PRODUCTION LINE FOR PRODUCING NATIONAL-STANDARD MAGNESIUM ALLOY INGOTS ON THE BASIS OF MAGNESIUM ALLOY WASTE MATERIAL

Abstract

A production line comprises: a pretreatment system, a melting and refining system, and a casting system; magnesium alloy waste material passes in sequence through the pretreatment system, the melting and refining system, and the casting system, resulting in magnesium alloy ingots that conform to national standards. The production line for producing national-standard magnesium alloy ingots on the basis of magnesium alloy waste material processes magnesium alloy waste material, passing same through a pretreatment system, a preheating system a melting and refining system, a thermal insulation system, a casting system, and a post-treatment system; coatings and impurities on the surface of the magnesium alloy waste material are removed, and the material is processed into magnesium alloy ingots conforming to national standards; the pieces of equipment of each system are well-connected, the degree of automation is high, operation is simple, and production is highly efficient.

Claims

1. A production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material, being characterized in comprising: a pretreatment system, a smelting-and-refining system, and a casting system that are in sequence connected, wherein the magnesium alloy waste material passes through the pretreatment system, the smelting-and-refining system, and the casting system in sequence to be converted into the GB-standard magnesium alloy ingots; wherein the pretreatment system includes a high-pressure cleaning device and a pickling line.

2. The production line of claim 1, wherein the pickling line comprises a batch-containing device, a pickling area, and a water-rinse area, wherein the batch-containing device contains the magnesium alloy waste material, and the pickling area is independent of the water-rinse area; and wherein the material travels in the pickling line in such manner: after fed into the batch-containing device, the magnesium alloy waste material is sent by the batch-containing device to the pickling area and the water-rinse area for pickling and water rinse in sequence.

3. The production line of claim 1, wherein the pickling line comprises a batch-containing device, a pickling area, a water-rinse area, and a hoisting device, wherein the batch-containing device contains the magnesium alloy waste material, and the pickling area is independent of the water-rinse area, and the hoisting device drives the batch-containing device to travel between the pickling area and the water-rinse area; and wherein the material travels in the pickling line in such manner: after feeding the magnesium alloy waste material into the batch-containing device, the batch-containing device driven by the hoisting device enters the pickling area and the water-rinse area in sequence for pickling and water rinse respectively.

4. The production line of claim 2, wherein the magnesium alloy waste material is pickled in the pickling area and rinsed in the water-rinse area, respectively, as the batch-containing device rotates.

5. The production line of claim 2, wherein the batch-containing device is a power-driven drum, which power-driven drum contains the magnesium alloy waste material and is provided with a rotatory shaft passing through the drum.

6. The production line of claim 3, wherein the hoisting device is a power-driven hoisting unit equipped with hooks, which hooks work with the hoisting elements of the batch-containing device to drive the batch-containing device to perform the operations of loading material, entering the pickling area, exiting the pickling area, entering the water-rinse area, exiting the water-rinse area or unloading material in sequence.

7. The production line of claim 2, wherein the pickling area includes a pickling bath, an acid-in channel, and an acid-out channel, wherein the acid-in channel and the acid-out channel pass through the pickling bath and get communicated with the pickling bath, respectively.

8. The production line of claim 2, wherein the water-rinse area includes a rinse unit, a material unloading unit and a spraying unit, wherein the pickled magnesium alloy waste material passes through the rinse unit, the material unloading unit, and the spraying unit in sequence, so that the rinse unit and the spraying unit perform double water rinse on the magnesium alloy waste material.

9. The production line of claim 8, wherein the spraying unit includes a water pressurizer, a water nozzle, a spraying conveyer, and a spraying hood, wherein the water nozzles and the water pressurizer are disposed at one side of the spraying conveyer and the water nozzles and the water pressurizer are connected with each other, and the magnesium alloy waste material in the spraying unit is rinsed again by the water nozzle wherein the spraying hood is a three-side hood covering the spraying conveyer's two laterals and top, and wherein the spraying conveyer is a vibrating conveyer board.

10. The production line of claim 2, wherein the pickling line further comprises a dewatering-drying device, for dewatering and desiccating the pickled and water-rinsed material.

11. The production line of claim 2, wherein the pickling line further comprises an automatic acid-changing/refilling system, which includes a pH meter, an Mg2+ concentration detector, an electric control valve, an acid-metering pump, a water-metering pump, and a control unit, wherein the portion of the pH meter, the Mg2+ concentration detector, and the electric control valve are disposed inside the pickling bath, while the portion of the acid-metering pump, the water-metering pump, and the control unit are disposed outside the pickling bath; wherein the pH meter, the Mg2+ concentration detector, the electric control valve, the acid-metering pump, and the water-metering pump are in data connection with the control unit, wherein the pH meter serves to regularly measure acidity of an acid solution in the pickling bath, the Mg2+ concentration detector serves to measure Mg2+ concentration in the pickling bath in a real-time manner, the pH meter and the Mg2+ concentration detector send signals to the control unit according to their measurement for controlling operations of the electric control valve, the acid-metering pump, and the water-metering pump by the control unit; the electric control valve controls acid discharging via the acid-out channel, and the acid-metering pump controls acid charging via the acid-in channel.

12. The production line of claim 1, wherein the high-pressure cleaning device in the pretreatment system acts as a preliminary washing apparatus before the magnesium alloy waste material is pickled, and the high-pressure cleaning device includes a revolvable perforated material-holding device and a high-pressure cleaning machine, wherein the magnesium alloy waste material is placed in the material-holding device so as to rotate with the material-holding device, and cleaning nozzles of the high-pressure cleaning machine generates high-pressure water to impact the waste evenly; and in the pretreatment system, the magnesium alloy waste material is cleaned by the high-pressure cleaning device and then enters the pickling line for further cleaning.

13. The production line of claim 12, wherein the cleaning nozzles of the high-pressure cleaning machine are arranged within the material-holding device and distributed evenly in an axial direction of the material-holding device.

14. The production line of claim 1, wherein the pretreatment system further comprises a sorting device, for screening out impurities other than magnesium alloy waste material from the magnesium alloy waste material.

15. The production line of claim 14, wherein the sorting device includes a first sorting unit and a second sorting unit, wherein the first sorting unit is disposed upstream the high-pressure cleaning device, and the second sorting unit is disposed downstream the pickling line; wherein the material travels in the pretreatment system in such manner: the magnesium alloy waste material is sorted and has impurities removed by the first sorting unit sorting, and then is cleaned by the high-pressure cleaning device, enters the pickling line for further cleaning, and is sorted and has impurities removed again by the second sorting unit.

16. The production line of claim 1, wherein the production line further comprises a pre-heating system that is located between the pretreatment system and the smelting-and-refining system, for further removing moisture from the magnesium alloy waste material that has been processed by the pretreatment system, wherein the magnesium alloy waste material is processed by the pretreatment system, and preheated by the pre-heating system before entering the smelting-and-refining system where the magnesium alloy waste material is refined into liquid magnesium alloy.

17. The production line of claim 1, wherein the smelting-and-refining system includes a refining unit, a slag-skimming unit, and a liquid-transferring unit, wherein the slag-skimming unit can be placed into the refining unit, and the refining unit is connected to the liquid-transferring unit, so that liquid magnesium alloy generated from the smelting furnace is transferred into the casting system through the liquid-transferring unit.

18. The production line of claim 1, wherein the casting system includes an ingot casting unit, a fixed-quantity pouring pump, and a pouring control unit, wherein liquid magnesium alloy is poured into the ingot casting unit by the fixed-quantity pouring pump, and the pouring control unit is connected to the ingot casting unit and the fixed-quantity pouring pump.

19. The production line of claim 1, wherein the production line further comprises a environmental protection system including a waste-gas processing unit, a waste-residue processing unit and a waste-acid processing unit, which units are independent of each other, so that the waste-gas processing unit, the waste-residue processing unit, and the waste-acid processing unit process waste gas, waste residue, and waste acid generated in the entire pickling line, respectively.

