Mid-IR microchip laser: ZnS:Cr2+ laser with saturable absorber material
09887510 ยท 2018-02-06
Assignee
Inventors
Cpc classification
H01S3/1055
ELECTRICITY
C30B31/00
CHEMISTRY; METALLURGY
Y10S438/917
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01S3/0617
ELECTRICITY
C30B31/02
CHEMISTRY; METALLURGY
H01S3/09415
ELECTRICITY
C30B29/48
CHEMISTRY; METALLURGY
C30B29/48
CHEMISTRY; METALLURGY
C30B31/00
CHEMISTRY; METALLURGY
H01S3/108
ELECTRICITY
International classification
H01S3/08
ELECTRICITY
C30B31/00
CHEMISTRY; METALLURGY
C30B31/02
CHEMISTRY; METALLURGY
H01S3/1055
ELECTRICITY
Abstract
A method of fabrication of laser gain material and utilization of such media includes the steps of introducing a transitional metal, preferably Cr.sup.2+ thin film of controllable thickness on the ZnS crystal facets after crystal growth by means of pulse laser deposition or plasma sputtering, thermal annealing of the crystals for effective thermal diffusion of the dopant into the crystal volume with a temperature and exposition time providing the highest concentration of the dopant in the volume without degrading laser performance due to scattering and concentration quenching, and formation of a microchip laser either by means of direct deposition of mirrors on flat and parallel polished facets of a thin Cr:ZnS wafer or by relying on the internal reflectance of such facets.
Claims
1. An integrated optical chip comprising: a II-VI substrate comprising: a fiber connection section operable to: connect with fiber lasers or fiber coupled diode lasers; and receive pump radiation from the connected fiber lasers or fiber coupled diode lasers, a plurality of etched V-grooves disposed in the fiber connection section and operable to provide spatially separate channels for the connected fiber lasers or the fiber coupled diode lasers; an active section comprising a plurality of transition metal doped binary II-VI waveguides configured to generate output radiation, wherein the transition metals are selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, and Cu; and waveguides to deliver the received pump radiation from the spatially separate channels to the active section.
2. The integrated optical chip of claim 1, wherein the active section further comprises a dispersive element.
3. The integrated optical chip of claim 2, wherein the dispersive element comprises a tapered grating.
4. The integrated optical chip of claim 1, comprising: a Mach-Zehnder or electro-reflection internal modulator integrated with the active section.
5. The integrated optical chip of claim 1, wherein the II-VI substrate comprises ZnSe semiconductor material or ZnS semiconductor material or both.
6. The integrated optical chip of claim 1, wherein the plurality of transition metal doped waveguides comprise II-VI semiconductor material.
7. The integrated optical chip of claim 1, wherein the plurality of transition metal doped waveguides are doped with TM.sup.2+.
8. A laser transmitter comprising: a pump radiation source; a II-VI substrate, integrated on an optical chip, the II-VI substrate comprising: a fiber connection section operable to: connect with fiber lasers or fiber coupled diode lasers; and receive pump radiation from the connected fiber lasers or fiber coupled diode lasers; and a plurality of etched V-grooves disposed in the fiber connection section and operable to provide spatially separate channels for the fiber lasers or the fiber coupled diode lasers; an active section comprising a plurality of transition metal doped binary II-VI waveguides configured to generate output radiation, wherein the transition metals are selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, and Cu; and waveguides configured to deliver the received pump radiation from the spatially separate channels to the active section.
9. The laser transmitter of claim 8, further comprising an active gain medium, integrated as part of the II-VI substrate, the active gain medium comprising a plurality of transition metal doped waveguides configured to generate output radiation, each channel representing a corresponding wavelength.
10. The laser transmitter of claim 9, further comprising one of an acousto-optic modulator or an electro-optic modulator integrated as part of the active gain medium.
11. The laser transmitter of claim 9, further comprising a pump focusing system to focus the radiation generated by the pump radiation source towards the active gain medium.
12. The laser transmitter of claim 9, wherein the active gain medium comprises chromium doped ZnS crystals or chromium doped ZnSe crystals or both.
13. The laser transmitter of claim 9 wherein the output radiation is in the range from approximately 1850 to 2700 nm.
14. The laser transmitter of claim 8, wherein the pump radiation source comprises an array of diode stripes or a fiber bunch.
