Tunable amplified spontaneous emission (ASE) laser
09923339 ยท 2018-03-20
Assignee
Inventors
- Kin Long Chan (Hong Kong, HK)
- Gui Xin Li (Hong Kong, HK)
- Ka Suen Lee (Hong Kong, HK)
- Kok Wai Cheah (Hong Kong, HK)
Cpc classification
H01S2301/02
ELECTRICITY
International classification
H01S5/04
ELECTRICITY
H01S3/23
ELECTRICITY
Abstract
This invention relates to a tunable amplified spontaneous emission (ASE) laser source comprising at least two laser sources excited by a single pump laser. More particularly, the present invention relates to a tunable amplified spontaneous emission (ASE) laser source comprising at least two laser sources excited by a single pump laser wherein said at least two laser sources each comprise an organic laser or a cascaded organic laser. The invention is used for providing a tunable amplified spontaneous emission (ASE) laser source comprising at least two laser sources excited by a single pump laser.
Claims
1. A tunable amplified spontaneous emission (ASE) laser source comprising at least two laser sources excited by a single laser pump wherein each of said at least two laser sources comprises an organic laser or a cascaded organic laser; wherein one of the at least two laser sources comprises a thin film laser generating device comprising Poly (9, 9-di-n-dodecylfluorenyl-2, 7-diyl) and the other of the at least two laser sources comprises a thin film laser generating device comprising Poly [(9, 9-di-n-octylfluorenyl-2, 7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)].
2. The tunable ASE laser source according to claim 1 wherein said organic laser or said cascaded organic laser is a thin film laser generating device.
3. The tunable ASE laser source according to claim 1 wherein said organic laser or said cascaded organic laser comprises at least blue and green emission organic semiconductors.
4. The tunable ASE laser source according to claim 1 wherein the single laser pump comprises a third harmonic laser from Nd:YAG.
5. The tunable ASE laser source according to claim 3 wherein the single laser pump comprises a pulsed UV emission laser.
6. The tunable ASE laser source according to claim 1 wherein said organic laser or said cascaded organic laser comprises at least blue and green emission organic semiconductors and wherein the single laser pump is comprises a pulsed UV emission laser.
7. The tunable ASE laser source according to claim 1 wherein at least one of the at least two laser sources is a two-dimensional paired laser element.
8. The tunable ASE laser source according to claim 7 wherein each of the at least two laser sources is a two-dimensional paired laser element.
9. A method of operating a tunable ASE laser source comprising: emitting an optical pulse from a pulsed laser pump source to a thin film laser device comprising at least first and second cascaded organic thin films; emitting a first laser pulse from the first organic thin film at a first time slot; emitting a second laser pulse from the second organic film at a second time slot; wherein a time delay between the first time slot and the second time slot is a picosecond or less.
10. The method of operating a tunable ASE laser source according to claim 9 wherein the first organic thin film comprises Poly (9, 9-di-n-dodecylfluorenyl-2, 7-diyl) and the second organic thin film comprises Poly [(9, 9-di-n-octylfluorenyl-2, 7-diyl)-alt-(benzo [2,1,3]thiadiazol-4,8-diyl)].
11. The method of operating a tunable ASE laser source according to claim 9 wherein at least one of the at least two laser sources is a two-dimensional paired laser element.
12. The method of operating a tunable ASE laser source according to claim 9 wherein each of the at least two laser sources is a two-dimensional paired laser element.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The above and other objects and features of the present invention will become apparent from the following description of the present invention, when taken in conjunction with the accompanying drawings, in which:
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DETAILED DESCRIPTION OF THE INVENTION
(16) The presently claimed invention is further illustrated by the following experiments or embodiments which should be understood that the subject matters disclosed in the experiments or embodiments may only be used for illustrative purpose but are not intended to limit the scope of the presently claimed invention.
