Method for producing a molded body

Abstract

The invention relates to a method for producing a molded body, having a silicon carbide support matrix and an integral carbon structure, wherein a base body on the basis of a powder mixture containing silicon carbide or silicon and carbon and of a binder is built in layers in a generative method, and wherein a pyrolysis of the base body is effected for realizing the molded body after the binder has been cured, wherein the carbon content of the carbon structure is adjusted by way of the pyrolysis of the binder and by way of the carbon content of the powder mixture or infiltration of a carbon material into the silicon carbide support matrix.

Claims

1. A method for producing a molded body having a silicon carbide support matrix and an integral carbon structure, said method comprising: building a layered base body using a generative method from a powder mixture containing carbon, a binder, and at least one of silicon and silicon carbide; curing the binder; and pyrolyzing the base body including the binder after the binder has been cured to form the molded body, said pyrolyzing forming a silicon carbide support matrix and an integral carbon structure, wherein a carbon content of the carbon structure is defined by a free carbon in its entirety and is adjusted by way of the pyrolysis of the binder and by way of the carbon content of the powder mixture or infiltration of a carbon material into the silicon carbide support matrix.

2. The method according to claim 1, in which the powder mixture presents a carbon content between 0 and 30% by weight.

3. The method according to claim 2, in which the powder mixture presents a carbon content between 10 and 20% by weight.

4. The method according to claim 1, in which the powder mixture presents an SiC particle fraction having particles of an average grain size D.sub.s50 between 0.5 and 100 m.

5. The method according to claim 4, in which the average grain size D.sub.s50 is between 2 and 60 m.

6. The method according to claim 5, in which the average grain size D.sub.s50 is between 3 and 10 m.

7. The method according to claim 1, in which for adjusting the carbon content of the molded body, following the pyrolysis of the base body, the infiltration of the silicon carbide support matrix with a polymer is effected, said polymer being transformed into carbon with the aid of a following pyrolysis.

8. The method according to claim 7, in which the polymer comprises a polymer containing silicon or silicon carbide.

9. The method according to claim 7, in which prepolymers are used as the polymer.

10. The method of claim 9, wherein the prepolymers are selected from the group consisting polyimides, and cyanate ester resins.

11. The method according to claim 7, in which phenolic resins, furan resins, cyanate ester resins are used as the polymer.

12. The method of claim 7, wherein the polymers are selected from the group consisting of siloxanes, silazanes, carbosiloxanes, carbosilazanes, and carbosilanes.

13. The method according to claim 1, in which an infiltration of the silicon carbide support matrix with silicon is effected following the pyrolysis.

14. The method according to claim 1, in which an infiltration of the silicon carbide support matrix with silicon carbide is effected following the pyrolysis.

15. The method according to claim 14, in which the infiltration of the silicon carbide support matrix with silicon carbide is effected by way of vapor deposition of silicon carbide.

16. The method according to claim 15, in which the vapor deposition of silicon carbide is effected in a CVI method or CVD method.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) In the figures:

(2) FIGS. 1 to 3 show a molded body being realized as a resistance heating element;

(3) FIG. 2 shows a schematic illustration of the texture of the resistance heating element being illustrated in FIG. 1;

(4) FIG. 3 shows a silicon carbide support matrix;

(5) FIG. 4 shows the texture being illustrated in FIG. 3, with a polymer being realized as a phenolic resin and being infiltrated into the support matrix;

(6) FIG. 5 shows the texture being illustrated in FIG. 4 after a pyrolysis has been carried out for transforming the polymer into pyrolysis carbon.

(7) FIG. 6 shows a molded body being realized as a static mixer;

(8) FIG. 7 shows the lattice structure of the molded body; and

(9) FIG. 8 shows a schematic illustration of a method for producing a molded body.

DETAILED DESCRIPTION OF THE EXAMPLE EMBODIMENTS

(10) FIG. 1 shows a resistance heating element which is realized as a tunnel heater, and which is realized so as to be tubular, and to have a round circular cross-section. The resistance heating element presents a molded body 22 having a thin tube wall 11, which includes apertures in the form of two slits 12 and 13. The slits 12 and 13 are realized, in the area of a lower end 14 of the resistance heating element 10, so as to be straight in the longitudinal direction of the same, in this way forming two connection faces 15 and 16 for connection of the resistance heating element 10 to connecting contacts of a connection apparatus not being illustrated in greater detail here.

