COSMETIC COMPOSITIONS COMPRISING CHITOSAN AND HYDROXYPROPYL METHYLCELLULOSE AND THEIR USE FOR IMPROVING HAIR STRENGTH AND RELATED PROPERTIES

Abstract

Provided are hair treatment compositions comprising one or more polysaccharides and their use in improving hair strength.

Claims

1. A hair treatment composition comprising chitosan and hydroxypropyl methylcellulose (HPMC).

2. The hair treatment composition of claim 1, wherein the wt % ratio of chitosan to HPMC is about 1:2.

3. The hair treatment composition of claim 1, further comprising a cosmetically acceptable aqueous medium.

4. The hair treatment composition of claim 1, further comprising at least one product having a water content of 40% or greater.

5. The hair treatment composition of claim 1, wherein the hair treatment composition comprises at least one of a shampoo, a rinse-off conditioner, a leave-on conditioner, or a styling product.

6. The hair treatment composition of claim 1, wherein the hair treatment further comprise one or more additional ingredients selected from anionic surfactants, nonionic surfactants, amphoteric surfactants, cationic surfactants, fatty alcohols, fatty acids, emulsifiers, emollients, glycols, polymers or rheology modifiers, pH adjusters, UV absorbers, fragrance or other odor masking agents, and preservatives.

7. A method of improving the strength of hair comprising applying to the hair the composition of claim 1.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0009] FIG. 1 is a comparison of the film strength, humidity resistance, and/or curl snap between various polysaccharides.

[0010] FIG. 2 is a comparison of the film strength, humidity resistance, and/or curl snap between various polysaccharides.

[0011] FIG. 3 is a comparison of the film strength, humidity resistance, and/or curl snap between various polysaccharides.

[0012] FIG. 4 is a comparison of the film strength of various polysaccharides.

[0013] FIG. 5 is a graph quantifying the difference in number of lifted cuticles on virgin hair swatches versus bleach hair fibers when exposed to increasing levels of strain.

[0014] FIG. 6. is a series of four images of untreated bleached hair fibers exposed to increasing levels of strain. Images were captured using the Sensofar S Neox model light microscope at 50× magnification.

[0015] FIG. 7. is a series of four images of bleached hair fibers, treated with an aqueous polysaccharide solution, and exposed to increasing levels of strain. Images were captured using the Sensofar S Neox model light microscope at 50× magnification.

[0016] FIG. 8. is a graph quantifying the difference in the number of lifted cuticles between the untreated bleached hair fibers and the bleached hair fibers treated with an aqueous polysaccharide solution when exposed to increasing levels of strain.

[0017] FIG. 9. is an image of the Lifecycle Rig setup used to repeatedly brush hair fibers.

[0018] FIG. 10. Is a graph quantifying the difference in broken fibers between untreated bleached hair and bleached hair treated with the inventive shampoo and conditioner.

DETAILED DESCRIPTION

1. Compositions

[0019] Provided herein are hair treatment compositions comprising one or more polysaccharides selected from chitosan, hydroxylpropyl methylcellulose (HPMC), pectin, pullulan, and hyaluronic acid.

[0020] In a first aspect, the hair treatment compositions described herein comprise chitosan and HPMC.

[0021] In a second aspect, the hair treatment compositions described herein comprise chitosan and HPMC, wherein the ratio of chitosan to HPMC ranges from about 0.5 wt % to about 1.5 wt % chitosan to about 1.5 wt % to about 2.5 wt % HMPC. Alternatively, the ratio of chitosan to HPMC ranges from about 0.7 wt % to about 1.3 wt % chitosan to about 1.7 wt % to about 2.3 wt % HMPC; from about 0.8 wt % to about 1.2 wt % chitosan to about 1.8 wt % to about 2.2 wt % HMPC; or from about 0.9 wt % to about 1.1 wt % chitosan to about 1.9 wt % to about 2.1 wt % HMPC. In another aspect, the ratio of chitosan to HPMC is about 1.0 wt % chitosan to about 2.0 wt % HMPC.

[0022] In a third aspect, the chitosan in the disclosed compositions (e.g., as in the second aspect) is present in an amount of less than or equal to about 0.5 wt %, less than or equal to about 0.4 wt %, less than or equal to about 0.3 wt %, less than or equal to about 0.2 wt %, or less than or equal to about 0.1 wt % based on the total weight of the composition. Alternatively, as part of a second aspect, the chitosan in the disclosed compositions (e.g., as in the second aspect) is present in an amount ranging from about 0.01 wt % to about 0.5 wt %, from about 0.03 wt % to about 0.4 wt %, or from about 0.04 wt % to about 0.3 wt % based on the total weight of the composition.