20. The production line of claim 1, wherein the production line includes a pretreatment system, a pre-heating system, a smelting-and-refining system, a temperature-holding system, and a casting system in sequence, wherein the magnesium alloy waste material is cleaned by the pretreatment system to remove impurities, after preheated by the pre-heating system the magnesium alloy waste material enters the smelting-and-refining system to be refined and/or alloyed into liquid magnesium alloy, which is then maintained at as liquid magnesium alloy by the temperature-holding system, and finally be casted into the GB-standard magnesium alloy ingots by the casting system.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0144] FIG. 1 is a schematic drawing of a production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material according to one preferable mode of the present invention;

[0145] FIG. 2 is a schematic drawing of a high-pressure cleaning device in the pretreatment system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material according to one preferable mode of the present invention;

[0146] FIG. 3 is a schematic drawing of a batch-containing device in the pretreatment system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention;

[0147] FIG. 4 is a schematic drawing of a water-rinse area in the pretreatment system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention;

[0148] FIG. 5 is a flowchart of an automatic acid adding and changing device in the pretreatment system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention;

[0149] FIG. 6 is a flowchart of the pretreatment system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention;

[0150] FIG. 7 is a flowchart of a pre-heating system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention;

[0151] FIG. 8 is a flowchart of a smelting-and-refining system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention;

[0152] FIG. 9 is a flowchart of a temperature-holding system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention;

[0153] FIG. 10 is a flowchart of a casting system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention; and

[0154] FIG. 11 is a flowchart of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

[0155] The invention as well as a preferred mode of use, further objectives and advantages thereof will be best understood by reference to the following detailed description of illustrative embodiments when read in conjunction with the accompanying drawings.

[0156] Any equipment or component whose model is not specified in the following modes can be realized using a commercially available counterpart thereof known in the art, as long as it supports the disclosed production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material to function normally, and the present invention places no limitation thereon. All such equipment or components shall be operated and used as indicated in the relevant operational instructions or standards.

[0157] FIG. 1 through FIG. 11 illustrate a production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material according to one preferable mode of the present invention. With the production line, magnesium alloy waste material can be directly processed into GB-standard magnesium alloy ingots, thereby realizing industrialization of GB-standard magnesium alloy ingots production 100% from magnesium alloy scraps directly. The production line includes a pretreatment system 1, a pre-heating system 2, a smelting-and-refining system 3, a temperature-holding system 4, and a casting system 5. The magnesium alloy waste material is processed by the pretreatment system 1, the pre-heating system 2, the smelting-and-refining system 3, the temperature-holding system 4, and the casting system 5 in sequence to be processed into GB-standard magnesium alloy ingots.

[0158] FIG. 2 through 6 illustrate preferred modes of the pretreatment system 1 of the disclosed production line. Magnesium alloy waste has coating and impurities on its surface removed in the pretreatment system 1. The pretreatment system 1 includes a high-pressure cleaning device 10 and a pickling line, after processed by which the magnesium alloy waste material can be used directly as raw material of GB-standard magnesium alloy ingots that conforms to P.R.C. national standards.

[0159] FIG. 2 illustrates one preferred mode of a high-pressure cleaning device in the pretreatment system of the disclosed production line. As shown in FIG. 2, the high-pressure cleaning device 10 includes a revolvable perforated material-holding device 101 and a high-pressure cleaning machine (not shown). The magnesium alloy waste material a is placed in the material-holding device 101 and rotates with the material-holding device 101 inside the material-holding device 101. Cleaning nozzles 102 of the high-pressure cleaning machine use the generated high-pressure water to impact the waste evenly, thereby removing harmful impurities from the waste's surface. Rolling of the magnesium alloy waste material ensures all the magnesium alloy waste material in the material-holding device gets equal opportunity to be scrubbed, thereby ensuring uniform washing. In addition, the meshes of the material-holding device 101 allow the high-pressure cleaning water to be discharged timely. The material-holding device 101 is cylindrical. The high-pressure cleaning machine's cleaning nozzles 102 are arranged in the material-holding device and distributed evenly along the axial direction of the material-holding device 101, so as to ensure consistency of washing. The rotatory shaft 1011 of the material-holding device 101 is hollow so that the high-pressure cleaning machine's water pipe 103 can pass through it and position the nozzles 102 inside the material-holding device 101, thereby optimizing cleaning effects. In addition, for full recycle, a waste water recycling pit may be provided below the material-holding device 101 for collecting and recycling waste water generated during high-pressure cleaning.

[0160] FIG. 3 is a schematic drawing of a pickling line in the pretreatment system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention. As shown in FIG. 3, the pickling line includes a batch-containing device 11, a pickling area 12, a water-rinse area 13, a hoisting device 14, an automatic acid-changing/refilling system 15 and a dewatering-drying device 16. The pickling area 12 and the water-rinse area 13 are separated. The batch-containing device 11 serves to contain the magnesium alloy waste material. The hoisting device 14 moves the batch-containing device 11 between the pickling area 12 and the water-rinse area 13. The dewatering-drying device 16 dries the magnesium alloy waste material that has been processed in the pickling area 12 and the water-rinse area 13. The automatic acid-changing/refilling system 15 maintains acid liquid in the pickling area 12 at certain concentration. The magnesium alloy waste material passes through the high-pressure cleaning device 10, the pickling area 12, the water-rinse area 13, and the dewatering-drying device 16 in sequence to be processed into dry and clean magnesium alloy waste material that can be directly used to produce GB-standard magnesium alloy ingots.

[0161] The travel of the magnesium alloy waste material is described below. The magnesium alloy waste material is fed into the batch-containing device 11, and the hoisting device 14 drives the batch-containing device 11 to take the magnesium alloy waste material into the pickling area 12 and the water-rinse area 13 in sequence for pickling and water-rinse. Afterward, the dewatering-drying device 16 performs dewatering and desiccation. The hoisting device 14 controls movement of the batch-containing device 11. The hoisting device 14 moves the batch-containing device 11 between the pickling area 12 and the water-rinse area 13. The magnesium alloy waste material is pickled and rinsed as the batch-containing device 11 rotates in the pickling area 12 and the water-rinse area 13, respectively. The magnesium alloy waste material in the batch-containing device 11 is separated from external foreign objects, while washing liquid of the pickling area 12 and the water-rinse area 13 can enter the batch-containing device 11 to contact the magnesium alloy waste material therein.

[0162] FIG. 3 is a schematic drawing of a batch-containing device in the pretreatment system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention. As shown in FIG. 2, the batch-containing device 11 includes a drum 111 and a drive motor 112. The drum 111 contains the magnesium alloy waste material and has a rotatory shaft 116. The rotatory shaft 115 passes through the drum 111 and is fixedly connected to the drum 111, preferably by means of welding. The drive motor 112 is disposed at one end of the pickling area 12. The drive motor 112 rotates the drum 111 by driving the rotatory shaft 116 to rotate. At this time, the magnesium alloy waste material in the drum 111 get well pickled and rinsed in the pickling area 12 and the water-rinse area 13. The magnesium alloy waste material in the drum 111 rotates with the drum 111, thereby ensuring that the magnesium alloy waste material and washing liquid contacts sufficiently. Meanwhile, impurities on the magnesium alloy waste material's surface (especially in grooves) are more likely to come off during the rolling process, thereby ensuring washing consistency and increasing washing efficiency.

[0163] The drum 111 is a cylinder or a regular polygonal column made by welding titanium alloy boards, engineering plastic boards or other acid-proof and high-strength boards together. The drum 111 is provided with plural through holes 112 distributing across the wall defining the drum 111. The through hole 112 has a diameter smaller than the lump diameter of the minimum lump of the magnesium alloy waste material. The through hole 112 has a diameter of 5-30 mm, so as to prevent the magnesium alloy waste material from coming off from the through holes 112 in the pickling and water-rinse processes, thereby minimizing loss of the magnesium alloy waste material while allowing solution in the pickling area 12 and the water-rinse area 13 to enter the drum 111 through the through holes 112 to sufficiently contact the magnesium alloy waste material. This ensures homogeneity of the magnesium alloy waste material throughout the pickling and water-rinse processes, and shortens the overall pickling and water-rinse time.

