METHOD OF FABRICATING STRETCHABLE ELECTRONIC DEVICE, STRETCHABLE ELECTRONIC DEVICE, AND STRETCHABLE DISPLAY APPARATUS
20230093498 · 2023-03-23
Assignee
- Chengdu Boe Optoelectronics Technology Co., Ltd. (Chengdu, CN)
- Boe Technology Group Co., Ltd. (Beijing, CN)
Inventors
Cpc classification
H01L27/1218
ELECTRICITY
H01L27/1262
ELECTRICITY
B32B38/10
PERFORMING OPERATIONS; TRANSPORTING
B32B37/144
PERFORMING OPERATIONS; TRANSPORTING
B32B2457/20
PERFORMING OPERATIONS; TRANSPORTING
G09F9/301
PHYSICS
B32B27/30
PERFORMING OPERATIONS; TRANSPORTING
B32B38/0008
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B37/14
PERFORMING OPERATIONS; TRANSPORTING
B32B27/30
PERFORMING OPERATIONS; TRANSPORTING
B32B38/00
PERFORMING OPERATIONS; TRANSPORTING
B32B38/10
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A stretchable electronic device is provided. The stretchable electronic device includes a stretchable elastomer polymer base substrate; a plurality of electronic devices; and a plurality of recesses partially extending into the stretchable elastomer polymer base substrate. The stretchable elastomer polymer base substrate includes a plurality of stiffened portions respectively in a plurality of stiffened regions spaced apart by one or more elastomeric portions in one or more elastomeric regions. A respective electronic device of the plurality of electronic devices is at least partially in a respective recess of the plurality of recesses, and is in a respective stiffened region of the plurality of stiffened regions. The respective electronic device in the respective recess is stacked on a respective stiffened portion of the plurality of stiffened portions.
Claims
1. A stretchable electronic device, comprising: a stretchable elastomer polymer base substrate; a plurality of electronic devices; and a plurality of recesses partially extending into the stretchable elastomer polymer base substrate; and wherein the stretchable elastomer polymer base substrate comprises a plurality of stiffened portions respectively in a plurality of stiffened regions spaced apart by one or more elastomeric portions in one or more elastomeric regions; a respective electronic device of the plurality of electronic devices is at least partially in a respective recess of the plurality of recesses, and is in a respective stiffened region of the plurality of stiffened regions; and the respective electronic device in the respective recess is stacked on a respective stiffened portion of the plurality of stiffened portions.
2. The stretchable electronic device of claim 1, further comprising an encapsulating layer at least partially in the plurality of recesses and on a side of the plurality of electronic devices away from the stretchable elastomer polymer base substrate; wherein the stretchable electronic device in the respective stiffened region comprises a stacked structure comprising the respective stiffened portion, the respective electronic device, and a portion of the encapsulating layer encapsulating the respective electronic device.
3. The stretchable electronic device of claim 2, wherein the encapsulating layer is at least partially absent in the one or more elastomeric regions. The stretchable electronic device of claim 1, wherein the stretchable elastomer polymer base substrate in the one or more elastomeric regions comprises a polydimethylsiloxane-based material; and the stretchable elastomer polymer base substrate in the plurality of stiffened regions comprises silicon oxide (SiO.sub.x).
4. The stretchable electronic device of claim 1, further comprising a passivation layer on the stretchable elastomer polymer base substrate; wherein the passivation layer is at least partially in the one or more elastomeric regions, and at least partially absent in the plurality of stiffened regions.
5. The stretchable electronic device of claim 1, further comprising a plurality of stretchable signal lines passing through the one or more elastomeric regions thereby connecting adjacent electronic devices of the plurality of electronic devices.
6. The stretchable electronic device of claim 5, wherein each of the plurality of stretchable signal lines has a zig-zag pattern in the one or more elastomeric regions.
7. A stretchable display apparatus, comprising the stretchable electronic device of claim 1.
8. A method of fabricating a stretchable substrate for electronic device, comprising: forming an elastomer polymer layer on a base substrate; forming a plurality of recesses partially extending into the elastomer polymer layer; subsequent to forming the plurality of recesses, selectively stiffening the elastomer polymer layer in a plurality of defined regions of the elastomer polymer layer corresponding to the plurality of recesses, thereby forming a modified elastomer polymer layer comprising a plurality of stiffened portions respectively in a plurality of stiffened regions spaced apart by one or more elastomeric portions in one or more elastomeric regions, the plurality of stiffened portions having a Young's modulus greater than a Young's modulus of the one or more elastomeric portions; separating the modified elastomer polymer layer from the base substrate; stretching the modified elastomer polymer layer to form a stretched modified elastomer polymer layer; and transferring the stretched modified elastomer polymer layer to an intermediate base substrate.
