1. Patent Search
  2. Details

Organic light-emitting device

09896621 ยท 2018-02-20

Assignee

Inventors

Cpc classification

International classification

Abstract

An organic light-emitting device includes a first electrode, a second electrode facing the first electrode, an emission layer between the first electrode and the second electrode, a hole transport region between the first electrode and the emission layer, and an electron transport region between the second electrode and the emission layer. The hole transport region includes a first compound represented by one of Formulae 1A, 1B, and 1C, and the electron transport region includes a second compound represented by one of Formulae 40A and 40B: ##STR00001## ##STR00002##

Claims

1. An organic light-emitting device, comprising: a first electrode; a second electrode facing the first electrode; an emission layer between the first electrode and the second electrode; a hole transport region between the first electrode and the emission layer; and an electron transport region between the second electrode and the emission layer, wherein the hole transport region includes a first compound represented by one of Formulae 1A, 1B, and 1C, and the electron transport region includes a second compound represented by one of Formulae 40A and 40B: ##STR00255## wherein, in Formulae 1A, 1B, 1C, 40A, and 40B, X.sub.41 is N or C-(L.sub.41).sub.a41-(R.sub.41).sub.b41, X.sub.42 is N or C-(L.sub.42).sub.a42-(R.sub.42).sub.b42, X.sub.43 is N or C-(L.sub.43).sub.a43-(R.sub.43).sub.b43, X.sub.44 is N or C-(L.sub.44).sub.a44-(R.sub.44).sub.b44, and at least one selected from X.sub.41 to X.sub.44 is N; X.sub.51 is N or C-(L.sub.51).sub.a51-(R.sub.51).sub.b51, X.sub.52 is N or C-(L.sub.52).sub.a52-(R.sub.52).sub.b52, X.sub.53 is N or C-(L.sub.53).sub.a53-(R.sub.53).sub.b53, and at least one selected from X.sub.51 to X.sub.53 is N; L.sub.1 to L.sub.12 are each independently selected from a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkylene group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkylene group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenylene group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenylene group, a substituted or unsubstituted C.sub.6-C.sub.60 arylene group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroarylene group, a substituted or unsubstituted divalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted divalent non-aromatic condensed heteropolycyclic group; L.sub.41 to L.sub.46 and L.sub.51 to L.sub.57 are each independently selected from a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkylene group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenylene group, a substituted or unsubstituted C.sub.6-C.sub.60 arylene group, and a substituted or unsubstituted divalent non-aromatic condensed polycyclic group; a1 to a12, a41 to a46, and a51 to a57 are each independently an integer selected from 0 to 3; Ar.sub.1 to Ar.sub.8, R.sub.41 to R.sub.46, and R.sub.51 to R.sub.57 are each independently selected from a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryl group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group; Ar.sub.1 and Ar.sub.2 are optionally linked to each other to form a saturated or unsaturated ring, Ar.sub.3 and Ar.sub.4 are optionally linked to each other to form a saturated or unsaturated ring, Ar.sub.5 and Ar.sub.6 are optionally linked to each other to form a saturated or unsaturated ring, and Ar.sub.7 and Ar.sub.8 are optionally linked to each other to form a saturated or unsaturated ring; at least one of R.sub.41 to R.sub.46 or at least one of R.sub.51 to R.sub.57 is selected from a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, and a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group; b1 to b8, b41 to b46, and b51 to b57 are each independently an integer selected from 1 to 4; R.sub.1 to R.sub.12 and R.sub.58 to R.sub.60 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a substituted or unsubstituted C.sub.1-C.sub.60 alkyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkenyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkynyl group, a substituted or unsubstituted C.sub.1-C.sub.60 alkoxy group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryloxy group, a substituted or unsubstituted C.sub.6-C.sub.60 arylthio group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group, and Si(Q.sub.1)(Q.sub.2)(Q.sub.3); R.sub.11 and R.sub.12 are optionally linked to each other to form a saturated or unsaturated ring; c1 to c10 are each independently an integer selected from 0 to 4; n1 to n4 and n7 to n10 are each independently an integer selected from 0 to 4, and n5 and n6 are each independently an integer selected from 0 to 5, provided that n1+n2+n3+n4 is 1 or more, n5+n6+n7+n8 is 1 or more, and n9+n10 is 1 or more; at least one of substituents of the substituted C.sub.3-C.sub.10 cycloalkylene group, substituted C.sub.1-C.sub.10 heterocycloalkylene group, substituted C.sub.3-C.sub.10 cycloalkenylene group, substituted C.sub.1-C.sub.10 heterocycloalkenylene group, substituted C.sub.6-C.sub.60 arylene group, substituted C.sub.1-C.sub.60 heteroarylene group, substituted divalent non-aromatic condensed polycyclic group, substituted divalent non-aromatic condensed heteropolycyclic group, substituted C.sub.1-C.sub.60 alkyl group, substituted C.sub.2-C.sub.60 alkenyl group, substituted C.sub.2-C.sub.60 alkynyl group, substituted C.sub.1-C.sub.60 alkoxy group, substituted C.sub.3-C.sub.10 cycloalkyl group, substituted C.sub.1-C.sub.10 heterocycloalkyl group, substituted C.sub.3-C.sub.10 cycloalkenyl group, substituted C.sub.1-C.sub.10 heterocycloalkenyl group, substituted C.sub.6-C.sub.60 aryl group, substituted C.sub.6-C.sub.60 aryloxy group, substituted C.sub.6-C.sub.60 arylthio group, substituted C.sub.1-C.sub.60 heteroaryl group, substituted monovalent non-aromatic condensed polycyclic group, and substituted monovalent non-aromatic condensed heteropolycyclic group is selected from: a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group; a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group(aryloxy), a C.sub.6-C.sub.60 arylthio group(arylthio), a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, and Si(Q.sub.11)(Q.sub.12)(Q.sub.13); a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.2-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group; a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, and Si(Q.sub.21)(Q.sub.22)(Q.sub.23); and Si(Q.sub.31)(Q.sub.32)(Q.sub.33), wherein Q.sub.1 to Q.sub.3, Q.sub.11 to Q.sub.13, Q.sub.21 to Q.sub.23, and Q.sub.31 to Q.sub.33 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group.

2. The organic light-emitting device as claimed in claim 1, wherein: the second compound is represented by Formula 40A, and in Formula 40A, X.sub.41, X.sub.42, and X.sub.44 are N, and X.sub.43 is C(R.sub.43); X.sub.41 and X.sub.44 are N, X.sub.42 is C(R.sub.42), and X.sub.43 is C(R.sub.43); or X.sub.41 and X.sub.43 are N, X.sub.42 is C(R.sub.42), and X.sub.44 is C(R.sub.44); or the second compound is represented by Formula 40B and in Formula 40B, X.sub.51, X.sub.52, and X.sub.53 are N; or X.sub.52 and X.sub.53 are N, and X.sub.51 is C(R.sub.51).

3. The organic light-emitting device as claimed in claim 1, wherein L.sub.1 to L.sub.12, L.sub.41 to L.sub.46, and L.sub.51 to L.sub.57 are each independently selected from a phenylene group, a pentalenylene group, an indenylene group, a naphthylene group, an azulenylene group, a heptalenylene group, an indacenylene group, an acenaphthylene group, a fluorenylene group, a spiro-fluorenylene group, a benzofluorenylene group, a dibenzofluorenylene group, a phenalenylene group, a phenanthrenylene group, an anthracenylene group, a fluoranthenylene group, a triphenylenylene group, a pyrenylene group, a chrysenylene group, a naphthacenylene group, a picenylene group, a perylenylene group, a pentaphenylene group, a hexacenylene group, a pentacenylene group, a rubicenylene group, a coronenylene group, a ovalenylene group, a pyrrolylene group, a thiophenylene group, a furanylene group, an imidazolylene group, a pyrazolylene group, a thiazolylene group, an isothiazolylene group, an oxazolylene group, an isoxazolylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, an isoindolylene group, an indolylene group, an indazolylene group, a purinylene group, a quinolinylene group, an isoquinolinylene group, a benzoquinolinylene group, a phthalazinylene group, a naphthyridinylene group, a quinoxalinylene group, a quinazolinylene group, a cinnolinylene group, a carbazolylene group, a phenanthridinylene group, an acridinylene group, a phenanthrolinylene group, a phenazinylene group, a benzoimidazolylene group, a benzofuranylene group, a benzothiophenylene group, an isobenzothiazolylene group, a benzoxazolylene group, an isobenzoxazolylene group, a triazolylene group, a tetrazolylene group, an oxadiazolylene group, a triazinylene group, a dibenzofuranylene group, a dibenzothiophenylene group, a benzocarbazolylene group, a dihenzocarbazolylene group, a thiadiazolylene group, an imidazopyridinylene group, and an imidazopyrimidinylene group; and a phenylene group, a pentalenylene group, an indenylene group, a naphthylene group, an azulenylene group, a heptalenylene group, an indacenylene group, an acenaphthylene group, a fluorenylene group, a spiro-fluorenylene group, a benzofluorenylene group, a dibenzofluorenylene group, a phenalenylene group, a phenanthrenylene group, an anthracenylene group, a fluoranthenylene group, a triphenylenylene group, a pyrenylene group, a chrysenylene group, a naphthacenylene group, a picenylene group, a perylenylene group, a pentaphenylene group, a hexacenylene group, a pentacenylene group, a rubicenylene group, a coronenylene group, an ovalenylene group, a pyrrolylene group, a thiophenylene group, a furanylene group, an imidazolylene group, a pyrazolylene group, a thiazolylene group, an isothiazolylene group, an oxazolylene group, an isoxazolylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, an isoindolylene group, an indolylene group, an indazolylene group, a purinylene group, a quinolinylene group, an isoquinolinylene group, a benzoquinolinylene group, a phthalazinylene group, a naphthyridinylene group, a quinoxalinylene group, a quinazolinylene group, a cinnolinylene group, a carbazolylene group, a phenanthridinylene group, an acridinylene group, a phenanthrolinylene group, a phenazinylene group, a benzoimidazolylene group, a benzofuranylene group, a benzothiophenylene group, an isobenzothiazolylene group, a benzoxazolylene group, an isobenzoxazolylene group, a triazolylene group, a tetrazolylene group, an oxadiazolylene group, a triazinylene group, a dibenzofuranylene group, a dibenzothiophenylene group, a benzocarbazolylene group, a dibenzocarbazolylene group, a thiadiazolylene group, an imidazopyridinylene group, and an imidazopyrimidinylene group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group, a cyclohexenyl group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group.

4. The organic light-emitting device as claimed in claim 1, wherein L.sub.1 to L.sub.12 are each independently selected from groups represented by Formulae 3-1 to 3-41, and L.sub.41 to L.sub.46 and L.sub.51 to L.sub.57 are each independently selected from groups represented by Formulae 3-1 to 3-9, 3-25, and 3-33 to 3-41: ##STR00256## ##STR00257## ##STR00258## ##STR00259## ##STR00260## wherein, in Formulae 3-1 to 3-41, Y.sub.1 is O, S, C(Z.sub.3)(Z.sub.4), N(Z.sub.5), or Si(Z.sub.6)(Z.sub.7), provided that in Formulae 3-3 and 3-4, Y.sub.1?C(Z.sub.3)(Z.sub.4); Z.sub.1 to Z.sub.7 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, and a C.sub.1-C.sub.20 alkoxy group; a C.sub.1-C.sub.20 alkyl group and a C.sub.1-C.sub.20 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, and a phosphoric acid group or a salt thereof; a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a carbazolyl group, a benzocarbazolyl group, and a dibenzocarbazolyl group; a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a carbazolyl group, a benzocarbazolyl group, and a dibenzocarbazolyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, and a naphthyl group; and Si(Q.sub.31)(Q.sub.32)(Q.sub.33), wherein Q.sub.1 to Q.sub.3 and Q.sub.31 to Q.sub.33 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, and a carbazolyl group; d2 is an integer selected from 1 and 2; d3 is an integer selected from 1 to 3; d4 is an integer selected from 1 to 4; d5 is an integer selected from 1 to 5; d6 is an integer selected from 1 to 6; d8 is an integer selected from 1 to 8; and * and * each indicate a binding site to an adjacent atom.

5. The organic light-emitting device as claimed in claim 1, wherein L.sub.1 to L.sub.12 are each independently selected from groups represented by Formulae 4-1 to 4-36, and L.sub.41 to L.sub.46 and L.sub.51 to L.sub.57 are each independently selected from groups represented by Formulae 4-1, 4-3, 4-5, 4-7 to 4-13, 4-17, and 4-24 to 4-36: ##STR00261## ##STR00262## ##STR00263## ##STR00264## ##STR00265## wherein, in Formulae 4-1 to 4-36, *and * each indicate a binding site to an adjacent atom.

6. The organic light-emitting device as claimed in claim 1, wherein Ar.sub.1 to Ar.sub.8, R.sub.41 to R.sub.46, and R.sub.51 to R.sub.57 are each independently selected from a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group; and a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group, a cyclohexenyl group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, an imidazopyrimidinyl group, and Si(Q.sub.31)(Q.sub.32)(Q.sub.33), wherein Q.sub.31 to Q.sub.33 are each independently selected from a hydrogen, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a pyridinyl group, a pyrimidinyl group, a triazinyl group, a quinolinyl group, and an isoquinolinyl group.

7. The organic light-emitting device as claimed in claim 1, wherein Ar.sub.1 to Ar.sub.8, R.sub.41 to R.sub.46, and R.sub.51 to R.sub.57 are each independently selected from groups represented by Formulae 5-1 to 5-87: ##STR00266## ##STR00267## ##STR00268## ##STR00269## ##STR00270## ##STR00271## ##STR00272## ##STR00273## ##STR00274## wherein, in Formulae 5-1 to 5-87, Y.sub.11 is O, S, C(Z.sub.13)(Z.sub.14), N(Z.sub.15), or Si(Z.sub.16)(Z.sub.17); Z.sub.11 to Z.sub.17 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, and a C.sub.1-C.sub.20 alkoxy group; a C.sub.1-C.sub.20 alkyl group and a C.sub.1-C.sub.20 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, and a phosphoric acid group or a salt thereof; a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a carbazolyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, and a dibenzofuranyl group; a phenyl group, a naphthyl group, a pyridinyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a carbazolyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, and a dibenzofuranyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, and a pyridinyl group; and Si(Q.sub.31)(Q.sub.32)(Q.sub.33); and Z.sub.11 and Z.sub.12 are optionally linked to each other to form a saturated or unsaturated ring, and Z.sub.13 and Z.sub.14 are optionally linked to each other to form a C.sub.5 to C.sub.20 saturated or unsaturated ring, wherein Q.sub.31 to Q.sub.33 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, and a carbazolyl group; e2 is an integer selected from 1 and 2; e3 is an integer selected from 1 to 3; e4 is an integer selected from 1 to 4; e5 is an integer selected from 1 to 5; e6 is an integer selected from 1 to 6; e7 is an integer selected from 1 to 7; e8 is an integer selected from 1 to 8; e9 is an integer selected from 1 to 9; and * indicates a binding site to an adjacent atom.

8. The organic light-emitting device as claimed in claim 1, wherein Ar.sub.1 to Ar.sub.8, R.sub.41 to R.sub.46, and R.sub.51 to R.sub.57 are each independently selected from groups represented by Formulae 6-1 to 6-170: ##STR00275## ##STR00276## ##STR00277## ##STR00278## ##STR00279## ##STR00280## ##STR00281## ##STR00282## ##STR00283## ##STR00284## ##STR00285## ##STR00286## ##STR00287## ##STR00288## ##STR00289## ##STR00290## ##STR00291## ##STR00292## ##STR00293## ##STR00294## ##STR00295## ##STR00296## ##STR00297## ##STR00298## ##STR00299## ##STR00300## ##STR00301## wherein, in Formulae 6-1 to 6-170, * indicates a binding site to an adjacent atom.

