MARINE SALINITY MEASURING ARRANGEMENT AND METHOD
20220349065 · 2022-11-03
Assignee
Inventors
Cpc classification
B63B39/061
PERFORMING OPERATIONS; TRANSPORTING
C23F2213/31
CHEMISTRY; METALLURGY
C23F2213/21
CHEMISTRY; METALLURGY
C23F13/04
CHEMISTRY; METALLURGY
B63H20/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
The invention relates to an arrangement for measuring salinity in water, which arrangement is part of an impressed current cathodic protection system having an electrical circuit comprising a source of electrical power (310); at least one first electrode (315) connected to a positive pole of the power source (310); at least one second electrode (317) connected to a negative pole of the power source (310); a voltage sensor (341); a current sensor (342); and a control unit (313). The control unit is arranged to initiate a measurement sequence at predetermined intervals, wherein the control unit is arranged to connect at least one first electrode (315) to the negative pole of the power source (310) to act as a cathode; connect at least one passive electrode (326) to the positive pole of the power source (310) to act as an active anode; register the output voltage; register the current; determine the circuit resistance using the output voltage and the current; and calculate the resistivity of the electrolyte based on the determined circuit resistance and at least one stored electrode property value, which resistivity is inversely proportional to the salinity. The invention further relates to a vessel provided with such a measuring arrangement and a method for its operation.
Claims
1.-15. (canceled)
16. Arrangement for measuring salinity in water, which arrangement comprises an impressed current cathodic protection system having an electrical circuit comprising: a source of electrical power from a direct current power source; at least one first electrode connected to a positive pole of the power source whereby the at least one first electrode is an active anode; at least one second electrode connected to a negative pole of the power source whereby the at least one second electrode is a cathode; at least one sacrificial electrode normally disconnected from the circuit; a voltage sensor detecting an output voltage impressed on the circuit; a current sensor detecting a current supplied to the circuit; and a control unit for controlling the impressed current cathodic protection system; characterized in that the control unit is operable to initiate a measurement sequence at predetermined intervals, during which measurement sequence the control unit is operable to; connect at least one first electrode to the negative pole of the power source whereby the at least one first electrode is a cathode; connect at least one sacrificial electrode to the positive pole of the power source whereby the at least one sacrificial electrode is an active anode; wherein the control unit is operable to register the output voltage and the current in order to determine the circuit resistance; and further operable to perform a calculation of the resistivity of the electrolyte based on the determined circuit resistance and at least one stored electrode property value, which resistivity is inversely proportional to the salinity.
17. Arrangement according to claim 16, characterized in that the at least one stored electrode property value is the surface area of the sacrificial electrode.
18. Arrangement according to claim 17, characterized in that the control unit is operable to calculate the resistivity using the formula:
19. Arrangement according to claim 17, characterized in that a further electrode property value is the surface area of the first electrode connected to the negative pole.
20. Arrangement according to claim 19, characterized in that the control unit is operable to calculate the resistivity using the formula:
21. Arrangement according to claim 16, characterized in that the control unit is operable to maintain the impressed current cathodic protection system in operation if the determined resistivity is above a set threshold value.
22. Arrangement according to claim 16, characterized in that the control unit is operable to determine a current salinity value based on the determined resistivity and to generate an output signal indicating the salinity value to a user.
23. Arrangement according to claim 16, characterized in that the control unit is operable to monitor changes in the determined resistivity; to compare an increase in the determined resistivity to stored values for resistivity; and to determine if the increase is indicative of an electrical circuit malfunction.
24. Arrangement according to claim 16, characterized in that the control unit is operable to disconnect each second electrode from the negative pole of the power source during the measuring sequence.
25. Marine vessel characterized in that the marine vessel is provided with an impressed current cathodic protection system comprising an arrangement for measuring salinity according to claim 16.