15. The laser transmitter of claim 8, wherein the laser transmitter is a laser module that is reprogrammable to operate in one of a monochromatic, ultrabroadband or multiline regime of operation.
16. The laser transmitter of claim 8, wherein the plurality of transition metal doped waveguides comprise material doped with TM.sup.2+ and the output radiation is in the range from approximately 1850 to 2700 nm.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The herein described features of the present invention, as well as others which will become apparent, are attained and can be understood in more detail by reference to the following description and appended drawings, which form a part of this specification. It is to be noted, however, that the appended drawings illustrate only exemplary embodiments of the invention and therefore not be considered limiting of its scope, for the invention may admit other equally effective embodiments.
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DESCRIPTION OF THE PREFERRED EMBODIMENT
(21) In the preferred embodiment, the Cr.sup.2:ZnS crystals are prepared by a three-stage method according to a flow chart depicted in
(22) At the second stage and third stages, introduction of chromium (or other transitional metal) into the crystalline host is performed by thermal diffusion (third stage) from a then film deposited, preferably, by the pulse laser deposition method (second stage). Plasma spluttering or other thin-film deposition methods could also be sued. Thermal annealing can be carried out in sealed ampoules under a pressure of, preferably, approximately 10.sup.5 torr and temperature of approximately 830 to approximately 1100 C. over 3 to 20 days. In some cases to provide more effective thermo-diffusion it was performed under simultaneous action of electric field of 1-30 kV/cm magnitude with positive terminal being applied to Cr film and negativeto the Ag electrode deposited on the opposite surface of the wafer. Polished samples of 1-3 mm thickness and up to 5 mm aperture can then be produced.
(23) The room-temperature absorption and fluorescence spectra of the studied Cr.sup.2+:ZnS and Cr.sup.2+:ZnSe crystals are given in cross section units in
(24) The luminescence kinetics of the crystals were measured at 1950, 2100, 2400, and 2600 nm across a broad temperature range using D.sub.2 and H.sub.2 Raman-shifted Nd:YAG laser excitation at 1560 and 1907 nm. Within the 0.4 s accuracy of measurements there was no difference in the lifetime of luminescence for different wavelengths of excitation and registration.
(25) The spontaneous-emission cross-sections .sub.em() (
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where A is the spontaneous emission probability from the upper laser level, and n is the index of refraction.
(27) To derive the absorption cross-section magnitude from the absorption spectrum, one needs to know the Cr.sup.2+ concentration. Unfortunately, the absolute dopant concentration is neither uniform nor accurately known in the case of diffusion doping. We therefore used the reciprocity method for the broadband transition:
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(29) in conjunction with measured absorption spectra to calculate the absorption cross-section in
(30) Similar graphs of room temperature absorption and emission spectra of Cr.sup.2+:CdS(A) and Cr.sup.2+:CdSe(C) crystals prepared according to the invention, measured at 300K, and plotted in cross-sectional units, and corresponding emission lifetime temperature dependences (B, D) are displayed in
(31) One of the important potential applications of TM:II_-VI crystals is the passive Q-switching of the resonators of solid state lasers (e.g. Cr.sup.2+:ZnS crystals for passive Q-switching of Er:glass lasers). Experiments on saturation of Cr.sup.2+:ZnS absorption were performed under 1.56 m excitation. The radiation of a D.sub.2-Raman-shifted YAG:Nd laser with a pulse duration of 5 ns and pulse energy of up to 20 mJ and repetition rate of 10 Hz was used. Saturation experiments utilized a 2.5 mm thick Cr.sup.2:ZnS crystal with initial transmission of T=0.43 at 1.56 m. The pump radiation was focused on the sample by a 26.5 cm lens and the dependence of the crystal transmission as a function of pumping energy density was measured by means of the sample Z-scanning. Spatial energy distributions of the pump radiation were determined by a standard knife-edge method. The effective radius of the pumping beam was measured at the 0.5 level of maximum pump intensity of radiation.