9. The organic light-emitting device as claimed in claim 1, wherein, in Formulae 1A to 1C, at least one of ##STR00302## is selected from groups represented by Formulae 7-1 and 7-2: ##STR00303## wherein, in Formulae 7-1 and 7-2, Y.sub.21 is selected from O, S, C(Z.sub.23)(Z.sub.24), N(Z.sub.25), and Si(Z.sub.26)(Z.sub.27); and Z.sub.21 to Z.sub.27 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a triazinyl group, and Si(Q.sub.31)(Q.sub.32)(Q.sub.33), wherein Q.sub.31 to Q.sub.33 are each independently selected from a C.sub.1-C.sub.10 alkyl group, a C.sub.1-C.sub.10 alkoxy group, a phenyl group, and a naphthyl group; f4 is an integer selected from 1 to 4; and * indicates a binding site to an adjacent atom.

10. The organic light-emitting device as claimed in claim 1, wherein at least one of R.sub.41 to R.sub.46 in Formula 40A or at least one of R.sub.51 to R.sub.57 in Formula 40B is selected from groups represented by Formulae 5-1 to 5-67: ##STR00304## ##STR00305## ##STR00306## ##STR00307## ##STR00308## ##STR00309## wherein, in Formulae 5-1 to 5-67, Z.sub.11 and Z.sub.12 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, and a C.sub.1-C.sub.20 alkoxy group; a C.sub.1-C.sub.20 alkyl group and a C.sub.1-C.sub.20 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, and a phosphoric acid group or a salt thereof; a phenyl group, a naphthyl group, a fluorenyl group, a Spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a carbazolyl group, a benzocarbazolyl group, and a dibenzocarbazolyl group; a phenyl group, a naphthyl group, a pyridinyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a carbazolyl group, a benzocarbazolyl group, and a dibenzocarbazolyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, and a pyridinyl group; and Si(Q.sub.31)(Q.sub.32)(Q.sub.33), Z.sub.11 and Z.sub.12 are optionally linked to each other to form a C.sub.5 to C.sub.20 saturated or unsaturated ring, wherein Q.sub.31 to Q.sub.33 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, and a carbazolyl group; e2 is an integer selected from 1 and 2; e3 is an integer selected from 1 to 3; e4 is an integer selected from 1 to 4; e5 is an integer selected from 1 to 5; e6 is an integer selected from 1 to 6; e7 is an integer selected from 1 to 7; e8 is an integer selected from 1 to 8; e9 is an integer selected from 1 to 9; and * indicates a binding site to an adjacent atom.

11. The organic light-emitting device as claimed in claim 1, wherein at least one of R.sub.41 to R.sub.46 in Formula 40A or at least one of R.sub.51 to R.sub.57 in Formula 40B is selected from groups represented by Formulae 10-1 to 10-123: ##STR00310## ##STR00311## ##STR00312## ##STR00313## ##STR00314## ##STR00315## ##STR00316## ##STR00317## ##STR00318## ##STR00319## ##STR00320## ##STR00321## ##STR00322## ##STR00323## ##STR00324## ##STR00325## ##STR00326## wherein, in Formulae 10-1 to 10-123, * indicates a binding site to an adjacent atom.

12. The organic light-emitting device as claimed in claim 1, wherein R.sub.1 to R.sub.12 and R.sub.58 to R.sub.60 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a phenalenyl group, a pyrenyl group, a dibenzothiophenyl group, and Si(Q.sub.1)(Q.sub.2)(Q.sub.3).

13. The organic light-emitting device as claimed in claim 1, wherein the first compound is represented by one of Formulae 1A-1 to 1A-10, 1B-1 to 1B-4, 1C-1, and 1C-2, and the second compound is represented by one of Formulae 40A-1 to 40A-3, 40B-1, and 40B-2: ##STR00327## ##STR00328## ##STR00329## wherein, in the Formulae above, descriptions of L.sub.1 to L.sub.12, L.sub.41 to L.sub.46, L.sub.51 to L.sub.57, a1 to a12, a41 to a46, a51 to a57, Ar.sub.1 to Ar.sub.8, R.sub.1 to R.sub.12, R.sub.42 to R.sub.46, R.sub.51, R.sub.54 to R.sub.60, b1 to b20, b42 to b46, b51 to b57, and c1 to c10 are the same as described in claim 1.

14. The organic light-emitting device as claimed in claim 1, wherein the first compound is represented by Formulae 1A-1(1), 1A-2(1), 1A-2(2), 1A-3(1), 1A-4(1), 1A-4(2), 1A-5(1), 1A-6(1), 1A-7(1), 1A-8(1), 1A-8(2), 1A-9(1), 1A-9(2), 1A-9(3), 1A-10(1), 1A-10(2), 1B-(1), 1B-2(1), 1B-3(1), 1B-4(1), 1C-1(1), and 1C-1(2), and the second compound is represented by Formulae 40A-1(1), 40A-1(2), 40A-1(3), 40A-2(1), 40A-3(1), 40B-1(1), 40B-1(2), 40B-2(1), and 40B-2(1) to 40B-2(5): ##STR00330## ##STR00331## ##STR00332## ##STR00333## ##STR00334## ##STR00335## wherein, in the Formulae above, descriptions of L.sub.1 to L.sub.3, L.sub.7, L.sub.10, L.sub.12, L.sub.43, L.sub.45, L.sub.46, L.sub.56, L.sub.57, Ar.sub.1 to Ar.sub.8, R.sub.2, R.sub.3, R.sub.7, R.sub.42 to R.sub.44, R.sub.46, R.sub.54, and R.sub.55 are the same as described in claim 1, R.sub.45 is selected from groups represented by Formulae 10-1 to 10-123, and at least one of R.sub.56 and R.sub.57 is selected from groups represented by Formulae 10-1 to 10-123: ##STR00336## ##STR00337## ##STR00338## ##STR00339## ##STR00340## ##STR00341## ##STR00342## ##STR00343## ##STR00344## ##STR00345## ##STR00346## ##STR00347## ##STR00348## ##STR00349## ##STR00350## ##STR00351## ##STR00352## wherein, in Formulae 10-1 to 10-123, * indicates a binding site to an adjacent atom.

15. The organic light-emitting device as claimed in claim 1, wherein the first compound is a compound represented by one of Compounds 1 to 53, and the second compound is a compound represented by one of Compounds A 1 to A32: ##STR00353## ##STR00354## ##STR00355## ##STR00356## ##STR00357## ##STR00358## ##STR00359## ##STR00360## ##STR00361## ##STR00362## ##STR00363## ##STR00364## ##STR00365## ##STR00366## ##STR00367## ##STR00368##

16. The organic light-emitting device as claimed in claim 1, wherein the emission layer includes at least one selected from a first host represented by Formula 101, a second host represented by Formula 201, a third host represented by Formula 202, a fourth host represented by Formula 301, and a fifth host represented by Formula 302: ##STR00369## wherein, in the Formulae above, Ar.sub.101, A.sub.201 to A.sub.204, A.sub.211 to A.sub.214, A.sub.301 to A.sub.303, A.sub.311, and A.sub.312 are each independently a substituted or unsubstituted C.sub.6-C.sub.20 aromatic ring; A.sub.304 and A.sub.314 are each independently a group represented by Formula 303; X.sub.301 is selected from N(L.sub.302).sub.a302-Ar.sub.302, an oxygen (O) atom, a sulfur (S) atom, C(R.sub.303)(R.sub.304), Si(R.sub.303)(R.sub.304), P(R.sub.303), B(R.sub.303), and P(?O)(R.sub.303); L.sub.101, L.sub.201 to L.sub.203, L.sub.211, L.sub.301, L.sub.302, and L.sub.311 are each independently selected from a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkylene group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkylene group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenylene group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenylene group, a substituted or unsubstituted C.sub.6-C.sub.60 arylene group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroarylene group, a substituted or unsubstituted divalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted divalent non-aromatic condensed heteropolycyclic group; a101, a201 to a203, a211, a301, a302, and a311 are each independently an integer selected from 0 to 3; R.sub.101, Ar.sub.201, Ar.sub.202, Ar.sub.301, Ar.sub.302, and Ar.sub.311 are each independently selected from a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryl group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group; R.sub.201 to R.sub.204, R.sub.211 to R.sub.214, R.sub.301 to R.sub.304, R.sub.311, and R.sub.312 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a substituted or unsubstituted C.sub.1-C.sub.60 alkyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkenyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkynyl group, a substituted or unsubstituted C.sub.1-C.sub.60 alkoxy group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryloxy group, a substituted or unsubstituted C.sub.6-C.sub.60 arylthio group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group, N(Q.sub.101)(Q.sub.102), Si(Q.sub.103)(Q.sub.104)(Q.sub.105), and B(Q.sub.106)(Q.sub.107); b201 and b203 are each independently an integer selected from 0 to 3, b202, b204, b211 to b214, b301, b302, b311, and b312 are each independently an integer selected from 0 to 4; n101 is an integer selected from 0 to 3, n201 and n202 are each independently an integer selected from 0 to 4, n211 is an integer selected from 1 and 2; at least one of substituents of the substituted C.sub.6-C.sub.20 aromatic ring, substituted C.sub.3-C.sub.10 cycloalkylene group, substituted C.sub.1-C.sub.10 heterocycloalkylene group, substituted C.sub.3-C.sub.10 cycloalkenylene group, substituted C.sub.1-C.sub.10 heterocycloalkenylene group, substituted C.sub.6-C.sub.60 arylene group, substituted C.sub.1-C.sub.60 heteroarylene group, substituted divalent non-aromatic condensed polycyclic group, substituted divalent non-aromatic condensed heteropolycyclic group, substituted C.sub.1-C.sub.60 alkyl group, substituted C.sub.2-C.sub.60 alkenyl group, substituted C.sub.2-C.sub.60 alkynyl group, substituted C.sub.1-C.sub.60 alkoxy group, substituted C.sub.3-C.sub.10 cycloalkyl group, substituted C.sub.1-C.sub.10 heterocycloalkyl group, substituted C.sub.3-C.sub.10 cycloalkenyl group, substituted C.sub.1-C.sub.10 heterocycloalkenyl group, substituted C.sub.6-C.sub.60 aryl group, substituted C.sub.6-C.sub.60 aryloxy group, substituted C.sub.6-C.sub.60 arylthio group, substituted C.sub.1-C.sub.60 heteroaryl group, substituted monovalent non-aromatic condensed polycyclic group, and substituted monovalent non-aromatic condensed heteropolycyclic group is selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group; a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.2-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, N(Q.sub.101)(Q.sub.102), Si(Q.sub.103)(Q.sub.104)(Q.sub.105), and B(Q.sub.106)(Q.sub.107); a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, aryloxy group, a C.sub.6-C.sub.60, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group; a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, N(Q.sub.111)(Q.sub.112), Si(Q.sub.113)(Q.sub.114)(Q.sub.115), and B(Q.sub.116)(Q.sub.117); and N(Q.sub.121)(Q.sub.122), Si(Q.sub.123)(Q.sub.124)(Q.sub.125), and B(Q.sub.126)(Q.sub.127), wherein Q.sub.101 to Q.sub.107, Q.sub.111 to Q.sub.117, and Q.sub.121 to Q.sub.127 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group.

17. The organic light-emitting device as claimed in claim 16, wherein the first host is represented by one of Formulae 101A to 101D, the second host is represented by Formula 201A, the third host is represented by one of Formulae 202A and 202B, the fourth host is represented by one of Formulae 301A to 301H, and the fifth host is represented by one of Formulae 302A and 302B: ##STR00370## ##STR00371## ##STR00372## ##STR00373## wherein, in the Formulae above, descriptions of Ar.sub.101, A.sub.201 to A.sub.204, A.sub.211 to A.sub.214, A.sub.301 to A.sub.304, A.sub.311, A.sub.312, A.sub.314, X.sub.30I, L.sub.101, L.sub.201 to L.sub.203, L.sub.301, L.sub.302, L.sub.311, a101, a201 to a203, a301, a302, a311, Ar.sub.201, Ar.sub.202, Ar.sub.301, Ar.sub.302, Ar.sub.311, R.sub.101, R.sub.201 to R.sub.204, R.sub.211 to R.sub.214, R.sub.301, R.sub.302, R.sub.311, R.sub.312, b101, b201 to b204, b211 to b214, b301, b302, b311, and b312 are the same as described in claim 15, descriptions of L.sub.102 and L.sub.103 are each the same as descriptions of L.sub.101, descriptions of a102 and a103 are each the same as descriptions of a101, descriptions of R.sub.102 and R.sub.103 are each the same as descriptions of R.sub.101, and descriptions of b102 and b103 are each the same as descriptions of b101, and descriptions of A.sub.213a and A.sub.213b are each the same as descriptions of A.sub.213, descriptions of A.sub.214a and A.sub.214b are each the same as descriptions of A.sub.214, descriptions of R.sub.213a and R.sub.213b are each the same as descriptions of R.sub.213, descriptions of R.sub.214b and R.sub.214b are each the same as descriptions of R.sub.214, descriptions of ba213 and bb213 are each the same as descriptions of b213, and descriptions of ba214 and bb214 are each the same as descriptions of b214.

18. The organic light-emitting device as claimed in claim 1, wherein the hole transport region includes a hole transport layer and a hole injection layer between the first electrode and the hole transport layer, the hole transport region includes a hole transport layer and a hole injection layer between the first electrode and the hole transport layer, the first compound is included in the hole injection layer and the hole transport layer, the first compound included in the hole injection layer and the first compound included in the hole transport layer are identical to or different from each other, the electron transport region includes an electron transport layer and an electron injection layer between the second electrode and the electron transport layer, and the second compound is included in the electron transport layer.