26. A method for measuring salinity in water using an impressed current cathodic protection system onboard a marine vessel; the impressed current cathodic protection system having an electrical circuit comprising: a source of electrical power from a direct current power source at least one first electrode connected to a positive pole of the power source to act as an active anode; at least one second electrode connected to a negative pole of the power source to act as a cathode; at least one sacrificial electrode normally disconnected from the circuit; a voltage sensor detecting an output voltage impressed on the circuit; a current sensor detecting a current supplied to the circuit; and a control unit for controlling the impressed current cathodic protection system; characterized by performing the following steps: initiating a measurement sequence at predetermined intervals; and during the measurement sequence performing the further steps of: connecting the at least one first electrode to the negative pole of the power source; connecting the at least one sacrificial electrode to the positive pole of the power source; registering the output voltage; registering current; determining the circuit resistance using said output voltage and current, and calculating the resistivity of the electrolyte based on the determined circuit resistance and at least one stored electrode property value, which resistivity is inversely proportional to the salinity.
27. A method according to claim 26, characterized by calculating the resistivity of the electrolyte based on the determined circuit resistance and the surface area of the sacrificial electrode.
28. A method according to claim 27, characterized by calculating the resistivity of the electrolyte based on the determined circuit resistance and the surface area of the first electrode connected to the negative pole.
29. A method according to claim 27, characterized by calculating the resistivity of the electrolyte based on the determined circuit resistance and the combined surface area of each electrode connected to the negative pole.
30. Method according to any one of claim 26, characterized by maintaining the impressed current cathodic protection system in operation if the determined resistivity is above a set threshold value.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0065] With reference to the appended drawings, below follows a more detailed description of embodiments of the invention cited as examples. In the drawings:
[0066]
[0067]
[0068]
[0069]
[0070]
DETAILED DESCRIPTION OF EXAMPLE EMBODIMENTS OF THE INVENTION
[0071]
[0072] Regulation of the voltage and current output from the direct current power source is controlled to automate the current output while the voltage output is varied, or to automate the voltage output while the current output is varied. This allows the corrosion protection level to be maintained under changing conditions, e.g. variations in water resistivity or water velocity. In a sacrificial anode system, increases in the seawater resistivity can cause a decrease in the anode output and a decrease in the amount of protection provided, while a change from stagnant conditions results in an increase in current demand to maintain the required protection level. With ICCP systems protection does not decrease in the range of standard seawater nor does it change due to moderate variations in current demand. An advantage of ICCP systems is that they can provide constant monitoring of the electrical potential at the water/hull interface and can adjust the output to the anodes in relation to this. An ICCP system comprising a reference electrode is more effective and reliable than sacrificial anode systems where the level of protection is unknown and uncontrollable.
[0073] The corrosion protection arrangement is an impressed current cathodic protection (ICCP) arrangement using the propellers 102, 103 as an anode 115. In
[0074]
[0075] In the example shown in
[0076] As schematically indicated in
[0077]
[0078] The control unit 313 is adapted to measure an electrical potential of the cathode 317 with a reference electrode 324 (R) as a ground reference. The electrical potential of the cathode 317 is measured using a voltage sensor 330. The electrical potential is indicative of the surface polarization at the interface between the cathode 317 and an electrolyte W; in this case water. The control unit 313 is further adapted to control the electrical power to the active anode 315 (A) and the cathode 317 (C) based at least partly on the measured electrical potential of the cathode 317 with the reference electrode 324 (R) as a ground reference. Through the control of the electrical power, a first electrical current (indicated in
[0079] More specifically, the parameter of interest for control of the corrosion protection of the cathode 317 is the electrical potential of the cathode 317 with the reference electrode as a ground reference, corresponding to the surface polarization at the interface between the cathode 317 and the water W, and the electrical power to the active anode 315 and the cathode 317 is subjected to a closed loop control so as for said surface polarization to assume a desired value.