[0023] In a fourth aspect, the HPMC in the disclosed compositions (e.g., as in the second or third aspect) is present in an amount of less than or equal to about 1 wt %, less than or equal to about 0.8 wt %, less than or equal to about 0.6 wt %, or less than or equal to about 0.4 wt %. Alternatively, as part of a third aspect, the HPMC in the disclosed compositions (e.g., as in the second or third aspect) is present in an amount ranging from about 0.05 wt % to about 0.6 wt %, from about 0.08 wt % to about 0.5 wt %, or from about 0.09 wt % to about 0.45 wt % based on the total weight of the composition.

[0024] In a fifth aspect, the disclosed compositions (e.g., as in the first through fourth aspects) further comprise a cosmetically acceptable medium. Alternatively, as part of a fifth aspect, the disclosed compositions (e.g., as in the first through third aspects) further comprise a cosmetically acceptable aqueous medium. In one aspect, this aqueous medium comprises at least one product having a water content of 40% or greater. In another aspect, this aqueous medium comprises at least one product having a water content of 40% or greater and can be applied to the hair for the purpose of cleansing, conditioning, or styling the hair (e.g., shampoo, rinse-off conditioner, leave-on conditioner, styling product).

[0025] In a sixth aspect, the disclosed compositions (e.g., as in the first through fifth aspects) further comprise one or more additional ingredients selected from anionic surfactants, nonionic surfactants, amphoteric surfactants, cationic surfactants, fatty alcohols, fatty acids, emulsifiers, emollients (e.g., silicones, hydrocarbons, esters, ethers, waxes, naturally derived oils and butters, and ceramides), glycols (e.g., glycerin, butylene glycol, propylene glycol, propanediol, pentylene glycol, and dipropylene glycol), polymers or rheology modifiers (e.g., gums, including but not limited to: guar, xanthan, tara, acacia or derivatives; cellulosics, including but not limited to: hydroxyethylcellulose, carboxymethylcellulose, hydroxypropylcellulose, or derivatives; and acrylic polymers, including but not limited to: carbomer, polyacrylamide, acrylates copolymer, acrylates/C10-30 Alkyl Acrylate Crosspolymer, polyacrylate crosspolymer-6, or similar), pH adjusters (including but not limited to: acids/pH decreasing agents (e.g., citric acid, lactic acid, glycolic acid, malic acid, gluconolactone or salts thereof) and bases/pH increasing agents (e.g., sodium hydroxide, potassium hydroxide, or amines, including, but not limited to: arginine, monoethanolamine, triethanolamine, triisopropanolamine, aminomethyl propanol, dimethylamino methylpropanol, tromethamine), UV absorbers, fragrance or other odor masking agents, and preservatives.

[0026] Specific compositions are described in the Exemplification section and are included herein.

2. Methods of Use

[0027] In one aspect, the disclosed compositions improve the strength of hair. In another aspect, the disclosed compositions are useful for improving the strength of hair.

EXEMPLIFICATION

Example 1. Methods for Determining Performance

[0028] The properties of various polysaccharides were evaluated as follows.

[0029] A 1% aqueous solution was made of each polysaccharide. Solutions were stored in a refrigerator to avoid the need for preservative, which could alter the performance of the polysaccharide films. To assess film strength, 15 mL of the 1% solutions were filled into rectangular silicone molds. The molds were placed in a humidity chamber set at 60 degrees C. and 20% relative humidity for one hour. At the end of one hour, the temperature was reduced to 50 degrees C. and 20% relative humidity. The solutions continued to dry overnight (˜12 hours) until the water completely evaporated, leaving a solid film. Films were then removed from the silicone molds and evaluated. See FIGS. 1-4.

[0030] In the case of many polysaccharides, the films were extremely brittle. The arabinoxylan alone as well as the flax (blend of arabinoxylan and pectin) were so brittle that the films could not be removed from the molds without breaking. Only a few (chitosan, hydroxypropyl methylcellulose, pectin, pullulan, and hyaluronic acid) provided strong films that can be pulled without breaking or tearing. Of these five polysaccharides, pullulan and chitosan both provided very thick, rigid films. Contrastingly, hydroxypropyl methylcellulose and hyaluronic acid provided more flexible films, similar to Saran Wrap™. Taking into account the other attributes (hydrophobicity and elasticity), we chose to combine chitosan and hydroxypropyl methylcellulose to give a film with optimal strength and flexibility, with the goal of improving hair strength while maintaining a natural feel on hair.

