Method and arrangement for removing gaseous elementary mercury from a stream of gas
09884287 ยท 2018-02-06
Assignee
Inventors
Cpc classification
B01D2252/30
PERFORMING OPERATIONS; TRANSPORTING
B01D53/1493
PERFORMING OPERATIONS; TRANSPORTING
B01D2253/112
PERFORMING OPERATIONS; TRANSPORTING
B01D2257/602
PERFORMING OPERATIONS; TRANSPORTING
International classification
B01D53/64
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The invention relates to a method and to an arrangement for removing gaseous elementary mercury from a stream of gas and to an arrangement for carrying out the method. The arrangement comprises a first washing tower (2) for receiving a stream of gas, a second washing tower (6) for receiving a stream of once processed gas (5) from the first washing tower (2), and a third washing tower (9) for receiving a stream of twice processed gas (23) from the second washing tower (6) and configured for discharging a stream of cleaned gas (12).
Claims
1. A method for removing gaseous elementary mercury from a stream of gas, wherein the method comprises (i) feeding the stream of gas into a first washing tower, (ii) treating the stream of gas in the first washing tower with a first washing solution that circulates in a first closed system through the first washing tower and that contains mercury (II)-ions to form a stream of once processed gas of the stream of gas, (iii) feeding the stream of once processed gas from the first washing tower into a second washing tower, (iv) treating the stream of once processed gas in the second washing tower with a second washing solution circulating in a second closed system through the second washing tower and that contains a higher concentration of mercury (II)-ions than the first washing solution form a stream of twice processed gas of the stream of once processed gas, (v) feeding the stream of twice processed gas from the second washing tower into a third washing tower, (vi) treating the stream of twice processed gas in the third washing tower with a third washing solution circulating in a third closed system through the third washing tower and that contains a lower concentration of mercury (II)-ions than the first washing solution to form a stream of cleaned gas of the stream of twice processed gas, and (vii) discharging the stream of cleaned gas from the third washing tower.
2. The method according to claim 1, further comprising feeding additional washing solution containing mercury (II)-ions from a tank means into first washing solution circulating in the first closed system.
3. The method according to claim 1, further comprising removing calomel from the first washing solution circulating in the first closed system.
4. The method according to claim 1, further comprising feeding a part of the second washing solution circulating in the second closed system into first washing solution circulating in the first closed system to remove calomel from the second washing solution.
5. The method according to claim 1, further comprising feeding additional washing solution containing mercury (II)-ions from a tank means into second washing solution circulating in the second closed system.
6. The method according to claim 1, wherein the cleaned gas is brought to a filter for absorption of any remaining gaseous elementary mercury.
7. The method according to claim 1, further comprising removing mercury from the third washing solution circulating in the third closed system by means of an active filter.
8. The method according to claim 1, wherein the first washing solution has a mercury (II)-ion content that is between about 0.1 g/l and about 2 g/l.
9. The method according to claim 1, wherein the first washing solution additionally contains an amount of ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions, which said amount of ions is at least twice the amount of mercury (II)-ions.
10. The method according to claim 1, wherein the second washing solution has a mercury (II)-ion content that is more than about 3.0 g/l.
11. The method according to claim 1, wherein the second washing solution additionally contains an amount of ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions, which said amount of ions is at least twice the amount of mercury (II)-ions.
12. The method according to claim 1, wherein the third washing solution has a mercury (II)-ion content that is less than about 0.3 g/l.
13. The method according to claim 1, wherein the third washing solution additionally contains an amount of ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions, which said amount of ions is at least twice the amount of mercury (II)-ions.
14. An arrangement for removing gaseous elementary mercury from a stream of gas, wherein the arrangement comprises a first washing tower for receiving a stream of gas containing gaseous elementary mercury, wherein the first washing tower is configured for treating the stream of gas with a first washing solution that circulates in a first closed system through the first washing tower and that contains mercury (II) ions to form a stream of once processed gas of the stream of gas, a second washing tower for receiving a stream of once processed gas from the first washing tower, wherein the second washing tower is configured for treating the stream of once processed gas with a second washing solution circulating in a second closed system through the second washing tower and that contains a higher concentration of mercury (II)-ions than the first washing solution to form a stream of twice processed gas of the stream of once processed gas, a third washing tower for receiving a stream of twice processed gas from the second washing tower, wherein the third washing tower is configured for treating the stream of twice processed gas with a third washing solution circulating in a third closed system through the third washing tower and that contains a lower concentration of mercury (II)-ions than the first washing solution to form a stream of cleaned gas of the stream of twice processed gas, and wherein the third washing tower is configured for discharging a stream of cleaned gas from the third washing tower, and a filter for absorption of any remaining gaseous elementary mercury in the cleaned gas.
