Raw water channel spacer and spiral wound membrane element including the same
11484840 · 2022-11-01
Assignee
Inventors
Cpc classification
B01D65/02
PERFORMING OPERATIONS; TRANSPORTING
B32B3/28
PERFORMING OPERATIONS; TRANSPORTING
B32B27/12
PERFORMING OPERATIONS; TRANSPORTING
B01D61/025
PERFORMING OPERATIONS; TRANSPORTING
D04H3/02
TEXTILES; PAPER
D04H3/04
TEXTILES; PAPER
International classification
B32B27/12
PERFORMING OPERATIONS; TRANSPORTING
D04H3/04
TEXTILES; PAPER
D04H3/02
TEXTILES; PAPER
B01D65/08
PERFORMING OPERATIONS; TRANSPORTING
B32B3/28
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A raw water channel spacer capable of suppressing formation of a concentration polarization layer in a region in the vicinity of a separation membrane in a raw water channel, and a spiral wound membrane element including the same are provided. A raw water channel spacer is formed by superposing a first yarn row and a second yarn row, and includes alternately a first mesh structure having a configuration in which first rectangular meshes formed of the yarn rows are continuous in an extending direction of the second yarn row, and a second mesh structure having a configuration in which meshes are continuous in the extending direction of the second yarn row such that an interval in the second yarn row is smaller than an interval of the second yarn row forming the first mesh structure.
Claims
1. A raw water channel spacer having a two-layer structure that is adapted to be sandwiched between a first separation membrane and a second separation membrane in a state in which the first separation membrane, the two-layer structure, and the second separation membrane are all wound around a water collecting pipe of a spiral wound membrane element, the two-layer structure comprising: a first layer that includes first rows of parallel yarns and a second layer that includes second rows of parallel yarns, the first rows of parallel yarns and the second rows of parallel yarns being inclined in opposite directions from each other with respect to a flow direction across the two-layer structure, and the first rows of parallel yarns and the second rows of parallel yarns alternatingly forming a first mesh region and a second mesh region, wherein the first mesh region and the second mesh region alternate throughout the raw water channel spacer, the first mesh region extends in an extending direction of the second rows of parallel yarns so as to be parallel to the second mesh region, and the first mesh region comprising mesh openings formed by the first rows of parallel yarns and the second rows of parallel yarns; the second mesh region extends in the extending direction of the second rows of parallel yarns so as to be parallel to the first mesh region, and the second mesh region comprising mesh openings formed by the first rows of parallel yarns and the second rows of parallel yarns, wherein spacing between the second rows of parallel yarns forming the second mesh region is smaller than spacing between the second rows of parallel yarns forming the first mesh region; wherein the first layer is provided on one side of the second layer, wherein the first layer is formed only by the first rows of parallel yarns and the second layer is formed only by the second rows of parallel yarns, wherein one pattern of the first mesh region and another pattern of the first mesh region alternate, in the extending direction of the second rows of parallel yarns, throughout the raw water channel spacer, and the mesh openings that form the one pattern of the first mesh region are different in size from the mesh openings that form the another pattern of the first mesh region, wherein one pattern of the second mesh region and another pattern of the second mesh region alternate, in the extending direction of the second rows of parallel yarns, throughout the raw water channel spacer, and the mesh openings that form the one pattern of the second mesh region are different in size from the mesh openings that form the another pattern of the second mesh region, and wherein the first mesh region and the second mesh region alternate, throughout the raw water channel spacer, in an extending direction of the first rows of parallel yarns.
2. The raw water channel spacer according to claim 1, wherein an inclination, with respect to the flow direction across the two-layer structure, of the first rows of parallel yarns forming the second mesh region is larger than an inclination, with respect to the flow direction across the two-layer structure, of the first rows of parallel yarns forming the first mesh region.
3. The raw water channel spacer according to claim 2, wherein the first mesh region is configured by alternatingly arranging a first set of mesh openings as the one pattern of the first mesh region and a first set of intermediate mesh openings as the another pattern of the first mesh region, the first set of intermediate mesh openings having smaller mesh openings than the mesh openings of the first set of mesh openings, and the second mesh region is configured by alternatingly arranging a second set of intermediate mesh openings as the one pattern of the second mesh region and a second set of mesh openings as the another pattern of the second mesh region, the second set of mesh openings having smaller mesh openings than the second set of intermediate mesh openings.