19. An organic light-emitting device, comprising: a first electrode; a second electrode facing the first electrode; an emission layer between the first electrode and the second electrode; a hole transport region between the first electrode and the emission layer; an electron transport region between the second electrode and the emission layer, wherein the hole transport region includes a hole transport layer, a hole injection layer between the first electrode and the hole transport layer, and an auxiliary emission layer between the hole transport layer and the emission layer, the electron transport region includes an electron transport layer and an electron injection layer between the second electrode and the electron transport layer, wherein the hole injection layer, the hole transport layer, and the auxiliary emission layer each include a first compound represented by one of Formulae 1A, 1B, and 1C, the first compound included in the hole injection layer, the first compound included in the hole transport layer, and the first compound included in the auxiliary emission layer are identical to or different from each other, the electron transport layer includes a second compound represented by one of Formulae 40A and 40B: ##STR00374## wherein, in Formulae 1A, 1B, 1C, 40A, and 40B, X.sub.41 is N or C-(L.sub.41).sub.a41-(R.sub.41).sub.b41, X.sub.42 is N or C-(L.sub.42).sub.a42-(R.sub.42).sub.b42, X.sub.43 is N or C-(L.sub.43).sub.a43-(R.sub.43).sub.b43, X.sub.44 is N or C-(L.sub.44).sub.a44-(R.sub.44).sub.b44, and at least one selected from X.sub.41 to X.sub.44 is N; X.sub.51 is N or C-(L.sub.51).sub.a51-(R.sub.51).sub.b51, X.sub.52 is N or C-(L.sub.52).sub.a52-(R.sub.52).sub.b52, X.sub.53 is N or C-(L.sub.53).sub.a53-(R.sub.53).sub.b53, and at least one selected from X.sub.51 to X.sub.53 is N; L.sub.1 to L.sub.12 are each independently selected from a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkylene group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkylene group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenylene group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenylene group, a substituted or unsubstituted C.sub.6-C.sub.60 arylene group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroarylene group, a substituted or unsubstituted divalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted divalent non-aromatic condensed heteropolycyclic group; L.sub.41 to L.sub.46 and L.sub.51 to L.sub.57 are each independently selected from a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkylene group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenylene group, a substituted or unsubstituted C.sub.6-C.sub.60 arylene group, and a substituted or unsubstituted divalent non-aromatic condensed polycyclic group; a1 to a12, a41 to a46, and a51 to a57 are each independently an integer selected from 0 to 3; Ar.sub.1 to Ar.sub.8, R.sub.41 to R.sub.46, and R.sub.51 to R.sub.57 are each independently selected from a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryl group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group; Ar.sub.1 and Ar.sub.7 are optionally linked to each other to form a saturated or unsaturated ring, Ar.sub.3 and Ar.sub.4 are optionally linked to each other to form a saturated or unsaturated ring, Ar.sub.5 and Ar.sub.6 are optionally linked to each other to form a saturated or unsaturated ring, and Ar.sub.7 and Ar.sub.8 are optionally linked to each other to form a saturated or unsaturated ring; at least one of R.sub.41 to R.sub.46 or at least one of R.sub.51 to R.sub.57 is selected from a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, and a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group; b1 to b8, b41 to b46, and b51 to b57 are each independently an integer selected from 1 to 4; R.sub.1 to R.sub.12 and R.sub.58 to R.sub.60 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a substituted or unsubstituted C.sub.1-C.sub.60 alkyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkenyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkynyl group, a substituted or unsubstituted C.sub.1-C.sub.60 alkoxy group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryloxy group, a substituted or unsubstituted C.sub.6-C.sub.60 arylthio group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group, and Si(Q.sub.1)(Q.sub.2)(Q.sub.3); R.sub.11 and R.sub.12 are optionally linked to each other to form a saturated or unsaturated ring; c1 to c10 are each independently an integer selected from 0 to 4; n1 to n4 and n7 to n10 are each independently an integer selected from 0 to 4, and n5 and n6 are each independently an integer selected from 0 to 5, provided that n1+n2+n3+n4 is 1 or more, n5+n6+n7+n8 is 1 or more, and n9+n10 is 1 or more; at least one of substituents of the substituted C.sub.3-C.sub.10 cycloalkylene group, substituted C.sub.1-C.sub.10 heterocycloalkylene group, substituted C.sub.3-C.sub.10 cycloalkenylene group, substituted C.sub.1-C.sub.10 heterocycloalkenylene group, substituted C.sub.6-C.sub.60 arylene group, substituted C.sub.1-C.sub.60 heteroarylene group, substituted divalent non-aromatic condensed polycyclic group, substituted divalent non-aromatic condensed heteropolycyclic group, substituted C.sub.1-C.sub.60 alkyl group, substituted C.sub.2-C.sub.60 alkenyl group, substituted C.sub.2-C.sub.60 alkynyl group, substituted C.sub.1-C.sub.60 alkoxy group, substituted C.sub.3-C.sub.10 cycloalkyl group, substituted C.sub.1-C.sub.10 heterocycloalkyl group, substituted C.sub.3-C.sub.10 cycloalkenyl group, substituted C.sub.1-C.sub.10 heterocycloalkenyl group, substituted C.sub.6-C.sub.60 aryl group, substituted C.sub.6-C.sub.60 aryloxy group, substituted C.sub.6-C.sub.60 arylthio group, substituted C.sub.1-C.sub.60 heteroaryl group, substituted monovalent non-aromatic condensed polycyclic group, and substituted monovalent non-aromatic condensed heteropolycyclic group is selected from: a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group; a C.sub.1-C.sub.60 alkyl group, a C.sub.7-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group(aryloxy), a C.sub.6-C.sub.60 arylthio group(arylthio), a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, and Si(Q.sub.11)(Q.sub.12)(Q.sub.13); a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.2-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group; a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.20 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.7-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, and Si(Q.sub.21)(Q.sub.22)(Q.sub.23); and Si(Q.sub.31)(Q.sub.32)(Q.sub.33), wherein Q.sub.1 to Q.sub.3, Q.sub.11 to Q.sub.13, Q.sub.21 to Q.sub.23, and Q.sub.31 to Q.sub.33 are each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group.

20. The organic light-emitting device as claimed in claim 18, wherein the hole injection layer further includes a charge-generating material, the charge-generating material is a p-dopant, and the electron transport layer further includes a metal-containing material.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) Features will become apparent to those of skill in the art by describing in detail exemplary embodiments with reference to the attached drawings in which:

(2) FIG. 1 illustrates a schematic view of an organic light-emitting device according to an embodiment.

DETAILED DESCRIPTION

(3) Example embodiments will now be described more fully hereinafter with reference to the accompanying drawings; however, they may be embodied in different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey exemplary implementations to those skilled in the art.

(4) In the drawing FIGURES, the dimensions of layers and regions may be exaggerated for clarity of illustration. It will also be understood that when a layer or element is referred to as being on another layer or substrate, it can be directly on the other layer or substrate, or intervening layers may also be present. Further, it will be understood that when a layer is referred to as being under another layer, it can be directly under, and one or more intervening layers may also be present. In addition, it will also be understood that when a layer is referred to as being between two layers, it can be the only layer between the two layers, or one or more intervening layers may also be present. Like reference numerals refer to like elements throughout.

(5) Expressions such as at least one of when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list.

(6) FIG. 1 illustrates a schematic view of an organic light-emitting according to an embodiment. The organic light-emitting device may include a first electrode 110, a hole transport region 130, an emission layer 150, an electron transport region 170, and a second electrode 190.

(7) Hereinafter, a structure and a method of manufacturing the organic light-emitting device according to an embodiment will be described with reference to FIG. 1.

(8) Referring to FIG. 1, a substrate may be additionally disposed under the first electrode 110 or on the second electrode 190. The substrate may be a substrate with excellent mechanical strength, thermal stability, transparency, surface smoothness, ease of handling, and water resistance. For example, the substrate may be a glass substrate or a transparent plastic substrate.

(9) The first electrode 110 may be formed by depositing or sputtering a material for forming the first electrode on the substrate. When the first electrode 110 is an anode, the material for the first electrode may be selected from materials with a high work function to make holes be easily injectable. The first electrode 110 may be a reflective electrode, a semi-transmissive electrode, or a transmissive electrode. The material for the first electrode may be a transparent and highly conductive material. Examples of such a material include indium tin oxide (ITO), indium zinc oxide (IZO), tin oxide (SnO.sub.2), and zinc oxide (ZnO). When the first electrode 110 is a semi-transmissive electrode or a reflective electrode, as a material for forming the first electrode, at least one selected from magnesium (Mg), aluminum (Al), aluminum-lithium (AlLi), calcium (Ca), magnesium-indium (MgIn), and magnesium-silver (MgAg) may be used.

(10) The first electrode 110 may have a single-layer structure, or a multi-layer structure including a plurality of layers. For example, the first electrode 110 may have a triple-layer structure of ITO/Ag/ITO.

(11) The hole transport region 130, the emission layer 150, and the electron transport region 170 may be sequentially stacked on the first electrode 110.

(12) The hole transport region may include a first compound represented by one of Formulae 1A, 1B, and 1C, and the electron transport region may include a second compound represented by Formulae 40A and 40B:

(13) ##STR00004##

(14) In the Formulae above, L.sub.1 to L.sub.12, L.sub.41 to L.sub.46, and L.sub.51 to L.sub.57 may be each independently selected from a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkylene group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkylene group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenylene group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenylene group, a substituted or unsubstituted C.sub.6-C.sub.60 arylene group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroarylene group, a substituted or unsubstituted divalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted divalent non-aromatic condensed heteropolycyclic group.

(15) In some embodiments, in the Formulae above, L.sub.1 to L.sub.12, L.sub.41 to L.sub.46, and L.sub.51 to L.sub.57 may be each independently selected from a phenylene group, a pentalenylene group, an indenylene group, a naphthylene group, an azulenylene group, a heptalenylene group, an indacenylene group, an acenaphthylene group, a fluorenylene group, a spiro-fluorenylene group, a benzofluorenylene group, a dibenzofluorenylene group, a phenalenylene group, a phenanthrenylene group, an anthracenylene group, a fluoranthenylene group, a triphenylenylene group, a pyrenylene group, a chrysenylene group, a naphthacenylene group, a picenylene group, a perylenylene group, a pentaphenylene group, a hexacenylene group, a pentacenylene group, a rubicenylene group, a coronenylene group, an ovalenylene group, a pyrrolylene group, a thiophenylene group, a furanylene group, an imidazolylene group, a pyrazolylene group, a thiazolylene group, an isothiazolylene group, an oxazolylene group, an isoxazolylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, an isoindolylene group, an indolylene group, an indazolylene group, a purinylene group, a quinolinylene group, an isoquinolinylene group, a benzoquinolinylene group, a phthalazinylene group, a naphthyridinylene group, a quinoxalinylene group, a quinazolinylene group, a cinnolinylene group, a carbazolylene group, a phenanthridinylene group, an acridinylene group, a phenanthrolinylene group, a phenazinylene group, a benzoimidazolylene group, a benzofuranylene group, a benzothiophenylene group, an isobenzothiazolylene group, a benzoxazolylene group, an isobenzoxazolylene group, a triazolylene group, a tetrazolylene group, an oxadiazolylene group, a triazinylene group, a dibenzofuranylene group, a dibenzothiophenylene group, a benzocarbazolylene group, and a dibenzocarbazolylene group; and

(16) a phenylene group, a pentalenylene group, an indenylene group, a naphthylene group, an azulenylene group, a heptalenylene group, an indacenylene group, an acenaphthylene group, a fluorenylene group, a spiro-fluorenylene group, a benzofluorenylene group, a dibenzofluorenylene group, a phenalenylene group, a phenanthrenylene group, an anthracenylene group, a fluoranthenylene group, a triphenylenylene group, a pyrenylene group, a chrysenylene group, a naphthacenylene group, a picenylene group, a perylenylene group, a pentaphenylene group, a hexacenylene group, a pentacenylene group, a rubicenylene group, a coronenylene group, an ovalenylene group, a pyrrolylene group, a thiophenylene group, a furanylene group, an imidazolylene group, a pyrazolylene group, a thiazolylene group, an isothiazolylene group, an oxazolylene group, an isoxazolylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, an isoindolylene group, an indolylene group, an indazolylene group, a purinylene group, a quinolinylene group, an isoquinolinylene group, a benzoquinolinylene group, a phthalazinylene group, a naphthyridinylene group, a quinoxalinylene group, a quinazolinylene group, a cinnolinylene group, a carbazolylene group, a phenanthridinylene group, an acridinylene group, a phenanthrolinylene group, a phenazinylene group, a benzoimidazolylene group, a benzofuranylene group, a benzothiophenylene group, an isobenzothiazolylene group, a benzoxazolylene group, an isobenzoxazolylene group, a triazolylene group, a tetrazolylene group, an oxadiazolylene group, a triazinylene group, a dibenzofuranylene group, a dibenzothiophenylene group, a benzocarbazolylene group, and a dibenzocarbazolylene group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group, a cyclohexenyl group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, and an imidazopyridinyl group.

(17) In some embodiments, in the Formulae above, L.sub.1 to L.sub.12, L.sub.41 to L.sub.46, and L.sub.51 to L.sub.57 may be each independently selected from a phenylene group, a naphthylene group, a fluorenylene group, a spiro-fluorenylene group, a phenanthrenylene group, an anthracenylene group, a fluoranthenylene group, a triphenylenylene group, a pyrenylene group, and a chrysenylene group; and

(18) a phenylene group, a naphthylene group, a fluorenylene group, a spiro-fluorenylene group, a phenanthrenylene group, an anthracenylene group, a fluoranthenylene group, a triphenylenylene group, a pyrenylene group, and a chrysenylene group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a Spiro-fluorenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a biphenyl group, a terphenyl group, and Si(Q.sub.31)(Q.sub.32)(Q.sub.33);

(19) wherein Q.sub.31 to Q.sub.33 may be each independently selected from a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a biphenyl group, and a terphenyl group.

(20) In some embodiments, in the Formulae above, L.sub.1 to L.sub.12 may be each independently selected from groups represented by Formulae 3-1 to 3-41, and L.sub.41 to L.sub.46 and L.sub.51 to L.sub.57 may be each independently selected from groups represented by Formulae 3-1 to 3-9, 3-25, and 3-33 to 3-41 (provided that Y.sub.1?C(Z.sub.3)(Z.sub.4) in Formulae 3-3 and 3-4):

(21) ##STR00005## ##STR00006## ##STR00007## ##STR00008## ##STR00009## ##STR00010##
wherein, in Formulae 3-1 to 3-41,

(22) Y.sub.1 may be O, S, C(Z.sub.3)(Z.sub.4), N(Z.sub.5), or Si(Z.sub.6)(Z.sub.7);

(23) Z.sub.1 to Z.sub.7 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, and a C.sub.1-C.sub.20 alkoxy group;

(24) a C.sub.1-C.sub.20 alkyl group and a C.sub.1-C.sub.20 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, and a phosphoric acid group or a salt thereof;

(25) a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a carbazolyl group, a benzocarbazolyl group, and a dibenzocarbazolyl group;

(26) a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a carbazolyl group, a benzocarbazolyl group, and a dibenzocarbazolyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, and a naphthyl group; and

(27) Si(Q.sub.31)(Q.sub.32)(Q.sub.33);

(28) wherein Q.sub.1 to Q.sub.3 and Q.sub.31 to Q.sub.33 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a Spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, and a carbazolyl group;

(29) d2 may be an integer selected from 1 and 2;

(30) d3 may be an integer selected from 1 to 3;

(31) d4 may be an integer selected from 1 to 4;

(32) d5 may be an integer selected from 1 to 5;

(33) d6 may be an integer selected from 1 to 6;

(34) d8 may be an integer selected from 1 to 8; and

(35) * and * each indicate a binding site to an adjacent atom.

(36) In some embodiments, in the Formulae above, L.sub.1 to L.sub.12 may be each independently selected from groups represented by Formulae 4-1 to 4-36, and L.sub.41 to L.sub.46 and L.sub.51 to L.sub.57 may be each independently selected from groups represented by Formulae 4-1, 4-3, 4-5, 4-7 to 4-13, 4-17, and 4-24 to 4-36:

(37) ##STR00011## ##STR00012## ##STR00013## ##STR00014## ##STR00015##
wherein, in Formulae 4-1 to 4-36, * and * each indicate a binding site to an adjacent atom.

(38) In the Formulae above, a1 to a12, a41 to a46, and a51 to a57 may each independently be an integer selected from 0 to 3. a1 indicates the number of L.sub.1. When a1 is 0, -(L.sub.1).sub.a1- may be a single bond. When a1 is two or more, a plurality of a1 L.sub.1 may be identical to or different from each other. a2 to a12, a41 to a46, and a51 to a57 may be understood by referring to the descriptions of a1 and the structures of Formulae 1A to 1C and Formulae 40A and 40B.

(39) In some embodiments, a1 to a12, a41 to a46, and a51 to a57 may each independently be 0, 1, or 2, or, for example, 0 or 1.

(40) In the Formulae above, Ar.sub.1 to Ar.sub.8, R.sub.41 to R.sub.46, and R.sub.51 to R.sub.57 may be each independently selected from a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryl group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group; and

(41) Ar.sub.1 and Ar.sub.2 may be optionally linked to each other to form a C.sub.5 to C.sub.20 saturated or unsaturated ring, Ar.sub.3 and Ar.sub.4 may be optionally linked to each other to form a C.sub.5 to C.sub.20 saturated or unsaturated ring, Ar.sub.5 and Ar.sub.6 may be optionally linked to each other to form a C.sub.5 to C.sub.20 saturated or unsaturated ring, and Ar.sub.7 and Ar.sub.8 may be optionally linked to each other to form a C.sub.5 to C.sub.20 saturated or unsaturated ring.

(42) In some embodiments, in the Formulae above, Ar.sub.1 to Ar.sub.8, R.sub.41 to R.sub.46, and R.sub.51 to R.sub.57 may be each independently selected from a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a Spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group; and

(43) a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group, a cyclohexenyl group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, an imidazopyrimidinyl group, and Si(Q.sub.33)(Q.sub.34)(Q.sub.35);

(44) wherein Q.sub.33 to Q.sub.35 may be each independently selected from a hydrogen, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a pyridinyl group, a pyrimidinyl group, a triazinyl group, a quinolinyl group, and an isoquinolinyl group.