(17) Without wishing to be bound by theory, the inventors have discovered through their trials, experimentations and research that to accomplish the task of tuning multiple color emissions from an organic laser and using such tuning to measure displacements and movements.
(18) Tunable Color Emission: White Light Amplified Simultaneous Emission
(19) Semiconducting (conjugated) polymer draws much attention nowadays as it is a promising possible application. With increasing emission efficiency, excited emission such as ASE (amplified spontaneous emission) and lasing have been achieved. Recently, the white ASE has been reported but with one ASE spectrum and one much broader spectrum. In this invention, the gain media in optical amplifiers will be studied. Two individual shape ASE spectra in one sample will be demonstrated.
(20) A first aspect of the present invention aims at getting white light ASE with two different color ASE spectra that have near-equal spectral profiles. Two lasing organic materials, Poly (9, 9-di-n-dodecylfluorenyl-2, 7-diyl) (PFO) and Poly [(9, 9-di-n-octylfluorenyl-2, 7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)] (F8BT) were selected. The corresponding peaks of PFO and F8BT are at 450 nm and 575 nm, respectively, and the full width half maximum are 5 nm and 10 nm. Therefore, they are suitable to be combined to give a white ASE. A PFO thin film was first deposited onto a glass substrate, and then a high transmittance optically clear adhesive (over than 90% transmittance in visible range) was added as a spacer that separates it from the F8BT thin film. The sample successfully demonstrated white light ASE when pumped by a 355 nm third harmonic laser from Nd:YAG. The CIE coordinate achieved is (0.36, 0.45) and a comparable threshold.
(21) In conclusion, it is shown that a simple thin film configuration that can produce white light ASE was achieved and it is possible to tune the CIE coordinate from the thin film thickness. Such device can be used as a strong white light source in spectroscopy experiments.
(22) Tunable Color Emission from Cascaded Amplified Spontaneous Emissions in Organic Thin Films
(23) Since the demonstrations of the semiconducting (conjugated) polymer light emitting diodes, semiconducting (conjugated) polymer draws lots of attention as promising gain materials in lasing applications. In the second aspect of the present invention, we demonstrated the Amplified Spontaneous Emission (ASE) processes can be used to realize tunable emission spectra of a cascaded organic thin film system, consisting of blue and green emission organic semiconductors. When the cascaded films were pumped by a pulsed UV emission laser, the directional emission of ASE from the two kinds of materials are partially overlapped in the far field. The emission spectra can be tuned almost linearly in the CIE coordinates from (0.42, 0.55) to (0.18, 0.11) by spatially choosing the emission signals. The method shown herein can be used to design a polychrome light source for display, bio-imaging and related applications.
Experimental Details
(24) Sample Structure (
(25) Condition: Using Toluene as solvent and Spin-coating for fabrication. PFO (Poly(9, 9-di-n-dodecylfluorenyl-2, 7-diyl): 16 mg/ml, 120 nm. F8BT (Poly[(9, 9-di-n-octylfluorenyl-2, 7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)]): 23 mg/ml, 250 nm. Optically Clear Adhesive (OCA): 60 m, n=1.48.
Experiment (FIG. 1b)
(26) Pumped by Nd:YAG laser (=355 nm, repetition rate:10 Hz and pulse width:5 ns). Excitation Area: 5 mm300 m. The spontaneous emission and ASE signals from Sample were collected at edge of the device and analyzed by a fiber coupled spectrometer (Ocean Optics, USB 4000). Using a photodiode to monitor and calibrate the pumping power of the laser.