Example 2. Methods for Assessing Hair Damage

[0031] The hair fiber is comprised of overlapping cuticle cells, which protect the inner corticular cells from mechanical stress from styling and heat exposure as well as chemical stress from bleaching and UV exposure. These cuticle cells tend to lift and can ultimately become damaged as the hair is subjected to everyday grooming habits such as shampooing and or styling the hair. These lifted cuticles can influence the interaction with light and are amenable to study with a light microscope.

[0032] As a result, the improvement of hair strength was evaluated as follows.

[0033] Virgin and Bleached hair swatches were washed before use using a sink with controlled flow and temperature (4 L/min at 35° C.). Hair was washed with a 14% aqueous solution of sodium laureth sulfate (SLES).

[0034] Images of the hair swatches were acquired using the Sensofar S Neox model. The microscope was set to take a standard light image, with the light source set at 25%, and magnification set to 50×.

[0035] Individual strands of hair were loaded onto a strain rig which fits on the microscope's Z-platform, allowing real-time imaging and strain application to the fibre. Images were taken at increasing increments of 7% strain. The number of lifted cuticles were quantified at each strain increment.

[0036] When subjected to increasing strain, the damaged hair represented by the bleached fibers showed an increase in the number of raised cuticles compared to the virgin hair fibers. See FIG. 5.

Example 3. Improvement in Strength Using Inventive Composition

[0037] Aqueous Polysaccharide Solution

TABLE-US-00001 Supplier INCI Name Trade Name Qty % W/W N/A Water/Aqua/Eau Water, DI - room 33.400000 g 33.400000% temperature ChiBio Biotech Chitosan Water Soluble  0.200000 g 0.200000% Mushroom Chitosan Ashland Specialty Hydroxypropyl Benecel K35M  0.400000 g 0.400000% Ingredients G.P. Methylcellulose N/A Water/Aqua/Eau Water, DI - 5° C. 66.000000 g 66.000000% Total 100.000000 g  100.00%

[0038] Charge vessel with room temperature deionized water. Begin mixing at moderate speed. Add Chitosan to vortex. Mix for 15 minutes or until dissolved. Begin heating to 80-85° C. When the temperature of the batch is above 80° C., add Hydroxypropyl Methylcellulose to the vortex. Mix for not more than 10 minutes to disperse. Add chilled deionized water to the batch. Mix until Hydroxypropyl Methylcellulose is fully dissolved.

[0039] Bleached hair swatches were washed before use using a sink with controlled flow and temperature (4 L/min at 35° C.). Hair was washed with a 14% aqueous solution of sodium laureth sulfate (SLES). Half of the bleached hair swatches were than treated with the prepared aqueous polysaccharide solution. The treated swatches were prepared by submerging the bleached swatches into a beaker containing the above polysaccharide solution for a total of 5 seconds. Excess product was rinsed from the hair swatch for 30 seconds using a sink with controlled flow and temperature (4 L/min at 35° C.).

[0040] Images of both the bleached untreated and bleached treated hair swatches were acquired using the Sensofar S Neox model. The microscope was set to take a standard light image, with the light source set at 25%, and magnification set to 50×. The number of lifted cuticles were quantified at each strain increment.

[0041] When subjected to increasing strain, the bleached hair swatches treated with the aqueous solution showed a decrease in the number of raised cuticles compared to the bleached hair fibers at lower levels of strain. represented by the bleached fibers showed an increase in the number of raised cuticles compared to the virgin hair fibers. See FIGS. 6-8.