(45) In some embodiments, in Formulae 1A to 1C, Ar.sub.1 to Ar.sub.8, R.sub.41 to R.sub.46, and R.sub.51 to R.sub.57 may be each independently selected from:

(46) a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a phenanthrolinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group; and

(47) a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a phenanthrolinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a phenanthrolinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, an imidazopyrimidinyl group, and Si(Q.sub.31)(Q.sub.32)(Q.sub.33);

(48) wherein Q.sub.31 to Q.sub.33 may be each independently selected from a hydrogen, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a pyridinyl group, a pyrimidinyl group, a triazinyl group, a quinolinyl group, and an isoquinolinyl group, as examples.

(49) In some embodiments, Ar.sub.1 to Ar.sub.8 in Formulae 1A to 1C may be each independently selected from groups represented by Formulae 5-1 to 5-87:

(50) ##STR00016## ##STR00017## ##STR00018## ##STR00019## ##STR00020## ##STR00021## ##STR00022## ##STR00023## ##STR00024## ##STR00025##

(51) In Formulae 5-1 to 5-87,

(52) Y.sub.11 may be O, S, C(Z.sub.13)(Z.sub.14), N(Z.sub.15), or Si(Z.sub.16)(Z.sub.17);

(53) Z.sub.11 to Z.sub.17 may be each independently selected from a hydrogen, a deuterium, F, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, and a C.sub.1-C.sub.20 alkoxy group;

(54) a C.sub.1-C.sub.20 alkyl group and a C.sub.1-C.sub.20 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, and a phosphoric acid group or a salt thereof;

(55) a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a carbazolyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, and a dibenzofuranyl group;

(56) a phenyl group, a naphthyl group, a pyridinyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a carbazolyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, and a dibenzofuranyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, and a pyridinyl group;

(57) and Si(Q.sub.31)(Q.sub.32)(Q.sub.33); and

(58) Z.sub.11 and Z.sub.12 may be optionally linked to each other to form a saturated or unsaturated ring, and Z.sub.13 and Z.sub.14 may be optionally linked to each other to form a saturated or unsaturated ring;

(59) wherein Q.sub.31 to Q.sub.33 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, and a carbazolyl group;

(60) e2 may be an integer selected from 1 and 2;

(61) e3 may be an integer selected from 1 to 3;

(62) e4 may be an integer selected from 1 to 4;

(63) e5 may be an integer selected from 1 to 5;

(64) e6 may be an integer selected from 1 to 6;

(65) e7 may be an integer selected from 1 to 7;

(66) e8 may be an integer selected from 1 to 8;

(67) e9 may be an integer selected from 1 to 9; and

(68) * indicates a binding site to an adjacent atom.

(69) In some embodiments, Ar.sub.1 to Ar.sub.8, R.sub.41 to R.sub.46, and R.sub.51 to R.sub.57 in Formulae 1A to 1C may be each independently selected from groups represented by Formulae 6-1 to 6-170:

(70) ##STR00026## ##STR00027## ##STR00028## ##STR00029## ##STR00030## ##STR00031## ##STR00032## ##STR00033## ##STR00034## ##STR00035## ##STR00036## ##STR00037## ##STR00038## ##STR00039## ##STR00040## ##STR00041## ##STR00042## ##STR00043## ##STR00044## ##STR00045## ##STR00046## ##STR00047## ##STR00048## ##STR00049## ##STR00050##
wherein, in Formulae 6-1 to 6-170, * indicates a binding site to an adjacent atom.

(71) In some embodiments, in Formulae 1A to 1C, at least one of

(72) ##STR00051##
may be selected from groups represented by Formulae 7-1 and 7-2:

(73) ##STR00052##

(74) In Formulae 7-1 and 7-2,

(75) Y.sub.21 may be selected from O, S, C(Z.sub.23)(Z.sub.24). N(Z.sub.25), and Si(Z.sub.26)(Z.sub.27); and

(76) Z.sub.21 to Z.sub.27 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a triazinyl group, and Si(Q.sub.31)(Q.sub.32)(Q.sub.33);

(77) wherein Q.sub.31 to Q.sub.33 may be each independently selected from a C.sub.1-C.sub.10 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, and a naphthyl group;

(78) f4 may be an integer selected from 1 to 4, and * indicates a binding site to an adjacent atom.

(79) In the Formulae above, b1 to b8, b41 to b46, and b51 to b57 may each independently be an integer selected from 1 to 4. b1 indicate the number of Ar.sub.1, and when b1 is two or more, a plurality of Ar.sub.1 may be identical to or different from each other. b2 to b8, b41 to b46, and b51 to b57 may be understood by referring to the descriptions of b1 and the structures of Formulae 1A to 1C and Formulae 40A and 40B.

(80) In some embodiments, b1 to b8, b41 to b46, and b51 to b57 may each independently be 1 or 2, or, for example, may each be 1.

(81) In Formulae 40A and 40B, X.sub.41 may be N or C-(L.sub.41).sub.a41-(R.sub.41).sub.b41, X.sub.42 may be N or C-(L.sub.42).sub.a42-(R.sub.42).sub.b42, X.sub.43 may be N or C-(L.sub.43).sub.a43-(R.sub.43).sub.b43, X.sub.44 may be N or C-(L.sub.44).sub.a44-(R.sub.44).sub.b44, and at least one of X.sub.41 to X.sub.44 may be N; and X.sub.51 may be N or C-(L.sub.51).sub.a51-(R.sub.51).sub.b51, X.sub.52 may be N or C-(L.sub.52).sub.a52-(R.sub.52).sub.b52, X.sub.53 may be N or C-(L.sub.53).sub.a53-(R.sub.53).sub.b53, and at least one of X.sub.51 to X.sub.53 may be N. In some embodiments, in Formula 40A, X.sub.41, X.sub.42, and X.sub.44 may be N, and X.sub.43 may be C(R.sub.43); X.sub.41 and X.sub.44 may be N, X.sub.42 may be C(R.sub.42), and X.sub.43 may be C(R.sub.43); or X.sub.41 and X.sub.43 may be N, X.sub.42 may be C(R.sub.42), and X.sub.44 may be C(R.sub.44). In Formula 40B, X.sub.51, X.sub.52, and X.sub.53 may be N; or X.sub.52 and X.sub.53 may be N, and X.sub.51 may be C(R.sub.51).

(82) In Formulae 40A and 40B, at least one selected from R.sub.41 to R.sub.46 or at least one selected from R.sub.51 to R.sub.57 may be selected from a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, and a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group.

(83) In some embodiments, in Formula 40A, at least one selected from R.sub.41 to R.sub.46 may be an electron transporting group including at least one N as a ring-forming atom, and at least one carbon of at least one selected from R.sub.41 to R.sub.46 may be bound to a carbon in the core in Formula 40A or each be bound to at least one selected from L.sub.41 to L.sub.46; and in Formula 40B, at least one selected from R.sub.51 to R.sub.57 may be an electron transporting group including at least one N as a ring-forming atom, and at least one carbon of at least one selected from R.sub.51 to R.sub.57 may be bound to a carbon in the core in Formula 40B or each be bound to at least one selected from L.sub.51 to L.sub.57.

(84) In some embodiments, at least one selected from R.sub.41 to R.sub.46 in Formula 40A or at least one selected from R.sub.51 to R.sub.57 in Formula 40B may be selected from:

(85) a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group; and

(86) a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group, a cyclohexenyl group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, an imidazopyrimidinyl group, and Si(Q.sub.31)(Q.sub.32)(Q.sub.33);

(87) wherein Q.sub.31 to Q.sub.33 may be each independently selected from a C.sub.1-C.sub.10 alkyl group, a C.sub.1-C.sub.10 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a phenanthrolinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a dibenzosilolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group.

(88) In some embodiments, at least one selected from R.sub.41 to R.sub.46 in Formula 40A or at least one selected from R.sub.51 to R.sub.57 in Formula 40B may be selected from a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group; and

(89) a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group, a cyclohexenyl group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a thiadiazolyl group, an imidazopyridinyl group, an imidazopyrimidinyl group, a biphenyl group, a terphenyl group, and Si(Q.sub.31)(Q.sub.32)(Q.sub.33);

(90) wherein Q.sub.31 to Q.sub.33 may be each independently selected from a C.sub.1-C.sub.10 alkyl group, a C.sub.1-C.sub.10 alkoxy group, a phenyl group, a naphthyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a triazinyl group, a biphenyl group, and a terphenyl group.

(91) In some embodiments, at least one selected from R.sub.41 to R.sub.46 in Formula 40A or at least one selected from R.sub.51 to R.sub.57 in Formula 40B may be selected from groups represented by Formulae 5-1 to 5-67:

(92) ##STR00053## ##STR00054## ##STR00055## ##STR00056## ##STR00057## ##STR00058## ##STR00059## ##STR00060## ##STR00061##

(93) In Formulae 5-1 to 5-67,

(94) Z.sub.11 and Z.sub.12 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, and a C.sub.1-C.sub.20 alkoxy group;

(95) a C.sub.1-C.sub.20 alkyl group and a C.sub.1-C.sub.20 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, and a phosphoric acid group or a salt thereof;

(96) a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a carbazolyl group, a benzocarbazolyl group, and a dibenzocarbazolyl group;

(97) a phenyl group, a naphthyl group, a pyridinyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a carbazolyl group, a benzocarbazolyl group, and a dibenzocarbazolyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, and a pyridinyl group; and

(98) Si(Q.sub.31)(Q.sub.32)(Q.sub.33);

(99) Z.sub.11 and Z.sub.12 may be optionally linked to each other to form a C.sub.5 to C.sub.20 saturated or unsaturated ring;

(100) wherein Q.sub.31 to Q.sub.33 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, and a carbazolyl group;

(101) e2 may be an integer selected from 1 and 2;

(102) e3 may be an integer selected from 1 to 3;

(103) e4 may be an integer selected from 1 to 4;

(104) e5 may be an integer selected from 1 to 5;

(105) e6 may be an integer selected from 1 to 6;

(106) e7 may be an integer selected from 1 to 7;

(107) e8 may be an integer selected from 1 to 8;

(108) e9 may be an integer selected from 1 to 9; and

(109) * indicates a binding site to an adjacent atom.

(110) In some embodiments, at least one selected from R.sub.41 to R.sub.46 in Formula 40A or at least one selected from R.sub.51 to R.sub.57 in Formula 40B may be selected from groups represented by Formulae 10-1 to 10-122:

(111) ##STR00062## ##STR00063## ##STR00064## ##STR00065## ##STR00066## ##STR00067## ##STR00068## ##STR00069## ##STR00070## ##STR00071## ##STR00072## ##STR00073## ##STR00074## ##STR00075## ##STR00076## ##STR00077## ##STR00078## ##STR00079## ##STR00080##

(112) In Formulae 10-1 to 10-123, * indicates a binding site to an adjacent atom.

(113) In some embodiments, R.sub.4 in Formula 40A or at least one selected from R.sub.56 and R.sub.57 in Formula 40B may be selected from groups represented by Formulae 10-1 to 10-123.

(114) in the Formulae above, R.sub.1 to R.sub.12 and R.sub.58 to R.sub.60 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a substituted or unsubstituted C.sub.1-C.sub.60 alkyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkenyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkynyl group, a substituted or unsubstituted C.sub.1-C.sub.60 alkoxy group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryloxy group, a substituted or unsubstituted C.sub.6-C.sub.60 arylthio group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group, and Si(Q.sub.1)(Q.sub.2)(Q.sub.3); and R.sub.11 and R.sub.12 may be optionally linked to each other to form a C.sub.5 to C.sub.20 saturated or unsaturated ring. Here, descriptions of Q.sub.1 to Q.sub.5 may be referred to the descriptions below.

(115) In some embodiments, in the Formulae above, R.sub.1 to R.sub.12 and R.sub.58 to R.sub.60 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, and a C.sub.1-C.sub.20 alkoxy group;

(116) a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group;

(117) a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.10 alkyl group, a C.sub.1-C.sub.10 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a Spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, an imidazopyridinyl group, an imidazopyrimidinyl group, a biphenyl group, a terphenyl group, and Si(Q.sub.31)(Q.sub.32)(Q.sub.33); and

(118) Si(Q.sub.1)(Q.sub.2)(Q.sub.3).

(119) wherein Q.sub.1 to Q.sub.3 and Q.sub.31 to Q.sub.33 may be each independently selected from a C.sub.1-C.sub.10 alkyl group, a C.sub.1-C.sub.10 alkoxy group, a phenyl group, and a naphthyl group.

(120) In some embodiments, in the Formulae above, R.sub.1 to R.sub.12 and R.sub.58 to R.sub.60 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.10 alkyl group, and a C.sub.1-C.sub.10 alkoxy group;

(121) a phenyl group, a naphthyl group, a pyridinyl group, a pyrimidinyl group, and a triazinyl group;

(122) a phenyl group, a naphthyl group, a pyridinyl group, a pyrimidinyl group, and a triazinyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.10 alkyl group, a C.sub.1-C.sub.10 alkoxy group, a phenyl group, a naphthyl group, a pyridinyl group, a pyrimidinyl group, a triazinyl group, a biphenyl group, a terphenyl group, and Si(Q.sub.31)(Q.sub.32)(Q.sub.33); and

(123) Si(Q.sub.1)(Q.sub.2)(Q.sub.3),

(124) wherein Q.sub.1 to Q.sub.3 and Q.sub.31 to Q.sub.33 may be each independently selected from a C.sub.1-C.sub.10 alkyl group, a C.sub.1-C.sub.10 alkoxy group, a phenyl group, and a naphthyl group.

(125) In some embodiments, in the Formulae above, R.sub.1 to R.sub.12 and R.sub.58 to R.sub.60 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.10 alkyl group, a C.sub.1-C.sub.10 alkoxy group, a phenyl group, and a naphthyl group, as examples.

(126) In the Formulae above, c1 to c10 may each independently be an integer selected from 0 to 4. c1 indicates the number of R.sub.1, and when c1 is two or more, a plurality of R.sub.1 may be identical to or different from each other. c2 to c10 may be understood by referring to the descriptions of c1 and structures of Formulae 1A to 1C and Formulae 40A and 40B.

(127) In some embodiments, c1 to c10 may each independently be 0, 1, or 2; or, for example, may each independently be 0 or 1.

(128) In Formulae 1A to 1C, n1 to n4 and n7 to n10 may each independently be an integer selected from 0 to 4, and n5 and n6 may each independently be an integer selected from 0 to 5, provided that n1+n2+n3+n4 may be 1 or more, n5+n6+n7+n8 may be 1 or more, and n9+n10 may be 1 or more.

(129) In some embodiments, the first compound may be represented by one of Formulae 1A-1 to 1A-10, 1B-1 to 1B-4, 1C-1, and 1C-2, and the second compound may be represented by one of Formulae 40A-1 to 40A-3, 40B-1, and 40B-2:

(130) ##STR00081## ##STR00082## ##STR00083## ##STR00084## ##STR00085## ##STR00086##

(131) In the Formulae above, descriptions of L.sub.1 to L.sub.12, L.sub.41 to L.sub.46, L.sub.51 to L.sub.57, a1 to a12, a41 to a46, a51 to a57, Ar.sub.1 to Ar.sub.8, R.sub.1 to R.sub.12, R.sub.42 to R.sub.46, R.sub.51, R.sub.54 to R.sub.60, b1 to b20, b42 to b46, b51 to b57, and c1 to c10 may be understood by referring to the descriptions provided herein.

