Multi-layer heat shrinkable tubular sleeve
09882369 ยท 2018-01-30
Assignee
Inventors
- David Francis Pearce (Wiltshire, GB)
- Richard Graf (Unterschleissheim, DE)
- Thomas Rohde (Bad Aibling, DE)
- John David Stoker (Wiltshire, GB)
- Timothy S. Smith (Wiltshire, GB)
Cpc classification
B32B2597/00
PERFORMING OPERATIONS; TRANSPORTING
B32B27/28
PERFORMING OPERATIONS; TRANSPORTING
International classification
H02G3/04
ELECTRICITY
B32B27/28
PERFORMING OPERATIONS; TRANSPORTING
F16L55/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16L11/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
A multi-layer heat-shrinkable tubular sleeve (100) comprises an outer layer (110) and an inner layer (120). The outer layer (110) is arranged around the inner layer (120). The outer layer (110) comprises a partially crystalline thermoplastic material with a major part of partially crystalline thermoplastic material with a crystallinity of more than 60%. The inner layer (120) comprises a partially crystalline thermoplastic material or an elastomeric material.
Claims
1. A multi-layer heat-shrinkable tubular sleeve comprising an outer layer and an inner layer, wherein the outer layer is adjacently arranged around the inner layer, the outer layer defines an outermost surface of the tubular sleeve and is comprised of an electrically-insulating material; wherein the outer layer comprises a partially crystalline thermoplastic electrically-insulating material, wherein the inner layer comprises a partially crystalline thermoplastic material or an elastomeric material, wherein the outer layer comprises a major part of partially crystalline thermoplastic material with a crystallinity of more than 60%; and wherein the outer layer comprises at least two elongate electrodes positioned within a portion of the outer layer and positioned radially outward from a circumference of an outer surface of the outer layer, the at least two elongate electrodes extending at least partially along the sleeve.
2. The sleeve according to claim 1, wherein the inner layer comprises a thermoplastic elastomeric material.
3. The sleeve according to claim 1, wherein the major part of the material of the outer layer comprises a crystallinity between 75% and 90%.
4. The sleeve according to claim 1, wherein the outer layer comprises a density of at least 0.94 g/cm.sup.3.
5. The sleeve according to claim 1, wherein the outer layer comprises an electrical resistivity of at least 1 T.Math.cm.
6. The sleeve according to claim 1, wherein the outer layer comprises a comparative tracking index of at least 600.
7. The sleeve according to claim 1, wherein the outer layer comprises an electrical resistivity between 10 M.Math.cm and 1 T.Math.cm, preferably between 50 G.Math.cm and 1 T.Math.cm, and/or the outer layer comprises a relative permittivity of at least 5.
8. The sleeve according to claim 1, wherein the outer layer comprises an electrical resistivity between 10 M.Math.cm and 1 T.Math.cm, preferably between 50 G.Math.cm and 1 T.Math.cm, and/or the outer layer comprises a relative permittivity of at least 10.
9. The sleeve according to claim 1, wherein the outer layer comprises an electrical resistivity between 10 M.Math.cm and 1 T.Math.cm, preferably between 50 G.Math.cm and 1 T.Math.cm, and/or the outer layer comprises a relative permittivity of at least 15.
10. The sleeve according to claim 1, wherein the inner layer comprises an electrical resistivity between 10 M.Math.cm and 1 T.Math.cm, preferably between 50 G.Math.cm and 1 T.Math.cm, and/or the inner layer comprises a relative permittivity of at least 5.
11. The sleeve according to claim 1, wherein the inner layer comprises an electrical resistivity between 10 M.Math.cm and 1 T.Math.cm, preferably between 50 G.Math.cm and 1 T.Math.cm, and/or the inner layer comprises a relative permittivity of at least 10.
12. The sleeve according to claim 1, wherein the inner layer comprises an electrical resistivity between 10 M.Math.cm and 1 T.Math.cm, preferably between 50 G.Math.cm and 1 T.Math.cm, and/or the inner layer comprises a relative permittivity of at least 15.
13. The sleeve according to claim 1, wherein the inner layer comprises an electrical resistivity of less than 100 .Math.cm.