4. A spiral wound membrane element comprising: a water collecting pipe through which permeate flows; a sheet-like permeate spacer; a first separation membrane and a second separation membrane that are each formed in a bag shape in which three sides are sealed in a state where the separation membranes are superimposed on both surfaces of the permeate spacer, and the other side is made to be an open end, the separation membranes wound around the water collecting pipe in a state where the open end is connected to the water collecting pipe; and the raw water channel spacer according to claim 3.
5. A raw water channel spacer having a two-layer structure that is adapted to be sandwiched between a first separation membrane and a second separation membrane in a state in which the first separation membrane, the two-layer structure, and the second separation membrane are all wound around a water collecting pipe of a spiral wound membrane element, the two-layer structure comprising: a first layer that includes first rows of parallel yarns and a second layer that includes second rows of parallel yarns, the first rows of parallel yarns and the second rows of parallel yarns being inclined in opposite directions from each other with respect to a flow direction across the two-layer structure, and the first rows of parallel yarns and the second rows of parallel yarns alternatingly forming a first mesh region and a second mesh region, wherein the first mesh region and the second mesh region alternate throughout the raw water channel spacer, the first mesh region extends in an extending direction of the second rows of parallel yarns so as to be parallel to the second mesh region, and the first mesh region comprising mesh openings formed by the first rows of parallel yarns and the second rows of parallel yarns; the second mesh region extends in the extending direction of the second rows of parallel yarns so as to be parallel to the first mesh region, and the second mesh region comprising mesh openings formed by the first rows of parallel yarns and the second rows of parallel yarns, wherein spacing between the second rows of parallel yarns forming the second mesh region is smaller than spacing between the second rows of parallel yarns forming the first mesh region; wherein the first layer is provided on one side of the second layer, wherein the first layer is formed only by the first rows of parallel yarns and the second layer is formed only by the second rows of parallel yarns, and wherein the first mesh region is configured by alternatingly arranging a first pair of mesh openings and a first pair of intermediate mesh openings having smaller mesh openings than the mesh openings of the first pair of mesh openings, and the second mesh region is configured by alternatingly arranging a second pair of intermediate mesh openings and a second pair of mesh openings having smaller mesh openings than the second pair of intermediate mesh openings.
6. A spiral wound membrane element comprising: a water collecting pipe through which permeate flows; a sheet-like permeate spacer; a first separation membrane and a second separation membrane that are each formed in a bag shape in which three sides are sealed in a state where the separation membranes are superimposed on both surfaces of the permeate spacer, and the other side is made to be an open end, the separation membranes wound around the water collecting pipe in a state where the open end is connected to the water collecting pipe; and the raw water channel spacer according to claim 1.
7. A spiral wound membrane element comprising: a water collecting pipe through which permeate flows; a sheet-like permeate spacer; a first separation membrane and a second separation membrane that are each formed in a bag shape in which three sides are sealed in a state where the separation membranes are superimposed on both surfaces of the permeate spacer, and the other side is made to be an open end, the separation membranes wound around the water collecting pipe in a state where the open end is connected to the water collecting pipe; and the raw water channel spacer according to claim 2.
8. A spiral wound membrane element comprising: a water collecting pipe through which permeate flows; a sheet-like permeate spacer; a first separation membrane and a second separation membrane that are each formed in a bag shape in which three sides are sealed in a state where the separation membranes are superimposed on both surfaces of the permeate spacer, and the other side is made to be an open end, the separation membranes wound around the water collecting pipe in a state where the open end is connected to the water collecting pipe; and the raw water channel spacer according to claim 5.