[0164] The drum 111 includes a material port 113 and a lid 114. The lid 114 opens and closes the material port. The lid 114 is fixed to the drum's wall outside the material port 113 through hinges so that it can cover the material port 113. The magnesium alloy waste material enters and exits the drum 111 through the material port 113. For material to enter or exit, the lid 114 and in turn the material port 113 are open. During rotation of the drum 111, the lid 114 is shut down to close the material port 113. The drum 111 further includes a handle 115. The handle 115 is coaxial with or parallel to the center line of the drum 111. The handle 115 is arranged outside the wall of the drum 111 and fixedly attached to the drum 111. By rotating the handle 115, rotation of the drum 111 can be controlled to orient the material port 113 of the drum 111 differently for allowing material to be loaded or unloaded. Particularly, the material port 113 faces upward for material loading, and downward for material unloading.

[0165] The rotatory shaft 116 is a solid, columnar structure made of titanium alloy or other acid-proof metals and alloy materials thereof. When the hoisting device 14 moves the batch-containing device 11, the rotatory shaft 116 is the major force-bearing component throughout the hoisting process. The rotatory shaft 116 has its one end provided with a transmission gear 1111, and the drive motor 112 is provided with a matching drive motor gear 1121. With engagement between the transmission gear 1111 and the drive motor gear 1121, the drive motor 112 drives the rotatory shaft 116 to rotate, thereby rotating the drum 111.

[0166] Besides, both ends of the rotatory shaft 116 are provided with rolling bearings 1112 and hoisting elements 1113. The hoisting elements 1113 and the hoisting devices 14 are in movable and coordinative connection. In the present embodiment, the hoisting elements 1113 are bearings mounted around the rotatory shaft, and have a diameter not greater than the diameter of the hooks of the hoisting device 14. The rolling bearings 1112 serve to reduce drag against rotation of the drum 111. As shown in FIG. 2, along the rotatory shaft 116, there are transmission gear 1111, hoisting element 1113, rolling bearing 1112, body of the drum 111, rolling bearing 1112, and hoisting element 1113 from top to bottom in sequence.

[0167] The hoisting device 14 adopts the structure of any known crane. In the present embodiment, it includes a hoisting motor, a hoisting controller, and a hoisting unit. The hoisting controller is a programmable logic controller. The controller controls the hoisting motor to drive the hoisting unit to move, so as to make the batch-containing device 11 move between and within the pickling area 12 and the water-rinse area 13. The hoisting device 14 lifts the drum 111 by means of the hoisting elements 1113 at the two ends of the rotatory shaft 116 and aids the drum 111 to perform operations of material-loading, entering the pickling area, exiting the pickling area, entering the water-rinse area, and exiting the water-rinse area in sequence.

[0168] The magnesium alloy waste material is filled in the drum 111 through the batch-containing device 11, and placed into the pickling area 12 and the water-rinse area 13 by the hoisting device 14 for pickling and water-rinse. For ensuring that the magnesium alloy waste material sufficiently contacts washing liquid in the pickling and water-rinse processes, the inventor basing on any of the foregoing configurations of the pickling line, makes structural improvement in the pickling area 12 and the water-rinse area 13 to adapt them to the batch-containing device 11. The magnesium alloy waste material sufficiently contacts acid liquid in the pickling process to have oxide layers and impurities removed from its surface. In the water-rinse process, double water-rinse is performed to thoroughly remove residual acid and residue from the magnesium alloy waste material's surface.

[0169] The magnesium alloy waste material is pickled in the pickling area 12 through the batch-containing device 11. The pickling area 12 includes a pickling bath 121, an acid-in channel 122, and an acid-out channel 123. The acid-out channel 123 passes through the pickling bath's lateral wall and the acid-out channel 123 has its wall tangent to the pickling bath's bottom. The acid-in channel 122 passes through the pickling bath's lateral wall. The acid-in channel 122 is higher than the acid-out channel 123 in altitude. The acid-in channel 122 and the acid-out channel 123 control charging and discharging of acid solution to and from the pickling bath 121. The acid-in channel 122 is a double acid-in channel. The double acid-in channel includes two side tubes extending from the same main tube. The two side tubes pass through different lateral walls of the pickling bath 121, respectively. Preferably, the two side tubes are disposed at two opposite lateral walls of the pickling bath, so that during acid charging the acid solution in the pickling bath 121 can be prepared more homogeneous.

[0170] The pickling bath 121 is made of engineering plastic or fiber-reinforced plastic. The pickling bath 121 has a pickling bath lid to close the bath as a pickling room to preventing volatilization of acid solution in the pickling bath 121 when the pickling bath 121 is not in use (having no batch-containing device therein), thereby reducing loss of material and preventing atmospheric pollution. The pickling bath 121 and the drum 111 match each other in size. The dimension of the pickling bath 121 in its length direction is 20-50 cm greater than the dimension of the drum 111 in its height direction. The dimension of the pickling bath 121 in its width direction is 20-100 cm greater than the diameter of the drum 111. The dimension of the pickling bath 121 in its height direction is 10-100 cm greater than the radius of the drum 111.

[0171] The pickling bath 121 has its two sides provided with pickling force-bearing seats 1211. The two pickling force-bearing seat 1211 are such installed that they are coaxial with the center line of the pickling bath 121. When the drum 111 is in the pickling bath 121, the two rotating bearings 1112 on the rotatory shaft 116 are settled in the two pickling force-bearing seats 1211, respectively, thereby securing the relative position between the drum 111 and the pickling bath 121 unchanged and reducing drag against rotation of the drum 111.

[0172] FIG. 4 schematically depicts the water-rinse area in the pickling line for magnesium alloy waste material of the present invention. After the drum 111 of the batch-containing device 11 receives pickling in the pickling bath 121 in the pickling area 12, the hoisting device 14 lifts the drum 111 by means of the two hoisting elements 1113 on the rotatory shaft 116 and moves it to the water-rinse area 13 for water-rinse. As shown in FIG. 3, the water-rinse area 13 includes a rinse unit 131, a material unloading unit 132, and a spraying unit 133. The pickled magnesium alloy waste material in the water-rinse area 13 is processed by the rinse unit 131, the material unloading unit 132, and the spraying unit 133 in sequence. The rinse unit 131 and the spraying unit 133 wash the magnesium alloy waste material. Thus, the pickled magnesium alloy waste material receives two kinds of wash, namely rinse and sprinkling, in the water-rinse area 13, so as to have residual acid and residue removed from its surface thoroughly.

[0173] When the drum 111 is moved to the water-rinse area 13 from the pickling bath 121 by the hoisting device 14, the drum 111 first enters the rinse unit 131. The first water-rinse of the magnesium alloy waste material is performed in the rinse unit 131 for primarily removing residual acid and residue from the magnesium alloy waste material's surface. The rinse unit 131 further includes a rinse bath 1311. As the drum 111 rotates in the rinse bath 1311, the magnesium alloy waste material is rinsed. The rinse bath 1311 and the drum 111 match each other in size. The rinse bath 1311 has an area smaller than the area of the pickling bath 121 in the pickling area 12. The area of the rinse bath 1311 is greater than the horizontal section area of the drum 111. The rinse bath 1311 has a depth greater than the radius of the drum 111, thereby allowing smooth rotation of the drum 111 in the rinse bath 1311.

[0174] The rinse bath 1311 has two ends thereof each provided with a rinse force-bearing seat 13111. The two rinse force-bearing seats 13111 are such installed that they are coaxial with the center line of the rinse bath 1311. When the drum 111 is in the rinse bath 1311 for rinse, the two rotating bearings 1112 on the rotatory shaft 116 are settled in the two rinse force-bearing seats 13111, thereby securing the relative position between the drum 111 and the rinse bath 1311 unchanged, and reducing drag against rotation of the drum 111.