14. The sleeve according to claim 1, wherein the sleeve comprises an innermost layer, wherein the inner layer is arranged around the innermost layer and the inner layer comprises an elastomeric material comprised of an electrically-insulating material.
15. The sleeve according to claim 14, wherein the innermost layer comprises an elastomeric material that is electrically stress grading.
16. The sleeve according to claim 14, wherein the innermost layer comprises an elastomeric material that is electrically insulating.
17. A cable termination comprising a multi-layer heat-shrinkable tubular sleeve according to claim 1.
18. A cable joint comprising a multi-layer heat-shrinkable tubular sleeve according to claim 1.
19. A method for producing a multi-layer heat-shrinkable tubular sleeve the method comprising steps of: co-extruding an inner layer and an outer layer of the sleeve, wherein the outer layer is arranged around the inner layer and is comprised of an electrically-insulating material; cross-linking the sleeve material; expanding the sleeve; and inserting at least two elongate electrodes within a portion of the outer layer and positioning the at least two elongate electrodes radially outward from a circumference of an outer surface of the outer layer, the at least two elongate electrodes extending at least partially along the sleeve.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The invention will now be explained in more detail with reference to the Figures, in which:
(2)
(3)
(4)
(5)
(6)
DETAILED DESCRIPTION
(7)
(8) The tubular sleeve 100 may for example be used in a joint or a termination for an electrical power cable. The electrical power cable may for example be designed for being used with operation voltages of or above 6 kV (kilovolts). The power cable may be a low voltage power cable, a medium voltage power cable or a high voltage power cable designed for voltages above 42 kV.
(9) The tubular sleeve 100 may be shrunk into position around the ends of two electrical power cables that have been electrically connected together. The tubular sleeve 100 may also be used in a cable termination.
(10) The multi-layer heat-shrinkable tubular sleeve 100 is preferably of tubular, one-piece construction. The term tubular is used to indicate an elongate hollow article, which may be a substantially straight sleeve of substantially uniform round or oval cross-section, but is not necessarily limited to any particular longitudinal outline or uniformity of transverse dimension.
(11) The tubular sleeve 100 may be manufactured efficiently by co-extrusion. However, layered moldings are not excluded and will often be preferable for articles of more complex shape. After co-extrusion or molding, the material constituting the outer layer 110 and/or the inner layer 120 may be cross-linked by heating up the tubular sleeve 100. In a following process step the tubular sleeve 100 may be expanded radially to enable a later recovery of the tubular sleeve 100.
(12) In a first embodiment, the outer layer 110 may comprise an electrically insulating material that is electrically non-tracking and is provided for exerting an enhanced contact pressure on the inner layer 120 when the tubular sleeve 100 has been heat-shrunk or recovered and thus also for exerting an enhanced contact pressure on a cable interface that is arranged in the tubular sleeve 100. In this first embodiment, the inner layer 120 may comprise a thermoplastic material that is electrically stress-grading.
(13) A material may be regarded as electrically insulating if the material comprises an electrical resistivity of at least 1 T.Math.cm (teraohm times centimeter). According to the first embodiment, the outer layer 110 therefore comprises an electrical resistivity of at least 1 T.Math.cm.
(14) A material may be regarded as electrically non-tracking if the material comprises a comparative tracking index of at least 600. The comparative tracking index indicates a voltage level that still results in a sufficiently low degradation of the material in case of creepage current in the presence of humidity or wetness.
(15) On the basis of the so called Barlow's Formula, an equation for the long term hydrostatic pressure resistance on pipes, a radial pressure p is proportional to a stress S in a tubular material: p=2 S t/D, wherein t is the wall thickness and D is the diameter of the tube. The stress S is defined by the force per area. Thus, the pressure exerted on the cable interface is proportional to the tangential force the tubular sleeve 100 can reach. Consequently, to assess a relative enhancement of different materials, a simple tension test on a ring cut of the tubular sleeve to measure the force during cooling is sufficient.