9. A raw water channel spacer having a two-layer structure that is adapted to be sandwiched between a first separation membrane and a second separation membrane in a state in which the first separation membrane, the two-layer structure, and the second separation membrane are all wound around a water collecting pipe of a spiral wound membrane element, the two-layer structure comprising: a first layer that includes first rows of parallel yarns and a second layer that includes second rows of parallel yarns, the first rows of parallel yarns and the second rows of parallel yarns being inclined in opposite directions from each other with respect to a flow direction across the two-layer structure, and the first rows of parallel yarns and the second rows of parallel yarns alternatingly forming a first mesh region and a second mesh region, the first mesh region extends in an extending direction of the second rows of parallel yarns so as to be parallel to the second mesh region, and the first mesh region comprising mesh openings formed by the first rows of parallel yarns and the second rows of parallel yarns; the second mesh region extends in the extending direction of the second rows of parallel yarns so as to be parallel to the first mesh region, and the second mesh region comprising mesh openings formed by the first rows of parallel yarns and the second rows of parallel yarns, wherein spacing between the second rows of parallel yarns forming the second mesh region is smaller than spacing between the second rows of parallel yarns forming the first mesh region; wherein the first layer is provided on one side of the second layer; and further comprising: (i) the first rows of parallel yarns having a repeating pattern defined by: three consecutively arranged parallel yarns that are equally spaced by a first spacing distance in the extending direction of the second rows of parallel yarns, a fourth consecutively arranged parallel yarn extending adjacent one of the three consecutively arranged parallel yarns, the fourth consecutively arranged parallel yarn being spaced from the adjacent one of the three consecutively arranged parallel yarns by a second spacing distance in the extending direction of the second rows of parallel yarns, and the second spacing distance being larger than the first spacing distance; and (ii) the second rows of parallel yarns having a repeating pattern defined by: three consecutively arranged parallel yarns that are equally spaced by a third spacing distance in the extending direction of the first rows of parallel yarns, a fourth consecutively arranged parallel yarn extending adjacent one of the three consecutively arranged parallel yarns, the fourth consecutively arranged parallel yarn being spaced from the adjacent one of the three consecutively arranged parallel yarns by a fourth spacing distance in the extending direction of the first rows of parallel yarns, and the fourth spacing distance being larger than the third spacing distance.
10. The raw water channel spacer according to claim 9, further comprising: the first rows of parallel yarns being oriented at a 45° angle with respect to the flow direction across the two-layer structure, and the second rows of parallel yarns being oriented at a 90° angle with respect to the first rows of parallel yarns.
11. The raw water channel spacer according to claim 9, wherein the first rows of parallel yarns and the second rows of parallel yarns each have a same diameter.
12. The raw water channel spacer according to claim 10, wherein the first rows of parallel yarns and the second rows of parallel yarns each have a same diameter.
13. The raw water channel spacer according to claim 10, wherein the first rows of parallel yarns and the second rows of parallel yarns are made of a polyester, polyethylene, or polypropylene material.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
BEST MODE FOR CARRYING OUT THE INVENTION
(17) A filtration device including a spiral wound membrane element according to an embodiment of the present invention will be described below with reference to the drawings. In the following description, an “X” direction indicates a direction parallel to an axial direction of a water collecting pipe, and a “Y” direction and a “Z” direction indicate radial directions of the water collecting pipe orthogonal to each other.
(18) As shown in
(19) The spiral wound membrane element 20 has a function of producing permeate obtained by removing ions and salts from the raw water, and concentrate containing the removed ions and salts. The permeate produced by the spiral wound membrane element 20 is stored in a permeate tank 18 via a permeate pipe L3, and the concentrate is discharged to the outside via a concentrate pipe 14.
(20)
(21) As shown in
(22) In the first separation membrane 24, separation membranes 24a, 24b formed of, for example, a reverse osmosis membrane, an ultrafiltration membrane, or a microfiltration membrane, are superimposed with each other on both sides with a permeate spacer 26 interposed therebetween to form a bag shape, and the opening end is connected to the water collecting pipe 22. The permeate spacer 26 forms a channel communicating with the water collecting pipe 22, and the permeate that has permeated through the separation membranes 24a, 24b along this channel flows into the water collecting pipe 22.
(23) A plurality of communicating holes 22a, 22b, 22c are provided in the water collecting pipe 22 at a predetermined pitch along an axial direction, and the permeate that has permeated through both the separation membranes 24, 28 flows into the water collecting pipe 22 from the communicating holes 22a through 22c. The other three sides excluding the open end of the first separation membrane 24 are sealed with an adhesive or the like to prevent, mixing of the permeate and the concentrate.
(24) As shown in
(25) An upstream cap member 32 and a downstream cap member 34 may be attached to both axial end surfaces of the spiral wound membrane element 20. The upstream cap member 32 is provided with a gap through which the raw water flows into the spiral wound membrane element 20. The downstream cap member 34 is provided with two channels so that the permeate flowing through the water collecting pipe 22 and the concentrate discharged from the raw water channel are not mixed with each other.
