Multiple steady state liquid crystal display panels

Abstract

The present application provides a multiple steady state LCD panel, in which a side of a first substrate close to a liquid crystal layer has a first plane electrode and spaced several horizontal electrodes disposed thereon, a side of a second substrate close to the liquid crystal layer has a second plane electrode disposed thereon; the liquid crystal layer includes plural positive liquid crystal molecules and bipolar low molecular weight alignment molecules; thus, to adopt PI materials for the horizontal or perpendicular alignment of the liquid crystal molecules is not needed for the present application. By adjusting one or two of the voltage applied to the first plane electrode and the second plane electrode and the voltage applied to any two of the horizontal electrodes, the positive liquid crystal molecules are arranged at a specific angle under an alignment action of the bipolar low molecular weight alignment molecules.

Claims

1. A multiple steady state liquid crystal display (LCD) panel, comprising a first substrate, a second substrate disposed opposite to the first substrate, a liquid crystal layer interposed between the first substrate and the second substrate, a first plane electrode covering the first substrate on a side of first substrate close to the liquid crystal layer, an insulation layer covering the first plane electrode, several horizontal electrodes spaced and disposed on the insulation layer, and a second plane electrode covering the second substrate on a side of the second substrate close to the liquid crystal layer; wherein the liquid crystal layer includes plural positive liquid crystal molecules and bipolar low molecular weight alignment molecules, a structural formula of the bipolar low molecular weight alignment molecules is ##STR00005## by adjusting a voltage applied to the first plane electrode and the second plane electrode and/or a voltage applied to any two of the horizontal electrodes, the positive liquid crystal molecules are arranged at a specific angle under an alignment action of the bipolar low molecular weight alignment molecules, after the applied voltage is removed, the positive liquid crystal molecules can still keep at the specific angle, so as to achieve a multiple steady state display.

2. The multiple steady state liquid crystal display (LCD) panel according to claim 1, wherein the bipolar low molecular weight alignment molecules account for 0.02%5% by weight of the liquid crystal layer.

3. The multiple steady state liquid crystal display (LCD) panel according to claim 1, wherein a material of the insulation layer is silicon nitride, silicon oxide or a combination thereof.

4. The multiple steady state liquid crystal display (LCD) panel according to claim 1, wherein materials of the first plane electrode, the second plane electrode, and the several horizontal electrodes are indium tin oxide (ITO).

5. The multiple steady state liquid crystal display (LCD) panel according to claim 1, wherein one of the first substrate and the second substrate is a thin-film transistor (TFT) substrate, the other one is a color filter (CF) substrate.

6. The multiple steady state liquid crystal display (LCD) panel according to claim 1, wherein an amount of the horizontal electrodes is two.

7. A multiple steady state liquid crystal display (LCD) panel, comprising a first substrate, a second substrate disposed opposite to the first substrate, a liquid crystal layer interposed between the first substrate and the second substrate, a first plane electrode covering the first substrate on a side of first substrate close to the liquid crystal layer, an insulation layer covering the first plane electrode, several horizontal electrodes spaced and disposed on the insulation layer, and a second plane electrode covering the second substrate on a side of the second substrate close to the liquid crystal layer; wherein the liquid crystal layer includes plural positive liquid crystal molecules and bipolar low molecular weight alignment molecules, a structural formula of the bipolar low molecular weight alignment molecules is ##STR00006## by adjusting a voltage applied to the first plane electrode and the second plane electrode and/or a voltage applied to any two of the horizontal electrodes, the positive liquid crystal molecules are arranged at a specific angle under an alignment action of the bipolar low molecular weight alignment molecules, after the applied voltage is removed, the positive liquid crystal molecules can still keep at the specific angle, so as to achieve a multiple steady state display; wherein a material of the insulation layer is silicon nitride, silicon oxide or a combination thereof; wherein materials of the first plane electrode, the second plane electrode, and the several horizontal electrodes are indium tin oxide (ITO); wherein one of the first substrate and the second substrate is a thin-film transistor (TFT) substrate, the other one is a color filter (CF) substrate.

8. The multiple steady state liquid crystal display (LCD) panel according to claim 7, wherein the bipolar low molecular weight alignment molecules account for 0.02%5% by weight of the liquid crystal layer.

9. The multiple steady state liquid crystal display (LCD) panel according to claim 7, wherein an amount of the horizontal electrodes is two.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The above objects and advantages of the present invention will become more readily apparent to those ordinarily skilled in the art after reviewing the following detailed description and accompanying drawings, in which:

(2) FIG. 1 is a three-dimensional structure view schematically illustrating the multiple steady state LCD panel of the present application;

(3) FIG. 2 is a cross-sectional view schematically illustrating the multiple steady state LCD panel when a voltage is applied to the two plane electrodes; and

(4) FIG. 3 is a cross-sectional view schematically illustrating the multiple steady state LCD panel when a voltage is applied to the horizontal electrodes.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

(5) The present invention will now be described more specifically with reference to the following embodiments.