(16)
(17) Samples of the same overall cross section area are tested and compared with each other. A sample that shows a higher force after 60 minutes of cooling time is suitable to exert an enhanced contact pressure to an interface.
(18) We define that a multi-layer tubular sleeve exerts an enhanced contact pressure if that multi-layer sleeve shows at least a 25% higher, preferably a 50% higher, force 630 in a simple tension test compared to a single-layer sleeve of the same base material with the same cross section.
(19) In other words, the outer layer 110 of the tubular sleeve 100 may be regarded as being suitable to exert an enhanced contact pressure on the inner layer 120 of the tubular sleeve 100 if the tubular sleeve 100 exerts a contact pressure after heat-shrinking of the tubular sleeve 100 that is at least 25%, preferentially at least 50%, higher than a contact pressure exerted by a tubular sleeve with an outer layer that comprises the same material as the inner layer, provided that both tubular sleeves comprise the same thickness.
(20) According to the first embodiment, the outer layer 110 comprises a major part of partially crystalline thermoplastic material with a crystallinity of more than 60%. The term major part means that among all individual components of the material of the outer layer 110, the partially crystalline thermoplastic material with a crystallinity of more than 60% is the biggest component by weight.
(21) In a preferred embodiment of the invention the major part of the material of the outer layer is preferably a high density polyethylene comprising a crystallinity between 70% and 80%. High density polyethylenes are heat-shrinkable (heat-recoverable) thermoplastic materials from the class of polyolefins. A tubular sleeve layer composed from such a thermoplastic material with a high crystallinity is suited for exerting a high contact pressure on the inner layer.
(22) It is further preferred that the material of the outer layer 110 comprises a density of at least 0.94 g/cm.sup.3 (gramm per cubic centimeter). It is known that the density of high density polyethylene is linked to the crystallinity of the high density polyethylene. The higher the crystallinity, the higher the density and the higher the possible contact pressure exerted by a tubular sleeve layer composed of that material.
(23) The outer layer 110 of the tubular sleeve 100 is capable of exerting an enhanced contact pressure on the inner layer 120 of the tubular sleeve 100 because the outer layer 110 comprises a major part of partially crystalline thermoplastic material with a crystallinity of more than 60%. Experiments have shown this surprising effect. A layer comprising a smaller fraction of partially crystalline thermoplastic material with a crystallinity of more than 60% or a layer comprising only material with a lower crystallinity is not suited for exerting an enhanced contact pressure.
(24) According to the first embodiment, the inner layer 120 is composed of a thermoplastic stress-grading material.
(25) A material may be regarded as electrically stress-grading if the material comprises an electrical resistivity between 10 M.Math.cm (megaohm times centimeter) and 1 T.Math.cm (teraohm times centimeter), preferably between 50 G.Math.cm (gigaohm times centimeter) and 1 T.Math.cm. A material may also be regarded as electrically stress-grading if the material comprises a relative permittivity of at least 5, preferably at least 10, most preferably at least 15.
(26) The inner layer 120 of the tubular sleeve 100 according to the first embodiment may for example be comprised of
(27) 35% by weight of chlorinated polyethylene,
(28) 20% by weight of low density polyethylene,
(29) 40% by weight of thermal and semiconductive carbon blacks,
(30) 4.5% by weight of antioxidants and stabilizers, and
(31) 0.5% by weight of cross-linking promoters.
(32) In a second embodiment of the present invention the outer layer 110 of the tubular sleeve 100 may be composed of the same material as the outer layer 110 of the tubular sleeve 100 according to the first embodiment discussed above.
(33) The inner layer of the tubular sleeve 100 according to the second embodiment comprises an electrically stress-grading elastomeric material. The inner layer 120 of the tubular sleeve 100 according to the second embodiment may for example comprise
(34) 55% by weight of ethylene-propylene-diene-monomer elastomer,
(35) 40% by weight of thermal and semiconductive carbon blacks,
(36) 4.5% by weight of antioxidants and stabilizers, and
(37) 0.5% by weight of cross-linking promoters.