(11) In a central area 17 of the molded body 22, the slits 12 and 13 in each instance run helically in the longitudinal direction along the circumference of the tube wall 11 up to an upper end 18 of the resistance heating element. The slits 12 and 13 in this way form two heating coils 19 and 20, which are linked to each other at their upper end in an annular portion 32. The resistance heating element is heated during operation substantially in the area of the heating coils 19 and 20. The resistance heating element is realized in one piece and substantially consists of silicon carbide and carbon.

(12) FIG. 2 shows a schematic enlarged illustration of a part of a texture cross-section of the molded body 22 being illustrated in FIG. 1. The texture presents a silicon carbide support matrix 21, wherein a carbon structure 23 is integrated into the silicon carbide support matrix 21. An inner wall surface 24 and an outer wall surface 25 are furnished with a silicon carbide coating 26 or 27.

(13) In FIGS. 3 to 5, using texture illustrations, the successive method steps for producing the texture of the molded body 22 being illustrated in FIG. 2 are explained by way of example.

(14) FIG. 3 shows the texture of a base body presenting silicon carbide particles 28, which are linked to one another via binding agent particles 29. The base body obtains its dimensional stability by way of the cured binding agent particles 29.

(15) FIG. 4 shows the texture having polymer particles 30 which are integrated into the silicon carbide support matrix 21 of the base body, and which are, for instance, formed from a phenolic resin.

(16) FIG. 5 shows the polymer particles 30 which have been transformed into carbon particles 31 after a pyrolysis procedure, and which realize the carbon structure 23 in the silicon carbide support matrix 21.

(17) Finally, a coating with silicon carbide particles 28 is effected with the CVD method for realizing the silicon carbide coating 26 being illustrated in FIG. 2 on the inner wall surface 24 and for realizing the silicon carbide coating 27 on the outer wall surface 25 of the resistance heating element 10.

(18) FIG. 6 shows a molded body 40 which is realized as a static mixer, and which is furnished with an electrical connection unit 44 at each of its axial ends 42, 43 in relation to a flow-through axis 41, said unit being formed from a graphite material in the present case, and serving to feed an electrical current into or out of the molded body 40.

(19) The molded body 40 being realized as a static mixer presents a three-dimensional lattice structure 45, which is formed from interlaced material crosspieces 46, 47 of the molded body 40. Here, as FIG. 7 in particular shows, which illustrates the molded body 40 without any connection units 44, the material crosspieces 46, 47 extend in interpenetrative crosspiece planes 48, 49. As a result of the lattice structure 45 being built in layers in generative method, which means for example a 3D printing method, the material crosspieces 46, 47 are linked to one another in one piece.

(20) By way of example, FIG. 8 shows a method for producing the molded bodies 22, 40 which are illustrated in FIGS. 1 and 6, 7, and which are, by way of example, configured as a resistance heating element (FIG. 1) or as a static mixer (FIG. 6).

(21) The method being illustrated in FIG. 8 starts from the production of a powder mixture 50, which may present proportions of silicon carbide or silicon and carbon or silicon carbide and silicon and carbon and to which, as a binder 51, a synthetic resin containing carbon, such as phenolic resin, is added, such that a homogenized mixture 53 is subsequently produced in a homogenizing stage 52, said mixture being supplied to a 3D printing unit 54 and being transformed into a base body 55 in a layer building process, which base body is subjected to a pyrolysis 56 after curing in a furnace working. As a result of the pyrolysis, the binder 51 is transformed into carbon and any carbon and silicon proportions of the powder mixture 50 are equally transformed into silicon carbide by way of a reactive firing.

(22) The result of the pyrolysis is a mechanically stable molded body 22, 40, whose proportion of free carbon for realizing a carbon structure is determined by the composition of the powder mixture 50 or by a residue proportion of free carbon remaining after a reactive firing of silicon and carbon.

(23) Any free carbon proportions which might have remained at the surface of the molded body 22, 40, and which are not present in an encapsulated form in the silicon carbide support matrix, can be transformed, after an infiltration with silicon, into silicon carbide in a subsequent reactive firing that might be carried out in a further furnace working.

(24) In order to preclude that there is any free silicon in the silicon carbide support matrix or at the surface of the molded body after the reactive firing, in a further furnace working, the free silicon can be evaporated in a vacuum atmosphere.