Experimental Results
(27) The photoluminescence (PL) spectra of PFO and F8BT (
(28) The transmission efficiency of the optical adhesive, PFO, F8BT and PFO/F8BT cascaded films (
(29) ASE measurement: The ASE signals from PFO (ASE.sub.PFO) and F8BT (ASE.sub.F8BT) were separated in the near field by the OCA, and the two directional emissions were then imaged in the far field. As shown in
(30) The power dependence ASE at D1 and D2 positions (
(31) Commission Internationale d'Eclairage (CIE) coordinates (
(32) Findings
(33) We have demonstrated a device made of cascaded organic semiconducting films. The ASE from the two kinds of materials can be obtained after being pumped by a single laser beam. The tunable emission spectrum of ASE was achieved in the far field with tunable CIE coordinates from (0.42, 0.55) to (0.18, 0.11). The device has great potential to be used as a polychrome light source in display, imaging and bio-sensing applications.
(34) Remote Measurement Schemes
(35) The schematic illustration is shown in
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(37) Examples of Organic Laser Sensors:
(38) (a) Sensor for 2 Axis Position and Vibration Measurement
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(40) In addition, when the subject moves along the z-axis, the optical fiber will receive the intensity changes at both wavelengths A and B. Again, with calibration of the intensity changes at A and B against displacement, real-time displacement of the subject at the z direction can be monitored.
(41) Besides the position measurement, by using the RF spectrum analyzer, photo-detector and optical filter, the vibration frequency of the subject can also be directly detected at both the z-axis and the x- or y-axis.
(42) (b) Sensor for 3-Axis Position and Vibration Measurements
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(46) (i) X-Axis Monitoring
(47) The wavelength pair A and B is assigned for measuring the x-axis position and vibration. When the subject moves along the x-direction, the position of optical fiber is changed. The received optical signals at wavelengths A and B are also changed accordingly. Therefore, with calibration of the intensity changes at A and B against position, the real-time displacement of the subject can be monitored. The optical signal changes are depicted in
(48) (ii) Y-Axis Monitoring
(49) The wavelength pair A and B is assigned for measuring the y-axis position and vibration. When the subject moves along the y-direction, the position of the optical fiber is changed. The received optical signals at wavelengths A and B are also changed accordingly. Therefore, with calibration of the intensity changes at A and B against position, the real-time displacement of the subject can be monitored. The optical signal changes are depicted in
(50) (iii) Z-Axis Monitoring
(51) At the same time, the intensities of wavelengths A, A, B and B are also sensitive to the z-axis position change. When the subject moves along the z-direction, the received optical signals at wavelengths A, A, B and B are changed as shown in
(52) (iv) Vibration Measurement
(53) Again, by using the RF spectrum analyzer, photo-detector and optical filters, the vibration frequency of the subject at x, y and z directions can also be monitored.
(54) (c) Sensor for Rotational Motion Measurement
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(57) Clockwise Rotation Measurement
(58) When the subject is rotated clockwise about the rotation axis, both fiber F1 and F2 can receive the intensity changes at wavelengths AA and BB, respectively. Under this situation, the received intensities at wavelengths A and B are increased, and received intensities at wavelengths A and B are decreased.
(59) Anti-Clockwise Rotation Measurement
(60) When the subject is rotated anti-clockwise about the rotation axis, both fiber F1 and F2 can receive the intensity changes at wavelengths AA and BB, respectively. Under this situation, the received intensities at wavelengths A and B are decreased, and received intensities at wavelengths A and B are increased.
(61) Therefore, with the calibration of the intensity changes for A, A, B and B against angle, real-time angular change of the subject can be measured. In addition, by using the RF spectrum analyzer, photo-detector and optical filters, the angular frequency of the subject at the rotation axis can also be monitored.