[0175] After the magnesium alloy waste material in the drum 111 is rinsed in the rinse bath 1311, the hoisting device 14 uses the two hoisting elements 1113 on the rotatory shaft 116 to lift the drum 111 and move it to the material unloading unit 132. The material unloading unit 132 includes a discharge hopper 1321. When the drum 111 is moved from the rinse bath 1311 to the material unloading unit 132 by the hoisting device 14, the drum 111 with the assistance of the hoisting device 14, pours the magnesium alloy waste material into the discharge hopper 1321 and thus accomplishes the operation of material unloading.

[0176] The spraying unit 133 and the material unloading unit 132 are connected to each other. The magnesium alloy waste material receives the secondary water-rinse in the spraying unit 133, to further remove residual acid and residue left on the magnesium alloy waste material's surface. The spraying unit 133 includes a water pressurizer 1331, water nozzles 1332, a spraying conveyer 1333, and a spraying hood 1334. The discharge hopper 1321 is disposed at one end of the spraying conveyer 1333. The magnesium alloy waste material unloaded from the discharge hopper 1321 is laid evenly on the spraying conveyer 1333 and conveyed by the spraying conveyer 1333. The water nozzles 1332 and the water pressurizer 1331 are connected. The magnesium alloy waste material is water-rinsed again in the spraying unit 133 by the water nozzles 1332. The water nozzles 1332 and the water pressurizer 1331 are disposed at one side of the spraying conveyer 1333. The spraying hood 1334 is a three-side hood and covers the spraying conveyer 1333 at its two laterals and top, so as to prevent the magnesium alloy waste material from coming off the spraying conveyer 1333 when hit by water from the water nozzles 1332, thereby reducing material wasting. The spraying conveyer 1333 is a vibrating conveyer board. In the present embodiment, the conveyer board 1333 is electrically connected to a vibration motor, and is meshed and sloping. This not only allows water from the water nozzles 1332 to permeate in the magnesium alloy waste material in the sprinkling process, but also makes the material on the vibrating conveyer board move forward evenly under vibration, thereby preventing the material from being piled on the spraying conveyer. The conveyer board 1333 has a slope of 10 degrees. The sprinkling conveyer has its two sides equipped with retaining plates for retaining the material from falling.

[0177] The spraying unit 133 further includes a collecting tube 1335. The collecting tube 1335 has its one end disposed below the spraying conveyer 1333, and an opposite end communicated with the rinse bath 1311 of the rinse unit 131. The collecting tube 1335 collects waste water generated in the sprinkling process and uses it as a part of the aqueous solution in the rinse bath 1311. Such recycling and reuse of the waste water in the sprinkling process is helpful to conserve resources.

[0178] After finished material unloading in the water-rinse area 13, the drum 111 in the batch-containing device 11 is moved by the hoisting device 14 to the initial stage and gets ready for the next round of operations of material-loading, entering the pickling bath, exiting the pickling bath, entering the rinse bath, exiting the rinse bath and material unloading.

[0179] For ensuring safety in the subsequent processes, and reducing the reject rate of reprocessing of the magnesium alloy waste material, the inventor of the present invention adds the pickling line with a dewatering-drying device, so as to quickly evaporate liquid left on the magnesium alloy waste material's surface, thereby ensuring the magnesium alloy waste material's safety in the subsequent processes, reducing gas inclusion, and decreasing the reject rate of reprocessing of the magnesium alloy waste material.

[0180] As shown in FIG. 1, the dewatering-drying device 16 is disposed at the rear end of the water-rinse area 13. The dewatering-drying device 16 is connected to the rear end of the spraying conveyer 1333 of the spraying unit 133 of the water-rinse area 13. The dewatering-drying device 16 includes an air-blowing unit 161 and a hot-air drying unit 162. The air-blowing unit 161 and the hot-air drying unit 162 are connected together. The air-blowing unit 161 is connected to the spraying unit 133 of the water-rinse area 13. After the magnesium alloy waste material washed by the spraying unit 133 in the water-rinse area 13 then passes through the air-blowing unit 161 and the hot-air drying unit 162 in sequence for dewatering and desiccation, so as to evaporate liquid from the magnesium alloy waste material's surface with increased speed, thereby ensuring the magnesium alloy waste material's safety in the subsequent processes and reducing gas inclusion.

[0181] The air-blowing unit 161 may be one known in the art that includes an air-blowing compressor, an air-blowing conveyer, an air-blowing nozzle, and an air-blowing hood. The air-blowing hood is a three-side hood and covers the air-blowing conveyer's two laterals and top. The air-blowing nozzles are arranged above the air-blowing conveyer and inside the air-blowing hood. The air-blowing conveyer has its one end connected to the spraying unit in the water-rinse area, and has its opposite end connected to the hot-air drying unit. The air-blowing compressor supplies the air-blowing nozzles with pressurized air. The magnesium alloy waste material in the air-blowing unit is transferred by the air-blowing conveyer and treated by the compressed air gushing from the air-blowing nozzles, so as to have liquid at is surface preliminarily removed, thereby reducing working load in the hot-air drying process.

[0182] The hot-air drying unit 162 is also known in the art and includes a hot-air compressor, a heat source, hot-air nozzles, heat-baking conveyer and heat-baking hood. The heat-baking hood is a three-side hood and covers the heat-baking conveyer's two laterals and top. The hot-air compressor and the heat source are connected. The hot-air nozzles are disposed above the heat-baking conveyer and inside the heat-baking hood. The heat-baking conveyer has its one end connected to the air-blowing unit's air-blowing conveyer. The hot-air drying unit works as below. The pressurized air generated by the hot-air compressor is heated by the heat source into pressurized hot air. The hot-air compressor generates hot air and makes it gush from the hot-air nozzles. The magnesium alloy waste material transferred by the heat-baking conveyer is dried by the pressurized hot air coming from the hot-air nozzles, so as to evaporate liquid at the magnesium alloy waste material's surface quickly. Therein, the heat source may be one known in the art, such as electric heating or gas heating, as long as it is as energy-conserving and environmentally friendly as possible.

[0183] The hot-air drying unit 162 further includes an air extractor. The air extractor is disposed at one side of the heat-baking conveyer for quickly exhausting the gas at the magnesium alloy waste material's surface after evaporation, thereby preventing gas condensation and secondary contamination.

[0184] It is to be noted that, the air-blowing conveyer in the air-blowing unit 161 and the heat-baking conveyer in the hot-air drying unit 162 are both meshed conveyers, so as to facilitate ventilation and water permeation in the magnesium alloy waste material when transferred in the air-blowing unit 161 and the hot-air drying unit 162. The mesh of the meshed conveyer is smaller than the magnesium alloy waste material's minimum lump diameter.

[0185] FIG. 5 is a flowchart of an automatic acid-changing/refilling system in the pickling line for magnesium alloy waste material according to the present invention. As shown in FIG. 5, for maintaining the acid liquid concentration in a predetermined range throughout the magnesium alloy waste material's pickling process, so as to ensure desired pickling intensity and pickling effectiveness, the inventor of the present invention adds an automatic acid-changing/refilling system 15 in the pickling line, which monitors variation of the acid liquid throughout the pickling process and automatically adds or changes acid, thereby maintaining the acid liquid concentration and in turn the pickling effectiveness.

[0186] As shown in FIG. 5, the automatic acid-changing/refilling system 15 includes a pH meter 151, an Mg.sup.2+ concentration detector 152, an electric control valve 153, an acid-metering pump 154, a water-metering pump 155, and a control unit 156. Therein, the pH meter 151, the Mg.sup.2+ concentration detector 152, and the electric control valve 153 are partially disposed inside the pickling bath 121, while the acid-metering pump 154, the water-metering pump 155, and the control unit 156 are partially disposed outside the pickling bath 121. The pH meter 151, the Mg.sup.2+ concentration detector 152, the electric control valve 153, the acid-metering pump 154, and the water-metering pump 155 are in data connection with the control unit 156, and are connected in parallel to each other in the present embodiment. Accordingly, the electric control valve 153 controls acid discharging of the acid-out channel 123, and the acid-metering pump 154 controls acid charging of the acid-in channel 122. The pH meter 151, the Mg.sup.2+ concentration detector 152, electric control valve 153, the acid-metering pump 154, and the water-metering pump 155 are connected to the control unit 156. The pH meter 151 regularly measures acidity of the acid solution in the pickling bath 121, and the Mg.sup.2+ concentration detector 152 measures Mg.sup.2+ concentration in the pickling bath 121 in a real-time manner. The pH meter 151 and the Mg.sup.2+ concentration detector 152 send signals to the control unit 156 according to their measurement. The control unit 156 controls operations of the electric control valve 153, the acid-metering pump 154, and the water-metering pump 155.