Example 4. Inventive Compositions

[0042] Shampoo

TABLE-US-00002 Supplier INCI Name Trade Name Qty % W/W N/A Water/Aqua/Eau Water, DI 46.4350000 g  46.4350000% Lubrizol Acrylates/C10-30 Alkyl Carbopol Ultrez 0.5000000 g 0.5000000% Acrylate Crosspolymer 21 Polymer Innospec Trisodium Ethylenedi- Natrlquest E- 0.5000000 g 0.5000000% amine Disuccinate, 30 Water/Aqua/Eau Innospec Sodium Lauroyl Methyl Iselux 7.1580000 g 7.1580000% Isethionate, Sodium Methyl Isethionate, Sodium Laurate, Lactic Acid Innospec Water/Aqua/Eau, Sodium Pureact WS 9.2850000 g 9.2850000% Methyl Cocoyl Taurate, Conc Coconut Fatty Acid, Sodium Chloride, Sodium Methyltaurate CLARIANT Water/Aqua/Eau, GlucoTain 2.0000000 g 2.0000000% CORPORATION Sunfloweroyl Sense Methylglucamide AJINOMOTO Water/Aqua/Eau, Disodium Amilite ET- 6.0000000 g 6.0000000% Cocoyl Glutamate, Sodium CS-12 Cocoyl Glutamate ,Sodium Cocoyl Threoninate COLONIAL Water/Aqua/Eau, ColaTeric 8.9740000 g 8.9740000% CHEMICAL, INC. Babassuamidopropyl BBS Hydroxysultaine Stepan Glyceryl Caprylate/ Stepan-Mild 1.0000000 g 1.0000000% Caprate, Glycerin GCC Symrise Hydroxyacetophenone SymSave H 0.5000000 g 0.5000000% #672096 GATTEFOSSE Jojoba Esters (and) Definicire 1.0000000 g 1.0000000% Helianthus Annuus (Sunflower) Seed Wax (and) Polylgycerin-3 Dewolf Chemical, Inc. Cetearyl Alcohol Lanette O 2.5250000 g 2.5250000% Koster Keunen Cetyl Stearate Kester Wax 2.0000000 g 2.0000000% K-56 Aak PEG-75 Shea Butter Lipex 102 0.5000000 g 0.5000000% Glycerides E-75 100% PREMIER Rosmarinus Officinalis Premox R- 0.1000000 g 0.1000000% SPECIALTIES INC (Rosemary) Leaf Extract, 3204 Helianthus Annuus (Sunflower) Seed Oil Evonik Bis-(Isostearoyl/Oleoyl Varisoft EQ 0.2500000 g 0.2500000% Isopropyl) Dimonium 100 Methosulfate Lubrizol PPG-20 Methyl Glucose Glucam P-20 0.5000000 g 0.5000000% Ether Distearate Distearate Emollient CLARIANT Lauryl/Myristyl Genadvance 0.5000000 g 0.5000000% CORPORATION Polyricinoleate, Glycerin Hydra Dsm Nutritional Potassium Cetyl Phosphate Amphisol K 0.5000000 g 0.5000000% Products Llc Lincoln Fine Propanediol LinPure 1.0000000 g 1.0000000% Ingredients Lubrizol PEG-120 Methyl Glucose Glucamate 0.5000000 g 0.5000000% Trioleate, Water/Aqua/ VLT Eau, Propanediol Ashland Specialty Hydroxypropyl Benecel E4M 0.1000000 g 0.1000000% Ingredients G.P. Methylcellulose ChiBio Biotech Chitosan Water Soluble 0.0500000 g 0.0500000% Mushroom Chitosan USP Water/Aqua/Eau (and) Sodium 1.0000000 g 1.0000000% Sodium Hydroxide Hydroxide 10% Lubrizol Polyquaternium-47, Merquat 2001 0.6000000 g 0.6000000% Water/Aqua/Eau, Sodium N Polymer Benzoate Lubrizol Polyquaternium-22, Merquat 295 0.2130000 g 0.2130000% Water/Aqua/Eau COLONIAL Water/Aqua/Eau, Sodium ColaLipid GS 2.0000000 g 2.0000000% CHEMICAL, INC. Grapeseed Amidopropyl PG-Dimonium Chloride Phosphate DKSH NORTH Water/Aqua/Eau, MG-60 2.0000000 g 2.0000000% AMERICA INC Maltooligosyl Glucoside, Hydrogenated Starch Hydrolysate BIOSIL Water/Aqua/Eau, Methiopeptide 0.0100000 g 0.0100000% TECHNOLOGIES, INC. Methylthiopropylamido Acetyl Methionine, Methylpropanediol Schulke Ethylhexylglycerin Sensiva SC 50 0.2500000 g 0.2500000% Sozio Inc Fragrance (Parfum) SZUS030844 0.8000000 g 0.8000000% Living Proof Octafluoropentyl AN101 0.5000000 g 0.5000000% Methacrylate (OFPMA) USP Water/Aqua/Eau (and) Sodium 0.7500000 g 0.7500000% Hydroxide 10% Total 100.000000 g  100.00%