(6) Please refer to FIG. 1, the present application provides a multiple steady state LCD panel including a first substrate 10, a second substrate 20 disposed opposite to the first substrate 10, a liquid crystal layer 30 interposed between the first substrate 10 and the second substrate 20, a first plane electrode 11 covering the first substrate 10 on a side of the first substrate 10 close to the liquid crystal layer 30, an insulation layer 12 covering the first plane electrode 11, several horizontal electrodes 13 spaced and disposed on the insulation layer 12, and a second plane electrode 21 covering the second substrate 20 on a side of the second substrate 20 close to the liquid crystal layer 30.

(7) A body part of the liquid crystal layer 30 is plural positive liquid crystal molecules 31, and the liquid crystal layer 30 further includes a certain percentage of bipolar low molecular weight alignment molecules 32. A molecular weight of the bipolar low molecular weight alignment molecules 32 is in a range of 100-1000; further, a structural formula of the bipolar low molecular weight alignment molecules 32 is

(8) ##STR00002##
wherein H is a benzene ring structure; L1, L2, L3 are benzene rings or saturated six-membered ring structures; h.sub.1 and h.sub.2 are substituent groups connected to H of benzene rings; m is a number of h.sub.1 or h.sub.2 ranging in 02; h.sub.1 is a substituent including a polymerizable group, the polymerizable group can be selected from substituted or unsubstituted methacrylate-yl, acrylate-yl, epoxy, vinyl, ethyleneoxy, ethynyl and butadienyl; h.sub.2 is a polarity group containing heteroatom group(s), a number of the heteroatom group(s) is in 14 and selected from one or more than one of following groups: OH, SH, NH.sub.2, O, S, NHR, NH, NR.sub.2, NR, ; (a) is a substituent group respectively connected to L1, L2, or L3; n is a number of (a) ranging in 04; (a) is selected from H, F, Cl, Br, CN, and one of linear or branched alkyl including 110 carbon atom(s); T is a tail end group; the tail end group is a molecular chain including 125 carbon atom(s).

(9) For example, one structural formula of the bipolar low molecular weight alignment molecules 32 is

(10) ##STR00003##
another one structural formula thereof is

(11) ##STR00004##
One of the first substrate 10 and the second substrate 20 is the TFT substrate, the other one is the CF substrate. The specific structures of the TFT substrate and the CF substrate are current technique without further description herein.

(12) A material of the insulation layer 12 is silicon nitride (SiNx), silicon oxide or a combination thereof.

(13) Materials of the first plane electrode 11, the second plane electrode 21, and the several horizontal electrodes 13 are indium tin oxide (ITO).

(14) The several horizontal electrodes 13 are arranged in comb shape, an amount of the horizontal electrodes 13 as shown in FIG. 1 is two; certainly, the amount of the horizontal electrodes 13 can be more.

(15) As shown in FIG. 1, it is particularly noted that the LCD panel of the present application does not need to adopt the PI materials for the horizontal or perpendicular alignment of the liquid crystal molecules; that is, there is not an alignment film made of polyimide (PI) coated on inner sides of the two substrates and contacting the liquid crystal layer; the bipolar low molecular weight alignment molecules 32 have strong binding force both to the first substrate 10 and the second substrate 20, and are capable of arranging the positive liquid crystal molecules 31 according to directions perpendicular to the surfaces of the first substrate 10 and the second substrate 20. The ability of the bipolar low molecular weight alignment molecules 32 allowing the positive liquid crystal molecules 31 in the perpendicular arrangement is related to the content thereof in the liquid crystal layer 30, the content thereof is more, the ability of aligning the positive liquid crystal molecules 31 in the perpendicular arrangement is stronger. When the content of the bipolar low molecular weight alignment molecules 32 in the liquid crystal layer 30 is in a certain range, that can allow the alignment condition of the positive liquid crystal molecules 31 being in the critical state that has neither strong perpendicular alignment nor strong horizontal alignment, the final arrangement condition thereof is extremely easily affected by external electric field; once the applied voltage is removed, the positive liquid crystal molecules 31 tend to not change and maintain the original alignment state in the condition of neither electric field effect nor extremely strong aligning force. Due to a variety of the bipolar low molecular weight alignment molecules 32, and aligning force, molecular eight and the like thereof are different, the content of the bipolar low molecular weight alignment molecules 32, that allow the alignment condition of positive liquid crystal molecules 31 being in the aforesaid critical state, in the liquid crystal layer 30 is not fixed; in general, the content of the bipolar low molecular weight alignment molecules 32 accounted for the liquid crystal layer is 0.02%-5% by weight, most preferably 0.1%-2% by weight.