(26) Next, a configuration of the raw water channel spacer 40 will be described with reference to
(27) As shown in
(28) As shown in
(29) A first side portion. 52a-1 and a second side portion 52a-2 of the first rectangular mesh 52a are formed by first yarns M1, M2, respectively, and a third side portion 52a-3 and a fourth side portion 52a-4 are formed by the second yarns N2, N3. As an example, the first rectangular mesh 52a has an appearance of a square shape configured such that the dimension of each of the side portions 52a-1 to 52a-4 is 3 mm. The yarn rows M, N are arranged so as to incline in opposite directions, for example, by 45° with respect to the X direction. Each of the yarn rows M, N is formed of a resin material such as polyester, polyethylene, or polypropylene, for example, in a cylindrical shape having a diameter D of 0.4 mm. A width F of the raw water channel formed by the raw water channel spacer 40 is 0.8 mm, as an example. The shape of each of the yarn rows M, N is not limited to a columnar shape, and may be formed in a flat plate shape or the like, for example.
(30) Since the second mesh structures 61 to 63 have the same configuration, only the second mesh structure 61 will be described, and the second mesh structures 62, 63 will not be described as appropriate. In the second mesh structure 61, the second rectangular meshes 61a, 61b, 61c having the same configuration are formed to be continuous in an extending direction of second yarns N1, N2.
(31) The first side portion 61a-1 and the second side portion 61a-2 of the second rectangular mesh 61a are formed by the first yarns M1, M2, respectively, and the third side portion 61a-3 of the second rectangular mesh 61a is formed by the second yarn N1. The fourth side portion of the second rectangular mesh 61a is formed of the third side portion 52a-3 in the above-described first rectangular mesh 52a. For example, the second rectangular mesh 61a may be formed in a parallelogram shape with the dimension of each of the side portions 61a-1, 61a-2, 61a-3 being 3 mm.
(32) Here, the second rectangular mesh 61a is configured such that an inclination angle α1 of the first side portion 61a-1 and the second side portion 61a-2 with respect to the X direction is larger than an inclination angle α2 of the first side portion 52a-1 and the second side portion 52a-2 of the first rectangular mesh 52a with respect to the X direction, by bending the first yarns M1, M2. As an example, the inclination angle α1 may be 90° and the inclination angle α2 may be 45°. An interval R1 between both the side portions 61a-1, 61a-2 in the second rectangular mesh 61a is formed to be smaller than an interval between both the side portions 52a-1, 52a-2 in the first rectangular mesh 52a (that is, a length of the third side portion 52a-3).
(33) Similarly, an interval R2 between both the side portions 52a-3, 61a-3 in the second rectangular mesh 61a is formed to be smaller than an interval between both the side portions 52a-3, 52a-4 in the first rectangular mesh 52a (that is, a length of the first side portion 52a-1).
(34) As a result, the second rectangular mesh 61a is configured to have a finer mesh (that is, a smaller surrounding area) than the first rectangular mesh 52a, and is provided such that a resistance (hereinafter referred to as “channel resistance”) that the raw water flowing an the X direction receives from the channel is large. Accordingly, a channel resistance of the second mesh structure 61 configured by the meshes having the same configuration as the second rectangular mesh 61a being continuous is larger than a channel resistance of the first mesh structure 52 configured by the meshes of the same configuration as the first rectangular mesh 52a being continuous.
(35) Here, the raw water flow in each of the mesh structures 52, 61, 62 will be described with reference to
(36) An extending direction of each of the mesh structures 52, 61, 62 inclines with respect to the X direction as shown in
(37) The rectangular meshes 52a, 61a, 62a are arranged adjacently in an order of the second rectangular mesh 61a, the first rectangular mesh 52a, and the second rectangular mesh 62a from the upstream side in the X direction. In the second rectangular mesh 61a, part of the raw water flows into the first rectangular mesh 52a while meandering toward the second separation membrane 28 along a flow C1. This makes it possible to increase the flow speed of the raw water in the region close to the second separation membrane 28 and to sweep away remaining ions and salts retained in the region close to the second separation membrane 28 to the downstream side.
(38) Similarly, in the first rectangular mesh 52a, a part of the raw water flows into the second rectangular mesh 62a while meandering toward the second separation membrane 28 along a flow C2. As a result, residual ions and salts retained in the region close to the second separation membrane 28 can be swept away to the downstream side.