[0043] Conditioner

TABLE-US-00003 Trade Supplier INCI Name Name Qty % W/W N/A Water/Aqua/Eau Water, DI 71.4680000 g  71.4680000% Ashland Specialty Hydroxyethylcellulose, Natrosol 0.2500000 g 0.2500000% Ingredients G.P. Disodium Phosphate, Sodium 250 HR CS Phosphate, Polysorbate 60 Ashland Specialty Guar Hydroxypropyltrimonium N-Hance 3000 0.3500000 g 0.3500000% Ingredients G.P. Chloride, Water/Aqua/Eau RITA Chemical Lactic Acid Ritalac LA 0.1500000 g 0.1500000% Corporation Symrise Hydroxyacetophenone SymSave H 0.2500000 g 0.2500000% #672096 COLONIAL Water/Aqua/Eau, Sodium ColaLipid GS 1.2500000 g 1.2500000% CHEMICAL, INC. Grapeseed Amidopropyl PG- Dimonium Chloride Phosphate Dewolf Chemical, Inc. Cetearyl Alcohol Lanette O 6.7050000 g 6.7050000% Croda Behentrimonium Chloride, Incroquat 1.6670000 g 1.6670000% Isopropyl Alcohol Behenyl TMC- 85-PA-(MH) Koster Keunen Cetyl Stearate Kester Wax K-56 0.6500000 g 0.6500000% Aak PEG-75 Shea Butter Lipex 102 E-75 0.5000000 g 0.5000000% Glycerides 100% GATTEFOSSE Jojoba Esters (and) Definicire 2.0000000 g 2.0000000% Helianthus Annuus (Sunflower) Seed Wax (and) Polylgycerin-3 Croda Hydroxyethyl Crodamine SC- 0.7500000 g 0.7500000% Diethylenetriamine SS-(MH) Dioleamide/Palmitamide PREMIER Butyrospermum Parkii Shea Butter 2.0000000 g 2.0000000% SPECIALTIES INC (Shea) Butter #421580 PREMIER Rosmarinus Officinalis Premox R-3204 0.1000000 g 0.1000000% SPECIALTIES INC (Rosemary) Leaf Extract, Helianthus Annuus (Sunflower) Seed Oil Alzo Linoleamidopropyl Necon LO-80 0.5000000 g 0.5000000% International Inc. Dimethylamine Dimer Dilinoleate Evonik Bis-(Isostearoyl/Oleoyl Varisoft EQ 100 0.7500000 g 0.7500000% Isopropyl) Dimonium Methosulfate Solvay Fluorides Llc Glyceryl Triacetyl Mackaderm AR 33 1.0000000 g 1.0000000% Hydroxy stearate CLARIANT CORPORATION Lauryl/Myristyl Genadvance Hydra 1.0000000 g 1.0000000% Polyricinoleate, Glycerin Centerchem Squalane Neossance Squalane 1.0000000 g 1.0000000% SEPPIC INC C21-28 Alkane Emosmart C28 2.0000000 g 2.0000000% Lincoln Fine Propanediol LinPure 1.5000000 g 1.5000000% Ingredients Ashland Specialty Hydroxypropyl Benecel K200M 0.2000000 g 0.2000000% Ingredients G.P. Methylcellulose ChiBio Biotech Chitosan Water Soluble 0.1000000 g 0.1000000% Mushroom Chitosan Vertellus Cetylpyridinium Chloride, Freshstat CPC-PG 0.7500000 g 0.7500000% Propylene Glycol BIOSIL Water/Aqua/Eau, Methiopeptide 0.0100000 g 0.0100000% TECHNOLOGIES, INC. Methylthiopropylamido Acetyl Methionine, Methylpropanediol AJINOMOTO Water/Aqua/Eau, Sodium Ajidew NL-50 0.2500000 g 0.2500000% PCA Sozio Inc Fragrance (Parfum) SZUS030844 0.8000000 g 0.8000000% Living Proof Octafluoropentyl AN101 2.0000000 g 2.0000000% Methacrylate (OFPMA) RITA Chemical Lactic Acid Ritalac LA 0.0500000 g 0.0500000% Total 100.000000 g  100.0

