Composite material and method for preparing the same

Abstract

Disclosed are a composite material and a method for preparing the same. The composite material is consisted of TiO.sub.2 and BaZn.sub.1.2Co.sub.0.8Fe.sub.16O.sub.27. The composite material of the invention has the advantages of high absorption frequency band, good compatibility and wide frequency band, and it is applicable for the shell protection material of a mobile phone or a TV set, thereby absorbing the electromagnetic wave band that is the most harmful to human bodies, without influencing the normal communication function of an electronic device, for example, a mobile phone.

Claims

1. A composite material, comprising TiO.sub.2-coated BaZn.sub.1.2Co.sub.0.8Fe.sub.16O.sub.27 particulates.

2. The composite material according to claim 1, wherein, a weight ratio of TiO.sub.2 to BaZn.sub.1.2Co.sub.0.8Fe.sub.16O.sub.27 is (0.1-10):(1-10).

3. The composite material according to claim 1, wherein, the composite material is a powder with a micrometer-level grain size.

4. The composite material according to claim 1, wherein, a reflection loss of the composite material at 7.76-13.68 GHz is less than 10 dB, and a reflection loss thereof at 10.3 GHz is 47.6 dB.

5. An electronic device shell, which is made from a raw material comprising the composite material according to claim 1.

6. The electronic device shell according to claim 5, wherein, the weight ratio of TiO.sub.2 to BaZn.sub.1.2Co.sub.0.8Fe.sub.16O.sub.27 is (0.1-10):(1-10).

7. The electronic device shell according to claim 5, wherein, the composite material is a powder with a micrometer-level grain size.

8. The electronic device shell according to claim 5, wherein, the reflection loss of the composite material at 7.76-13.68 GHz is less than 10 dB, and the reflection loss thereof at 10.3 GHz is -47.6 dB.

9. The electronic device shell according to claim 5, wherein, the electronic device is a mobile phone.

10. A method for preparing a composite material, comprising the steps of: dissolving Ba(NO.sub.3).sub.2, Zn(NO.sub.3).sub.2.6H.sub.2O, Co(NO.sub.3).sub.2.6H.sub.2O and Fe(NO.sub.3).sub.3.9H.sub.2O in distilled water at a molar ratio of 1:1.2:0.8:16, adding a citric acid at a molar ratio of 10:1 relative to Ba(NO.sub.3).sub.2, stirring till complete dissolution, adjusting a pH value of a resultant solution to neutrality, evaporating the solution to prepare a sol, drying to obtain a gel, and then calcining the gel to obtain BaZn.sub.1.2Co.sub.0.8Fe.sub.16O.sub.27; and adding BaZn.sub.1.2Co.sub.0.8Fe.sub.16O.sub.27 into a TiO.sub.2 sol, stirring and filtering, washing the obtained filter residue, drying the obtained filter residue to obtain a precursor, and drying the precursor to obtain the composite material which comprises TiO.sub.2-coated BaZn.sub.1.2Co.sub.0.8Fe.sub.16O.sub.27 particulates.

11. The method according to claim 10, wherein, Ba(NO.sub.3).sub.2 is analytically pure Ba(NO.sub.3).sub.2, Zn(NO.sub.3).sub.2.6H.sub.2O is analytically pure Zn(NO.sub.3).sub.2.6H.sub.2O, Co(NO.sub.3).sub.2.6H.sub.2O is analytically pure Co(NO.sub.3).sub.2.6H.sub.2O, Fe(NO.sub.3).sub.3.9H.sub.2O is analytically pure Fe(NO.sub.3).sub.3.9H.sub.2O.

12. The method according to claim 10, wherein, the evaporation is constant-temperature evaporation in 70 C. water bath.

13. The method according to claim 10, wherein, before being calcined at 1300 C., the gel is ground into powder.

14. The method according to claim 10, wherein, the filter residue is washed with absolute ethyl alcohol.

15. The method according to claim 14, wherein, the filter residue washed with absolute ethyl alcohol is dried at 80 C.

16. The method according to claim 10, wherein, the TiO.sub.2 sol is prepared by: dissolving 2 parts by weight of butyl titanate and 1 part by weight of glacial acetic acid in 10 parts by weight of absolute ethyl alcohol, and stirring to obtain a transparent solution; and adding 4 parts by weight of an ethanol solution with a volume fraction of 75% dropwise into the transparent solution slowly, and stirring to obtain the TiO.sub.2 sol.

17. The method according to claim 10, wherein, the calcining is performed at 1300 C.

18. The method according to claim 10, wherein, a weight ratio of TiO.sub.2 to BaZn.sub.1.2Co.sub.0.8Fe.sub.16O.sub.27 is (0.1-10):(1-10).

Description

BRIEF DESCRIPTION

(1) FIG. 1 shows XRD diagrams of a BaW/TiO.sub.2 composite material, BaW and TiO.sub.2 according to Embodiment 1;

(2) FIG. 2 shows an SEM diagram of a sample of the BaW/TiO.sub.2 composite material according to Embodiment 1; and

(3) FIG. 3 shows reflection loss curves of the BaW/TiO.sub.2 composite material and BaW according to Embodiment 1.