(16) On the LCD panel of the present application displaying, by adjusting one or two of the voltage applied to the first plane electrode and the second plane electrode and the voltage applied to any two of the horizontal electrodes, the positive liquid crystal molecules are arranged at the specific angle under the alignment action of the bipolar low molecular weight alignment molecules. After the applied voltage was removed, the positive liquid crystal molecules can still keep the alignment state when the voltage applied thereon, so as to achieve the multiple steady state display.

(17) As shown in FIG. 2, when only a strong enough voltage is applied to the first plane electrode 11 and the second plane electrode 21 to form a vertical electric field, rotations of the positive liquid crystal molecules 31 along the direction of vertical electric field occur under the alignment action of the bipolar low molecular weight alignment molecules 32, and then the positive liquid crystal molecules 31 are arranged perpendicular to the surfaces of the first substrate 10 and the second substrate 20. After that, even the applied voltage between the first plane electrode 11 and the second plane electrode 21 is removed; the positive liquid crystal molecules 31 can still keep the state of being arranged perpendicular to the surfaces of the first substrate 10 and the second substrate 20 when the voltage was applied thereto.

(18) As shown in FIG. 3, when only a strong enough voltage is applied to any two of the horizontal electrodes 13 to form a horizontal electric field, rotations of the positive liquid crystal molecules 31 along the direction of horizontal electric field occur under the alignment action of the bipolar low molecular weight alignment molecules 32, and then the positive liquid crystal molecules 31 are arranged parallel to the surfaces of the first substrate 10 and the second substrate 20. After that, even the applied voltage between the two horizontal electrodes is removed; the positive liquid crystal molecules 31 can still keep the state of being arranged parallel to the surfaces of the first substrate 10 and the second substrate 20 when the voltage was applied thereto.

(19) The above two conditions as shown in FIG. 2 and FIG. 3 are more extreme, if adjusting the magnitude of voltage applied to the first plane electrode 11 and the second plane electrode 21, or adjusting the magnitude of voltage applied to any two of the horizontal electrodes 13, or simultaneously adjusting the magnitude of voltage applied to the first plane electrode 11 and the second plane electrode 21 and the magnitude of voltage applied to the two horizontal electrodes 13 is performed, then the positive liquid crystal molecules can be arranged at an inclined angle relative to the surfaces of the first substrate 10 and second substrate 20 under the alignment action of the bipolar low molecular weight alignment molecules. After that, even the applied voltage is removed, the positive liquid crystal molecules 31 can still keep the inclined alignment state when the voltage was applied thereto, so as to achieve the multiple steady state display that no longer requires continuously supplying voltage at a time of no need to change display data (i.e. static picture), and thus the energy consumption is reduced and the battery life of mobile display equipment is increased.

(20) In summary, the multiple steady state LCD panel of the present application in which the side of the first substrate close to the liquid crystal layer has the first plane electrode and the spaced several horizontal electrodes disposed thereon, the side of second substrate close to the liquid crystal layer has the second plane electrode disposed thereon; the liquid crystal layer includes the plural positive liquid crystal molecules and the bipolar low molecular weight alignment molecules; thus, to adopt the PI materials for the horizontal or perpendicular alignment of the liquid crystal molecules is not needed for the present application. By controlling the content of the bipolar low molecular weight alignment molecules in the liquid crystal layer to allow the alignment condition being in the critical state that has neither strong perpendicular alignment nor strong horizontal alignment, the arrangement condition thereof is extremely easily affected by external electric field. By adjusting one or two of the voltage applied to the first plane electrode and the second plane electrode and the voltage applied to any two of the horizontal electrodes, the positive liquid crystal molecules are arranged at the specific angle under the alignment action of the bipolar low molecular weight alignment molecules. After the applied voltage was removed, the positive liquid crystal molecules can still keep the state when the voltage was applied thereto, so as to achieve the multiple steady state display that the LCD panel does not require continuously supplying electricity at displaying a static picture, and thus the energy consumption is reduced and the battery life of mobile display equipment is increased.

(21) While the invention has been described in terms of what is presently considered to be the most practical and preferred embodiments, it is to be understood that the invention needs not be limited to the disclosed embodiment. On the contrary, it is intended to cover various modifications and similar arrangements included within the spirit and scope of the appended claims which are to be accorded with the broadest interpretation so as to encompass all such modifications and similar structures.