[0080] Thus, the corrosion protection system for the cathode 317 comprises an ICCP system with the active anode 315, the reference electrode 324, the battery 310 and the control unit 313. In
[0081] The control unit 313 further comprises a number of controllable switches for controlling different functions of the corrosion protection system. A first switch 331 is arranged between the positive terminal of the battery 310 and the anode 315, which first switch 331 is normally closed to supply the anode with power during an active corrosion protection mode. When opened, the first switch 331 disconnects the active anode 315 from the positive terminal of the battery 310. A second switch 332 is arranged between the negative terminal of the battery 310 and the cathode 317, which second switch 332 is normally switched to a closed position to maintain a closed circuit including the active anode 315, the cathode 317 and the battery 310 during active corrosion protection mode, wherein a current I.sub.1 flows from the battery 310 to the active anode 315. When opened, the second switch 332 can disconnect the cathode 317 from the negative terminal of the battery 310. A third switch 333 is arranged between the negative terminal of the battery 310 and the anode 315, which third switch 333 is normally open during active corrosion protection mode. When closed, the third switch 333 can connect the active anode 317 to the negative terminal of the battery 310. A fourth switch 334 is arranged to connect or disconnect a sacrificial, or passive anode 326 (P) to or from the corrosion protection system. The fourth switch 334 is a three position switch that is normally in a first position (lower contactor in
[0082] The corrosion protection system for the cathode 317 comprises a passive corrosion protection system with the passive anode 326 and the control unit 313. Should a fault occur in the active corrosion protection system, then the fourth switch 334 is switched from its open position to a first closed position (central contactor in
[0083]
[0084] However, in the salinity measurement mode, the switches in the electrical circuit are controlled by the control unit 313 so that the active anode 315 temporarily forms a cathode (C) and the normally disconnected passive anode 326 temporarily forms an active anode (A). While the corrosion protection system is in a salinity measurement mode, the cathode 317 which is normally protected by the corrosion protection system is temporarily disconnected from the circuit. The control unit 313 is arranged to interrupt the corrosion protection mode and switch to the salinity measurement mode at regular intervals to monitor the salinity of the water in which the vessel is operated. Any suitable time interval can be selected for this purpose, although an interval of 5-10 minutes is sufficient for the intended purpose.
[0085] In operation, when switching to the salinity measurement mode, the control unit 313 will actuate the controllable switches as follows. Initially, the first switch 331, arranged between the positive terminal of the battery 310 and the anode 315, is opened to disconnect the active anode 315 from the battery. Subsequently, the second switch 332, arranged between the negative terminal of the battery 310 and the cathode 317, is switched to disconnect the cathode 317 from the battery 310. The third switch 333, arranged between the negative terminal of the battery 310 and the active anode 315, is then closed to connect the active anode 315 to the negative terminal of the battery 310. The active anode 315 now forms a cathode for the duration of the measurement mode. Finally, the fourth switch 334, arranged to connect or disconnect the passive anode 326 to or from the corrosion protection system, is switched to a second position (upper contactor in
[0086] It should be noted that the electrical circuit described above is only one of a multitude of possible solutions allowing the circuit to be switched between a corrosion protection mode, a salinity measurement mode and a passive protection mode. Hence, the inventive concept is not limited to the electrical circuit shown in
[0087] During the salinity measurement mode, the control unit 313 performs a measurement sequence. As indicated above, at least one first active electrode or anode 315 is disconnected from the positive pole and connected to the negative pole of the battery 310 to act as a cathode, at least one passive electrode 326 is connected to the positive pole of the battery 310 to act as an active anode and each second electrode 317 is disconnected from the negative pole of the power source. A temporary measurement circuit is then formed by the active anode 315 acting as a cathode, the passive anode 326 acting as an active anode and the battery 310, wherein a current I.sub.2 flows from the battery 310 to the passive anode 326 acting as an active anode.
[0088] During the measurement sequence the control unit 313 is arranged to register the output voltage to the measurement circuit using a voltage sensor 341. The control unit 313 is further arranged to register the current using a current sensor 342. Subsequently, the circuit resistance can be determined using the output voltage and the current, by applying Ohm's law. Based on the determined circuit resistance and at least one stored electrode property value, the resistivity of the electrolyte can be calculated. In this example, the stored electrode property values are the surface area A.sub.a of the passive anode 326 acting as an active anode is used. Alternatively, the surface area A.sub.a of the passive anode 326 and the surface area A.sub.c of the active anode 315, acting as a cathode can be used.
[0089] According to one example, the control unit is arranged to calculate the resistivity (ρ) using the formula:
[0090] wherein: R.sub.c is the circuit resistance (Ω); [0091] k is a correlation factor (−); [0092] ρ is the resistivity of the electrolyte (Ωcm); [0093] A.sub.a is the surface area of the passive electrode acting as an anode (cm.sup.2).
