 40 Mooney unitsPMoo60 Mooney units and more preferably such that 40 Mooney unitsPMoo55 Mooney units. More preferably still, the first elastomer has a Mooney plasticity PMoo such that 40 Mooney unitsPMmoo<55 Mooney units and more preferably still such that 40 Mooney unitsPMoo50 Mooney units.
(40) Examples of Compositions of the Sidewall Insert of the Tyre According to the Invention and Comparative Tests
(41) Various crosslinkable rubber compositions and the physical properties thereof are compared in Table 1. The amounts of the various components are given in parts by weight per hundred parts of elastomer (phr).
(42) The Mooney plasticity is measured according to the following principle and in accordance with the ASTM D-1646 standard. The generally uncured polybutadiene is moulded in a cylindrical chamber heated at a given temperature, usually 100 C. After preheating for one minute, an L-type rotor rotates within the test specimen at 2 revolutions/minute and the working torque for maintaining this movement is measured after rotating for 4 minutes. The Mooney plasticity (ML 1+4) is expressed in Mooney units (MU, with 1 MU=0.83 newton.Math.meter).
(43) The nominal secant moduli (or apparent stresses, in MPa) are measured in second elongation (i.e. after an accommodation cycle at the extension rate provided for the measurement itself) at 10% elongation (denoted by MA10) and at 100% elongation (denoted by MA100) at 23 C.2 C., and under normal hygrometry conditions (50%5% relative humidity) in accordance with the ASTM D-412 standard.
(44) The hysteresis losses, denoted by P60, are measured as percentage rebound at the sixth rebound at 60 C. in accordance with the following equation: HL (%)=100.Math.{(W0W1)/W1} in which W0 is the energy supplied and W1 is the energy returned.
(45) The flow measurements are carried out using a DOLI Ultimate flexometer manufactured by DOLI Industrie Electronik GMBH in accordance with the ASTM D-623 standard (Heat Generation and Flexing Fatigue in Compression) on test specimens having a length of 25 mm and a diameter of 17.8 mm. Each test lasts 3 hours, at the end of which period the percentage flow (variation in the height of the test specimen between the start and the end of the test, expressed in % of the initial height) of the test specimen subjected to repeated cyclic flexing, is recorded. If the test specimen breaks before the end of these 3 hours, the percentage flow is not measured. The test is carried out in a chamber at 90 C. with a pre-stress of 2 MPa and by giving rise to an elongation of 25% (6.25 mm) at a frequency of 30 Hz.
(46) The extrusion speed of the crosslinkable rubber composition is also measured by continuously manufacturing on an extruder a strip of the rubber composition to be tested of predetermined width. The length of strip manufactured over a predetermined time interval is measured. The extrusion speed of the strip in m.Math.min.sup.1 is deduced therefrom.
(47) In the table below, the caption NM means that the characteristic was not measured for the composition in question.
(48) TABLE-US-00001 TABLE 1 Formulations C1 C2 C3 C4 F2 M1 M2 Natural rubber 50 35 50 35 35 35 35 Tin-functionalized 50 polybutadiene, 50 MU Polybutadiene, 50 65 65 Mooney 44 MU Polybutadiene, 65 Mooney 63 MU Polybutadiene, 65 65 Mooney 75 MU Carbon black N650 50 50 50 Carbon black S204 50 50 50 50 Oil 2 Additives 9 9 9 8 9 9 9 Vulcanization system 6.2 6.2 6.2 5.5 6.2 6.2 6.2 Physical properties MA10 at 23 C. 6.6 6.4 6.4 6.5 6.2 6.8 6.8 (MPa) MA100 at 23 C. 4.9 4.3 4.6 4.7 4.3 4.3 4.4 (MPa) P60 (%) 5.9 6.4 5.6 6.5 5.5 6.8 6.8 Flow (%) 4.5 14 6.9 23 2.9 NM NM Processability properties Extrusion speed NM NM NM NM 1.5 2 6.5 (m .Math. min.sup.1)
(49) The compositions C1 to C4 and F2 are control crosslinkable rubber compositions. The compositions M1, M2 are crosslinkable rubber compositions according to the invention.
(50) Each composition C1 to C4, F2 and M1, M2 comprises two elastomers, here two elastomers of diene type, here a polybutadiene and natural rubber.
(51) Each composition C1 to C4, F2 and M1, M2 comprises additives comprising N-1,3-dimethylbutyl-N-phenyl-para-phenylenediamine (Santoflex 6-PPD from FLEXSYS), 2,2,4-trimethyl-1,2-dihydroquinoline polymer (TMQ), zinc oxide and stearic acid.
(52) Each composition C1 to C4, F2 and M1, M2 comprises a conventional vulcanization system comprising accelerators and insoluble sulphur. The composition C2 comprises a paraffinic oil.