(39) As described above, the channel resistance of the second rectangular meshes 61a, 62a forming a part of the second mesh structures 61, 62 is larger than the channel resistance of the first rectangular mesh 52a forming a part of the first mesh structure 52. Therefore, as shown in
(40) Therefore, among the raw water flows flowing while meandering along flows S1, S2, S3 around the side portions 52a-2, 61a-2, 62a-2 (see
(41) On the other hand, the flow rates of the flows S2, S3 of the raw water in the second rectangular meshes 61a, 62a are smaller than the flow rate of the flow S1. However, the interval R1 (see
(42)
(43) As shown in
(44) A proportion of an area of the region where the magnitude of the shear stress acting on each of the separation membranes 24, 28 is 0.75 Pa or less, that is, the region where the flow of the raw water in the region close to each of the separation membranes 24, 28 is gentle and the effect of the raw water to sweep away the residual ions and salts is small to the surfaces of both the separation membranes 24, 28 was 16%. In the following description, the above-mentioned region where the magnitude of the shear stress is 0.75 Pa or less is referred to as an easy-polarization region. The average value of the shear stress acting on both the separation membranes 24, 28 shown in
(45)
(46) As shown in
(47) As shown in
(48) As described above, in the raw water channel spacer 300 of the comparative example, as in the raw water channel spacer 40 of the present embodiment, no large shear stress acts on both the separation membranes 24, 28, and the proportion of the area of the easy-polarization region formed in both the separation membranes 24, 28 is 20% which is relatively high. Thus, the residual ions and salts in the region close to both the separation membranes 24, 28 cannot be swept away thoroughly.
(49) It is conceivable that a raw water channel spacer formed only of the second mesh structures 61, 62, 63 is used, but in this case, the pressure loss caused by the raw water channel spacer is excessive. Thus, there is also a problem that the raw water channel spacer is swept away to the downstream side and a telescope phenomenon occurs.
(50) In contrast, in the raw water channel spacer 40 of the present embodiment, the first mesh structures 51, 52, 53 and the second mesh structures 61, 62, 63 are arranged alternately, and the raw water flowing in the X direction is harder to pass through the second mesh structures 61, 62, 63 than through the first mesh structures 51 to 53. Thus, for example, it is possible to increase the flow rate of the raw water flowing from the second rectangular mesh 61a in the second mesh structure 61 to the first rectangular mesh 52a in the first mesh structure 52. As a result, the same level of the shear stress as that acting on both the separation membranes 24, 28 in the region surrounded by the second rectangular mesh 61a can act on both the separation membranes 24, 28 in the region surrounded by the first rectangular mesh 52a.
(51) As a result, according to the raw water channel spacer 40, formation of the concentration polarization layer can be suppressed by sweeping away the ions and salts remaining in the region in the vicinity of both the separation membranes 24, 28, while an increase in the pressure loss is prevented.
(52) According to the raw water channel spacer 40, a large shear stress can act on both the separation membranes 24, 28, so that it is possible to suppress occurrence of biofouling, that is, a state where both the separation membranes 24, 28 are clogged by a substance derived from bacterial cells such as a biofilm.
(53) Next, modifications of the raw water channel spacer of the present embodiment will be described with reference to
(54) Table 1 shown in
(55) As shown in
(56) As shown in
(57) As shown in
(58) As shown in
(59) If the inclination angle is made larger than the inclination angle α1 of the raw water channel spacer shown in Modification 4, the first mesh structure and the second mesh structure interfere with each other, making manufacturing difficult. Therefore, it is preferable to set the inclination angle α1 to 120° or less.
(60) As described above, also in the configurations of Modifications 1 to 4, formation of the concentration polarization layer can be suppressed as similar to the raw water channel spacer 40 of the above embodiment.
(61) Table 2
(62) A raw water channel spacer 110 of Modification 5 alternately includes a first mesh structure 112 and a second mesh structure 114 shown in
(63) A raw water channel spacer 120 of Modification 6 alternately includes a first mesh structure 122 and a second mesh structure 124 shown in
(64) A raw water channel spacer 130 of Modification 7 alternately includes a first mesh structure 132 and a second mesh structure 134 shown in
(65) A raw water channel spacer 140 of Modification 8 alternately includes a first mesh structure 142 and a second mesh structure 144 shown in
(66) The raw water channel spacer 150 of Modification 9 alternately includes a first mesh structure 152 and a second mesh structure 154 shown in
(67) As described above, also in the configurations of Modifications 5 to 9, formation of the concentration polarization layer can be suppressed as similar to the raw water channel spacer 40 of the above embodiment.