(32) As one can see from
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(34) where z=W.sub.ab, T.sub.o crystal transition at W=0, and .sub.abs-absorption cross section (cm.sup.2). Equation (3) was solved numerically, and from the best fit to the experimental results (
(35) The Cr.sup.2+ concentration in the crystal was 3.510.sup.18 cm.sup.3. This satisfactory agreement of .sub.abs values determined from spectroscopic and saturation measurements indicates negligible excited state absorption losses for Cr.sup.2+:ZnS at 1.56 m and the wavelength of Er:glass laser oscillation (1.54 m). Hence, Cr.sup.2+:ZnS crystals feature a relatively high cross section of absorption 0.710.sup.18 cm.sup.2 at 1.56 m compared with 710.sup.21 cm.sup.2 for Er:glass. This value is practically two times larger than 0.2710.sup.18 cm.sup.2 cross section value for Cr.sup.2+:ZnSe known in the prior art and in conjunction with negligible excited state absorption losses reveal possible application of Cr.sup.2+:ZnS crystals as a promising saturable absorber for resonators of Er:glass lasers. In addition to this it is advantageous to utilize for solid state laser Q switching and mode-locking Cr.sup.2+:ZnS crystals with dichroic mirrors deposited on their faces. These mirrors are supposed to be transparent at the wavelength of solid state laser (e.g. Er-glass laser) oscillation and reflective in the region of Cr.sup.2+:ZnS lasing. In this coupled cavity configuration Cr.sup.2+:ZnS element will serve simultaneously as passive Q-switch or mode-locker, as a load for solid state laser, and as an active element. Due to stimulated processes in Cr.sup.2+:ZnS one can expect that the effective time of depopulation of Cr.sup.2+:ZnS excited levels will be much faster than for regular arrangement without coupled cavity. It will result in a shorter pulsed duration in a Q-switch regime and even possibility of mode-locked operation.
(36) A block-diagram of experimental nonselective hemispherical cavity used for Cr.sup.2+:ZnS gain switched lasing is depicted in
(37) Room temperature laser operation was realized with a threshold of 170 J and slope efficiency of 9.5% with respect to the pump energy when output coupler R.sub.2.360 m=90% was utilized. The laser had an output linewidth of approximately 90 nm (FWHM), centered at 2.24 m and maximum output energy reached 100 J. A graph of output-input energies of Cr.sup.2+:ZnS gain switched laser in hemispherical cavity is depicted in
(38) With the R.sub.2.360 m=80% mirror laser operation was obtained with a threshold of 250 J. This allowed a Findlay-Clay calculation of the losses within the cavity.sup.29. With the crystal length of 1.7 mm and .sub.abs=0.810.sup.18 cm.sup.2 the losses in the cavity were calculated to be 14.7%. It is felt that this can also be improved by the optimization of the crystal preparation techniques.
(39) In the wavelength tuning experiment, depicted in
(40) The pump source was operating at 1.5607 m with the pulse energy of about 600 J and 5 ns pulse duration in a TEM.sub.00 mode. This pump energy was about three times larger than the threshold pump energy level. The Cr.sup.2+:ZnS laser output was directed through a CaF.sub.2 lens to a 0.3 m SpectraPro monochromator with a PbS detector for wavelength measurements.
(41) The output of the chromium laser oscillation had a linewidth of approximately 30 nm (FWHM). The peak efficiency of the tunable output was centered at 2.25 m. The tuning limits were due to coatings of the cavity optics and not the emission spectrum of Cr.sup.2+:ZnS crystal. The use of proper broadband coatings could potentially increase the tuning range to 1.85-2.7 m.
(42) The laser output linewidth could be further narrowed by means of a Littrow or Littman configured grating tuned cavity.
(43) A block diagram of experimental set-up for Cr.sup.2+:ZnS CW lasing under Er fiber laser excitation in external hemispherical cavity is depicted in
(44) The minimum threshold values were measured to be 100 mW and 200 mW of absorbed pump power for output couplers with 2% and 20% transmission, respectively. An output power of 63 mW near 2370 nm at an absorbed pump power of 0.6 W was demonstrated with an output coupler with 2% transmission for maximum output power adjustment. The maximum slope efficiency with respect to the absorbed pump power was 18% in this experiment. The round trip passive losses L.sub.d in the cavity were estimated to be of 3.7% from the Findley-Clay analysis. The limiting slope efficiency of studied crystal was estimated to be 51% from a Caird analysis of inverse slope efficiency versus inverse output coupling using equation
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where is the slope efficiency, .sub.0 is the limiting slope efficiency, and T is the mirror transmission. This value is close to the quantum defect of 65% for the studied crystal.
