Coating method, surface layer structure, as well as applications
09887349 · 2018-02-06
Assignee
Inventors
Cpc classification
Y10T428/12389
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C23C14/024
CHEMISTRY; METALLURGY
Y10T428/24545
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H10N30/883
ELECTRICITY
Y10T428/24521
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02T50/60
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B15/01
PERFORMING OPERATIONS; TRANSPORTING
C23C4/01
CHEMISTRY; METALLURGY
C23C14/028
CHEMISTRY; METALLURGY
International classification
B05D5/00
PERFORMING OPERATIONS; TRANSPORTING
C23C4/01
CHEMISTRY; METALLURGY
C21D10/00
CHEMISTRY; METALLURGY
B29C43/20
PERFORMING OPERATIONS; TRANSPORTING
B32B15/01
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A coating method for producing a function layer on mechanically loaded components or surfaces includes providing or applying a first material layer of a first material or substrate matrix having a mechanical flexibility higher than that of a second material on a substrate constituting the component or the surface, respectively, structuring the first material layer such that the material layer surface of the first material layer, which is opposite to the substrate, obtains a three-dimensionally molded basic structure with projections and recesses, and coating the material layer surface of the first material layer with a second material layer of the second material in such a way that the second material layer adopts substantially the basic structure of the material layer surface with the projections and recesses. Also, surface layer structures can be produced by this method.
Claims
1. A coating method for producing a function layer on a substrate formed of a substrate material including one of a metal sheet and a fiber composite component, the substrate deforming in response to a force in a longitudinal direction of the substrate, and warping or twisting about the longitudinal direction in response to a torque impose on the substrate, the method comprising: providing a first material layer made of a first material with a mechanical flexibility higher than that of a second material at or on the substrate, such that the first material exhibits a resilient load in response to the deforming, warping and twisting of the substrate; structuring the first material layer so that the material layer surface of the first material layer is given a three-dimensionally moulded basic structure with projections and recesses; and coating the material layer surface of the first material layer with a second material layer made of the second material, such that the second material layer adopts substantially the basic structure of the material layer surface with the projections and recesses.
2. The coating method according to claim 1, wherein at least one of the following the substrate is formed of a substrate material selected from a group of materials including metal, ceramic, plastic and fibre fabric; the first material is selected from a group of materials including metal, plastic and ceramic; and the second material is selected from a group of materials including metal, plastic and ceramic.
3. The coating method according to claim 2, wherein the providing includes selecting the first material and the second material such that the second material has at least one of the following a higher modulus of elasticity than the first material, a higher hardness than the first material, a lower breaking elongation, reduction of area at break, and fracture toughness than the first material, and a lower dynamic strength than the first material.
4. The coating according to claim 2, further comprising providing or forming the first material layer both as first function layer for providing at least a first function or as a mold for formation of the second material layer; and forming the second material layer as second function layer for providing at least one second function.
5. The coating method according to claim 2, wherein the structuring of the first material layer includes at least one of the following: microscopic structuring of the first material layer by an energetic beam, a laser beam, an ion beam or an electron beam; thermal microscopic structuring by a heated counter-mould; and microscopic embossing the basic structure on the material layer surface.
6. The coating method according to claim 2, wherein the structuring of the first material layer includes at least one of the following: selecting the basic structure or the shape and the size dimensions of the basic structure in consideration of at least one of the following criteria: level of a load to be expected, type of a load to be expected, desired or predetermined deformation path, and influence from the environment on the component or the surface; and forming the basic structure with a period succession of recesses and projections.
7. The coating method according to claim 1, wherein the providing includes selecting the first material and the second material such that the second material has at least one of the following a higher modulus of elasticity than the first material, a higher hardness than the first material, a lower breaking elongation, reduction of area at break, and fracture toughness than the first material, and a lower dynamic strength than the first material.
8. The coating according to claim 7, further comprising providing or forming the first material layer both as first function layer for providing at least a first function or as a mold for formation of the second material layer; and forming the second material layer as second function layer for providing at least one second function.
9. The coating method according to claim 7, wherein the structuring of the first material layer includes at least one of the following: microscopic structuring of the first material layer by an energetic beam, a laser beam, an ion beam or an electron beam; thermal microscopic structuring by a heated counter-mould; and microscopic embossing the basic structure on the material layer surface.
10. The coating method according to claim 7, wherein the structuring of the first material layer includes at least one of the following: selecting the basic structure or the shape and the size dimensions of the basic structure in consideration of at least one of the following criteria: level of a load to be expected, type of a load to be expected, desired or predetermined deformation path, and influence from the environment on the component or the surface; and forming the basic structure with a period succession of recesses and projections.
11. The coating according to claim 1, further comprising providing or forming the first material layer both as first function layer for providing at least a first function or as a mold for formation of the second material layer; and forming the second material layer as second function layer for providing at least one second function.