(132) In some embodiments, the first compound may be represented by one of Formulae 1A-1(1), 1A-2(1), 1A-2(2), 1A-3(1), 1A-4(1), 1A-4(2), 1A-5(1), 1A-6(1), 1A-7(1), 1A-8(1), 1A-8(2), 1A-9(1), 1A-9(2), 1A-9(3), 1A-10(1), 1A-10(2), 1B-(1), 1B-2(1), 1B-3(1), 1B-4(1), 1C-1(1), and 1C-1(2), and the second compound may be represented by one of Formulae 40A-1(1), 40A-1(2), 40A-1(3), 40A-2(1), 40A-3(1), 40B-1(1), 40B-1(2), 40B-2(1), and 40B-2(1) to 40B-2(5):

(133) ##STR00087## ##STR00088## ##STR00089## ##STR00090## ##STR00091## ##STR00092## ##STR00093## ##STR00094## ##STR00095##

(134) In the Formulae above, descriptions of L.sub.1 to L.sub.3, L.sub.7, L.sub.10, L.sub.12, L.sub.43, L.sub.45, L.sub.46, L.sub.56, L.sub.57, Ar.sub.1 to Ar.sub.8, R.sub.2, R.sub.3, R.sub.7, R.sub.42 to R.sub.46, and R.sub.54 to R.sub.57 may be understood by referring to the descriptions provided herein.

(135) In some embodiments, L.sub.1 to L.sub.3, L.sub.7, L.sub.10, and L.sub.12 may be each independently selected from groups represented by Formulae 3-1 to 3-41, L.sub.43, L.sub.45, L.sub.46, L.sub.56, and L.sub.57 may be each independently selected from groups represented by Formulae 3-1 to 3-9, 3-25, and 3-33 to 3-41 (provided that Y.sub.1?C(Z.sub.3)(Z.sub.4) in Formulae 3-3 and 3-4),

(136) Ar.sub.1 to Ar.sub.8, R.sub.42 to R.sub.44, R.sub.46, R.sub.54, and R.sub.55 may be each independently selected from groups represented by Formulae 5-1 to 5-87,

(137) R.sub.45 may be selected from groups represented by Formulae 5-1 to 5-67,

(138) at least one of R.sub.56 and R.sub.57 may be selected from groups represented by Formulae 5-1 to 5-67, and

(139) R.sub.2, R.sub.3, and R.sub.7 may be each independently selected from a hydrogen, a phenyl group, a phenalenyl group, a pyrenyl group, and a dibenzothiophenyl group.

(140) In some embodiments, L.sub.1 to L.sub.3, L.sub.7, L.sub.10, and L.sub.12 may be each independently selected from groups represented by Formulae 4-1 to 4-36, and L.sub.43, L.sub.45, L.sub.46, L.sub.56, and L.sub.57 may be each independently selected from groups represented by Formulae 4-1, 4-3, 4-5, 4-7 to 4-13, 4-17, and 4-24 to 4-36,

(141) Ar.sub.1 to Ar.sub.8, R.sub.42 to R.sub.44, R.sub.46, R.sub.54, and R.sub.55 may be each independently selected from groups represented by Formulae 6-1 to 6-170,

(142) R.sub.45 may be selected from groups represented by Formulae 10-1 to 10-123, and

(143) at least one of R.sub.56 and R.sub.57 may be selected from groups represented by Formulae 10-1 to 10-123.

(144) The first compound may be a compound represented by one of Compounds 1 to 53, and the second compound may be a compound represented by one of Compounds A1 to A32:

(145) ##STR00096## ##STR00097## ##STR00098## ##STR00099## ##STR00100## ##STR00101## ##STR00102## ##STR00103## ##STR00104## ##STR00105## ##STR00106## ##STR00107## ##STR00108## ##STR00109## ##STR00110##

(146) The first compound represented by one of Formulae 1A to 1C may have an excellent hole transporting ability. Thus, controlling the charge balance may be facilitated, and electrical stability may be excellent, improving lifespan characteristics. The second compound represented by one of Formulae 40A and 40B essentially has at least one electron transporting moiety other than a core. The second compound may have an excellent electron transporting ability. The second compound may easily transport electrons, increasing the exciton forming rate and having a relatively high resistance to charges. Accordingly, when an organic light-emitting device includes the first compound represented by one of Formulae 1A to 1C in a hole transport region and a second compound represented by one of Formulae 40A and 40B in a electron transport region, the balance of charges may be maintained, the hole transporting ability and electron transporting ability may be excellent, emission efficiency may be improved, and the electrical stability may be excellent, such that the organic light-emitting device may have long lifespan characteristics. Thus, the organic light-emitting device has a high emission efficiency and long lifespan characteristics even in a low voltage region.

(147) In some embodiments, the hole transport region 130 may include at least one selected from a hole injection layer (HIL), a hole transport layer (HTL), a buffer layer, and an auxiliary emission layer, and the electron transport region 170 may include at least one selected from a hole blocking layer (HBL), an electron transport layer (ETL), and an electron injection layer (EIL).

(148) In some embodiments, the hole transport region 130 may include the hole transport layer and the hole injection layer, and the hole injection layer may be between the first electrode and the hole transport layer. The first compound may be included in the hole injection layer and the hole transport layer. The first compound included in the hole injection layer and the first compound included in the hole transport layer may be identical to or different from each other. The electron transport region 170 may include the electron transport layer and the electron injection layer. The electron injection layer may be between the second electrode and the electron transport layer, and the second compound may be included in the electron transport layer.

(149) The hole transport region may have a single-layered structure formed of a single material, a single-layered structure formed of a plurality of different materials, or a multi-layered structure having a plurality of layers formed of a plurality of different materials.

(150) In some embodiments, the hole transport region 130 may have a structure of hole injection layer/hole transport layer/auxiliary emission layer, a structure of hole injection layer/hole transport layer/buffer layer/auxiliary emission layer, a structure of hole injection layer/auxiliary emission layer, a structure of hole injection layer/buffer layer/auxiliary emission layer, a structure of hole transport layer/hole auxiliary layer, and a structure of hole transport layer/buffer layer/auxiliary emission layer, wherein layers of each structure are sequentially stacked from the first electrode 110 in this stated order.

(151) In some embodiments, the hole transport region 130 may further include an auxiliary emission layer. The auxiliary emission layer may be between the hole transport layer and the emission layer. The auxiliary emission layer may include the first compound, the electron transport region 170 may include the electron transport layer, and the electron transport layer may include the second compound.

(152) When the hole transport region includes a hole injection layer, the hole injection layer may be formed on the first electrode 110 by using a suitable method, such as vacuum-deposition, spin coating, casting, Langmuir-Blodgett (LB) method, ink-jet printing, laser-printing, or laser-induced thermal imaging (LITI).

(153) When the hole injection layer is formed by vacuum-deposition, for example, the vacuum-deposition may be performed at a temperature of a deposition temperature of about 100? C. to about 500? C., at a vacuum degree of about 10.sup.?8 Torr to about 10.sup.?3 Torr, and at a vacuum-deposition rate in a range of about 0.01 ?/sec to about 100 ?/sec in consideration of a compound for the hole injection layer to be deposited, and the structure of the hole injection layer to be formed.

(154) When a hole injection layer is formed by spin coating, the spin coating may be performed at a coating rate of about 2,000 rpm to about 5,000 rpm, and at a temperature of about 80? C. to 200? C. in consideration of a compound for a hole injection layer to be deposited, and the structure of a hole injection layer to be formed.

(155) Methods of forming the hole transport layer, hole auxiliary layer, and buffer layer may be understood by referring to that of the hole injection layer.

(156) The thickness of the hole transport region may be in a range of about 100 ? to about 10,000 ?, or, for example, about 100 ? to about 1,000 ?. When the hole transport region includes a hole injection layer and a hole transport layer, the thickness of the hole injection layer may be in a range of about 100 ? to about 10,000 ?, or, for example, about 100 ? to about 1,000 ?, and the thickness of the hole transport layer may be in a range of about 50 ? to about 2,000 ?, or, for example, about 100 ? to about 1,500 ?. When the thicknesses of the hole transport region, the hole injection layer, and the hole transport layer are within these ranges, excellent hole transport characteristics may be obtained without a substantial increase in driving voltage.

(157) The hole transport region may further include, in addition to the first compound, a charge-generating material to improve conductive properties. The charge-generating material may be homogeneously or non-homogeneously dispersed throughout the hole transport region.

(158) The charge-generating material may be, for example, a p-dopant. The p-dopant may be one selected from a quinone derivative, a metal oxide, and a cyano group-containing compound. Examples of the p-dopant may include a quinone derivative, such as tetracyanoquinonedimethane (TCNQ) or 2,3,5,6-tetrafluoro-tetracyano-1,4-benzoquinonedimethane (F4-TCNQ); a metal oxide, such as a tungsten oxide or a molybdenum oxide, and Compound HT-D1 illustrated below.

(159) ##STR00111##

(160) The hole transport region may further include, in addition to the hole injection layer and the hole transport layer, at least one selected from a buffer layer and an electron blocking layer. The buffer layer may compensate for an optical resonance distance according to a wavelength of light emitted from the emission layer. Accordingly, the light-emission efficiency of a formed organic light-emitting device may be improved. As a material included in the buffer layer, materials that are included in the hole transport region may be used. The electron blocking layer may prevent injection of electrons from the electron transport region.

(161) An emission layer may be formed on the first electrode 110 or the hole transport region by using a suitable method, such as vacuum-deposition, spin coating, casting, LB method, ink-jet printing, laser-printing, or LITI. When the emission layer is formed by vacuum-deposition or spin coating, deposition and coating conditions for the emission layer may be determined by referring to the deposition and coating conditions for the hole injection layer.

(162) When the organic light-emitting device 10 is a full color organic light-emitting device, the emission layer may be patterned into a red emission layer, a green emission layer, or a blue emission layer, according to a sub pixel. In some implementations, the emission layer may have a stacked structure of a red emission layer, a green emission layer, and a blue emission layer, or may include a red-light emission material, a green-light emission material, and a blue-light emission material, which are mixed with each other in a single layer, to emit white light.

(163) The emission layer may include a host and a dopant.

(164) The host may include at least one selected from TPBi, TBADN, ADN (also known as DNA), CBP, CDBP, and TCP:

(165) ##STR00112## ##STR00113##

(166) In some embodiments, the host may include at least one selected from a first host represented by Formula 101, a second host represented by Formula 201, a third host represented by Formula 202, a fourth host represented by Formula 301, and a fifth host represented by Formula 302:

(167) ##STR00114##

(168) In the Formulae above,

(169) Ar.sub.101, A.sub.201 to A.sub.204, A.sub.211 to A.sub.214, A.sub.301 to A.sub.303, A.sub.311, and A.sub.312 may be each independently a substituted or unsubstituted C.sub.6-C.sub.20 aromatic ring;

(170) A.sub.304 and A.sub.314 may each independently be a group represented by Formula 303;

(171) X.sub.301 may be selected from N-(L.sub.302).sub.a302-Ar.sub.302, O, S, C(R.sub.303)(R.sub.304), Si(R.sub.303)(R.sub.304), P(R.sub.303), B(R.sub.303), and P(?O)(R.sub.303);

(172) L.sub.101, L.sub.201 to L.sub.203, L.sub.211, L.sub.301, L.sub.302, and L.sub.311 may be each independently selected from a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkylene group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkylene group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenylene group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenylene group, a substituted or unsubstituted C.sub.6-C.sub.60 arylene group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroarylene group, a substituted or unsubstituted divalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted divalent non-aromatic condensed heteropolycyclic group;

(173) a101, a201 to a203, a211, a301, a302, and a311 may each independently be an integer selected from 0 to 3;

(174) R.sub.101, Ar.sub.201, Ar.sub.202, Ar.sub.301, Ar.sub.302, and Ar.sub.311 may be each independently selected from a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryl group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group;

(175) R.sub.201 to R.sub.204, R.sub.211 to R.sub.214, R.sub.301 to R.sub.304, R.sub.311, and R.sub.312 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a substituted or unsubstituted C.sub.1-C.sub.60 alkyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkenyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkynyl group, a substituted or unsubstituted C.sub.1-C.sub.60 alkoxy group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkyl group, a substituted or unsubstituted heterocycloalkyl group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryloxy group, a substituted or unsubstituted C.sub.6-C.sub.60 arylthio group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group, N(Q.sub.101)(Q.sub.102), Si(Q.sub.103)(Q.sub.104)(Q.sub.105), and B(Q.sub.106)(Q.sub.107);

(176) b201 and b203 may each independently be an integer selected from 0 to 3, b202, b204, b211 to b214, b301, b302, b311, and b312 may each independently be an integer selected from 0 to 4;

(177) n101 may be an integer selected from 0 to 3, n201 and n202 may each independently be an integer selected from 0 to 4, n211 may be an integer selected from 1 and 2;

(178) at least one of substituents of the substituted C.sub.6-C.sub.20 aromatic ring, substituted C.sub.3-C.sub.10 cycloalkylene group, substituted C.sub.1-C.sub.10 heterocycloalkylene group, substituted C.sub.3-C.sub.10 cycloalkenylene group, substituted C.sub.1-C.sub.10 heterocycloalkenylene group, substituted C.sub.6-C.sub.60 arylene group, substituted C.sub.1-C.sub.60 heteroarylene group, substituted divalent non-aromatic condensed polycyclic group, substituted divalent non-aromatic condensed heteropolycyclic group, substituted C.sub.1-C.sub.60 alkyl group, substituted C.sub.2-C.sub.60 alkenyl group, substituted C.sub.2-C.sub.60 alkynyl group, substituted C.sub.1-C.sub.60 alkoxy group, substituted C.sub.3-C.sub.10 cycloalkyl group, substituted C.sub.1-C.sub.10 heterocycloalkyl group, substituted C.sub.3-C.sub.10 cycloalkenyl group, substituted C.sub.1-C.sub.10 heterocycloalkenyl group, substituted C.sub.6-C.sub.60 aryl group, substituted C.sub.6-C.sub.60 aryloxy group, substituted C.sub.6-C.sub.60 arylthio group, substituted C.sub.1-C.sub.60 heteroaryl group, substituted monovalent non-aromatic condensed polycyclic group, and substituted monovalent non-aromatic condensed heteropolycyclic group may be selected from:

(179) a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group;

(180) a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, N(Q.sub.101)(Q.sub.102), Si(Q.sub.103)(Q.sub.104)(Q.sub.105), and B(Q.sub.106)(Q.sub.107);

(181) a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group;

(182) a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, N(Q.sub.111)(Q.sub.112), Si(Q.sub.113)(Q.sub.114)(Q.sub.115), and B(Q.sub.116)(Q.sub.117); and

(183) N(Q.sub.121)(Q.sub.122), Si(Q.sub.123)(Q.sub.124)(Q.sub.125), and B(Q.sub.126)(Q.sub.127);

(184) wherein Q.sub.101 to Q.sub.107, Q.sub.111 to Q.sub.117, and Q.sub.121 to Q.sub.127 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group.

(185) In some embodiments, Ar.sub.101, A.sub.201 to A.sub.204, A.sub.211 to A.sub.214, A.sub.301 to A.sub.303, A.sub.311, and A.sub.312 may be each independently selected from a benzene, a naphthalene, a pyridine, a pyrimidine, a pyrazine, a quinoline, an isoquinoline, a 2,6-naphthyridine, a 1,8-naphthyridine, a 1,5-naphthyridine, a 1,6-naphthyridine, a 1,7-naphthyridine, a 2,7-naphthyridine, a quinoxaline, a phthalazine, and a quinazoline. In some embodiments, Ar.sub.101, A.sub.201 to A.sub.204, A.sub.211 to A.sub.214, A.sub.301 to A.sub.303, A.sub.311, and A.sub.312 may be each independently selected from a benzene and a naphthalene.