(38) According to a third embodiment, the outer layer 110 of the tubular sleeve may comprise a thermoplastic material that is electrically stress-grading and capable of exerting an enhanced contact pressure on the inner layer 120. The material of the outer layer 110 comprises a major part of partially crystalline thermoplastic material with a crystallinity of more than 60%.
(39) According to the third embodiment, the inner layer 120 of the tubular sleeve 100 may comprise an electrically stress-grading elastomeric material. The inner layer 120 may comprise the same material as the inner layer 120 of the tubular sleeve 100 according to the second embodiment disclosed above.
(40) According to a fourth embodiment of the present invention, the outer layer 110 of the tubular sleeve 100 may comprise a thermoplastic electrically insulating and electrically non-tracking material that is capable of exerting an enhanced contact pressure on the inner layer 120 of the tubular sleeve. The material of the outer layer 110 comprises a major part of partially crystalline thermoplastic material with a crystallinity of more than 60%. The outer layer 110 of the tubular sleeve 100 according to the fourth embodiment may for example comprise the same material as the outer layer 110 of the tubular sleeve 100 according to the first embodiment disclosed above.
(41) According to the fourth embodiment, the inner layer 120 of the tubular sleeve 100 may comprise an electrically conductive thermoplastic material.
(42) A material may be regarded as being electrically conductive if the material comprises an electrical resistivity of less than 100 .Math.cm (ohm times centimeter).
(43) The inner layer 120 of the tubular sleeve 100 according to the fourth embodiment therefore comprises an electrical resistivity of less than 100 .Math.cm. The inner layer 120 of the tubular sleeve 100 may for example comprise
(44) 60% to 70% by weight of an ethylene-vinyl-acetate copolymer,
(45) 10% to 20% by weight of high density polyethylene,
(46) 15% to 25% by weight of conductive carbon black and
(47) 1% to 2% by weight of aromatic amine antioxidant.
(48) The individual components of the material may be selected from the specified ranges to total 100%.
(49)
(50) The tubular sleeve 200 is preferably of tubular, one-piece construction. The term tubular is used to indicate an elongate hollow article, which may be a substantially straight sleeve of substantially uniform around or oval cross-section, but is not necessarily limited to any particular longitudinal outline or uniformity of transverse dimension.
(51) The tubular sleeve 200 may be manufactured efficiently by co-extrusion. However, layered moldings are not excluded and will often be preferable for tubular sleeves of more complex shape.
(52) According to a fifth embodiment, the outer layer 210 of the tubular sleeve 200 may comprise a thermoplastic material that is electrically insulating and electrically non-tracking and capable of exerting an enhanced contact pressure on the inner layer 220 of the tubular sleeve 200. The material of the outer layer 210 comprises a major part of partially crystalline thermoplastic material with a crystallinity of more than 60%. The outer layer 210 of the tubular sleeve 200 according to the fifth embodiment may for example comprise the same material as the outer layer 110 of the tubular sleeve 100 according to the first embodiment.
(53) According to the fifth embodiment, the inner layer 220 may comprise an elastomeric material that is electrically insulating. The inner layer 220 of the tubular sleeve 200 according to the fifth embodiment may for example comprise
(54) 40% to 50% by weight of ethylene propylene diene monomer rubber,
(55) 10% to 20% by weight of polyisobutylene,
(56) 25% to 40% by weight of a filler material,
(57) 2% to 5% by weight of process aids,
(58) 3% to 7% by weight of the stabilizers, and
(59) 3% to 5% by weight of cross-linking agents.
(60) The individual components of the material of the inner layer 220 of the tubular sleeve 200 according to the fifth embodiment may be selected from the specified ranges to total 100%.
(61) The innermost layer 230 of the tubular sleeve 200 according to the fifth embodiment comprises an elastomeric material that is electrically stress-grading. The innermost layer 230 of the tubular sleeve 200 according to the fifth embodiment may for example comprise the same material as the inner layer 120 of the tubular sleeve 100 according to the second embodiment disclosed above.