12. The coating method according to claim 1, further comprising at least one of the following providing or forming the first material layer as at least one of the following an insulating layer for electric insulation, a protective layer for protection from moisture, and a resilient buffer layer for resilient balancing of relative displacements or relative movements between the second material layer and the substrate; and forming the second material layer as at least one of the following a protective layer for protection from chemical loads, a protective layer for protection from mechanical or physical loads, a protective layer for protection from thermal loads, an electrically conductive or electrically insulating function layer, and a field-influencing layer for influencing electromagnetic, electric or magnetic fields.
13. The coating method according to claim 1, wherein the structuring of the first material layer includes at least one of the following: microscopic structuring of the first material layer by an energetic beam, a laser beam, an ion beam or an electron beam; thermal microscopic structuring by a heated counter-mould; and microscopic embossing the basic structure on the material layer surface.
14. The coating method according to claim 1, wherein the structuring of the first material layer includes at least one of the following: selecting the basic structure or the shape and the size dimensions of the basic structure in consideration of at least one of the following criteria: level of a load to be expected, type of a load to be expected, desired or predetermined deformation path, and influence from the environment on the component or the surface; and forming the basic structure with a period succession of recesses and projections.
15. The coating method according to claim 1, wherein the first material has a thickness in a range of 1 m to 50 m; and the second material has a thickness in a range of 1 m to 10 m.
Description
DESCRIPTION OF THE DRAWINGS
(1) The invention will be explained in more details in the following, with reference to the enclosed drawings. In the drawings:
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DETAILED DESCRIPTION OF EMBODIMENTS
(16) In the following, first a fundamental principle of a conceivable embodiment of a coating method will be explained with reference to
(17)
(18)
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(20) As can be seen in
(21) In the illustrated embodiment, the basic structure has a wave-like configuration.
(22) In the illustrated embodiment, the basic structure is designed, for instance, with a periodic configuration providing constant distances x.sub.2 between two maximum projections 10 and with constant distances y.sub.2 between the respective maximum projections 10 and the lowest point of the recess 12 (seen in a direction of thickness d.sub.2). The basic structure 14 is provided with an equally constant radius r.sub.2 at the extreme points on the projections 10 and the recesses 12.
(23)
(24) As can be seen in
(25) For instance, Metal, ceramic, plastic or fibre fabric may be provided as substrate material of the substrate 1.
(26) A metal, plastic or ceramic with a mechanical deformability higher than that of the second material 6 of the second material layer 3 may be provided as the first material 5 of the first material layer 2, for instance.
(27) A metal, plastic or ceramic with a mechanical deformability lower than that of the first material 5 may be provided as the second material 6 of the second material layer 3, for instance.
(28) As can be seen in the steps of
(29) The first material layer 2 with the first material 5 serves as functional layer or function layere.g. as the first function: electrical insulation or moisture protectionand as mould for the second material layer 3 at the same time.
(30) The first material 5 should be so selected that the static or dynamic loadstraction/compression forces F and/or torques Msubject it to a merely resilient or only a slightly plastic load.
(31) The second material layer 3 is applied on the first material 5 of the first material layer 2 in such a waye.g. deposition from the gaseous phase, thermal spraying, cold-gas spraying or electroplating that it adopts essentially the basic structure 14 of the latter.
(32) Depending on the load level, the type of the load, the path of deformation and influences from the environment, a suitable structure on the first material layer 2 is selected with defined shape dimensions and size dimensionse.g. radius r.sub.2, distance x.sub.2, amplitude y.sub.2 and thickness d.sub.2.
(33) The second material layer 3 serves equally as functional layer of function layer. For example, this second material layer 3 is a protective layer providing protection from corrosive loads (e.g. moisture), from mechanical loads (e.g. scratches) or for reasons of a thermal function (e.g. amplified heat dissipation), an electrical function and/or an inductive function. For instance, different shielding measures may be provided for shielding from or of different fields (electric fields, magnetic fields, electromagnetic fields). It is also possible, however, to shape or influence fields in a targeted way.
(34) The second material 6 of the second material layer 3 is mechanically less flexible or robust, respectively, than the first material 5.
(35) For instance, the second material 6 has a higher modulus of elasticity, a higher hardness or a lower elongation at rupture than the first material 5.
(36) The specific geometric shapebasic structure 14is expedient so that this second material layer 3, of a correspondingly more robust/resistive nature, can also resist the static and/or dynamic load. This specific geometric shape is indirectly created by the structuring of the first material layer 2.
(37) For instance, the second material layer 2 is shaped like a bellows on account of the wave-like basic structure 14, and can correspondingly be compressed or stretched.