15. The arrangement according to claim 14, further comprising first feeding means for feeding additional washing solution containing mercury (II)-ions from a tank means into first washing solution circulating in the first closed system.
16. The arrangement according to claim 14, further comprising first removing means for removing calomel from the first washing solution circulating in the first closed system.
17. The arrangement according to claim 14, further comprising second feeding means for feeding a part of the second washing solution circulating in the second closed system into first washing solution circulating in the first closed system.
18. The arrangement according to claim 14, further comprising third feeding means for feeding additional washing solution containing mercury (II)-ions from a tank means into second washing solution circulating in the second closed system.
19. The arrangement according to claim 14, wherein the third closed system is provided with an active filter for removing mercury from the third washing solution circulating in the third closed system.
20. The arrangement according to claim 14, wherein the mercury (II)-ion content in the first washing solution is between about 0.1 g/l and about 2 g/l.
21. The arrangement according to claim 14, wherein the first washing solution additionally contains an amount of ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions, which said amount of ions is at least twice the amount of mercury (II)-ions.
22. The arrangement according to claim 14, wherein the mercury (II)-ion content in the second washing solution is more than about 3.0 g/l.
23. The arrangement according to claim 14, wherein the second washing solution additionally contains an amount of ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions, which said amount of ions is at least twice the amount of mercury (II)-ions.
24. The arrangement according to claim 14, wherein the mercury (II)-ion content in the third washing solution is less than about 0.3 g/l.
25. The arrangement according to claim 14, wherein the third washing solution additionally contains an amount of ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions, which said amount of ions is at least twice the amount of mercury (II)-ions.
Description
LIST OF FIGURES
(1) In the following the invention will described in more detail by referring to the figures, of which
(2)
(3)
(4)
(5)
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(7)
DETAILED DESCRIPTION OF THE INVENTION
(8) The figures show examples of methods and arrangements for removing gaseous elementary mercury from a stream of gas.
(9) First the method for removing gaseous elementary mercury (Hg.sup.0(g)) from a stream of gas and some preferred embodiment and variants of the method will be described in greater detail.
(10) The method comprises feeding the stream of gas 1 into a first washing tower 2.
(11) The method comprises treating the stream of gas 1 in the first washing tower 2 with a first washing solution 3 that circulates in a first closed system 4 through the first washing tower 2 and that contains mercury (II) ions and possible additionally at least twice this amount of ion or ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions to form a stream of once processed gas 5 of the stream of gas 1.
(12) In this first stage of the method that is performed in the first washing tower 2, the major part of the mercury vapor (Hg.sup.o) in the gas is removed. The mercury (II)-ion (Hg.sup.2) content in the first washing solution 3 may be decreased compared to a minimum often recommended level of about 1 to about 2 g/l, such as less than about 1.5 g/l, for the so-called Boliden-Norzink process but may be above a certain minimum level of about 0.1 to about 0.3 g/l, such as more than about 0.2 g/l. This will reduce the risk for formation of mercuric chloride (Hg.sub.2Cl.sub.2) mist or calomel mist in the gas.
(13) The main reaction in this first washing stage of the method that is performed in the first washing tower 2 is the following:
Hg.sup.0(g)+HgCl.sup.n.sub.(2+n)>Hg.sub.2Cl.sub.2(s)+nCl.sup., where 0n2
(14) The method comprises feeding a stream of once processed gas 5 from the first washing tower 2 into a second washing tower 6.