(186) L.sub.101, L.sub.201 to L.sub.203, L.sub.211, L.sub.301, L.sub.302, and L.sub.311 may be each independently selected from a phenylene group, a pentalenylene group, an indenylene group, a naphthylene group, an azulenylene group, a heptalenylene group, an indacenylene group, an acenaphthylene group, a fluorenylene group, a spiro-fluorenylene group, a benzofluorenylene group, a dibenzofluorenylene group, a phenalenylene group, a phenanthrenylene group, an anthracenylene group, a fluoranthenylene group, a triphenylenylene group, a pyrenylene group, a chrysenylene group, a naphthacenylene group, a picenylene group, a perylenylene group, a pentaphenylene group, a hexacenylene group, a pentacenylene group, a rubicenylene group, a coronenylene group, an ovalenylene group, a pyrrolylene group, a thiophenylene group, a furanylene group, an imidazolylene group, a pyrazolylene group, a thiazolylene group, an isothiazolylene group, an oxazolylene group, an isoxazolylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, an isoindolylene group, an indolylene group, an indazolylene group, a purinylene group, a quinolinylene group, an isoquinolinylene group, a benzoquinolinylene group, a phthalazinylene group, a naphthyridinylene group, a quinoxalinylene group, a quinazolinylene group, a cinnolinylene group, a carbazolylene group, a phenanthridinylene group, an acridinylene group, a phenanthrolinylene group, a phenazinylene group, a benzoimidazolylene group, a benzofuranylene group, a benzothiophenylene group, an isobenzothiazolylene group, a benzoxazolylene group, an isobenzoxazolylene group, a triazolylene group, a tetrazolylene group, an oxadiazolylene group, a triazinylene group, a dibenzofuranylene group, a dibenzothiophenylene group, a benzocarbazolylene group, a dibenzocarbazolylene group, a thiadiazolylene group, an imidazopyridinylene group, and an imidazopyrimidinylene group; and

(187) a phenylene group, a pentalenylene group, an indenylene group, a naphthylene group, an azulenylene group, a heptalenylene group, an indacenylene group, an acenaphthylene group, a fluorenylene group, a spiro-fluorenylene group, a benzofluorenylene group, a dibenzofluorenylene group, a phenalenylene group, a phenanthrenylene group, an anthracenylene group, a fluoranthenylene group, a triphenylenylene group, a pyrenylene group, a chrysenylene group, a naphthacenylene group, a picenylene group, a perylenylene group, a pentaphenylene group, a hexacenylene group, a pentacenylene group, a rubicenylene group, a coronenylene group, an ovalenylene group, a pyrrolylene group, a thiophenylene group, a furanylene group, an imidazolylene group, a pyrazolylene group, a triazolylene group, an isothiazolylene group, an oxazolylene group, an isoxazolylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, an isoindolylene group, an indolylene group, an indazolylene group, a purinylene group, a quinolinylene group, an isoquinolinylene group, a benzoquinolinylene group, a phthalazinylene group, a naphthyridinylene group, a quinoxalinylene group, a quinazolinylene group, a cinnolinylene group, a carbazolylene group, a phenanthridinylene group, an acridinylene group, a phenanthrolinylene group, a phenazinylene group, a benzoimidazolylene group, a benzofuranylene group, a benzothiophenylene group, an isobenzothiazolylene group, a benzoxazolylene group, an isobenzoxazolylene group, a triazolylene group, a tetrazolylene group, an oxadiazolylene group, a triazinylene group, a dibenzofuranylene group, a dibenzothiophenylene group, a benzocarbazolylene group, a dibenzocarbazolylene group, a thiadiazolylene group, an imidazopyridinylene group, and an imidazopyrimidinylene group, each substituted with at least one selected from a deuterium, F, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group, a cyclohexenyl group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group.

(188) R.sub.101, Ar.sub.201, Ar.sub.202, Ar.sub.301, Ar.sub.302, and Ar.sub.311 may be each independently selected from a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group; and

(189) a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group, a cyclohexenyl group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, an imidazopyrimidinyl group, and Si(Q.sub.31)(Q.sub.32)(Q.sub.33);

(190) wherein Q.sub.31 to Q.sub.33 may be each independently selected from a hydrogen, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a pyridinyl group, a pyrimidinyl group, a triazinyl group, a quinolinyl group, and an isoquinolinyl group.

(191) In some embodiments, the first host may be represented by one of Formulae 101A to 101D,

(192) the second host may be represented by Formula 201A,

(193) the third host may be represented by one of Formulae 202A and 202B,

(194) the fourth host may be represented by one of Formulae 301A to 301H, and

(195) the fifth host may be represented by one of Formulae 302A and 302B:

(196) ##STR00115## ##STR00116## ##STR00117## ##STR00118##

(197) In the Formulae above, descriptions of Ar.sub.101, A.sub.201 to A.sub.204, A.sub.211 to A.sub.214, A.sub.301 to A.sub.304, A.sub.311, A.sub.312, A.sub.314, X.sub.301, L.sub.101, L.sub.201 to L.sub.203, L.sub.301, L.sub.302, L.sub.311, a101, a201 to a203, a301, a302, a311, Ar.sub.201, Ar.sub.202, Ar.sub.301, Ar.sub.302, Ar.sub.311, R.sub.101, R.sub.201 to R.sub.204, R.sub.211 to R.sub.214, R.sub.301, R.sub.302, R.sub.311, R.sub.312, b101, b201 to b204, b211 to b214, b301, b302, b311, and b312 may be understood by referring to the descriptions thereof provided herein,

(198) descriptions of L.sub.102 and L.sub.103 may each be the same as defined in connection with descriptions of L.sub.101, descriptions of a102 and a103 may each be the same as defined in connection with a101, descriptions of b102 and b103 may each be the same as defined in connection with R.sub.101, and descriptions of b102 and b103 may each be the same as defined in connection with b101, and

(199) descriptions of A.sub.213a and A.sub.213b may each be the same as defined in connection with A.sub.213, descriptions of A.sub.214a and A.sub.214b may each be the same as defined in connection with A.sub.214, descriptions of R.sub.213a and R.sub.213b may each be the same as defined in connection with R.sub.213, descriptions of R.sub.214b and R.sub.214b may each be the same as defined in connection with R.sub.214, descriptions of ba213 and bb213 may each be the same as defined in connection with b213, and descriptions of ba214 and bb214 may each be the same as defined in connection with b214.

(200) The compound represented by Formula 101 may be one of Compounds H-1a to H-188a, the compound represented by Formula 201 may be one of Compounds H-1b to H-74b, the compound represented by Formula 301 may be one of Compounds H-1c to H-141c, as examples:

(201) ##STR00119## ##STR00120## ##STR00121## ##STR00122## ##STR00123## ##STR00124## ##STR00125## ##STR00126## ##STR00127## ##STR00128## ##STR00129## ##STR00130## ##STR00131## ##STR00132## ##STR00133## ##STR00134## ##STR00135## ##STR00136## ##STR00137## ##STR00138## ##STR00139## ##STR00140## ##STR00141## ##STR00142## ##STR00143## ##STR00144## ##STR00145## ##STR00146## ##STR00147## ##STR00148## ##STR00149## ##STR00150## ##STR00151## ##STR00152## ##STR00153## ##STR00154## ##STR00155## ##STR00156## ##STR00157## ##STR00158## ##STR00159## ##STR00160## ##STR00161## ##STR00162## ##STR00163## ##STR00164## ##STR00165## ##STR00166## ##STR00167## ##STR00168## ##STR00169## ##STR00170## ##STR00171## ##STR00172## ##STR00173## ##STR00174## ##STR00175## ##STR00176## ##STR00177## ##STR00178## ##STR00179## ##STR00180## ##STR00181## ##STR00182## ##STR00183## ##STR00184## ##STR00185## ##STR00186## ##STR00187## ##STR00188## ##STR00189## ##STR00190## ##STR00191## ##STR00192## ##STR00193## ##STR00194## ##STR00195## ##STR00196## ##STR00197## ##STR00198## ##STR00199## ##STR00200## ##STR00201## ##STR00202## ##STR00203## ##STR00204## ##STR00205## ##STR00206## ##STR00207## ##STR00208## ##STR00209## ##STR00210## ##STR00211## ##STR00212## ##STR00213## ##STR00214## ##STR00215## ##STR00216## ##STR00217## ##STR00218## ##STR00219## ##STR00220## ##STR00221## ##STR00222##

(202) The dopant may include at least one selected from a fluorescent dopant and a phosphorescent dopant.

(203) The phosphorescent dopant may include an organometallic complex represented by Formula 401 below:

(204) ##STR00223##

(205) wherein in Formula 401,

(206) M may be selected from iridium (Ir), platinum (Pt), osmium (Os), titanium (Ti), zirconium (Zr), hafnium (Hf), europium (Eu), terbium (Tb), and thulium (Tm);

(207) X.sub.401 to X.sub.404 may each independently be nitrogen or carbon;

(208) A.sub.401 and A.sub.402 rings may be each independently selected from a substituted or unsubstituted benzene, a substituted or unsubstituted naphthalene, a substituted or unsubstituted fluorene, a substituted or unsubstituted spiro-fluorene, a substituted or unsubstituted indene, a substituted or unsubstituted pyrrole, a substituted or unsubstituted thiophene, a substituted or unsubstituted furan, a substituted or unsubstituted imidazole, a substituted or unsubstituted pyrazole, a substituted or unsubstituted thiazole, a substituted or unsubstituted isothiazole, a substituted or unsubstituted oxazole, a substituted or unsubstituted isoxazole, a substituted or unsubstituted pyridine, a substituted or unsubstituted pyrazine, a substituted or unsubstituted pyrimidine, a substituted or unsubstituted pyridazine, a substituted or unsubstituted quinoline, a substituted or unsubstituted isoquinoline, a substituted or unsubstituted benzoquinoline, a substituted or unsubstituted quinoxaline, a substituted or unsubstituted quinazoline, a substituted or unsubstituted carbazole, a substituted or unsubstituted benzoimidazole, a substituted or unsubstituted benzofuran, a substituted or unsubstituted benzothiophene, a substituted or unsubstituted isobenzothiophene, a substituted or unsubstituted benzoxazole, a substituted or unsubstituted isobenzoxazole, a substituted or unsubstituted triazole, a substituted or unsubstituted oxadiazole, a substituted or unsubstituted triazine, a substituted or unsubstituted dibenzofuran, and a substituted or unsubstituted dibenzothiophene;

(209) at least one of substituents of the substituted benzene, substituted naphthalene, substituted fluorene, substituted spiro-fluorene, substituted indene, substituted pyrrole, substituted thiophene, substituted furan, substituted imidazole, substituted pyrazole, substituted thiazole, substituted isothiazole, substituted oxazole, substituted isoxazole, substituted pyridine, substituted pyrazine, substituted pyrimidine, substituted pyridazine, substituted quinoline, substituted isoquinoline, substituted benzoquinoline, substituted quinoxaline, substituted quinazoline, substituted carbazole, substituted benzoimidazole, substituted benzofuran, substituted benzothiophene, substituted isobenzothiophene, substituted benzoxazole, substituted isobenzoxazole, substituted triazole, substituted oxadiazole, substituted triazine, substituted dibenzofuran, and substituted dibenzothiophene may be selected from:

(210) a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group;

(211) a C.sub.1-C.sub.60 alkyl group, a C.sub.1-C.sub.60 alkenyl group, a C.sub.1-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.2-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, N(Q.sub.401)(Q.sub.402), Si(Q.sub.403)(Q.sub.404)(Q.sub.405), and B(Q.sub.406)(Q.sub.407);

(212) a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group;

(213) a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, N(Q.sub.411)(Q.sub.412), Si(Q.sub.413)(Q.sub.414)(Q.sub.415), and B(Q.sub.416)(Q.sub.417); and

(214) N(Q.sub.421)(Q.sub.422), Si(Q.sub.423)(Q.sub.424)(Q.sub.425), and B(Q.sub.426)(Q.sub.427);

(215) L.sub.401 may be an organic ligand;

(216) xc1 may be selected from 1, 2, and 3; and

(217) xc2 may be selected from 0, 1, 2, and 3.

(218) Descriptions of Q.sub.401 to Q.sub.407, Q.sub.411 to Q.sub.417, and Q.sub.421 to Q.sub.427 may be understood by referring to the description of Q.sub.1.

(219) L.sub.401 may be any suitable monovalent, divalent, or trivalent organic ligand. For example, L.sub.401 may be selected from a halogen ligand (for example, Cl or F), a diketone ligand (for example, acetylacetonate, 1,3-diphenyl-1,3-propanedionate, 2,2,6,6-tetramethyl-3,5-heptanedionate, or hexafluoroacetonate), a carboxylic acid ligand (for example, picolinate, dimethyl-3-pyrazolecarboxylate, or benzoate), a carbon monoxide ligand, an isonitrile ligand, a cyano ligand, and a phosphorous ligand (for example, phosphine, or phosphite), as examples.

(220) When A.sub.401 in Formula 401 has a plurality of substituents, the plurality of substituents of A.sub.401 may bind to each other to form a saturated or unsaturated ring.

(221) When A.sub.402 in Formula 401 has a plurality of substituents, the plurality of substituents of A.sub.402 may bind to each other to form a saturated or unsaturated ring.

(222) When xc1 in Formula 401 is two or more, a plurality of ligands

(223) ##STR00224##
in Formula 401 may be identical to or different from each other. When xc1 in Formula 401 is two or more, A.sub.401 and A.sub.402 of one ligand may be respectively linked to A.sub.401 and A.sub.402 of an adjacent ligand, directly or connected via a linking group (for example, a C.sub.1-C.sub.5 alkylene group, N(R) (wherein, R indicates a C.sub.1-C.sub.10 alkyl group or a C.sub.6-C.sub.20 aryl group), or C(?O)).

(224) The phosphorescent dopant may include at least one selected from Compounds PD1 to PD74 below.

(225) ##STR00225## ##STR00226## ##STR00227## ##STR00228## ##STR00229## ##STR00230## ##STR00231## ##STR00232## ##STR00233## ##STR00234## ##STR00235## ##STR00236## ##STR00237## ##STR00238## ##STR00239##

(226) In some embodiments, the phosphorescent dopant may include PtOEP below:

(227) ##STR00240##

(228) In some embodiments, the fluorescent dopant may include a compound represented by Formula 501:

(229) ##STR00241##

(230) In Formula 501,

(231) Ar.sub.501 may be selected from a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkylene group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkylene group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenylene group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenylene group, a substituted or unsubstituted C.sub.6-C.sub.60 arylene group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroarylene group, a substituted or unsubstituted divalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted divalent non-aromatic condensed heteropolycyclic group;

(232) L.sub.501 to L.sub.503 may be the same as defined in connection with L.sub.1 provided herein;

(233) R.sub.501 and R.sub.502 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a substituted or unsubstituted C.sub.1-C.sub.60 alkyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkenyl group, a substituted or unsubstituted C.sub.2-C.sub.60 alkynyl group, a substituted or unsubstituted C.sub.1-C.sub.60 alkoxy group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkyl group, a substituted or unsubstituted C.sub.3-C.sub.10 cycloalkenyl group, a substituted or unsubstituted C.sub.1-C.sub.10 heterocycloalkenyl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryl group, a substituted or unsubstituted C.sub.6-C.sub.60 aryloxy group, a substituted or unsubstituted C.sub.6-C.sub.60 arylthio group, a substituted or unsubstituted C.sub.1-C.sub.60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group, and Si(Q.sub.603)(Q.sub.604)(Q.sub.605);

(234) xd1 to xd3 may be each independently selected from 0, 1, 2, and 3; and

(235) xd4 may be selected from 1, 2, 3, and 4;

(236) at least one of substituents of the substituted C.sub.3-C.sub.10 cycloalkylene group, substituted C.sub.1-C.sub.10 heterocycloalkylene group, substituted C.sub.3-C.sub.10 cycloalkenylene group, substituted C.sub.1-C.sub.10 heterocycloalkenylene group, substituted C.sub.6-C.sub.60 arylene group, substituted C.sub.1-C.sub.60 heteroarylene group, substituted divalent non-aromatic condensed polycyclic group, substituted divalent non-aromatic condensed heteropolycyclic group, substituted C.sub.1-C.sub.60 alkyl group, substituted C.sub.2-C.sub.60 alkenyl group, substituted C.sub.2-C.sub.60 alkynyl group, substituted C.sub.1-C.sub.60 alkoxy group, substituted C.sub.3-C.sub.10 cycloalkyl group, substituted C.sub.1-C.sub.10 heterocycloalkyl group, substituted C.sub.3-C.sub.10 cycloalkenyl group, substituted C.sub.1-C.sub.10 heterocycloalkenyl group, substituted C.sub.6-C.sub.60 aryl group, substituted C.sub.6-C.sub.60 aryloxy group, substituted C.sub.6-C.sub.60 arylthio group, substituted C.sub.1-C.sub.60 heteroaryl group, substituted monovalent non-aromatic condensed polycyclic group, and substituted monovalent non-aromatic condensed heteropolycyclic group may be selected from

(237) a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group;

(238) a C.sub.1-C.sub.60 alkyl group, a C.sub.1-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.2-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, N(Q.sub.501)(Q.sub.502). Si(Q.sub.503)(Q.sub.504)(Q.sub.505), and B(Q.sub.506)(Q.sub.507);

(239) a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group;

(240) a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, N(Q.sub.511)(Q.sub.512), Si(Q.sub.513)(Q.sub.514)(Q.sub.515), and B(Q.sub.516)(Q.sub.517); and

(241) N(Q.sub.521)(Q.sub.522), Si(Q.sub.523)(Q.sub.524)(Q.sub.525), and B(Q.sub.526)(Q.sub.527);

(242) wherein Q.sub.501 to Q.sub.507, Q.sub.511 to Q.sub.517, and Q.sub.521 to Q.sub.527 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group.