[0187] When a pH value measured by the pH meter 151 is below a predetermined pH threshold (>7), the control unit 156 receives the signals so as to start the acid-metering pump 154 and open the acid-in channel 122 to add the pickling bath 121 with acid. When a detected value of the Mg.sup.2+ concentration detector 152 is over a predetermined Mg.sup.2+ concentration threshold, the control unit 156 receives the signals so as to open the electric control valve 153 and open the acid-out channel 123 for automatic acid discharge, after which the electric control valve 153 is closed while the control unit 156 starts the acid-metering pump 154 and the water-metering pump 155 to prepare the acid solution again according to a predetermined ratio. By regularly measuring the pH value and Mg.sup.2+ concentration in the pickling bath 121 and automatically adding or changing acid, the acid liquid concentration and Mg.sup.2+ concentration can be maintained in a predetermined range, thereby ensuring pickling effectiveness.

[0188] For removing impurities and coating from the magnesium alloy waste material's surface as much as possible, and reducing impurities in the magnesium alloy waste material, the inventor of the present invention pioneeringly adds a high-pressure cleaning device 10 in the pretreatment system 1, and makes structural improvements in the pickling area 12, the water-rinse area 13, and the dewatering-drying device 16. The magnesium alloy waste material is rinsed before and after pickling, so as to remove impurities adhering to the magnesium alloy waste material as many as possible. The cleaned magnesium alloy waste material is then dried so as to evaporate liquid on the magnesium alloy waste material's surface fast, thereby minimizing gas inclusion, ensuring safety in the subsequent processes, and increasing the magnesium alloy waste material's utilization.

[0189] For screening out apparent impurities such as screws and rubber from the magnesium alloy waste material, thereby minimizing impurities in the magnesium alloy ingots made of the magnesium alloy waste material ensuring purity of the magnesium alloy ingots and making it conform to P.R.C. national standards, the inventor of the present invention, on the basis of any of the foregoing configurations of the production line, adds a sorting device 17 in the pretreatment system 1 so as to facilitate screening out foreign objects from the magnesium alloy waste material, increasing the content of magnesium alloy, minimizing impurities in the magnesium alloy ingots made of the magnesium alloy waste material, ensuring purity of the magnesium alloy ingots and making it conform to P.R.C. national standards.

[0190] The sorting device 17 includes a first sorting unit 171 and a second sorting unit 172. The first sorting unit 171 is disposed upstream the high-pressure cleaning area 10, and the second sorting unit 172 is disposed downstream the dewatering and desiccation device 16. When the magnesium alloy waste material enters the pretreatment system 1, it is firstly sorted by the first sorting unit 171, and then passes through the high-pressure cleaning area 10, the pickling area 12, the water-rinse area 13, and the dewatering-drying area 16 in sequence, finally enters the second sorting unit 172 for secondary sorting operation, thereby ensuring screening out impurities from the magnesium alloy waste material and increasing the content of magnesium alloy in the magnesium alloy waste material.

[0191] The first sorting unit 171 is a sorting platform. The sorting platform is a manual sorting platform. For convenient manual operation, the sorting platform is static and has a height of 1000-1200 mm and a width of 800-1200 mm. The second sorting unit 172 includes a sorting conveyer and a sorting drive motor. The sorting conveyer has its one end connected to the dewatering-drying device 16. The sorting drive motor drives the sorting conveyer to run, where manual operation is performed on the sorting conveyer to screen out magnesium alloy waste material containing foreign objects. The sorting conveyer has its one end connected to the heat-baking conveyer's one end, and the sorting conveyer is lower than the heat-baking conveyer in position, so as to ensure that the magnesium alloy waste material leaving the hot-air drying unit 162 enters the sorting conveyer.

[0192] FIG. 6 is a flowchart of the pretreatment system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention. As shown in FIG. 6, the magnesium alloy waste material is processed in the pretreatment system 1 as follows. The first sorting unit 171 of the sorting device 17 first performs first sorting to the magnesium alloy waste material, and removes apparent non-magnesium alloy material such as rubber. After the first sorting unit 171, the magnesium alloy waste material is loaded in the batch-containing device 11. The hoisting device 15 uses the two hooks 11113 on the center shaft 1111 to lift the drum 111 and places the drum 111 into the high-pressure cleaning area 12 for rotation. After the High-pressure rinse in the high-pressure cleaning area 10, impurities at the magnesium alloy waste material's surface are removed. When the preliminary rinse is done, the hoisting device 15 uses the two hooks 11113 on the center shaft 1111 to lift the drum 111 again and moves the drum 111 out of the high-pressure cleaning area and into the pickling area. The drum 111 is placed into the pickling bath 131 of the pickling area 12 for rotation. With pickling of the acid liquid in the pickling bath 131, coating on the magnesium alloy waste material's surface is removed. After pickling, the hoisting device 15 uses the two hooks 11113 on the center shaft 1111 to lift the drum 111 and drives the batch-containing device 11 out of the pickling area and into the water-rinse area. The drum 111 is placed into the rinse unit 141 of the water-rinse area 13 for rotation. The magnesium alloy waste material is then rinsed by water in the rinse bath 1411 of the rinse unit 141, and has residual acid and residue attached to its surface preliminarily removed. After rinse, the hoisting device 15 uses the two hooks 11113 on the center shaft 1111 to lift the drum 111 and drives batch-containing device 11 out of the rinse unit and into the material unloading unit. The magnesium alloy waste material in the drum 111 is poured into the material unloading funnel 1421 of the material unloading unit 142 with the assistance of the hoisting device 15. The magnesium alloy waste material coming out of the material unloading funnel 1421 is washed by the water nozzles 1432 of the spraying unit 143, so as to further remove impurities and acid liquid on the magnesium alloy waste material's surface. The spraying conveyer 1434 sends the magnesium alloy waste material to the dewatering-drying device 16. The magnesium alloy waste material in the dewatering-drying device 16 passes through the air-blowing unit 161 and the hot-air drying unit 162 in sequence for dewatering and desiccation. The dried magnesium alloy waste material after dewatering and desiccation then receives second sorting performed by the second sorting unit 172 of the sorting device 17, so as to further remove impurities from the magnesium alloy waste material. To this point, processing of the magnesium alloy waste material in the pretreatment system 1 is finished.

[0193] The pre-heating system 2 is disposed between the pretreatment system 1 and the smelting-and-refining system 3, for further drying the magnesium alloy waste material processed by the pretreatment system 1, so as to remove moisture from the magnesium alloy waste material thereby preventing moisture-incurred explosion, and shortening the magnesium alloy waste material's subsequent smelting and refining time. FIG. 7 is a flowchart of the pre-heating system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention. As shown in FIG. 7, the pre-heating system 2 includes a drying cabinet 21, a batch container 22, and a pre-heating air-extracting device 23. The batch container 22 is movably installed in the drying cabinet 21. The pre-heating air-extracting device 23 is installed in the drying cabinet 21. The magnesium alloy waste material is placed into the drying cabinet 21 by means of the batch container 22. The pre-heating air-extracting device 23 extracts and removes moisture from the drying cabinet 21, so as to maintain dryness in the drying cabinet 21. The batch containers 22 are layered and settled in the drying cabinet 21 like drawers. The batch container 22 is equipped with wheels for conveniently entering and exiting the drying cabinet 21. The batch container 22 is made of meshed low-carbon steel plates. The mesh has a diameter smaller than the maximum diameter of the magnesium alloy waste material's minimum lump. The mesh has a diameter of 5-10 mm for facilitating thermal conduction and evaporation of generated moisture.