[0094] In this example the only surface area A.sub.a of the passive anode 326 acting as an active anode is used. This formula can be used if the surface area A.sub.c of the active anode 315, acting as a cathode is relatively large, whereby the contribution of this surface area is negligible.
[0095] According to one example, the control unit is arranged to calculate the resistivity (ρ) using the formula:
[0096] wherein: R.sub.c is the circuit resistance (Ω); [0097] k is a correlation factor (−); [0098] ρ is the resistivity of the electrolyte (Ωcm); [0099] A.sub.a is the surface area of the passive electrode (cm.sup.2); [0100] A.sub.c is the surface area of the electrode acting as a cathode (cm.sup.2).
[0101] In this example both the surface area A.sub.a of the passive anode 326 acting as an active anode and the surface area A.sub.c of the active anode 315, acting as a cathode is used.
[0102] As the resistivity is inversely proportional to the salinity, a current value for electrolyte salinity can be obtained using a stored conversion table and stored in a memory. Stored salinity values can subsequently be retrieved for comparison with updated salinity values.
[0103] A standard value for the correlation factor k can be taken from the McCoy formula:
[0104] wherein the correlation factor k=0.315 is a standard applicable to anodes that are flush mounted onto a hull or a similar surface. Active anodes and passive anodes can have different shapes and sizes, depending on anode design, which will affect the surface area and thereby the correlation factor. The correlation factor can also be dependent on which component part, e.g. a propeller, that is used as an active anode in the corrosion protection mode. Consequently the value of the correlation factor can vary. Suitable values for the correlation factor can be determined by testing and calibration of each system or type of installation.
[0105] The reason for using the active anode and the passive anode for performing a salinity measurement during the salinity measurement mode is that the surface areas of these anodes are known and will only be marginally reduced over time. The cathode(-s) of the corrosion protection system is less suitable for this purpose as the useful surface area of the at least one protected metallic components to be protected can vary with the type of installation and the number of components connected to the system. The surface area can also vary depending on the amount of surface oxidation or whether one or more components have been fully or partially coated with an anti-corrosion coating subsequent to the installation of the system.
[0106] As long as the detected salinity has a value within a range representing normal variations for sea water, having approximately 3.5% salinity, the corrosion protection system resumes normal operation after exiting the salinity measurement mode. The detected salinity values are registered for comparison with subsequently detected values. When a decrease in salinity is detected, the control unit will automatically attempt to compensate for this by regulating the voltage to maintain a desired potential. If the detected salinity value drops to a value at or near zero, the control unit will no longer be able to compensate for this to maintain the desired potential. However, by comparing a currently detected salinity value with previously registered values, the control unit 313 can determine that the reduction of the salinity value is caused by the vessel moving into a body of fresh or brackish water. By making this determination, the control unit can establish that the inability to compensate for the drop in potential is caused by a change in salinity value and not by a malfunction in the corrosion protection system. Consequently, the corrosion protection system will continue to operate, albeit at reduced efficiency level.
[0107]
[0108] With reference to
[0109] With reference to
[0110] In a first step 401, the method involves connecting the first electrode 315 to the negative pole of the power source to act as a cathode C. In a second step 402, the method involves connecting the passive electrode 326 to the positive pole of the power source to act as an active anode A. In a third step 403, the method involves registering the output voltage transmitted from the voltage sensor 341, which voltage represents the potential of the electrical circuit. In a fourth step 404, the method involves registering the current transmitted from the current sensor 342. In a fifth step 405, the method involves determining the circuit resistance using said output voltage and current. In a sixth step 406, the method involves calculating the resistivity p of the electrolyte based on the determined circuit resistance and at least one stored electrode property value, which resistivity is inversely proportional to the salinity. The electrode property value is preferably the surface area of the electrode, as described above. After a predetermined period of the measurement sequence has been completed and can be terminated. Subsequently, the first and second electrodes 315, 326 are reconnected to their original terminals on the power source 310 in a final step 407. The normal operation of the impressed cathodic corrosion protection can then be resumed.
[0111] It is to be understood that the present invention is not limited to the embodiments described above and illustrated in the drawings; rather, the skilled person will recognize that many changes and modifications may be made within the scope of the appended claims.