(62) According to a sixth embodiment, the outer layer 210 of the tubular sleeve 200 comprises a thermoplastic material that is electrically insulating and electrically non-tracking and capable of exerting an enhanced contact pressure on the inner layer 220. The material of the outer layer 210 comprises a major part of partially crystalline thermoplastic material with a crystallinity of more than 60%. According to the sixth embodiment, the outer layer 210 may for example comprise the same material as the outer layer 110 of the tubular sleeve 100 according to the first embodiment disclosed above.
(63) According to the sixth embodiment, the inner layer 220 of the tubular sleeve 200 and the innermost layer 230 of the tubular sleeve 200 both comprise an elastomeric material that is electrically insulating. The inner layer 220 and the innermost layer 230 may or may not comprise the same material. The inner layer 220 and/or the innermost layer 230 of the tubular sleeve 200 according to the sixth embodiment may for example comprise the same material as the inner layer 220 of the tubular sleeve 200 according to the fifth embodiment disclosed above.
(64)
(65) Again, the term tubular is used to indicate an elongated hollow article, which may be a substantially straight sleeve of substantially uniform around or oval cross-section, but is not necessarily limited to any particular longitudinal outline or uniformity of transverse dimensions. The tubular sleeve 300 may be manufactured efficiently by co-extrusion. However, layered moldings are not excluded.
(66) According to a seventh embodiment, the outermost layer 330 of the tubular sleeve 300 comprises a thermoplastic material that is electrically conductive. The outermost layer 330 may for example comprise the same material as the inner layer 120 of the tubular sleeve 100 according to the fourth embodiment described above.
(67) The outer layer 310 of the tubular sleeve 300 according to the seventh embodiment comprises a thermoplastic material that is electrically insulating and capable of exerting an enhanced contact pressure on the inner layer 320. The material of the outer layer 310 comprises a major part of partially crystalline thermoplastic material with a crystallinity of more than 60%. The inner layer 320 of the tubular sleeve 300 according to the seventh embodiment comprises an elastomeric material that is electrically stress-grading. The inner layer 320 of the tubular sleeve 300 according to the seventh embodiment may for example comprise the same material as the inner layer 120 of the tubular sleeve 100 according to the second embodiment described above.
(68) According to an eighth embodiment, the outermost layer 330 of the tubular sleeve 300 may comprise a thermoplastic material that is electrically insulating and electrically non-tracking. The outermost layer 330 of the tubular sleeve 300 according to the eight embodiment may for example comprise
(69) 60% to 70% by weight of a linear low density polyethylene,
(70) 30% to 40% by weight of a filler material, and
(71) 1% to 2% by weight of stabilizers.
(72) The individual components may be chosen from the specified ranges to total 100%.
(73) The outer layer 310 of the tubular sleeve 300 according to the eighth embodiment comprises a thermoplastic material that is electrically insulating and capable of exerting an enhanced contact pressure on the inner layer 320 of the tubular sleeve 300. The material of the outer layer 310 comprises a major part of partially crystalline thermoplastic material with a crystallinity of more than 60%. The outer layer 310 of the tubular sleeve 300 according to the eighth embodiment may for example comprise the same material as the outer layer 310 of the tubular sleeve 300 according to the seventh embodiment described above.
(74) The inner layer 320 of the tubular sleeve 300 according to the eighth embodiment comprises a thermoplastic material that is electrically stress-grading. The inner layer 320 of the tubular sleeve 300 according to the eighth embodiment may for example comprise the same material as the inner layer 120 of the tubular sleeve 100 according to the first embodiment disclosed above.
(75) According to a ninth embodiment, the outermost layer 330 of the tubular sleeve 300 comprises a thermoplastic material that is electrically insulating and electrically non-tracking. The outermost layer 330 of the tubular sleeve 300 of the ninth embodiment may for example comprise the same material as the outermost layer 330 of the tubular sleeve 300 according to the eighth embodiment described above.
(76) The outer layer 310 of the tubular sleeve 300 according to the ninth embodiment comprises a thermoplastic material that is electrically insulating and capable of exerting an enhanced contact pressure on the inner layer 320. The material of the outer layer 310 comprises a major part of partially crystalline thermoplastic material with a crystallinity of more than 60%. The outer layer 310 of the tubular sleeve 300 according to the ninth embodiment may for example comprise the same material as the outer layer 310 of the tubular sleeve 300 according to the eighth embodiment described above.