[0194] After processed in the pretreatment system 1 and the pre-heating system 2 in sequence, the magnesium alloy waste material is placed into the smelting-and-refining system 3 and transformed into liquid magnesium alloy (the melt) in the smelting-and-refining system 3. For ensuring fully smelting of the pretreated magnesium alloy waste material in the refining process, and preventing adsorption of impurities during the smelting process, the inventor of the present invention, on the basis of any of the foregoing configurations of the production line, makes structural improvements in the smelting-and-refining system 3. FIG. 8 is a flowchart of the smelting-and-refining system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention. As shown in FIG. 8, the smelting-and-refining system 3 includes a refining unit 31, a slag-skimming unit 32, and a liquid-transferring unit 33. The slag-skimming unit 32 is placed in the refining unit 31. The refining unit 31 and the liquid-transferring unit 33 are connected. The liquid magnesium alloy after melted and refined in the smelting furnace is transferred into the casting system 5 by the liquid-transferring unit 33. The refining unit 31 is a natural gas regenerative smelting furnace 31, and is equipped with an agitating device 315 and a degasing device 316. The agitating device 315 serves to agitate the liquid magnesium alloy in the smelting furnace 31. The degasing device 316 serves to reduce the gas content in the liquid magnesium alloy (the melt). The smelting furnace 31 includes a magnesium smelting crucible 311, a smelting furnace body 312, a heating device 313, and a heating control device 314. The magnesium smelting crucible 311 is mounted on the smelting furnace body 312. The heating device 313 heats the magnesium smelting crucible 311. The heating control device 314 controls heating of the heating device 313. The magnesium smelting crucible 311 is made of composite steel plates, and lined with nickel-free steel plates, while the outer layer is formed by SUS310S stainless steel boards. The heating device 313 burns natural gas to heat the magnesium smelting crucible 311. With the regenerative heat-exchange burning technology, advantages of high thermal utilization, relatively low energy consumption, and conserving resources can be achieved. The degasing device 316 uses argon gas to blow the liquid magnesium alloy (the melt) in the magnesium smelting crucible 311, thereby better reducing the gas content in the liquid magnesium alloy (the melt). The liquid magnesium alloy (the melt) is refined for the second time to reduce the solid impurity content in the liquid magnesium alloy (the melt). The degasing device 316 includes an argon airbrush, a compressed-air drying filter, bottled argon gas, and a pressure controller. The argon airbrush, the bottled argon gas, and the pressure controller are connected to the compressed-air drying filter. The pressure controller controls the compressed-air drying filter. The bottled argon gas is dried by the compressed-air drying filter before supplied to the argon airbrush, thereby ensuring proper dryness of the argon gas, and preventing moisture from entering the liquid magnesium alloy (the melt) to cause splash of the liquid magnesium alloy (the melt) and secondary gas inclusion. The liquid magnesium alloy (the melt) processed by the refining unit 31 is further processed by the slag-skimming unit 32 to remove magnesium slag from the liquid magnesium alloy (the melt). The slag-skimming unit 32 includes a slag collector 321 and an air-blowing device 322. The slag collector 321 is pre-heated and immersed into the magnesium smelting crucible 311 in the smelting furnace. The air-blowing device 322 blows and lifts magnesium slag from the bottom of the magnesium smelting crucible 311 so that the magnesium slag falls into the slag collector 321, thereby removing magnesium slag from the liquid magnesium alloy (the melt), and increasing concentration of magnesium alloy in the liquid magnesium alloy (the melt). It is to be noted that the air-blowing device 322 blows noble gas, thereby preventing the liquid magnesium alloy (the melt) from contacting air and getting oxidized.

[0195] The liquid magnesium alloy (the melt) processed by the refining unit 31 (the smelting furnace 31) and the slag-skimming unit 32 in sequence is transferred to the casting system 5 by the liquid-transferring unit 33 to be made into magnesium alloy ingots. The liquid-transferring unit 33 includes a casting pump 331, a liquid-in duct 332, a liquid-out duct 333, and a liquid-transferring drive motor 334. The liquid-in duct 332 and the liquid-out duct 333 are both connected to the casting pump 331. The liquid-transferring drive motor 334 controls the rotational speed of the casting pump 331. The liquid-in duct 332 sucks the liquid magnesium alloy (the melt) into the casting pump 331, and the liquid magnesium alloy (the melt) is then sent to the casting system 5 through the liquid-out duct 333. The liquid-transferring drive motor 334 is a variable-frequency speed-control motor, which can adapt its speed to different conditions.

[0196] In the process where the liquid magnesium alloy (the melt) is transferred to the casting system 5 by the liquid-transferring unit 34, for ensuring that the liquid magnesium alloy (the melt) keeps in liquid phase and has no coagulation along its travel from the smelting-and-refining system to the casting system process, the inventor of the present invention on the basis of any of the foregoing configurations of the production line, adds a temperature-holding system 4. The temperature-holding system 4 is disposed between the smelting-and-refining system 3 and the casting system 5. The temperature-holding system 4 holds the liquid magnesium alloy (the melt) melted by the smelting-and-refining system 3 at a certain temperature, so that the liquid magnesium alloy (the melt) maintains its liquid state. With prolonged standing at the certain temperature, the melt's purity is further increased and the temperature is easy to control. This also ensures smooth production of plural magnesium smelting furnaces. This also ensures smooth production of plural magnesium smelting furnaces 31 for successful transfer.

[0197] FIG. 9 is a flowchart of the temperature-holding system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention. As shown in FIG. 9, the temperature-holding system 4 includes a temperature-holding furnace 41 and a gas protection unit 42. The gas protection unit 42 is mounted on the temperature-holding furnace 41. The gas protection unit 42 introduces dry noble gas into the temperature-holding furnace 41 to prevent the liquid magnesium alloy (the melt) from oxidization in the temperature-holding furnace 41.

[0198] The temperature-holding furnace 41 includes a temperature-holding crucible 411, a temperature-holding furnace body 412, a temperature-holding heating device 413, and a temperature-holding control device 414. The temperature-holding crucible 411 is disposed on the temperature-holding furnace body 412. The temperature-holding heating device 413 is disposed inside the temperature-holding furnace body 412. The temperature-holding heating device 413 and the temperature-holding control device 414 are connected. The temperature-holding control device 414 controls the heating temperature of the temperature-holding heating device 413. The liquid-out duct 333 on the liquid-transferring unit 34 is communicated with the temperature-holding crucible 411. The liquid-out duct 332 sends the liquid magnesium alloy (the melt) to the temperature-holding crucible 411. The temperature-holding crucible 411 is made of s composite steel plates, and lined with nickel-free steel plates, while the outer layer is formed by SUS310S stainless steel boards. The temperature-holding crucible 411 has partitions that divide the temperature-holding crucible into 2-3 sub-chambers. The partitions are made of nickel-free steel plates. The partition is provided with at least one drain hole, and preferable 1-3 drain holes. The drain hole is 200-500 mm away from the bottom of the temperature-holding crucible 411. The drain holes can effectively block bottom ash and oxide scale in the liquid magnesium alloy (the melt) from entering the casting system 5, thereby ensuring the liquid magnesium alloy (the melt) used in the casting system 5 is of great purity. The temperature-holding heating device 413 uses spiral high-resistance chromium aluminum alloy resistance wires as heating elements. The resistance wires are inlaid in the temperature-holding furnace body 412. The resistance wires when installing are configured to correspond to the sub-chambers of the temperature-holding crucible 411, respectively. The resistance wires for different sub-chambers of the temperature-holding crucible 411 are independent, so that the heating areas associated to the different sub-chambers of the temperature-holding crucible 411 are independent. The areas can having their heating temperatures adjusted independently by means of the temperature-holding control device 414, thereby allowing the liquid magnesium alloy (the melt) in different sub-chambers of the temperature-holding crucible 411 to be heated separately, and in turn ensuring more reasonable heat-consumption distribution among the sub-chambers. It is to be noted that, every temperature-holding furnace 41 works with 3-4 smelting furnaces 31 in the smelting-and-refining systems, thereby increasing production efficiency. The distance between the temperature-holding furnace 41 and each of the smelting furnaces 31 does not exceed 1 m, thereby preventing coagulation in the liquid-transferring process between the smelting furnace 31 and the temperature-holding furnace 41.