(15) The method comprises treating the stream of once processed gas 5 in the second washing tower 6 with a second washing solution 7 circulating in a second closed system 8 through the second washing tower 6 and that contains a higher concentration of mercury (II)-ions than the first washing solution 3, such as more than about 1 to about 2 g/l, such as more than about 1.5 g/l, of mercury (II)-ions, and possible additionally at least twice this amount of ion or ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions to form a stream of twice processed gas 23 of the stream of once processed gas 5.
(16) In this second stage of the method, the amount of mercury vapor (Hg.sup.o) will be decreased to very low values.
(17) The main reaction in this second washing stage of the method that is performed in the second washing tower is the following:
Hg.sup.0(g)+HgCl.sup.n.sub.(2+n)>Hg.sub.2Cl.sub.2(s)+nCl.sup., where 0n2
(18) The method comprises feeding a stream of twice processed gas 23 from the second washing tower 6 into a third washing tower 9.
(19) The method comprises treating the stream of twice processed gas 23 in the third washing tower 9 with a third washing solution 10 circulating in a third closed system 11 through the third washing tower 9 and that contains a lower concentration of mercury (II)-ions than the first washing solution 3, such as less that about 0.1 to about 0.3 g/l, such as such as less than about 0.2 g/l, of mercury (II)-ions, and possible additionally at least twice this amount of ion or ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions to form a stream of cleaned gas (12) of the stream of twice processed gas (23).
(20) In this third stage of the method that is performed in the third washing tower 9, the mercuric chloride (Hg.sub.2Cl.sub.2) vapor that is formed in the second washing tower 6 is removed from the gas. It is important to avoid reduction of Hg.sup.2+ to Hg.sup.o and this may be achieved by careful control of the Hg concentration in the third washing solution 10, which is not allowed to exceed a certain maximum level of about 10 mg/l.
(21) The main reaction in this third washing stage of the method that is performed in the third washing tower 9 is the following:
HgCl.sub.2(g)+H.sub.20>HgCl.sub.2(a)
(22) The method comprises discharging a stream of cleaned gas 12 from the third washing tower 9.
(23) The method may include feeding additional washing solution 13 containing mercury (II)-ions from a tank means 14 into first washing solution 3 circulating in the first closed system 4.
(24) The method may include removing calomel 15 from the first washing solution 3 circulating in the first closed system 4.
(25) The method may include feeding a part 16 of the second washing solution 7 circulating in the second closed system 8 from the second closed system 8 into first washing solution 3 circulating in the first closed system 4.
(26) The method may include feeding additional washing solution 13 containing mercury (II)-ions from a tank means 14 into the second washing solution 7 circulating in the second closed system 8.
(27) The method may include filtering out mercury from the third washing solution 10 circulating in the third closed system 11.
(28) The method may include feeding third washing solution 21 circulating in the third closed system 11 to process steps (not shown in the figure) which are performed prior the method as described here. By such feeding, the amount of third washing solution 21 will be lower and it will be easier to maintain an optimal chemical composition of the third washing solution 21.
(29) In an embodiment of the method, such as in the embodiments illustrated in
(30) In an embodiment of the method, such as in the embodiments illustrated in
(31) In an embodiment of the method, such as in the embodiments illustrated in
(32) In the method the cleaned gas 12 may be brought to a filter 33 for absorption of any remaining gaseous elementary mercury. A filter 33 containing selenium and/or carbon can for example be used.
(33) The method may comprise removing mercury from the third washing solution 10 circulating in the third closed system 11 by means of an active filter 34.
(34) Next the arrangement for removing gaseous elementary mercury (Hg.sup.0.sub.(g)) from a stream of gas and some preferred embodiment and variants of the arrangement will be described in greater detail.
(35) The arrangement comprises a first washing tower 2 for receiving a stream of gas 1.
(36) The first washing tower 2 is configured for treating the stream of gas 1 with a first washing solution 3 that circulates in a first closed system 4 through the first washing tower 2 and that contains mercury (II) ions and possible additionally at least twice this amount of ion or ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions. The mercury (II)-ion (Hg.sup.2+) content in the first washing solution 3 may be decreased compared to a minimum often recommended level of about 1 to about 2 g/l, such as less than about 1.5 g/l, for the so-called Boliden-Norzink process but may be above a certain minimum level of about 0.1 to about 0.3 g/l, such as more than about 0.2 g/l. This will reduce the risk for formation of mercuric chloride (Hg.sub.2Cl.sub.2) mist or calomel mist in the gas.