(68)
(69) As shown in
(70) As shown in
(71) The first mesh structure 172 is configured by alternately arranging along the extending direction of the second yarn row B, a first mesh 172a-1 formed of the first yarns A1 to A3 and the second yarns B1 to B3, and an intermediate mesh 172a-2 formed of the first yarns A3 to A5 and the second yarns B1 to B3. The first mesh 172a-1 has, for example, an appearance of a square shape. On the other hand, the intermediate mesh 172a-2, for example, has an appearance of a rectangular shape and is configured to have a finer mesh than the first mesh 172a-1. Therefore, when the first mesh 172a-1 and the intermediate mesh 172a-2 are compared, the channel resistance of the first mesh 172a-1 is smaller than that of the intermediate mesh 172a-2.
(72) The second mesh structure 182 is configured by alternately arranging along the extending direction of the second yarn row B, an intermediate mesh 182a-1 formed of the first yarns A1 to A3 and the second yarns B3 to B5, and a second mesh 182a-2 formed of the first yarns A3 to A5 and the second yarns B3 to B5. As similar to the intermediate mesh 172a-2, the intermediate mesh 182a-1 has, for example, an appearance of a rectangular shape and is configured to have a mesh of the same roughness as the intermediate mesh 172a-2. The second mesh 182a-2 has, for example, an appearance of a square shape and is formed to have finer meshes than the intermediate mesh 182a-1. Therefore, when the second mesh 182a-2 and the intermediate mesh 182a-1 are compared, the channel resistance of the second mesh 182a-2 is larger than that of the intermediate mesh 182a-1.
(73) As shown in
(74) Here, the second mesh. 182a-2 and the first mesh 172a-1 are adjacent to the downstream side of the raw water flow of the intermediate mesh 182a-1. Since the second mesh 182a-2 has a greater flow resistance than that of the first mesh 172a-1, a flow rate Q11 of the raw water flowing along the flows C11, C12 from the intermediate mesh 182a-1 into the first mesh 172a-1 is larger than a flow rate Q12 of the raw water flowing into the second mesh 182a-2.
(75) On the other hand, the intermediate meshes 172a-2, 183a-1 are adjacent on the downstream side of the first mesh 172a-1. The meshes 172a-2, 183a-1 have almost the same roughness, and thus have almost the same level of channel resistance. Therefore, a flow rate Q12 of the raw water flowing along the flows C21, C22 out to the intermediate mesh 183a-1 and a flow rate Q13 of the raw water flowing along the flows S11, S12 out to the intermediate mesh 172a-2 are almost the same.
(76) Accordingly, the flow rate Q13 of the raw water flowing along the flows S11, S12 from the first mesh 172a-1 in the first mesh structure 172 into the intermediate mesh 172a-2 on the downstream side increases by an amount of a differential flow rate ΔQ.sub.11-12 between the flow rate Q11 flowing along the flows C11, C12 from the second mesh structure 182 into the first mesh 172a-1 in the first mesh structure 172 and the flow rate Q12 flowing along the flows C21, C22 from the first mesh 172a-1 out to the second mesh structure 183. As described above, also in the raw water channel spacer 160, the water force of the raw water flowing through the first mesh structure 172 can be increased, and an effect similar to that of the raw water channel spacer 40 of the above embodiment can be obtained.
(77) According to the fluid analysis simulation performed on the raw water channel spacer 160 under the same conditions as those of the above-described raw water channel spacer 40, the proportion of the area of the easy-polarization region to the surfaces of both the separation membranes 24, 28 was 17%.
(78) In the fluid analysis simulation, the average value of the shear stress acting on both the separation membranes 24, 28 by the raw water flow when the raw water channel spacer 160 was used was 2.6 Pa, whereas the average value of the shear stress in the case of the above-described raw water channel spacer 40 was 3.3 Pa.
(79) Therefore, when the raw water channel spacer 160 is used, the average shear stress acting on both the separation membranes 24, 28 is reduced by approximately 20% as compared with the above-described raw water channel spacer 40. Therefore, it is possible to obtain an effect that the pressure loss can be suppressed as compared with the raw water channel spacer 40.
(80)
(81) As shown in
(82) As shown in
(83) The first mesh structure 202 includes a first mesh 202a formed of the first yarns A11, A12 and the second yarns B11 to B13, and is configured by a number of meshes having the same configuration as that of the first mesh 202a being continuous in multiple in the extending direction of the second yarn row B10.