9. The method of claim 8, wherein selectively stiffening the elastomer polymer layer comprises exposing the elastomer polymer layer in a plurality of exposure regions with an ultraviolet light in an oxygen-containing atmosphere using a mask plate.
10. The method of claim 8, wherein the elastomer polymer layer comprises a polydimethylsiloxane-based material; the modified elastomer polymer layer in the one or more elastomeric regions comprises the polydimethylsiloxane-based material; and the modified elastomer polymer layer in the plurality of stiffened regions comprises silicon oxide (SiO.sub.x).
11. A stretchable substrate for electronic device, comprising a stretchable elastomer polymer base substrate having a plurality of stiffened portions respectively in a plurality of stiffened regions spaced apart by one or more elastomeric portions in one or more elastomeric regions; wherein the stretchable substrate comprises a plurality of recesses partially extending into the stretchable elastomer polymer base substrate.
12. The stretchable substrate of claim 11, wherein the stretchable elastomer polymer base substrate in the one or more elastomeric regions comprises a polydimethylsiloxane-based material; and the stretchable elastomer polymer base substrate in the plurality of stiffened regions comprises silicon oxide (SiO.sub.x).
Description
BRIEF DESCRIPTION OF THE FIGURES
[0049] The following drawings are merely examples for illustrative purposes according to various disclosed embodiments and are not intended to limit the scope of the present invention.
[0050]
[0051]
[0052]
[0053]
[0054]
DETAILED DESCRIPTION
[0055] The disclosure will now be described more specifically with reference to the following embodiments. It is to be noted that the following descriptions of some embodiments are presented herein for purpose of illustration and description only. It is not intended to be exhaustive or to be limited to the precise form disclosed.
[0056] The present disclosure provides, inter alia, a method of fabricating a stretchable electronic device, a stretchable electronic device, and a stretchable display apparatus that substantially obviate one or more of the problems due to limitations and disadvantages of the related art. In one aspect, the present disclosure provides a method of fabricating a stretchable electronic device. In some embodiments, the method includes forming an elastomer polymer layer on a base substrate; selectively stiffening the elastomer polymer layer in a plurality of defined regions of the elastomer polymer layer, thereby forming a modified elastomer polymer layer including a plurality of stiffened portions respectively in a plurality of stiffened regions spaced apart by one or more elastomeric portions in one or more elastomeric regions, the plurality of stiffened portions having a Young's modulus greater than a Young's modulus of the one or more elastomeric portions; and forming a plurality of electronic devices respectively in the plurality of stiffened regions, each of the plurality of electronic devices formed on a side of one of the plurality of stiffened portions distal to the base substrate.
[0057] As used herein, the term “stretchable” refers to the ability of a material, structure, device or device component to be strained in tension (e.g., being made longer and/or wider) without undergoing permanent deformation or failure such as fracture, e.g., the ability to elongate at least 10% of its length without permanently deforming, tearing, or breaking. The term is also meant to encompass substrates having components (whether or not the components themselves are individually stretchable as stated above) that are configured in such a way so as to accommodate a stretchable, inflatable, or expandable surface and remain functional when applied to a stretchable, inflatable, or otherwise expandable surface that is stretched, inflated, or otherwise expanded respectively. The term is also meant to encompass substrates that may be elastically and/or plastically deformable (i.e. after being stretched, the substrate may return to its original size when the stretching force is released or the substrate may not return to its original size and in some examples, may remain in the stretched form) and the deformation (i.e. stretching and optionally flexing) may occur during manufacture of the substrate (e.g. with the substrate being stretched and optionally flexed to form its final shape), during assembly of a device incorporating the substrate (which may be considered part of the manufacturing operation) and/or during use (e.g. with the user being able to stretch and optionally flex the substrate).
[0058]
[0059] Referring to
[0060] Referring to
[0061] Various appropriate stiffening methods may be used for selectively stiffening the elastomer polymer layer 30. Examples of appropriate stiffening methods include chemical stiffening, stiffening by irradiation (e.g., stiffening by radiation-induced cross-linking, stiffening by radiation-induced decomposition), mechanical stiffening, physical stiffening (e.g., freeze-drying, heating), and other stiffening methods.