[0044] Strengthening of hair products are frequently quantified as a reduction in fiber breakage during repeated grooming experiment. Twenty dark-brown European hair tresses measuring 10 inches in length and 5 grams by weight were bleached. Ten of the bleached hair swatches were washed before use using a sink with controlled flow and temperature (4 L/min at 35° C.). Hair was washed with a 14% aqueous solution of sodium laureth sulfate (SLES). The remaining ten hair swatches were treated by applying a 15% dosage by weight of the hair swatch (i.e. 0.75 g per 5 g swatch) of the shampoo, massaging through the hair, then rinsing using a sink with controlled flow and temperature as described above. The conditioner was subsequently applied using the same technique. Both the control and treated swatches were dried and allowed to equilibrate overnight at 22° C./60% relative humidity.

[0045] The dried swatches were loaded into a Lifecycle Rig set to one pass of the comb per second. See FIG. 9. Collection plates are position under each swatch to save the broken fiber fragments. Swatches were repeatedly brushed up to a total of 10,000 brush strokes. The quantity of broken fibers was recorded after 200, 600, 1,000, 2,000, 5,000, and 10,000 passes.

[0046] The inventive Shampoo and Conditioner demonstrate a significant reduction in fiber breakage compared to the swatches treated with the control. See FIG. 10.

Example 5. Additional Inventive Compositions

[0047] Coily Styler

TABLE-US-00004 Supplier INCI Name Trade Name Qty % W/W N/A Water/Aqua/Eau Water, DI 71.7850000 g  71.7850000% ChiBio Biotech Chitosan Water Soluble 0.2000000 g 0.2000000% Mushroom Chitosan Lincoln Fine Propanediol LinPure 3.0000000 g 3.0000000% Ingredients Ashland Specialty Hydroxyethylcellulose, Natrosol 250 0.7500000 g 0.7500000% Ingredients G.P. Disodium Phosphate, Sodium HR CS Phosphate, Polysorbate 60 Ashland Specialty Guar Hydroxypropyltrimonium N-Hance 0.2000000 g 0.2000000% Ingredients G.P. Chloride, Acrylamidopropyl- 4572 trimonium Chloride/Acrylamide Copoplymer RITA Chemical Lactic Acid Ritalac LA 0.0500000 g 0.0500000% Corporation Croda Quaternium-91, PPG-3 Crodazosoft 1.5000000 g 1.5000000% Benzyl Ether Myristate SCQ-PA-(MH) Croda Behentrimonium Chloride, Incroquat Behenyl 2.0000000 g 2.0000000% Isopropyl Alcohol TMC-85-PA-(MH) COLONIAL CHEMICAL, Water/Aqua/Eau, Sodium ColaLipid GS 1.0000000 g 1.0000000% INC. Grapeseed Amidopropyl PG- Dimonium Chloride Phosphate Alzo Linoleamidopropyl Necon LO-80 0.0800000 g 0.0800000% International Inc. Dimethylamine Dimer Dilinoleate AJINOMOTO PCA Ethyl Cocoyl CAE 0.2000000 g 0.2000000% Arginate AJINOMOTO Phytosteryl/Octyldodecyl Eldew PS-203R 0.2000000 g 0.2000000% SOLABIA USA Behenyl/Stearyl Rep'Hair 0.3750000 g 0.3750000% INC Aminopropanediol Esters Croda Hydroxyethyl Crodamine 0.5000000 g 0.5000000% Diethylenetriamine Dioleamide/ SC-SS-(MH) Palmitamide Dewolf Myristyl Alcohol Lanette 14 2.5000000 g 2.5000000% Chemical, Inc. Dewolf Cetearyl Alcohol Lanette 0 2.0000000 g 2.0000000% Chemical, Inc. GATTEFOSSE Jojoba Esters (and) Definicire 1.6000000 g 1.6000000% Helianthus Annuus (Sunflower) Seed Wax (and) Polylgycerin-3 PREMIER Butyrospermum Parkii Shea Butter #421580 1.6000000 g 1.6000000% SPECIALTIES INC (Shea) Butter Centerchem Squalane Neossance Squalane 2.6000000 g 2.6000000% JEEN INTERNATIONAL Ethylhexyl Stearate Jeechem OS 2.2500000 g 2.2500000% Inolex Chemical Propylene Glycol LexFeel Shine 2.0000000 g 2.0000000% Company Dibenzoate Ashland Specialty Hydroxypropyl Benecel K35M 0.4000000 g 0.4000000% Ingredients G.P. Methylcellulose Living Proof Octafluoropentyl AN101 2.0000000 g 2.0000000% Methacrylate (OFPMA) Sozio Inc Fragrance (Parfum) SZUS030844 1.0000000 g 1.0000000% BIOSIL Water/Aqua/Eau, Methiopeptide 0.0100000 g 0.0100000% TECHNOLOGIES, INC. Methylthiopropylamido Acetyl Methionine, Methylpropanediol RITA Chemical Lactic Acid Ritalac LA 0.2000000 g 0.2000000% Corporation Total 100.000000 g  100.00%

