Method for molding fiber-reinforced plastic
09925703 ยท 2018-03-27
Assignee
Inventors
Cpc classification
B29C70/48
PERFORMING OPERATIONS; TRANSPORTING
B29C70/44
PERFORMING OPERATIONS; TRANSPORTING
B29C33/54
PERFORMING OPERATIONS; TRANSPORTING
International classification
B29C45/00
PERFORMING OPERATIONS; TRANSPORTING
B29C70/48
PERFORMING OPERATIONS; TRANSPORTING
B29C33/54
PERFORMING OPERATIONS; TRANSPORTING
B29C70/86
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The present invention relates to a method for molding fiber-reinforced plastic that is characterized: in comprising a process (1) for accommodating flowable grains comprising multiple particles in a flexible bag to form a core, a process (2) for interposing the core between fabric configured from fibers and placing the fabric and core inside a molding die, and a process (3) for injecting a resin into the molding die into which the fabric and core have been placed and curing; and in that, when performing the curing in process (3), a portion of one of the outer surfaces of the core is pressed and deformed by a pressing means to increase the internal pressure inside the core. The present invention provides a method for manufacturing fiber-reinforced plastics of excellent external appearance in which there are no defects such as wrinkles in the outer surface during forming using a core.
Claims
1. A method of molding a fiber-reinforced plastic, comprising injecting a resin into a molding die in which a fiber fabric and a core have been placed, and then performing curing; wherein: the core comprises a flowable granular material comprising particles in a flexible bag, the core is interposed between the fabric in the molding die, and during the curing, a portion of an outer surface of the core is deformed by pressing by projecting a pressing member into a cavity of the molding die, thereby increasing an internal pressure inside the core.
2. The method of claim 1, wherein the flexible bag is a packaging film, and core is formed by vacuum-packaging the granular material with the packaging film.
3. The method of claim 2, wherein the granular material comprises particles having different diameters.
4. The method of claim 3, further comprising mold clamping pressurization after injecting the resin.
5. The method of claim 4, further comprising, after injecting the resin: opening a fluid-discharging hole at a position of a deformed portion of the outer surface of the core by pressing; and discharging the particles through the fluid-discharging hole.
6. The method of claim 3, further comprising, after injecting the resin: opening a fluid-discharging hole at a position of a deformed portion of the outer surface of the core by pressing; and discharging the particles through the fluid-discharging hole.
7. The method of claim 2, further comprising mold clamping pressurization after injecting the resin.
8. The method of claim 7, further comprising, after injecting the resin: opening a fluid-discharging hole at a position of a deformed portion of the outer surface of the core by pressing; and discharging the particles through the fluid-discharging hole.
9. The method of claim 2, further comprising, after injecting the resin: opening a fluid-discharging hole at a position of a deformed portion of the outer surface of the core by pressing; and discharging the particles through the fluid-discharging hole.
10. The method of claim 1, wherein the granular material comprises particles having different diameters.
11. The method of claim 10, further comprising mold clamping pressurization after injecting the resin.
12. The method of claim 11, further comprising, after injecting the resin: opening a fluid-discharging hole at a position of a deformed portion of the outer surface of the core by pressing; and discharging the particles through the fluid-discharging hole.
13. The method of claim 10, further comprising, after injecting the resin: opening a fluid-discharging hole at a position of a deformed portion of the outer surface of the core by pressing; and discharging the particles through the fluid-discharging hole.
14. The method of claim 1, further comprising mold clamping pressurization after injecting the resin.
15. The method of claim 14, further comprising, after injecting the resin: opening a fluid-discharging hole at a position of a deformed portion of the outer surface of the core by pressing; and discharging the particles through the fluid-discharging hole.
16. The method of claim 1, further comprising, after injecting the resin: opening a fluid-discharging hole at a position of a deformed portion of the outer surface of the core by pressing; and discharging the particles through the fluid-discharging hole.
17. The method of claim 1, wherein the pressing member is a piston rod.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1)
(2)
(3)
(4)
(5)
(6)
(7)
PREFERRED MODE FOR CARRYING OUT THE INVENTION
(8) Suitable embodiments of the present invention will be specifically described with reference to the following
(9) In the method of molding a fiber-reinforced plastic according to the present invention, the step (1) comprises accommodating a flowable granular material comprising a large number of particles in a flexible bag to form a core.