(46) A block diagram of Cr.sup.2+:ZnS and Cr.sup.2+:ZnSe gain switched microchip lasers with no mirrors deposited on the crystal facets is depicted in
(47) A block diagram of experimental set-up for Cr.sup.2+:ZnS and Cr.sup.2+:ZnSe CW lasing under Er fiber laser excitation in microchip configuration is displayed in
(48) In a focused pump beam arrangement a laser threshold of 120 mW and a slope efficiency of 53% with respect to the absorbed pump power were realized for Cr.sup.2+:ZnS microchip laser. High, close to theoretical limit of 65%, slope efficiency of the microchip laser indicates a good quality of the used crystal. The maximum output power of optimized Cr.sup.2+:ZnS microchip laser reached 150 mW as demonstrated in
(49) In the case of ZnSe microchip lasing in a focused pump beam arrangement a laser threshold of 190 mW and a slope efficiency of 20% with respect to the absorbed pump power were demonstrated. The maximum output power reached 100 mW.
(50) For the second pump arrangement, when the microchip lasers were directly coupled to the fiber tip laser thresholds of 150 mW and 240 mW and slope efficiencies of 36 and 14% with respect to the absorbed pump power were realized for Cr.sup.2+:ZnS and Cr.sup.2+:ZnSe microchip lasers, respectively. The maximum output power of the Cr.sup.2+:ZnS microchip laser was practically unchanged while it dropped for Cr.sup.2+:ZnSe by a factor of 1.6 in comparison to the focused pump arrangement. This can be explained by the excessive length and corresponding mismatch in the mode size and pump beam profile of the ZnSe microchip.
(51) The output spectrum in free-running laser operation covered the spectrum range from 2280 to 2360 and from 2480 to 2590 for ZnS and ZnSe microchip lasers, respectively. At maximum pump power the output spectrum of the Cr.sup.2+:ZnSe laser consisted of more than 100 axial modes with a free spectral range =0.8 cm.sup.1. The typical output spectra of the microchip lasers are depicted in the A traces of
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(53) The proposed approach of superbroadband/multiwavelength (SBML) system is based on spatial separation of different wavelengths in a single laser cavity. In that regard the teachings of U.S. Pat. Nos. 5,461,635 and 6,236,666 are incorporated herein by reference. The basic optical scheme of the laser transmitter is shown in
(54) The laser operates as follows. Emission from the spatially separated channels of the active medium passes through the intracavity lens into the off-axis mode suppression element, aperture A, which together with the spatially filtered pump radiation divides active zone of the gain waveguide into a number of channels and separates from the amplified emission of individual channel only part of it that is spread parallel to the resonator axis. This separated radiation is diffracted on the diffraction grating. The Littrow mount grating works as a retroreflector in the auto-collimating regime in the first order of diffraction and returns part of radiation back to the aperture. The off-axis mode suppression element, aperture, in turn extracts from the diffracted radiation only the radiation of the main laser modes. Secondary laser modes, which diverge from the optical axes, are expelled from the process of generation. Hence, the aperture should simultaneously select the fundamental transverse modes for all existing channels in the cavity. The radiation of the main laser modes, each with a distinct wavelength, is collimated by the focusing lens and directed back to the active medium. As
(55) There are different schemes that can provide single longitudinal mode operation of Ii-VI microchip laser coupled to external etalon cavity in combination with narrowband output coupler, fiber grating butt-coupling, external grating, hybridly coupled phase array demultiplexer, and waveguide grating mirror.
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(57) There are many other possible schemes of utilization of acousto-optic, electro-optic, photorefractive and birefringent properties of II-VI crystals in one integrated microchip system combining active medium, acousto- or electro-optic modulator, filter, other passive components of the cavity.
(58) While our invention has been disclosed in various forms, this disclosure is not to be construed as limiting the invention solely to these forms, rather the invention is limited solely by the breadth of the claims appended hereto.
BIBLIOGRAPHY
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