[0048] Curly Styler

TABLE-US-00005 Supplier INCI Name Trade Name Qty % W/W N/A Water/Aqua/Eau Water, DI 59.1850000 g  59.1850000% ChiBio Biotech Chitosan Water Soluble 0.2000000 g 0.2000000% Mushroom Chitosan Lincoln Fine Propanediol LinPure 1.3250000 g 1.3250000% Ingredients Ashland Specialty Guar Hydroxypropyltrimonium N-Hance 4572 0.1500000 g 0.1500000% Ingredients G.P. Chloride, Acrylamidopropyl- trimonium Chloride/Acrylamide Copoplymer Ashland Specialty Hydroxyethylcellulose, Natrosol 250 0.3500000 g 0.3500000% Ingredients G.P. Disodium Phosphate, Sodium HR CS Phosphate, Polysorbate 60 N/A Water/Aqua/Eau Water, DI 20.0000000 g  20.0000000% Ashland Specialty Water/Eau/Aqua, VP/DMAPA Styleze 5.0000000 g 5.0000000% Ingredients G.P. Acrylates Copolymer CC-10 Dewolf Chemical, Inc. Myristyl Alcohol Lanette 14 2.3000000 g 2.3000000% Dewolf Chemical, Inc. Cetyl Alcohol Lanette 16 1.5000000 g 1.5000000% Croda Water/Eau/Aqua, Cetrimonium Incroquat CTC- 1.5380000 g 1.5380000% Chloride 30-LQ-(MH) Vantage Specialty Ricinoleamidopropyl Lipoquat R 0.2000000 g 0.2000000% Ingredients Inc Ethyldimonium Ethosulfate COLONIAL CHEMICAL, Water/Aqua/Eau, Sodium ColaLipid 0.2500000 g 0.2500000% INC. Grapeseed Amidopropyl PG- GS Dimonium Chloride Phosphate AJINOMOTO PCA Ethyl Cocoyl Arginate CAE 0.2000000 g 0.2000000% GATTEFOSSE Jojoba Esters (and) Definicire 0.5000000 g 0.5000000% Helianthus Annuus (Sunflower) Seed Wax (and) Polylgycerin-3 SOLABIA USA INC Behenyl/Stearyl Aminopropanediol Rep'Hair 0.1500000 g 0.1500000% Esters PREMIER Butyrospermum Parkii Shea Butter 0.5000000 g 0.5000000% SPECIALTIES INC (Shea) Butter #421580 Ashland Specialty DimethylPABAmidopropyl Laurdimonium Escalol HP 0.0300000 g 0.0300000% Ingredients G.P. Tosylate Inolex Chemical Brassica Alcohol, Brassicyl AminoSensyl HC 1.3670000 g 1.3670000% Company Valinate Esylate GATTEFOSSE Glyceryl Behenate Compritol 888 0.0600000 g 0.0600000% Croda Steareth-21 SP Brij S721 0.0500000 g 0.0500000% MBAL- SO-(AP) Inolex Chemical Propylene Glycol Dibenzoate LexFeel Shine 1.1000000 g 1.1000000% Company Centerchem Squalane Neossance 0.5000000 g 0.5000000% Squalane JEEN INTERNATIONAL Ethylhexyl Stearate Jeechem OS 0.5000000 g 0.5000000% Living Proof Octafluoropentyl Methacrylate AN101 1.2500000 g 1.2500000% (OFPMA) SEPPIC INC C13-15 Alkane Emosmart L15 0.3500000 g 0.3500000% Croda Polyamide-8 SP OleocraftLP- 0.2250000 g 0.2250000% 20-MBAL - PA-(MV) Ashland Specialty Hydroxypropyl Methylcellulose Benecel E10M 0.1000000 g 0.1000000% Ingredients G.P. Ashland Specialty Hydroxypropyl Methylcellulose Benecel K35M 0.3000000 g 0.3000000% Ingredients G.P. BIOSIL Water/Aqua/Eau, Methiopeptide 0.0100000 g 0.0100000% TECHNOLOGIES, INC. Methylthiopropylamido Acetyl Methionine, Methylpropanediol Sozio Inc Fragrance (Parfum) SZUS030844 0.8000000 g 0.8000000% USP Citric Acid Citric Acid 0.0100000 g 0.0100000% Total 100.000000 g  100.00%