(10) A core comprises a packaging film made of an expandable and unfoldable material and a flowable granular material comprising particles. Among these, preferred is one in which a flowable granular material comprising a large number of particles is vacuum-packaged with the above packaging film. Further, examples of the above packaging film include nylon films, polyethylene films, fluororesin films, silicone rubber, and the like. Among these, nylon films and fluororesin films are preferred in view of thermal resistance and strength.
(11) A core in which a flowable granular material comprising a large number of particles is vacuum-packaged with the above packaging film is preferred because it is easily formed, and can be formed into a precise shape. Further, in a case where such a core is used, when the internal pressure of the core increases, each particle in a granular material inside the core is to cause slippage in the directions from front to back and from side to side. Then, the packaging film with which the granular material is packaged is expandable and unfoldable, and can accommodate the deformation of the external shape of the core accompanied by the movement of the granular material.
(12) The flowable granular material preferably comprises particles having different particle diameters. Here, the phrase comprising particles having different particle diameters refers to a granular material in which particles having particle diameters of 0.1 to 20 mm and having a substantially globular shape are combined so that subsets of the particles have different particle diameters, and the subsets of the particles having different particle diameters are each present in the mixture in a proportion of 10 to 90% relative to the total mass of particles constituting the granular material. As particles constituting a granular material, those in which ceramics such as alumina and zirconia, quartz, glass, hard thermal resistant resins, metals, foundry sand and the like are granulated can be used. Among these, it is preferable to use zirconia and quartz, which have a low thermal conductivity.
(13) In the step (1), a core is configured such that a highly flowable granular material comprising a large number of particles is accommodated in a flexible bag. Therefore the core is deformable. Meanwhile, in a case where the above configuration is used, when one of the outer surfaces of the core is pressed to form a depressed portion in the outer surface so that the core is deformed, the internal pressure inside the core will not always show the same pressure condition at all the positions unlike it does when a fluid or gas is used. That is, even when a part of the outer surfaces of the core is pressed to apply pressure to the granular material inside, at the position other than the position to which pressure is applied, a pressure of a smaller magnitude than the pressure at the position to which the pressure was applied. Then, when the applied pressure is more than a certain value, slippage develops between particles constituting the granular material.
(14) Therefore, in a case where a part of the outer surfaces of a core is pressed, even when the internal pressure is significantly increased at a position where a depressed portion is formed on a portion of one of the outer surfaces of the core due to pressing pressure, the increase in pressure at a position of the outer surfaces of the core distant from that position will be lower than the internal pressure at the position where the depressed portion is formed.
(15) In particular, the transmissibility of pressure in a core and the fluidity of a granular material are affected by the surface roughness and particle diameter of the particles constituting the granular material. In a case where a granular material comprising particles having a homogenous particle diameter is used, the granular material is most densely packed in the core, which impairs the fluidity of the granular material, and decreases the transmissibility of pressure. Therefore, the fluidity of a granular material and the transmissibility of pressure in a core can be improved by considering the distribution of particle diameters and the surface roughness of particles inside the core, and by using granular materials comprising particles having different particle diameters in combination. According to the present invention, a granular material is used in which particles having particle diameters of 0.1 to 20 mm and having a substantially globular shape are combined so that subsets of the particles have different particle diameters, and the subsets of the particles having different particle diameters are each present in a mixture in a proportion of 10 to 90% relative to the total mass of the particles constituting the granular material. Therefore, it will not be most densely packed, allowing the granular material to have high fluidity and superior pressure transmittability inside the core.
(16) A position in a core distant from a position in which a depressed portion is formed by pressing is also deformed so that the surface area of the outer periphery of the core expands due to the slippage of particles constituting a granular material. By this, a fabric can be pressed along the mold surface of the molding die.
(17) A core can be stably pressurized since it is externally pressed in its closed form. In a case where the internal pressure of a core is excessively increased due to the clamping of the molding die or the pressing to form a depressed portion, a granular material may cause rupture of the packaging film since the packaging film does not have strength enough to maintain such pressure. However, if the spacing in the molding die is configured to be smaller than the diameters of particles, the granular material does not leak out of the molding die unless particles are crushed.