(77) The inner layer 320 of the tubular sleeve 300 according to the ninth embodiment comprises an elastomeric material that is electrically stress-grading. The inner layer 320 of the tubular sleeve 300 according to the ninth embodiment may for example comprise the same material as the inner layer 120 of the tubular sleeve 100 according to the second embodiment described above.
(78) The tubular sleeves 100, 200, 300 according to the embodiments described above are each composed of multiple layers of which at least one layer each is heat-recoverable. The various layers of each tubular sleeves 100, 200, 300 perform different functions within the tubular sleeves 100, 200, 300. Each tubular sleeve 100, 200, 300 according to the embodiments described above comprises at least one layer that exerts an enhanced contact pressure on other layers located further inwards of the respective tubular sleeve 100, 200, 300 and therefore also onto an electrical interface of an electrical cable accessory that is equipped with the tubular sleeve 100, 200, 300. The electrical cable accessory could be a cable termination or a joint or splice. The enhanced recovery force is important as it creates a much more reliable electrical interface.
(79)
(80) The outer layer 410 comprises a thermoplastic heat-shrinkable material.
(81) The outer layer 410 of the tubular sleeve 400 comprises a first flange 403 and a second flange 404. Each of the flanges 403, 404 extend along the longitudinal direction of the tubular sleeve 400. The flanges 403, 404 are both arranged on an outer circumference of the outer layer 410 of the tubular sleeve 400. The first flange 403 and the second flange 404 are located at radially opposing positions of the outer layer 410 of the tubular sleeve 400.
(82) Embedded in the first flange 403 is a first wire 401. Embedded in the second flange 404 is a second wire 402. The first wire 401 and the second wire 402 are both electrically conductive. A power source not shown in
(83)
(84) The outer layer 510 comprises a thermoplastic heat-shrinkable material.
(85) The outer layer 510 comprises a first flange 505, a second flange 506, a third flange 507 and a fourth flange 508. Each of the flanges 505, 506, 507, 508 extend along a longitudinal direction of the outer layer 510. All flanges 505, 506, 507, 508 are arranged on an outer circumference of the outer layer 510. The first flange 505 and the third flange 507 are longitudinally arranged one after another and are separated by a first notch 511. The second flange 506 and the fourth flange 508 are longitudinally arranged one after another and are separated by a second notch 512. The first flange 505 and the third flange 507 are arranged on a radially opposing position of the outer layer 510 with respect to the second flange 506 and the fourth flange 508.
(86) The first flange 505 comprises a first wire 501. The second flange 506 comprises a second wire 502. The third flange 507 comprises a third wire 503. The fourth flange 508 comprises a fourth wire 504. Each wire 501, 502, 503, 504 is embedded in the respective flange 505, 506, 507, 508 and extends in the same longitudinal direction as the respective flange 505, 506, 507, 508.
(87) A power source 520 may be connected to the first wire 501 and the second wire 502 to apply a voltage between the first wire 501 and the second wire 502. Application of a voltage between the first wire 501 and the second wire 502 causes an electric current to flow between the first wire 501 and the second wire 502 via the outer layer 510 of the tubular sleeve 500, thereby generating heat to heat-shrink the outer layer 510 of the tubular sleeve 500.
(88) The first notch 511 and the second notch 512 prevent the electric currents to flow also via the third wire 503 and the fourth wire 504 when the power source 520 is connected to the first wire 501 and the second wire 502. Consequently, driving a current between the first wire 501 and the second wire 502 heat-shrinks only a part of the outer layer 510 of the tubular sleeve 500 that is arranged between the first wire 501 and the second wire 502. The part of the outer layer 510 of the tubular sleeve 500 that is arranged between the third wire 503 and the fourth wire 504 remains expanded and does not shrink. In order to shrink that part of the tubular sleeve 500, the power source 520 may be connected to the third wire 503 and the fourth wire 504 to drive a current between the third wire 503 and the fourth wire 504 through the outer layer 510 of the tubular sleeve 500.
(89) The tubular sleeve 500 shown in