(37) The main reaction in this first washing stage is the following:
Hg.sup.0(g)+HgCl.sup.n.sub.(2+n)>Hg.sub.2Cl.sub.2(s)+nCl.sup., where 0n2
(38) The arrangement comprises a second washing tower 6 for receiving a stream of once processed gas 5 from the first washing tower 2.
(39) The second washing tower 6 is configured for treating the stream of once processed gas 5 with a second washing solution 7 circulating in a second closed system 8 through the second washing tower 6 and that contains a higher concentration of mercury (II)-ions than the first washing solution 3 such as more than about 1 to 2 g/l, such more than about 1.5 g/l of mercury (II)-ions and that contains possible additionally at least twice this amount of ion or ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions.
(40) The main reaction in this second washing stage is the following:
Hg.sup.0(g)+HgCl.sup.n.sub.(2+n)>Hg.sub.2Cl.sub.2(s)+nCl.sup., where 0n2
(41) The arrangement comprises a third washing tower 9 for receiving a stream of twice processed gas 23 in the second washing tower 6.
(42) The third washing tower 9 is configured for treating the stream of twice processed gas 23 with a third washing solution 10 circulating in a third closed system 11 through the third washing tower 9 and that contains a lower concentration of mercury (II)-ions than the first washing solution 3 such as less than about 0.1 to about 0.3 g/l, such as less than about 0.2 g/l, of mercury (II)-ions and that contains possible additionally at least twice this amount of ion or ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions.
(43) The main reaction in this third washing stage is the following:
HgCl.sub.2(g)+H.sub.20>HgCl.sub.2(a)
(44) The second washing tower 6 is configured for discharging a stream of cleaned gas 12 from the third washing tower 9.
(45) The arrangement may comprise first feeding means 17 for additional washing solution 13 containing mercury (II)-ions from a tank means 14 into first washing solution 3 circulating in the first closed system 4.
(46) The arrangement may comprise first removing means 18 for removing calomel 15 from the first washing solution 3 circulating in the first closed system 4.
(47) The arrangement may comprise second feeding means 19 for feeding a part 16 of the second washing solution 7 circulating in the second closed system 8 into first washing solution 3 circulating in the first closed system 4.
(48) The arrangement may comprise third feeding means 20 for feeding additional washing solution 13 containing mercury (II)-ions from a tank means 14 into second washing solution 7 circulating in the second closed system 8.
(49) The arrangement may include fourth feeding means 22 for feeding third washing solution 21 circulating in the third closed system 11 to process steps (not shown in the figure) which are performed prior the method as described here. By such feeding, the amount of third washing solution 21 will be lower and it will be easier to maintain an optimal chemical composition of the third washing solution 21.
(50) In an embodiment of the arrangement, such as in the embodiments shown in
(51) In an embodiment of the arrangement, such as in the embodiments shown in
(52) In an embodiment of the arrangement, such as in the embodiments shown in
(53) The arrangement may comprise a filter 33 for absorption of any remaining gaseous elementary mercury in the cleaned gas 12. The filter 33 may comprise selenium and/or carbon.
(54) The third closed system 11 may be provided with an active filter 34 for removing mercury from the third washing solution 10 circulating in the third closed system 11.
(55) The first closed system 4 of the arrangement illustrated in
(56) The second closed system 8 of the arrangement illustrated in
(57) The third closed system 11 of the arrangement illustrated in
(58) Next the arrangement for carrying out the method for removing gaseous elementary mercury from a stream of gas and some preferred embodiment and variants of the arrangement for carrying out the method will be described in greater detail.
(59) The arrangement for carrying out the method comprises a first washing tower 2 for receiving a stream of gas 1.
(60) The first washing tower 2 is configured for treating the stream of gas 1 with a first washing solution 3 that circulates in a first closed system 4 through the first washing tower 2 and that contains mercury (II) ions and possible additionally at least twice this amount of ion or ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions. The mercury (II)-ion (Hg.sup.2+) content in the first washing solution 3 may be decreased compared to a minimum often recommended level of about 1 to about 2 g/l, such as less than about 1.5 g/l, for the so-called Boliden-Norzink process but may be above a certain minimum level of about 0.1 to about 0.3 g/l, such as more than about 0.2 g/l. This will reduce the risk for formation of mercuric chloride (Hg.sub.2Cl.sub.2) mist or calomel mist in the gas.