(18) In the present invention, pressing means that press a portion of one of the outer surfaces of the core include a means in which the portion of the outer surface of the core is pressed with a rod projectable inwardly from the mold surface of the molding die. Examples of the rod projectable inwardly from the mold surface of a molding die include, for example, a configuration in which a piston rod is used as the rod. Further, a pressing member can be arranged at multiple positions.
(19) In the present invention, the step (2) comprises interposing the core between fabric composed of fiber and placing the fabric and core inside a molding die so that the core is enclosed by the fabric.
(20) As the fabric, preferred are those in which one or more fibers selected from carbon fiber, glass fiber, aramid fiber, silicon carbide fiber and the like are subjected to single axle weaving or multiaxial weaving. Further preferred are those composed of a nonwoven fabric which has random fiber directions and the like.
(21) By interposing the core between fabric composed of fiber and placing the fabric and core inside a molding die so that the core is enclosed by the fabric, a portion of one of the outer surfaces of the core can be pressed through or not through the fabric when pressing a part of the outer surfaces of the core.
(22) Here, as shown in
(23) Here, the term substantially planar portion refers to a portion having a shape like a replica of an inner surface of a molding die.
(24) After the step (3), the present invention preferably comprises a step (4) of opening a fluid-discharging hole at a portion deformed by pressing a part of the outer surfaces of the core (hereinafter also referred to as a pressed portion), i.e., the above concave portion and planer portion, and a step (5) of discharging the above particles through the above fluid-discharging hole. In the present invention, a fluid-discharging hole may be opened at a position different from the pressed portion.
(25) Further, in the present invention, when pressing a part of the outer surfaces of the core, the part of the outer surfaces of the core may be pressed without going through a fabric. When pressing a part of the outer surfaces of the core not through a fabric, a hole for a pressing member such as a rod is pre-opened in the fabric, and pressure is to be directly applied to the core. In the case of a molded article obtained by the method as described above, a packaging film can be torn via the above hole for a pressing member to discharge particles.
(26) Further, in the present invention, a packaging film of the core is preferably subjected to a mold release treatment in which a release agent is applied and the like, or is preferably double-packaged. This allows the packaging film with which particles are in contact to be simultaneously removed when discharging the granular material through the fluid-discharging hole.
(27) In the present invention, the step (3) comprises injecting a resin into the above molding die in which the above fabric and core have been placed, and then curing the resin.
(28) Further, the method of molding a fiber-reinforced plastic according to the present invention is characterized in that the method comprises pressing and deforming a portion of one of the outer surfaces of the above core with a pressing means to increase the internal pressure of the above core when molding in step (3).
(29) Specifically, in step (3) according to the present invention, first, a resin is injected into the molding die for casting in which the fabric and core have been placed, and then a part of the outer surfaces of the core is pressed with a pressing means. Then, in this step, the resin is cured while applying pressing pressure with the above pressing means.
(30) As a resin to be injected into a molding die for casting, the followings can be used: a thermosetting resin such as an epoxy resin, a urea resin, a vinyl ester resin, an unsaturated polyester resin, a polyurethane resin and a phenolic resin. Among these, in view of the strength of an FRP product as the final molded article, an epoxy resin and a vinyl ester resin are preferably used.
(31) A molding temperature when molding can be appropriately adjusted depending on the resin with which the molding die is filled, but is preferably 80 to 180 C., more preferably 110 to 150 C.
(32) A curing time for the resin (hereinafter also referred to as cure) is preferably 2 to 60 minutes, more preferably 3 to 10 minutes.
(33) In the present invention, as a pressing means, a means for pressing a core with a piston rod as described above can be used, and further, two or more piston rods can be arranged. Alternatively, as shown in
(34) As a shape of a piston rod for pressing a core, the shape of a portion which makes contact with a core is preferably a round shape such as a cylindrical or a hemispherical. A portion in contact with a core having a round shape is preferred because a packaging film is less likely damaged.