(62) (d) Multiwavelength Pulsed Organic Laser for Remote Pump-Probe Test
(63) Two configurations of multiwavelength pulsed organic laser source are shown in
(64) In general, when using a pulsed laser as an optical pump, the organic laser will emit an optical pulse accordingly. It follows that, in our configurations, when the optical pump pulse is incident on the laser device, it will be sequentially transmitted through the cascaded organic thin films. Therefore, each thin film is excited by the pump pulse at a different time slot. As a result, each thin film will emit the laser pulse with a sequential time delay. The time sequences of output laser pulses are shown in
Experimental Details
(65) We employed two different color materials in our experiment, the blue emission polymer PFO (Poly(9, 9-di-n-dodecylfluorenyl-2, 7-diyl) and green emission polymer F8BT (Poly[(9, 9-di-n-octylfluorenyl-2, 7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)]). Those materials were purchased from Sigma-Aldrich. The molecule weight and polydispersity index of PFO are Mw 20000 and 3.7, respectively. The average molecule weight of F8BT is 10000-20000 and polydispersity index is <3. Both of the two materials were dissolved in toluene solution with concentrations of 16 mg/mL and 23 mg/mL, respectively. The polymer films were fabricated by spin-coating onto pre-cleaned fused silica substrates with thickness of 120 nm and 250 nm, respectively. As shown in
(66) In the ASE experiment (
RESULTS AND DISCUSSION
(67) Before the experiment, we firstly tested the device's basic optical property. In
(68) The purpose of this optical sensor is to monitor and measure relatively small distance vibrations. Assume that there is an object to be detected for vibration using this sensor. The sensor's operating principle is to first receive lasing spectra before and after the vibration, and then to calculate the peak ratios (or both peak intensities) between PFO and F8BT. Finally, using the ratios (or both peak intensities), we can extract the distances to find the vibration of the object. For the optical sensor, we separate the sensor results to two parts: one for the horizontal direction and another one for the vertical direction (x and y directions respectively shown in
(69) For the vertical direction, we use the original ASEPFO and ASEF8BT peak intensities to replace the ratio as a parameter for the sensor. It is because along this direction the peak intensities are both decreased as the distance increased. Thus, the ratio between both peak intensities remains the same, and it is no longer suitable to be a characterizing factor of the sensor. In
(70) Findings and the Present Invention: Examples and Applications
(71) We have demonstrated a device made of cascaded organic thin films. The ASE from the two materials can be simultaneously obtained after being pumped by an optical laser. The emission spectrum of ASE was achieved in the far field with tunable color. In both the vertical and the horizontal directions, we have shown that the device that can be used as a distance sensor.
(72) Based on the findings, the present invention is detailed as follows.
(73) In example one, the present invention includes a tunable amplified spontaneous emission (ASE) laser source comprising at least two laser sources excited by a single laser pump wherein each of said at least two laser sources comprises an organic laser or a cascaded organic laser.
(74) Example 2 includes the tunable ASE laser source of example 1 wherein said organic laser or said cascaded organic laser is a thin film laser generating device.
(75) Example 3 includes the features of example 1 wherein said organic laser or said cascaded organic laser comprises at least blue and green emission organic semiconductors.
(76) Example 4 includes the tunable ASE laser source of example 1 wherein one of the at least two laser sources comprises a thin film laser generating device comprising Poly (9, 9-di-n-dodecylfluorenyl-2, 7-diyl) and the other of the at least two laser sources comprises a thin film laser generating device comprising Poly [(9, 9-di-n-octylfluorenyl-2, 7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)].
(77) Example 5 includes the tunable ASE laser source of example 1 wherein the single laser pump comprises a third harmonic laser from Nd:YAG.
(78) Example 6 includes the tunable ASE laser source of example 3 wherein the single laser pump comprises a pulsed UV emission laser.
(79) Example 7 includes the tunable ASE laser source of example 1 wherein one of the at least two laser sources comprises a thin film laser generating device of lasing organic material comprising Poly (9, 9-di-n-dodecylfluorenyl-2, 7-diyl) and the other of the at least two laser sources comprises a thin film laser generating device comprising Poly [(9, 9-di-n-octylfluorenyl-2, 7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)] and wherein the single laser pump comprises a pulsed laser which further comprises a third harmonic laser comprising Nd:YAG.