DETAILED DESCRIPTION

(4) The composite material of the embodiment of the invention comprises TiO.sub.2 and BaZn.sub.1.2Co.sub.0.8Fe.sub.16O.sub.27. Optionally, the composite material is a powder with a micrometer-level grain size. Optionally, the reflection loss of the composite material at 7.76-13.68 GHz is less than 10 dB, and the reflection loss thereof at 10.3 GHz is 47.6 dB.

(5) The composite material of the embodiment of the invention has the advantages of high absorption frequency band, good compatibility and wide frequency band, and it may be used as the material of the shell of an electronic device such as a mobile phone, etc., thereby absorbing the electromagnetic wave band that is the most harmful to human bodies, without influencing the normal communication function of an electronic device, for example, a mobile phone.

(6) The specific implementation modes of the invention will be further described in detail below in conjunction with the drawings and embodiments. The embodiments below are used for illustrating the invention, rather than limiting the scope of the invention.

(7) Embodiment 1

(8) 1) Preparation of BaZn.sub.1.2Co.sub.0.8Fe.sub.16O.sub.27:

(9) First Step: 2.61 g Ba(NO.sub.3).sub.2, 2.97 g Zn(NO.sub.3).sub.2.6H.sub.2O, 2.91 g Co(NO.sub.3).sub.2.6H.sub.2O and 3.42 g Fe(NO.sub.3).sub.3.9H.sub.2O are dissolved in 50 mL distilled water, and after sufficient dissolution, 19.5 g analytically pure citric acid is added thereto and is stirred sufficiently till complete dissolution, and then the pH of the solution is adjusted to neutrality with ethylene diamine.

(10) Second Step: The above solution is placed in a 70 C. water bath for constant-temperature evaporation to prepare a sol, and it is dried to obtain a gel. The gel is ground to powder and calcined at 1300 C. for 3 h to obtain BaW particulates.

(11) Third Step: 2 mg butyl titanate and 1 mg glacial acetic acid are dissolved in 10 mg absolute ethyl alcohol and stirred sufficiently to obtain a transparent solution A, and 4 mg ethanol solution with a volume fraction of 75% is added dropwise into solution A, and it is stirred for 30 min to obtain a light yellow TiO.sub.2 sol. 7.94 g BaW powder is weighted out and added into the sol, and it is filtered after being stirred for 3 h at room temperature, the obtained filter residue is washed with absolute ethyl alcohol, and then the obtained filter residue is dried at 80 C. for 10 h to obtain a precursor. The precursor is dried at 500 C. for 3 h to obtain a BaW/TiO.sub.2 composite material powder that is composed of TiO.sub.2-coated BaZn.sub.1.2Co.sub.0.8Fe.sub.16O.sub.27 particulates, wherein the grain size of the powder is at micrometer-level (1-1000 um).

(12) 2) The structure, compositions, appearance, magnetic performance and wave-absorbing performance of the composite material BaW/TiO.sub.2:

(13) The BaW/TiO.sub.2 composite material obtained in Embodiment 1 is mixed with paraffin with a mass ratio of 2.4:1, and pressed into an annular sample with an outer diameter of 7 mm, an inner diameter of 3 mm and a thickness of about 4 mm via a mould.

(14) The BaW/TiO.sub.2 composite material sample is observed via a scanning electron microscope, and the result is as shown in FIG. 2. The BaW/TiO.sub.2 composite material is a micrometer-level wave-absorbing material.

(15) The BaW/TiO.sub.2 composite material sample is analyzed via X-ray diffraction, the result is as shown in FIG. 1, and it indicates that the composite material obtained is truly a BaW/TiO.sub.2 composite material.

(16) The electromagnetic parameters thereof, i.e., real part of magnetic permeability ()imaginary part of magnetic permeability (), real part of dielectric constant () and imaginary part of dielectric constant (), are tested in a range of 2-18 GHz via a vector network analyzer.

(17) The reflectivity R(dB) of the sample is finally simulated via complex magnetic permeability r=j, complex dielectric constant r=j and formula

(18) $Z_{\mathrm{in}}=\sqrt{\frac{{}_r}{{\mathrm{.Math.}}_r}}\tanh \left(j\frac{2\mathrm{fd}}{c}\sqrt{{}_r{\mathrm{.Math.}}_r}\right)\mathrm{and}$$R\left(\mathrm{dB}\right)=20\lg .Math.\frac{Z_{\mathrm{in}}-1}{Z_{\mathrm{in}}+1}.Math..$

(19) It is measured that the reflection loss of the BaW/TiO.sub.2 composite material sample at 7.76-13.68 GHz is less than 10 dB, and the reflection loss thereof at 10.3 GHz is 47.6 dB (as shown in FIG. 3). The bandwidth of the BaW/TiO.sub.2 composite material sample at which the electromagnetic wave reflectivity is less than 10 dB may reach 3.92 GHz and the minimum reflectivity is 47.6 dB, which indicates that the BaW/TiO.sub.2 composite material has the advantages of high absorption frequency band, good compatibility and wide frequency band.

(20) The above description only shows some preferred embodiments of the invention. It should be noted that, various improvements and substitutions may also be made by one of ordinary skills in the art without departing from the technical principles of the invention, and all these improvements and substitutions should be regarded as falling into the protection scope of the invention.