(35) Further, a molding die having a mold clamping mechanism which can produce a high pressure is preferably made of steel. A steel molding die having a mold clamping mechanism which can produce a high pressure is preferred in view of sufficient pressure resistance and durability.
(36) The pressure when pressing a core with the above pressing means is preferably 1 to 10 MPa, more preferably 2 to 8 MPa.
(37) Further, in the present invention, the step (3) preferably further comprises performing mold clamping pressurization after resin injection. Here, the term mold clamping pressurization refers to supplementary pressurization. Further, a pressure to be applied is preferably 1 to 10 MPa. This is preferred because by performing mold clamping pressurization at 1 to 10 MPa after resin injection, cure shrinkage can be controlled even when molding a resin showing a large cure shrinkage.
Example 1
(38) As shown in
(39) In
(40) Then a thermosetting resin is injected from an injection hole (not shown) of the molding die 15 to impregnate the fabric 3 with the resin. Subsequently, thermal curing can be performed in the molding die 15 to manufacture a molded article of a fiber-reinforced plastic (FRP) of a desired shape.
(41) In
(42) A cylinder 5 having a piston rod 5a projectable into the cavity of the molding die 15 is provided in the lower mold 1. Note that in
(43) First, the fabric 3 placed inside the concave portion 1a of the lower mold 1 can be pressurized by moving the upper mold 2 and the lower mold 1 in a direction where they become closer, and then performing mold clamping. Here, as a mold clamping device comprising the upper mold 2 and the lower mold 1, a high-pressure press machine is preferably used.
(44) When performing resin injection, the upper mold 2 and the lower mold 1 described above are preferably separated from the core 4 by a distance of about 0.1 to 1 mm so that the resin can be injected at relatively low pressure. After resin filling, the pressure in the core 4 is increased with the piston rod 5a or by further performing mold clamping. That is, after resin filling, pressurization is performed with at least either the piston rod 5a or mold clamping. Meanwhile, in a case where mold pressurization is not performed after resin filling, any mold clamping device can be used as long as it has an open-close mechanism of a mold, and a high-pressure press machine is not required.
(45) After mold clamping, a portion of one of the outer surfaces of the core 4 interposed within the fabric 3 is pressed by projecting the piston rod 5a into the cavity of the molding die 15. This pressing pressure allows the fluidity of the granular material 4a comprising particles having different particle diameters to be improved to cause slippage in the granular material 4a inside the core 4, as shown in
(46) In particular, the core 4 can be closely attached to the inner surface of the fabric 3 by deforming the core 4 even at four corners of the inner surface of the fabric 3 where a space or void often occurs. Therefore, a bend, a wrinkle, a space, and a void are not likely generated at a region along a longitudinal part of the inner surface formed along the wall of the concave portion 1a. As a result, a molded article with high dimensional precision can be obtained.
(47) Even in a case where a space or void is formed between the fabric 3 impregnated with a resin in which the core 4 is enclosed and the core 4, by deforming the core 4, the air of the space or void will be crushed due to the high pressure in the core 4, or will be released into the atmosphere from the molding die 15 through the fabric 3 impregnated with the resin. Further, a passage formed when the air passes through the fabric 3 impregnated with the resin will be spontaneously closed by the fabric 3 impregnated with the resin.
(48) Moreover, even in a case where a space or void is present between the molding die 15 and the fabric 3 impregnated with the resin in a corner of the molding die 15, the fabric 3 moves toward the space or void by pressing pressure from the core 4 which has expanded the shape of the outer surfaces. Then, the air of the space or void can be crushed by the high internal pressure, or can be extruded from the molding die 15 out to the atmosphere.
(49) Note that in each figure used for the descriptions in Examples, for the purpose for clearly illustrating the packaging film 4b, the thickness of the packaging film 4b is shown to be exaggeratedly thick. Actually, the packaging film 4b can be configured to have a thin-film like shape having a thickness of 1 mm or less. More specifically, the film thickness of the packaging film 4b is preferably 0.05 to 1 mm. Note that the configuration for forming a molded article having a rectangular-pipe like shape is described in each figure, but a molded article according to the present invention may have other shapes having a closed cross-section.