(243) In some embodiments, Ar.sub.501 may be selected from a naphthalene, a heptalene, a fluorene, a spiro-fluorene, a benzofluorene, a dibenzofluorene, a phenalene, a phenanthrene, an anthracene, a fluoranthene, a triphenylene, a pyrene, a chrysene, a naphthacene, a picene, a perylene, a pentaphene, and an indenoanthracene; and

(244) a naphthalene, a heptalene, a fluorene, a spiro-fluorene, a benzofluorene, a dibenzofluorene, a phenalene, a phenanthrene, an anthracene, a fluoranthene, a triphenylene, a pyrene, a chrysene, naphthacene, a picene, a perylene, a pentaphene, and an indenoanthracene, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, N(Q.sub.601)(Q.sub.602), and Si(Q.sub.603)(Q.sub.604)(Q.sub.605);

(245) L.sub.501 to L.sub.503 may be each independently selected from:

(246) a phenylene group, a naphthylene group, a fluorenylene group, a spiro-fluorenylene group, a benzofluorene group, a dibenzofluorene group, a phenanthrenylene group, an anthracenylene group, a pyrenylene group, a chrysenylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, a quinolinylene group, an isoquinolinylene group, a quinoxalinylene group, a quinazolinylene group, a carbazolylene group, and a triazinylene group; and

(247) a phenylene group, a naphthylene group, a fluorenylene group, a spiro-fluorenylene group, a benzofluorenylene group, a dibenzofluorenylene group, a phenanthrenylene group, an anthracenylene group, a pyrenylene group, a chrysenylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, a quinolinylene group, an isoquinolinylene group, a quinoxalinylene group, a quinazolinylene group, a carbazolylene group, and a triazinylene group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, a quinolinyl group, an isoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group;

(248) R.sub.501 and R.sub.502 may be each independently selected from:

(249) a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazole group, a triazinyl group, a dibenzofuranyl group, and a dibenzothiophenyl group; and

(250) a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a triazinyl group, a dibenzofuranyl group, and a dibenzothiophenyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.20 alkyl group, a C.sub.1-C.sub.20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a triazinyl group, a dibenzofuranyl group, and a dibenzothiophenyl group;

(251) wherein Q.sub.501 to Q.sub.505 may be each independently selected from a hydrogen, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.6-C.sub.60 aryl group, and a C.sub.2-C.sub.60 heteroaryl group.

(252) The fluorescent dopant may include at least one selected from Compounds FD1 to FD16 below:

(253) ##STR00242## ##STR00243## ##STR00244## ##STR00245## ##STR00246##

(254) The amount of the dopant in the emission layer may be, in general, in a range of about 0.01 part by weight to about 15 parts by weight based on 100 parts by weight of the host.

(255) The thickness of the emission layer may be in a range of about 100 ? to about 1,000 ?, or, for example, about 200 ? to about 600 ?. When the thickness of the emission layer is within this range, excellent light-emission characteristics may be obtained without a substantial increase in driving voltage.

(256) An electron transport region may be on the emission layer 150.

(257) The electron transport region 170 may include at least one selected from a hole blocking layer, an electron transport layer (ETL), and an electron injection layer.

(258) In some embodiments, the electron transport region may have a structure of electron transport layer/electron injection layer or a structure of hole blocking layer/electron transport layer/electron injection layer, wherein layers of each structure are sequentially stacked from the emission layer in the stated order.

(259) The electron transport region may include a hole blocking layer. The hole blocking layer may be formed, when the emission layer includes a phosphorescent dopant, to prevent diffusion of excitons or holes into an electron transport layer.

(260) When the electron transport region includes a hole blocking layer, the hole blocking layer may be formed on the emission layer by using various methods, such as vacuum-deposition, spin coating, casting, LB method, ink-jet printing, laser-printing, or LITI. When the hole blocking layer is formed by vacuum-deposition or spin coating, deposition and coating conditions for the hole blocking layer may be determined by referring to the deposition and coating conditions for the hole injection layer.

(261) The hole blocking layer may include, for example, at least one selected from BCP and Bphen:

(262) ##STR00247##

(263) A thickness of the hole blocking layer may be in a range of about 20 ? to about 1,000 ?, for example, about 30 ? to about 300 ?. When the thickness of the hole blocking layer is within this range, excellent hole blocking characteristics may be obtained without a substantial increase in driving voltage.

(264) The electron transport region may include an electron transport layer. The electron transport layer may be formed on the emission layer or the hole blocking layer by using a suitable method, such as vacuum deposition, spin coating, casting, LB method, ink-jet printing, laser-printing, or LITI. When the electron transport layer is formed by using vacuum deposition or spin coating, vacuum deposition and coating conditions for the electron transport layer may be determined by referring to the vacuum deposition and coating conditions for the hole injection layer.

(265) In some embodiments, the organic layer 150 of the organic light-emitting device may include an electron transport region disposed between the emission layer and the second electrode 190. The electron transport region may include, for example, at least one selected from an electron transport layer and an electron injection layer.

(266) The thickness of the electron transport layer may be in a range of about 100 ? to about 1,000 ?, for example, about 150 ? to about 500 ?. When the thickness of the electron transport layer is within this range, excellent electron transport characteristics may be obtained without a substantial increase in driving voltage.

(267) The electron transport layer may further include a metal-containing material, in addition to the second compound.

(268) The metal-containing material may include a Li complex. The Li complex may include, for example, Compound ET-D1 (lithium quinolate, LiQ) or ET-D2:

(269) ##STR00248##

(270) The electron transport region may include an electron injection layer that facilitates electron injection from the second electrode 190.

(271) The electron injection layer may be formed on the electron transport layer by a suitable method, such as vacuum-deposition, spin coating, casting, LB method, ink-jet printing, laser-printing, or LITI. When the electron injection layer is formed by vacuum-deposition or spin coating, vacuum-deposition and coating conditions for the electron injection layer may be determined by referring to the vacuum-deposition and coating conditions for the hole injection layer.

(272) The electron injection layer may include at least one selected from, LiF, NaCl, CsF, Li.sub.2O, BaO, and LiQ.

(273) A thickness of the electron injection layer may be in a range of about 1 ? to about 100 ?, for example, about 3 ? to about 90 ?. When the thickness of the electron injection layer is within this range, excellent electron injection characteristics may be obtained without a substantial increase in driving voltage.

(274) The second electrode 190 may be on the electron transport region 170. The second electrode 190 may be a cathode that is an electron injection electrode, and in this regard, a material for forming the second electrode 190 may be a material having a low work function, and such a material may be metal, alloy, an electrically conductive compound, or a mixture thereof. Examples of the second electrode 190 include lithium (Li), magnesium (Mg), aluminum (Al), aluminum-lithium (AlLi), calcium (Ca), magnesium-indium (MgIn), and magnesium-silver (MgAg). In some embodiments, the material for forming the second electrode 190 may be ITO or IZO. The second electrode 190 may be a reflective electrode, a semi-transmissive electrode, or a transmissive electrode.

(275) The term C.sub.1-C.sub.60 alkyl group used herein refers to a linear or branched aliphatic hydrocarbon monovalent group having 1 to 60 carbon atoms. Examples thereof include a methyl group, an ethyl group, a propyl group, an iso-butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, an iso-amyl group, and a hexyl group. The term C.sub.1-C.sub.60 alkylene group used herein refers to a divalent group having the same structure as a C.sub.1-C.sub.60 alkyl group.

(276) The term C.sub.1-C.sub.60 alkoxy group used herein refers to a monovalent group represented by OA.sub.101 (wherein A.sub.101 is the C.sub.1-C.sub.60 alkyl group). Examples thereof include a methoxy group, an ethoxy group, and an isopropyloxy group.

(277) The term C.sub.2-C.sub.60 alkenyl group used herein refers to a hydrocarbon group formed by substituting at least one carbon double bond in the middle or at the terminal of the C.sub.2-C.sub.60 alkyl group. Examples thereof include an ethenyl group, a propenyl group, and a butenyl group. The term C.sub.2-C.sub.60 alkenylene group used herein refers to a divalent group having the same structure as a C.sub.2-C.sub.60 alkenyl group.

(278) The term C.sub.2-C.sub.60 alkynyl group used herein refers to a hydrocarbon group formed by substituting at least one carbon triple bond in the middle or at the terminal of the C.sub.2-C.sub.60 alkyl group. Examples thereof include an ethynyl group and a propynyl group. The term C.sub.2-C.sub.60 alkynylene group used herein refers to a divalent group having the same structure as a C.sub.2-C.sub.60 alkynyl group.

(279) The term C.sub.3-C.sub.10 cycloalkyl group used herein refers to a monovalent monocyclic saturated hydrocarbon group including 3 to 10 carbon atoms. Examples thereof include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and a cycloheptyl group. The term C.sub.3-C.sub.10 cycloalkylene group used herein refers to a divalent group having the same structure as a C.sub.3-C.sub.10 cycloalkyl group.

(280) The term C.sub.1-C.sub.10 heterocycloalkyl group used herein refers to a monovalent monocyclic group including at least one heteroatom selected from N, O, P, and S as a ring-forming atom and 1 to 10 carbon atoms. Examples thereof include a tetrahydrofuranyl group and a tetrahydrothiophenyl group. The term C.sub.1-C.sub.10 heterocycloalkylene group used herein refers to a divalent group having the same structure as a C.sub.1-C.sub.10 heterocycloalkyl group.

(281) The term C.sub.3-C.sub.10 cycloalkenyl group used herein refers to a monovalent monocyclic group that has 3 to 10 carbon atoms and at least one double bond in its ring, and which is not aromatic. Examples thereof include a cyclopentenyl group, a cyclohexenyl group, and a cycloheptenyl group. The term C.sub.3-C.sub.10 cycloalkenylene group used herein refers to a divalent group having the same structure as a C.sub.3-C.sub.10 cycloalkenyl group.

(282) The term C.sub.1-C.sub.10 heterocycloalkenyl group used herein refers to a monovalent monocyclic group including at least one heteroatom selected from N, O, P, and S as a ring-forming atom, 1 to 10 carbon atoms, and at least one double bond in its ring. Examples of the C.sub.1-C.sub.10 heterocycloalkenyl group include a 2,3-hydrofuranyl group and a 2,3-hydrothiophenyl group. The term C.sub.1-C.sub.10 heterocycloalkenylene group used herein refers to a divalent group having the same structure as a C.sub.1-C.sub.10 heterocycloalkenyl group.

(283) The term C.sub.6-C.sub.60 aryl group used herein refers to a monovalent group including a carbocyclic aromatic system having 6 to 60 carbon atoms. The term C.sub.6-C.sub.60 arylene group used herein refers to a divalent group including a carbocyclic aromatic system having 6 to 60 carbon atoms. Examples of the C.sub.6-C.sub.60 aryl group include a phenyl group, a naphthyl group, an anthracenyl group, a phenanthrenyl group, a pyrenyl group, and a chrysenyl group. When the C.sub.6-C.sub.60 aryl group or the C.sub.6-C.sub.60 arylene group include a plurality of rings, the rings may be fused to each other.

(284) The term C.sub.1-C.sub.60 heteroaryl group used herein refers to a monovalent group having a carbocyclic aromatic system including at least one hetero atom selected from N, O, P, and S as a ring-forming atom and 1 to 60 carbon atoms. The term C.sub.1-C.sub.60 heteroarylene group used herein refers to a divalent group having a carbocyclic aromatic system including at least one hetero atom selected from N, O, P, and S as a ring-forming atom and 1 to 60 carbon atoms. Examples of the C.sub.1-C.sub.60 heteroaryl group include a pyridinyl group, a pyrimidinyl group, a pyrazinyl group, a pyridazinyl group, a triazinyl group, a quinolinyl group, and an isoquinolinyl group. When the C.sub.1-C.sub.60 heteroaryl group or the C.sub.1-C.sub.60 heteroarylene group include a plurality of rings, the rings may be fused to each other.

(285) The term C.sub.6-C.sub.60 aryloxy group used herein indicates OA.sub.102 (wherein A.sub.102 is the C.sub.6-C.sub.60 aryl group). The term C.sub.6-C.sub.60 arylthio group used herein indicates SA.sub.103 (wherein A.sub.103 is the C.sub.6-C.sub.60 aryl group).

(286) The term monovalent non-aromatic condensed polycyclic group used herein refers to a monovalent group that has two or more rings condensed to each other, and has only carbon atoms (for example, the number of carbon atoms may be in a range of 8 to 60) as ring forming atoms, wherein the molecular structure as a whole is non-aromatic in the entire molecular structure. An example of the monovalent non-aromatic condensed polycyclic group is a fluorenyl group. The term divalent non-aromatic condensed polycyclic group used herein refers to a divalent group having the same structure as the monovalent non-aromatic condensed polycyclic group.

(287) The term monovalent non-aromatic condensed heteropolycyclic group used herein refers to a monovalent group that has two or more rings condensed to each other, and has a heteroatom selected from N, O, P, and S, other than carbon atoms (for example, the number of carbon atoms may be in a range of 2 to 60), as ring-forming atoms, wherein the molecular structure as a whole is non-aromatic in the entire molecular structure. An example of a monovalent non-aromatic condensed heteropolycyclic group is a carbazolyl group. The term divalent non-aromatic condensed hetero-polycyclic group used herein refers to a divalent group having the same structure as the monovalent non-aromatic condensed hetero-polycyclic group.