(84) The second mesh structure 212 includes a second mesh 212a formed of the first yarns A11, A12 and the second yarns B13 to B15, and is configured by a number of meshes having the same configuration as that of the second mesh 212a being continuous is multiple in the extending direction of the second yarn row B10. This second mesh 212a is formed to have finer meshes than the first mesh 202a. Therefore, the channel resistance of the second mesh 212a is larger than that of the first mesh 202a.
(85) According to the fluid analysis simulation performed on the raw water channel spacer 200 under the same conditions as those of the raw water channel spacer 40 of the above embodiment, the proportion of the area of the easy-polarization region to the surface of each of the separation membranes 24, 28 was 17%. Also in the raw water channel spacer 200 of Modification 11, an effect similar to that of the raw water channel spacer 160 described above can be obtained.
(86)
(87) The configuration of the raw water channel spacer 230 is different from the configuration of the above-described raw water channel spacer 40 in that the intervals of the yarn rows N are regular intervals. On the other hand, for the intervals of the yarn rows M, an interval R4 between the yarns M1, M2 forming the second mesh structure 241 is smaller than an interval R3 between the yarns M1, M2 forming the first mesh structure 232. In this way, the raw water channel spacer 230 may be configured such that the intervals in the second mesh structure 241 is smaller than the intervals in the first mesh structure 231 only for the yarn row M. In this case, however, the yarn row M corresponds to the second yarn row and the yarn row N corresponds to the first yarn row.
(88) Next, a method of using an evaluation cell 400 used for an evaluation test of a concentration polarization suppression effect by the above-described raw water channel spacer 40, and the evaluation test using the cell 400 will be described with reference to
(89) As shown in
(90) The female mold 420 is a metal or resin member having a recess 422 provided in the center portion to be fit to the protrusion 412 of the male mold 410. In the evaluation cell 400, by fitting both the molds 410, 420, an evaluation channel 430 is formed between the protrusion 412 and the recess 422. As shown in
(91) As shown in
(92) Next, a method of using the evaluation cell 400 will be described. The evaluation channel 430 formed inside the evaluation cell 400 stores in a laminated state a test body 26-T of the permeate spacer 26, a test body 24-T of the separation membrane 24a, and the test body 40-T of the raw water channel spacer 40. Each of the test bodies 26-T, 24-T, 40-T is processed in advance into a rectangular rounded shape so as to fit in the recess 422 of the female mold 420 without gaps. At this time, as shown in
(93) Then, as shown in
(94) After each of the test bodies 24-T, 26-T, 40-T and the O-ring 432 are installed in the recess 422 of the female mold 420, the protrusion 412 of the male mold 410 is fit to the recess 422 as described above, and both the molds 410, 420 are fixed by a plurality of bolts BL1 to BL4 or the like (see
(95) In this evaluation test, the test body 300-T was manufactured such that each of the intervals of yarn rows V (see
(96) The test body 40-T was manufactured such that each of the intervals of the first yarn rows N (see
(97) The test body 160-T was manufactured so as to have an interval between the first yarns A1, A2 and an interval between the first yarns A2, A3 forming the first yarn row A (see
(98) Next, an evaluation test of the raw water channel spacer using the evaluation cell 400 will be described. This evaluation test was carried out under the condition of temperature of 25° C.
(99) First, a pure water permeability coefficient A is calculated. This “pure water” permeability coefficient is a permeability coefficient determined from the relationship of the following formula (1) in the case where the raw water supplied from the pipe end 414 to the evaluation cell 400 is pure water containing no impurities such as salt.
J.sub.W=A×P.sub.out (1)
In the above formula (1), J.sub.W is a pure water volume flux [m.sup.3/(m.sup.2s)], and P.sub.out is a measurement value of a water pressure gauge (not shown) installed in the concentrate pipe 14. As a method of calculating the pure water permeability coefficient A, a permeate flow rate Q.sub.L3 [m.sup.3/s] is measured, that is of the permeate pipe 13 in the case where P.sub.out=0.5 MPa, and a concentrate flow rate Q.sub.L4 in the concentrate pipe L4 is 14.5 cc/min due to adjustment of a flow rate adjustment valve (not shown) of the concentrate pipe L4 and a flow rate adjustment valve of a bypass pipe L2-B. Then, this permeate flow rate Q.sub.L3 is divided by the area of the test body 24-T of the separation membrane 24a so that the pure water volume flux J.sub.W1 is determined.