[0049] Wavy Styler

TABLE-US-00006 Supplier INCI Name Trade Name Qty % W/W N/A Water/Aqua/Eau Water, DI 86.2680000 g  86.2680000% ChiBio Biotech Chitosan Water Soluble 0.3750000 g 0.3750000% Mushroom Chitosan Symrise Pentylene Glycol Hydrolite-5 0.7650000 g 0.7650000% Ashland Specialty Hydroxyethylcellulose, Disodium Natrosol 250 0.3000000 g 0.3000000% Ingredients G.P. Phosphate, Sodium Phosphate, HR CS Polysorbate 60 Dewolf Chemical, Inc. Myristyl Alcohol Lanette 14 2.0000000 g 2.0000000% Dewolf Chemical, Inc. Cetyl Alcohol Lanette 16 0.5000000 g 0.5000000% Croda Water/Eau/Aqua, Cetrimonium Incroquat CTC- 1.5000000 g 1.5000000% Chloride 30-LQ-(MH) Croda Cetearyl Alcohol, Behentrimonium SP Incroquat Behenyl 0.6000000 g 0.6000000% Chloride TMC-25-MBAL-PA-(MH) AJINOMOTO PCA Ethyl Cocoyl Arginate CAE 0.2000000 g 0.2000000% GATTEFOSSE Jojoba Esters (and) Definicire 0.0200000 g 0.0200000% Helianthus Annuus (Sunflower) Seed Wax (and) Polylgycerin-3 SOLABIA USA INC Behenyl/Stearyl Aminopropanediol Rep'Hair 0.0570000 g 0.0570000% Esters Ashland Specialty DimethylPABAmidopropyl Escalol HP 0.0250000 g 0.0250000% Ingredients G.P. Laurdimonium Tosylate GATTEFOSSE Glyceryl Behenate Compritol 888 0.1000000 g 0.1000000% Croda Steareth-2 SP Brij S2 0.1500000 g 0.1500000% MBAL-SO-(AP) Croda Steareth-21 SP Brij S721 0.1500000 g 0.1500000% MBAL-SO-(AP) Inolex Chemical Propylene Glycol Dibenzoate LexFeel Shine 1.6000000 g 1.6000000% Company Living Proof Octafluoropentyl Methacrylate AN101 0.5000000 g 0.5000000% (OFPMA) SEPPIC INC C13-15 Alkane Emosmart L15 0.4590000 g 0.4590000% Croda Polyamide-8 SP Oleocraft LP- 0.1000000 g 0.1000000% 20-MBAL-PA-(MV) Ashland Specialty Hydroxypropyl Methylcellulose Benecel E10M 0.1000000 g 0.1000000% Ingredients G.P. Ashland Specialty Hydroxypropyl Methylcellulose Benecel K200M 0.3000000 g 0.3000000% Ingredients G.P. Sozio Inc Fragrance (Parfum) SZUS030844 0.3200000 g 0.3200000% BIOSIL Water/Aqua/Eau, Methiopeptide 0.0100000 g 0.0100000% TECHNOLOGIES, INC. Methylthiopropylamido Acetyl Methionine, Methylpropanediol Akzo Nobel Water/Aqua/Eau, Maltodextrin/ BioStyle CGP 1.0000000 g 1.0000000% VP Copolymer, Maltodextrin, PVP, 1-vinyl-2-pyrrolidone, Phenoxyethanol, Ethylhexylglycerin Croda Water, Polyquaternium-72 Mirustyle CP-LQ-(WD) 2.6000000 g 2.6000000% USP Citric Acid Citric Acid 0.0010000 g 0.0010000% Total 100.000000 g  100.00%

[0050] Unless otherwise defined, all technical and scientific terms used herein are accorded the meaning commonly known to one with ordinary skill in the art.