(61) The main reaction in this first washing stage is the following:
Hg.sup.0(g)+HgCl.sup.n.sub.(2+n)>Hg.sub.2Cl.sub.2(s)+nCl.sup., where 0n2
(62) The arrangement for carrying out the method comprises a second washing tower 6 for receiving a stream of once processed gas 5 from the first washing tower 2.
(63) The second washing tower 6 is configured for treating the stream of once processed gas 5 with a second washing solution 7 circulating in a second closed system 8 through the second washing tower 6 and that contains a higher concentration of mercury (II)-ions than the first washing solution 3 such as more than about 1 to 2 g/l, such more than about 1.5 g/l of mercury (II)-ions and that contains possible additionally at least twice this amount of ion or ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions.
(64) The main reaction in this second washing stage is the following:
Hg.sup.0(g)+HgCl.sup.n.sub.(2+n)>Hg.sub.2Cl.sub.2(s)+nCl.sup., where 0n2
(65) The arrangement for carrying out the method comprises a third washing tower 9 for receiving a stream of twice processed gas 23 in the second washing tower 6.
(66) The third washing tower 9 is configured for treating the stream of twice processed gas 23 with a third washing solution 10 circulating in a third closed system 11 through the third washing tower 9 and that contains a lower concentration of mercury (II)-ions than the first washing solution 3 such as less than about 0.1 to about 0.3 g/l, such as less than about 0.2 g/l, of mercury (II)-ions and that contains possible additionally at least twice this amount of ion or ions selected from the group consisting of chlorine, bromine, iodine, cyanide and rhodanide ions. The main reaction in this third washing stage is the following:
HgCl.sub.2(g)+H.sub.20>HgCl.sub.2(a)
(67) The second washing tower 6 is configured for discharging a stream of cleaned gas 12 from the third washing tower 9.
(68) The arrangement for carrying out the method may comprise first feeding means 17 for additional washing solution 13 containing mercury (II)-ions from a tank means 14 into first washing solution 3 circulating in the first closed system 4.
(69) The arrangement for carrying out the method may comprise first removing means 18 for removing calomel 15 from the first washing solution 3 circulating in the first closed system 4.
(70) The arrangement for carrying out the method may comprise second feeding means 19 for feeding a part 16 of the second washing solution 7 circulating in the second closed system 8 into first washing solution 3 circulating in the first closed system 4.
(71) The arrangement for carrying out the method may comprise third feeding means 20 for feeding additional washing solution 13 containing mercury (II)-ions from a tank means 14 into second washing solution 7 circulating in the second closed system 8.
(72) The arrangement for carrying out the method may include fourth feeding means 22 for feeding third washing solution 21 circulating in the third closed system 11 to process steps (not shown in the figure) which are performed prior the method as described here. By such feeding, the amount of third washing solution 21 will be lower and it will be easier to maintain an optimal chemical composition of the third washing solution 21.
(73) In an embodiment of the arrangement for carrying out the method, such as in the embodiments shown in
(74) In an embodiment of the arrangement for carrying out the method, such as in the embodiments shown in
(75) In an embodiment of the arrangement for carrying out the method, such as in the embodiments shown in
(76) The arrangement for carrying out the method may comprise a filter 33 for absorption of any remaining gaseous elementary mercury in the cleaned gas 12. The filter 33 may comprise selenium and/or carbon.
(77) The third closed system 11 may be provided with an active filter 34 for removing mercury from the third washing solution 10 circulating in the third closed system 11.
(78) The first closed system 4 of the arrangement for carrying out the method illustrated in
(79) The second closed system 8 of the arrangement for carrying out the method illustrated in
(80) The third closed system 11 of the arrangement for carrying out the method illustrated in
(81) It is apparent to a person skilled in the art that as technology advanced, the basic idea of the invention can be implemented in various ways. The invention and its embodiments are therefore not restricted to the above examples, but they may vary within the scope of the claims.