(50) Shapes having an approximately closed cross-section include those having a C-letter like cross-sectional shape and the like. For example, in a case where a molded article having a C-letter like cross-sectional shape is formed, a part of the cores 4 can be positioned to make direct contact with the molding surface of the upper mold 2 or the lower mold 1. Then, a molded article having a C-letter like cross-sectional shape can be manufactured by covering the surfaces of the core 4 which is not in contact with the molding surface with the fabric 3. Therefore, a closed cross-section in the present invention encompasses not only a rectangular-pipe like shape but also, for example, a C-letter like cross-sectional shape as described above.
(51) As shown in
(52) When the internal pressure of the core 4 is increased, the particles constituting the granular material 4a cause slippage amongst the particles, allowing the particles to move in the directions back and forth from side to side. However, since the packaging film 4b for packaging the granular material 4a is made of a material with which vacuum-sealed packaging can be performed, the packaging film 4b can be expanded and unfolded without substantially restricting the movement of the particles constituting the granular material 4a.
(53) As described above, the method of molding a fiber-reinforced plastic according to the present invention is characterized in that the internal pressure of the core 4 can be increased to cause slippage between the particles constituting the granular material 4a. Therefore, as shown in
(54) Moreover, the core 4 is deformed at a position where a space or void is likely generated, i.e., a position where the pressure between the fabrics 3 impregnated with a resin is low. Therefore, the thickness of the fabric 3 impregnated with a resin can be maintained at a predetermined thickness, i.e., 0.1 to 1 cm while eliminating the space or void.
(55) As described above, the fabric 3 impregnated with a resin having a thickness of 0.1 to 1 cm and a desired outer periphery shape, i.e., the same shape as the inner shape of the molding die 15, can be pressure-molded.
(56)
(57)
(58) The packaging film 4b which makes contact with the granular material 4a can also be removed from the molded article 10 in a case where the packaging film 4b with which the granular material 4a has been vacuum-sealed is made of a material having good detachability from the molded article 10, or the packaging film 4b is double-packaged.
(59) As described above, the method of molding a fiber-reinforced plastic according to the present invention can allow the fabric 3 impregnated with a resin to be pressure molded in a state where a space or void is not present between the core 4 and the fabric 3. Therefore, the molded article 10 having a desired outer periphery shape and a desired thickness without a bend and a wrinkle can be manufactured. Moreover, even in a case where the internal pressure inside the core 4 is low in a state where the molding die 15 is closed, the internal pressure inside the core 4 can be increased by the pressing pressure applied with the piston rod 5a. Therefore, the molded article 10 can be manufactured as a product having a desired thickness and a desired outer periphery shape.
(60) The present Example 1 will be described more specifically.
(61) As shown in
Example 2
(62) The configuration of Example 2 according to the present invention will be described with reference to
(63) As shown in
(64) After resin injection, pressure molding is performed with the upper mold 2 and the lower mold 1 using a mold clamping device which can generate a high pressure, for example, a hydraulic press machine. By performing mold clamping, the fluidity of the granular material 4a comprising particles having different particle diameters can be improved, and formation of a space or void can be prevented between the core 4 and the fabric 3 impregnated with a resin by deforming the core 4. Then, formation of a space or void which is otherwise often generated between the mold surface of the casting mold 15 and the fabrics 3 impregnated with a resin can be prevented.
(65) Example 2 will be more specifically described.
(66) As shown in
INDUSTRIAL APPLICABILITY
(67) The present invention can be suitably applied to a method of molding a fiber-reinforced plastic in which a core is used.
EXPLANATION OF REFERENCE NUMERALS
(68) 1 Lower mold 1a Concave portion 2 Upper mold 3 Fabric 4 Core 4a Granular material 4b Packaging film 5 Cylinder 5a Piston rod 6 Concave portion 10a Semi-finished molded article 10b Hollow portion 15 Molding die 16 Injection hole 104 Core 105 Film bag as a bag member 106 Particle 107 Preform 108 Molding die 109 Cavity 110 Resin injection device 111 Injection hole 111a Inlet 112 Injection line 113 Three-way valve 114 Vacuum pump 115 Discharging hole 116 Aspiration line 117 Three-way valve 118 Pressure gage