[0062] Various appropriate elastomer polymer materials may be used for making the elastomer polymer layer 30. Examples of appropriate elastomer polymers include polyimides, polysilicones, polysiloxanes, polyepoxides, silicone-based polymers (e.g., polydimethylsiloxane-based materials such as polydimethylsiloxane, hexamethyldisiloxane, and polyphenylmethylsiloxane), polyurethane-based materials (such as polyurethane, polyurethane acrylate, polyether urethane, and polycarbonate-polyurethane elastomers), polyvinylfluoride, polyvinylchloride, acrylate polymer, acrylate terpolymer, rubbers (e.g., chloroprene rubber, acryl-based rubber, and nitrile rubber), polyvinylpyrrolidone, polyvinyl alcohol, polymethyl methacrylate, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, polymethyl acrylate, polyvinyl acetate, polyacrylonitrile, polyfurfuryl alcohol, polystyrene, polyethylene oxide, polypropylene oxide, polycarbonate, polyvinyl chloride, polycaprolactone, and any combination thereof.
[0063] Optionally, the elastomer polymer layer includes a polydimethylsiloxane-based material. The stiffening step is performed by ultraviolet light irradiation in an oxygen-containing atmosphere. The stiffening step partially degrades the polydimethylsiloxane-based material into SiO.sub.x.
[0064] Referring to
[0065] Optionally, the one or more elastomeric portions 30e have a Young's modulus in a range of approximately 0.001 GPa to approximately 0.5 GPa, e.g., approximately 0.001 GPa to approximately 0.05 GPa, approximately 0.05 GPa to approximately 0.1 GPa, approximately 0.1 GPa to approximately 0.2 GPa, approximately 0.2 GPa to approximately 0.3 GPa, approximately 0.3 GPa to approximately 0.4 GPa, and approximately 0.4 GPa to approximately 0.5 GPa. Optionally, the one or more elastomeric portions 30e have a Young's modulus in a range of approximately 0.5 GPa to approximately 1.5 GPa, e.g., approximately 0.5 GPa to approximately 1.0 GPa and approximately 1.0 GPa to approximately 1.5 GPa.
[0066] Optionally, the plurality of stiffened portions 30s have a Young's modulus greater than 2.0 GPa, e.g., in a range of approximately 2.0 GPa to approximately 20 GPa, e.g., approximately 2.0 GPa to approximately 4.0 GPa, approximately 4.0 GPa to approximately 6.0 GPa, approximately 6.0 GPa to approximately 8.0 GPa, approximately 8.0 GPa to approximately 10 GPa, approximately 10 GPa to approximately 12.5 GPa, approximately 12.5 GPa to approximately 15 GPa, approximately 15 GPa to approximately 17.5 GPa, and approximately 17.5 GPa to approximately 20 GPa. Optionally, the plurality of stiffened portions 30s have a Young's modulus greater than 20 GPa, e.g., greater than 40 GPa, greater than 60 GPa, greater than 80 GPa, greater than 100 GPa, greater than 150 GPa, greater than 200 GPa, greater than 300 GPa, greater than 400 GPa, greater than 500 GPa, greater than 600 GPa, greater than 700 GPa, greater than 800 GPa, greater than 900 GPa, and greater than 1000 GPa.
[0067] Referring to
[0068] Referring to
[0069] Referring to
[0070] Referring to
[0071]
[0072] Referring to
[0073] Referring to
[0074] Referring to
[0075] Referring to
[0076] Referring to
[0077] Referring to
[0078] Referring to
[0079] Referring to
[0080] Referring to
[0081] Referring to
[0082]
[0083] Referring to
[0084] Referring to
[0085] Referring to
[0086] Referring to
[0087] Referring to
[0088]
[0089] Referring to
[0090]
[0091] In some embodiments, the method further includes forming a plurality of organic light emitting diodes in the plurality of stiffened regions.
[0092] In another aspect, the present disclosure provides a stretchable electronic device fabricated by the method described herein.
[0093] In another aspect, the present disclosure provides a stretchable electronic device. In some embodiments, and referring to
[0094] Optionally, and referring to
[0095] Optionally, and referring to
[0096] Optionally, and referring to
[0097] Optionally, and referring to
[0098] In another aspect, the present disclosure provides a stretchable display apparatus having a stretchable electronic device described herein or fabricated by a method described herein. Examples of appropriate stretchable display apparatuses include, but are not limited to, an electronic paper, a mobile phone, a tablet computer, a television, a monitor, a notebook computer, a digital album, a GPS, etc.