(80) Example 8 includes the tunable ASE laser source of example 1 wherein said organic laser or said cascaded organic laser comprises at least blue and green emission organic semiconductors and wherein the single laser pump is comprises a pulsed UV emission laser.
(81) Example 9 includes the tunable ASE laser source of example 1 wherein at least one of the at least two laser sources is a two-dimensional paired laser element.
(82) Example 10 includes the tunable ASE laser source of example 1 wherein each of the at least two laser sources is a two-dimensional paired laser element.
(83) Example 11 includes a method of operating a tunable ASE laser source comprising emitting an optical pulse from a pulsed laser pump source to a thin film laser device comprising at least first and second cascaded organic thin films; emitting a first laser pulse from the first organic thin film at a first time slot; emitting a second laser pulse from the second organic film at a second time slot; wherein a time delay between the first time slot and the second time slot is a picosecond or less.
(84) Example 12 includes the method of operating a tunable ASE of example 11 wherein the first organic thin film comprises Poly (9, 9-di-n-dodecylfluorenyl-2, 7-diyl) and the second organic thin film comprises Poly [(9, 9-di-n-octylfluorenyl-2, 7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)].
(85) Example 13 includes the method of operating a tunable ASE of example 11 wherein at least one of the at least two laser sources is a two-dimensional paired laser element.
(86) Example 14 includes the method of operating a tunable ASE of example 11 wherein each of the at least two laser sources is a two-dimensional paired laser element.
(87) The present invention provides a system for measuring displacements and movements, wherein said measured displacements include very fine displacements and said measured movements include very minute movements. The system comprises one or more measuring means at least configured to tune multiple color emissions from a laser such that the tuned multiple color emissions of the laser are used to measure said displacements and said movements. Said laser comprises an organic laser and/or a cascaded organic laser. In particular, said system is scalable in order to support the measuring of displacements and movements across one or more physical/geographical spaces including very large physical and/or geographical spaces.
(88) Optionally, the system further comprises a thin film laser generating device for generating said laser. The system may further comprise blue and green emission organic semiconductors for generating said organic laser. It is also optional that the system further comprises laser sensors for sensing said laser wherein said laser sensors comprise organic laser sensors and/or cascaded organic laser sensors. Said laser sensors may or may not require any power for operation, or may be passive devices.
(89) One advantage of the system is that the system is configurable for measuring one or more directions simultaneously.
(90) The system is configurable for position and vibration measurements as well as for measurements of rotational displacements/movements and of angular displacements/movements.
(91) The present invention also provides a method for measuring displacements and movements. Said measured displacements include very fine displacements and said measured movements include very minute movements. One or more directions may be measured simultaneously by the method. The method comprises tuning multiple color emissions from a laser such that the tuned multiple color emissions of the laser are used to measure said displacements and said movements. Said laser comprises an organic laser and/or a cascaded organic laser. In addition, said method is scalable in order to support the measuring of displacements and movements across one or more physical/geographical spaces including very large physical and/or geographical spaces.
(92) Said measured displacements and/or said measured movements may include one or more of: rotational displacements; rotational movements; angular displacements; and angular movements.
(93) Optionally, said laser is generated by a thin film laser generating device. It is also optional that said organic laser is generated at least from blue and green emission organic semiconductors, and that laser sensors are used for sensing said laser where said laser sensors comprise organic laser sensors and/or cascaded organic laser sensors. Said laser sensors may or may not require any power for operation.
INDUSTRIAL APPLICABILITY
(94) This invention relates to a tunable amplified spontaneous emission (ASE) laser source comprising at least two laser sources excited by a single pump laser. More particularly, the present invention relates to a tunable amplified spontaneous emission (ASE) laser source comprising at least two laser sources excited by a single pump laser wherein each of said at least two laser sources comprises an organic laser or a cascaded organic laser. The invention is used for providing a tunable amplified spontaneous emission (ASE) laser source comprising at least two laser sources excited by a single pump laser.