[0199] The gas protection unit 42 includes an air inlet 421, an air outlet 422, and a gas protection device 423. The air inlet 421 and the air outlet 422 are disposed on the temperature-holding crucible 411. The gas protection device 423 includes bottled noble gas, a pressure controller, and an introducing duct. The pressure controller is disposed on the introducing duct. The pressure controller controls the output flow of the bottled noble gas. The introducing duct communicates the bottled noble gas and the air inlet 421, so that when there is liquid magnesium alloy (the melt) in the temperature-holding crucible 411, noble gas is introduced to the temperature-holding crucible 411 continuously to cover the surface of the liquid magnesium alloy (the melt), thereby preventing the liquid magnesium alloy (the melt) from contacting oxygen and in turn oxidization.

[0200] The magnesium alloy waste material is melted by the smelting-and-refining system 3 into the liquid magnesium alloy (the melt). The liquid magnesium alloy (the melt) is kept in the temperature-holding system 4 for heat preservation, thereby ensuring that the liquid magnesium alloy (the melt) remains liquid before it enters the casting system 5 for casting. For casting the liquid magnesium alloy (the melt) into magnesium alloy ingots continuously, increasing the production efficiency of magnesium alloy ingots, improving utilization of the liquid magnesium alloy (the melt), and conserving resources, the inventor of the present invention, on the basis of any of the foregoing configurations of the production line, makes improvements in the casting system 5, so that the liquid magnesium alloy (the melt) processed by the smelting-and-refining system 3 and the temperature-holding system 4 can be made into magnesium alloy ingots quickly, thereby preventing impurity contamination, increasing production efficiency, improving utilization of the liquid magnesium alloy (the melt), and conserving resources.

[0201] FIG. 10 is a flowchart of the casting system of the production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention. As shown in FIG. 10, the casting system 5 includes an ingot casting unit 51, a fixed-quantity pouring pump 52, and a pouring control unit 53. The liquid magnesium alloy (the melt) is injected into the ingot casting unit 51 by the fixed-quantity pouring pump 52. The pouring control unit 53 is connected to the ingot casting unit 51 and the fixed-quantity pouring pump 52. The pouring control unit 53 controls the pouring speed of the fixed-quantity pouring pump 52.

[0202] The ingot casting unit 51 includes an ingot casting machine 511, an ingot mold 512, and a conveying track 513. The ingot casting machine 511 is divided into a casting area, an ingot cooling area, a material unloading area, an ingot mold cooling area, a pre-heating area, and a coating-applying area. The ingot mold 512 is installed on the conveying track 513 and passes through the casting area, the ingot cooling area, the material unloading area, the ingot mold cooling area, the pre-heating area, and the coating-applying area in sequence. The fixed-quantity pouring pump 52 pours the liquid magnesium alloy (the melt) into the ingot mold 512 in the casting area. The conveying track 513 has a variable-frequency speed-control motor and an axle-mounted reducer control. The ingot mold 512 on the conveying track 513 passes through the casting area, the ingot cooling area, the material unloading area, the pre-heating area, and the coating-applying area in sequence at a speed controlled by the variable-frequency speed-control motor and the axle-mounted reducer.

[0203] The casting area is a semi-closed area, where noble gas is used to protect the liquid magnesium alloy (the melt) through the casting process. The ingot cooling area uses air as cooling medium to cool ingots after casting. The ingot mold cooling area uses water acts as cooling medium to cool the ingot mold after material unloading. In the pre-heating area, natural gas or coal gas is burnt as a pre-heating heat source. In the ingot casting machine 511, except for the casting area, the material unloading area, the ingot mold cooling area, and the coating-applying area, all the areas are closed and provide with dust hood openings.

[0204] The fixed-quantity pouring pump 52 is connected to the pouring control unit 53. The fixed-quantity pouring pump 52 includes a casting mouth 521 and a conductive probe 522. The casting mouth corresponds to the casting area of the ingot casting machine 511, and the conductive probe 522 has its two poles electrically connected to the ingot mold and the end of the fixed-quantity pouring pump 52, respectively. The probe 522 is tangent to a predetermined level of the liquid magnesium alloy, so that when the liquid magnesium alloy reaches the predetermined level, the probe contacts the magnesium liquid to form a short circuit. The pouring control unit receives the short circuit signal and makes the fixed-quantity pouring pump stop pouring.

[0205] The magnesium alloy ingots formed by the casting system 5 are the semi-finished product of the GB-standard magnesium alloy ingots, and the surface thereof is not of the required quality. In order to make the semi-finished product of the GB-standard magnesium alloy ingots formed by the casting system 5 have qualified surface, the inventor of the present invention, on the basis of any of the foregoing configurations of the production line, adds a post-treatment system 6. The post-treatment system 6 is disposed downstream the casting system. The post-treatment system 6 provides surface treatment to the semi-finished product of the GB-standard magnesium alloy ingots, so as to obtain the final product of the GB-standard magnesium alloy ingots.

[0206] The post-treatment system 6 includes a burnisher 61, a code printer 62, and a packing machine 63. The semi-finished product of the GB-standard magnesium alloy ingots formed by the casting system 5 then passes through the burnisher 61, the code printer 62, and the packing machine 63 in sequence to be processed into the final product of the GB-standard magnesium alloy ingots.

[0207] The burnisher 61 includes a frame, a burnishing wire wheel, a burnishing motor, and a dedusting device. The burnishing wire wheel is disposed on the frame. The burnishing motor drives the burnishing wire wheel to burnish semi-finished products of the GB-standard magnesium alloy ingots. The dedusting device reclaims dust of magnesium alloy and magnesium oxide produced during the burnishing operation. The dedusting device adopts wet scrubbing to introduce dust of the magnesium alloy and magnesium oxide directly into a liquid solvent. The dedusting device is communicated with the dust hood opening of the ingot casting machine 511, and collects dust from the scrap generated in the ingot casting machine 511. The code printer 62 is a laser code printer, which is easy to operate and highly efficient.

[0208] For reducing environmental pollution, conserving resources, and making the entire production line safe and environmentally friendly, the inventor of the present invention, on the basis of any of the foregoing configurations of the production line, adds an environmental protection system 7 to process waste gas, magnesium slag and waste acid generated throughout the production line, so that it achieves zero discharge of waste gas, magnesium slag, and waste acid, thereby protecting the environment and conserving resources. Accordingly, the environmental protection system 70 includes a waste-gas processing unit 71, a residue processing unit 72, and a waste-acid processing unit 73. The waste-gas processing unit, the waste residue, and the waste-acid processing unit process waste gas, waste residue, and waste acid generated in the entire pickling line, respectively.

[0209] The exhaust-processing unit 71 is an acid-gas spray column serves to process acid gas. The acid-gas spray column includes a blower, filler, a spraying device, a defogging device, a sprinkling liquid circulating pump, and an absorption column. It neutralizes acid gas to eliminate emission of acid gas, and thus provides environmentally friendly processing to the waste gas.

[0210] The waste-gas processing unit 71 further includes an airtight glass chamber. The exhauster is disposed inside the glass chamber. The exhauster draws the acid gas in the glass chamber into the acid-gas spray column. The rinse units in the pickling area and the water-rinse area are both disposed inside the glass chamber, thereby preventing the acid gas in the pickling area and the rinse unit from escape, and minimizing environmental pollution. The glass chamber has a batch-in gate, a batch-out gate, and a control sensor. The control sensor opens or closes the batch-in gate and the batch-out gate. When magnesium alloy waste material as the raw material enters the pickling line, the batch-in gate opens automatically, and automatically closes when material loading is finished. When magnesium alloy waste material as the raw material has been processed by the entire pickling line and outputs, the batch-out gate opens automatically and closes automatically when output ends.