(53) The tin-functionalized polybutadiene (Nipol BR 1250H) used in the composition C1 has a Mooney plasticity equal to 50 MU and a content of cis-1,4-units equal to 35%. The polybutadiene (Buna CB21, LANXESS) used in the compositions C2 and F2 has a Mooney plasticity equal to 75 MU and a content of cis-1,4-units equal to 96%. The polybutadiene (Buna CB24, LANXESS) used in the compositions C3, C4 and M2 has a Mooney plasticity equal to 44 MU and a content of cis-1,4-units equal to 96%. The polybutadiene (Buna CB22, LANXESS) used in the composition M1 has a Mooney plasticity equal to 63 MU and a content of cis-1,4-units equal to 96%.
(54) The carbon black having a low specific surface area and a high structure S204 is sold by Orion Engineered Carbons. The carbon black S204 has a specific surface area equal to 19 m.sup.2/g, an oil adsorption number (OAN) equal to 138 ml/100 g, an oil adsorption number of compressed sample (COAN) equal to 76 ml/100 g and an iodine number equal to 19.6 mg/g.
(55) The various compositions C1 to C4, F2 and M1, M2 were manufactured in a Banbury mixer by mixing, in a first step, the components from Table 1, with the exception of the vulcanization system, until the components are dispersed and until a temperature between 130 C. and 170 C. is achieved. Then, in a second step, the vulcanization system is added in a mixer. The composition is cured at 150 C. for 25 minutes.
(56) The composition C1 comprises a functionalized polybutadiene and a conventional N650 carbon black for a sidewall insert of a run-flat tyre of the prior art.
(57) In the composition C2, the functionalized polybutadiene from C1 was replaced by an unfunctionalised polybutadiene having a high Mooney plasticity. However, the composition C2 has insufficient stiffness (MA10 at 23 C.) and too high a flow.
(58) The composition C3 comprising a polybutadiene having a low Mooney plasticity with a content less than or equal to 50 phr, here 50 phr and a carbon black having a low specific surface area and a high structure, has insufficient stiffness (MA10 at 23 C.).
(59) The properties of the composition C4 comprising a conventional N650 carbon black are even worse than those of C3, in particular the flow which is too high.
(60) The composition F2, comprising a carbon black having a low specific surface area and a high structure and also a polybutadiene having a Mooney plasticity of greater than 70 MU, has satisfactory physical properties but a limited extrusion speed.
(61) The rubber compositions M1, M2 have a modulus of elongation MA10 at 23 C. of between 5.5 MPa and 7 MPa, preferably between 6 MPa and 7 MPa and more preferably between 6.5 MPa and 7 MPa.
(62) Furthermore, each composition M1 and M2 has a hysteresis loss P60 of less than 8%, preferably less than 7%.
(63) Each composition M1, M2 has stiffness properties, in particular the MA10 at 23 C., that enable the sidewall insert to provide the EM running performance. In addition, each composition M1, M2 has a processing property, here the extrusion speed, superior to that of the other control compositions, in particular F2.
(64) Thus, the compositions M1 and M2 comprising a predominant content of polybutadiene having a relatively low Mooney plasticity PMoo and a carbon black having a low specific surface area and a high structure in accordance with the invention have physical properties that are compatible with use in a sidewall insert of a run-flat tyre and a high processability.
(65) Characteristics of the reinforcing element 36 of tyres P1 to P4 in accordance with the embodiments of the invention described above and of reinforcing elements of other tyres of the prior art are compared in Table 2.
(66) Among other characteristics, each tyre P1 to P4 comprises a carcass reinforcement comprising polyester reinforcing elements and two sidewall inserts manufactured from a rubber composition based on one of the crosslinkable rubber compositions M1, M2 described above.
(67) The tyre I is of standard type not provided with self-supporting sidewalls and comprises a carcass reinforcement comprising a single carcass ply. The carcass ply comprises textile reinforcing elements made of polyester.
(68) The tyre II is a run-flat tyre and comprises a carcass reinforcement comprising two carcass plies. Each carcass ply comprises textile reinforcing elements. Each reinforcing element comprises two multifilament strands made of rayon that are plied together. The tyre II comprises sidewall inserts manufactured from a rubber composition based on the control crosslinkable rubber composition C1 described above.
(69) All the properties indicated are measured on sized textile reinforcing elements (i.e. ones that are ready to use, or else that have been extracted from the tyre that they reinforce) that have been subjected to a pre-conditioning; the term conditioning is understood to mean the storage of the cords (after drying) for at least 24 hours, before measurement, in a standard atmosphere according to the DIN EN 20139 European standard (temperature of 202 C.; hygrometry of 65%2%).
(70) The count (or linear density) of the elementary strands or of the reinforcing elements is determined on at least two samples, each corresponding to a length of at least 5 m, by weighing this length; the count is given in tex (weight in grams of 1000 m of productremember: 0.111 tex is equal to 1 denier).