[0099] In another aspect, the present disclosure provides a method of fabricating a stretchable substrate for electronic device. In some embodiments, the method includes forming an elastomer polymer layer on a base substrate; and selectively stiffening the elastomer polymer layer in a plurality of defined regions of the elastomer polymer layer, thereby forming a modified elastomer polymer layer comprising a plurality of stiffened portions respectively in a plurality of stiffened regions spaced apart by one or more elastomeric portions in one or more elastomeric regions. The plurality of stiffened portions having a Young's modulus greater than a Young's modulus of the one or more elastomeric portions.
[0100] Optionally, prior to forming the elastomer polymer layer, the method further includes forming a sacrificial material layer on the base substrate; and forming a plurality of first recesses in the sacrificial material layer thereby forming a sacrificial layer. Optionally, the plurality of first recesses respectively correspond to the plurality of defined regions.
[0101] Optionally, the method further includes removing the sacrificial layer thereby separating the modified elastomer polymer layer from the base substrate.
[0102] Optionally, prior to selectively stiffening the elastomer polymer layer, the method further includes forming a plurality of second recesses partially extending into the elastomer polymer layer. Optionally, the plurality of second recesses respectively correspond to the plurality of defined regions. Optionally, selectively stiffening the elastomer polymer layer includes stiffening an elastomer polymer material in regions corresponding to the plurality of second recesses.
[0103] Optionally, the method further includes separating the modified elastomer polymer layer from the base substrate; and stretching the modified elastomer polymer layer to form a stretched modified elastomer polymer layer.
[0104] Optionally, the method further includes transferring the stretched modified elastomer polymer layer to an intermediate base substrate.
[0105] Optionally, selectively stiffening the elastomer polymer layer includes exposing the elastomer polymer layer in a plurality of exposure regions with an ultraviolet light in an oxygen-containing atmosphere using a mask plate.
[0106] Optionally, the elastomer polymer layer includes a polydimethylsiloxane-based material. Optionally, the modified elastomer polymer layer in the one or more elastomeric regions includes the polydimethylsiloxane-based material. Optionally, the modified elastomer polymer layer in the plurality of stiffened regions comprises silicon oxide (SiO.sub.x).
[0107] In another aspect, the present disclosure provides a stretchable substrate for electronic device fabricated by the method described herein.
[0108] In another aspect, the present disclosure provides a stretchable substrate for electronic device. The stretchable substrate includes a stretchable elastomer polymer base substrate having a plurality of stiffened portions respectively in a plurality of stiffened regions spaced apart by one or more elastomeric portions in one or more elastomeric regions.
[0109] Optionally, the stretchable elastomer polymer base substrate in the one or more elastomeric regions includes a polydimethylsiloxane-based material. Optionally, the stretchable elastomer polymer base substrate in the plurality of stiffened regions comprises silicon oxide (SiO.sub.x).
[0110] In another aspect, the present disclosure provides a stretchable display apparatus having the stretchable substrate described herein or fabricated by a method described herein. Examples of appropriate stretchable display apparatuses include, but are not limited to, an electronic paper, a mobile phone, a tablet computer, a television, a monitor, a notebook computer, a digital album, a GPS, etc.
[0111] The foregoing description of the embodiments of the invention has been presented for purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form or to exemplary embodiments disclosed. Accordingly, the foregoing description should be regarded as illustrative rather than restrictive. Obviously, many modifications and variations will be apparent to practitioners skilled in this art. The embodiments are chosen and described in order to explain the principles of the invention and its best mode practical application, thereby to enable persons skilled in the art to understand the invention for various embodiments and with various modifications as are suited to the particular use or implementation contemplated. It is intended that the scope of the invention be defined by the claims appended hereto and their equivalents in which all terms are meant in their broadest reasonable sense unless otherwise indicated. Therefore, the term “the invention”, “the present invention” or the like does not necessarily limit the claim scope to a specific embodiment, and the reference to exemplary embodiments of the invention does not imply a limitation on the invention, and no such limitation is to be inferred. The invention is limited only by the spirit and scope of the appended claims. Moreover, these claims may refer to use “first”, “second”, etc. following with noun or element. Such terms should be understood as a nomenclature and should not be construed as giving the limitation on the number of the elements modified by such nomenclature unless specific number has been given. Any advantages and benefits described may not apply to all embodiments of the invention. It should be appreciated that variations may be made in the embodiments described by persons skilled in the art without departing from the scope of the present invention as defined by the following claims. Moreover, no element and component in the present disclosure is intended to be dedicated to the public regardless of whether the element or component is explicitly recited in the following claims.