[0211] The residue processing unit 72 is a magnesium residue recycling unit that includes a recycling dissolving tank, a recycling filter, a recycling evaporation crystallizer, and a recycling calcining furnace, in which magnesium slag generated in the production line is processed by the recycling dissolving tank, the recycling filter, the recycling evaporation crystallizer, and the recycling calcining furnace in sequence, so as to be converted into high-purity magnesium oxide and mixed chlorine salts, thereby protecting the environment and conserving resources.

[0212] The waste-acid processing unit 73 includes a neutralization pit, a filter, an evaporation crystallizer, and a drier connected in sequence, in which waste acid in the pickling area is processed by the neutralization pit, the filter, the evaporation crystallizer, and the drier in sequence and converted into dry magnesium salts, so as to eliminate waste acid discharge, to protect the environment, and to conserve resources. Therein, the neutralization pit and the acid-out channel are communicated.

[0213] FIG. 11 is a flowchart of a production line for producing GB-standard magnesium alloy ingots from magnesium alloy waste material of the present invention. As shown in FIG. 11, in order to produce magnesium alloy ingots from magnesium alloy waste material, magnesium alloy waste material is first processed by the pretreatment system 1 that selects magnesium alloy waste material and removes oxidation films and other coatings from the surface. The pretreated magnesium alloy waste material is placed into the pre-heating system 2. The magnesium alloy waste material is dried and pre-heated. The dried magnesium alloy waste material is placed into the smelting-and-refining system 3 to be melted and refined. The melted and refined liquid magnesium alloy (the melt) is transferred to the temperature-holding system 4 for heat preservation, thereby prevent the liquid magnesium alloy (the melt) from coagulation when transferring to the casting system 5. The liquid magnesium alloy (the melt) in the temperature-holding system 4 is transferred to the casting system 5 where it is formed into the semi-finished product of the GB-standard magnesium alloy. The semi-finished product of the GB-standard magnesium alloy is placed into post-treatment system 6. The burnisher 61 in the post-treatment system 6 burnish the surface of the semi-finished product of the GB-standard magnesium alloy ingots, so as to obtain GB-standard magnesium alloy ingots that has qualified surface quality as final product. Waste gas, magnesium slag, and waste acid generated in the smelting-and-refining system 3 of the production line are processed by the exhaust-processing unit 71, the residue processing unit 72, and the waste-acid processing unit 73 of the environmental protection system 7, respectively. The detailed flow is described below.

[0214] The magnesium alloy waste material first enters the pretreatment system 1, and receives manual sorting in the first sorting unit 171 of the sorting device 17, with visible impurities such as screws and rubber and other non-magnesium alloy waste materials removed from the magnesium alloy waste material. Then the magnesium alloy waste material enters the material-holding device 101 of the high-pressure cleaning device 10 for high-pressure cleaning, before it is loaded into the drum 111 of the batch-containing device 11. The hoisting device 14 uses the two hoisting elements 1113 on the rotatory shaft 116 to lift the drum 111 and moves it to the pickling area 12. The two rotating bearings 1112 on the rotatory shaft 116 are settled on the two pickling force-bearing seats 1211 of the pickling bath 121, respectively. The drum 11 is placed into pickling bath 121. The transmission gear 1111 of the rotatory shaft 116 and the motor gear 1121 of the drive motor 112 engage with each other. The drive motor 112 drives the rotatory shaft 116 to rotate, and thereby the drum 111 rotates in the pickling bath 121. The magnesium alloy waste material in the drum 111 randomly rolls as the drum 111 rotates, thereby ensuring sufficient contact between the magnesium alloy waste material and the acid liquid. Meanwhile, impurities attached to the surface of the magnesium alloy waste material (especially those in grooves) are more likely to come off in the rolling process, thereby harmful impurities on the surface of the magnesium alloy waste material are removed. After pickling, the drum 111 is placed into the rinse unit 131 of the water-rinse area 13 by the hoisting device 14. The two rotating bearings 1112 of the rotatory shaft 116 are settled in the two rinse force-bearing seats 13111, respectively. The drum 11 is placed into the rinse bath 1311, and the drive motor 112 drives the rotatory shaft 116 to rotate and thus drives the drum 111 to rotate for rinse. The magnesium alloy waste material in the drum 111 rolls randomly with the drum 111, thereby ensuring sufficient contact between magnesium alloy waste material and water. The magnesium alloy waste material receives first water-rinse in the rinse bath 311 for preliminarily removing residual acid and residue on the magnesium alloy waste material's surface. After rinse, the drum 111 is moved by the hoisting device 14 and placed into the material unloading unit 132. The drum 111 performs material unloading via the discharge hopper 1321 with the assistance of the hoisting device 14. The spraying conveyer 1333 of the spraying unit 133 has one end thereof disposed below the discharge hopper 1321. The magnesium alloy waste material unloaded from the discharge hopper 1321 is laid evenly on the spraying conveyer 1333. The spraying conveyer 1333 conveys it to a place below the water nozzles 1332. The water nozzles 1332 sprinkle water on the magnesium alloy waste material on the spraying conveyer 1333. The magnesium alloy waste material is thus washed for a second time by the spraying unit 133, so as to further clean residual acid and residue left on the magnesium alloy waste material's surface. After the magnesium alloy waste material receives water-rinse through the entire water-rinse area 13, it is transferred to the dewatering-drying device 16. In the dewatering-drying device 16, the air-blowing unit 161 preliminarily removes liquid on the magnesium alloy waste material's surface, and the hot-air drying unit 162 provides secondarily drying by hot-air, thereby obtaining dry magnesium alloy waste material with its surface stripped. It then enters the second sorting unit 172 for second sorting, thereby ensuring that all the impurities other than magnesium alloy waste material in the magnesium alloy waste material are cleaned. This allows the magnesium alloy waste material to be used directly as raw material for producing the GB-standard magnesium alloy ingots. The pretreatment process thus ends here. Afterward, the batch container 22 of the pre-heating system 2 carrying the waste into the drying cabinet 21. The pre-heating air-extracting device 23 extracts moisture from the drying cabinet 21 for pre-heating and drying. The magnesium alloy waste material then enters the smelting-and-refining system 3 to be processed into magnesium alloy melt, namely magnesium alloy in the form of liquid. It first enters the smelting furnace 31 of the refining unit 31 to be heated and melted. With operation of the agitating device 315 and the degasing device 316, the waste is refined and/or alloyed into liquid magnesium alloy. Then the slag-skimming unit 32 removes magnesium slag from the liquid magnesium alloy by pre-heating the slag collector 321 and immersing it into the magnesium smelting crucible 311 in the smelting furnace. The air-blowing device 322 blows magnesium slag from the bottom of the magnesium smelting crucible 311 and makes it fall in the slag collector 321, thereby removing magnesium slag from the magnesium alloy melt, increasing magnesium alloy's purity in the magnesium alloy melt. The liquid magnesium alloy is then drawn into the casting pump 331 through the liquid-in duct 332 of the liquid-transferring unit 33. The liquid-out duct 333 thus transfers it into the temperature-holding system 4 or the casting system 5. In the temperature-holding system 4, the liquid magnesium alloy is sent through the liquid-out duct 316 to the temperature-holding crucible 411 of the temperature-holding furnace 41 in the temperature-holding system 4 to hold the temperature while standing still. The liquid magnesium alloy is poured into the ingot mold 512 of the ingot casting unit 51 through the fixed-quantity pouring pump 52 at a speed controlled by the pouring control unit 53, thereby forming magnesium alloy ingots. The waste is processed by the post-treatment system 6 through the burnisher 61, the code printer 62, and the packing machine 63 in sequence to obtain the final product of the GB-standard magnesium alloy ingot.

[0215] The present invention has been described with reference to the preferred embodiments and it is understood that the embodiments are not intended to limit the scope of the present invention. Moreover, as the contents disclosed herein should be readily understood and can be implemented by a person skilled in the art, all equivalent changes or modifications which do not depart from the concept of the present invention should be encompassed by the appended claims.