(38) The second material 6 may act like a spring, for instance, with an appropriate specific geometric formation, and with a defined deformation path, it covers a smaller area than a planar layer. Compared against the planar layer, the appropriate deformed material layer 3 behaves as a spring compared against a tension bar, in particular.
(39) With this general coating method as explained with reference to
(40) With a modification of the method explained with reference to
(41) In the following, special embodiments will be explained in more detail.
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(43) As is shown in
(44) According to
(45) In the method for the production of the surface layer structure 22 on the piezo ceramic 30, a laser structures the Parylene layer 32 on a piezo ceramic 30. Subsequently, an aluminium layer 34 is vapour-deposited. A dynamic load is induced via the actuator mechanism of the piezos.
(46) This surface layer structure 22 ensures a reliable application of the piezo ceramic 30 under rough environmental conditions such as humid salty air. The protective layermetal layer 34displays both very good fatigue strength and a lower thermal resistance at high environmental temperatures particularly with high dynamic demands on the actuator system.
(47) It has so far been common to provide piezo ceramic with an envelope in the form of a varnish layer in order to protect them from moisture. Such a varnish layer only delays, however, the diffusion process. It is merely possible to set the time up to the point by which the critical moisture/salt level at the ceramic surface is reached, via the thickness of the varnish layer. Hereby applies: the thicker the varnish layer, the less heat is dissipated. Emerging electric fields enforce a chemical reaction on the varnish surface, which may result in destruction of the varnish.
(48) In another common approach, the piezo ceramic (so-called stack) is encapsulated in a metal bellows with connexion plates. Even though such a solution provides very good protection from any influence from the outside, it is accompanied by a distinct increase of weight and high manufacturing costs.
(49) In the approach taken here, the piezo ceramic 30 is initially provided with a thin insulation layer 32 (e.g. Parylene, 15 m). In a further step, this insulation layer 32 is structured by means of a laser 4 or the like and subsequently a metal coatingmetal layer 34 (e.g. aluminium, 5 m)is applied. In order to avoid fatigue of a metal coating under high dynamic loads, it is a to expose the coating also to a bending load rather than to a traction load exclusively. The employed structure of the applied metal coating resembles the structure of a metal bellows that is subjected to a low load only even with a high mechanical deformation. The metal layer 34 hence remains permanently in good order and provides optimum protection from moisture.
(50) Prominent advantages of the surface layer structure 22 presented here are, for instance: a very small thickness of the protective layer 42 (formed of the layers 32, 34; roughly 20 m); an electric field is encapsulated to the outside so that electrolyses cannot occur; on account of the thinner layers 32, 34 a good heat dissipation is ensured; on account of the metal layer 34, a good heat distribution is achieved; there is no weight increase; the manufacturing process is very simple; the piezo ceramic 30 is protected from being touched; there are no restrictions in the integration of the piezo ceramic.
(51) The
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(56) For instance, the projections and recesses 16, 18 of the second material layer 3 may be designed in parallel, i.e. substantially orthogonal to the longitudinal central axis 38, as is shown in
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(59) Whereas
(60) As is shown in
(61) As is illustrated in
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(64) For the formation of this possible cable link 48, one operates in such a way that initially in the step shown in
(65) The coating method described her is particularly advantageous for the provision of an efficient protection from moisture and the provision of a protective layer with further functions for piezo ceramics, as is illustrated. However, the invention is not restricted to this application.
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(67) Then a thin layer of the second material layer 3 is applied on this appropriately structured primer layer 62. For example, here a hard varnish 64 (Top Coat) or a tungsten-carbide layer 66 (protection from erosion) is applied on the basic structure 14 so that the varnish 64 or the tungsten-carbide layer 66 will conform to the basic structure with projections 16 and recesses 18. A dynamic load is induced by cyclic heating/cooling of the metal sheet 60, which results in expansion of the metal sheet 60 or in its contraction. The second material layer 3, designed as varnish 64 or tungsten carbide layer 66, can easily follow these dynamic loads in the manner of a metal bellows, despite its higher hardness on account of the shaping by the basic structure 14.
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(71) The aerodynamic component 90 is an aerodynamic profile, for instance, which is deformable by means of actors not illustrated here, e.g. for the employment in aircraft as wing part or as part of a control surface or a rotor, or for application in power installations, for instance, e.g. wind or hydroelectric rotor wings or the like.
(72) The graphic in
(73) The metal layer 98 is applied here as the second material layer 3 on a laser-structured primer layer 99 (first material layer 2) in accordance with the coating method explained here. The flexibility of the structured primer layer 99 supports the deformability of the metal layer 98.
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(75) The surface 34 with a metallic structure enables the application of a colour coat 100 whose colour effect depends on the viewing angle (cf.
(76) With such optical effects, it is possible, for instance, to perform a sensor-less analysis of structures variable in terms of shape. This should be explained by the example of the wing leading edge 92 in
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