(288) In the present specification, at least one of the substituents of the substituted C.sub.6-C.sub.20 aromatic ring, substituted C.sub.3-C.sub.10 cycloalkylene group, substituted C.sub.1-C.sub.10 heterocycloalkylene group, substituted C.sub.3-C.sub.10 cycloalkenylene group, substituted C.sub.1-C.sub.10 heterocycloalkenylene group, substituted C.sub.6-C.sub.60 arylene group, substituted C.sub.1-C.sub.60 heteroarylene group, substituted divalent non-aromatic condensed polycyclic group, substituted divalent non-aromatic condensed heteropolycyclic group, substituted C.sub.1-C.sub.60 alkyl group, substituted C.sub.2-C.sub.60 alkenyl group, substituted C.sub.2-C.sub.60 alkynyl group, substituted C.sub.1-C.sub.60 alkoxy group, substituted C.sub.3-C.sub.10 cycloalkyl group, substituted C.sub.1-C.sub.10 heterocycloalkyl group, substituted C.sub.3-C.sub.10 cycloalkenyl group, substituted C.sub.1-C.sub.10 heterocycloalkenyl group, substituted C.sub.6-C.sub.60 aryl group, substituted C.sub.6-C.sub.60 aryloxy group, substituted C.sub.6-C.sub.60 arylthio group, substituted C.sub.1-C.sub.60 heteroaryl group, substituted monovalent non-aromatic condensed polycyclic group, and substituted monovalent non-aromatic condensed heteropolycyclic group may be selected from:

(289) a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group;

(290) a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group(aryloxy), a C.sub.6-C.sub.60 arylthio group(arylthio), a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, and Si(Q.sub.11)(Q.sub.12)(Q.sub.13);

(291) a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group;

(292) a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, and Si(Q.sub.21)(Q.sub.22)(Q.sub.23),

(293) and Si(Q.sub.31)(Q.sub.32)(Q.sub.33),

(294) wherein Q.sub.1 to Q.sub.3, Q.sub.11 to Q.sub.13, Q.sub.21 to Q.sub.23 and Q.sub.31 to Q.sub.33 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a C.sub.3-C.sub.10 cycloalkyl group, a C.sub.1-C.sub.10 heterocycloalkyl group, a C.sub.3-C.sub.10 cycloalkenyl group, a C.sub.1-C.sub.10 heterocycloalkenyl group, a C.sub.6-C.sub.60 aryl group, a C.sub.6-C.sub.60 aryloxy group, a C.sub.6-C.sub.60 arylthio group, a C.sub.1-C.sub.60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group.

(295) In some embodiments, at least one of the substituents of the substituted C.sub.6-C.sub.20 aromatic ring, substituted C.sub.3-C.sub.10 cycloalkylene group, substituted C.sub.1-C.sub.10 heterocycloalkylene group, substituted C.sub.3-C.sub.10 cycloalkenylene group, substituted C.sub.1-C.sub.10 heterocycloalkenylene group, substituted C.sub.6-C.sub.60 arylene group, substituted C.sub.1-C.sub.60 heteroarylene group, substituted divalent non-aromatic condensed polycyclic group, substituted divalent non-aromatic condensed heteropolycyclic group, substituted C.sub.1-C.sub.60 alkyl group, substituted C.sub.2-C.sub.60 alkenyl group, substituted C.sub.2-C.sub.60 alkynyl group, substituted C.sub.1-C.sub.60 alkoxy group, substituted C.sub.3-C.sub.10 cycloalkyl group, substituted C.sub.1-C.sub.10 heterocycloalkyl group, substituted C.sub.3-C.sub.10 cycloalkenyl group, substituted C.sub.1-C.sub.10 heterocycloalkenyl group, substituted C.sub.6-C.sub.60 aryl group, substituted C.sub.6-C.sub.60 aryloxy group, substituted C.sub.6-C.sub.60 arylthio group, substituted C.sub.1-C.sub.60 heteroaryl group, substituted monovalent non-aromatic condensed polycyclic group, and substituted monovalent non-aromatic condensed heteropolycyclic group may be selected from:

(296) a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group;

(297) a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, and a C.sub.1-C.sub.60 alkoxy group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group, a cyclohexenyl group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, an imidazopyrimidinyl group, and Si(Q.sub.11)(Q.sub.12)(Q.sub.13);

(298) a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group, a cyclohexenyl group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a Spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group;

(299) a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group, a cyclohexenyl group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group, each substituted with at least one selected from a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group, a cyclohexenyl group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, an imidazopyrimidinyl group, and Si(Q.sub.21)(Q.sub.22)(Q.sub.23); and

(300) Si(Q.sub.31)(Q.sub.32)(Q.sub.33);

(301) wherein Q.sub.11 to Q.sub.13, Q.sub.21 to Q.sub.23, and Q.sub.31 to Q.sub.33 may be each independently selected from a hydrogen, a deuterium, F, Cl, Br, I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C.sub.1-C.sub.60 alkyl group, a C.sub.2-C.sub.60 alkenyl group, a C.sub.2-C.sub.60 alkynyl group, a C.sub.1-C.sub.60 alkoxy group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group, a cyclohexenyl group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group.

(302) Hereinafter, an organic light-emitting device according to an embodiment will be described in detail with reference to Synthesis Examples and Examples. The wording B was used instead of A used in describing Synthesis Examples means that a molar equivalent of A was identical to a molar equivalent of B.

(303) The following Examples and Comparative Examples are provided in order to highlight characteristics of one or more embodiments, but it will be understood that the Examples and Comparative Examples are not to be construed as limiting the scope of the embodiments, nor are the Comparative Examples to be construed as being outside the scope of the embodiments. Further, it will be understood that the embodiments are not limited to the particular details described in the Examples and Comparative Examples.

EXAMPLES

Example 1

(304) For an anode, an ITO glass substrate (a product of Corning Co., Ltd) with an ITO layer having a thickness of 15 ?/cm.sup.2 (1,200 ?) thereon was cut to a size of 50 mm?50 mm?0.7 mm. Then, the substrate was sonicated using isopropyl alcohol and pure water each for 5 minutes, and cleaned by exposure to ultraviolet rays for 30 minutes, and then ozone. Then, the ITO glass substrate was mounted on a vacuum deposition apparatus.

(305) Compound 1 and F4-TCNQ were co-vacuum-deposited on the ITO anode to form a hole injection layer having a thickness of about 200 ?. Then, Compound 1 was vacuum-deposited on the hole injection layer to form a hole transport layer having a thickness of about 1,000 ? Then, Compound H1-a (host) and FD9 (fluorescent dopant) were co-vacuum-deposited on the hole transport layer in a weight ratio of about 95:5 to form an emission layer having a thickness of about 200 ?.

(306) Thereafter, Compound A4 and Liq were co-vacuum-deposited on the emission layer to form an electron transport layer having a thickness of 300 ?. Then, LiF was vacuum-deposited on the electron transport layer to form an electron injection layer having a thickness of 10 ?. Then, Al was vacuum-deposited on the electron injection layer to form a cathode having a thickness of 1,000 ?, thereby completing the manufacture of an organic light-emitting device.

Example 2

(307) An organic light-emitting device was manufactured in the same manner as in Example 1, except that in forming a hole injection layer and a hole transport layer, Compound 2 was used instead of Compound 1.

Example 3

(308) An organic light-emitting device was manufactured in the same manner as in Example 1, except that in forming a hole injection layer and a hole transport layer, Compound 3 was used instead of Compound 1.

Example 4

(309) For an anode, an ITO glass substrate (a product of Corning Co., Ltd) with an ITO layer having a thickness of 15 ?/cm.sup.2 (1,200 ?) thereon was cut to a size of 50 mm?50 mm?0.7 mm. Then, the substrate was sonicated using isopropyl alcohol and pure water each for 5 minutes, and cleaned by exposure to ultraviolet rays for 30 minutes, and then ozone. Then, the ITO glass substrate was mounted on a vacuum deposition apparatus.

(310) Compound HT-2 and F4-TCNQ were co-vacuum-deposited on the ITO anode to form a hole injection layer having a thickness of about 200 ?. Then, Compound HT-2 was vacuum-deposited on the hole injection layer to form a hole transport layer having a thickness of about 1000 ?.

(311) Compound 24 was vacuum-deposited on the hole transport layer to form an auxiliary emission layer having a thickness of about 100 ?.

(312) Compound H1-a (host) and FD9 (fluorescent dopant) were co-vacuum-deposited on the auxiliary emission layer in a weight ratio of about 95:5 to form an emission layer having a thickness of about 200 ?.

(313) Thereafter, Compound A4 and Liq were co-vacuum-deposited on the emission layer to form an electron transport layer having a thickness of 300 ?. Then, LiF was vacuum-deposited on the electron transport layer to form an electron injection layer having a thickness of 10 ?. Then, Al was vacuum-deposited on the electron injection layer to form a cathode having a thickness of 1,000 ?, thereby completing the manufacture of an organic light-emitting device.

(314) ##STR00249##

Example 5

(315) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an emission layer, Compound H-11b, Compound H-141a, and PD14 (phosphorescent dopant) were co-vacuum-deposited, instead of Compound H1-a and FD9, in a weight ratio of about 45:45:10.

Example 6

(316) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an emission layer, Compound H-124c, Compound H-128a, and PD18 (phosphorescent dopant) were co-vacuum-deposited, instead of Compound H1-a and FD9, in a weight ratio of about 45:45:10.

Example 7

(317) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an emission layer, Compound H-124c, Compound H-128a, and PD19 (phosphorescent dopant) were co-vacuum-deposited, instead of Compound H1-a and FD9, in a weight ratio of about 45:45:10.

Example 8

(318) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an auxiliary emission layer, Compound 7 was used instead of Compound 24.

Example 9

(319) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an auxiliary emission layer, Compound 25 was used instead of Compound 24.

Example 10

(320) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an auxiliary emission layer, Compound 29 was used instead of Compound 24.

Example 11

(321) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an electron transport layer, Compound A8 was used instead of Compound A4.

Example 12

(322) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an electron transport layer, Compound A12 was used instead of Compound A4.

Example 13

(323) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an electron transport layer, Compound A14 was used instead of Compound A4.

Example 14

(324) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an electron transport layer, Compound A18 was used instead of Compound A4.

Example 15

(325) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an electron transport layer, Compound A19 was used instead of Compound A4.

Example 16

(326) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an electron transport layer, Compound A26 was used instead of Compound A4.

Comparative Example 1

(327) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an auxiliary emission layer, Compound X1 was used instead of Compound 24, and in forming an electron transport layer, Compound Y1 was used instead of Compound A4.

Comparative Example 2

(328) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an auxiliary emission layer, Compound X2 was used instead of Compound 24, and in forming an electron transport layer, Compound Y2 was used instead of Compound A4.

Comparative Example 3

(329) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an auxiliary emission layer, Compound X3 was used instead of Compound 24, and in forming an electron transport layer, Compound Y2 was used instead of Compound A4.

Comparative Example 4

(330) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an auxiliary emission layer, Compound X4 was used instead of Compound 24.

Evaluation Example 1

(331) The driving voltage, efficiency, and lifespan (800 nit) of the organic light-emitting devices manufactured according to Examples 1 to 16 and Comparative Examples 1 to 4 were evaluated. The results thereof are shown in Table 1. A Keithley 2400 current voltmeter and a PR650 Spectroscan Source Measurement Unit luminance meter (available from PhotoResearch) were used in evaluation. The term lifespan used herein indicates a period of time required for the luminance of the organic light-emitting device to reach 95% with respect to an initial luminance. Here, the efficiency and lifespan of the organic light-emitting devices manufactured according to Examples 2 to 16 and Comparative Examples 1 to 4 were described as a comparison, based on the value of efficiency and lifespan of the organic light-emitting device according to Example 1, which was determined as 1.

(332) TABLE-US-00001 TABLE 1 Hole trans- Emission aux- Electron trans- Emission layer Driving volt- Effi- Life- port layer iliary layer port layer Host Dopant age (V) ciency time Example 1 Compound 1 Compound 1 Compound A4 Compound H-1a FD9 4.5 1 1 Example 2 Compound 2 Compound 2 Compound A4 Compound H-1a FD9 4.3 1.1 1 Example 3 Compound 3 Compound 3 Compound A4 Compound H-1a FD9 4.3 1.1 1.1 Example 4 Compound HT-2 Compound 24 Compound A4 Compound H-1a FD9 4.1 1.2 1 Example 5 Compound HT-2 Compound 24 Compound A4 Compound H-11b + PD14 4.7 1 1 Compound H-141a Example 6 Compound HT-2 Compound 24 Compound A4 Compound H-124c + PD18 4.6 1.2 1 Compound H-128a Example 7 Compound HT-2 Compound 24 Compound A4 Compound H-124c + PD19 4.6 1.1 1 Compound H-128a Example 8 Compound HT-2 Compound 7 Compound A4 Compound H-1a FD9 4.8 1.1 1.1 Example 9 Compound HT-2 Compound 25 Compound A4 Compound H-1a FD9 4.1 1.3 1.1 Example 10 Compound HT-2 Compound 29 Compound A4 Compound H-1a FD9 4.2 1.2 1.1 Example 11 Compound HT-2 Compound 24 Compound A8 Compound H-1a FD9 4.2 1.1 1 Example 12 Compound HT-2 Compound 24 Compound A12 Compound H-1a FD9 4.3 1 1.1 Example 13 Compound HT-2 Compound 24 Compound A14 Compound H-1a FD9 4.3 1.2 1.1 Example 14 Compound HT-2 Compound 24 Compound A18 Compound H-1a FD9 4.0 1.3 1 Example 15 Compound HT-2 Compound 24 Compound A19 Compound H-1a FD9 4.1 1.2 1.1 Example 16 Compound HT-2 Compound 24 Compound A26 Compound H-1a FD9 4.1 1.2 1.2 Comparative Compound HT-2 Compound X1 Compound Y1 Compound H-1a FD9 5.2 0.9 0.8 Example 1 Comparative Compound HT-2 Compound X2 Compound Y2 Compound H-1a FD9 5.4 0.8 0.7 Example 2 Comparative Compound HT-2 Compound X3 Compound Y2 Compound H-1a FD9 5.4 0.8 0.8 Example 3 Comparative Compound HT-2 Compound X4 Compound A4 Compound H-1a FD9 5.3 0.9 0.8 Example 4

(333) ##STR00250## ##STR00251## ##STR00252## ##STR00253## ##STR00254##

Example 17

(334) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an auxiliary emission layer, Compound 7 was used instead of Compound 24, and in forming an emission layer, FD19 was used instead of FD9 as a dopant.

Comparative Example 5

(335) An organic light-emitting device was manufactured in the same manner as in Example 4, except that in forming an auxiliary emission layer, Compound X4 was used instead of Compound 24, and in forming an emission layer, PD14 was used instead of FD9 as a dopant.

Evaluation Example 2

(336) The efficiency at a voltage of 4V of the organic light-emitting devices according to Examples 5 to 7 and 17 and Comparative Example 5 were evaluated by using a PR650 Spectroscan Source Measurement Unit. (available from PhotoResearch) luminance meter. The results thereof are shown in Table 2. Here, the efficiency of the organic light-emitting devices according to Example 6 to 7 and 17 and Comparative Example 5 were described as a comparison, based on the value of the efficiency of the organic light-emitting device according to Example 5, which was determined as 1.

(337) TABLE-US-00002 TABLE 2 Hole trans- Emission aux- electron trans- Emission layer Effi- port layer iliary layer port layer Host Dopant ciency Example 5 Compound HT-2 Compound 24 Compound A4 Compound H-11b + PD14 1 Compound H-141a Example 6 Compound HT-2 Compound 24 Compound A4 Compound H-124c + PD18 1 Compound H-128a Example 7 Compound HT-2 Compound 24 Compound A4 Compound H-124c + PD19 1 Compound H-128a Example 17 Compound HT-2 Compound 7 Compound A4 Compound H-1a PD19 1 Comparative Compound HT-2 Compound X4 Compound A4 Compound H-1a PD14 0.8 Example 5

(338) Referring to Tables 1 and 2, it was found that the organic light-emitting devices according to Examples 1 to 17 exhibited low driving voltage, improved emission efficiency compared to the organic light-emitting devices according to Comparative Examples 1 to 5. The organic light-emitting devices according to Examples 1 to 17 exhibited low driving voltage, even at a low voltage.

(339) As described above, according to the one or more of the above exemplary embodiments, the organic light-emitting device may have low driving voltage, improved efficiency, improved luminance, and long lifespan characteristics.

(340) It should be understood that exemplary embodiments described herein should be considered in a descriptive sense only and not for purposes of limitation. Descriptions of features or aspects within each exemplary embodiment should typically be considered as available for other similar features or aspects in other exemplary embodiments.

(341) While one or more exemplary embodiments have been described with reference to the FIGURES, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope as defined by the following claims.