(100) Similarly, in the case where P.sub.out=2.0 MPa and the concentrate flow rate Q.sub.L4 is set to 14.5 cc/min, the permeate flow rate Q.sub.L3 [m.sup.3/s] is measured, and the measurement value is divided by the area of the test body 24-T so that a pure water volume flux J.sub.W2 is measured.
(101) Then, using the P.sub.out=0.5 MPa, the pure water volume flux J.sub.W1, P.sub.out=2.0 MPa, and the pure water volume flux J.sub.W2, the pure water permeability coefficient A in the above formula (1) is determined by linear approximation by the least squares method.
(102) Next, the raw water to be supplied to the evaluation cell 400 from the pipe end 414 changed to, for example, a sodium chloride (NaCl) solution adjusted so that the salt concentration is around 250 ppm, P.sub.out is set to 0.5 MPa, and the concentrate flow rate Q.sub.L4 is set to 14.5±0.5 [cc/min], and the flow rate Q.sub.L3 [m.sup.3/s] of the permeate in this case is measured. Then, a solution volume flux Jv is calculated by dividing the flow rate Q.sub.L3 of the permeate by the area of the test body 24-T, the calculated solution volume flux Jv is substituted into the following formula (2), and osmotic pressure P.sub.f on the membrane surface of the test body 24-T is calculated. In the following formula (2), P.sub.out is 0.5 MPa.
P.sub.f=P.sub.out−(Jv/A) (2)
Then, a membrane surface concentration C.sub.m indicating the salt concentration in the raw water in the vicinity of the membrane surface of the test body 24-T that is the separation membrane is calculated by the following formula (3).
C.sub.m=B×P.sub.f (3)
A conversion coefficient B in the above formula (3) is a constant determined by the relationship between the salt concentration of NaCl, MgSO.sub.4, CaCl.sub.2 and the like contained in the raw water and the osmotic pressure, and as in the present embodiment, when the salt contained in the raw water is sodium chloride, the conversion coefficient B is 1.2294.
(103) Next, bulk concentration Cb is calculated from the relationship of formula (4).
C.sub.b=(C.sub.in+C.sub.out)/2 (4)
C.sub.in in the above formula (4) is the salt concentration of the raw water flowing through the water feed pipe L2, and C.sub.out is the salt concentration of the concentrate flowing through the concentrate pipe L4. In the present embodiment, since the salt concentration of sodium chloride contained in the raw water is adjusted in advance to around 250 ppm as described above, only the salt concentration C.sub.out of the concentrate flowing through the concentrate pipe 14 needs to be measured. Measurement of the salt concentration in the concentrate or the raw water may be performed by measuring electric conductivity as an example.
(104) Then, the concentration ratio C.sub.r shown in the formula (5) that is the ratio of C.sub.m calculated by the formula (3) to C.sub.b calculated by the formula (4) is calculated.
C.sub.r=C.sub.m/C.sub.b (5)
Here,
(105) As shown in
(106) Thus,
(107) In the following description, the test body 40-T of the raw water channel spacer 10 in the installation state of “A” described above is referred to as a test body 40-TA, and the test body 40-T in the installation state of “B” described above is referred to as a test body 40-TB, as appropriate.
(108) As shown in
(109) As shown in
(110) In the evaluation test using the test body 160-T, the pressure loss P.sub.L in the case of the concentrate flow rate Q.sub.L4 in the concentrate pipe L4 of 14.5cc/min was measured to be 6.4 kPa. The pressure loss P.sub.L is a differential pressure between the water pressure P.sub.in of the raw water supplied to the evaluation channel 430 of the evaluation cell 400 from the pipe end 414, and the above-described P.sub.out.
(111) Similarly, in the evaluation test using the test body 300-T, the pressure loss P.sub.L in the case of the concentrate flow rate Q.sub.L4 described above of 14.5 cc/min was measured to be 8.6 kPa.
(112) As described above, it was seen that the pressure loss can be reduced more than the conventional test body 300-T when the test body 160-T is used. Thus, the raw water channel spacer 160 can reduce both concentration polarization and pressure loss.
(113) The present invention can be implemented in a mode in which various improvements, modifications, or variations are added on the basis of knowledge of those skilled in the art without departing from the spirit of the present invention. Further, the present invention may be implemented by replacing any matter specifying the invention with other technologies within the range where the same action or effect is produced.