(71) TABLE-US-00002 TABLE 2 Tyre I II P1/P2/P4 P3 Composition of NA C4 M1/M1/M2 M1 the sidewall inserts Nature of the PET/PET Rayon/Rayon PET/PET PET/PET strands Count of the 334/334 184/184 334/334 144/144 strands (tex) Twists of the 270/270 480/480 270/270 420/420 strands (turns/m) Diameter (mm) 0.96 0.68 0.96 0.62 Twist factor of 133 170 133 136 each strand Breaking force 40 17 40 17 (daN) of the reinforcing element Glass transition 110 NA 110 110 temperature ( C.) Melting point 260 NA 260 260 ( C.) Degradation ~350 ~350 ~350 ~350 temperature ( C.)
(72) The caption NA (not applicable) means that the value does not exist or has no significance.
(73) The PET is sold by Performance Fibers under the name 150. The rayon is sold by Cordenka under the name Super 3-T700.
(74) The IM running performance of the tyres I, II, P3 and P4 and the EM running performance of the tyres I, II, P1 to P4 are compared in Table 3.
(75) Mass of the Tyre
(76) The value of the mass is indicated in relative units (base 100) in relation to the mass of the tyre I of the prior art. The higher the mass in comparison with that of the tyre I of the prior art, the greater the extent to which the value is lower than 100.
(77) Rolling Resistance
(78) The rolling resistance is measured, after a thermal stabilization step, from measuring the deceleration of a wheel provided with the tested tyre pressed against a test flywheel. The load applied is equal to 85% of the ETRTO (European Tyre and Rim Technical Organisation) load.
(79) The rolling resistance value is indicated in relative units (base 100) in relation to the rolling resistance of the tyre I of the prior art. The higher the rolling resistance in comparison with that of the tyre I of the prior art, the greater the extent to which the value is lower than 100.
(80) Comfort
(81) Comfort is determined from a vertical firmness measurement. The vertical firmness measurement is carried out on a wheel comprising a dynamometric hub on which the tested tyre is mounted. The wheel is pressed against a test flywheel under a load equal to 80% of the ETRTO load. The flywheel comprises a bar acting as an obstacle. The vertical firmness of the tyre is determined from the force measured by the dynamometric hub. The higher the force, the greater the vertical firmness and the lower the perception of comfort.
(82) The vertical firmness value is indicated in relative units (base 100) in relation to the vertical firmness of the tyre I of the prior art. The lower the vertical firmness in comparison with that of the tyre I of the prior art and therefore the better the comfort, the closer the value is to 100.
(83) Run-Flat Test
(84) The run-flat test is carried out in accordance with UNECE regulation 30. A value of 0 indicates that the tested tyre failed the run-flat test. A value of 1 indicates that the tested tyre successfully passed the run-flat test
(85) TABLE-US-00003 TABLE 3 Tyre I II P1 P2 P3 P4 Mass of the tyre 100 79 NM NM 80 82 Rolling resistance 100 94 NM NM 96 97 Vertical firmness 100 92 NM NM 90 92 Run-flat test 0 1 1 1 1 1
(86) In the table above, the caption NM means that the characteristic was not measured for the tyre in question.
(87) The results of Table 3 indicate that the tyres according to the invention provide the required EM running performance (value of 1 for the run-flat test). It will furthermore be noted that, advantageously, the tyres P1 to P4 satisfy the EM running performance while avoiding the use of rayon within the carcass plies owing to a combination of the composition according to the invention and of polyester reinforcing elements. The tyres P3 and P4, but also by transitivity of the results, the tyres P1 and P2, have, among the run-flat tyres (tyres II, P1 to P4), the IM running performance closest to the standard tyre I. Although their IM running performance is inferior to that of the standard tyre I, each tyre according to the invention has IM running performance superior or equal to that of run-flat tyre II while avoiding the use of rayon within the carcass plies. Moreover, the carcass ply of each tyre according to the invention has a breaking force at least equal to that of tyres I and II.
(88) The invention is not limited to the embodiments described above.
(89) The reinforcing elements could be made from a textile material other than polyester. For example, the textile material could also be selected from a polyamide, a polyketone, a cellulose or a mixture of these materials.
(90) An embodiment could be conceived of in which the turn-up strand 40 extends up between the crown reinforcement 14, here the crown ply 18, and the main strand 38. In this case, the tyre is generally referred to as a tyre of shoulder lock architecture in order to indicate that the turn-up strand 40 is locked at the shoulder between the main strand 38 and the crown reinforcement 18. Such an architecture makes it possible to reinforce the tyre at the shoulder of the latter.
(91) An embodiment could also be conceived of in which the carcass reinforcement comprises an auxiliary reinforcing element extending between the bead 24 and the crown 12 of the tyre. This auxiliary reinforcing element is inserted between the main strand 38 and the turn-up strand 40 and extends up between the crown ply 18 and the main strand 38.
(92) These two embodiments above are particularly advantageous in instances in which the tyre comprises a single carcass ply, the turn-up strand 40 or the auxiliary reinforcing element providing additional reinforcement in the shoulder zone of the tyre.
(93) Furthermore, each multifilament strand may have a twist different from that of the other multifilament strand or strands so as to obtain a reinforcing element that is not twist-balanced.
(94) It may also be possible to combine the features of the various embodiments described or envisaged above, as long as these are compatible with one another.